CN115231929A - High-temperature-resistant non-combustible fiber composite material and preparation method thereof - Google Patents

High-temperature-resistant non-combustible fiber composite material and preparation method thereof Download PDF

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CN115231929A
CN115231929A CN202210765493.2A CN202210765493A CN115231929A CN 115231929 A CN115231929 A CN 115231929A CN 202210765493 A CN202210765493 A CN 202210765493A CN 115231929 A CN115231929 A CN 115231929A
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fiber
parts
resin
combustible
composite material
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CN115231929B (en
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刘章友
胡之峰
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Kuberd Chemical Shanghai Co ltd
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Kuberd Chemical Shanghai Co ltd
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Abstract

The invention discloses a high temperature resistant non-combustible fiber composite material and a preparation method thereof, wherein the composite material comprises the following components: a fiber fabric and a non-combustible resin base material; the non-combustible resin matrix material comprises the following components in parts by weight: 100 parts of KB-8812 resin, 10 to 90 parts of short fibers, 3 to 30 parts of boron nitride, 0.5 to 10 parts of bentonite, 0.1 to 5 parts of dicumyl peroxide and 1 to 10 parts of silane coupling agent. The composite fiber material has the characteristics of high temperature resistance and non-combustibility by compounding the high temperature resistant non-combustible resin and the fiber fabric, and has wide application prospects in the fields of aerospace vehicle shell materials, near space and high-speed aircrafts in atmosphere, recoverable satellites, automobiles, industry and the like.

Description

High-temperature-resistant non-combustible fiber composite material and preparation method thereof
Technical Field
The invention relates to a high-temperature-resistant non-combustible fiber composite material, in particular to a high-temperature-resistant non-combustible fiber composite material and a preparation method thereof.
Background
Since the development of resin-based composite materials in the last century, thermosetting resin-based composite materials have been developed, and fiber-reinforced thermosetting resin-based composite materials (fiber composite materials) have been widely used in various fields of national economy, such as aviation, aerospace, automobiles, sports equipment and energy sources, due to the advantages of light weight, high strength, high modulus, strong designability, corrosion resistance, friction resistance, convenience in integral forming and the like.
With the development of the industries of aerospace, wind energy, automobiles, sports equipment and the like, the application of the fiber reinforced composite material under extreme conditions becomes a further pursuit target after pursuing the requirements of light weight and high strength. Such as Olympic torches, aerospace vehicle housing materials, near space and high speed aircraft in the atmosphere, recoverable satellites, engine exhaust structures for aerospace, liquid fuel housings and engine nacelles, etc., which tend to have a short life due to pyrolysis, high temperature degradation and thermo-mechanical stress, etc., and thus, there is an increasing demand for high temperature resistant, non-combustible fibrous composites.
The performance of the fiber composite material is determined by the fiber body, the resin matrix and the interface bonding performance between the fiber body and the resin matrix. At present, the research on the high-temperature resistance and non-combustibility of fiber composite materials mainly focuses on improving the interface modification of fibers and resin, and the research on improving the high-temperature resistance of the composite materials by improving the high-temperature resistance of the resin is rarely reported. For example, in patents (CN 111534050A), CN 113105717A, and CN 107629224A), the surface of carbon fiber is modified or nanoparticles are introduced into the interface to improve the high temperature resistance of the fiber composite material, but these methods are often very limited in the improvement of the high temperature resistance, and cannot fundamentally solve the problem of high temperature resistance.
Disclosure of Invention
The invention aims to provide a high-temperature-resistant non-combustible fiber composite material and a preparation method thereof.
In order to achieve the above object, the present invention provides a high temperature resistant non-combustible fiber composite material comprising: a fiber fabric and a non-combustible resin base material; the high-temperature-resistant non-combustible fiber composite material is obtained by pouring a non-combustible resin matrix material into a three-satin carbon fiber fabric through a resin transfer molding process or a vacuum auxiliary molding process.
Wherein the non-combustible resin matrix material comprises the following components in parts by weight: 100 parts of KB-8812 resin, 10 to 90 parts of short fibers, 3 to 30 parts of boron nitride, 0.5 to 10 parts of bentonite, 0.1 to 5 parts of dicumyl peroxide and 1 to 10 parts of silane coupling agent; the short fiber is selected from any one or more than two of carbon fiber, ceramic fiber, metal fiber, aramid fiber, boron fiber, basalt fiber, ultra-high molecular weight polyethylene fiber, PBO fiber, M5 fiber, vectran fiber with the length-diameter ratio of 0.5 to 200, and carbon nanotube fiber with the length-diameter ratio of 0.5 to 10000; the KB-8812 resin is vinyl-containing polysilazane resin, the viscosity of the resin is 200 to 10000 cps, and the resin is cured and ceramized by a resin transfer molding process or a vacuum auxiliary molding process to form a three-dimensional SiNCO ceramic structure.
The fiber fabric is compounded with the non-combustible resin base material, in the molding process, KB-8812 resin forms a three-dimensional ceramic structure of SiNCO after being cured and ceramized, and the composite material prepared from the fiber fabric has the characteristic of high temperature resistance. The composite material of the invention needs the combined action of a plurality of components to achieve good effect. The short fibers play a toughening role, if the short fibers are not added, the resin can crack, a large number of fibers are exposed, the composite material has many defects and serious deformation, and the composite material cannot be used in practice; the low expansion coefficient of boron nitride can improve heat resistance and reduce volume shrinkage of a system in a curing/ceramic process, and if the boron nitride is not added, the resin can crack; the bentonite increases the mutual adhesion of a filler system, and if the bentonite is not added, the resin has a plurality of microcracks; dicumyl peroxide is used as an initiator, so that the curing temperature can be reduced, the curing reaction rate can be increased, and if the dicumyl peroxide is not added, the resin cannot be completely cured; the silane coupling agent can increase the interface bonding force among the components, and if the silane coupling agent is not added, the mechanical property is poor.
Preferably, the non-combustible resin matrix material comprises the following components in parts by weight: 100 parts of KB-8812 resin, 50 to 60 parts of short fibers, 20 to 30 parts of boron nitride, 8 to 10 parts of bentonite, 2 to 3 parts of dicumyl peroxide and 1 to 2 parts of silane coupling agent.
Preferably, in the composite material, the volume content of the three-satin carbon fiber fabric is 40-80%, and the volume content of the non-combustible resin matrix material is 20-60%.
Preferably, the volume content of the three-satin carbon fiber fabric is 60 to 70 percent, and the volume content of the non-combustible resin matrix material is 30 to 40 percent.
Preferably, the short fiber is any one selected from carbon fiber, glass fiber, aramid fiber and basalt fiber with the length-diameter ratio of 0.5 to 200, and carbon nanotube fiber with the length-diameter ratio of 0.5 to 10000.
More preferably, the short fiber is selected from any one of carbon fiber, glass fiber, aramid fiber, basalt fiber, and carbon nanotube fiber having an aspect ratio of 5 and 1000.
Preferably, the KB-8812 resin has viscosity of 800 to 900 cps.
Preferably, the fiber fabric is selected from any one of plain weave fabric, twill weave fabric, satin weave fabric, unidirectional fabric and multilayer multiaxial fabric.
Another object of the present invention is to provide a method for preparing the high temperature resistant non-combustible fiber composite material, which comprises:
(1) And (3) curing: pouring a non-combustible resin matrix material into the three-satin carbon fiber fabric, and curing at 180 to 240 ℃ for 1 to 4 hours;
(2) The ceramic process comprises the following steps: heating to 300 ℃ at the speed of 5-20 ℃/min, heating to 1100-1600 ℃ at the speed of 1-6 ℃/min under the protection of nitrogen atmosphere, preserving heat for 0-3 h, and then cooling to below 240 ℃ at the speed of 1-6 ℃/min.
Preferably, in the curing process, the curing is carried out for 2 to 4 hours at 200 to 240 ℃.
Preferably, in the ceramic forming process, the temperature is raised to 300 ℃ at a speed of 10 to 20 ℃/min, the temperature is raised to 1100 to 1400 ℃ at a speed of 3 to 6 ℃/min under the protection of nitrogen atmosphere, the temperature is kept for 1 to 2h, and then the temperature is lowered to below 200 ℃ at a speed of 4 to 6 ℃/min.
Another object of the present invention is to provide a non-combustible resin base material comprising the following components in parts by weight: 100 parts of KB-8812 resin, 10 to 90 parts of short fibers, 3 to 30 parts of boron nitride, 0.5 to 10 parts of bentonite, 0.1 to 5 parts of dicumyl peroxide and 1 to 10 parts of silane coupling agent; the short fiber is selected from any one or more than two of carbon fiber, ceramic fiber, metal fiber, aramid fiber, boron fiber, basalt fiber, ultra-high molecular weight polyethylene fiber, PBO fiber, M5 fiber, vectran fiber with the length-diameter ratio of 0.5 to 200 and carbon nanotube fiber with the length-diameter ratio of 0.5 to 10000; the KB-8812 resin is vinyl-containing polysilazane resin, the viscosity of the vinyl-containing polysilazane resin is 200 to 10000 cps, and the resin is cured and ceramized by a resin transfer molding process or a vacuum auxiliary molding process to form a three-dimensional SiNCO ceramic structure.
The high-temperature-resistant non-combustible fiber composite material and the preparation method thereof have the following advantages:
the fiber fabric is compounded with the non-combustible resin matrix material, through the design of the components and the content of the non-combustible resin matrix material and the molding process conditions, in the molding process, the non-combustible resin matrix can form a three-dimensional SiNCO ceramic structure after being cured and ceramized, and the composite material prepared from the fiber fabric has the characteristic of high temperature resistance.
The composite material of the invention needs the combined action of a plurality of components to achieve good effect. The short fibers play a toughening role, if the short fibers are not added, the resin can crack, a large number of fibers are exposed, the composite material has many defects and serious deformation, and the composite material cannot be used practically; the low expansion coefficient of boron nitride can improve heat resistance and reduce volume shrinkage of a system in a curing/ceramic process, and if the boron nitride is not added, the resin can crack; the bentonite increases the mutual adhesion of a filler system, and if the bentonite is not added, the resin has a plurality of microcracks; dicumyl peroxide is used as an initiator, so that the curing temperature can be reduced, the curing reaction rate can be increased, and if the dicumyl peroxide is not added, the resin cannot be completely cured; the silane coupling agent can increase the interface bonding force among the components, and if the silane coupling agent is not added, the mechanical property is poor.
The fiber composite material is prepared by using the high-temperature-resistant non-combustible resin and the fiber fabric through a RTM (resin transfer molding) or VARI (vacuum transfer molding) process, so that the fiber composite material has the characteristics of high-temperature resistance and non-combustion, and has wide application prospects in the fields of aerospace vehicle shell materials, high-speed aircrafts in near space and atmosphere, recoverable satellites, automobiles, industry and the like.
Drawings
FIG. 1 is a microscopic structural view of a fiber composite prepared in example 1 of the present invention.
Fig. 2 is a microscopic structural view of the fiber composite prepared in example 2 of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
A high temperature resistant, non-combustible fibrous composite material comprising: three satin carbon fiber fabrics and a non-combustible resin matrix material. The high-temperature-resistant non-combustible fiber composite material is obtained by pouring a non-combustible resin matrix material into a three-satin carbon fiber fabric through a Resin Transfer Molding (RTM) forming process. The non-combustible resin matrix material comprises the following components in parts by weight: 100 parts of KB-8812 resin (supplied by Kubei chemical Shanghai Co., ltd.) having a viscosity of about 800 cps, 60 parts of glass fiber powder having an aspect ratio of 5, 20 parts of boron nitride, 8 parts of bentonite, 2 parts of dicumyl peroxide and 2 parts of a silane coupling agent.
Figure 422924DEST_PATH_IMAGE001
KB-8812
The preparation process of the high-temperature-resistant non-combustible fiber composite material comprises the following specific steps:
(1) And (3) curing: pouring a non-combustible resin matrix material into the three-satin carbon fiber fabric, reacting for 2 hours at 240 ℃, and carrying out a double-bond cross-linking curing reaction;
(2) The ceramic process comprises the following steps: heating to 300 ℃ at the speed of 20 ℃/min, heating to 1100 ℃ at the speed of 6 ℃/min under the protection of nitrogen atmosphere, preserving heat for 1h, cooling to 240 ℃ at the speed of 6 ℃/min, and deaminizing, dehydrogenating and decarbonizing the resin matrix to form a three-dimensional SiCNO structure, thereby obtaining the high-temperature-resistant non-combustible fiber composite material.
The microstructure of the high-temperature-resistant non-combustible fiber composite material is shown in fig. 1, resin permeates fiber bundles and is uniformly distributed in the fiber bundles to wrap the fibers, and through calculation of the content of the fibers and the resin in SEM, the volume content of the triple-forged-grain carbon fiber fabric in the composite material is about 55%, and the volume content of a non-combustible resin matrix material is about 45%.
The decomposition temperature (measured under nitrogen) and mechanical properties of the high temperature resistant non-combustible fiber composite material are shown in table 1 below.
TABLE 1
Item Decomposition temperature Tensile strength Tensile modulus Bending strength Flexural modulus Interlaminar shear strength
Test method No damage in a tube furnace at 1900 DEG C ASTM D3039 ASTM D3039 ASTM D7264 ASTM D7264 ASTM D2344
Test results ≈1900 ℃ 610 MPa 56 GPa 530 MPa 65 GPa 46 MPa
Example 2
A high-temperature-resistant non-combustible fiber composite material is obtained by a vacuum assisted molding (VARI) process through the following components in parts by weight: 100 parts of a plain weave carbon fiber fabric, 100 parts of KB-8812 resin (supplied by Kubei chemical Shanghai Co., ltd.) having a viscosity of about 900 cps, 50 parts of glass fiber powder having an aspect ratio of 5, 30 parts of boron nitride, 8 parts of bentonite, 3 parts of dicumyl peroxide and 1 part of a silane coupling agent.
The preparation process of the high-temperature-resistant non-combustible fiber composite material comprises the following specific steps:
(1) And (3) curing process: reacting for 4 hours at 180 ℃ to generate a curing reaction of double bond crosslinking;
(2) The ceramic process comprises the following steps: heating to 300 ℃ at the speed of 10 ℃/min, heating to 1300 ℃ at the speed of 5 ℃/min under the protection of nitrogen atmosphere, preserving heat for 0.5 h, cooling to 200 ℃ at the speed of 6 ℃/min, and carrying out deamination, dehydrogenation and decarbonization on a resin matrix to form a SiCNO three-dimensional structure, thereby obtaining the high-temperature-resistant non-combustible fiber composite material.
The microstructure of the high-temperature resistant non-combustible fiber composite material is shown in fig. 2, resin permeates fiber bundles, is uniformly distributed in the fiber bundles, and wraps the fibers, and through calculation of the content of the fibers and the resin in the SEM, the volume content of the three-forged-grain carbon fiber fabric in the composite material is about 60%, and the volume content of the non-combustible resin matrix material is 40%.
The decomposition temperature (measured under nitrogen) and mechanical properties of the high temperature resistant non-combustible fiber composite material are shown in the following table 2, and the fiber composite material cracks and decomposes into powder after the decomposition temperature is exceeded.
TABLE 2
Item Decomposition temperature Tensile strength Tensile modulus Flexural strength Flexural modulus Interlaminar shear strength
Test method No damage in 1900 deg.C tube furnace ASTM D3039 ASTM D3039 ASTM D7264 ASTM D7264 ASTM D2344
Test results ≈1900 ℃ 630 MPa 66 GPa 560 MPa 68 GPa 50 MPa
Example 3
A high temperature resistant non-combustible fibrous composite material substantially identical to that of example 2 except that: the carbon nanotube fiber with the length-diameter ratio of 1000 is adopted to replace the glass fiber powder with the length-diameter ratio of 5. The composite was prepared by the same procedure as in example 2.
The decomposition temperature (measured under nitrogen) and mechanical properties of the high temperature resistant non-combustible fiber composite material are shown in table 3 below.
TABLE 3
Item Decomposition temperature Tensile strength Tensile modulus Bending strength Flexural modulus Interlaminar shear strength
Test method No damage in 1900 deg.C tube furnace ASTM D3039 ASTM D3039 ASTM D7264 ASTM D7264 ASTM D2344
Test results ≈1900 ℃ 635 MPa 60 GPa 580 MPa 70 GPa 54 MPa
By comparison with example 2, it can be seen that the carbon nanotube fiber has more excellent synergistic enhancement effect than the glass fiber.
Example 4
A high temperature resistant non-combustible fibrous composite material substantially identical to that of example 1 except that: in the incombustible resin base material, the addition amount of glass fiber powder with the length-diameter ratio of 5 is 10 parts, the addition amount of boron nitride is 3 parts, the addition amount of bentonite is 0.5 part, the addition amount of dicumyl peroxide is 0.5 part, and the addition amount of silane coupling agent is 1 part. The composite material was prepared by the same procedure as in example 1.
The decomposition temperature (measured under nitrogen) and mechanical properties of the high temperature resistant non-combustible fiber composite material are shown in table 4 below.
TABLE 4
Item Decomposition temperature Tensile strength Tensile modulus Flexural strength Flexural modulus Interlaminar shear strength
Test method No damage in 1900 deg.C tube furnace ASTM D3039 ASTM D3039 ASTM D7264 ASTM D7264 ASTM D2344
Test results ≈1900 ℃ 550 MPa 40 GPa 490 MPa 55 GPa 40 MPa
Example 5
A high temperature resistant non-combustible fibrous composite material substantially identical to that of example 1 except that: in the incombustible resin base material, the addition amount of the glass fiber powder with the length-diameter ratio of 5 is 90 parts, the addition amount of the boron nitride is 30 parts, the addition amount of the bentonite is 10 parts, the addition amount of the dicumyl peroxide is 5 parts, and the addition amount of the silane coupling agent is 10 parts. The composite material was prepared by the same procedure as in example 1.
The decomposition temperature (measured under nitrogen) and mechanical properties of the high temperature resistant non-combustible fiber composite material are shown in table 5 below.
TABLE 5
Item Decomposition temperature Tensile strength Tensile modulus Flexural strength Flexural modulus Interlaminar shear strength
Test method No damage in a tube furnace at 1900 DEG C ASTM D3039 ASTM D3039 ASTM D7264 ASTM D7264 ASTM D2344
Test results ≈1900 ℃ 600 MPa 53 GPa 518 MPa 62 GPa 43 MPa
By comparing example 1, example 4 and example 5, it can be seen that the change of the component content in the non-combustible resin matrix material can cause the change of the mechanical property of the material, and the high-temperature resistant non-combustible fiber composite material with higher mechanical property can be obtained under the condition of proper proportion of the resin matrix component.
Example 6
A high temperature resistant non-combustible fibrous composite material substantially identical to that of example 2 except that: glass fiber powder (short fiber) having an aspect ratio of 5 was not added.
The preparation process of the composite material is the same as that of example 2, but in the ceramization process, the resin is seriously cracked, the fibers are greatly exposed, and the composite material has many defects and is seriously deformed, so that the composite material cannot be practically used.
Example 7
A high temperature resistant non-combustible fibrous composite material substantially identical to that of example 2 except that: no boron nitride was added.
The preparation process of the composite material is the same as that of example 2, but in the ceramization process, the resin is cracked, part of the fibers are exposed, the defects of the composite material are increased, the composite material is deformed, and the composite material cannot be practically used.
Example 8
A high temperature resistant non-combustible fibrous composite material substantially identical to that of example 2 except that: bentonite is not added.
The preparation process of the composite material is the same as that of the embodiment 2, but in the ceramic process, the resin has a plurality of microcracks, and the composite material has obvious defects, so that the actual use is influenced.
Example 9
A high temperature resistant non-combustible fibrous composite material substantially identical to that of example 2 except that: dicumyl peroxide was not added.
The composite was prepared by the same procedure as in example 2, but during the curing process, the resin was not fully cured.
Example 10
A high temperature resistant non-combustible fibrous composite material substantially identical to that of example 2 except that: no silane coupling agent was added.
The composite was prepared by the same procedure as in example 2. The decomposition temperature (measured under nitrogen) and mechanical properties of the high temperature resistant non-combustible fiber composite material are shown in table 6 below.
TABLE 6
Item Decomposition temperature Tensile strength Tensile modulus Bending strength Flexural modulus Interlaminar shear strength
Test method No damage in 1900 deg.C tube furnace ASTM D3039 ASTM D3039 ASTM D7264 ASTM D7264 ASTM D2344
Test results ≈1900 ℃ 366 MPa 25 GPa 370 MPa 31 GPa 31 MPa
By comparison with example 2, it can be seen that the silane coupling agent has an excellent interface enhancing effect.
While the present invention has been described in detail with reference to the preferred embodiments, it should be understood that the above description should not be taken as limiting the invention. Various modifications and alterations to this invention will become apparent to those skilled in the art upon reading the foregoing description. Accordingly, the scope of the invention should be determined from the following claims.

Claims (10)

1. A high temperature resistant non-combustible fibrous composite material, characterized in that the composite material comprises: a fiber fabric and a non-combustible resin base material; the high-temperature-resistant non-combustible fiber composite material is obtained by pouring a non-combustible resin matrix material into a three-satin carbon fiber fabric through a resin transfer molding process or a vacuum auxiliary molding process;
wherein the non-combustible resin matrix material comprises the following components in parts by weight: 100 parts of KB-8812 resin, 10 to 90 parts of short fibers, 3 to 30 parts of boron nitride, 0.5 to 10 parts of bentonite, 0.1 to 5 parts of dicumyl peroxide and 1 to 10 parts of a silane coupling agent;
the short fiber is selected from any one or more than two of carbon fiber, ceramic fiber, metal fiber, aramid fiber, boron fiber, basalt fiber, ultra-high molecular weight polyethylene fiber, PBO fiber, M5 fiber, vectran fiber with the length-diameter ratio of 0.5 to 200 and carbon nanotube fiber with the length-diameter ratio of 0.5 to 10000;
the KB-8812 resin is vinyl-containing polysilazane resin, the viscosity of the resin is 200 to 10000 cps, and the resin is cured and ceramized by a resin transfer molding process or a vacuum-assisted molding process to form a three-dimensional SiNCO ceramic structure.
2. The high temperature resistant non-combustible fiber composite material of claim 1, wherein the non-combustible resin matrix material comprises the following components in parts by weight: 100 parts of KB-8812 resin, 50 to 60 parts of short fibers, 20 to 30 parts of boron nitride, 8 to 10 parts of bentonite, 2 to 3 parts of dicumyl peroxide and 1 to 2 parts of silane coupling agent.
3. The high-temperature-resistant non-combustible fiber composite material as claimed in claim 1, wherein the volume content of the three-satin carbon fiber fabric is 40-80%, and the volume content of the non-combustible resin matrix material is 20-60%.
4. The high-temperature-resistant non-combustible fiber composite material as claimed in claim 3, wherein the volume content of the three-satin carbon fiber fabric is 60 to 70%, and the volume content of the non-combustible resin matrix material is 30 to 40%.
5. The high-temperature-resistant non-combustible fiber composite material as claimed in claim 1, wherein the short fiber is selected from any one of carbon fiber, glass fiber, aramid fiber and basalt fiber with an aspect ratio of 0.5 to 200, and carbon nanotube fiber with an aspect ratio of 0.5 to 10000.
6. The high temperature resistant, non-combustible fiber composite material according to claim 1, wherein the fiber fabric is selected from any one of plain weave fabric, twill weave fabric, satin weave fabric, unidirectional fabric and multilayer multiaxial fabric.
7. A method for producing a high temperature resistant, non-combustible fibre composite material according to any of claims 1-6, characterised in that the method comprises:
(1) And (3) curing process: pouring a non-combustible resin matrix material into the three-satin carbon fiber fabric, and curing at 180 to 240 ℃ for 1 to 4 hours;
(2) The ceramic process comprises the following steps: heating to 300 ℃ at the speed of 5-20 ℃/min, heating to 1100-1600 ℃ at the speed of 1-6 ℃/min under the protection of nitrogen atmosphere, preserving heat for 0-3 h, and then cooling to below 240 ℃ at the speed of 1-6 ℃/min.
8. The production method according to claim 7, wherein the curing is performed at 200 to 240 ℃ for 2 to 4 hours.
9. The preparation method according to claim 7, wherein in the ceramization process, the temperature is raised to 300 ℃ at a speed of 10 to 20 ℃/min, the temperature is raised to 1100 to 1400 ℃ at a speed of 3 to 6 ℃/min under the protection of a nitrogen atmosphere, and the temperature is lowered to 200 ℃ at a speed of 4 to 6 ℃/min after the temperature is maintained for 1 to 2h.
10. A non-combustible resin base material is characterized by comprising the following components in parts by weight: 100 parts of KB-8812 resin, 10 to 90 parts of short fibers, 3 to 30 parts of boron nitride, 0.5 to 10 parts of bentonite, 0.1 to 5 parts of dicumyl peroxide and 1 to 10 parts of a silane coupling agent;
the short fiber is selected from any one or more than two of carbon fiber, ceramic fiber, metal fiber, aramid fiber, boron fiber, basalt fiber, ultra-high molecular weight polyethylene fiber, PBO fiber, M5 fiber, vectran fiber with the length-diameter ratio of 0.5 to 200 and carbon nanotube fiber with the length-diameter ratio of 0.5 to 10000;
the KB-8812 resin is vinyl-containing polysilazane resin, the viscosity of the resin is 200 to 10000 cps, and the resin is cured and ceramized by a resin transfer molding process or a vacuum-assisted molding process to form a three-dimensional SiNCO ceramic structure.
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Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06336551A (en) * 1993-05-27 1994-12-06 Mitsubishi Petrochem Co Ltd Thermoplastic resin composition
US6063327A (en) * 1996-12-18 2000-05-16 Raytheon Company Method for making high yield-low carbon ceramic via polysilazane
US20110268577A1 (en) * 2008-12-04 2011-11-03 Snecma Method for smoothing the surface of a part made from a cmc material
US20120034428A1 (en) * 2007-10-22 2012-02-09 Clarke William A Fire resistant flexible ceramic resin blend and composite products formed therefrom
CN106398119A (en) * 2016-08-31 2017-02-15 四川国能高科生物树脂有限公司 Fiber-reinforced biological resin adhesive composite material and preparation method thereof
CN106893106A (en) * 2017-03-08 2017-06-27 航天材料及工艺研究所 Can in-situ ceramic type anti-oxidation resin, resin matrix, ceramic material and process for preparing resins
CN109678539A (en) * 2017-10-19 2019-04-26 中国科学院上海硅酸盐研究所 A kind of densification Cf/ SiBCN ceramic matric composite and preparation method thereof
CN113150486A (en) * 2021-03-31 2021-07-23 大连理工大学 Siloxane-based ceramic polyolefin and preparation method and application thereof
CN113717639A (en) * 2021-09-15 2021-11-30 库贝化学（上海）有限公司 Polysilazane high-temperature resistant paint for carbon fiber composite material and preparation method thereof
CN113788697A (en) * 2021-10-29 2021-12-14 核工业第八研究所 Ceramic precursor slurry applicable to winding process and preparation method thereof
CN113817291A (en) * 2021-09-30 2021-12-21 广东博汇新材料科技股份有限公司 Carbon fiber vacuum infusion epoxy resin

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06336551A (en) * 1993-05-27 1994-12-06 Mitsubishi Petrochem Co Ltd Thermoplastic resin composition
US6063327A (en) * 1996-12-18 2000-05-16 Raytheon Company Method for making high yield-low carbon ceramic via polysilazane
US20120034428A1 (en) * 2007-10-22 2012-02-09 Clarke William A Fire resistant flexible ceramic resin blend and composite products formed therefrom
US20110268577A1 (en) * 2008-12-04 2011-11-03 Snecma Method for smoothing the surface of a part made from a cmc material
CN102239129A (en) * 2008-12-04 2011-11-09 斯奈克玛动力部件公司 Method for smoothing the surface of a part made from a cmc material
CN106398119A (en) * 2016-08-31 2017-02-15 四川国能高科生物树脂有限公司 Fiber-reinforced biological resin adhesive composite material and preparation method thereof
CN106893106A (en) * 2017-03-08 2017-06-27 航天材料及工艺研究所 Can in-situ ceramic type anti-oxidation resin, resin matrix, ceramic material and process for preparing resins
CN109678539A (en) * 2017-10-19 2019-04-26 中国科学院上海硅酸盐研究所 A kind of densification Cf/ SiBCN ceramic matric composite and preparation method thereof
CN113150486A (en) * 2021-03-31 2021-07-23 大连理工大学 Siloxane-based ceramic polyolefin and preparation method and application thereof
CN113717639A (en) * 2021-09-15 2021-11-30 库贝化学（上海）有限公司 Polysilazane high-temperature resistant paint for carbon fiber composite material and preparation method thereof
CN113817291A (en) * 2021-09-30 2021-12-21 广东博汇新材料科技股份有限公司 Carbon fiber vacuum infusion epoxy resin
CN113788697A (en) * 2021-10-29 2021-12-14 核工业第八研究所 Ceramic precursor slurry applicable to winding process and preparation method thereof

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