CN115197789A - Novel reactive polyurethane hot melt adhesive cleaning agent - Google Patents
Novel reactive polyurethane hot melt adhesive cleaning agent Download PDFInfo
- Publication number
- CN115197789A CN115197789A CN202210957469.9A CN202210957469A CN115197789A CN 115197789 A CN115197789 A CN 115197789A CN 202210957469 A CN202210957469 A CN 202210957469A CN 115197789 A CN115197789 A CN 115197789A
- Authority
- CN
- China
- Prior art keywords
- hot melt
- melt adhesive
- cleaning agent
- reactive polyurethane
- polyurethane hot
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004814 polyurethane Substances 0.000 title claims abstract description 82
- 229920002635 polyurethane Polymers 0.000 title claims abstract description 81
- 239000004831 Hot glue Substances 0.000 title claims abstract description 63
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 52
- 229920005989 resin Polymers 0.000 claims abstract description 21
- 239000011347 resin Substances 0.000 claims abstract description 21
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 17
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 17
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 17
- 235000007586 terpenes Nutrition 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 11
- 229920000570 polyether Polymers 0.000 claims abstract description 11
- 239000004094 surface-active agent Substances 0.000 claims abstract description 11
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 10
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 10
- -1 terpene compound Chemical class 0.000 claims abstract description 10
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims abstract description 8
- 239000003495 polar organic solvent Substances 0.000 claims abstract description 8
- 239000004014 plasticizer Substances 0.000 claims abstract description 7
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229940073769 methyl oleate Drugs 0.000 claims abstract description 5
- 229920001971 elastomer Polymers 0.000 claims description 12
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims description 6
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 claims description 6
- 150000003505 terpenes Chemical class 0.000 claims description 5
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000025 natural resin Substances 0.000 claims description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 4
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 4
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 4
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 claims description 3
- FAMJUFMHYAFYNU-UHFFFAOYSA-N 1-methyl-4-(propan-2-yl)cyclohex-1-ene Chemical compound CC(C)C1CCC(C)=CC1 FAMJUFMHYAFYNU-UHFFFAOYSA-N 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 3
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 3
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 3
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- FAMJUFMHYAFYNU-JTQLQIEISA-N (4r)-1-methyl-4-propan-2-ylcyclohexene Chemical compound CC(C)[C@@H]1CCC(C)=CC1 FAMJUFMHYAFYNU-JTQLQIEISA-N 0.000 claims description 2
- WDQFELCEOPFLCZ-UHFFFAOYSA-N 1-(2-hydroxyethyl)pyrrolidin-2-one Chemical compound OCCN1CCCC1=O WDQFELCEOPFLCZ-UHFFFAOYSA-N 0.000 claims description 2
- LVUQCTGSDJLWCE-UHFFFAOYSA-N 1-benzylpyrrolidin-2-one Chemical compound O=C1CCCN1CC1=CC=CC=C1 LVUQCTGSDJLWCE-UHFFFAOYSA-N 0.000 claims description 2
- JMVIVASFFKKFQK-UHFFFAOYSA-N 1-phenylpyrrolidin-2-one Chemical compound O=C1CCCN1C1=CC=CC=C1 JMVIVASFFKKFQK-UHFFFAOYSA-N 0.000 claims description 2
- DCALJVULAGICIX-UHFFFAOYSA-N 1-propylpyrrolidin-2-one Chemical compound CCCN1CCCC1=O DCALJVULAGICIX-UHFFFAOYSA-N 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 claims description 2
- WPPOGHDFAVQKLN-UHFFFAOYSA-N N-Octyl-2-pyrrolidone Chemical compound CCCCCCCCN1CCCC1=O WPPOGHDFAVQKLN-UHFFFAOYSA-N 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000806 elastomer Substances 0.000 claims description 2
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 2
- 229920006226 ethylene-acrylic acid Polymers 0.000 claims description 2
- 235000001510 limonene Nutrition 0.000 claims description 2
- 229940087305 limonene Drugs 0.000 claims description 2
- PZYDAVFRVJXFHS-UHFFFAOYSA-N n-cyclohexyl-2-pyrrolidone Chemical compound O=C1CCCN1C1CCCCC1 PZYDAVFRVJXFHS-UHFFFAOYSA-N 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 abstract description 22
- 239000000853 adhesive Substances 0.000 abstract description 12
- 230000001070 adhesive effect Effects 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 11
- 230000008569 process Effects 0.000 abstract description 11
- 238000004132 cross linking Methods 0.000 abstract description 5
- 239000002244 precipitate Substances 0.000 abstract description 5
- 238000005336 cracking Methods 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000004026 adhesive bonding Methods 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000003292 glue Substances 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical group CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 238000007790 scraping Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000012668 chain scission Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/188—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/362—Phosphates or phosphites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3726—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a novel reactive polyurethane hot melt adhesive cleaning agent, and particularly relates to the field of cleaning agents. The cleaning agent comprises 10-30% of ethylene-vinyl acetate copolymer, 1-10% of tackifying resin, 20-70% of long-chain fatty alcohol, 5-20% of polar organic solvent, 2-10% of polyether surfactant, 1-5% of methyl oleate, 1-5% of terpene compound, 1-5% of plasticizer and 0.1-1% of antioxidant. The reactive polyurethane hot melt adhesive cleaning agent can thoroughly neutralize residual NCO ends in the PUR hot melt adhesive, and polyurethane condensate is prevented from being generated in the cleaning process; the infusible precipitate generated by curing and crosslinking of the reactive polyurethane hot melt adhesive can be deeply decomposed and converted into a low molecular weight cracking mixture which can be dissolved in a cleaning adhesive system, so that the aim of completely removing the cured polyurethane is fulfilled; the reactive polyurethane hot melt adhesive cleaning agent disclosed by the invention is high in quality and low in production cost, and can well meet the increasing equipment cleaning requirements of domestic reactive polyurethane hot melt adhesive users.
Description
Technical Field
The invention relates to the field of cleaning agents, and particularly relates to a cleaning agent capable of sufficiently removing residual hot melt adhesive of a gluing device and polyurethane condensate which is difficult to remove in the application process of reactive Polyurethane (PUR) hot melt adhesive.
Background
Reactive polyurethane hot melts are a class of adhesives that are solvent-free and that exhibit a solid form at room temperature. The adhesive strength of the reactive polyurethane hot melt adhesive is different from that of the common hot melt adhesive, the reactive polyurethane hot melt adhesive contains isocyanate-terminated (NCO) polyurethane prepolymer, and the isocyanate-terminated (NCO) polyurethane prepolymer can react with moisture or active hydrogen substances in the air or on an adherend to form a partially crosslinked reticular structure, so that the adhesive strength, chemical resistance, heat resistance, hydrolysis resistance and other properties of the reactive polyurethane hot melt adhesive are superior to those of the common hot melt adhesive. Meanwhile, the polyurethane adhesive has the thermoplastic cold setting property of common hot melt adhesive, is simple and convenient to bond, and has the characteristics of wide range of adherends, large performance adjustability, good surface compatibility on paint surfaces and the like, and the like. The PUR hot melt adhesive has the characteristics of 100% solid content, no solvent, environmental protection and the like, and enters various new application fields along with the continuous development of the technology, so that the share of the PUR hot melt adhesive in the adhesive industry is increased, meanwhile, the sizing equipment of the PUR hot melt adhesive is gradually developed towards the diversification direction, and the thorough cleaning of the sizing equipment becomes a more prominent problem.
Generally, the known reactive polyurethane hot melt adhesive cleaning agent is mainly formed by mixing ethylene-vinyl acetate copolymer (EVA) with other resins, and the system is not well compatible with common PUR hot melt adhesives, but removes residual adhesives by mixing, diluting and transferring with the PUR hot melt adhesives. However, since the PUR hot melt adhesive has functional reactive group NCO, once the reactive group NCO is cross-linked and cured due to misoperation, improper control of environmental humidity, untimely cleaning after glue application, and the like during the use of the hot melt adhesive, infusible precipitates which are difficult to remove are generated at various positions of pipelines, rollers and the like of a glue application device, so that the glue application points of the pipelines, the rollers and the like are blocked. The common reactive polyurethane hot melt adhesive cleaning agent can not effectively clean the polyurethane condensate, and customers have to clean the polyurethane condensate in a mode of scraping, sanding, even burning at high temperature and the like which are complicated in operation and can damage the service life of equipment.
The prior Chinese patent CN102719325A discloses a novel reactive polyurethane hot melt adhesive cleaning agent; the product of the patent can thoroughly neutralize the residual NCO in the PUR hot melt adhesive, inhibit the further reaction of the functional reaction group NCO in the reactive PUR adhesive, and ensure that no polyurethane condensate can appear in the cleaning process. However, for the existing polyurethane condensate, the product of the patent does not have the treatment capacity as the common reactive polyurethane hot melt adhesive cleaning agent on the market, but the polyurethane condensate does not only appear in the cleaning process, and NCO groups can be crosslinked and cured at any time in the environment with proper humidity, so that once the conditions of misoperation, improper control of environmental humidity, untimely cleaning after glue application and the like occur in the use process of the hot melt adhesive, the polyurethane condensate can be rapidly generated in pipelines, rollers and the like of gluing equipment.
Therefore, the development of a cleaning agent capable of fully removing residual hot melt adhesive of gluing equipment and polyurethane condensate which is difficult to remove in the application process of reactive Polyurethane (PUR) hot melt adhesive solves the difficult problems in the actual cleaning process, and has great significance for hot melt adhesive enterprises and downstream customers such as automobiles, textiles, wood, electronics and other industries.
Disclosure of Invention
Therefore, the invention provides a novel reactive polyurethane hot melt adhesive cleaning agent, which aims to solve the problems that the existing reactive polyurethane hot melt adhesive cleaning agent is difficult to treat infusible precipitates generated by curing and crosslinking of reactive polyurethane hot melt adhesive, so that equipment pipelines and roller gluing points are easy to block, and the cleaning agent has to be cleaned in a mode of scraping, sanding, even high-temperature firing and the like, which are complicated in operation and can damage the service life of equipment.
Except that the long-chain fatty alcohol in the formula can also play a role in inhibiting NCO group crosslinking and curing in the cleaning process, when the reactive polyurethane hot melt adhesive residual adhesive is cleaned, the polar organic solvent in the formula can effectively penetrate through the surface layer of a cured product and firstly cracks a polyurethane polymer chain, so that other components in the formula are allowed to penetrate into the core of the cured product. The chemical structure of the polyether surfactant in the formula is similar to that of the soft segment of the polyurethane polyether, and the contact and penetration of the cleaning agent component and a single polyurethane polymer chain are facilitated.
After the cleaning agent breaks the cured skin and penetrates the core sufficiently, the combination of polyether surfactant, methyl oleate and terpene compounds can initiate swelling of the polymer matrix, provide a greater contact area between the polar solvent and the polymer chains, and further lead to polymer chain scission. The generated low molecular weight cracking products are dissolved/rinsed by the cleaning agent from the polymer matrix batch by batch under the solubilization/emulsification action of the surfactant, and finally the purpose of completely removing the polyurethane cured product is achieved.
In order to achieve the above purpose, the invention provides the following technical scheme:
the novel reactive polyurethane hot melt adhesive cleaning agent provided by the invention comprises 10-30% of ethylene-vinyl acetate copolymer, 1-10% of tackifying resin, 20-70% of long-chain fatty alcohol, 5-20% of polar organic solvent, 2-10% of polyether surfactant, 1-5% of methyl oleate, 1-5% of terpene compound, 1-5% of plasticizer and 0.1-1% of antioxidant.
Further, the ethylene-vinyl acetate copolymer contains 20-40% of vinyl acetate; as an example, it is preferably 25% to 35%;
the melt index of the ethylene-vinyl acetate copolymer is 300-600g/10min; as an example, 400 to 500g/10min is preferable.
As an example, the ethylene-vinyl acetate copolymer is preferably 20% to 30%.
Furthermore, the tackifying resin is one or more of natural resin, petroleum resin and thermoplastic elastomer; the natural resin comprises one or more of rosin resin, terpene resin and terpene phenolic resin; the thermoplastic elastomer is one or more of EVA, EAA, acrylic resin and thermoplastic polyurethane elastomer TPU;
the ring and ball softening point of the tackifying resin is less than 80 ℃.
Tackifying resins are used in the formulation in the range of 1% to 10%, by way of example, preferably 1% to 5%. The EVA copolymer and the tackifying resin are combined in the formula to adjust the melt flowability of the cleaning agent, so that the cleaning agent is fixed on a non-horizontal surface with polyurethane residual gum and cured substances, the exposure time of the residual gum and the cured substances in the cleaning agent is prolonged, and the dissolution and rinsing are accelerated.
Further, the long-chain fatty alcohol is one or more of hexadecanol, heptadecanol and octadecanol; by way of example, the preferred range of long chain fatty alcohols is 30% to 60%. Hydroxyl in the long-chain fatty alcohol can neutralize the residual NCO end in the PUR hot melt adhesive, so that the effect of the long-chain fatty alcohol in the formula is used for completely neutralizing the residual NCO end in the PUR hot melt adhesive besides being used as a solvent to participate in the dissolution and rinsing of low-molecular-weight cracking products, and the generation of new polyurethane condensate in the cleaning process is avoided.
Further, the polar organic solvent includes one or more N-substituted pyrrolidones including, but not limited to, one or more of N-methylpyrrolidone, N-ethylpyrrolidone, N-hydroxyethylpyrrolidone, N-propylpyrrolidone, N-phenylpyrrolidone, N-benzylpyrrolidone, N-cyclohexylpyrrolidone, and N-octylpyrrolidone, with a preferred range of 10% to 20% being exemplified.
Further, the polyether surfactant is C9-C20 fatty alcohol-polyoxyethylene ether; the number of ethoxy groups is 2-10; alternative polyether surfactants include Rhodasurf LA-3 and Surfonic L24-3 from Solvino Diya, surfonic TDA-3B and Surfonic L12-3 from Hounsfield, tomadol 91-2.5 from American air chemistry, and the like; the range of use in the present invention is 2% to 10%, and as an example, the range is preferably 5% to 10%.
The methyl oleate of the invention is used in the range of 1% to 5%, for example, preferably in the range of 4% to 5%.
Further, the terpene compounds are one or more of pinene, menthene, p-menthene and limonene; the range of use in the present invention is 1% to 5%, preferably 2% to 4%.
Further, the plasticizer is one or more of dibutyl phthalate, dioctyl phthalate and tributyl phosphate; the range of use in the present invention is 1% to 5%, preferably 1% to 3%.
Further, the antioxidant is antioxidant 168, antioxidant 1010 or antioxidant 1076; the range of use in the present invention is 0.1% to 1%, preferably 0.15% to 0.2%.
The invention has the following advantages:
1. the reactive polyurethane hot melt adhesive cleaning agent can thoroughly neutralize residual NCO ends in the PUR hot melt adhesive, and polyurethane condensate is prevented from being generated in the cleaning process;
2. the reactive polyurethane hot melt adhesive cleaning agent can deeply decompose infusible precipitates generated by curing and crosslinking of the reactive polyurethane hot melt adhesive, and convert the infusible precipitates into a low-molecular-weight cracking mixture which can be dissolved in a cleaning adhesive system, thereby achieving the purpose of completely removing cured polyurethane.
3. The reactive polyurethane hot melt adhesive cleaning agent disclosed by the invention is high in quality and low in production cost, and can well meet the increasing equipment cleaning requirements of domestic reactive polyurethane hot melt adhesive users.
Detailed Description
The present invention is described in terms of particular embodiments, other advantages and features of the invention will become apparent to those skilled in the art from the following disclosure, and it is to be understood that the described embodiments are merely exemplary of the invention and that it is not intended to limit the invention to the particular embodiments disclosed. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
Example 1
The embodiment provides a novel reactive polyurethane hot melt adhesive cleaning agent, and the weight ratio of each component is shown in table 1:
TABLE 1
| Name of raw materials | Number of copies |
| Ethylene-vinyl acetate copolymer (ethylene-vinyl acetate copolymer resin VA > 30%) | 25 |
| Tackifying resin (terpene phenolic resin) | 5 |
| Long chain fatty alcohol (with hexadecanol) | 40 |
| Polar organic solvent (N-methyl pyrrolidone is adopted) | 10 |
| Polyether surfactant (using Solvadoria Rhodasurf LA-3) | 10 |
| Oleic acid methyl ester | 5 |
| Terpene compounds (using menthene) | 4 |
| Plasticizer (dibutyl phthalate is adopted) | 1 |
| Antioxidant 1010 | 0.2 |
The preparation method comprises the following steps: adding long-chain fatty alcohol and an antioxidant into a reaction kettle, heating to 100 ℃, stirring and adding other raw materials in batches after the long-chain fatty alcohol and the antioxidant are completely melted, stirring at 200r/min until the raw materials are completely dissolved and uniform, cooling, granulating and packaging.
Example 2
The embodiment provides a novel reactive polyurethane hot melt adhesive cleaning agent, and the weight ratio of each component is shown in table 2:
TABLE 2
| Name of raw materials | Number of parts |
| Ethylene-vinyl acetate copolymer (ethylene-vinyl acetate copolymer resin VA > 30%) | 30 |
| Tackifying resin (petroleum resin is adopted) | 5 |
| Long chain fatty alcohol (with heptadecanol) | 37 |
| Polar organic solvent (N-ethyl pyrrolidone is adopted) | 15 |
| Polyether surfactant (using Hensmei surfionic TDA-3B) | 5 |
| Oleic acid methyl ester | 4 |
| Terpene compounds (using pinene) | 3 |
| Plasticizer (dioctyl phthalate) | 1 |
| Antioxidant 168 | 0.15 |
The preparation method comprises the following steps: adding long-chain fatty alcohol and an antioxidant into a reaction kettle, heating to 100 ℃, stirring and adding other raw materials in batches after the long-chain fatty alcohol and the antioxidant are completely melted, stirring at 200r/min until the raw materials are completely dissolved and uniform, cooling, granulating and packaging.
Example 3
The embodiment provides a novel reactive polyurethane hot melt adhesive cleaning agent, and the weight ratio of each component is shown in table 3:
TABLE 3
The preparation method comprises the following steps: adding long-chain fatty alcohol and an antioxidant into a reaction kettle, heating to 100 ℃, stirring and adding other raw materials in batches after the long-chain fatty alcohol and the antioxidant are completely melted, stirring at 200r/min until the raw materials are completely dissolved and uniform, cooling, granulating and packaging.
Test example
The comparison sample selects cleaning agent C60 special for the American Fule PUR hot melt adhesive and cleaning agent for rubber roll rubber tube gun nozzle PUR rubber neutralized in Suzhou. The test equipment adopts a roll coating film laminating machine, and the test process is as follows:
500g of cleaning agent is respectively added into a rubber conveying pipeline and a roller gap of the roll coating machine, the temperature is heated to 75-80 ℃, the cleaning agent is kept to flow in the pipeline, the roller is kept to rotate, the cleaning agent is removed after the temperature is kept for about 10 minutes, and the comparative cleaning effect is observed and shown in table 4.
TABLE 4
| Time of cleaning | Cleaning effect | |
| Example 1 | 10min | Has no residue |
| Example 2 | 10min | Has no residue |
| Example 3 | 10min | Has no residue |
| C60 | 10min | With residual white particles |
| Rubber covered roller rubber tube gun nozzle PUR | 10min | With residual white particles |
And (4) conclusion: the reactive polyurethane hot melt adhesive cleaning agent and the C60 cleaning agent in the embodiments 1-3 of the invention can complete the cleaning of residual adhesive, but the cleaning effect of the cleaning agent for PUR adhesive of the rubber roll rubber tube gun nozzle neutralized in Suzhou is poor, and the cleaning time needs to be prolonged. Residual white particles are observed on the pipe wall and the roller gluing point of the pipeline after C60 cleaning, and are polyurethane infusible substances after crosslinking and curing, and no residue is left after the reactive polyurethane hot melt adhesive cleaning agent in the embodiments 1-3 of the invention is cleaned.
From experimental test results, the cleaning effect of the reactive polyurethane hot melt adhesive cleaning agent is superior to that of a cleaning agent C60 special for the American Fule PUR hot melt adhesive and a cleaning agent for the rubber roll rubber tube gun nozzle PUR in Suzhou, and polyurethane condensate which cannot be cleaned can be cleaned.
Although the invention has been described in detail above with reference to a general description and specific examples, it will be apparent to one skilled in the art that modifications or improvements may be made thereto based on the invention. Accordingly, such modifications and improvements are intended to be within the scope of the invention as claimed.
Claims (10)
1. A novel reactive polyurethane hot melt adhesive cleaning agent is characterized by comprising 10% -30% of an ethylene-vinyl acetate copolymer, 1% -10% of tackifying resin, 20% -70% of long-chain fatty alcohol, 5% -20% of a polar organic solvent, 2% -10% of a polyether surfactant, 1% -5% of methyl oleate, 1% -5% of terpene compounds, 1% -5% of a plasticizer and 0.1% -1% of an antioxidant.
2. The novel reactive polyurethane hot melt adhesive cleaning agent as claimed in claim 1, wherein the ethylene-vinyl acetate copolymer contains 20-40% of vinyl acetate.
3. The novel reactive polyurethane hot melt adhesive cleaning agent according to claim 1, wherein the melt index of the ethylene-vinyl acetate copolymer is 300-600g/10min.
4. The novel reactive polyurethane hot melt adhesive cleaning agent according to claim 1, wherein the tackifying resin is one or more of natural resin, petroleum resin and thermoplastic elastomer; the natural resin comprises one or more of rosin resin, terpene resin and terpene phenolic resin; the thermoplastic elastomer is one or more of EVA, EAA, acrylic resin and thermoplastic polyurethane elastomer TPU.
5. The novel reactive polyurethane hot melt adhesive cleaning agent as claimed in claim 4, wherein the tackifying resin has a ring and ball softening point of less than 80 ℃.
6. The novel reactive polyurethane hot melt adhesive cleaning agent according to claim 1, wherein the long-chain fatty alcohol is one or more of hexadecanol, heptadecanol and octadecanol.
7. The novel reactive polyurethane hot melt adhesive cleaning agent according to claim 1, wherein the polar organic solvent is one or more of N-methylpyrrolidone, N-ethylpyrrolidone, N-hydroxyethyl pyrrolidone, N-propylpyrrolidone, N-phenylpyrrolidone, N-benzylpyrrolidone, N-cyclohexylpyrrolidone and N-octylpyrrolidone.
8. The novel reactive polyurethane hot melt adhesive cleaning agent according to claim 7, wherein the polyether surfactant is C9-C20 fatty alcohol-polyoxyethylene ether; the number of ethoxy groups is 2-10.
9. The novel reactive polyurethane hot melt adhesive cleaning agent as claimed in claim 1, wherein the terpene compound is one or more of pinene, menthene, p-menthene and limonene.
10. The novel reactive polyurethane hot melt adhesive cleaning agent according to claim 1, wherein the plasticizer is one or more of dibutyl phthalate, dioctyl phthalate and tributyl phosphate.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5348680A (en) * | 1991-11-27 | 1994-09-20 | H. B. Fuller Licensing & Financing, Inc. | Cleaning composition for removing reactive polyurethane hot melt adhesives |
| US20060186379A1 (en) * | 2005-02-10 | 2006-08-24 | Coleman Kenneth C | Composition and method using same to remove urethane products from a substrate |
| CN102719325A (en) * | 2012-06-26 | 2012-10-10 | 中国科学院理化技术研究所嘉兴工程中心 | Novel reactive-type polyurethane hot-melt adhesive cleaning agent |
-
2022
- 2022-08-10 CN CN202210957469.9A patent/CN115197789A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5348680A (en) * | 1991-11-27 | 1994-09-20 | H. B. Fuller Licensing & Financing, Inc. | Cleaning composition for removing reactive polyurethane hot melt adhesives |
| US20060186379A1 (en) * | 2005-02-10 | 2006-08-24 | Coleman Kenneth C | Composition and method using same to remove urethane products from a substrate |
| CN102719325A (en) * | 2012-06-26 | 2012-10-10 | 中国科学院理化技术研究所嘉兴工程中心 | Novel reactive-type polyurethane hot-melt adhesive cleaning agent |
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