CN115216971A - Skin layer composition, foamed layer composition and low-odor PVC artificial leather - Google Patents
Skin layer composition, foamed layer composition and low-odor PVC artificial leather Download PDFInfo
- Publication number
- CN115216971A CN115216971A CN202110429383.4A CN202110429383A CN115216971A CN 115216971 A CN115216971 A CN 115216971A CN 202110429383 A CN202110429383 A CN 202110429383A CN 115216971 A CN115216971 A CN 115216971A
- Authority
- CN
- China
- Prior art keywords
- antioxidant
- weight
- parts
- layer composition
- pvc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 239000002649 leather substitute Substances 0.000 title claims abstract description 58
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 98
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 90
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 51
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims abstract description 47
- 239000004014 plasticizer Substances 0.000 claims abstract description 27
- 239000003381 stabilizer Substances 0.000 claims abstract description 26
- 238000005187 foaming Methods 0.000 claims abstract description 25
- 239000011347 resin Substances 0.000 claims abstract description 22
- 229920005989 resin Polymers 0.000 claims abstract description 22
- 239000004088 foaming agent Substances 0.000 claims abstract description 5
- 239000003292 glue Substances 0.000 claims description 33
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 30
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 claims description 28
- 239000006260 foam Substances 0.000 claims description 24
- -1 3, 5-di-tert-butyl-4-hydroxyphenyl Chemical group 0.000 claims description 13
- 239000002530 phenolic antioxidant Substances 0.000 claims description 13
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 claims description 12
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims description 7
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical group OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 128
- 239000004800 polyvinyl chloride Substances 0.000 description 102
- 229920000915 polyvinyl chloride Polymers 0.000 description 100
- 210000003491 skin Anatomy 0.000 description 51
- 238000009472 formulation Methods 0.000 description 24
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 15
- 239000000047 product Substances 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 238000002360 preparation method Methods 0.000 description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 230000006872 improvement Effects 0.000 description 7
- 229920002521 macromolecule Polymers 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 5
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical class CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 5
- 238000006731 degradation reaction Methods 0.000 description 5
- 239000004604 Blowing Agent Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 230000002452 interceptive effect Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 239000011265 semifinished product Substances 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 238000004049 embossing Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000002666 chemical blowing agent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 239000010985 leather Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004643 material aging Methods 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical class O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0095—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by inversion technique; by transfer processes
- D06N3/0097—Release surface, e.g. separation sheets; Silicone papers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/18—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with two layers of different macromolecular materials
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/045—Vinyl (co)polymers
- D06N2203/048—Polyvinylchloride (co)polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/26—Vehicles, transportation
- D06N2211/263—Cars
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a skin layer composition, which comprises PVC resin, a plasticizer, a stabilizer and an antioxidant, wherein the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant. The invention also relates to a foaming layer composition which comprises the PVC resin, a plasticizer, a stabilizer, an antioxidant and a foaming agent, wherein the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant. In addition, the present invention relates to a low-odor PVC artificial leather comprising a skin layer formed of the skin layer composition of the present invention and/or a foamed layer formed of the foamed layer composition of the present invention. The invention effectively improves the smell of the PVC artificial leather and reduces the smell grade.
Description
Technical Field
The present invention relates to a skin layer composition for forming low-odor polyvinyl chloride (PVC) artificial leather, a foaming layer composition, and low-odor PVC artificial leather including a skin layer formed of the skin layer composition and a foaming layer formed of the foaming layer composition, which can be used for, for example, automobile interior trims.
Background
In recent years, people have been pursuing healthy life more and more with the improvement of the overall living standard of society. In addition to concern about air quality in a home, air quality in an automobile is receiving increasing attention from consumers, and its odor is receiving great attention from host factories and consumers as polyvinyl chloride (PVC) artificial leather, which is a large percentage of interior trims of automobiles.
With the promulgation and implementation of GB 27630 air quality guideline in automobiles, the requirement of a host factory on the smell of automotive interior materials is getting stricter. However, the odor improvement of the PVC artificial leather is a problem that manufacturers of the artificial leather are always headache, almost the whole formula is replaced by raw materials with optimized odor, and the standard requirements of customers cannot be met. Even the subsequent baking can be carried out only with the cost, and the level desired by the customer can be barely achieved.
PVC artificial leather generally comprises a dense skin layer, in which PVC resin, plasticizer and stabilizer are generally contained, and/or a foamed layer, in which PVC resin, plasticizer, stabilizer and foaming agent are generally contained. The odor of PVC artificial leather comes from the raw materials themselves, such as plasticizers, stabilizers; another aspect is from the manufacturing process. During the processing of the PVC artificial leather, the raw materials in the PVC artificial leather are subjected to oxidative degradation under the action of heat and oxygen, and the PVC artificial leather also generates odor.
The present invention focuses on solving the problem of odor generated during processing.
Disclosure of Invention
Based on the above prior art, an object of the present invention is to provide a skin layer composition for forming a low-odor PVC artificial leather, a foamed layer composition, and a low-odor PVC artificial leather prepared from the skin layer composition and/or the foamed layer composition. The skin layer composition, the foaming layer composition and the PVC artificial leather obtained therefrom according to the present invention can realize a significantly improved PVC odor.
In order to achieve the technical purpose, the invention provides a skin layer composition for forming low-odor PVC artificial leather, which comprises PVC resin, a plasticizer, a stabilizer and an antioxidant, wherein the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant.
In order to achieve aging resistance in conventional PVC artificial leather, a stabilizer is generally added. The addition of the stabilizer is able to adequately resist material aging, which helps prevent heat aging degradation. However, satisfactory PVC odor-improving effect is not sufficiently achieved only by selection and addition of the stabilizer. The invention discovers that the specific antioxidant and the stabilizer are matched, so that the oxidation degradation reaction of the PVC artificial leather and oxygen is reduced in the production process, and the generation of odor caused by material degradation is avoided.
The antioxidant is beneficial to preventing oxygen aging degradation. Oxygen can participate in thermal and oxygen degradation, oxygen reacts with hydrogen in PVC macromolecules and part of macromolecules such as plasticizer macromolecules to generate hydrogen peroxide, the hydrogen peroxide is further decomposed into free radicals, and the free radicals react with the macromolecules and the macromolecules to degrade chains of the macromolecules and the macromolecules. In the present invention, as the antioxidant, a symmetrical hindered phenol antioxidant, or a phosphite antioxidant, or a combination of both is preferably used. The symmetrical hindered phenol is a tert-butyl group at two ortho-positions of the phenolic hydroxyl group. The symmetric hindered phenol antioxidant and the phosphite antioxidant can be used independently or in combination. When the hindered phenol and the hindered phenol are compounded for use, the hindered phenol is used as a main antioxidant, can capture polymer peroxide free radicals and does not participate in chain degradation reaction; the phosphite ester is used as an auxiliary antioxidant and can prevent hydrogen peroxide from generating free radicals, and the main antioxidant and the auxiliary antioxidant can act synergistically. In other words, hindered phenols generally have a superior antioxidant effect than phosphites.
Preferably, the symmetrical hindered phenolic antioxidant used in the skin layer composition of the present invention is pentaerythrityl tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] (also known as hindered phenolic antioxidant 1010 or hindered phenol 1010) or n-octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate (also known as hindered phenolic antioxidant 1076 or hindered phenol 1076). The two hindered phenol antioxidants can improve the odor of PVC artificial leather more remarkably than conventional other hindered phenols. More preferably, pentaerythritol tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] is used.
Preferably, the phosphite antioxidant used in the skin layer composition of the present invention is tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite (also known as phosphite antioxidant P-EPQ or phosphite P-EPQ). The present inventors have surprisingly found that the phosphite antioxidant alone provides better PVC odor improvement than some conventional hindered phenol primary antioxidants, such as diethylene glycol bis [ beta- (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate ], also known as hindered phenol antioxidant 245 or hindered phenol 245.
Preferably, the antioxidants used in the skin layer composition of the present invention are pentaerythrityl tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] (also known as hindered phenolic antioxidant 1010 or hindered phenolic 1010) and tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite (also known as phosphite antioxidant P-EPQ or phosphite P-EPQ). Wherein the hindered phenol 1010 and the phosphite P-EPQ are in particular 2:1 or more, preferably compounded and added together to the skin layer composition. When hindered phenol 1010 and phosphite P-EPQ are mixed in a ratio of 2:1 or more, the obtained compound antioxidant can realize a particularly excellent PVC odor improving effect. Therefore, the stability of the material in the processing process is ensured, and the long-term stability of the material in use is improved.
According to a preferred embodiment of the present invention, the skin layer composition comprises, based on 100 parts by weight of the sum of the contents of the PVC resin and the plasticizer:
40 to 60 parts by weight, for example, 40 parts by weight, 41 parts by weight, 42 parts by weight, 43 parts by weight, 44 parts by weight, 45 parts by weight, 46 parts by weight, 47 parts by weight, 48 parts by weight, 49 parts by weight, 50 parts by weight, 51 parts by weight, 52 parts by weight, 53 parts by weight, 54 parts by weight, 55 parts by weight, 56 parts by weight, 57 parts by weight, 58 parts by weight, 59 parts by weight, 60 parts by weight, or a range between any two of these values;
40 to 60 parts by weight, such as 40 parts by weight, 41 parts by weight, 42 parts by weight, 43 parts by weight, 44 parts by weight, 45 parts by weight, 46 parts by weight, 47 parts by weight, 48 parts by weight, 49 parts by weight, 50 parts by weight, 51 parts by weight, 52 parts by weight, 53 parts by weight, 54 parts by weight, 55 parts by weight, 56 parts by weight, 57 parts by weight, 58 parts by weight, 59 parts by weight, 60 parts by weight, or a plasticizer in a range between any two of these values;
1 to 5 parts by weight, such as 1 part by weight, 2 parts by weight, 3 parts by weight, 4 parts by weight, 5 parts by weight, or a stabilizer ranging between any two of these values;
0.1 to 0.3 parts by weight, such as 0.1 parts by weight, 0.15 parts by weight, 0.2 parts by weight, 0.25 parts by weight, 0.3 parts by weight, or a range between any two of these values.
In order to achieve the technical objects mentioned at the beginning, the present invention also provides a foaming layer composition for forming low odor PVC artificial leather, comprising PVC resin, plasticizer, stabilizer, antioxidant and foaming agent, wherein the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant.
Preferably, the symmetrical hindered phenolic antioxidant used in the foam layer composition of the present invention is pentaerythrityl tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate (also known as hindered phenolic antioxidant 1010 or hindered phenolic 1010) or n-octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate (also known as hindered phenolic antioxidant 1076 or hindered phenolic 1076). The two hindered phenol antioxidants can improve the odor of PVC artificial leather more remarkably than conventional other hindered phenols. More preferably, pentaerythritol tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] is used.
Preferably, the phosphite antioxidant used in the foam layer composition of the present invention is tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite (also known as phosphite antioxidant P-EPQ or phosphite P-EPQ). The present inventors have surprisingly found that the phosphite antioxidant alone provides better PVC odor improvement than some conventional hindered phenol primary antioxidants, such as diethylene glycol bis [ beta- (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate ], also known as hindered phenol antioxidant 245 or hindered phenol 245.
Preferably, the antioxidants used in the foam layer composition of the present invention are pentaerythrityl tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] (also known as hindered phenol antioxidant 1010 or hindered phenol 1010) and tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite (also known as phosphite antioxidant P-EPQ or phosphite P-EPQ). The hindered phenol 1010 and the phosphite P-EPQ are in particular 2:1 or more, preferably compounded and added together to the foam layer composition. When hindered phenol 1010 and phosphite P-EPQ are mixed in a ratio of 2:1 or more, the obtained compound antioxidant can realize a particularly excellent PVC odor improvement effect. Therefore, the stability of the material in the processing process is ensured, and the long-term stability of the material in use is improved.
According to a preferred embodiment of the present invention, the foamed layer composition comprises, based on 100 parts by weight of the sum of the contents of the PVC resin and the plasticizer:
40 to 60 parts by weight, for example, 40 parts by weight, 41 parts by weight, 42 parts by weight, 43 parts by weight, 44 parts by weight, 45 parts by weight, 46 parts by weight, 47 parts by weight, 48 parts by weight, 49 parts by weight, 50 parts by weight, 51 parts by weight, 52 parts by weight, 53 parts by weight, 54 parts by weight, 55 parts by weight, 56 parts by weight, 57 parts by weight, 58 parts by weight, 59 parts by weight, 60 parts by weight, or a range between any two of these values;
40 to 60 parts by weight, such as 40 parts by weight, 41 parts by weight, 42 parts by weight, 43 parts by weight, 44 parts by weight, 45 parts by weight, 46 parts by weight, 47 parts by weight, 48 parts by weight, 49 parts by weight, 50 parts by weight, 51 parts by weight, 52 parts by weight, 53 parts by weight, 54 parts by weight, 55 parts by weight, 56 parts by weight, 57 parts by weight, 58 parts by weight, 59 parts by weight, 60 parts by weight, or a plasticizer in a range between any two of these values;
1 to 5 parts by weight, such as 1 part by weight, 2 parts by weight, 3 parts by weight, 4 parts by weight, 5 parts by weight, or a stabilizer ranging between any two of these values;
0.1 to 0.3 parts by weight, e.g., 0.1 parts by weight, 0.15 parts by weight, 0.2 parts by weight, 0.25 parts by weight, 0.3 parts by weight, or a range between any two of these values;
1 to 3 parts by weight, such as 1 part by weight, 2 parts by weight, 3 parts by weight, or a range between any two of these values.
The PVC resin used in the present invention may be conventional PVC powder, pellets, etc. The plasticizer used in the present invention may be a conventional plasticizer, for example, an o-benzene type plasticizer. The stabilizer used in the present invention may be a conventional stabilizer, for example, a calcium zinc stabilizer. Perchlorate and calcium carbonate are preferably used as built stabilizers.
It should be noted that the PVC resin in the skin layer composition may be the same as or different from the PVC resin in the foam layer composition; the plasticizer in the skin layer composition and the plasticizer in the foaming layer composition can be the same or different; the stabilizer in the epidermal layer composition may be the same as or different from the stabilizer in the foam layer composition.
The blowing agent used in the foamed layer composition of the present invention may be various conventional physical blowing agents well known to those skilled in the art, such as low boiling liquids of alkanes; or chemical blowing agents such as azo-type blowing agents. Preferably, a physical blowing agent is used, which facilitates better control of the odor of the PVC layer.
Various suitable toners well known to those skilled in the art may be optionally added to the PVC skin and/or foam layers depending on the color requirements of the product. For example, in the skin layer composition, 1 to 5 parts by weight, for example, 1 part by weight, 2 parts by weight, 3 parts by weight, 4 parts by weight, 5 parts by weight, or a toner in a range between any two of these values may be additionally added, based on 100 parts by weight of the total content of the PVC resin and the plasticizer. In the foaming layer composition, 1 to 3 parts by weight, for example, 1 part by weight, 2 parts by weight, 3 parts by weight, or a toner in a range between any two of these values may be additionally added, based on 100 parts by weight of the sum of the contents of the PVC resin and the plasticizer.
In addition, other adjuvants may be included in the PVC skin and/or foam layers, and conventional materials known to those skilled in the art may be selected as desired. For example, it is also possible to add 3 to 5 parts by weight of a flame retardant to the PVC foam layer, based on 100 parts by weight of the sum of the contents of the PVC resin and the plasticizer.
Accordingly, the present invention also provides a low-odor PVC artificial leather comprising a skin layer formed of the skin layer composition according to the present invention and/or a foamed layer formed of the foamed layer composition according to the present invention.
The characteristics and technical effects of the composition for the skin layer and/or the composition for the foamed layer are also applicable to the low-odor PVC artificial leather, and are not described again here in order to avoid redundancy.
The foamed layer may be bonded to the base fabric, for example, by a glue layer. Preferably, the glue layer of the present invention comprises a PVC resin, a plasticizer, a stabilizer and an antioxidant, wherein the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant.
Here, the antioxidant in the glue layer can be the same as that in the skin layer and the foaming layer, and has the same characteristics and technical effects, and the description thereof is not repeated here in order to avoid redundancy.
Preferably, a paint layer, preferably an aqueous polyurethane system paint, is further provided above the skin layer and/or the foamed layer of the PVC artificial leather of the present invention, whereby gloss, hand feeling, and light, heat, dirt, abrasion, scratch and other functionalities of the surface of the obtained PVC artificial leather can be advantageously improved.
In order to prepare the low-odor PVC artificial leather according to the present invention, a method comprising the steps of:
(A) Preparing a PVC skin layer which contains PVC resin, a plasticizer, a stabilizer and an antioxidant,
and/or preparing a PVC foaming layer which contains PVC resin, a plasticizer, a stabilizer, an antioxidant and a foaming agent,
wherein the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant.
Optionally performing step (B) after step (a): compounding the surface layer or the foaming layer with the base cloth. Preferably, the PVC resin-based waterproof adhesive is compounded with base cloth through a glue layer, wherein the glue layer contains PVC resin, a plasticizer, a stabilizer and an antioxidant, and the antioxidant is preferably a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant.
Step (C) is preferably carried out after step (B): and printing a paint layer on the PVC skin layer and/or the foaming layer.
Wherein the slurry viscosity used to prepare the PVC skin layer is in the range of 3000 to 30000mpa.s; the viscosity of the slurry used to prepare the glue layer ranged from 4000 to 15000mpa.s. The grammage of the PVC skin layer is in the range of 200 to 400g/m 2 (ii) a The gram weight of the PVC foaming layer is 200 to 400g/m 2 (ii) a The grammage of the glue layer is in the range of 70 to 150g/m 2 。
The aforementioned characteristics and technical effects applicable to the low-odor PVC artificial leather according to the present invention are also applicable to the method for manufacturing the low-odor PVC artificial leather according to the present invention, and will not be described repeatedly herein in order to avoid redundancy.
The low-odor PVC artificial leather according to the invention can be applied in particular to automotive interiors, and of course can also be applied in other leather fields.
The invention has the advantages that: the odor grade of the PVC artificial leather is effectively reduced, the odor grade measured according to PV 3900C 3 reaches a grade of 4.0 or less, and even in a preferred embodiment, the odor grade reaches a grade of 3.5 or less, so that the requirements of users on the pleasure and health of products are met.
Detailed Description
In order to make those skilled in the art better understand the technical solution of the present invention, the following description will be made for clarity and completeness in combination with examples and comparative examples, and it is obvious that the described examples are a part of the examples of the present invention, but not all of the examples. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Example 1
The low-odor PVC artificial leather is prepared according to the following steps:
mixing materials: slurries of the PVC skin layer, the PVC foam layer and the glue layer were prepared according to the formulations of the PVC skin layer, foam layer and glue layer given in table 1, respectively, by conventional mixing with stirring.
Coating: and sending release paper, sequentially coating the release paper on a coating machine according to the sequence of the surface layer, the foaming layer and the glue, compounding the release paper with the base cloth, peeling the release paper from the formed laminated material, and rolling to obtain a coated semi-finished product.
Printing: and printing paint on the surface of the coated semi-finished product to obtain a printed semi-finished product.
Embossing: and embossing the surface of the printed semi-finished product to endow the surface with patterns to obtain a finished product.
Cutting: the finished product obtained after preparation can be cut and packaged according to the required size.
Table 1: example 1 formulation of skin, foam and glue layers
* Hindered phenol antioxidant 1010: tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid]Pentaerythritol esters, commercially available
Example 2
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 2.
Table 2: example 2 formulation of skin, foam and glue layers
* Hindered phenol antioxidantAgent 1076: n-octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, commercially available
Example 3
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 3.
Table 3: example 3 formulation of skin, foam and glue layers
* Phosphite antioxidant P-EPQ: tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite, commercially available
Comparative example 1
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 4. In comparison with example 1, no antioxidant was added in comparative example 1.
Table 4: formulation of skin layer, foam layer and glue layer in comparative example 1
Comparative example 2
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 5. In comparison with example 1, the hindered phenolic antioxidant used in comparative example 2 was an asymmetric hindered phenolic antioxidant 245.
Table 5: formulation of skin layer, foam layer and glue layer in comparative example 2
* Hindered phenol antioxidant 245: diethylene glycol bis [ beta- (3-tert-butyl-4-hydroxy-5-methylphenyl) propionate]Is commercially available
Comparative example 3
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 6.
Table 6: formulation of skin layer, foam layer and glue layer in comparative example 3
* Phosphite antioxidant 168: tris [2, 4-di-tert-butylphenyl ] -phenyl]Phosphites, commercially available
Comparative example 4
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 7.
Table 7: formulation of skin layer, foam layer and glue layer in comparative example 4
* Phosphite antioxidant 626: bis (2, 4-di-tert-butylphenyl) propanoic acid pentaerythritol diphosphite, commercially available
Example 4
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 8. In this example 4 the hindered phenolic antioxidant 1010 and the phosphite antioxidant P-EPQ were used in a ratio of 1:1, and a compound antioxidant mixed according to the proportion of the composition.
Table 8: example 4 formulation of skin, foam and glue layers
* Hindered phenol antioxidant 1010: tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid]Pentaerythritol esters, commercially available
* Phosphite antioxidant P-EPQ: tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite, commercially available
Example 5
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 9. In this example 4 the hindered phenolic antioxidant 1010 and the phosphite antioxidant P-EPQ were used in a ratio of 2:1, and a compound antioxidant mixed according to the proportion of the composition.
Table 9: example 5 formulation of skin-, foam-and glue-layers
* Hindered phenol antioxidant 1010: tetrakis [ beta- (3, 5-di-tert-butyl) etherButyl-4-hydroxyphenyl) propionic acid]Pentaerythritol esters, commercially available
* Phosphite antioxidant P-EPQ: tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite, commercially available
Example 6
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 10. In this example 4 the hindered phenol antioxidant 1010 and the phosphite antioxidant P-EPQ were used in a ratio of 3:1, and a compound antioxidant mixed according to the proportion of the composition.
Table 10: example 6 formulation of skin, foam and glue layers
* Hindered phenol antioxidant 1010: tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid]Pentaerythritol esters, commercially available
* Phosphite antioxidant P-EPQ: tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite, commercially available
Example 7
A PVC artificial leather product was prepared according to the preparation method of PVC artificial leather in example 1 according to the formulation of PVC skin layer, foaming layer and glue layer given in table 11. In this example 4, the hindered phenol antioxidant 1010 and the phosphite antioxidant P-EPQ were used in a ratio of 5:1, and mixing the components in the proportion of 1.
Table 11: example 7 formulation of skin-, foam-, and glue-layers
* Hindered phenol antioxidant 1010: tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid]Pentaerythritol esters, commercially available
* Phosphite antioxidant P-EPQ: tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite, commercially available
Example 8
PVC artificial leather products were prepared according to the preparation method of PVC artificial leather in example 1 according to the formulations of PVC skin layer, foamed layer and glue layer given in table 12. In this example 4 the hindered phenolic antioxidant 1010 and the phosphite antioxidant P-EPQ were used in a ratio of 1:3, and mixing the components in the proportion to obtain the compound antioxidant.
Table 12: example 8 formulation of skin, foam and glue layers
* Hindered phenol antioxidant 1010: tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionic acid]Pentaerythritol esters, commercially available
* Phosphite antioxidant P-EPQ: tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite, commercially available
Performance detection
The PVC artificial leathers prepared in examples 1 to 8 and comparative examples 1 to 4 were subjected to an odor test in accordance with International publication standard PV 3900C 3, and the test results are shown in Table 13. The odor characteristics of the material are classified according to standard regulations:
grade 1, no odor;
grade 2, odorous, but non-interfering odor;
grade 3, obvious smell, but no interfering smell;
grade 4, with interfering odor;
grade 5, strong interfering odor;
grade 6, intolerable odor.
TABLE 13 PVC odor ratings of examples 1-8 and comparative examples 1-4
As can be seen from Table 13, examples 1-3 of the present invention were able to achieve a low odor rating of 4.0 or less using a single antioxidant, with example 3 using the phosphite antioxidant P-EPQ as the antioxidant having an odor rating even lower than comparative example 2 using the hindered phenol antioxidant 245 as the antioxidant.
In the case of using hindered phenol 1010 and phosphite P-EPQ as antioxidants in combination, when the combination ratio of the hindered phenol 1010 and the phosphite P-EPQ is 2: 1. 3: 1. 5:1, the odor-improving effect is remarkably superior to that in the case of using the two antioxidants alone. When the compounding ratio of the hindered phenol 1010 and the phosphite P-EPQ is 3:1, with an optimal low odor rating of only grade 3.1.
It will be understood that the above embodiments are merely exemplary embodiments taken to illustrate the principles of the present invention, which is not limited thereto. It will be apparent to those skilled in the art that various modifications and improvements can be made without departing from the spirit and substance of the invention, and these modifications and improvements are also considered to be within the scope of the invention.
Claims (10)
1. A skin layer composition comprises PVC resin, a plasticizer, a stabilizer and an antioxidant, and is characterized in that the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant.
2. A skin layer composition according to claim 1, wherein the symmetrical hindered phenolic antioxidant is pentaerythritol tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] or n-octadecyl β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate.
3. A skin layer composition according to claim 1, characterized in that the phosphite antioxidant is tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite.
4. A skin layer composition according to claim 1, wherein the antioxidant is pentaerythrityl tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] and tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite, both in a ratio of 2:1 or more.
5. A foaming layer composition comprises PVC resin, a plasticizer, a stabilizer, an antioxidant and a foaming agent, and is characterized in that the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant.
6. The foam layer composition of claim 5, wherein the symmetrical hindered phenol antioxidant is pentaerythritol tetrakis [ beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] or n-octadecyl beta- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate.
7. The foam layer composition according to claim 5, wherein the phosphite antioxidant is tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite.
8. The foam layer composition according to claim 5, wherein the antioxidant is pentaerythrityl tetrakis [ β - (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ] and tetrakis (2, 4-di-tert-butylphenol) -4,4' -biphenyldiphosphite, both in a ratio of 2:1 or more.
9. A low-odor PVC artificial leather comprising a skin layer formed of the skin layer composition according to any one of claims 1 to 4 and/or a foamed layer formed of the foamed layer composition according to any one of claims 5 to 8.
10. The low-odor PVC artificial leather according to claim 9, wherein the low-odor PVC artificial leather comprises a glue layer, the glue layer comprises PVC resin, a plasticizer, a stabilizer and an antioxidant, wherein the antioxidant is a symmetrical hindered phenol antioxidant and/or a phosphite antioxidant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110429383.4A CN115216971A (en) | 2021-04-21 | 2021-04-21 | Skin layer composition, foamed layer composition and low-odor PVC artificial leather |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110429383.4A CN115216971A (en) | 2021-04-21 | 2021-04-21 | Skin layer composition, foamed layer composition and low-odor PVC artificial leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115216971A true CN115216971A (en) | 2022-10-21 |
Family
ID=83604544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110429383.4A Pending CN115216971A (en) | 2021-04-21 | 2021-04-21 | Skin layer composition, foamed layer composition and low-odor PVC artificial leather |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115216971A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107337872A (en) * | 2017-06-12 | 2017-11-10 | 上海延锋金桥汽车饰件系统有限公司 | A kind of automotive upholstery low smell PVC powder and preparation method thereof |
| CN108530792A (en) * | 2018-03-13 | 2018-09-14 | 苏州银禧科技有限公司 | Low VOC polyvinyl chloride composite materials of a kind of low smell and preparation method thereof |
| CN110511506A (en) * | 2019-08-14 | 2019-11-29 | 宁波一舟塑胶有限公司 | Low-volatility PVC modified material and preparation method thereof |
| CN111040338A (en) * | 2019-12-26 | 2020-04-21 | 金发科技股份有限公司 | Low-odor soft PVC material |
| CN111321608A (en) * | 2020-03-09 | 2020-06-23 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | Skin layer composition, foaming layer composition and environment-friendly PVC artificial leather formed by same |
-
2021
- 2021-04-21 CN CN202110429383.4A patent/CN115216971A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107337872A (en) * | 2017-06-12 | 2017-11-10 | 上海延锋金桥汽车饰件系统有限公司 | A kind of automotive upholstery low smell PVC powder and preparation method thereof |
| CN108530792A (en) * | 2018-03-13 | 2018-09-14 | 苏州银禧科技有限公司 | Low VOC polyvinyl chloride composite materials of a kind of low smell and preparation method thereof |
| CN110511506A (en) * | 2019-08-14 | 2019-11-29 | 宁波一舟塑胶有限公司 | Low-volatility PVC modified material and preparation method thereof |
| CN111040338A (en) * | 2019-12-26 | 2020-04-21 | 金发科技股份有限公司 | Low-odor soft PVC material |
| CN111321608A (en) * | 2020-03-09 | 2020-06-23 | 贝内克-长顺汽车内饰材料（张家港）有限公司 | Skin layer composition, foaming layer composition and environment-friendly PVC artificial leather formed by same |
Non-Patent Citations (1)
| Title |
|---|
| 吕百龄: "《实用工业助剂全书》", 化学工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Al-Malaika et al. | Additives for plastics | |
| KR101769178B1 (en) | Flame-retardant resin composition | |
| JP5729552B2 (en) | Vinyl chloride resin composition for powder molding, vinyl chloride resin molded body and laminate | |
| TWI579294B (en) | Mixtures of at least one dialkylphosphinic acid with at least one other, different dialkylphosphinic acid, process for preparation thereof and use thereof | |
| WO2016098344A1 (en) | Vinyl chloride resin composition, method for producing same, vinyl chloride resin molded article, method for producing same, and laminate | |
| TWI629281B (en) | Mixtures of diphosphinic acids and alkylphosphonic acids, a process for preparation thereof and use thereof | |
| TW201718460A (en) | Plasticizer for vinyl chloride resin, vinyl chloride resin composition, wire harness, and dashboard | |
| TW201335170A (en) | Mixtures of diphosphinic acids and dialkylphosphinic acids, a process for preparation thereof and use thereof | |
| TW201335169A (en) | Mixtures of diphosphinic acids and alkylphosphinic acids, a process for preparation thereof and use thereof | |
| WO2015087522A1 (en) | Vinyl chloride resin composition, vinyl chloride resin molded article, and laminate | |
| WO2017170221A1 (en) | Vinyl chloride resin composition, vinyl chloride resin molded body, and laminate | |
| KR101191983B1 (en) | Adhesive improving agent using foam, foaming composition having the same and manufacturing method of adhesive improving agent using foam | |
| JPWO2017018390A1 (en) | Sheet-like molded body and laminate | |
| JP6673335B2 (en) | Laminates for automotive interior materials | |
| WO2015141171A1 (en) | Vinyl chloride resin composition, vinyl chloride resin molded body, and laminate | |
| CN115216971A (en) | Skin layer composition, foamed layer composition and low-odor PVC artificial leather | |
| CN103589066A (en) | PP (propene polymer)/HDPE (high-density polyethylene) fire retardant alloy plastic | |
| JPWO2016067564A1 (en) | Real Stitch Skin Powder Formable Vinyl Chloride Resin Composition and Method for Producing the Same, Real Stitch Skin Vinyl Vinyl Resin Molded Body and Method for Producing the Same, and Laminate | |
| JP6708205B2 (en) | Vinyl chloride resin composition for powder molding, vinyl chloride resin molding, and laminate | |
| JP2830358B2 (en) | High antioxidant resin composition | |
| WO2016147637A1 (en) | Layered body for automobile interior material | |
| CN111321608B (en) | Skin layer composition, foaming layer composition and environment-friendly PVC (polyvinyl chloride) artificial leather formed by same | |
| CN105348481A (en) | Light weight PU plate special for passenger vehicle skylight sunshading boards | |
| WO2015141181A1 (en) | Vinyl chloride resin composition, vinyl-chloride-resin moulded body, and stacked body | |
| KR20100001283A (en) | Magnesium hydroxide-melamine complex particle and flame retardant compositions including the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Country or region after: China Address after: No. 108 Jianghai South Road, Jingang Town, Zhangjiagang City, Suzhou City, Jiangsu Province, 215632 Applicant after: Benecke Changshun automotive interior materials (Zhangjiagang) Co.,Ltd. Address before: 215632 No.1 Jianghai South Road, Jingang town, Zhangjiagang City, Jiangsu Province Applicant before: BENECKE-CHANGSHUN AUTO TRIM (ZHANGJIAGANG) Co.,Ltd. Country or region before: China |