CN115337774A - Integrated system for capturing and utilizing carbon dioxide in furnace flue gas - Google Patents

Integrated system for capturing and utilizing carbon dioxide in furnace flue gas Download PDF

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Publication number
CN115337774A
CN115337774A CN202210932822.8A CN202210932822A CN115337774A CN 115337774 A CN115337774 A CN 115337774A CN 202210932822 A CN202210932822 A CN 202210932822A CN 115337774 A CN115337774 A CN 115337774A
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China
Prior art keywords
carbon dioxide
flue gas
capturing
furnace
utilizing
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CN202210932822.8A
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CN115337774B (en
Inventor
陈池
孙楠楠
曹先常
沈磊
俞峰
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Shanghai Advanced Research Institute of CAS
Shanghai Baosteel Energy Service Co Ltd
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Shanghai Advanced Research Institute of CAS
Shanghai Baosteel Energy Service Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/343Heat recovery
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8693After-treatment of removed components
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D17/00Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
    • F27D17/008Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases cleaning gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/50Carbon oxides
    • B01D2257/504Carbon dioxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Treating Waste Gases (AREA)
  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

The invention provides a furnace flue gas carbon dioxide capture and utilization integrated system which comprises a furnace, a carbon dioxide capture and utilization integrated device and an induced draft fan, wherein the furnace, the carbon dioxide capture and utilization integrated device and the induced draft fan are circularly connected through a flue gas pipeline to form a flue gas treatment circulation loop; in the carbon dioxide collecting and utilizing integrated device, the flue gas discharged from the furnace and the hydrogen entering the carbon dioxide collecting and utilizing integrated device react under the action of a catalyst to discharge nitrogen, moisture and combustible mixed gas, and the mixed gas enters the furnace again under the pumping of an induced draft fan.

Description

Integrated system for capturing and utilizing carbon dioxide in furnace flue gas
Technical Field
The invention belongs to the technical field of environmental protection treatment of industrial furnace flue gas, and particularly relates to a furnace flue gas carbon dioxide capture and utilization integrated system.
Background
Since the industrial revolution, human beings consume excessive high-carbon stone fuel, emit a large amount of greenhouse gases, and cause global warming. In the industrial field, various furnaces are widely used, such as various furnaces in the industries of metallurgy, building materials, chemical engineering and the like, and the various furnaces burn fuels such as coal, coal gas or natural gas, and the released flue gas contains a large amount of carbon dioxide, which is considered to be an important cause of climate warming. Under the situation that carbon peak reaching and carbon neutralization targets are proposed in various countries in the world, the reduction of carbon dioxide emission in the industrial field is imperative. How to reduce the emission of carbon dioxide in flue gas is an important direction of continuous attention.
In the aspect of carbon emission reduction of flue gas, the common practice is to capture carbon dioxide in the flue gas by absorption or adsorption, and then transmit the carbon dioxide out for storage or utilization. The method is suitable for a thermal power plant with large installed capacity, can have scale effect to reduce carbon emission reduction cost, but the subsequent transportation and storage operation cost is still considerable, so that large-scale popularization and application are still difficult to obtain at present. The kiln which is used in a large amount in industrial enterprises is difficult to be widely applied by adopting a mode of separately carrying out trapping and utilization due to large using amount and dispersion. On one hand, because the smoke discharge amount of a large number of furnaces is not large, the furnaces are large in number and are dispersed and difficult to be intensively treated on the scale of tens of thousands of cubic meters per hour; on the other hand, since even if it is possible to capture so much carbon dioxide, its utilization is a great problem, and after all, each kiln captures a small amount of carbon dioxide and is dispersed, and the difficulty of transportation and storage is greater. In this case, it is a better choice to adopt a technology of capturing and utilizing the integrated kiln smoke to reduce carbon.
Disclosure of Invention
In order to solve the problems, the invention provides a furnace kiln flue gas carbon dioxide capture and utilization integrated system which comprises a furnace kiln, a carbon dioxide capture and utilization integrated device and an induced draft fan, wherein the furnace kiln, the carbon dioxide capture and utilization integrated device and the induced draft fan are circularly connected through a flue gas pipeline to form a flue gas treatment circulating loop; in the carbon dioxide entrapment utilized integrated device, follow furnace kiln exhaust flue gas with get into the hydrogen in the carbon dioxide entrapment utilized integrated device reacts under the effect of catalyst, discharges nitrogen gas, moisture and combustible gas mixture, the gas mixture enters into again under the pump-out of draught fan in the furnace kiln.
Preferably, the mixed gas comprises methane, hydrogen, carbon dioxide and nitrogen.
Preferably, the fuel used by the kiln is the mixed gas and the carbon-containing fuel gas which are recycled.
Preferably, the flue gas treatment circulation loop further comprises a pretreatment device, and the pretreatment device is communicated between the smoke outlet of the kiln and the smoke inlet of the carbon dioxide capture and utilization integrated device.
Preferably, the pretreatment device comprises a first purification module or and a temperature regulation module.
Preferably, the flue gas treatment circulation loop further comprises a post-treatment device, and the post-treatment device is arranged between the mixed gas outlet of the carbon dioxide capture and utilization integrated device and the gas inlet of the kiln.
Preferably, the post-treatment device comprises a second purification module or/and a composition adjustment module.
Preferably, the induced draft fan is connected between the air outlet of the after-treatment device and the air inlet of the kiln.
Preferably, the carbon dioxide capture and utilization integrated device is further provided with a nitrogen outlet, and nitrogen separated from the carbon dioxide capture and utilization integrated device is discharged to the outside of the carbon dioxide capture and utilization integrated device through the nitrogen outlet.
Preferably, the catalyst is a Ni-based two-dimensional nanomaterial.
Compared with the prior art, the invention has the following technical effects:
according to the integrated system for capturing and utilizing the carbon dioxide in the furnace flue gas, provided by the invention, the clean gas hydrogen without carbon is introduced, the clean gas hydrogen reacts with the purified flue gas under the action of the catalyst, nitrogen, moisture and combustible mixed gas are discharged, and the mixed gas can return to the furnace for secondary combustion, so that the integrated capturing and utilizing of the carbon dioxide in the flue gas is realized. Compared with the existing carbon emission reduction technology which separates the trapping and utilization, the method can realize carbon emission reduction under the condition of not changing the existing furnace condition, does not need to treat a large amount of trapped carbon dioxide, can also utilize the waste heat in the flue gas, obviously improve the operating cost, and finally realize complete zero carbon emission. The system can form a modularized complete device, is very convenient for field application, and realizes clean energy source replacement without changing the running condition of the existing furnace. The technology of the invention is very suitable for being applied to large-scale and dispersive industrial furnaces.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings required to be used in the description of the embodiments will be briefly described below, and it is obvious that the drawings in the description below are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained based on the drawings without creative efforts. In the drawings:
fig. 1 is a schematic structural diagram of a kiln flue gas carbon dioxide capture and utilization integrated system according to a preferred embodiment of the present invention.
Detailed Description
The present invention will be described in detail with reference to specific examples. The following examples will assist those skilled in the art in further understanding the invention, but are not intended to limit the invention in any way. It should be noted that it would be obvious to those skilled in the art that various changes and modifications can be made without departing from the spirit of the invention. All falling within the scope of the invention.
Referring to fig. 1, a kiln flue gas and carbon dioxide capturing and utilizing integrated system comprises a kiln 1, a pretreatment device 2, a carbon dioxide capturing and utilizing integrated device 3, a post-treatment device 4 and an induced draft fan 5, wherein the kiln 1, the pretreatment device 2, the carbon dioxide capturing and utilizing integrated device 3, the post-treatment device 4 and the induced draft fan 5 are connected in sequence through a flue gas pipeline in a circulating manner to form a flue gas treatment circulation loop.
When the system is operated, the flue gas discharged from the kiln 1 is treated by the pretreatment device 2 and then discharged into the carbon dioxide capture and utilization integrated device 3, namely, the pretreatment device 2 is communicated between the smoke outlet of the kiln 1 and the smoke inlet of the carbon dioxide capture and utilization integrated device 3. The specific structure of the pretreatment device 2 is not limited, and can be selected according to specific flue gas components, and the specific structure of the pretreatment device 2 is different due to different flue gas components and flue gas temperatures. In the present embodiment, the fuel used in the kiln 1 is recycled mixed gas and other fuel gas, for example, the mixed gas includes methane, hydrogen, carbon dioxide, and nitrogen, and the other fuel gas is carbon-containing fuel gas. The pretreatment device 2 comprises a first purification module and a temperature regulation module, wherein the first purification module is used for purifying flue gas, such as removing components which are mainly smoke dust or some sulfides, nitrogen oxides and the like and possibly bring adverse effects to a catalyst through electric precipitation or gravity dust removal; such as by freezing. The temperature adjusting module is used for adjusting the temperature of the flue gas so as to meet the applicable temperature range of the catalyst. The temperature adjusting processing module heats the flue gas to reach the required temperature through a heating furnace (using electricity or fuel gas).
Follow kiln 1 exhaust flue gas is through pretreatment device 2 processing back, gets into in the carbon dioxide entrapment utilizes integrated device 3, the flue gas with send into the carbon dioxide entrapment utilizes the hydrogen in the integrated device 3, reacts under the effect of catalyst (the catalyst that different flue gas composition adopted is different, this embodiment is mainly Ni base two-dimensional nano-material), discharges nitrogen gas, moisture, a small amount of carbon dioxide that can not handle and combustible gas mixture, carries out aftertreatment in the gas mixture aftertreatment device 4, then enters into kiln 1 burning again under the pump-out of draught fan 5.
In this embodiment, the carbon dioxide capture and utilization integrated device 3 includes a smoke inlet, a hydrogen inlet, a mixed gas outlet and a nitrogen outlet, the smoke inlet is used for introducing smoke into the carbon dioxide capture and utilization integrated device 3, the hydrogen inlet is used for introducing hydrogen into the carbon dioxide capture and utilization integrated device 3, the mixed gas outlet is used for discharging the mixed gas in the carbon dioxide capture and utilization integrated device 3, the nitrogen outlet is used for discharging the nitrogen in the carbon dioxide capture and utilization integrated device 3 to the outside of the carbon dioxide capture and utilization integrated device 3, and the nitrogen is mainly separated through partial pressure and density difference.
The post-treatment device 4 is arranged between a mixed gas outlet of the carbon dioxide capture and utilization integrated device 3 and the draught fan 5, and the draught fan 5 is connected between a gas outlet of the post-treatment device 4 and a gas inlet of the kiln 1.
The specific structure of the pretreatment device 2 is not limited, and can be selected according to specific flue gas components, and the specific structures of the aftertreatment device 4 are different due to different flue gas components and flue gas temperatures. In this embodiment, the post-treatment device 4 includes a second purification module or/and a composition adjustment module, the second purification module is used to purify the mixed gas to meet the requirements of the kiln 1 on the gas performance, such as removing impurities (possibly containing a small amount of catalyst or side reaction impurities, mainly achieved by a filtration module), reducing moisture (removed by a drying agent or a cooling manner); the heat value of the component adjusting module can be adjusted by mixing a plurality of gas components through mixed gas or adjusting the components through a mixer, and the adjustment of the heat value (not necessarily increasing the heat value) is mainly used for meeting the requirement of the burner of the kiln 1 on the quality of the fuel gas.
In this embodiment, the induced draft fan 5 can satisfy the requirements of the furnace 1 on the gas pressure and flow control by adjustment. So connect draught fan 5 the gas outlet of after-treatment device 4 with between the air inlet of kiln 1, and do not place other positions, the purpose prevents that the temperature and the composition of flue gas from influencing the normal operating of draught fan 5, and the control of atmosphere in the kiln 1 is unfavorable for in fear.
In this embodiment, a detection instrument is further disposed on the flue gas treatment circulation loop.
According to the integrated system for capturing and utilizing the carbon dioxide in the flue gas of the kiln 1, the carbon-free clean energy hydrogen is introduced and reacts with the flue gas under the action of the catalyst, so that the hydrogen reacts with the purified flue gas, nitrogen, moisture and combustible mixed gas are discharged, and the mixed gas can return to the kiln 1 to be combusted again, so that the integration of capturing and utilizing the carbon dioxide in the flue gas is realized. Compared with the existing carbon emission reduction technology which separates the trapping and utilization, the method can realize carbon emission reduction under the condition of not changing the condition of the existing furnace kiln 1, does not need to treat a large amount of trapped carbon dioxide, can also utilize the waste heat in the flue gas, obviously reduce the operating cost, and finally realize zero carbon emission of the furnace kiln 1.
According to the integrated system for capturing and utilizing the carbon dioxide in the flue gas of the kiln 1, the carbon-free clean energy hydrogen is introduced and reacts with the flue gas under the action of the catalyst, so that the hydrogen reacts with the purified flue gas, nitrogen, moisture and combustible mixed gas are discharged, and the mixed gas can return to the kiln 1 to be combusted again, so that the integration of capturing and utilizing the carbon dioxide in the flue gas is realized. Compared with the existing carbon emission reduction technology which separates the trapping and utilization, the method can realize carbon emission reduction under the condition of not changing the condition of the existing furnace kiln 1, does not need to treat a large amount of trapped carbon dioxide, can also utilize the waste heat in the flue gas, obviously reduce the operating cost, and finally realize zero carbon emission of the furnace kiln 1.
The foregoing description of specific embodiments of the present invention has been presented. It is to be understood that the present invention is not limited to the specific embodiments described above, and that various changes or modifications may be made by one skilled in the art within the scope of the appended claims without departing from the spirit of the invention. The embodiments and features of the embodiments of the present application may be combined with each other arbitrarily without conflict.

Claims (10)

1. The integrated system for capturing and utilizing the carbon dioxide in the furnace flue gas is characterized by comprising a furnace, an integrated device for capturing and utilizing the carbon dioxide and an induced draft fan, wherein the furnace, the integrated device for capturing and utilizing the carbon dioxide and the induced draft fan are circularly connected through a flue gas pipeline to form a flue gas treatment circulating loop; in the carbon dioxide entrapment utilized integrated device, follow furnace kiln exhaust flue gas with get into the hydrogen in the carbon dioxide entrapment utilized integrated device reacts under the effect of catalyst, discharges nitrogen gas, moisture and combustible gas mixture, the gas mixture enters into again under the pump-out of draught fan in the furnace kiln.
2. The integrated system for capturing and utilizing carbon dioxide in furnace flue gas of claim 1, wherein the mixed gas comprises methane, hydrogen, carbon dioxide and nitrogen.
3. The integrated system for capturing and utilizing carbon dioxide in furnace flue gas of claim 1, wherein the fuel used by the furnace is the recycled mixed gas and the carbon-containing fuel gas.
4. The integrated system for capturing and utilizing carbon dioxide in furnace flue gas as claimed in claim 1, wherein the flue gas treatment circulation loop further comprises a pretreatment device, and the pretreatment device is communicated between a smoke outlet of the furnace and a smoke inlet of the integrated device for capturing and utilizing carbon dioxide.
5. The integrated system for capturing and utilizing the carbon dioxide in the flue gas of the kiln according to claim 1, wherein the pretreatment device comprises a first purification module or a temperature regulation module.
6. The integrated system for capturing and utilizing carbon dioxide in flue gas of a furnace kiln according to claim 1, wherein the flue gas treatment circulation loop further comprises an after-treatment device, and the after-treatment device is arranged between the mixed gas outlet of the integrated device for capturing and utilizing carbon dioxide and the air inlet of the furnace kiln.
7. The integrated system for capturing and utilizing carbon dioxide in furnace flue gas according to claim 1, wherein the post-treatment device comprises a second purification module or/and a composition regulation module.
8. The integrated system for capturing and utilizing carbon dioxide in flue gas of a furnace kiln according to claim 1, wherein the induced draft fan is connected between the gas outlet of the after-treatment device and the gas inlet of the furnace kiln.
9. The integrated system for capturing and utilizing carbon dioxide in furnace flue gas as claimed in claim 1, wherein the integrated device for capturing and utilizing carbon dioxide is further provided with a nitrogen outlet, and nitrogen separated from the integrated device for capturing and utilizing carbon dioxide is discharged out of the integrated device for capturing and utilizing carbon dioxide through the nitrogen outlet.
10. The integrated system for capturing and utilizing carbon dioxide in furnace flue gas according to claim 1, wherein the catalyst is a Ni-based two-dimensional nano material.
CN202210932822.8A 2022-08-04 2022-08-04 Integrated system for capturing and utilizing carbon dioxide in kiln flue gas Active CN115337774B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160017800A1 (en) * 2012-02-20 2016-01-21 Thermogas Dynamics Limited Methods and systems for energy conversion and generation
CN112569739A (en) * 2020-12-07 2021-03-30 华东理工大学 System and method for capturing carbon dioxide at high temperature and converting carbon dioxide into synthesis gas in situ
CN113694724A (en) * 2021-08-26 2021-11-26 无锡碳谷科技有限公司 Used for capturing and catalyzing CO2Reaction system of
CN114377679A (en) * 2022-01-26 2022-04-22 中国科学院上海高等研究院 Carbon dioxide capturing and converting integrated bifunctional catalyst, preparation method and application
CN114377514A (en) * 2022-01-26 2022-04-22 中国科学院上海高等研究院 Carbon dioxide capturing and converting integrated continuous production device and method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160017800A1 (en) * 2012-02-20 2016-01-21 Thermogas Dynamics Limited Methods and systems for energy conversion and generation
CN112569739A (en) * 2020-12-07 2021-03-30 华东理工大学 System and method for capturing carbon dioxide at high temperature and converting carbon dioxide into synthesis gas in situ
CN113694724A (en) * 2021-08-26 2021-11-26 无锡碳谷科技有限公司 Used for capturing and catalyzing CO2Reaction system of
CN114377679A (en) * 2022-01-26 2022-04-22 中国科学院上海高等研究院 Carbon dioxide capturing and converting integrated bifunctional catalyst, preparation method and application
CN114377514A (en) * 2022-01-26 2022-04-22 中国科学院上海高等研究院 Carbon dioxide capturing and converting integrated continuous production device and method

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