CN115353326A - Reflective anti-vehicle-mark asphalt and preparation method thereof - Google Patents
Reflective anti-vehicle-mark asphalt and preparation method thereof Download PDFInfo
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- CN115353326A CN115353326A CN202210893380.0A CN202210893380A CN115353326A CN 115353326 A CN115353326 A CN 115353326A CN 202210893380 A CN202210893380 A CN 202210893380A CN 115353326 A CN115353326 A CN 115353326A
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- 239000010426 asphalt Substances 0.000 title claims abstract description 72
- 238000002360 preparation method Methods 0.000 title claims abstract description 25
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 63
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 51
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000002134 carbon nanofiber Substances 0.000 claims abstract description 42
- 239000004471 Glycine Substances 0.000 claims abstract description 21
- 239000004831 Hot glue Substances 0.000 claims abstract description 21
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 20
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 18
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 150000002009 diols Chemical class 0.000 claims abstract description 18
- 229920000909 polytetrahydrofuran Polymers 0.000 claims abstract description 18
- CFPHMAVQAJGVPV-UHFFFAOYSA-N 2-sulfanylbutanoic acid Chemical compound CCC(S)C(O)=O CFPHMAVQAJGVPV-UHFFFAOYSA-N 0.000 claims abstract description 17
- CPVBZQZTHLHWLI-UHFFFAOYSA-N (5-chloro-2-hydroxy-4-methylphenyl)-(2-chlorophenyl)methanone Chemical compound C1=C(Cl)C(C)=CC(O)=C1C(=O)C1=CC=CC=C1Cl CPVBZQZTHLHWLI-UHFFFAOYSA-N 0.000 claims abstract description 11
- AXDZFGRFZOQVBV-UHFFFAOYSA-N 2-chlorocyclopentan-1-one Chemical compound ClC1CCCC1=O AXDZFGRFZOQVBV-UHFFFAOYSA-N 0.000 claims abstract description 11
- XYAVQXSVVRVAKJ-UHFFFAOYSA-N 3-(oxiran-2-ylmethoxy)benzoic acid Chemical compound OC(=O)C1=CC=CC(OCC2OC2)=C1 XYAVQXSVVRVAKJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 4-amino-2-chloro-phenyl Chemical group 0.000 claims abstract description 8
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 claims abstract description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 42
- 238000002156 mixing Methods 0.000 claims description 34
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 19
- 239000004917 carbon fiber Substances 0.000 claims description 19
- 239000000243 solution Substances 0.000 claims description 19
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 15
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 15
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 14
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 14
- RHQDFWAXVIIEBN-UHFFFAOYSA-N Trifluoroethanol Chemical compound OCC(F)(F)F RHQDFWAXVIIEBN-UHFFFAOYSA-N 0.000 claims description 11
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 11
- 239000003981 vehicle Substances 0.000 claims description 10
- 239000011521 glass Substances 0.000 claims description 8
- 239000002243 precursor Substances 0.000 claims description 8
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 7
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 7
- HIZCIEIDIFGZSS-UHFFFAOYSA-L trithiocarbonate Chemical compound [S-]C([S-])=S HIZCIEIDIFGZSS-UHFFFAOYSA-L 0.000 claims description 7
- 239000012989 trithiocarbonate Substances 0.000 claims description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011324 bead Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 239000011259 mixed solution Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- 235000019738 Limestone Nutrition 0.000 claims description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 3
- 239000006028 limestone Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229910000831 Steel Inorganic materials 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 239000010959 steel Substances 0.000 claims description 2
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims 6
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- 239000004005 microsphere Substances 0.000 claims 2
- YZUPZGFPHUVJKC-UHFFFAOYSA-N 1-bromo-2-methoxyethane Chemical compound COCCBr YZUPZGFPHUVJKC-UHFFFAOYSA-N 0.000 claims 1
- 239000005711 Benzoic acid Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- 239000012965 benzophenone Substances 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229920006395 saturated elastomer Chemical class 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 15
- 230000000694 effects Effects 0.000 abstract description 14
- 230000002441 reversible effect Effects 0.000 abstract description 5
- 239000011384 asphalt concrete Substances 0.000 abstract description 3
- 230000000052 comparative effect Effects 0.000 description 14
- 150000001721 carbon Chemical class 0.000 description 10
- 238000002791 soaking Methods 0.000 description 8
- 238000009210 therapy by ultrasound Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000002265 prevention Effects 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical group C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 230000035876 healing Effects 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/26—Bituminous materials, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/38—Fibrous materials; Whiskers
- C04B14/386—Carbon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
- C04B20/023—Chemical treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/16—Sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4854—Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Abstract
The invention discloses a reflective anti-vehicle-mark asphalt and a preparation method thereof, and relates to the technical field of asphalt concrete. According to the invention, firstly, mercaptobutyric acid, sodium hydroxide, carbon disulfide, [5- (4-amino-2-chloro-phenyl) -2-furan ] methanol, polytetrahydrofuran diol, isophorone diisocyanate and 1, 3-bis (4-maleimide phenoxy) benzene are utilized to obtain a modified hot melt adhesive, and the photo-thermal reversible self-repairing effect is achieved; then utilizing carbon nano fiber, glycine, 2', 5-dichloro-2-hydroxy-4-methylbenzophenone, 3- (oxiranylmethoxy) benzoic acid and 2-chlorocyclopentanone to obtain modified carbon fiber; then negative pressure treatment is carried out to form a compact net structure, so that the car mark resistance and the light aging resistance of the asphalt are enhanced. The asphalt prepared by the invention has the effects of preventing car marks and resisting light aging.
Description
Technical Field
The invention relates to the technical field of asphalt concrete, in particular to reflective anti-vehicle-mark asphalt and a preparation method thereof.
Background
At present, in order to improve the visibility of a road surface at night and enable a driver to drive safely, glass beads are often added into asphalt concrete, and the light reflection characteristic of the glass beads can improve the brightness of the road surface under the irradiation of street lamps, car lamps and even weak moonlight at night. Asphalt pavement occupies a considerable proportion of highways due to its excellent service performance. However, in recent years, due to the limitations of the performance of the raw materials of the asphalt pavement, the increase of traffic volume and heavy-load overloaded vehicles, ruts appear to deteriorate the flatness of the pavement and cause other diseases such as net cracks, pits, holes and the like, and if the damage cannot be controlled in time, the ruts will be spread and cracked under the action of the outer load, so that the service life of the pavement structure is influenced, and the structure of the whole pavement is damaged.
Photo-oxidative aging is the main cause of long-term aging of asphalt roads. Ultraviolet energy exceeds the energy of broken bonds, and weak chemical bonds in asphalt molecules are broken to generate chemical reaction, so that the molecular structure is changed, and the performance is reduced. A large amount of condensed ring compounds, SBS modifiers and the like in the asphalt have strong ultraviolet absorption capacity, and undergo photolysis reaction to cause aging, thus influencing the service performance and the service life of roads. In western regions such as Xinjiang and Tibet in China, the altitude is high, the air is thin, the ultraviolet absorption radiation is particularly strong, the ultraviolet aging phenomenon can cause the temperature crack resistance and fatigue failure resistance of the asphalt pavement to be reduced, the pavement is easy to generate diseases such as cracks, pits and the like, and the service life of the asphalt pavement is shortened.
Disclosure of Invention
The invention aims to provide a reflective anti-vehicle-mark asphalt and a preparation method thereof, which are used for solving the problems in the prior art.
In order to solve the technical problems, the invention provides the following technical scheme: the reflective car-mark-proof asphalt mainly comprises foamed asphalt, modified hot melt adhesive, modified carbon fiber, glass beads, aggregate, LOF65-00 anti-stripping agent and mineral powder.
Further, the modified hot melt adhesive is prepared by reacting mercaptobutyric acid, sodium hydroxide and carbon disulfide, 5- (4-amino-2-chloro-phenyl) -2-furan ] methanol, polytetrahydrofuran diol, isophorone diisocyanate and 1, 3-bis (4-maleimide phenoxy) benzene.
Further, the modified carbon fiber is prepared from carbon nanofibers, glycine, 2', 5-dichloro-2-hydroxy-4-methylbenzophenone, 3- (oxiranylmethoxy) benzoic acid and 2-chlorocyclopentanone.
Further, the preparation method of the reflective anti-vehicle-mark asphalt comprises the following preparation steps:
(1) Mixing isophorone diisocyanate and N, N-dimethyl imide according to a mass ratio of 1.2-1, stirring at 50-60 ℃ and 80-100 rpm for 15-30 min, then adding polytetrahydrofuran diol 1000 and dibutyltin dilaurate according to a mass ratio of 1;
(2) Mixing a carbon fiber base material, sodium carbonate, trifluoroethanol and 2', 5-dichloro-2-hydroxy-4-methylbenzophenone according to a mass ratio of 1.0-1; mixing a modified precursor, 3- (ethylene oxide methoxyl) benzoic acid and chloroform according to the mass ratio of 1.4;
(3) Reacting the primary material, sodium carbonate, trifluoroethanol and 2-chlorocyclopentanone for 3-7 h at the mass ratio of 1.8-1.4;
(4) Mixing foamed asphalt, a modified hot melt adhesive and modified carbon fibers according to a mass ratio of 1.5.
Further, the preparation method of the trithiocarbonate in the step (1) comprises the following steps: mixing a mixed solution of sodium hydroxide and acetone according to a mass ratio of 1-18-1.
Further, the acetone mixed solution is prepared by mixing acetone and tetrahydrofuran according to a mass ratio of 1.13; the mercaptobutyric acid solution is prepared by mixing mercaptobutyric acid, acetone and tetrahydrofuran according to a mass ratio of 1.7.
Further, the preparation method of the carbon fiber base material in the step (2) comprises the following steps:
A. soaking the carbon nano fiber in acetone with the mass 2-5 times that of the carbon nano fiber, performing ultrasonic treatment at 25-35 kHz for 26-39 min, then soaking in absolute ethyl alcohol with the mass 3-7 times that of the carbon nano fiber, performing ultrasonic treatment at the same frequency for 20-36 min, then placing in nitric acid with the mass fraction of 65% and the mass 3-5 times that of the carbon nano fiber, and performing water bath treatment at 80-90 ℃ for 120-144 min to obtain pretreated carbon nano fiber;
B. placing the pretreated carbon nanofiber in a glycine solution with the mass 31-42 times that of the pretreated carbon nanofiber, wherein the mass ratio of glycine to deionized water in the glycine solution is 1.
Further, the length of the carbon nanofiber in the step A is 10-20 mu m, and the diameter of the carbon nanofiber is 150-200 nm.
Further, the preparation method of the foamed asphalt in the step (4) comprises the following steps: mixing the matrix asphalt at the temperature of 150-170 ℃ with the deionized water at the temperature of 40-50 ℃ according to the mass ratio of 100.
Further, the aggregate in the step (4) is one or a mixture of basalt, diabase, limestone or steel slag, and the particle size is 4.8-9.5 mm; the grain size of the glass beads is 2.4-4.7 mm.
Compared with the prior art, the invention has the following beneficial effects:
the invention takes the foamed asphalt as the raw material, mixes with the modified hot melt adhesive and the modified carbon fiber, and realizes the effects of car mark prevention and ultraviolet aging resistance through negative pressure treatment.
Firstly, mercaptobutyric acid, sodium hydroxide and carbon disulfide react to form a trithio compound, and chloride ions of [5- (4-amino-2-chloro-phenyl) -2-furan ] methanol substitute sodium ions of the trithio compound to obtain trithiocarbonate, which can be repeatedly self-repaired under ultraviolet light, so that the car mark trace is repaired, and the asphalt has the car mark prevention effect; then polymerizing hydroxyl of polytetrahydrofuran diol and isocyanate group of isophorone diisocyanate to obtain polyurethane, and further reacting the isocyanate group with amino of trithiocarbonate; then the furyl reacts with maleimide of 1, 3-bis (4-maleimide phenoxy) benzene to form a thermally reversible covalent bond, and the thermally reversible self-repairing effect is achieved, so that the modified hot melt adhesive is obtained; then, negative pressure treatment is carried out, so that the modified hot melt adhesive and the modified carbon fibers are filled into holes and cracks of the foamed asphalt and are mutually crosslinked to form a compact network structure, the stress is mutually dispersed, the bearing capacity of the asphalt is increased, and the anti-vehicle mark property of the asphalt is enhanced; in addition, the modified carbon fiber has a photo-thermal conversion effect and has a synergistic effect with the modified hot melt adhesive, so that the self-repairing performance of the hot melt adhesive is improved, and the car mark prevention effect of the asphalt is enhanced.
Secondly, preparing modified carbon fibers from carbon nanofibers, glycine, 2', 5-dichloro-2-hydroxy-4-methylbenzophenone, 3- (oxiranylmethoxy) benzoic acid and 2-chlorocyclopentanone; the amino group of glycine is grafted on the surface of the carbon nanofiber, chloride ions of 2', 5-dichloro-2-hydroxy-4-methylbenzophenone react with carboxyl of the glycine, then hydroxyl of the glycine reacts with 3- (oxiranylmethoxy) benzoic acid to form a ring-opening reaction, and then the carboxyl of the 3- (oxiranylmethoxy) benzoic acid reacts with chloride ions of 2-chlorocyclopentanone to form a benzoate compound which acts together with a benzophenone group to effectively absorb ultraviolet rays and improve the ultraviolet aging resistance of the asphalt; in addition, the residual chloride ions on the surface of the modified carbon fibers can react with the hydroxyl groups of the modified hot melt adhesive, so that the modified carbon fibers are mutually crosslinked and stacked to form an ultraviolet absorption network, and the ultraviolet aging resistant effect of the asphalt is enhanced.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
In order to more clearly illustrate the method provided by the present invention, the following examples are used to describe the method for testing each index of the reflective anti-vehicle-mark asphalt prepared in the following examples as follows:
pouring the asphalt of the same mass example and the asphalt of the same mass comparative example at 135 ℃, compacting by using a roller to prepare a test sample, and then carrying out car mark resistance and ultraviolet aging resistance effect tests;
anti-vehicle-mark property: testing stability and self-repairing effect;
stability: determining Marshall stability and dynamic stability with reference to JTG E20;
self-repairing: and cutting a section of the middle part of the test sample by using a blade to generate damage, wherein the undamaged depth is the thickness of two 1-yuan coins at the lower part of the sample, so that the damaged sample is subjected to self-repairing, and after the self-repairing is finished, the ductility is tested according to T0605, and the healing rate = repaired ductility/undamaged ductility.
Ultraviolet aging resistance: using 1200 μ w/cm 2 Irradiating for 8 days by an ultraviolet lamp, and carrying out three points on the asphalt before and after aging by referring to JTG E20And (4) bending test.
Example 1
(1) Mixing sodium hydroxide and acetone mixed liquor according to a mass ratio of 1.13, adding a mercaptobutyric acid solution with a mass of 194 times that of sodium hydroxide at 60rpm, wherein the mass ratio of mercaptobutyric acid to acetone to tetrahydrofuran in the acetone mixed liquor is 1;
(2) Mixing isophorone diisocyanate and N, N-dimethyl imide according to a mass ratio of 1.2, stirring at 50 ℃ and 80rpm for 15min, then adding polytetrahydrofuran diol 1000 and dibutyltin dilaurate according to a mass ratio of 1.00005, wherein the mass ratio of the polytetrahydrofuran diol 1000 to the isophorone diisocyanate is 1.5;
(3) Soaking carbon nanofibers with the length of 10 mu m and the diameter of 150nm in acetone with the mass of 2 times that of the carbon nanofibers, carrying out ultrasonic treatment at 25kHz for 26min, then soaking in absolute ethyl alcohol with the mass of 3 times that of the carbon nanofibers, carrying out ultrasonic treatment at the same frequency for 20min, then placing in nitric acid with the mass fraction of 65% and the mass of 3 times that of the carbon nanofibers, and carrying out water bath treatment at 80 ℃ for 120min to obtain pretreated carbon nanofibers;
(4) Placing the pretreated carbon nanofiber in a glycine solution with the mass ratio of glycine to deionized water being 1;
(5) Mixing a carbon fiber base material, sodium carbonate, trifluoroethanol and 2', 5-dichloro-2-hydroxy-4-methylbenzophenone according to a mass ratio of 1; mixing the modified precursor, 3- (ethylene oxide methoxyl) benzoic acid and chloroform according to the mass ratio of 1.4;
(6) Reacting the primary material, sodium carbonate, trifluoroethanol and 2-chlorocyclopentanone for 3h at the temperature of 55 ℃ and the frequency of 30kHz according to the mass ratio of 1.0;
(7) Mixing the matrix asphalt at 150 ℃ with the deionized water at 40 ℃ according to a mass ratio of 100; mixing foamed asphalt, a modified hot melt adhesive and modified carbon fibers according to a mass ratio of 1.5.
Example 2
(1) Mixing sodium hydroxide and acetone mixed liquor according to a mass ratio of 1.13, adding a mercaptobutyric acid solution with 21.5 times of the mass of sodium hydroxide at 70rpm, wherein the mass ratio of mercaptobutyric acid, acetone and tetrahydrofuran in the mercaptobutyric acid solution is 1;
(2) Mixing isophorone diisocyanate and N, N-dimethyl imide according to a mass ratio of 1.3, stirring at 55 ℃ and 90rpm for 23min, then adding polytetrahydrofuran diol 1000 and dibutyltin dilaurate according to a mass ratio of 1.00006, wherein the mass ratio of the polytetrahydrofuran diol 1000 to the isophorone diisocyanate is 1.75;
(3) Soaking carbon nanofibers with the length of 15 micrometers and the diameter of 175nm in acetone with the mass of 3.5 times that of the carbon nanofibers, carrying out ultrasonic treatment at 30kHz for 32min, then soaking in absolute ethyl alcohol with the mass of 5 times that of the carbon nanofibers, carrying out ultrasonic treatment at the same frequency for 28min, then placing in nitric acid with the mass fraction of 65% and the mass of 4 times that of the carbon nanofibers, and carrying out water bath treatment at 85 ℃ for 132min to obtain pretreated carbon nanofibers;
(4) Placing the pretreated carbon nanofiber in a glycine solution with the mass 36.5 times that of the pretreated carbon nanofiber, wherein the mass ratio of glycine to deionized water in the glycine solution is 1;
(5) Mixing a carbon fiber base material, sodium carbonate, trifluoroethanol and 2', 5-dichloro-2-hydroxy-4-methylbenzophenone according to a mass ratio of 1.1; mixing the modified precursor, 3- (oxiranylmethoxy) benzoic acid and chloroform according to a mass ratio of 1.55;
(6) Reacting the primary material, sodium carbonate, trifluoroethanol and 2-chlorocyclopentanone at the mass ratio of 1.2;
(7) Mixing the base asphalt at 160 ℃ with deionized water at 45 ℃ according to a mass ratio of 100; mixing foamed asphalt, a modified hot melt adhesive and modified carbon fibers according to a mass ratio of 1.65.
Example 3
(1) Mixing sodium hydroxide and acetone mixed liquor according to a mass ratio of 1.13, adding a mercaptobutyric acid solution with the mass of 24 times that of sodium hydroxide at 80rpm, wherein the mass ratio of mercaptobutyric acid to acetone to tetrahydrofuran in the mercaptobutyric acid solution is 1;
(2) Mixing isophorone diisocyanate and N, N-dimethyl imide according to a mass ratio of 1.4, stirring at 60 ℃ and 100rpm for 30min, then adding polytetrahydrofuran diol 1000 and dibutyltin dilaurate according to a mass ratio of 1:0.00007, wherein the mass ratio of the polytetrahydrofuran diol 1000 to the isophorone diisocyanate is 2;
(3) Soaking carbon nanofibers with the length of 20 mu m and the diameter of 200nm in acetone with the mass 5 times that of the carbon nanofibers, carrying out 35kHz ultrasonic treatment for 39min, then soaking in absolute ethyl alcohol with the mass 7 times that of the carbon nanofibers, carrying out ultrasonic treatment for 36min at the same frequency, then placing in nitric acid with the mass fraction 65% and the mass 5 times that of the carbon nanofibers, and carrying out 90-DEG C water bath treatment for 144min to obtain pretreated carbon nanofibers;
(4) Placing the pretreated carbon nanofiber in a glycine solution with the mass ratio of glycine to deionized water being 1;
(5) Mixing a carbon fiber base material, sodium carbonate, trifluoroethanol and 2', 5-dichloro-2-hydroxy-4-methylbenzophenone according to a mass ratio of 1.4; mixing the modified precursor, 3- (ethylene oxide methoxyl) benzoic acid and chloroform according to the mass ratio of 1.7;
(6) Reacting the primary material, sodium carbonate, trifluoroethanol and 2-chlorocyclopentanone at the mass ratio of 1.4;
(7) Mixing matrix asphalt at 170 ℃ with deionized water at 50 ℃ according to a mass ratio of 100; mixing foamed asphalt, modified hot melt adhesive and modified carbon fiber according to the mass ratio of 1.8.
Comparative example 1
Comparative example 1 differs from example 2 in that there is no step (1) and step (2) is changed to: mixing isophorone diisocyanate and N, N-dimethyl imide according to a mass ratio of 1.3, stirring at 55 ℃ and 90rpm for 23min, adding polytetrahydrofuran diol 1000 and dibutyltin dilaurate according to a mass ratio of 1:0.00006, wherein the mass ratio of the polytetrahydrofuran diol 1000 to the isophorone diisocyanate is 1.75. The rest of the preparation steps are the same as example 2.
Comparative example 2
Comparative example 2 differs from example 2 in that step (2) is different, step (2) being changed to: mixing isophorone diisocyanate and N, N-dimethyl imide according to a mass ratio of 1.3, stirring at 55 ℃ and 90rpm for 23min, then adding polytetrahydrofuran diol 1000 and dibutyltin dilaurate according to a mass ratio of 1.00006, wherein the mass ratio of the polytetrahydrofuran diol 1000 to the isophorone diisocyanate is 1.75. The rest of the preparation steps are the same as example 2.
Comparative example 3
Comparative example 3 differs from example 2 in that step (7) is different, step (7) being changed to: mixing the base asphalt at 160 ℃ with deionized water at 45 ℃ according to a mass ratio of 100; mixing foamed asphalt, modified hot melt adhesive and modified carbon fiber according to the mass ratio of 1.65 to 0.14, stirring at 70 ℃ and 350rpm for 45min, adding limestone with the particle size of 7.2mm, which is 2.7 times of the mass of the foamed asphalt, continuously stirring at 125 ℃ for 15s, then adding LOF65-00 antistripping agent with the particle size of 0.002 time of the mass of the foamed asphalt, glass beads with the particle size of 3.6mm, which is 0.12 times of the mass of the foamed asphalt, continuously stirring at 147 ℃ for 33s, then adding mineral powder with the mass of 0.9 time of the foamed asphalt, deionized water with the mass of 0.23 time of the foamed asphalt, and continuously stirring at 115 ℃ for 45s to obtain the reflective anti-vehicle mark asphalt. The rest of the preparation steps are the same as example 2.
Comparative example 4
Comparative example 4 differs from example 2 in that step (5) is different, step (5) being changed to: mixing a carbon fiber base material, 3- (ethylene oxide methoxyl) benzoic acid and chloroform according to the mass ratio of 1.55. The rest of the preparation steps are the same as example 2.
Comparative example 5
Comparative example 5 differs from example 2 in that step (6) is not present and step (5) is changed to: mixing a carbon fiber base material, sodium carbonate, trifluoroethanol and 2', 5-dichloro-2-hydroxy-4-methylbenzophenone according to a mass ratio of 1.1; mixing the modified precursor, 3- (ethylene oxide methoxyl) benzoic acid and chloroform according to the mass ratio of 1.55. The rest of the preparation steps are the same as example 2.
Examples of effects
Table 1 below shows the results of performance analysis of the reflective anti-vehicle-marking asphalt using examples 1 to 3 of the present invention and comparative examples 1 to 5.
TABLE 1
The comparison of the stability and the healing rate data of the embodiment and the comparative example shows that trithiocarbonate obtained by the invention by utilizing mercaptobutyric acid, sodium hydroxide, carbon disulfide and [5- (4-amino-2-chloro-phenyl) -2-furan ] methanol can be repeatedly self-repaired under ultraviolet light, so that the car mark trace can be repaired, and the asphalt has the car mark prevention effect; then, the modified hot melt adhesive is obtained by using polytetrahydrofuran diol, isophorone diisocyanate, trithiocarbonate and maleimide of 1, 3-bis (4-maleimide phenoxy) benzene, contains a thermally reversible covalent bond and has a thermally reversible self-repairing effect; through negative pressure treatment, the foamed asphalt is filled, the modified hot melt adhesive and the modified carbon fiber are mutually crosslinked to form a compact network structure, and the anti-vehicle-mark property of the asphalt is enhanced; from comparison of the data before and after aging of examples and comparative examples, it can be seen that the present invention produces modified carbon fibers using carbon nanofibers, glycine, 2', 5-dichloro-2-hydroxy-4-methylbenzophenone, 3- (oxiranylmethoxy) benzoic acid, 2-chlorocyclopentanone; the benzoate group and the benzophenone group act together to effectively absorb ultraviolet rays and improve the ultraviolet aging resistance of the asphalt; in addition, the modified carbon fibers can react with the modified hot melt adhesive, so that the modified carbon fibers are mutually crosslinked and stacked to form an ultraviolet absorption network, and the ultraviolet aging resistant effect of the asphalt is enhanced.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Claims (10)
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