CN115224032A - Semiconductor structure and method of making the same - Google Patents
Semiconductor structure and method of making the same Download PDFInfo
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/30—DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
- H10B12/31—DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells having a storage electrode stacked over the transistor
- H10B12/315—DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells having a storage electrode stacked over the transistor with the capacitor higher than a bit line
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B10/00—Static random access memory [SRAM] devices
- H10B10/12—Static random access memory [SRAM] devices comprising a MOSFET load element
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/02—Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
- H10B12/03—Making the capacitor or connections thereto
- H10B12/033—Making the capacitor or connections thereto the capacitor extending over the transistor
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/01—Manufacture or treatment
- H10B12/02—Manufacture or treatment for one transistor one-capacitor [1T-1C] memory cells
- H10B12/05—Making the transistor
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/30—DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
- H10B12/48—Data lines or contacts therefor
- H10B12/482—Bit lines
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B12/00—Dynamic random access memory [DRAM] devices
- H10B12/30—DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
- H10B12/48—Data lines or contacts therefor
- H10B12/488—Word lines
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Abstract
Description
技术领域technical field
本发明实施例涉及半导体技术领域,特别涉及一种半导体结构及其制造方法。Embodiments of the present invention relate to the technical field of semiconductors, and in particular, to a semiconductor structure and a manufacturing method thereof.
背景技术Background technique
随着对半导体器件具有高性能和低成本的需求的增加,对半导体器件的高集成密度和低功耗的需求也增加。As the demand for semiconductor devices to have high performance and low cost increases, so does the demand for high integration density and low power consumption of semiconductor devices.
然而,半导体器件集成密度的增加和半导体器件工作时功耗的降低均对其制造工艺提出了更高的要求。二维(2D)或平面型半导体器件的集成密度主要由组成半导体器件中单个功能器件(如存储单元)所占的面积决定。单个功能器件所占的面积很大程度上取决于用于定义单个功能器件以及功能器件之间相互连接的电连接结构的尺寸参数。为提供尺寸更精细的单个功能器件和电连接结构,用于形成单个功能器件和电连接结构的开发成本和使用成本都很高。为降低半导体器件工作时的功耗,对半导体器件中单个功能器件之间的电连接方式也提出了更高的要求。However, the increase in the integration density of semiconductor devices and the reduction in power consumption during operation of the semiconductor devices have put forward higher requirements on their manufacturing processes. The integration density of two-dimensional (2D) or planar semiconductor devices is mainly determined by the area occupied by individual functional devices (eg, memory cells) that make up the semiconductor device. The area occupied by a single functional device depends to a large extent on the dimensional parameters of the electrical connection structures used to define the single functional device and the interconnections between the functional devices. In order to provide individual functional devices and electrical connection structures with finer dimensions, both the development cost and the use cost for forming the individual functional devices and electrical connection structures are high. In order to reduce the power consumption of the semiconductor device during operation, higher requirements are also placed on the electrical connection between the individual functional devices in the semiconductor device.
发明内容SUMMARY OF THE INVENTION
本发明实施例解决的技术问题为提供一种半导体结构及其制造方法,有利于提高半导体结构集成密度,和降低半导体结构工作时的功耗。The technical problem solved by the embodiments of the present invention is to provide a semiconductor structure and a manufacturing method thereof, which are beneficial to improve the integration density of the semiconductor structure and reduce the power consumption of the semiconductor structure during operation.
为解决上述问题,本发明实施例提供一种半导体结构,包括:基底,所述基底内具有金属位线,且所述基底露出所述金属位线表面;半导体通道,所述半导体通道位于所述金属位线的部分表面,在沿所述基底指向所述金属位线的方向上,所述半导体通道包括依次排列的第一掺杂区、沟道区以及第二掺杂区,所述第一掺杂区与所述金属位线电连接;字线,所述字线环绕所述沟道区设置;介质层,所述介质层位于所述金属位线与所述字线之间,且还位于所述字线远离所述基底的一侧;电容结构,所述电容结构位于所述第二掺杂区远离所述沟道区的一侧,且所述电容结构与所述第二掺杂区相接触。In order to solve the above problem, an embodiment of the present invention provides a semiconductor structure, including: a substrate having a metal bit line in the substrate, and the substrate exposes the surface of the metal bit line; a semiconductor channel, the semiconductor channel is located in the A part of the surface of the metal bit line, along the direction of the substrate to the metal bit line, the semiconductor channel includes a first doped region, a channel region and a second doped region arranged in sequence, the first doped region a doped region is electrically connected to the metal bit line; a word line, the word line is arranged around the channel region; a dielectric layer, the dielectric layer is located between the metal bit line and the word line, and also is located on the side of the word line away from the substrate; a capacitor structure, the capacitor structure is located on the side of the second doped region away from the channel region, and the capacitor structure is connected to the second doped region area contact.
相应地,本发明实施例还提供一种半导体结构的制造方法,包括:提供基底,所述基底内具有金属位线,且所述基底露出所述金属位线表面;形成半导体通道,所述半导体通道位于所述金属位线的部分表面上,在沿所述基底指向所述金属位线的方向上,所述半导体通道包括依次排列的第一掺杂区、沟道区以及第二掺杂区,所述第一掺杂区与所述金属位线电连接;形成字线,所述字线环绕所述沟道区设置;形成介质层,所述介质层位于所述金属位线与所述字线之间,且还位于所述字线远离所述基底的一侧;形成电容结构,所述电容结构位于所述第二掺杂区远离所述沟道区的一侧,且所述电容结构与所述第二掺杂区相接触。Correspondingly, an embodiment of the present invention also provides a method for manufacturing a semiconductor structure, including: providing a substrate with a metal bit line in the substrate, and the substrate exposes the surface of the metal bit line; forming a semiconductor channel, the semiconductor A channel is located on a part of the surface of the metal bit line, and in a direction along the substrate to the metal bit line, the semiconductor channel includes a first doped region, a channel region and a second doped region arranged in sequence , the first doped region is electrically connected to the metal bit line; a word line is formed, and the word line is arranged around the channel region; a dielectric layer is formed, and the dielectric layer is located between the metal bit line and the between the word lines, and also on the side of the word line away from the substrate; forming a capacitor structure, the capacitor structure is located on the side of the second doped region away from the channel region, and the capacitor A structure is in contact with the second doped region.
与现有技术相比,本发明实施例提供的技术方案具有以下优点:Compared with the prior art, the technical solutions provided by the embodiments of the present invention have the following advantages:
上述技术方案中,半导体通道的沟道区垂直设置在金属位线表面,即沟道区的延伸方向垂直于金属位线表面,在无需对半导体通道的尺寸进行缩小的前提下,有利于节省半导体通道在平行于金属位线表面方向(通常为水平方向)上的布局空间,从而提高半导体结构在水平方向上的集成密度。进一步地,半导体通道位于金属位线部分表面,与金属位线相接触,第二掺杂区与电容结构相接触,则无需额外的电连接结构实现半导体通道与金属位线和电容结构之间的电连接,有利于降低半导体结构的制造成本,以及降低电信号在半导体通道与金属位线和电容结构之间传递所需的功耗。此外,金属位线的电阻率低,导电性能优良,有利于进一步降低半导体结构工作时的能耗;且金属位线位于基底中,有利于降低半导体结构的整体厚度,以进一步缩减半导体结构的整体尺寸。In the above technical solution, the channel region of the semiconductor channel is vertically arranged on the surface of the metal bit line, that is, the extension direction of the channel region is perpendicular to the surface of the metal bit line, which is conducive to saving semiconductors without reducing the size of the semiconductor channel. The layout space of the channel in the direction parallel to the surface of the metal bit line (usually the horizontal direction), thereby improving the integration density of the semiconductor structure in the horizontal direction. Further, the semiconductor channel is located on a part of the surface of the metal bit line and is in contact with the metal bit line, and the second doped region is in contact with the capacitor structure, so that no additional electrical connection structure is required to realize the connection between the semiconductor channel and the metal bit line and the capacitor structure. The electrical connection is beneficial to reduce the manufacturing cost of the semiconductor structure and reduce the power consumption required for the transmission of electrical signals between the semiconductor channel and the metal bit line and the capacitor structure. In addition, the metal bit line has low resistivity and excellent electrical conductivity, which is conducive to further reducing the energy consumption of the semiconductor structure during operation; and the metal bit line is located in the substrate, which is conducive to reducing the overall thickness of the semiconductor structure, so as to further reduce the overall semiconductor structure. size.
另外,半导体通道构成的器件为无结晶体管,无结晶体管无PN结,制备工艺简单,性能优越,增强了器件的可靠性特别是抗热载流子注入效应及噪声容限,有利于进一步改善半导体结构的电学性能。In addition, the device composed of the semiconductor channel is a junctionless transistor, and the junctionless transistor has no PN junction, the preparation process is simple, and the performance is excellent, which enhances the reliability of the device, especially the resistance to hot carrier injection effect and noise tolerance, which is conducive to further improvement. Electrical properties of semiconductor structures.
附图说明Description of drawings
一个或多个实施例通过与之对应的附图中的图片进行示例性说明,除非有特别申明,附图中的图不构成比例限制。One or more embodiments are exemplified by the pictures in the accompanying drawings, which do not constitute a scale limitation unless otherwise stated.
图1为本发明一实施例提供的半导体结构对应的剖面结构示意图;FIG. 1 is a schematic cross-sectional structure diagram corresponding to a semiconductor structure provided by an embodiment of the present invention;
图2至图16为本发明又一实施例提供的半导体结构的制造方法中各步骤对应的剖面结构示意图。2 to 16 are schematic cross-sectional structural diagrams corresponding to each step in a method for fabricating a semiconductor structure according to another embodiment of the present invention.
具体实施方式Detailed ways
由背景技术可知,现有技术中半导体器件的集成密度有待提高,且半导体器件工作时的功耗有待降低。It can be known from the background art that the integration density of the semiconductor device in the prior art needs to be improved, and the power consumption of the semiconductor device during operation needs to be reduced.
经分析可知,二维(2D)或平面型半导体器件的集成密度受单个功能器件所占的水平面积的影响较大,且受多个功能器件之间的排列方式以及功能器件之间的连接方式的影响。因而,为提高半导体器件的集成密度,常采取缩小单个功能器件的尺寸或者缩小相邻功能器件之间的间隔的措施。然而,用于定义单个功能器件以及功能器件之间相互连接的电连接结构的尺寸参数的制造设备的开发成本和使用成本都很高。此外,半导体器件工作时的功耗受功能器件之间的连接方式的影响,连接功能器件之间的连接结构的长度越长,半导体器件工作时的功耗越大。The analysis shows that the integration density of two-dimensional (2D) or planar semiconductor devices is greatly affected by the horizontal area occupied by a single functional device, and by the arrangement of multiple functional devices and the connection between functional devices. Impact. Therefore, in order to improve the integration density of semiconductor devices, measures are often taken to reduce the size of a single functional device or reduce the interval between adjacent functional devices. However, the development and use costs of manufacturing equipment for defining the dimensional parameters of the individual functional devices and the electrical connection structures interconnecting the functional devices are high. In addition, the power consumption during operation of the semiconductor device is affected by the connection method between the functional devices. The longer the length of the connection structure connecting the functional devices, the greater the power consumption during operation of the semiconductor device.
可见,半导体器件集成密度的显著提高是在增大其制造成本的条件下实现的。因此,为提高半导体器件的集成密度,发展三维(3D)半导体器件,即在水平方向上降低半导体器件中单个功能器件的占位面积很有必要。为降低半导体器件工作时的功耗,改善半导体器件中功能器件之间的连接方式很有必要。It can be seen that the significant increase in the integration density of semiconductor devices is achieved under the condition of increasing their manufacturing costs. Therefore, in order to increase the integration density of semiconductor devices, it is necessary to develop three-dimensional (3D) semiconductor devices, that is, to reduce the footprint of a single functional device in a semiconductor device in a horizontal direction. In order to reduce the power consumption of the semiconductor device during operation, it is necessary to improve the connection between functional devices in the semiconductor device.
为解决上述问题,本发明实施例提供一种半导体结构及其制造方法。在半导体结构中,通过改变半导体通道在金属位线上的排布方式,即使得沟道区的延伸方向垂直于金属位线表面,一方面,使得半导体通道的第一掺杂区与金属位线接触电连接,第二掺杂区与电容结构接触电连接,无需额外的电连接结构实现半导体通道与金属位线和电容结构之间的电连接,有利于降低半导体结构的制造成本,以及降低电信号在半导体通道与金属位线和电容结构之间传递所需的功耗;另一方面,在无需对半导体通道的尺寸进行缩小的前提下,有利于节省半导体通道在平行于金属位线表面方向上的布局空间,从而提高半导体结构在水平方向上的集成密度。此外,金属位线的电阻率低,有利于进一步降低半导体结构工作时的能耗;且金属位线位于基底中,有利于降低半导体结构的整体厚度,以进一步缩减半导体结构的整体尺寸。To solve the above problems, embodiments of the present invention provide a semiconductor structure and a manufacturing method thereof. In the semiconductor structure, by changing the arrangement of the semiconductor channel on the metal bit line, that is, the extending direction of the channel region is perpendicular to the surface of the metal bit line, on the one hand, the first doped region of the semiconductor channel is connected to the metal bit line. Contact and electrical connection, the second doped region is in contact and electrical connection with the capacitor structure, no additional electrical connection structure is required to realize the electrical connection between the semiconductor channel and the metal bit line and the capacitor structure, which is beneficial to reduce the manufacturing cost of the semiconductor structure and the electrical connection. The power consumption required for signal transmission between the semiconductor channel and the metal bit line and the capacitor structure; on the other hand, without reducing the size of the semiconductor channel, it is beneficial to save the semiconductor channel in the direction parallel to the surface of the metal bit line Therefore, the integration density of the semiconductor structure in the horizontal direction is improved. In addition, the low resistivity of the metal bit line is beneficial to further reduce the energy consumption of the semiconductor structure during operation; and the metal bit line is located in the substrate, which is beneficial to reduce the overall thickness of the semiconductor structure and further reduce the overall size of the semiconductor structure.
为使本发明实施例的目的、技术方案和优点更加清楚,下面将结合附图对本发明的各实施例进行详细的阐述。然而,本领域的普通技术人员可以理解,在本发明各实施例中,为了使读者更好地理解本申请而提出了许多技术细节。但是,即使没有这些技术细节和基于以下各实施例的种种变化和修改,也可以实现本申请所要求保护的技术方案。In order to make the objectives, technical solutions and advantages of the embodiments of the present invention clearer, each embodiment of the present invention will be described in detail below with reference to the accompanying drawings. However, those of ordinary skill in the art can appreciate that, in various embodiments of the present invention, many technical details are provided for the reader to better understand the present application. However, even without these technical details and various changes and modifications based on the following embodiments, the technical solutions claimed in the present application can be realized.
本发明一实施例提供一种半导体结构,以下将结合附图对本发明一实施例提供的半导体结构进行详细说明。图1为本发明一实施例提供的半导体结构对应的剖面结构示意图。An embodiment of the present invention provides a semiconductor structure, and the semiconductor structure provided by an embodiment of the present invention will be described in detail below with reference to the accompanying drawings. FIG. 1 is a schematic cross-sectional structure diagram corresponding to a semiconductor structure provided by an embodiment of the present invention.
参考图1,半导体结构包括:基底100,基底100内具有金属位线101,且基底100露出金属位线101表面;半导体通道102,半导体通道102位于金属位线101的部分表面,在沿基底100指向金属位线101的方向上,半导体通道102包括依次排列的第一掺杂区I、沟道区II以及第二掺杂区III,第一掺杂区I与金属位线101相接触;字线104,字线104环绕沟道区设置;介质层105,介质层105位于金属位线101与字线104之间,且还位于字线104远离基底100的一侧;电容结构106,电容结构106位于第二掺杂区III远离沟道区II的一侧,且电容结构106与第二掺杂区III相接触。Referring to FIG. 1 , the semiconductor structure includes: a
由于半导体结构包括垂直的全环绕栅极(GAA,Gate-All-Around)晶体管,且金属位线101位于基底100与全环绕栅极晶体管之间,因而能够构成3D堆叠的存储器件,有利于提高半导体结构的集成密度。Since the semiconductor structure includes a vertical gate-all-around (GAA, Gate-All-Around) transistor, and the
以下将结合图1对半导体结构进行更为详细的说明。The semiconductor structure will be described in more detail below with reference to FIG. 1 .
本实施例中,基底100可以包括:逻辑电路结构层110,具有若干逻辑电路;层间介质层120,层间介质层120位于逻辑电路结构层110表面,且金属位线101位于层间介质层120远离逻辑电路结构层110的部分表面;隔离层103,隔离层103位于金属位线101露出的层间介质层120表面,且覆盖金属位线101侧壁。为了便于图示,图1中未将103标示在100对应的括号内。In this embodiment, the
具体地,逻辑电路结构层110可以为叠层结构。层间介质层120远离逻辑电路结构层110的部分表面可以具有多个间隔排布的金属位线101,每一金属位线101可与至少一个第一掺杂区I相接触电连接,图1中以每一金属位线101与2个第一掺杂区I相接触作为示例,可根据实际电学需求,合理设置与每一金属位线101相接触电连接的第一掺杂区I的数量。金属位线101顶面可以与隔离层103顶面齐平,有利于给位于金属位线101顶面和隔离层103顶面的其他结构提供良好的支撑作用。Specifically, the logic
层间介质层120用于实现逻辑电路结构层110和金属位线101之间的绝缘,且层间介质层120有利于防止相邻金属位线101之间的漏电。其中,层间介质层120的材料包括氧化硅、氮化硅、碳氮化硅或者碳氮氧化硅中的至少一种。The interlayer
隔离层103位于相邻金属位线101之间,用于实现相邻金属位线101之间的绝缘。其中,隔离层103的材料包括氧化硅、氮化硅、碳氮化硅或者碳氮氧化硅中的至少一种。The
本实施例中,层间介质层120与隔离层103为一体结构,从而改善层间介质层120与隔离层103之间的界面态缺陷,改善半导体结构的性能,且层间介质层120的材料与隔离层103的材料相同,如此,有利于减少半导体结构的制作工艺步骤,降低半导体结构的制造成本和复杂度。在其他实施例中,层间介质层与隔离层可以为分层结构,层间介质层的材料与隔离层的材料可以不同。In this embodiment, the interlayer
可以理解的是,在其他实施例中,基底也可以包括:衬底,金属位线位于衬底上,且相邻的金属位线露出部分衬底表面;隔离层,隔离层位于相邻的金属位线之间的衬底表面,用于隔离相邻的金属位线。此外,衬底内也可以具有凹槽,凹槽的位置与相邻的金属位线之间的区域正对,且隔离层填充满该凹槽。还可以理解的是,衬底可以为绝缘衬底,也可以为半导体衬底以及层间介质层的叠层结构。It can be understood that, in other embodiments, the substrate may also include: a substrate, where metal bit lines are located on the substrate, and adjacent metal bit lines expose part of the surface of the substrate; an isolation layer, where the isolation layer is located on adjacent metal bit lines The surface of the substrate between bit lines used to isolate adjacent metal bit lines. In addition, the substrate may also have a groove, the position of the groove is directly opposite to the area between adjacent metal bit lines, and the spacer layer fills the groove. It can also be understood that the substrate may be an insulating substrate, or may be a stacked structure of a semiconductor substrate and an interlayer dielectric layer.
金属位线101的材料为金属,这样设置的好处包括:一方面,金属材料的金属位线101的电阻率一般较小,有利于降低金属位线101的电阻,提高金属位线101中的电学信号的传输速率,降低金属位线101的寄生电容,且降低热损耗以降低功耗;另一方面,半导体结构还可以包括电路结构,且电路结构中具有用于实现电连接的金属导电层,如本领域技术人员常称的M0层、M1层、M2层等,可以利用金属导电层的工艺步骤,在形成金属导电层的同时制作金属位线101,如此,可节省半导体结构制作工艺步骤,降低半导体结构的成本。The material of the
金属位线101的材料可以为单金属、金属化合物或者合金。其中,单金属可以为铜、铝、钨、金或者银等;金属化合物可以为氮化钽或者氮化钛;合金可以为铜、铝、钨、金或者银中至少2者构成的合金材料。此外,金属位线101的材料还可以为镍、钴或者铂中的至少一种。The material of the
在一些实施例中,金属位线101的材料为铜。In some embodiments, the material of the
半导体结构可以包括多个间隔排布的金属位线101,且每一金属位线101沿第一方向延伸;每一金属位线101可与至少2个半导体通道102电连接。The semiconductor structure may include a plurality of
半导体通道102的材料至少包括IGZO(铟镓锌氧化物,Indium Gallium ZincOxide)、IWO(掺钨氧化铟,Indium Tungsten Oxide)或者ITO(氧化铟锡,Indium TinOxide)中的一种,半导体通道102由上述材料组成时,有利于提高半导体通道102的载流子迁移率,从而有利于半导体通道102更高效地传递电信号。The material of the
在一个例子中,半导体通道102的材料为IGZO,IGZO的载流子迁移率是多晶硅的载流子迁移率的20~50倍,有利于提高半导体通道102中沟道区II的载流子迁移率,从而有利于降低半导体结构工作时的漏电流,以降低半导体结构的功耗和提高半导体结构的工作效率。此外,由IGZO半导体通道102构成的全环绕栅极晶体管配置的存储器单元的保留时间可超过400s,有利于降低存储器的刷新率和功耗。In one example, the material of the
本实施例中,半导体通道102为圆柱状结构,则半导体通道102的侧面为平滑过渡表面,有利于避免半导体通道102发生尖端放电或者漏电的现象,进一步改善半导体结构的电学性能。需要说明的是,在其他实施例中,半导体通道也可以为椭圆柱状结构、方柱状结构或者其他不规则结构。可以理解的是,半导体通道结构为方柱状结构时,方柱状结构的侧壁相邻面构成的拐角可以为圆滑化的拐角,同样能够避免尖端放电问题,方柱状结构可以为正方体柱状结构或者长方体柱状结构。In this embodiment, the
第一掺杂区I构成晶体管器件的源极或者漏极中的一者,第二掺杂区III构成晶体管器件的源极或者漏极中的另一者。第一掺杂区I、沟道区II和第二掺杂区III中的半导体元素相同,即第一掺杂区I、沟道区II以及第二掺杂区III为一体结构,有利于改善第一掺杂区I和沟道区II之间的界面态缺陷,和改善沟道区II和第二掺杂区III之间的界面态缺陷,以改善半导体结构的性能。可以理解的是,在其他实施例中,半导体通道也可以为三层结构,且每一层结构相应作为第一掺杂区、沟道区以及第三掺杂区。The first doped region I constitutes one of the source or the drain of the transistor device, and the second doped region III constitutes the other of the source or the drain of the transistor device. The semiconductor elements in the first doping region I, the channel region II and the second doping region III are the same, that is, the first doping region I, the channel region II and the second doping region III have an integrated structure, which is conducive to improving the The interface state defects between the first doping region I and the channel region II are improved, and the interface state defects between the channel region II and the second doping region III are improved to improve the performance of the semiconductor structure. It can be understood that, in other embodiments, the semiconductor channel may also have a three-layer structure, and each layer structure corresponds to a first doped region, a channel region, and a third doped region.
其中,第一掺杂区I可以包括:第一金属半导体层112,第一金属半导体层112与金属位线101相接触,且第一金属半导体层112的电阻率小于第一金属半导体层112以外的第一掺杂区I的电阻率。如此,有利于降低第一掺杂区I的电阻率,且第一金属半导体层112与第一金属半导体层112以外的第一掺杂区I构成欧姆接触,避免金属位线101与半导体材料直接接触而形成的肖特基势垒接触,欧姆接触有利于降低第一掺杂区I与金属位线101之间的接触电阻,从而降低半导体结构工作时的能耗,且改善RC延迟效应,以提高半导体结构的电学性能。可以理解的是,在其他实施例中,第一掺杂区的半导体材料也可以直接与金属位线相接触,即第一掺杂区不包括第一金属半导体层。The first doped region I may include: a first
具体地,第一金属半导体层112中的金属元素包括钴、镍或者铂中的至少一种。以半导体通道102的材料为IGZO为例,相应的,第一金属半导体层112的材料可以为含镍的IGZO、含钴的IGZO、含钴镍的IGZO或者含铂的IGZO等。此外,第一金属半导体层112内还可以掺杂有氮元素。Specifically, the metal element in the first
第一金属半导体层112中的半导体元素与第一金属半导体层112之外的第一掺杂区I中的半导体元素相同,即第一掺杂区I整体为一体结构,则第一金属半导体层112为第一掺杂区I的一部分,有利于改善第一金属半导体层112与除第一金属半导体层112之外的第一掺杂区I之间的界面态缺陷,改善半导体结构的性能。需要说明的是,在其他实施例中,第一金属半导体层中的半导体元素也可以与第一金属半导体层之外的第一掺杂区中的半导体元素不同,例如第一金属半导体层中的半导体元素可以为硅或者锗,相应的,第一掺杂区为包括第一金属半导体层的双层结构。The semiconductor elements in the first metal-
在一些实施例中,半导体通道102与金属位线101相接触,即第一掺杂区I位于金属位线101表面。进一步地,半导体结构还可以包括:金属层108,金属层108位于半导体通道102未覆盖的金属位线101表面,且金属层108由第一金属半导体层112内的金属元素构成。可以理解的是,金属层108为形成第一金属半导体层112工艺步骤中同时形成的,金属层108的材料可以为钴、镍或者铂中的至少一种。In some embodiments, the
另外,在另一些实施例中,金属位线101的材料为镍、钴或者铂中的至少一种,则相应的,在半导体结构的制造工艺步骤中,与第一掺杂区I相接触的金属位线101中的部分区域与第一掺杂区I发生反应,以形成第一金属半导体层112,如此,金属位线101与第一金属半导体层112为一体结构,有利于进一步降低金属位线101与第一金属半导体层112之间的接触电阻。即,金属位线101可以为形成第一金属半导体层112提供金属元素。In addition, in some other embodiments, the material of the
第二掺杂区III可以包括:第二金属半导体层122,第二金属半导体层122与电容结构相接触,且第二金属半导体层122的材料的电阻率小于第二金属半导体层122之外的第二掺杂区III的电阻率。如此,有利于降低第二掺杂区III的电阻率;且第二金属半导体层122与电容结构之间形成欧姆接触,有利于降低第二掺杂区III与电容结构之间的接触电阻,从而降低半导体结构工作时的能耗,以提高半导体结构的电学性能。The second doped region III may include: a second metal-
第二金属半导体层122中的金属元素包括钴、镍或者铂中的至少一种。本实施例中,第一金属半导体层112中的金属元素与第二金属半导体层122中的金属元素可以相同。在其他实施例中,第一金属半导体层中的金属元素与第二金属半导体层中的金属元素也可以不同。The metal element in the second
此外,第二金属半导体层122中的半导体元素与第二金属半导体层122之外的第二掺杂区III中的半导体元素相同,即第二掺杂区III整体为一体结构,则第二金属半导体层122为第二掺杂区III的一部分,有利于改善第二金属半导体层122与除第二金属半导体层122之外的第二掺杂区III之间的界面态缺陷,改善半导体结构的性能。需要说明的是,在其他实施例中,第二金属半导体层中的半导体元素也可以与第二金属半导体层之外的第二掺杂区中的半导体元素不同,例如第二金属半导体层中的半导体元素可以为硅或者锗,相应的,第二掺杂区为包括第二金属半导体层的双层结构。In addition, the semiconductor elements in the second metal-
以半导体元素为硅为例,第二金属半导体层122包括硅化钴、硅化镍或者硅化铂中的至少一种。此外,第二金属半导体层122中还可以掺杂有氮元素。Taking silicon as the semiconductor element as an example, the second
半导体通道102构成的器件可以为无结晶体管(Junctionless Transistor),即第一掺杂区I、沟道区II和第二掺杂区III中的掺杂离子的类型相同,例如掺杂离子均为N型离子或者均为P型离子,进一步地,第一掺杂区I、沟道区II和第二掺杂区III中的掺杂离子可以相同。其中,此处的“无结”指的是无PN结,即半导体通道102构成的晶体管中没有PN结,这样的好处包括:一方面,无需对第一掺杂区I和第二掺杂区III进行额外的掺杂,从而避免了对第一掺杂区I和第二掺杂区III的掺杂工艺难以控制的问题,尤其是随着晶体管尺寸进一步缩小,若额外对第一掺杂区I和第二掺杂区III进行掺杂,掺杂浓度更加难以控制;另一方面,由于器件为无结晶体管,有利于避免采用超陡峭源漏浓度梯度掺杂工艺,在纳米尺度范围内制作超陡峭PN结的现象,因而可以避免掺杂突变所产生的阈值电压漂移和漏电流增加等问题,还有利于抑制短沟道效应,在几纳米的尺度范围内仍然可以工作,因而有助于进一步提高半导体结构的集成密度和电学性能。可以理解的是,此处额外的掺杂指的是,为了让第一掺杂区I和第二掺杂区III的掺杂离子类型与沟道区的掺杂离子类型不同而进行的掺杂。The device formed by the
进一步地,第一掺杂区I的掺杂离子的浓度和第二掺杂区III的掺杂离子的浓度可以均大于沟道区II的掺杂离子的掺杂浓度。掺杂离子为N型离子或者P型离子,具体地,N型离子为砷离子、磷离子或者锑离子中的至少一种;P型离子为硼离子、铟离子或者镓离子中的至少一种。Further, the concentration of the doping ions in the first doping region I and the doping ion concentration in the second doping region III may both be greater than the doping concentration of the doping ions in the channel region II. Doping ions are N-type ions or P-type ions, specifically, N-type ions are at least one of arsenic ions, phosphorus ions or antimony ions; P-type ions are at least one of boron ions, indium ions or gallium ions .
字线104包括:栅介质层114,栅介质层114环绕沟道区II设置,且位于沟道区II的半导体通道102的侧壁表面;栅导电层124,栅导电层124环绕沟道区II设置,且位于沟道区II对应的栅介质层114的侧壁表面。The
其中,栅介质层114还可以环绕第二掺杂区III设置,即还位于第二掺杂区III的半导体通道102的侧壁表面,如此,栅介质层114用于将栅导电层124与半导体通道102隔离开来。此外,位于第二掺杂区III的半导体通道102的侧壁表面的栅介质层114能够对第二掺杂区III表面起到保护作用,避免在制造工艺过程中对第二掺杂区III表面造成的工艺损伤,从而有利于进一步改善半导体结构的电学性能。可以理解的是,在其他实施例中,栅介质层也可以仅位于沟道区的半导体通道的侧壁表面。The
栅介质层114的材料包括氧化硅、氮化硅或者氮氧化硅中的至少一种,栅导电层124的材料包括多晶硅、氮化钛、氮化钽、铜、钨或者铝中的至少一种。The material of the
本实施例中,半导体结构可以包括多个间隔排布的字线104,且每一字线104沿第二方向延伸,第二方向与第一方向不同,例如第一方向可以与第二方向相垂直。此外,对于每一字线104而言,每一字线104可环绕至少一个半导体通道102的沟道区II设置,图1中以每一字线104环绕2个半导体通道102作为示例,可根据实际电学需求,合理设置每一字线104环绕的半导体通道102的数量。In this embodiment, the semiconductor structure may include a plurality of
介质层105用于隔离金属层108和字线104,以隔离金属位线101与字线104,且还用于隔离相邻的字线104和相邻金属层108。也就是说,介质层105位于金属层108与字线104之间,且还位于相邻字线104的间隔中和相邻金属层108的间隔中。The
介质层105可以包括:第一介质层115,第一介质层115位于金属层108与字线104之间以及相邻的金属层108的间隔中,以使得金属层108与字线104之间绝缘,防止金属层108与字线104之间的电干扰,以进一步防止金属位线101与字线104之间的电干扰;第二介质层125,第二介质层125位于相邻的字线104之间且与第一介质层115相接触,用于实现相邻字线104之间的绝缘,防止相邻字线104之间的电干扰;第二介质层125还位于字线104远离基底100的表面,用于支撑位于第二介质层125远离基底100的表面上的其他导电结构,并实现字线104与其他导电结构之间的绝缘。The
第二介质层125顶面可以与第二掺杂区III顶面齐平,有利于给位于第二介质层125顶面和第二掺杂区III顶面的其他结构提供良好的支撑作用。The top surface of the
本实施例中,第一介质层115的材料和第二介质层125的材料相同,均可以为氧化硅、氮化硅、碳氮氧化硅或者氮氧化硅中的至少一种。在其他实施例中,第一介质层的材料和第二介质层的材料也可以不同。In this embodiment, the material of the
可以理解的是,在其他实施例中,介质层也可以为其它堆叠膜层结构,堆叠膜层结构的具体结构与制造工艺步骤有关,保证介质层能够起到隔离目的即可。It can be understood that, in other embodiments, the dielectric layer may also be other stacked film layer structures, and the specific structure of the stacked film layer structure is related to the manufacturing process steps, as long as the dielectric layer can serve the purpose of isolation.
进一步地,半导体结构还包括:绝缘层107,绝缘层107位于第二掺杂区III远离基底100的一侧,且绝缘层107内具有贯穿绝缘层107的通孔10,通孔10露出第二掺杂区III顶面。Further, the semiconductor structure further includes: an insulating
其中,电容结构106位于通孔10中,绝缘层107用于支撑电容结构106,避免电容结构106坍塌和隔离相邻电容结构106中的下电极层116。其中,绝缘层107的材料包括氮化硅、氮氧化硅、碳氮氧化硅或者氧化硅中的至少一种。The
可以理解的是,在其他实施例中,绝缘层也可以为堆叠膜层结构,堆叠膜层结构的具体结构与制造工艺步骤有关,保证绝缘层能够起到支撑和隔离目的即可。It can be understood that, in other embodiments, the insulating layer can also be a stacked film layer structure, and the specific structure of the stacked film layer structure is related to the manufacturing process steps, as long as the insulating layer can serve the purpose of support and isolation.
具体地,电容结构106包括:下电极层116,下电极层116位于通孔10的底部和侧壁;电容介质层126,电容介质层126覆盖下电极层116的表面;上电极层136,上电极层136覆盖电容介质层126表面且填充满通孔10。Specifically, the
本实施例中,位于相邻通孔10中的下电极层116之间相互分立,位于相邻下电极层116表面的电容介质层126之间也相互间隔,且电容介质层126还位于绝缘层107靠近通孔10的部分表面,未被电容介质层126覆盖的绝缘层107的表面覆盖有第一阻挡层117。在其他实施例中,电容介质层也可以覆盖绝缘层的整个表面。In this embodiment, the
上电极层136还位于相邻电容介质层126之间的第一阻挡层117的表面,即填充满相邻通孔10的上电极层136之间相互接触连接,上电极层136为一体结构。在其他实施例中,位于相邻通孔中的上电极层之间可以具有间隔,使得相邻的电容结构中的上电极层可以连接不同的电位,有利于实现对相邻电容结构的多元化控制。The
其中,下电极层116的材料和上电极层136的材料可以相同,下电极层116的材料和上电极层136的材料均可以为镍化铂、钛、钽、钴、多晶硅、铜、钨、氮化钽、氮化钛或者钌中的至少一种。在其他实施例中,下电极层的材料和上电极层的材料也可以不同。Wherein, the material of the
电容介质层126的材料包括氧化硅、氧化钽、氧化铪、氧化锆、氧化铌、氧化钛、氧化钡、氧化锶、氧化钇、氧化镧、氧化镨或者钛酸锶钡等高介电常数材料。The material of the
本实施例中,半导体通道102为柱状结构,柱状结构的一端面,即第一掺杂区I的端面与金属位线101相接触电连接,第一掺杂区I靠近金属位线101的部分侧壁与金属层108相接触,柱状结构的另一端面,即第二掺杂区III与电容结构106相接触,更具体地,第二掺杂区III与下电极层116相接触电连接。In this embodiment, the
需要说明的是,在其他实施例中,电容结构也可以为:下电极层填充满绝缘层内的通孔;电容介质层覆盖下电极层的表面,且上电极层覆盖电容介质层远离下电极层的表面。It should be noted that, in other embodiments, the capacitor structure may also be: the lower electrode layer fills the through holes in the insulating layer; the capacitor dielectric layer covers the surface of the lower electrode layer, and the upper electrode layer covers the capacitor dielectric layer away from the lower electrode the surface of the layer.
此外,半导体结构还包括:第二阻挡层127,位于上电极层136的表面和上电极层136未覆盖的第一阻挡层117的表面,用于防止上电极层136与外部导电结构之间的电干扰。In addition, the semiconductor structure further includes: a
第一阻挡层117的材料和第二阻挡层127的材料均与绝缘层107的材料相同,有利于减少半导体结构的制作工艺所需要的材料种类,降低半导体结构的制造成本和复杂度。在其他实施例中,第一阻挡层的材料和第二阻挡层的材料也可以均与绝缘层的材料不同。The material of the first barrier layer 117 and the material of the
综上所述,半导体通道102的沟道区II垂直设置在金属位线101上,一方面,无需额外的电连接结构即可实现半导体通道102与金属位线101和电容结构106之间的电连接,有利于降低半导体结构的复杂度,以及降低电信号在半导体通道102与金属位线101和电容结构106之间传递所需的功耗;另一方面,在无需对半导体通道102的尺寸进行缩小的前提下,有利于节省半导体通道102在平行于金属位线101表面方向上的布局空间,从而提高半导体结构在水平方向上的集成密度。此外,金属位线101的电阻率低,导电性能优良,有利于进一步降低半导体结构工作时的能耗;且金属位线101位于基底100中,有利于降低半导体结构的整体厚度,以进一步缩减半导体结构的整体尺寸。To sum up, the channel region II of the
此外,本实施例提供的半导体结构可应用于4F2的存储器,F是特征尺寸,存储器可以为DRAM存储器或者SRAM存储器。相应地,本发明又一实施例提供一种半导体结构的制造方法,用于形成上述半导体结构。In addition, the semiconductor structure provided in this embodiment can be applied to a 4F 2 memory, where F is a feature size, and the memory can be a DRAM memory or an SRAM memory. Correspondingly, yet another embodiment of the present invention provides a method for fabricating a semiconductor structure for forming the above-mentioned semiconductor structure.
图2至图16为本发明又一实施例提供的半导体结构的制造方法中各步骤对应的剖面结构示意图,以下将结合附图对本实施例提供的半导体结构的制造方法进行详细说明,与上述实施例相同或相应的部分,以下将不做详细赘述。2 to FIG. 16 are schematic cross-sectional structural diagrams corresponding to each step in a method for manufacturing a semiconductor structure provided by another embodiment of the present invention. The following will describe in detail the method for manufacturing a semiconductor structure provided by this embodiment with reference to the accompanying drawings. The same or corresponding parts of the examples will not be described in detail below.
参考图2至图3,提供基底100,基底100内具有金属位线101,且基底100露出金属位线101表面。Referring to FIG. 2 to FIG. 3 , a
具体地,形成基底100以及金属位线101的工艺步骤包括如下步骤:Specifically, the process steps of forming the
参考图2,提供层叠设置的逻辑电路结构层110以及层间介质层120。Referring to FIG. 2 , a logic
其中,层间介质层120整面覆盖逻辑电路结构层110的表面,用于保护逻辑电路结构层110,防止逻辑电路结构层110与后续在层间介质层120上形成的金属位线之间的电干扰。The
参考图3,在层间介质层120表面形成若干相互分立的金属位线101,且金属位线101露出层间介质层120部分表面;形成隔离层103,隔离层103位于金属位线101露出的层间介质层120表面,且覆盖金属位线101侧壁。Referring to FIG. 3 , a number of mutually separated
有关金属位线101的材料可参考前述实施例的相应说明,在此不再赘述。基底100可以包括逻辑电路结构层110、层间介质层120以及隔离层103。For the material of the
可以理解的是,在其他实施例中,逻辑电路结构层表面也可以具有初始介质层;图形化初始介质层,以在初始介质层内形成若干相互分立的沟槽,且位于沟槽下方的初始介质层作为层间介质层,位于相邻沟槽之间的初始介质层作为隔离层,如此,隔离层与初始介质层为一体结构;然后,形成填充满沟槽的金属位线。It can be understood that, in other embodiments, the surface of the logic circuit structure layer may also have an initial dielectric layer; the initial dielectric layer is patterned to form a plurality of mutually discrete trenches in the initial dielectric layer, and the initial dielectric layer located below the grooves is formed. The dielectric layer is used as an interlayer dielectric layer, and the initial dielectric layer between adjacent trenches is used as an isolation layer. In this way, the isolation layer and the initial dielectric layer have an integrated structure; then, metal bit lines that fill the trenches are formed.
参考图4,在金属位线101表面形成第一金属层118。Referring to FIG. 4 , a
第一金属层118用于与后续形成的半导体通道靠近金属位线101的区域发生反应,为后续形成第一金属半导体层提供金属元素,以降低半导体通道的电阻率。其中,第一金属层118的材料包括钴、镍或者铂中的至少一种。The
本实施例中,第一金属层118覆盖金属位线101整个表面,可避免刻蚀第一金属层118的工艺对金属位线101带来刻蚀损伤。在其他实施例中,第一金属层也可以仅位于金属位线的部分表面,且第一金属层的位置与后续形成的半导体通道位置相对应。In this embodiment, the
在其他实施例中,也可以不在金属位线表面形成第一金属层,后续直接在金属位线的部分表面形成半导体通道即可。此外,在一些实施例中,金属位线的材料为镍、钴或者铂中的至少一者,即金属位线可以后后续形成第一金属半导体层提供金属元素,则也无需在金属位线表面形成第一金属层。In other embodiments, the first metal layer may not be formed on the surface of the metal bit line, and the semiconductor channel may be directly formed on a part of the surface of the metal bit line subsequently. In addition, in some embodiments, the material of the metal bit line is at least one of nickel, cobalt, or platinum, that is, the metal bit line can be formed later to form the first metal semiconductor layer to provide metal elements, and there is no need to add metal elements on the surface of the metal bit line. A first metal layer is formed.
参考图5至图6,形成半导体通道102,半导体通道102位于金属位线101的部分表面上,在沿基底100指向金属位线101的方向上,半导体通道102包括依次排列的第一掺杂区I、沟道区II以及第二掺杂区III,第一掺杂区I与金属位线101电连接。Referring to FIGS. 5 to 6 , a
本实施例中,半导体通道102与第一金属层118相接触;在其他实施例中,半导体通道可以与金属位线直接相接触。In this embodiment, the
具体地,形成半导体通道102的工艺步骤包括如下步骤:Specifically, the process steps of forming the
参考图5,形成初始通道层132,初始通道层132位于金属位线101上以及基底100上。Referring to FIG. 5 , an
在一些实施例中,相邻金属位线101之间具有隔离层103,则初始通道层132覆盖隔离层103表面。In some embodiments, there is an
本实施例中,金属位线101表面形成有第一金属层118,初始通道层132覆盖第一金属层118表面。在其他实施例中,初始通道层可以直接覆盖金属位线表面。In this embodiment, the
具体地,形成初始通道层132的方法包括化学气相沉积、物理气相沉积、原子层沉积或者金属有机化合物化学气相沉淀。其中,初始通道层132的材料为IGZO、IWO或者ITO。Specifically, the method of forming the
继续参考图5,在初始通道层132表面形成图形化的掩膜层109。Continuing to refer to FIG. 5 , a patterned
掩膜层109用于定义后续形成的半导体通道102的位置和尺寸。掩膜层109的材料可以为氮化硅、碳氮化硅或者碳氮氧化硅。在其他实施例中,掩膜层的材料也可以为光刻胶。The
参考图6,以掩膜层109为掩膜对初始通道层132(参考图5)进行图形化处理,形成半导体通道102。Referring to FIG. 6 , the initial channel layer 132 (refer to FIG. 5 ) is patterned by using the
半导体通道102包括依次排列的第一掺杂区I、沟道区II和第二掺杂区III。The
其中,半导体通道102中的第一掺杂区I、沟道区II和第二掺杂区III中掺杂同种类型的掺杂离子,则半导体通道102构成的器件为无结晶体管,避免了掺杂突变所产生的阈值电压漂移和漏电流增加等问题,还有利于抑制短沟道效应。Wherein, the first doping region I, the channel region II, and the second doping region III in the
可以理解的是,可以在进行图形化处理之前,预先对初始通道层132进行掺杂处理,掺杂处理可以掺杂N型离子或者P型离子;也可以在对初始通道层132进行图形化处理之后进行掺杂处理,以形成具有合适离子分布的半导体通道102。It can be understood that the
本实施例中,可以通过热氧化、蚀刻和/或氢退火处理对半导体通道102进行圆角处理(corner-rounding),以形成圆柱状结构的半导体通道102,在半导体结构工作时,有利于避免半导体通道102发生尖端放电或者漏电的现象。In this embodiment, the
参考图7,形成第一介质层115,第一介质层115位于第一金属层118远离基底100的表面,以及位于相邻第一金属层118的间隔中。Referring to FIG. 7 , a first
具体地,第一介质层115位于隔离层103表面以及第一掺杂区I(参考图6)侧壁表面,用于隔离第一金属层118与后续形成的字线。第一介质层115为整面膜层结构,用于防止为第一金属层118和金属位线101与后续形成的字线之间的电干扰。Specifically, the
形成第一介质层115的步骤包括:在金属位线101远离基底100的表面上形成初始第一介质层;对初始第一介质层进行平坦化处理和回刻蚀至预设厚度,形成第一介质层115。The step of forming the
后续的步骤包括:形成字线,字线环绕沟道区设置。形成字线的步骤包括如下步骤:The subsequent steps include: forming word lines, and the word lines are arranged around the channel region. The step of forming the word lines includes the following steps:
参考图8,在沟道区II(参考图6)以及第二掺杂区III(参考图6)的半导体通道102侧壁形成栅介质层114。Referring to FIG. 8 , a
栅介质层114露出半导体通道102正下方的以外的第一介质层115表面。栅介质层114用于在后续的退火处理过程中保护半导体通道102,防止后续半导体通道102的材料与金属材料发生反应。The
本实施例中,栅介质层114位于第二掺杂区III远离基底100的端面,后续形成第二介质层的步骤中,一并去除位于第二掺杂区III远离基底100的端面的栅介质层114,便于后续在第二掺杂区III远离基底100的端面上形成金属层。在其他实施例中,可以通过刻蚀工艺去除覆盖第二掺杂区的端面的栅介质层。In this embodiment, the
参考图9,在沟道区II(参考图6)对应的栅介质层114的侧壁表面形成初始栅导电层134,且初始栅导电层134环绕沟道区II,初始栅导电层134为整面膜层结构。Referring to FIG. 9 , an initial gate
具体地,形成初始栅导电层134的方法包括化学气相沉积、物理气相沉积、原子层沉积或者金属有机化合物化学气相沉淀。此外,通过对初始栅导电层134进行平坦化处理和蚀刻,使得初始栅导电层134位于沟道区II对应的栅介质层114的侧壁表面。Specifically, the method of forming the initial gate
参考图10,图形化初始栅导电层134(参考图9),形成相互间隔的栅导电层124,使得位于同一金属位线101上的不同半导体通道102的栅导电层124可以连接不同的电位,从而有利于实现对半导体通道的多元化控制。其中,图形化处理的方法包括光刻。Referring to FIG. 10 , the initial gate conductive layer 134 (refer to FIG. 9 ) is patterned to form the gate
对于每一栅介质层114而言,每一栅介质层114可环绕至少一个半导体通道102的沟道区II设置,图10中以每一栅介质层114环绕2个半导体通道102作为示例,可根据实际电学需求,合理设置每一栅介质层114环绕的半导体通道102的数量。For each
栅介质层114和栅导电层124共同组成字线104,因而字线104也是环绕2个半导体通道102设置。The
参考图11,形成第二介质层125,第二介质层125位于相邻栅导电层124的间隔中,用于防止相邻栅导电层124之间的电干扰,且第二介质层125还位于栅导电层124远离基底100的表面,用于支撑后续在第二介质层125远离基底100的表面上形成的其他导电结构,并实现栅导电层124与其他导电结构之间的绝缘。Referring to FIG. 11 , a
此外,在形成第二介质层125之后,对第二介质层125进行平坦化处理,并将位于掩膜层109远离基底100端面上的栅介质层114去除,使得第二介质层125露出位于第二掺杂区III远离基底100的端面上的掩膜层109。In addition, after the
本实施例中,第一介质层115和第二介质层125共同组成介质层105,介质层105位于金属位线101与字线104之间,且还位于字线104远离基底100的一侧。且第一介质层115和第二介质层125的材料相同,如此,有利于减少半导体结构的制作工艺所需要的材料种类,降低半导体结构的制造成本和复杂度。此外,介质层105还露出掩膜层109顶面。In this embodiment, the
参考图11至图12,去除掩膜层109,以暴露出第二掺杂区III(参考图6)顶面,在暴露出的第二掺杂区III顶面形成第二金属层。11 to 12 , the
第二金属层用于与半导体通道的第二掺杂区III发生反应,为后续形成第二金属半导体层提供金属元素,以降低半导体通道的电阻率。其中,第二金属层的材料包括钴、镍或者铂中的至少一种。The second metal layer is used for reacting with the second doped region III of the semiconductor channel to provide metal elements for the subsequent formation of the second metal-semiconductor layer, so as to reduce the resistivity of the semiconductor channel. Wherein, the material of the second metal layer includes at least one of cobalt, nickel or platinum.
制造方法还可以包括:进行第一退火处理,第一金属层118与第一掺杂区I发生反应,以将朝向金属位线101的部分厚度的第一掺杂区I转化为第一金属半导体层112,第一金属半导体层112的材料的电阻率小于第一金属半导体层112以外的第一掺杂区I的材料的电阻率。The manufacturing method may further include: performing a first annealing treatment, and the
其中,与第一掺杂区I发生反应的第一金属层118成为第一掺杂区I的一部分,未与第一掺杂区I发生反应的第一金属层118作为金属层108。可以理解的是,金属位线101与第一金属半导体层112之间还可以残留有部分厚度的第一金属层118,该残留的第一金属层118作为金属层108,即金属层108既可以位于第一金属半导体层112以外的金属位线101表面,还可以位于第一金属半导体层112与金属位线101之间。The
本实施例中,在进行第一退火处理的同时,进行第二退火处理,第二金属层与第二掺杂区III发生反应,以将露出的部分厚度的第二掺杂区III转化为第二金属半导体层122,且第二金属半导体层122的材料的电阻率小于第二金属半导体层122以外的第二掺杂区III的电阻率。In this embodiment, while the first annealing treatment is carried out, the second annealing treatment is carried out, and the second metal layer reacts with the second doping region III, so as to convert the exposed part of the thickness of the second doping region III into the second annealing treatment. Two metal-
具体地,采用快速热退火进行退火处理,快速热退火的工艺参数包括:在N2氛围下对半导体结构进行退火处理,退火温度为600℃~850℃,退火时长为10秒~60秒。由于退火温度适中,有利于使得第一金属层118与第一掺杂区I充分反应,使得第二金属层与第二掺杂区III充分反应,以形成电阻率相对较小的第一金属半导体层112和第二金属半导体层122。此外,由于退火温度适中,有利于避免第一金属层118和第二金属层中的金属元素扩散至沟道区II内。此外,在N2氛围下进行退火处理,有利于避免第一金属层118、第二金属层和半导体通道102被氧化。Specifically, rapid thermal annealing is used for the annealing treatment. The process parameters of the rapid thermal annealing include: annealing the semiconductor structure in an N 2 atmosphere, the annealing temperature is 600°C to 850°C, and the annealing time is 10 seconds to 60 seconds. Since the annealing temperature is moderate, it is favorable for the
本实施例中,第一退火处理和第二退火处理是同时进行的,有利于简化半导体结构的制造工艺工序。在其他实施例中,在第一金属层上形成半导体通道后,即可进行第一退火处理;在第二掺杂区上形成第二金属层后,再进行第二退火处理。In this embodiment, the first annealing treatment and the second annealing treatment are performed simultaneously, which is beneficial to simplify the manufacturing process of the semiconductor structure. In other embodiments, after the semiconductor channel is formed on the first metal layer, the first annealing treatment may be performed; after the second metal layer is formed on the second doped region, the second annealing treatment may be performed.
另外,在一些其他实施例中,在形成半导体通道之前,也可以在第一金属层表面形成第一半导体层,第一半导体层的材料为硅或者锗,且在第一退火处理过程中第一半导体层与第一金属层发生反应以形成第一金属半导体层;在形成第二金属层之前,在第二掺杂区顶面形成第二半导体层,第二半导体层的材料为硅或者锗,且在第二退火处理过程中第二半导体层与第二金属层发生反应以形成第二金属半导体层。In addition, in some other embodiments, before forming the semiconductor channel, a first semiconductor layer may also be formed on the surface of the first metal layer, the material of the first semiconductor layer is silicon or germanium, and during the first annealing process the first semiconductor layer is formed. The semiconductor layer reacts with the first metal layer to form a first metal semiconductor layer; before forming the second metal layer, a second semiconductor layer is formed on the top surface of the second doped region, and the material of the second semiconductor layer is silicon or germanium, And during the second annealing process, the second semiconductor layer reacts with the second metal layer to form the second metal semiconductor layer.
参考图1、图13至图16,形成电容结构106,电容结构106位于第二掺杂区III(参考图6)远离沟道区II(参考图6)的一侧,且电容结构106与第二掺杂区III相接触。1 , 13 to 16 , a
形成电容结构106的工艺步骤包括如下步骤:The process steps of forming the
参考图13,形成初始绝缘层137,初始绝缘层137覆盖字线104以及第二金属半导体层122。Referring to FIG. 13 , an initial
具体地,初始绝缘层137位于第二介质层125远离基底100的表面和第二金属半导体层122远离基底100的表面,且相较于第二介质层125的厚度,初始绝缘层137的厚度较大,便于后续形成电容结构。其中,初始绝缘层137的材料可以包括硼硅玻璃、硼磷硅玻璃、正硅酸乙酯或者氧化硅等低介电常数材料中的至少一种。Specifically, the initial insulating
参考图14,刻蚀初始绝缘层137(参考图13),形成暴露出第二掺杂区III的通孔10,剩余的初始绝缘层137作为绝缘层107。Referring to FIG. 14 , the initial insulating layer 137 (refer to FIG. 13 ) is etched to form the through
具体地,形成通孔10的步骤可以包括:在初始绝缘层137表面形成图形化的掩膜层;以图形化的掩膜层为掩模,采用干法刻蚀工艺刻蚀初始绝缘层137直至露出第二掺杂区III,以形成通孔10。Specifically, the step of forming the through
参考图15,形成下电极层116,下电极层116位于通孔10(参考图14)的底部和侧壁。Referring to FIG. 15, a
具体地,在形成下电极层116时,会有部分下电极层116形成于绝缘层107远离基底100的表面,通过平坦化处理或者刻蚀工艺去除位于绝缘层107远离基底100表面的下电极层116。Specifically, when the
参考图16,形成电容介质层126,电容介质层126覆盖下电极层116的表面以及绝缘层107靠近通孔10的部分表面,位于通孔10中的电容介质层126围成凹槽11。16 , a
具体地,形成电容介质层126的步骤包括:形成初始电容介质层,初始电容介质层覆盖下电极层116的表面和绝缘层107的表面,且位于通孔10中的初始电容介质层围成凹槽11;对初始电容介质层进行图形化,保留覆盖下电极层116的表面以及绝缘层107靠近通孔10的部分表面的初始电容介质层作为电容介质层126。Specifically, the step of forming the
在其他实施例中,形成初始电容介质层后,可以不对初始电容介质层进行刻蚀处理,后续直接在初始电容介质层的基础上形成上电极层。In other embodiments, after the initial capacitive dielectric layer is formed, the initial capacitive dielectric layer may not be etched, and subsequently the upper electrode layer is directly formed on the basis of the initial capacitive dielectric layer.
结合参考图16和图1,形成第一阻挡层117,第一阻挡层117位于未被电容介质层126覆盖的绝缘层107的表面,且第一阻挡层117顶面与电容介质层126顶面齐平,有利于给位于第一阻挡层117顶面和电容介质层126顶面的其他结构提供良好的支撑作用。16 and FIG. 1, a first barrier layer 117 is formed, the first barrier layer 117 is located on the surface of the insulating
形成上电极层136,上电极层136位于电容介质层126表面且填充满凹槽11(参考图16)。本实施例中,下电极层116、电容介质层126和上电极层136共同组成电容结构106。An
本实施例中,位于相邻通孔10中的下电极层116之间相互分立,位于相邻下电极层116表面的电容介质层126之间也相互间隔,且电容介质层126还位于绝缘层107靠近通孔10的部分表面,未被电容介质层126覆盖的绝缘层107的表面覆盖有第一阻挡层117。在其他实施例中,电容介质层也可以覆盖绝缘层的整个表面。In this embodiment, the
上电极层136还位于相邻电容介质层126之间的第一阻挡层117的表面,即填充满相邻通孔10的上电极层136之间相互接触连接,上电极层136为一体结构。在其他实施例中,位于相邻通孔中的上电极层之间可以具有间隔,使得相邻的电容结构中的上电极层可以连接不同的电位,有利于实现对相邻电容结构的多元化控制。The
进一步地,形成第二阻挡层127,第二阻挡层127位于上电极层136的表面和上电极层136未覆盖的第一阻挡层117的表面,用于防止上电极层136与外部导电结构之间的电干扰。其中第二阻挡层127的材料氧化硅、氮化硅、碳氮氧化硅或者氮氧化硅中的至少一种,本实施例中,第二阻挡层127的材料与第一阻挡层117的材料相同。在其他实施例中,第二阻挡层的材料与第一阻挡层的材料也可以不同。Further, a
需要说明的是,在其他实施例中,形成下电极层的工艺步骤中,也可以形成填充满通孔的下电极层,相应的,下电极层为柱状结构。It should be noted that, in other embodiments, in the process step of forming the lower electrode layer, a lower electrode layer filled with through holes may also be formed, and correspondingly, the lower electrode layer has a columnar structure.
综上所述,半导体通道102的沟道区II垂直设置在金属位线101上,一方面,无需额外的电连接结构即可实现半导体通道102与金属位线101和电容结构106之间的电连接,有利于降低半导体结构的复杂度;另一方面,有利于节省半导体通道102在平行于金属位线101表面方向上的布局空间,从而提高半导体结构在水平方向上的集成密度。此外,形成与第一掺杂区I相接触的第一金属层118和与第二掺杂区III相接触的第二金属层,通过第一退火处理和第二退火处理,使得部分第一掺杂区I转化未第一金属半导体层112,部分第二掺杂区III转化未第二金属半导体层122,降低第一掺杂区I和第二掺杂区III的电阻率,从而有利于降低电信号在半导体通道102与金属位线101和电容结构106之间传递所需的功耗。To sum up, the channel region II of the
本领域的普通技术人员可以理解,上述各实施方式是实现本发明的具体实施例,而在实际应用中,可以在形式上和细节上对其作各种改变,而不偏离本发明的精神和范围。任何本领域技术人员,在不脱离本发明的精神和范围内,均可作各自更动与修改,因此本发明的保护范围应当以权利要求限定的范围为准。Those skilled in the art can understand that the above-mentioned embodiments are specific examples for realizing the present invention, and in practical applications, various changes in form and details can be made without departing from the spirit and the spirit of the present invention. scope. Any person skilled in the art can make respective changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention should be based on the scope defined by the claims.
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WO2024108991A1 (en) * | 2022-11-23 | 2024-05-30 | 北京超弦存储器研究院 | Semiconductor device and manufacturing method therefor, and electronic device |
WO2024152700A1 (en) * | 2023-01-18 | 2024-07-25 | 长鑫存储技术有限公司 | Semiconductor structure and manufacturing method therefor |
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WO2024098545A1 (en) * | 2022-11-11 | 2024-05-16 | 长鑫存储技术有限公司 | Manufacturing method for and structure of semiconductor structure |
WO2024108991A1 (en) * | 2022-11-23 | 2024-05-30 | 北京超弦存储器研究院 | Semiconductor device and manufacturing method therefor, and electronic device |
WO2024152700A1 (en) * | 2023-01-18 | 2024-07-25 | 长鑫存储技术有限公司 | Semiconductor structure and manufacturing method therefor |
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