CN115417594A - Energy powder, preparation method and ceramic tile - Google Patents
Energy powder, preparation method and ceramic tile Download PDFInfo
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- CN115417594A CN115417594A CN202211102710.6A CN202211102710A CN115417594A CN 115417594 A CN115417594 A CN 115417594A CN 202211102710 A CN202211102710 A CN 202211102710A CN 115417594 A CN115417594 A CN 115417594A
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- energy powder
- powder
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- energy
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/02—Pretreated ingredients
- C03C1/026—Pelletisation or prereacting of powdered raw materials
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2204/00—Glasses, glazes or enamels with special properties
- C03C2204/02—Antibacterial glass, glaze or enamel
Abstract
The invention belongs to the technical field of energy powder, and particularly discloses energy powder, a preparation method and a ceramic tile, which comprise the following components in parts by weight: 35.0 to 99.9 parts of inorganic powder, 20 to 50 parts of metal oxide and 0.05 to 2.00 parts of lanthanide rare earth; the energy powder is modified through a coherent field, and can continuously radiate terahertz waves. The energy powder of the invention can play a good antibacterial effect, has high removal rate to formaldehyde and ammonia gas, and the inorganic powder and metal oxide in the energy powder are common inorganic materials, and have abundant raw materials and no harm to human health.
Description
Technical Field
The invention relates to the technical field of energy powder, and particularly relates to energy powder, a preparation method and a ceramic tile.
Background
With the improvement of the quality of life, people have higher and higher requirements on functionality and environmental protection of decorative materials. Due to the production process and technical problems of the decorative material, TVOC such as formaldehyde and the like are inevitably generated, and the harmful gases are volatilized from the decorative material and exist in the air, thus being easy to harm the health of human bodies.
In the prior art, a spray for removing formaldehyde is sprayed indoors or a catalytic substance for catalyzing formaldehyde is placed indoors, but the formaldehyde removing effect can be achieved only in a short time or the formaldehyde in the decorative material is ineffective after a period of time, but the formaldehyde in the decorative material is continuously volatilized, and the method is not taken a long time.
In addition, bacteria also exist in the air, and enter human bodies through respiratory tracts, so that the health is endangered. In the prior art, nano silver, nano zinc oxide, nano titanium dioxide (photocatalyst) and the like are added on the surface of the decorative material, and metal ions of the material are combined with protein on the surface of bacteria, so that the structure of the bacteria is destroyed, the bacteria are killed, and the antibacterial effect is achieved. Meanwhile, the nanometer material has small granularity and large specific surface area, is easy to enter human bodies when contacting with the skin of the human bodies, and has certain harm to the health of the human bodies. The negative ion powder is added on the surface of the decorative material, but the method belongs to contact antibacterial, dirt such as dust falling on the surface of the decorative material can obstruct the contact of bacteria and the negative ion powder, the antibacterial performance is greatly influenced, and the negative ion powder has very high radioactivity and is unsafe per se.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention provides energy powder, a preparation method and a ceramic tile.
The technical scheme adopted by the invention for solving the technical problem is as follows:
an energy powder comprises the following components in parts by weight:
35.0 to 99.9 parts of inorganic powder;
20-50 parts of metal oxide;
0.05-2.00 parts of lanthanide rare earth;
the energy powder is modified through a coherent field and can continuously radiate terahertz waves.
In the scheme, the energy powder is applied to decorative materials needing high-temperature firing, such as artificial quartz stone, ceramic tiles and the like. The metal oxide is high-temperature resistant and keeps stability in the high-temperature sintering process, so that the effect of protecting the energy powder is achieved, and the energy powder can continuously and stably radiate terahertz waves after being sintered at high temperature; the lanthanide rare earth mainly has a catalytic function, and catalyzes energy powder sintered at high temperature, so that the energy powder can continuously absorb infrared light waves in a space and radiate terahertz waves. The coherent field is introduced to modify the energy powder, so that the inorganic powder absorbs certain energy, and the spontaneous radiation of the inorganic powder is modulated by changing the amplitude, phase and frequency of the coherent field, so that the energy powder has the capability of absorbing infrared light waves for a long time and continuously radiating terahertz waves.
Preferably, the inorganic powder is quartz powder or potassium feldspar. Specifically, the quartz powder and the potassium feldspar both have good energy storage performance, and under the modification of the coherent field, the quartz powder and the potassium feldspar can continuously absorb infrared light waves in the space and radiate terahertz waves. In addition, the quartz powder and the potassium feldspar are common inorganic materials, the raw materials are rich, and no harm is caused to the human health.
Preferably, the metal oxide is one or more of magnesium oxide, aluminum oxide and calcium oxide, preferably aluminum oxide. Specifically, the alumina has a high melting point (higher than quartz powder and potassium feldspar), has high temperature resistance, and can keep stability during high-temperature sintering of the ceramic tile.
Preferably, the lanthanide rare earth is one or more of cerium oxide, lanthanum oxide and europium oxide. Specifically, the cerium oxide, the lanthanum oxide and the europium oxide have the characteristics of well absorbing natural infrared waves and continuously radiating terahertz waves, and can catalyze and excite the quartz powder or the potash feldspar modified by the additional coherent field, so that the energy powder absorbs the infrared waves and continuously radiates the terahertz waves.
In addition, a preparation method of the energy powder is also disclosed, and the preparation method of the energy powder is used for preparing the energy powder.
Preferably, the preparation method comprises the following steps:
a. uniformly mixing inorganic powder, metal oxide and lanthanide rare earth to obtain a mixture;
b. b, placing the mixture obtained in the step a into an inner cavity of a muffle furnace, wherein a diode is distributed on the inner wall of the inner cavity of the muffle furnace, and a luminous body of the diode is a rare earth compound;
c. and electrifying the muffle furnace to keep the temperature of the inner cavity between 35 and 100 ℃, emitting light by the diode, and irradiating the mixture for 5 to 10 days (d is the number of days) to obtain the energy powder.
Specifically, a coherent field of 0.1 to 10T (terahertz) is introduced through the process, and a certain amount of energy is given to the energy powder.
Preferably, the rare earth compound is a compound of cerium oxide, lanthanum oxide and europium oxide with the purity of 99.9990-99.9999%. Specifically, a compound of cerium oxide, lanthanum oxide and europium oxide with the purity of 99.9990-99.9999% (the purity is the proportion of the compound of cerium oxide, lanthanum oxide and europium oxide in the rare earth compound) is used as a light emitting body of the diode, and the cerium oxide, the lanthanum oxide and the europium oxide in the compound are excited under the electrification to generate a strong coherent field.
The ceramic tile comprises a green body layer and a surface glaze layer, wherein the surface glaze layer comprises a base glaze and the energy powder, and the mass ratio of the energy powder to the base glaze is 0.02-0.03: 1. the energy powder is prepared by mixing the following components in a mass ratio of 0.02 to 0.03:1 into the base glaze, and producing the ceramic tile according to the disclosed process, wherein the added energy powder has no influence on the production process. Wherein the inorganic powder in the energy powder is potassium feldspar. The mesh number of the potassium feldspar is preferably 200 to 300 meshes.
The artificial quartz stone comprises a base material and the energy powder, and the mass ratio of the energy powder to the base material is 0.003 to 0.005:1. and (2) mixing the energy powder according to the mass ratio of 0.003 to 0.005: the proportion of 1 is added into a base material for producing the artificial quartz stone, the artificial quartz stone is produced according to the disclosed process, and the added energy powder has no influence on the production process. Wherein the inorganic powder in the energy powder is quartz powder. The mesh number of the quartz powder is preferably 200 to 300 meshes.
The invention has at least one of the following beneficial effects:
1. the ceramic tile added with the energy powder has a good antibacterial effect on staphylococcus aureus, and shows that the energy powder modified by the coherent field can continuously radiate terahertz waves, and the terahertz waves change the membrane potential of bacteria and the polar molecular structure on the surface of the membrane, so that proteins and physiologically active substances in the bacteria are changed, the bacteria lose vitality or die, and the antibacterial effect is achieved.
2. Inorganic powder and metal oxide in the energy powder are common inorganic materials, and the raw materials are rich and do not harm human health.
3. The ceramic tile has higher removal rate of formaldehyde and ammonia gas. The energy powder in the ceramic tile can generate continuous terahertz waves, namely ultra-far infrared light waves, and can effectively decompose polar molecular gases such as formaldehyde, ammonia and the like in the air into carbon dioxide and water, so that the effect of removing the formaldehyde and the ammonia can be achieved.
Detailed Description
The following further describes the embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, and is not intended to limit the present invention. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Example 1
Uniformly mixing 35.0 parts of potassium feldspar, 20 parts of alumina and 0.05 part of lanthanide rare earth to obtain a mixture, wherein the lanthanide rare earth is compounded by cerium oxide, lanthanum oxide and europium oxide; placing the mixture in an inner cavity of a muffle furnace, wherein a diode is distributed on the inner wall of the inner cavity of the muffle furnace, and a luminous body of the diode is a compound of cerium oxide, lanthanum oxide and europium oxide with the purity of 99.9999%; and electrifying the muffle furnace to keep the temperature of the inner cavity at 40 ℃, emitting light by the diode, and irradiating the mixture for 7d to obtain the energy powder. Energy powder is mixed according to the mass ratio of 0.02: the proportion of 1 is added into the basic glaze for producing the ceramic tile, and the ceramic tile is produced according to the disclosed process.
Example 2
Uniformly mixing 70.0 parts of potassium feldspar, 32 parts of alumina and 0.31 part of lanthanide rare earth to obtain a mixture, wherein the lanthanide rare earth is compounded by cerium oxide, lanthanum oxide and europium oxide; placing the mixture in an inner cavity of a muffle furnace, wherein a diode is distributed on the inner wall of the inner cavity of the muffle furnace, and a luminous body of the diode selects a compound of cerium oxide, lanthanum oxide and europium oxide with the purity of 99.9999 percent; and electrifying the muffle furnace to keep the temperature of the inner cavity at 40 ℃, emitting light by the diode, and irradiating the mixture for 7d to obtain the energy powder. Energy powder is mixed according to the mass ratio of 0.02:1 is added into the base glaze for producing the ceramic tile and the ceramic tile is produced according to the disclosed process.
Example 3
Uniformly mixing 92.3 parts of potassium feldspar, 44 parts of alumina and 1.20 parts of lanthanide rare earth to obtain a mixture, wherein the lanthanide rare earth is compounded by cerium oxide, lanthanum oxide and europium oxide; placing the mixture in an inner cavity of a muffle furnace, wherein a diode is distributed on the inner wall of the inner cavity of the muffle furnace, and a luminous body of the diode is a compound of cerium oxide, lanthanum oxide and europium oxide with the purity of 99.9999%; and electrifying the muffle furnace to keep the temperature of the inner cavity at 40 ℃, emitting light by the diode, and irradiating the mixture for 7d to obtain the energy powder. Energy powder is mixed according to the mass ratio of 0.02: the proportion of 1 is added into the basic glaze for producing the ceramic tile, and the ceramic tile is produced according to the disclosed process.
And (4) performance testing: the tile of example 1 was tested for antibacterial properties and for formaldehyde and ammonia removal rates.
1. Detection of antibacterial Properties
The detection mechanism comprises: the microbial analysis and detection center in Guangdong province;
detection basis and method: JC/T897-2014;
the results are shown in Table 1 below
Table 1:
2. detection of formaldehyde and ammonia removal rate
The detection mechanism comprises: the Guangdong province microorganism analysis and detection center;
detection basis and method: QB/T2761-2006;
the results are shown in Table 2 below
Table 2:
as shown in table 1, the ceramic tile of the present embodiment has a good antibacterial effect on staphylococcus aureus, which indicates that the energy powder modified by the coherent field can continuously radiate terahertz waves, which changes the membrane potential of bacteria and the polar molecular structure on the membrane surface, and causes variation of proteins and physiologically active substances in the bacteria, so that the bacteria lose vitality or die, thereby playing an antibacterial role; the potassium feldspar and the aluminum oxide in the energy powder are common inorganic materials, and the raw materials are rich and do not harm human health; as shown in table 2, the tile of this example has a high removal rate of formaldehyde and ammonia gas. The energy powder in the ceramic tile can generate continuous terahertz waves, namely ultra-far infrared light waves, can effectively decompose polar molecular gases such as formaldehyde, ammonia and the like in the air, the polar molecular gases have dipole moments, absorb the bond length and bond angle vibration of molecules after ultra-far infrared light waves, the dipole moments are repeatedly changed, and energy is absorbed, so that C-H and N-H bonds in the molecules are broken, and the bonds are decomposed into carbon dioxide and water, thereby playing a role in removing the formaldehyde and the ammonia.
Example 4
Uniformly mixing 99.9 parts of quartz powder, 50 parts of alumina and 2.00 parts of lanthanide rare earth to obtain a mixture, wherein the lanthanide rare earth is compounded by cerium oxide, lanthanum oxide and europium oxide; placing the mixture in an inner cavity of a muffle furnace, wherein a diode is distributed on the inner wall of the inner cavity of the muffle furnace, and a luminous body of the diode selects a compound of cerium oxide, lanthanum oxide and europium oxide with the purity of 99.9999 percent; and electrifying the muffle furnace to keep the temperature of the inner cavity at 70 ℃, emitting light by the diode, and irradiating the mixture for 7d to obtain the energy powder. Energy powder is added according to the mass ratio of 0.004: the proportion of 1 is added into a base material for producing the artificial quartz stone, and the artificial quartz stone is produced according to the disclosed process.
And (3) performance testing: the artificial quartz stone of the above example 4 was subjected to the antibacterial property test;
1. detection of antibacterial Properties
The detection mechanism comprises: the Guangdong province microorganism analysis and detection center;
detection basis and method: JC/T897-2014;
the results are shown in Table 3 below
Table 3:
as shown in table 3, the artificial quartzite of the embodiment has a good antibacterial effect on escherichia coli and staphylococcus aureus, which indicates that the energy powder modified by the coherent field can continuously radiate terahertz waves, which changes the membrane potential and the polar molecular structure on the membrane surface of bacteria, and changes proteins and physiologically active substances in the bacteria, so that the bacteria lose vitality or die, thereby playing an antibacterial role.
The embodiments of the present invention have been described in detail above, but the present invention is not limited to the described embodiments. It will be apparent to those skilled in the art that various changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, and the scope of protection is still within the scope of the invention.
Claims (8)
1. The energy powder is characterized by comprising the following components in parts by weight:
35.0 to 99.9 parts of inorganic powder;
20 to 50 parts of metal oxide;
0.05-2.00 parts of lanthanide rare earth;
the energy powder is modified through a coherent field and can continuously radiate terahertz waves.
2. An energy powder according to claim 1, wherein: the inorganic powder is quartz powder or potassium feldspar.
3. An energy powder according to claim 1, wherein: the metal oxide is one or more of magnesium oxide, aluminum oxide and calcium oxide.
4. An energy powder according to claim 1, wherein: the lanthanide rare earth is one or more of cerium oxide, lanthanum oxide and europium oxide.
5. The preparation method of the energy powder is characterized by comprising the following steps: the preparation method of the energy powder is used for preparing the energy powder as claimed in any one of claims 1 to 4.
6. The method for producing an energy powder according to claim 5, characterized in that: the preparation method comprises the following steps:
a. uniformly mixing inorganic powder, metal oxide and lanthanide rare earth to obtain a mixture;
b. placing the mixture obtained in the step a into an inner cavity of a muffle furnace, wherein diodes are distributed on the inner wall of the inner cavity of the muffle furnace, and luminous bodies of the diodes are rare earth compounds;
c. and electrifying the muffle furnace to keep the temperature of the inner cavity between 35 and 100 ℃, emitting light by the diode, and irradiating the mixture for 5 to 10 days to obtain the energy powder.
7. The method for producing an energy powder according to claim 6, characterized in that: the rare earth compound is a compound of cerium oxide, lanthanum oxide and europium oxide with the purity of 99.9990-99.9999%.
8. A ceramic tile characterized by: the glaze comprises a blank layer and a surface glaze layer, the surface glaze layer comprises a base glaze and the energy powder as defined in any one of claims 1 to 4, and the mass ratio of the energy powder to the base glaze is 0.02 to 0.03:1.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202211102710.6A CN115417594A (en) | 2022-09-09 | 2022-09-09 | Energy powder, preparation method and ceramic tile |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202211102710.6A CN115417594A (en) | 2022-09-09 | 2022-09-09 | Energy powder, preparation method and ceramic tile |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100084570A1 (en) * | 2008-10-08 | 2010-04-08 | Canon Kabushiki Kaisha | Terahertz wave generator |
| CN211383481U (en) * | 2019-06-28 | 2020-09-01 | 广州颜媚医疗器械有限公司 | Physiotherapy equipment |
| CN113416056A (en) * | 2021-02-02 | 2021-09-21 | 国启艾福佳健康科技(山东)有限公司 | Ceramic energy storage tube and preparation method thereof |
| CN113526948A (en) * | 2021-07-13 | 2021-10-22 | 泉州慈光科技有限公司 | Terahertz source emitting material, terahertz emitter and terahertz bedding |
| CN113832802A (en) * | 2021-08-18 | 2021-12-24 | 广州傲胜人造草股份有限公司 | Artificial lawn with terahertz frequency electromagnetic wave and manufacturing process thereof |
-
2022
- 2022-09-09 CN CN202211102710.6A patent/CN115417594A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100084570A1 (en) * | 2008-10-08 | 2010-04-08 | Canon Kabushiki Kaisha | Terahertz wave generator |
| CN211383481U (en) * | 2019-06-28 | 2020-09-01 | 广州颜媚医疗器械有限公司 | Physiotherapy equipment |
| CN113416056A (en) * | 2021-02-02 | 2021-09-21 | 国启艾福佳健康科技(山东)有限公司 | Ceramic energy storage tube and preparation method thereof |
| CN113526948A (en) * | 2021-07-13 | 2021-10-22 | 泉州慈光科技有限公司 | Terahertz source emitting material, terahertz emitter and terahertz bedding |
| CN113832802A (en) * | 2021-08-18 | 2021-12-24 | 广州傲胜人造草股份有限公司 | Artificial lawn with terahertz frequency electromagnetic wave and manufacturing process thereof |
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