CN115259875B - Anti-crack ceramic tile and production process thereof - Google Patents
Anti-crack ceramic tile and production process thereof Download PDFInfo
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- CN115259875B CN115259875B CN202210775743.0A CN202210775743A CN115259875B CN 115259875 B CN115259875 B CN 115259875B CN 202210775743 A CN202210775743 A CN 202210775743A CN 115259875 B CN115259875 B CN 115259875B
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- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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Abstract
The application relates to the technical field of ceramic tile production, and particularly discloses an anti-cracking ceramic tile and a production process thereof. The ceramic tile comprises a blank body and glaze coated on the blank body, wherein the blank body comprises the following raw materials in parts by weight: 20-35 parts of dolomite, 10-20 parts of quartz stone, 10-18 parts of bentonite, 10-20 parts of talcum powder, 5-12 parts of waste brick and 6-18 parts of modified basalt fiber; the preparation method comprises the following steps: mixing the blank raw materials except the modified basalt fiber uniformly, grinding, adding the modified basalt fiber, and mixing uniformly to obtain a blank; mixing the raw materials except water, grinding, adding water, and mixing to obtain glaze; pressing the blank into a green body, and drying to obtain the green body; and uniformly coating the glaze on the green body, drying, firing and cooling to obtain the anti-cracking ceramic tile. The anti-cracking ceramic tile has the advantage of improving the crack resistance of the ceramic tile through the synergistic effect of the raw materials.
Description
Technical Field
The application relates to the technical field of ceramic tile production, in particular to an anti-cracking ceramic tile and a production process thereof.
Background
Along with the improvement of the quality of life of people, the use of ceramic tiles is more and more extensive, and the class of ceramic tiles is full of eyes in the existing market, according to production technology, can divide the ceramic tile into polished tiles, glazed tiles, full-bodied tiles, vitrified tiles, and the ceramic tile is widely applied to the decoration of indoor or outdoor wall, ground.
The ceramic tile is an acid and alkali resistant porcelain or stone decorative material formed by grinding, mixing, pressing, glazing, sintering and other processes of refractory metal oxide and semimetal oxide. At present, the ceramic tile is mainly prepared by pressing quartz stone, kaolin and talcum powder serving as main raw materials into a green body and coating glaze on the green body, but the prepared ceramic tile is easy to crack and influences the use of the ceramic tile.
Disclosure of Invention
In order to improve the crack resistance of the ceramic tile, the application provides the crack-resistant ceramic tile and a production process thereof.
In a first aspect, the application provides an anti-crack ceramic tile, which adopts the following technical scheme:
the anti-cracking ceramic tile comprises a blank body and glaze coated on the blank body, wherein the blank body comprises the following raw materials in parts by weight: 20-35 parts of dolomite, 10-20 parts of quartz stone, 10-18 parts of bentonite, 10-20 parts of talcum powder, 5-12 parts of waste brick and 6-18 parts of modified basalt fiber, wherein the modified basalt fiber is prepared by modifying the basalt fiber by adopting a silane coupling agent.
By adopting the technical scheme, the anti-cracking ceramic tile not only can keep good breaking strength and Mohs hardness grade of the ceramic tile, but also has excellent modulus of rupture, namely, the anti-cracking property of the ceramic tile is improved, wherein the breaking strength is 1950-1970N, the Mohs hardness grade is 3-5 grade, and the modulus of rupture is 55.1-65.6MPa.
The ceramic tile is made of a blank body and glaze coated on the blank body, and the cracking resistance of the ceramic tile is mainly improved by the blank body. The dolomite has low cost and good weather resistance, and can also reduce the firing temperature. The quartz stone can enhance the mechanical strength of the blank body, also has an adjusting effect on the plasticity of the blank body, and can reduce the shrinkage rate, shorten the drying time and reduce the deformation of the blank body as a barren raw material, thereby having the effect of improving the crack resistance of the ceramic tile. The bentonite is a non-metal mineral product with the main content of montmorillonite, when a proper amount of bentonite is mixed in the raw material of the ceramic tile, the bentonite can generate a bonding and curing effect, and the bentonite can be filled in gaps of the raw material of the blank body to play a role in blocking, so that the cracking of the ceramic tile is reduced. The talcum powder has the functions of thickening, viscosity increasing and water retention, has fine molecules, can be filled among various raw materials, and enhances the strength of a blank body. The waste bricks are used as barren raw materials, so that shrinkage rate can be reduced, deformation of a blank body is reduced, crack resistance is improved, waste utilization is realized, resources are saved, and the environment is protected.
The basalt fibers are applied to the raw materials of the green body, can be randomly distributed in the green body and can be adhered to other raw materials of the green body, and the fibers have certain toughness, can play a role in restraining cracks and prevent the cracks from expanding, so that the crack resistance of the ceramic tile is improved, and the mechanical property of the ceramic tile is improved; moreover, the silane coupling agent is used for modifying the basalt fiber, so that the dispersibility of the basalt fiber in a blank can be improved, the basalt fiber can be dispersed more uniformly, and the crack resistance of the ceramic tile can be further improved.
Preferably, the method comprises the following steps: the blank body comprises the following raw materials in parts by weight: 25-30 parts of dolomite, 12-18 parts of quartz stone, 12-16 parts of bentonite, 14-17 parts of talcum powder, 6-10 parts of waste brick and 8-15 parts of modified basalt fiber.
By adopting the technical scheme, the mixing amount of the dolomite, the quartz stone, the bentonite, the talcum powder, the waste brick and the modified basalt fiber is optimized, so that the raw materials can play a role, and the crack resistance of the ceramic tile can be improved conveniently.
Preferably, the method comprises the following steps: the modified basalt fiber is prepared by adopting the following method: adding a silane coupling agent into acetone, uniformly stirring, adding basalt fibers, performing ultrasonic dispersion, filtering, washing and drying to obtain the modified basalt fibers.
Further, the modified basalt fiber is prepared by adopting the following method: putting a silane coupling agent into acetone, stirring for 20-30min, putting basalt fiber, performing ultrasonic dispersion for 30-40min, filtering, washing solids with chloroform, and drying to obtain modified basalt fiber;
wherein the weight ratio of the silane coupling agent to the acetone is 1: (10-15).
Preferably, the method comprises the following steps: the weight ratio of the silane coupling agent to the basalt fiber is (0.3-0.5): 1.
by adopting the technical scheme, the modified basalt fiber is prepared by the preparation method, so that the dispersibility of the basalt fiber in a blank can be improved, the basalt fiber can be dispersed in the blank more uniformly, and the improvement of the crack resistance of the ceramic tile is facilitated.
Preferably, the method comprises the following steps: the modified basalt fiber is pretreated by adopting the following method before use: and (3) soaking the modified basalt fiber in a sodium hydroxide solution, taking out, and drying until the water content is less than 0.5% to obtain the pretreated modified basalt fiber.
Further, the modified basalt fiber is pretreated by adopting the following method before use: soaking the modified basalt fiber in a sodium hydroxide solution for 22-26h, taking out, and drying until the moisture content is less than 0.5% to obtain a pretreated modified basalt fiber;
wherein the addition amount of the sodium hydroxide solution in each 1kg of the modified basalt fiber is 6-10L, and the mass fraction of the sodium hydroxide solution is 80-90%.
By adopting the technical scheme, the sodium hydroxide solution is utilized to pretreat the modified basalt fiber, so that a wax layer on the surface of the modified basalt fiber can be removed, and the surface of the modified basalt fiber is roughened on the premise of ensuring that the internal modified basalt fiber is not damaged, thereby improving the bonding capability between the modified basalt fiber and various raw materials of a blank body, and further improving the crack resistance of the ceramic tile.
Preferably, the method comprises the following steps: the length of the modified basalt fiber is 5-10mm.
The modified basalt fiber is too short in length, easy to generate self-aggregation and difficult to disperse, so that the mechanical property of the ceramic tile is influenced; the modified basalt fiber is too long and is easy to wind into a knot, so that the modified basalt fiber is not uniformly dispersed in a blank body, and the crack resistance of the ceramic tile is influenced. By adopting the technical scheme, when the modified basalt fiber is within the length range, the modified basalt fiber is beneficial to being dispersed in the blank more uniformly, is beneficial to forming a three-dimensional reticular structure in the blank, and is beneficial to improving the crack resistance of the ceramic tile.
Preferably, the method comprises the following steps: the bentonite is sodium bentonite.
By adopting the technical scheme, the bentonite particles can be connected together by the cations in the sodium bentonite, so that the dispersion of the bentonite is restricted, and the bentonite can be better filled in gaps among the raw materials in the blank body to fill, thereby enhancing the strength of the ceramic tile and reducing the cracking of the ceramic tile.
Preferably, the method comprises the following steps: the glaze comprises the following raw materials in parts by weight: 20-45 parts of potassium feldspar granite, 5-10 parts of nano zinc oxide, 5-10 parts of nano silicon dioxide, 3-8 parts of carboxymethyl cellulose, 1-2 parts of sodium hexametaphosphate and 50-56 parts of water.
Through adopting above-mentioned technical scheme, potassium long granite is applied to the frit, can provide the aluminium oxide, keeps the glossiness of frit, has still realized waste utilization, the resources are saved and the environment is convenient for. The nano zinc oxide can reduce the viscosity of glaze, has surface effect, quantum effect and larger surface energy, and can improve the hardness of the glaze. The nano silicon dioxide is mutually combined into an irregular network in a tetrahedral form to form a network forming body, and the glossiness and hardness of the ceramic tile can also be improved. Carboxymethyl cellulose can improve the suspensibility and adhesion of glaze. When the sodium hexametaphosphate is applied to the raw materials of the glaze, the dispersibility of the nano zinc oxide and the nano silicon dioxide can be further improved, and the nano zinc oxide and the nano silicon dioxide can better play a role.
In a second aspect, the application provides a production process of an anti-cracking ceramic tile, which adopts the following technical scheme:
a production process of the anti-crack ceramic tile comprises the following steps:
s1: uniformly mixing dolomite, quartz stone, bentonite, talcum powder and waste bricks, grinding, adding modified basalt fiber, and uniformly mixing to obtain a blank;
s2: uniformly mixing potassium feldspar granite, nano zinc oxide, nano silicon dioxide, carboxymethyl cellulose and sodium hexametaphosphate, grinding, adding water, and uniformly stirring to obtain a glaze;
s3: pressing the blank into a green body, and drying to obtain the green body;
s4: and uniformly coating the glaze on the green body, drying, firing and cooling to obtain the anti-cracking ceramic tile.
Further, the production process of the anti-crack ceramic tile comprises the following steps:
s1: mixing dolomite, quartz stone, bentonite, talcum powder and waste bricks, stirring for 1-2h, grinding until the average grain diameter is 250 meshes, adding modified basalt fiber, and stirring for 40-60min to obtain a blank;
s2: mixing potassium feldspar granite, nano zinc oxide, nano silicon dioxide, carboxymethyl cellulose and sodium hexametaphosphate, stirring for 1-2h, grinding until the average particle size is 100 meshes, adding water, and stirring for 2-3h to obtain a glaze;
s3: pressing the blank into a green body, and drying to obtain the green body;
s4: uniformly coating the glaze on the blank body, wherein the coating amount is 40-60g/m 2 And after drying, firing and cooling to obtain the anti-cracking ceramic tile.
Preferably, the method comprises the following steps: the firing temperature in the step S4 is 1150-1200 ℃, and the firing time is 60-70min.
By adopting the technical scheme, the raw materials of the green body are uniformly mixed, then the raw materials are ground, the raw materials of the glaze are uniformly mixed, the grinding is carried out, the green body and the raw materials of the glaze are more uniformly mixed, the raw materials can better play a role, then the glaze is uniformly coated on the green body, and the ceramic tile is prepared after firing and cooling, so that the crack resistance of the ceramic tile is improved.
In summary, the present application includes at least one of the following beneficial technical effects:
1. since the basalt fiber is modified by adopting the silane coupling agent, the basalt fiber has certain toughness, and after modification, the dispersity of the basalt fiber in a blank can be improved, so that the basalt fiber can play a better role, the crack resistance of the ceramic tile is further improved, the breaking strength can reach 1970N, the Mohs hardness grade reaches 5 grade, and the modulus of rupture reaches 65.6MPa.
2. In the application, the sodium hydroxide solution is preferably selected to pretreat the modified basalt fiber, so that a wax layer on the surface of the modified basalt fiber can be removed, the surface of the modified basalt fiber is roughened, the binding force between the modified basalt fiber and each raw material of a blank body can be enhanced, and the crack resistance of the ceramic tile can be improved.
Detailed Description
The present application is described in further detail below with reference to specific contents.
The apparent density of raw dolomite is 2600kg/m 3 The mud content is 0.01 percent, the water content is 0.01 percent, and the bulk density is 1800kg/m 3 (ii) a The specific gravity of the quartz stone is 1.762, the mud content is 0.025%, the water content is 0.87%, and the apparent density is 1831kg/m 3 Bulk density 1837kg/m 3 (ii) a The bentonite is sodium bentonite, the expansion multiple is 25-35, and the pH value is 7-10; the whiteness of the talcum powder is 96 percent, the content of the magnesium oxide is 28 percent, and the content of the silicon dioxide is 60 percent; the refractory temperature of the waste brick is 1580-1770 ℃, the compressive strength is 100MPa, the bending strength is 15MPa, the heat conductivity coefficient is 30w/m.k, the elongation at break is 20, the tensile strength is 20MPa, and the tearing strength is 30MPa; the basalt fiber has the service temperature of 650 ℃, the bending strength of 15MPa, the tensile strength of 3.4MPa, the compressive strength of 27MPa, the tear strength of 1240MPa, the fire-resistant temperature of 1470 ℃, the heat conductivity coefficient of 0.035w/m.k, the elongation at break of 3.4%, the elastic modulus of 92.7GPA, the wear rate of 0.23 and the sound absorption performance of 0.142-0.187;the silane coupling agent is 3-aminopropyl triethoxysilane with model number of KH-550, density of 0.940-0.950, refractive index of 1.4180-1.4210 and CAS number of 919-30-2; the CAS number of the potassium feldspar granite is 68476-25-5; the relative density of the nano zinc oxide is 5.606g/cm 3 Melting point 1975 ℃, refractive index 2.008-2.009, CAS No. 1314-13-2; the specific surface area of the nano silicon dioxide is 150-200m < 2 >/g, and the CAS number is 112945-52-5; carboxymethyl cellulose density 1.369, CAS No. 9000-11-7; the relative density of sodium hexametaphosphate was 2.48g/cm 3 Melting point 616 ℃ and CAS number 10124-56-8.
Preparation example
Preparation example 1
A modified basalt fiber is prepared by adopting the following method:
adding 0.6kg of silane coupling agent into acetone, stirring for 25min, adding 2kg of basalt fiber, performing ultrasonic dispersion for 35min, filtering, washing solid with chloroform, and drying to obtain the modified basalt fiber, wherein the weight ratio of the silane coupling agent to the acetone is 1.
Preparation example 2
A modified basalt fiber which is different from preparation example 1 in the addition amount of a silane coupling agent, and the addition amount of the silane coupling agent in preparation example 2 is 0.8kg.
Preparation example 3
A modified basalt fiber which is different from preparation example 1 in the addition amount of a silane coupling agent, and the addition amount of the silane coupling agent in preparation example 3 is 1kg.
Examples
Example 1
The raw material proportion of the anti-cracking ceramic tile is shown in table 1.
A production process of the anti-crack ceramic tile comprises the following steps:
s1: mixing dolomite, quartz stone, bentonite, talcum powder and waste bricks, stirring for 1.5h, grinding until the average grain diameter is 250 meshes, adding the modified basalt fiber prepared in preparation example 1, and stirring for 50min to obtain a blank;
s2: mixing potassium feldspar granite, nano zinc oxide, nano silicon dioxide, carboxymethyl cellulose and sodium hexametaphosphate, stirring for 1.5h, grinding until the average particle size is 100 meshes, adding water, and stirring for 2.5h to obtain a glaze;
s3: pressing the blank into a green body, and drying to obtain the green body;
s4: evenly coating the glaze on the blank body, wherein the coating amount is 50g/m 2 And after drying, firing for 65min at the temperature of 1175 ℃, and cooling to obtain the anti-cracking ceramic tile.
Examples 2 to 5
The anti-cracking ceramic tile is different from the ceramic tile in the embodiment 1 in the raw material ratio shown in the table 1.
TABLE 1 examples 1-5 weight of each raw material of ceramic tiles (unit: kg)
Examples 6 to 8
The difference between the anti-cracking ceramic tile and the ceramic tile in the embodiment 5 is that the raw material mixture ratio of the ceramic tile is different, and the raw material mixture ratio is shown in a table 2.
TABLE 2 examples 6-8 weight of each raw material for ceramic tiles (unit: kg)
Examples 9 to 10
The difference between the anti-cracking ceramic tile and the ceramic tile in the embodiment 7 is that the raw material mixture ratio of the ceramic tile is different, and the raw material mixture ratio is shown in a table 3.
TABLE 3 examples 9-10 weight of each raw material for ceramic tiles (unit: kg)
Example 11
An anti-cracking ceramic tile, which is different from that of example 9 in that modified basalt fiber in a ceramic tile raw material is prepared by using preparation example 2.
Example 12
An anti-cracking tile, which is different from that of example 9 in that modified basalt fiber in the tile raw material was prepared by using preparation example 3.
Example 13
An anti-cracking ceramic tile, which is different from the ceramic tile in example 11 in that modified basalt fibers in a ceramic tile raw material are pretreated by the following method before use:
soaking the modified basalt fiber in 85% sodium hydroxide solution for 24h, taking out, and drying until the moisture content is less than 0.5% to obtain the pretreated modified basalt fiber; wherein the addition amount of the sodium hydroxide solution in each 1kg of the modified basalt fiber is 8L.
Comparative example
Comparative example 1
An anti-cracking ceramic tile which is different from that of example 1 in that basalt fiber is replaced by modified basalt fiber in the raw material of the ceramic tile in an equal amount.
Comparative example 2
An anti-cracking ceramic tile is different from the ceramic tile in example 1 in that modified basalt fibers are not added in the raw materials of the ceramic tile.
Comparative example 3
An anti-cracking tile is different from that of example 1 in that sodium bentonite in the tile raw material is replaced with lithium bentonite in equal amount.
Performance test
The following tests were carried out on the tiles of examples 1 to 13 and comparative examples 1 to 3:
breaking strength: according to GB/T3810.4-2006 section 4 of the ceramic tile test method: fracture modulus and fracture strength measurement the fracture strength of the tile was measured, and the results are shown in table 4.
Modulus of rupture: according to GB/T3810.4-2006 part 4 of the ceramic tile test method: measurement of modulus of rupture and breaking Strength the modulus of rupture of the tile was measured and the results are shown in Table 4.
Mohs scale of hardness: the ceramic tile is stably placed on a hard support, the glaze surface faces upwards, the surface of the ceramic tile is sequentially scratched by selecting standard ores with different Mohs values from small to large, the surface of the ceramic tile is scratched by uniformly and vertically applying force by using the ore cutting edge, the lowest hardness value which just can generate obvious scratches is used as a detection result, and the detection result is recorded in a table 4.
TABLE 4 test results
As can be seen from Table 4, the anti-cracking ceramic tile provided by the invention not only can keep good breaking strength and Mohs hardness grade of the ceramic tile, but also has better breaking modulus, namely, the anti-cracking property of the ceramic tile is improved, wherein the breaking strength is 1950-1970N, the Mohs hardness grade is 3-5, and the breaking modulus is 55.1-65.6MPa.
It can be seen from the combination of example 1 and comparative example 1 that the tile of example 1 has 1950N of breaking strength, 3 on the mohs scale, and 55.1MPa of modulus of rupture, which is superior to that of comparative example 1, indicating that it is more suitable to modify basalt fiber with silane coupling agent in the raw material of the tile, not only to maintain excellent mechanical strength of the tile, but also to improve the modulus of rupture of the tile, i.e. to improve the crack resistance of the tile.
As can be seen by combining the embodiment 1 and the comparative example 2, the ceramic tile in the embodiment 1 has the breaking strength of 1950N, the Mohs hardness grade of 3 and the breaking modulus of 55.1MPa which are superior to the comparative example 2, and the modified basalt fiber is more suitable to be added into the raw materials of the ceramic tile, so that the ceramic tile can keep good breaking strength and Mohs hardness grade, also has better breaking modulus and improves the crack resistance of the ceramic tile.
As can be seen by combining example 1 and comparative example 3, the tile of example 1 has 1950N of breaking strength, 3-grade Mohs hardness and 55.1MPa of modulus of rupture, which is superior to that of comparative example 3, and shows that the sodium bentonite is more suitable for the raw materials of the tile, so that the tile not only maintains good breaking strength and Mohs hardness, but also has better modulus of rupture and improved crack resistance.
As can be seen by combining examples 1-5, the tile of example 5 has 1955N of breaking strength, 4 Mohs hardness scale and 59.4MPa of modulus of rupture, which is superior to other examples, and the modified basalt fiber of example 5 is added in a more appropriate amount, so that the tile not only has good mechanical strength, but also has improved crack resistance and better modulus of rupture.
Combining example 9 and examples 11-12, it can be seen that the tile of example 11 has a breaking strength of 1965N, a mohs hardness rating of 5, and a modulus of rupture of 65.2MPa, which is superior to other examples, indicating that the modified basalt fiber prepared by preparation example 2 is more suitable, and not only can the tile maintain good breaking strength and mohs hardness rating, but also has a better modulus of rupture, and the crack resistance of the tile is improved.
It can be seen from the combination of examples 11 and 13 that the tile of example 13 has a breaking strength of 1970N, a mohs scale of 5, and a modulus of rupture of 65.6MPa, which is superior to that of example 11, indicating that the modified basalt fiber is more suitably pretreated with a sodium hydroxide solution before use, and that the modified basalt fiber can enhance the binding property in the green body, and contribute to the improvement of the crack resistance of the tile, resulting in a better modulus of rupture of the tile.
The embodiments of the present invention are preferred embodiments of the present application, and the scope of the present application is not limited by the embodiments of the present application, so: all equivalent changes made according to the structure, shape and principle of the present application shall be covered by the protection scope of the present application.
Claims (4)
1. An anti-crack ceramic tile is characterized in that: the ceramic tile comprises a blank body and glaze coated on the blank body, wherein the blank body comprises the following raw materials in parts by weight: 20-35 parts of dolomite, 10-20 parts of quartz stone, 10-18 parts of bentonite, 10-20 parts of talcum powder, 5-12 parts of waste brick and 6-18 parts of modified basalt fiber, wherein the modified basalt fiber is prepared by modifying the basalt fiber by adopting a silane coupling agent;
the modified basalt fiber is prepared by adopting the following method: adding a silane coupling agent into acetone, uniformly stirring, adding basalt fibers, performing ultrasonic dispersion, filtering, washing and drying to obtain modified basalt fibers;
the weight ratio of the silane coupling agent to the basalt fiber is (0.3-0.5): 1;
the modified basalt fiber is pretreated by adopting the following method before use: soaking the modified basalt fiber in a sodium hydroxide solution, taking out, and drying until the water content is less than 0.5% to obtain a pretreated modified basalt fiber;
the length of the modified basalt fiber is 5-10mm;
the bentonite is sodium bentonite;
the glaze comprises the following raw materials in parts by weight: 20-45 parts of potassium feldspar granite, 5-10 parts of nano zinc oxide, 5-10 parts of nano silicon dioxide, 3-8 parts of carboxymethyl cellulose, 1-2 parts of sodium hexametaphosphate and 50-56 parts of water.
2. The crack-resistant ceramic tile according to claim 1, wherein: the blank body comprises the following raw materials in parts by weight: 25-30 parts of dolomite, 12-18 parts of quartz stone, 12-16 parts of bentonite, 14-17 parts of talcum powder, 6-10 parts of waste brick and 8-15 parts of modified basalt fiber.
3. A process for the production of an anti-crack tile according to any one of claims 1-2, characterized in that it comprises the following steps:
s1: uniformly mixing dolomite, quartz stone, bentonite, talcum powder and waste bricks, grinding, adding modified basalt fiber, and uniformly mixing to obtain a blank;
s2: uniformly mixing potassium feldspar granite, nano zinc oxide, nano silicon dioxide, carboxymethyl cellulose and sodium hexametaphosphate, grinding, adding water, and uniformly stirring to obtain a glaze;
s3: pressing the blank into a green body, and drying to obtain the green body;
s4: and uniformly coating the glaze on the green body, drying, firing and cooling to obtain the anti-cracking ceramic tile.
4. The process for producing an anti-cracking ceramic tile according to claim 3, wherein: the firing temperature in the step S4 is 1150-1200 ℃, and the firing time is 60-70min.
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| CN101508576A (en) * | 2009-04-03 | 2009-08-19 | 黄家遵 | High-strength tile and method of producing the same |
| CN103951402B (en) * | 2014-04-08 | 2015-08-19 | 安徽省亚欧陶瓷有限责任公司 | A kind of high-strength ceramic brick and preparation method thereof |
| WO2016098022A1 (en) * | 2014-12-16 | 2016-06-23 | Agenzia Nazionale Per Le Nuove Tecnologie, L'energia E Lo Sviluppo Economico Sostenibile (Enea) | A method to manufacture an article make of a fiber-reinforced thermostructural composite |
| CN106083014A (en) * | 2016-06-12 | 2016-11-09 | 浙江孚瓯科技有限公司 | Preparation method of foaming building stones roof heat insulation brick and products thereof |
| CN106278372A (en) * | 2016-08-11 | 2017-01-04 | 安庆太极新型建材开发有限公司 | A kind of micropore sintered brick of humus sour water glass composite strengthening crack resistance |
| CN107324777A (en) * | 2017-07-19 | 2017-11-07 | 合肥广民建材有限公司 | A kind of heat preservation and soundproof inner-wall ceramic tile and preparation method thereof |
| PL3466903T3 (en) * | 2017-10-04 | 2020-09-21 | Refractory Intellectual Property Gmbh & Co. Kg | Batch for producing a refractory product, method for the manufacture of a refractory product, a refractory product and the use of synthetic raw material |
| CN114605106B (en) * | 2022-03-17 | 2022-11-18 | 江苏洋林木业有限公司 | Composite building material and preparation method thereof |
| CN114671677B (en) * | 2022-04-11 | 2023-04-18 | 河北新玻尔瓷业有限公司 | Energy-saving high-hardness ceramic tile and production process thereof |
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