CN115212591B - Jigsaw puzzle component - Google Patents
Jigsaw puzzle component Download PDFInfo
- Publication number
- CN115212591B CN115212591B CN202111133161.4A CN202111133161A CN115212591B CN 115212591 B CN115212591 B CN 115212591B CN 202111133161 A CN202111133161 A CN 202111133161A CN 115212591 B CN115212591 B CN 115212591B
- Authority
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- Prior art keywords
- fatty alcohol
- polyoxyethylene ether
- parts
- magnetic
- matrix
- Prior art date
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- 239000000696 magnetic material Substances 0.000 claims abstract description 33
- 239000011159 matrix material Substances 0.000 claims abstract description 20
- 239000002023 wood Substances 0.000 claims abstract description 14
- 239000011087 paperboard Substances 0.000 claims abstract description 9
- 239000003973 paint Substances 0.000 claims abstract description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 65
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 65
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 239000000945 filler Substances 0.000 claims description 26
- -1 methyl hydrogen Chemical class 0.000 claims description 26
- 229920002545 silicone oil Polymers 0.000 claims description 26
- 150000002191 fatty alcohols Chemical class 0.000 claims description 25
- 239000012763 reinforcing filler Substances 0.000 claims description 22
- 239000010445 mica Substances 0.000 claims description 19
- 229910052618 mica group Inorganic materials 0.000 claims description 19
- 239000012764 mineral filler Substances 0.000 claims description 19
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000002736 nonionic surfactant Substances 0.000 claims description 14
- 230000000149 penetrating effect Effects 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 14
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- 239000000377 silicon dioxide Substances 0.000 claims description 13
- 239000007822 coupling agent Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 claims description 12
- 235000012239 silicon dioxide Nutrition 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 239000011111 cardboard Substances 0.000 claims description 5
- 125000000373 fatty alcohol group Chemical group 0.000 claims description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims 1
- 239000004033 plastic Substances 0.000 abstract description 10
- 229920003023 plastic Polymers 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 6
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 239000010410 layer Substances 0.000 description 26
- 239000000463 material Substances 0.000 description 14
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical group [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 12
- 230000037303 wrinkles Effects 0.000 description 6
- 239000006087 Silane Coupling Agent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- XGDRLCRGKUCBQL-UHFFFAOYSA-N 1h-imidazole-4,5-dicarbonitrile Chemical compound N#CC=1N=CNC=1C#N XGDRLCRGKUCBQL-UHFFFAOYSA-N 0.000 description 4
- 230000035699 permeability Effects 0.000 description 4
- 230000001681 protective effect Effects 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 230000002209 hydrophobic effect Effects 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 102220538112 Modulator of macroautophagy TMEM150B_A63H_mutation Human genes 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000007259 addition reaction Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229920003020 cross-linked polyethylene Polymers 0.000 description 1
- 239000004703 cross-linked polyethylene Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63H—TOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
- A63H33/00—Other toys
- A63H33/04—Building blocks, strips, or similar building parts
- A63H33/046—Building blocks, strips, or similar building parts comprising magnetic interaction means, e.g. holding together by magnetic attraction
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F9/00—Games not otherwise provided for
- A63F9/06—Patience; Other games for self-amusement
- A63F9/10—Two-dimensional jig-saw puzzles
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F9/00—Games not otherwise provided for
- A63F9/06—Patience; Other games for self-amusement
- A63F9/10—Two-dimensional jig-saw puzzles
- A63F2009/1016—Two-dimensional jig-saw puzzles the pieces having additional connections, i.e. in addition to the connection by the jig-saw shapes
- A63F2009/1022—Two-dimensional jig-saw puzzles the pieces having additional connections, i.e. in addition to the connection by the jig-saw shapes to the display board
- A63F2009/1033—Two-dimensional jig-saw puzzles the pieces having additional connections, i.e. in addition to the connection by the jig-saw shapes to the display board magnetic
-
- A—HUMAN NECESSITIES
- A63—SPORTS; GAMES; AMUSEMENTS
- A63F—CARD, BOARD, OR ROULETTE GAMES; INDOOR GAMES USING SMALL MOVING PLAYING BODIES; VIDEO GAMES; GAMES NOT OTHERWISE PROVIDED FOR
- A63F9/00—Games not otherwise provided for
- A63F9/06—Patience; Other games for self-amusement
- A63F9/10—Two-dimensional jig-saw puzzles
- A63F2009/1072—Manufacturing
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Multimedia (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
The assembly comprises a matrix made of non-magnetic materials and a magnetic piece inlaid on the matrix and made of magnetic materials, wherein the matrix is made of wood board or paperboard, and at least one of a waterproof layer, a pattern layer, a decal layer and a paint layer is arranged on the matrix. According to the technical scheme, the inventor connects magnetic pieces formed by magnetic materials on a matrix formed by paperboards or wood boards, and connects different jigsaw puzzle components together through the magnetic attraction effect of the magnetic pieces to form the jigsaw puzzle. According to the technical scheme, the paperboard or the wood board is used for replacing plastics, so that a die is not required to be arranged during processing, manual processing and forming can be directly carried out, the production cost is reduced, and various large jigsaw puzzle components can be formed through processing.
Description
Technical Field
The invention belongs to the technical field of toys, in particular to the technical field of classification number A63H, and particularly relates to a jigsaw puzzle component.
Background
The materials of the existing jigsaw puzzle components are mostly plastic, and various auxiliary agents are added in the process of processing and forming the plastic to improve the performance of the plastic materials, but many auxiliary agents can threaten the health of children. The patent application number CN200920246051.7 discloses a jigsaw assembly and a jigsaw, wherein the jigsaw assembly is made of a substrate made of an electronic laser crosslinked polyethylene foaming material and a surface layer positioned on the upper surface of the substrate, and the assembly of the jigsaw assembly is not environment-friendly and difficult to mold and process.
What is needed is an environmentally friendly and easily formed puzzle assembly.
Disclosure of Invention
In order to solve the technical problem, a first aspect of the invention provides a jigsaw puzzle component, which comprises a matrix made of non-magnetic materials and a magnetic piece inlaid on the matrix and made of magnetic materials, wherein the matrix is made of wood board or paperboard, and at least one of a waterproof layer, a pattern layer, a decal layer and a paint layer is arranged on the matrix.
As a preferred technical solution, the cardboard is at least one selected from the group consisting of pit paper, corrugated paper, gray board, gray cardboard, white board and white cardboard.
As a preferred embodiment, the magnetic element made of magnetic material is connected to the base body made of non-magnetic material by at least one of bonding, clamping or pressing.
According to the technical scheme, the inventor connects magnetic pieces formed by magnetic materials on a matrix formed by paperboards or wood boards, and connects different jigsaw puzzle components together through the magnetic attraction effect of the magnetic pieces to form the jigsaw puzzle. When the plastic is used as a base material, as the plastic is molded by the mold, different jigsaw components need to be molded by different molds, and corresponding larger molds need to be provided when toys with larger splicing are spliced, so that the production and processing costs are high. In the technical scheme, the paperboard or the wood board is used for replacing plastics, so that a die is not required to be arranged during processing, manual processing and forming can be directly carried out, the production cost is reduced, and various large jigsaw puzzle components can be formed by processing.
As a preferable technical scheme, the waterproof layer is prepared from the following raw materials, by weight, at least 60-80 parts of methyl hydrogen-containing silicone oil, 30-50 parts of methyl hydroxyl silicone oil, 5-15 parts of penetrating agent, 3-10 parts of reinforcing filler, 0.5-2 parts of coupling agent and 2-6 parts of catalyst.
As a preferred technical scheme, the penetrating agent is a nonionic surfactant.
As a preferable technical scheme, the nonionic surfactant is fatty alcohol polyoxyethylene ether, the hydroxyl value of the fatty alcohol polyoxyethylene ether is 130-180mgKOH/g, and the HLB value is 6-11.
As a preferable technical scheme, the fatty alcohol-polyoxyethylene ether comprises fatty alcohol-polyoxyethylene ether A and fatty alcohol-polyoxyethylene ether B, wherein the weight ratio of the fatty alcohol-polyoxyethylene ether A to the fatty alcohol-polyoxyethylene ether B is (1-3): 1, the hydroxyl value of the fatty alcohol polyoxyethylene ether A is 130-140mgKOH/g, the HLB value is 10-11, the hydroxyl value of the fatty alcohol polyoxyethylene ether B is 170-180mgKOH/g, and the HLB value is 6-7.
As a preferred embodiment, the reinforcing filler has a particle size of 1800-2100 mesh.
As a preferred embodiment, the reinforcing filler is at least one selected from the group consisting of a metal filler, an oxide filler and a mineral filler.
As a preferable technical scheme, the reinforcing filler is a mixture of oxide filler and mineral filler, and the mass ratio of the oxide filler to the mineral filler is (3-5): 1.
as a preferred embodiment, the oxide filler is at least one of titanium dioxide, silicon dioxide, aluminum oxide and calcium oxide.
As a preferred embodiment, the oxide filler is silica.
As a preferred technical scheme, the mineral filler is mica powder.
As a preferable technical scheme, the catalyst is zinc nitrate.
In the technical scheme, the inventor uses methyl hydrogen-containing silicone oil and methyl hydroxyl silicone oil to carry out addition reaction under the action of a catalyst to generate a silicon resin hydrophobic film, and the silicon resin hydrophobic film is attached to the surface of a substrate to form a waterproof protective film. However, when the jigsaw puzzle assembly is used, the hands of a user can continuously rub the waterproof layer, and the silicone hydrophobic film has poor wear resistance and is easy to form protection defects. The inventors found that the abrasion resistance of the waterproof protective film can be improved by adding a certain amount of mica powder to the waterproof raw material, but the formed waterproof protective film is wrinkled due to the high toughness of the mica powder, and the aesthetic property and durability of the waterproof layer are affected. The inventors have unexpectedly found that the addition of a certain amount of silica can not only greatly improve the resistance of the waterproof layer but also reduce wrinkles generated in the waterproof protective film, and have thought that the hardness of silica can be a certain balance with the toughness of the mica powder. But the suspension property of the filler in the waterproof raw material is poor, so that the concentration difference of the filler is large at different positions of the seasoning. And the permeability between the waterproof layer and the matrix is poor, and the adhesiveness on the matrix is poor. The inventor finds that the addition of fatty alcohol-polyoxyethylene ether with certain different hydroxyl values can not only improve the permeability of the raw material of the waterproof layer on the matrix, but also improve the distribution uniformity of the filler in the waterproof raw material. The inventors considered that the possible reason is that the higher-hydroxyl-value fatty alcohol-polyoxyethylene ether has a smaller molecular weight, and can improve the permeability of the waterproof layer, thereby improving the adhesive force of the waterproof layer, but the lower-molecular-weight fatty alcohol-polyoxyethylene ether has a smaller improvement on the dispersibility of the filler, whereas the lower-hydroxyl-value fatty alcohol-polyoxyethylene ether has a larger molecular weight, and although the effect of improving the permeability of the waterproof layer is limited, the higher-molecular-weight fatty alcohol-polyoxyethylene ether can improve the viscosity of the waterproof raw material, thereby improving the dispersion uniformity of the filler.
The beneficial effects are that: according to the technical scheme, the inventor connects magnetic pieces formed by magnetic materials on a matrix formed by paperboards or wood boards, and connects different jigsaw puzzle components together through the magnetic attraction effect of the magnetic pieces to form the jigsaw puzzle. When the plastic is used as a base material, as the plastic is molded by the mold, different jigsaw components need to be molded by different molds, and corresponding larger molds need to be provided when toys with larger splicing are spliced, so that the production and processing costs are high. In the technical scheme, the paperboard or the wood board is used for replacing plastics, so that a die is not required to be arranged during processing, manual processing and forming can be directly carried out, the production cost is reduced, and various large jigsaw puzzle components can be formed by processing.
Drawings
Fig. 1 is a photograph of a puzzle assembly of embodiment 1.
Wherein, the magnetic component is 1-matrix and 2-magnetic component.
Detailed Description
Example 1
To solve the above technical problem, as shown in fig. 1, a first aspect of this embodiment provides a jigsaw puzzle assembly, where the assembly includes a base body 1 made of a non-magnetic material and a magnetic member 2 made of a magnetic material embedded on the base body, the base body is a wood board, a waterproof layer is disposed on the base body, and the magnetic member 2 made of a magnetic material is connected with the base body made of a non-magnetic material by bonding. The waterproof layer is prepared from the following raw materials in parts by weight, including 60 parts of methyl hydrogen-containing silicone oil, 30 parts of methyl hydroxyl silicone oil, 5 parts of penetrating agent, 3 parts of reinforcing filler, 0.5 part of coupling agent and 2 parts of catalyst. The coupling agent is silane coupling agent KH-560. The methyl hydrogen silicone oil is purchased from Jinan fresh materials limited company, with the product number: 201, the methyl hydroxy silicone oil is purchased from Jinan Ming Xinda chemical technology Co. The penetrating agent is a nonionic surfactant, the nonionic surfactant is fatty alcohol-polyoxyethylene ether, the fatty alcohol-polyoxyethylene ether comprises fatty alcohol-polyoxyethylene ether A and fatty alcohol-polyoxyethylene ether B, and the weight ratio of the fatty alcohol-polyoxyethylene ether A to the fatty alcohol-polyoxyethylene ether B is 2:1, the hydroxyl value of the fatty alcohol polyoxyethylene ether A is 130-140mgKOH/g, the HLB value is 10-11, the hydroxyl value of the fatty alcohol polyoxyethylene ether B is 170-180mgKOH/g, and the HLB value is 6-7. The fatty alcohol polyoxyethylene ether A is purchased from Jiangsu province sea-ampere petrochemical factory, and the product number is: MOA-7, the fatty alcohol polyoxyethylene ether B is purchased from Jiangsu province sea-An petrochemical plant, and the product number is: MOA-3. The particle size of the reinforcing filler is 2000 meshes, the reinforcing filler is a mixture of an oxide filler and a mineral filler, and the mass ratio of the oxide filler to the mineral filler is 4:1. the oxide filler is silicon dioxide, and the mineral filler is mica powder. The silicon dioxide is purchased from the new materials limited company of Changtai in the god of longevity, and the mica powder is purchased from the Huayuan mica limited company of the Ministry of the Shaoshi. The catalyst is zinc nitrate.
Example 2
To solve the above-mentioned technical problem, a first aspect of this embodiment provides a jigsaw puzzle assembly, where the assembly includes a base body made of a non-magnetic material and a magnetic member made of a magnetic material embedded on the base body, the base body is a wood board, a waterproof layer is disposed on the base body, and the magnetic member made of a magnetic material is connected with the base body made of a non-magnetic material through bonding. The waterproof layer is prepared from the following raw materials in parts by weight, namely 70 parts of methyl hydrogen-containing silicone oil, 40 parts of methyl hydroxyl silicone oil, 10 parts of penetrating agent, 7 parts of reinforcing filler, 1.2 parts of coupling agent and 4 parts of catalyst. The coupling agent is silane coupling agent KH-560. The methyl hydrogen silicone oil is purchased from Jinan fresh materials limited company, with the product number: 201, the methyl hydroxy silicone oil is purchased from Jinan Ming Xinda chemical technology Co. The penetrating agent is a nonionic surfactant, the nonionic surfactant is fatty alcohol-polyoxyethylene ether, the fatty alcohol-polyoxyethylene ether comprises fatty alcohol-polyoxyethylene ether A and fatty alcohol-polyoxyethylene ether B, and the weight ratio of the fatty alcohol-polyoxyethylene ether A to the fatty alcohol-polyoxyethylene ether B is 2:1, the hydroxyl value of the fatty alcohol polyoxyethylene ether A is 130-140mgKOH/g, the HLB value is 10-11, the hydroxyl value of the fatty alcohol polyoxyethylene ether B is 170-180mgKOH/g, and the HLB value is 6-7. The fatty alcohol polyoxyethylene ether A is purchased from Jiangsu province sea-ampere petrochemical factory, and the product number is: MOA-7, the fatty alcohol polyoxyethylene ether B is purchased from Jiangsu province sea-An petrochemical plant, and the product number is: MOA-3. The particle size of the reinforcing filler is 2000 meshes, the reinforcing filler is a mixture of an oxide filler and a mineral filler, and the mass ratio of the oxide filler to the mineral filler is 4:1. the oxide filler is silicon dioxide, and the mineral filler is mica powder. The silicon dioxide is purchased from the new materials limited company of Changtai in the god of longevity, and the mica powder is purchased from the Huayuan mica limited company of the Ministry of the Shaoshi. The catalyst is zinc nitrate.
Example 3
To solve the above-mentioned technical problem, a first aspect of this embodiment provides a jigsaw puzzle assembly, where the assembly includes a base body made of a non-magnetic material and a magnetic member made of a magnetic material embedded on the base body, the base body is a wood board, a waterproof layer is disposed on the base body, and the magnetic member made of a magnetic material is connected with the base body made of a non-magnetic material through bonding. The waterproof layer is prepared from the following raw materials in parts by weight, namely 80 parts of methyl hydrogen-containing silicone oil, 50 parts of methyl hydroxyl silicone oil, 15 parts of penetrating agent, 10 parts of reinforcing filler, 2 parts of coupling agent and 6 parts of catalyst. The coupling agent is silane coupling agent KH-560. The methyl hydrogen silicone oil is purchased from Jinan fresh materials limited company, with the product number: 201, the methyl hydroxy silicone oil is purchased from Jinan Ming Xinda chemical technology Co. The penetrating agent is a nonionic surfactant, the nonionic surfactant is fatty alcohol-polyoxyethylene ether, the fatty alcohol-polyoxyethylene ether comprises fatty alcohol-polyoxyethylene ether A and fatty alcohol-polyoxyethylene ether B, and the weight ratio of the fatty alcohol-polyoxyethylene ether A to the fatty alcohol-polyoxyethylene ether B is 2:1, the hydroxyl value of the fatty alcohol polyoxyethylene ether A is 130-140mgKOH/g, the HLB value is 10-11, the hydroxyl value of the fatty alcohol polyoxyethylene ether B is 170-180mgKOH/g, and the HLB value is 6-7. The fatty alcohol polyoxyethylene ether A is purchased from Jiangsu province sea-ampere petrochemical factory, and the product number is: MOA-7, the fatty alcohol polyoxyethylene ether B is purchased from Jiangsu province sea-An petrochemical plant, and the product number is: MOA-3. The particle size of the reinforcing filler is 2000 meshes, the reinforcing filler is a mixture of an oxide filler and a mineral filler, and the mass ratio of the oxide filler to the mineral filler is 4:1. the oxide filler is silicon dioxide, and the mineral filler is mica powder. The silicon dioxide is purchased from the new materials limited company of Changtai in the god of longevity, and the mica powder is purchased from the Huayuan mica limited company of the Ministry of the Shaoshi. The catalyst is zinc nitrate.
Example 4
To solve the above-mentioned technical problem, a first aspect of this embodiment provides a jigsaw puzzle assembly, where the assembly includes a base body made of a non-magnetic material and a magnetic member made of a magnetic material embedded on the base body, the base body is a wood board, a waterproof layer is disposed on the base body, and the magnetic member made of a magnetic material is connected with the base body made of a non-magnetic material through bonding. The waterproof layer is prepared from the following raw materials in parts by weight, namely 80 parts of methyl hydrogen-containing silicone oil, 50 parts of methyl hydroxyl silicone oil, 15 parts of penetrating agent, 10 parts of reinforcing filler, 2 parts of coupling agent and 6 parts of catalyst. The coupling agent is silane coupling agent KH-560. The methyl hydrogen silicone oil is purchased from Jinan fresh materials limited company, with the product number: 201, the methyl hydroxy silicone oil is purchased from Jinan Ming Xinda chemical technology Co. The penetrating agent is a nonionic surfactant, the nonionic surfactant is fatty alcohol-polyoxyethylene ether, the hydroxyl value of the fatty alcohol-polyoxyethylene ether is 170-180mgKOH/g, and the HLB value is 6-7. The fatty alcohol polyoxyethylene ether is purchased from Jiangsu province sea-ampere petrochemical factory, and the product number is: MOA-3. The particle size of the reinforcing filler is 2000 meshes, the reinforcing filler is a mixture of an oxide filler and a mineral filler, and the mass ratio of the oxide filler to the mineral filler is 4:1. the oxide filler is silicon dioxide, and the mineral filler is mica powder. The silicon dioxide is purchased from the new materials limited company of Changtai in the god of longevity, and the mica powder is purchased from the Huayuan mica limited company of the Ministry of the Shaoshi. The catalyst is zinc nitrate.
Example 5
To solve the above-mentioned technical problem, a first aspect of this embodiment provides a jigsaw puzzle assembly, where the assembly includes a base body made of a non-magnetic material and a magnetic member made of a magnetic material embedded on the base body, the base body is a wood board, a waterproof layer is disposed on the base body, and the magnetic member made of a magnetic material is connected with the base body made of a non-magnetic material through bonding. The waterproof layer is prepared from the following raw materials in parts by weight, namely 80 parts of methyl hydrogen-containing silicone oil, 50 parts of methyl hydroxyl silicone oil, 15 parts of penetrating agent, 10 parts of reinforcing filler, 2 parts of coupling agent and 6 parts of catalyst. The coupling agent is silane coupling agent KH-560. The methyl hydrogen silicone oil is purchased from Jinan fresh materials limited company, with the product number: 201, the methyl hydroxy silicone oil is purchased from Jinan Ming Xinda chemical technology Co. The penetrating agent is a nonionic surfactant, the nonionic surfactant is fatty alcohol-polyoxyethylene ether, the fatty alcohol-polyoxyethylene ether comprises fatty alcohol-polyoxyethylene ether A and fatty alcohol-polyoxyethylene ether B, and the weight ratio of the fatty alcohol-polyoxyethylene ether A to the fatty alcohol-polyoxyethylene ether B is 2:1, the hydroxyl value of the fatty alcohol polyoxyethylene ether A is 130-140mgKOH/g, the HLB value is 10-11, the hydroxyl value of the fatty alcohol polyoxyethylene ether B is 170-180mgKOH/g, and the HLB value is 6-7. The fatty alcohol polyoxyethylene ether A is purchased from Jiangsu province sea-ampere petrochemical factory, and the product number is: MOA-7, the fatty alcohol polyoxyethylene ether B is purchased from Jiangsu province sea-An petrochemical plant, and the product number is: MOA-3. The particle size of the reinforcing filler is 2000 meshes, and the reinforcing filler mica powder is purchased from Huayuan mica limited company in the Ministry of the Shangshou. The catalyst is zinc nitrate.
Performance testing
Performance test 1
The toy components in examples 1-5 were coated with a waterproof layer, a 5cm x 5cm area was defined on the substrate, 1ml of water was added dropwise, and after 1h of standing, whether the waterproof layer in the drip area dropped or not was observed, or if there was no obvious change, the waterproof effect was recorded as acceptable, and if there was a drop or water immersion, the waterproof effect was recorded as unacceptable.
Performance test II
The toy modules of examples 1 to 5 were observed for wrinkles in the matrix coated with the waterproof layer, and the toy modules were recorded as unsatisfactory in wrinkle resistance when there were significant wrinkles, and as satisfactory in wrinkle resistance when there were no significant wrinkles.
Claims (3)
1. The jigsaw puzzle component is characterized by comprising a matrix made of non-magnetic materials and a magnetic piece inlaid on the matrix and made of magnetic materials, wherein the matrix is made of wood board or paperboard, and a waterproof layer, a pattern layer, an applique layer and a paint layer are arranged on the matrix; the waterproof layer is prepared from the raw materials of 60-80 parts by weight of methyl hydrogen silicone oil, 30-50 parts by weight of methyl hydroxyl silicone oil, 5-15 parts by weight of penetrating agent, 3-10 parts by weight of reinforcing filler, 0.5-2 parts by weight of coupling agent and 2-6 parts by weight of catalyst; the penetrating agent is a nonionic surfactant; the nonionic surfactant is fatty alcohol polyoxyethylene ether, the fatty alcohol polyoxyethylene ether comprises fatty alcohol polyoxyethylene ether A and fatty alcohol polyoxyethylene ether B, and the weight ratio of the fatty alcohol polyoxyethylene ether A to the fatty alcohol polyoxyethylene ether B is (1-3): 1, the hydroxyl value of the fatty alcohol-polyoxyethylene ether A is 130-140mgKOH/g, the HLB value is 10-11, the hydroxyl value of the fatty alcohol-polyoxyethylene ether B is 170-180mgKOH/g, the particle size of the reinforcing filler is 1800-2100 meshes, the reinforcing filler is a mixture of oxide filler and mineral filler, and the mass ratio of the oxide filler to the mineral filler is (3-5): 1, a step of; the oxide filler is silicon dioxide, and the mineral filler is mica powder.
2. The puzzle assembly of claim 1 wherein the cardboard is selected from at least one of a group consisting of board, corrugated board, gray cardboard, white board, and white board.
3. The puzzle assembly of claim 1 wherein the magnetic pieces of magnetic material are attached to the base of non-magnetic material by at least one of bonding, clamping or stamping.
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| CN115212591B true CN115212591B (en) | 2023-09-29 |
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| CN108587335A (en) * | 2018-03-23 | 2018-09-28 | 常德市万福达环保节能建材有限公司 | A kind of waterproof and anticorrosion insulating moulding coating and preparation method thereof |
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| JP5519774B2 (en) * | 2010-03-23 | 2014-06-11 | 株式会社朝日ラバー | Silicone resin reflective substrate, method for producing the same, and raw material composition used for the reflective substrate |
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|---|---|---|---|---|
| CN2056359U (en) * | 1989-01-17 | 1990-04-25 | 上海凯香塑料制品厂 | Magnetic intelligent building block |
| JP2007313191A (en) * | 2006-05-29 | 2007-12-06 | Pilot Ink Co Ltd | Puzzle toy and puzzle toy set using the same |
| CN201500439U (en) * | 2009-09-27 | 2010-06-09 | 上海贝博氏儿童用品有限公司 | Jigsaw puzzle component and jigsaw puzzle |
| JP3186637U (en) * | 2013-08-06 | 2013-10-17 | 山文株式会社 | Magnetic drawing toys |
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