CN115128423A - Heavy ion irradiation influence beta-Ga 2 O 3 Method for simulating electrical performance of MOSFET device - Google Patents
Heavy ion irradiation influence beta-Ga 2 O 3 Method for simulating electrical performance of MOSFET device Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及电子技术领域,具体而言,涉及一种重离子辐照影响β-Ga2O3 MOSFET器件电化学性能的方法。The invention relates to the field of electronic technology, in particular to a method for influencing the electrochemical performance of a β-Ga 2 O 3 MOSFET device by heavy ion irradiation.
背景技术Background technique
氧化镓(Ga2O3)具有约4.4-5.3eV的宽带隙,是具有代表性的宽带隙半导体材料之一。Ga2O3具有多种不同的多晶型物,并且不同的多晶型物具有不同的结构对称性和各向异性,其中β相具有单斜晶体结构,是热力学中最稳定的相,在近些年的研究中,大多数的研究都集中在β-Ga2O3。将β-Ga2O3材料和器件应用于空间环境中时,通常会暴露于多种类型的粒子和射线辐照下,当β-Ga2O3材料受到低能重离子的辐照时,粒子会沉积在材料内部,形成布拉格峰,产生单空位、间隙原子等位移缺陷,而这些缺陷会显著影响材料的物理和化学性能。Gallium oxide (Ga 2 O 3 ) has a wide band gap of about 4.4-5.3 eV, and is one of the representative wide band gap semiconductor materials. Ga 2 O 3 has many different polymorphs, and different polymorphs have different structural symmetry and anisotropy, among which the β phase has a monoclinic crystal structure and is the most stable phase in thermodynamics. In recent years, most of the studies have focused on β-Ga 2 O 3 . When β-Ga 2 O 3 materials and devices are applied in space environment, they are usually exposed to various types of particles and radiation. When β-Ga 2 O 3 materials are irradiated by low-energy heavy ions, the particles It will be deposited inside the material, form Bragg peaks, and generate displacement defects such as single vacancies and interstitial atoms, and these defects will significantly affect the physical and chemical properties of the material.
最近,β-Ga2O3作为用于未来功率和光电探测器器件的超宽禁带氧化物半导体引起了极大的关注,而β-Ga2O3 MOSFET(Metal-Oxide-Semiconductor Field-EffectTransistor,金属-氧化物半导体场效应晶体管)是常用的β-Ga2O3器件之一。为了实现半导体器件的高性能和高可靠性,控制晶体缺陷至关重要,因为这些缺陷可能对器件性能产生负面和破坏性影响,在某些情况下,这些晶体缺陷甚至会带来漏电流和较低的击穿电压。因此,表征晶体中的缺陷并了解其形成机制至关重要,但目前对此相关的研究较少,也无法确定哪种特定缺陷是晶体管不稳定的主要来源。Recently, β - Ga2O3 has attracted great attention as an ultra-wide bandgap oxide semiconductor for future power and photodetector devices, and β - Ga2O3 MOSFET (Metal-Oxide-Semiconductor Field-EffectTransistor , Metal-Oxide Semiconductor Field Effect Transistor) is one of the commonly used β-Ga 2 O 3 devices. In order to achieve high performance and reliability of semiconductor devices, it is critical to control crystal defects, as these defects can have negative and destructive effects on device performance, and in some cases, even cause leakage current and higher low breakdown voltage. Therefore, it is crucial to characterize defects in crystals and understand their formation mechanism, but there is little research on this, and it is impossible to determine which specific defects are the main source of transistor instability.
发明内容SUMMARY OF THE INVENTION
本发明解决的问题是如何提供一种重离子辐照影响β-Ga2O3 MOSFET器件电化学性能的方法,研究哪种特定缺陷是晶体管不稳定的主要来源。The problem solved by the present invention is how to provide a method for influencing the electrochemical performance of β-Ga 2 O 3 MOSFET devices by heavy ion irradiation, and to study which specific defect is the main source of transistor instability.
为解决上述问题中的至少一个方面,本发明提供一种重离子辐照影响β-Ga2O3MOSFET器件电化学性能的方法,包括以下步骤:In order to solve at least one aspect of the above problems, the present invention provides a method for affecting the electrochemical performance of a β-Ga 2 O 3 MOSFET device by heavy ion irradiation, comprising the following steps:
步骤S1、将外延层中掺杂施主Si元素的β-Ga2O3的外延晶片进行洗涤,然后在室温条件下进行不同注量的重离子辐照;Step S1, washing the epitaxial wafer of β-Ga 2 O 3 doped with the donor Si element in the epitaxial layer, and then performing heavy ion irradiation with different fluences at room temperature;
步骤S2、检测重离子辐照前后β-Ga2O3外延晶片的单斜结构、弯曲振动、拉伸模式光学性质和化学结合状态;Step S2, detecting the monoclinic structure, bending vibration, tensile mode optical properties and chemical bonding state of the β-Ga 2 O 3 epitaxial wafer before and after heavy ion irradiation;
步骤S3、对步骤S2中得到的实验数据进行总结,得出重离子辐照β-Ga2O3外延晶片后产生的点缺陷以及其衍化过程;In step S3, the experimental data obtained in step S2 are summarized, and the point defects and their derivatization processes generated after the β-Ga 2 O 3 epitaxial wafer is irradiated by heavy ions are obtained;
步骤S4、将步骤S3中产生的点缺陷引入β-Ga2O3 MOSFET模型中,输出模拟电学性能曲线,并进行分析。Step S4 , introducing the point defects generated in step S3 into the β-Ga 2 O 3 MOSFET model, outputting a simulated electrical performance curve, and performing analysis.
优选地,所述重离子辐照为N离子辐照。Preferably, the heavy ion irradiation is N ion irradiation.
优选地,所述步骤S1中,所述N离子辐照的能量为400keV,粒子通量为1×1013atomcm-2·s-1,粒子注量分别为5×1015ions/cm2、5×1016ions/cm2和5×1017ions/cm2。Preferably, in the step S1, the energy of the N ion irradiation is 400keV, the particle flux is 1×10 13 atomcm-2·s -1 , and the particle fluence is 5×10 15 ions/cm 2 , 5×10 16 ions/cm 2 and 5×10 17 ions/cm 2 .
优选地,所述步骤S2中,检测重离子辐照前后β-Ga2O3外延晶片的单斜结构、弯曲振动和拉伸模式时,激发波长设置为532nm,测试范围为100-800cm-1,分辨率设置为0.5cm-1。Preferably, in the step S2, when detecting the monoclinic structure, bending vibration and tensile mode of the β-Ga 2 O 3 epitaxial wafer before and after heavy ion irradiation, the excitation wavelength is set to 532 nm, and the test range is 100-800 cm -1 , the resolution is set to 0.5cm -1 .
优选地,所述步骤S2中,使用光功率为35mW的325nmHe-Cd激光器研究重离子辐照前后β-Ga2O3外延晶片的光学性质。Preferably, in the step S2, a 325 nm He-Cd laser with an optical power of 35 mW is used to study the optical properties of the β-Ga 2 O 3 epitaxial wafer before and after heavy ion irradiation.
优选地,将所述β-Ga2O3外延晶片发出的PL光引导至Jobin Yvon Triax320单色器上,然后由Hamamatsu Si光电倍增器记录,并使用与20Hz光斩波器同步的锁定放大器来提高信噪比。Preferably, the PL light from the β - Ga2O3 epitaxial wafer is directed onto a Jobin Yvon Triax320 monochromator, then recorded by a Hamamatsu Si photomultiplier and using a lock-in amplifier synchronized with a 20Hz photo-chopper Improve the signal-to-noise ratio.
优选地,所述步骤S2中,通过X射线光电子能谱分析技术检测重离子辐照前后β-Ga2O3外延晶片化学结合状态,使用单色铝靶X射线源和校准在284.8eV的标准碳元素结合能作为参考。Preferably, in the step S2, the chemical bonding state of the β-Ga 2 O 3 epitaxial wafer before and after heavy ion irradiation is detected by X-ray photoelectron spectroscopy, using a monochromatic aluminum target X-ray source and a standard calibrated at 284.8 eV The carbon binding energy is used as a reference.
优选地,所述步骤S3中,通过对比X射线光电子能谱分析测试结果,分析重离子辐照后β-Ga2O3材料中产生的点缺陷。Preferably, in the step S3, point defects generated in the β-Ga 2 O 3 material after heavy ion irradiation are analyzed by comparing the test results of X-ray photoelectron spectroscopy.
优选地,所述步骤S4中,在silvaco TCAD半导体仿真软件的模拟实例中找到β-Ga2O3 MOSFET模型,引入所述步骤S3中分析得到的点缺陷,输出模拟的电学性能曲线,并进行分析。Preferably, in the step S4, the β-Ga 2 O 3 MOSFET model is found in the simulation example of the silvaco TCAD semiconductor simulation software, the point defects obtained by the analysis in the step S3 are introduced, the simulated electrical performance curve is output, and the analyze.
优选地,利用silvaco TCAD半导体仿真软件中的Atlas和Athena模块进行仿真模拟。Preferably, the simulation is performed using Atlas and Athena modules in silvaco TCAD semiconductor simulation software.
本发明通过在不同离子注量条件下对掺杂施主Si元素的β-Ga2O3外延晶片进行N离子辐照,能够在β-Ga2O3材料上产生不同的点缺陷,然后通过分析N离子辐照前后β-Ga2O3材料中性质的变化,得到点缺陷情况,并将分析得到的点缺陷引入β-Ga2O3 MOSFET模型中,分析引入不同点缺陷前后β-Ga2O3 MOSFET模型的电化学性能,从而得到不同点缺陷对β-Ga2O3MOSFET模型电化学性能所产生的影响,而由于不同的点缺陷与不同离子注量的N离子辐照相对应,因此能够得到不同离子注量的N离子辐照对β-Ga2O3MOSFET模型产生的影响;本发明通过将β-Ga2O3外延晶片的辐照研究与β-Ga2O3 MOSFET器件的模拟研究进行结合,提供了N离子辐照与β-Ga2O3MOSFET器件性能之间的关系,对β-Ga2O3 MOSFET器件抗辐射机理研究产生了显著的效果。The invention can generate different point defects on the β-Ga 2 O 3 material by irradiating the β-Ga 2 O 3 epitaxial wafer doped with the donor Si element under different ion fluence conditions, and then analyze Changes in properties of β-Ga 2 O 3 materials before and after N ion irradiation, and point defects are obtained. The point defects obtained by analysis are introduced into the β-Ga 2 O 3 MOSFET model, and β-Ga 2 before and after the introduction of different point defects is analyzed. The electrochemical properties of the O 3 MOSFET model were obtained to obtain the effect of different point defects on the electrochemical performance of the β-Ga 2 O 3 MOSFET model. Since different point defects correspond to N ion radiation with different ion fluences, Therefore, the effect of N ion irradiation with different ion ions on the β-Ga 2 O 3 MOSFET model can be obtained; the present invention combines the irradiation research of β-Ga 2 O 3 epitaxial wafer with the β-Ga 2 O 3 MOSFET device. Combined with the simulation research of β-Ga 2
附图说明Description of drawings
图1为本发明实施例中重离子辐照影响β-Ga2O3MOSFET器件电化学性能的方法的流程图;Fig. 1 is the flow chart of the method for the electrochemical performance of β-Ga 2 O 3 MOSFET device affected by heavy ion irradiation in the embodiment of the present invention;
图2为本发明实施例中N粒子辐照前后β-Ga2O3外延晶片的PL广谱图及其拟合结果图;Fig. 2 is the PL broad spectrum diagram of the β-Ga 2 O 3 epitaxial wafer before and after N particle irradiation in the embodiment of the present invention and its fitting result diagram;
图3为本发明实施例中N粒子辐照前后β-Ga2O3外延晶片XPS拟合结果图;FIG. 3 is an XPS fitting result diagram of a β-Ga 2 O 3 epitaxial wafer before and after N particle irradiation in an embodiment of the present invention;
图4为本发明实施例中β-Ga2O3MOSFET中引入点缺陷前后的电化学性能分析图。FIG. 4 is an analysis diagram of electrochemical performance before and after introducing point defects in a β-Ga 2 O 3 MOSFET in an embodiment of the present invention.
具体实施方式Detailed ways
为使本发明的上述目的、特征和优点能够更为明显易懂,下面对本发明的具体实施例做详细的说明。In order to make the above objects, features and advantages of the present invention more clearly understood, specific embodiments of the present invention will be described in detail below.
需要说明的是,在不冲突的情况下,本发明中的实施例中的特征可以相互组合。术语“包含”、“包括”、“含有”、“具有”的含义是非限制性的,即可加入不影响结果的其它步骤和其它成分。以上术语涵盖术语“由……组成”和“基本上由……组成”。如无特殊说明的,材料、设备、试剂均为市售。It should be noted that the features in the embodiments of the present invention may be combined with each other without conflict. The meanings of the terms "comprising", "including", "containing", "having" are non-limiting, that is, other steps and other ingredients may be added that do not affect the result. The above terms cover the terms "consisting of" and "consisting essentially of". Unless otherwise specified, materials, equipment and reagents are all commercially available.
本发明实施例提供一种重离子辐照影响β-Ga2O3 MOSFET器件电化学性能的方法,如图1所示,包括以下步骤:An embodiment of the present invention provides a method for affecting the electrochemical performance of a β-Ga 2 O 3 MOSFET device by heavy ion irradiation, as shown in FIG. 1 , including the following steps:
步骤S1、将外延层中掺杂施主Si元素的β-Ga2O3的外延晶片进行洗涤,然后在室温条件下进行不同注量的重离子辐照;Step S1, washing the epitaxial wafer of β-Ga 2 O 3 doped with the donor Si element in the epitaxial layer, and then performing heavy ion irradiation with different fluences at room temperature;
步骤S2、检测重离子辐照前后β-Ga2O3外延晶片的单斜结构、弯曲振动、拉伸模式光学性质和化学结合状态;Step S2, detecting the monoclinic structure, bending vibration, tensile mode optical properties and chemical bonding state of the β-Ga 2 O 3 epitaxial wafer before and after heavy ion irradiation;
步骤S3、对步骤S2中得到的实验数据进行总结,得出重离子辐照β-Ga2O3外延晶片后产生的点缺陷以及其衍化过程;In step S3, the experimental data obtained in step S2 are summarized, and the point defects and their derivatization processes generated after the β-Ga 2 O 3 epitaxial wafer is irradiated by heavy ions are obtained;
步骤S4、将步骤S3中产生的点缺陷引入β-Ga2O3 MOSFET模型中,输出模拟电学性能曲线,并进行分析。Step S4 , introducing the point defects generated in step S3 into the β-Ga 2 O 3 MOSFET model, outputting a simulated electrical performance curve, and performing analysis.
其中,步骤S1中,将外延层中掺杂施主Si元素的β-Ga2O3的外延晶片切割成相同大小的块,用于对不同重离子辐照条件下的研究,将切割后的β-Ga2O3的外延晶片用丙酮超声处理,然后用蒸馏水洗涤,除去其表面的杂质。将清洗后的β-Ga2O3的外延晶片在室温条件下于串联范德格拉夫加速器(北京大学)中以400eV的能量进行不同注量的N离子辐照。其中,粒子通量为1×1013atom cm-2·s-1,粒子注量分别为5×1015ions/cm2、5×1016ions/cm2和5×1017ions/cm2。Wherein, in step S1, the epitaxial wafer of β-Ga 2 O 3 doped with the donor Si element in the epitaxial layer is cut into blocks of the same size, which are used for research under different heavy ion irradiation conditions. The epitaxial wafer of -Ga2O3 was sonicated with acetone and then washed with distilled water to remove impurities from its surface. The cleaned epitaxial wafers of β-Ga 2 O 3 were irradiated with different fluences of N ions at room temperature in a tandem van der Graaff accelerator (Peking University) with an energy of 400 eV. Among them, the particle flux is 1×10 13 atom cm-2·s -1 , and the particle fluence is 5×10 15 ions/cm 2 , 5×10 16 ions/cm 2 and 5×10 17 ions/cm 2 , respectively .
纯的半导体材料在室温下是不导电的,而要使半导体导电需要掺杂施主元素,通过在β-Ga2O3的外延晶片的外延层中掺杂Si元素,能够提供价电子,使β-Ga2O3的外延晶片导电,便于后续对其指标进行检测。采用不同粒子注量的N离子辐照,能够使β-Ga2O3材料产生不同的点缺陷,能够研究粒子注量与点缺陷的对应情况。Pure semiconductor materials are non - conductive at room temperature, but to make the semiconductor conductive requires doping with donor elements. -The epitaxial wafer of Ga 2 O 3 is conductive, which is convenient for subsequent detection of its indicators. Using N ion irradiation with different particle fluence can make β-Ga 2 O 3 material produce different point defects, and can study the correspondence between particle fluence and point defects.
步骤S2中,对N离子辐照前后β-Ga2O3外延晶片的单斜结构、弯曲振动、拉伸模式光学性质和化学结合状态进行检测。In step S2, the monoclinic structure, bending vibration, tensile mode optical properties and chemical bonding state of the β-Ga 2 O 3 epitaxial wafer before and after N ion irradiation are detected.
在InVia-Reflex尖端增强型激光共焦拉曼光谱系统监测N离子辐照前后β-Ga2O3的外延晶片的单斜结构、弯曲振动和拉伸模式,其中,激发波长设置为532nm,测试范围为100-800cm-1,分辨率设置为0.5cm-1。The monoclinic structure, bending vibration and tensile modes of epitaxial wafers of β-Ga 2 O 3 before and after N ion irradiation were monitored in an InVia-Reflex tip-enhanced laser confocal Raman spectroscopy system, where the excitation wavelength was set to 532 nm, and the test The range is 100-800cm -1 and the resolution is set to 0.5cm -1 .
使用光功率为35mW的325nm He-Cd激光器研究N离子辐照前后β-Ga2O3外延晶片的光学性质,检测过程中将β-Ga2O3外延晶片发出的光致发光(PhotoluminescenceSpectroscopy,PL)引导至Jobin Yvon Triax 320单色器上,然后由Hamamatsu Si光电倍增器记录,并使用与20Hz光斩波器同步的锁定放大器来提高信噪比。The optical properties of β - Ga 2 O 3 epitaxial wafers before and after N ion irradiation were investigated using a 325 nm He-Cd laser with an optical power of 35 mW. ) were directed onto a Jobin Yvon Triax 320 monochromator, and then recorded by a Hamamatsu Si photomultiplier, and a lock-in amplifier synchronized with a 20Hz photo-chopper was used to improve the signal-to-noise ratio.
通过X射线光电子能谱分析技术(XPS)检测N离子辐照前后β-Ga2O3外延晶片化学结合状态,并使用单色铝靶X射线源和校准在284.8eV的标准碳元素结合能作为参考。The chemical bonding state of β-Ga 2 O 3 epitaxial wafers before and after N ion irradiation was detected by X-ray photoelectron spectroscopy (XPS), and the monochromatic aluminum target X-ray source and the standard carbon element binding energy calibrated at 284.8 eV were used as the refer to.
步骤S3中,对步骤S2检测得到的结果进行分析,分析经过不同粒子注量的N离子辐照后,β-Ga2O3外延晶片产生了哪些点缺陷。通过对比分析N粒子辐照前后的检测结果,能分析出β-Ga2O3外延晶片产生了哪些点缺陷,从而得到N粒子辐照的粒子注量与所产生点缺陷之间的对应关系。In step S3, the result detected in step S2 is analyzed to analyze which point defects are generated in the β-Ga 2 O 3 epitaxial wafer after being irradiated by N ions with different particle fluences. By comparing and analyzing the test results before and after N particle irradiation, it is possible to analyze which point defects are generated in the β-Ga 2 O 3 epitaxial wafer, so as to obtain the corresponding relationship between the particle fluence of N particle irradiation and the point defects generated.
步骤S4中,在silvaco TCAD半导体仿真软件的模拟实例中找到β-Ga2O3MOSFET模型,使用软件中的Atlas和Athena模块进行分析,利用trap参数引入步骤S3中分析得到的点缺陷,用e.level设置分立陷阱能级,degen.fac定义陷阱能级的退化因子,并用于计算密度,sign和sigp定义对于电子或空穴的陷阱捕获横截部分。通过仿真模拟,输出引入不同缺陷点前后β-Ga2O3MOSFET模型的电学性能曲线,分析缺陷点对电学性能的影响,并根据不同粒子注量N离子辐照条件下能产生的缺陷点情况,分析不同粒子注量条件N粒子辐照条件对β-Ga2O3 MOSFET器件电学性能的影响。In step S4, find the β-Ga 2 O 3 MOSFET model in the simulation example of the silvaco TCAD semiconductor simulation software, use the Atlas and Athena modules in the software for analysis, and use the trap parameter to introduce the point defect analyzed in step S3, and use e .level sets the discrete trap level, degen.fac defines the degeneration factor for the trap level and is used to calculate the density, and sign and sigp define the trap trapping cross section for electrons or holes. Through simulation, the electrical performance curves of the β-Ga 2 O 3 MOSFET model before and after the introduction of different defect points are output, the influence of defect points on the electrical performance is analyzed, and the defect points that can be generated under the condition of N ion irradiation with different particle fluences are analyzed. , to analyze the influence of N particle irradiation conditions on the electrical properties of β-Ga 2 O 3 MOSFET devices with different particle fluence conditions.
通过在不同离子注量条件下对掺杂施主Si元素的β-Ga2O3外延晶片进行N离子辐照,能够在β-Ga2O3材料上产生不同的点缺陷,然后通过分析N离子辐照前后β-Ga2O3材料中性质的变化,得到点缺陷情况,并将分析得到的点缺陷引入β-Ga2O3 MOSFET模型中,分析引入不同点缺陷前后β-Ga2O3MOSFET模型的电化学性能,从而得到不同点缺陷对β-Ga2O3MOSFET模型电化学性能所产生的影响,而由于不同的点缺陷与不同离子注量的N离子辐照相对应,因此能够得到不同离子注量的N离子辐照对β-Ga2O3 MOSFET模型产生的影响;通过将β-Ga2O3外延晶片的辐照研究与β-Ga2O3 MOSFET器件的模拟研究进行结合,提供了N离子辐照与β-Ga2O3 MOSFET器件性能之间的关系,对β-Ga2O3 MOSFET器件抗辐射机理研究产生了显著的效果。By irradiating the β-Ga 2 O 3 epitaxial wafer doped with donor Si element with N ions under different ion fluence conditions, different point defects can be generated on the β-Ga 2 O 3 material, and then by analyzing the N ions Changes in the properties of β-Ga 2 O 3 materials before and after irradiation to obtain point defects, and introduce the point defects obtained by analysis into the β-Ga 2 O 3 MOSFET model, and analyze the β-Ga 2 O 3 before and after introducing different point defects The electrochemical performance of the MOSFET model can be obtained to obtain the effect of different point defects on the electrochemical performance of the β-Ga 2 O 3 MOSFET model. The effects of N ion irradiation with different ion ions on the model of β - Ga 2 O 3 MOSFET were obtained ; Combined, the relationship between N ion irradiation and the performance of β-Ga 2 O 3 MOSFET devices is provided, which has a significant effect on the study of radiation resistance mechanism of β-Ga 2 O 3 MOSFET devices.
下面结合具体实施例说明重离子辐照影响β-Ga2O3 MOSFET器件电学性能的模拟方法:The following describes the simulation method that heavy ion irradiation affects the electrical properties of β-Ga 2 O 3 MOSFET devices in conjunction with specific embodiments:
实施例Example
1.1、将外延层中掺杂施主Si元素的β-Ga2O3的外延晶片切割成大小均匀的小块,将其在丙酮重超声处理,然后用蒸馏水进行洗涤,在室温条件下采用400eV的N粒子对β-Ga2O3的外延晶片进行辐照试验,试验中N离子的粒子通量为1×1013atom cm-2·s-1,粒子注量分别设置为5×1015ions/cm2、5×1016ions/cm2和5×1017ions/cm2;1.1. The epitaxial wafer of β-Ga 2 O 3 doped with donor Si element in the epitaxial layer was cut into small pieces of uniform size, which were re-sonicated in acetone, and then washed with distilled water. The β-Ga 2 O 3 epitaxial wafer was irradiated by N particles. In the experiment, the particle flux of N ions was 1×10 13 atom cm-2·s -1 , and the particle fluence was set to 5×10 15 ions respectively. /cm 2 , 5×10 16 ions/cm 2 and 5×10 17 ions/cm 2 ;
1.2、在InVia-Reflex尖端增强型激光共焦拉曼光谱系统监测N离子辐照前后β-Ga2O3的外延晶片的单斜结构、弯曲振动和拉伸模式,其中,检测条件为:激发波长设置为532nm,测试范围为100-800cm-1,分辨率设置为0.5cm-1;使用光功率为35mW的325nmHe-Cd激光器研究N离子辐照前后β-Ga2O3外延晶片的光学性质,检测过程中将β-Ga2O3外延晶片发出的PL光引导至Jobin Yvon Triax 320单色器上,然后由Hamamatsu Si光电倍增器记录,并使用与20Hz光斩波器同步的锁定放大器来提高信噪比;通过XPS检测N离子辐照前后β-Ga2O3外延晶片化学结合状态,并使用单色铝靶X射线源和校准在284.8eV的标准碳元素结合能作为参考。1.2. The InVia-Reflex tip-enhanced laser confocal Raman spectroscopy system was used to monitor the monoclinic structure, bending vibration and tensile mode of the epitaxial wafer of β-Ga 2 O 3 before and after N ion irradiation. The detection conditions were: excitation The wavelength was set to 532nm, the test range was 100-800cm -1 , and the resolution was set to 0.5cm -1 ; the optical properties of β-Ga 2 O 3 epitaxial wafers before and after N ion irradiation were studied using a 325nm He-Cd laser with an optical power of 35mW , the PL light from the β - Ga2O3 epitaxial wafer was directed onto a Jobin Yvon Triax 320 monochromator during detection, which was then recorded by a Hamamatsu Si photomultiplier using a lock-in amplifier synchronized with a 20Hz optical chopper to Improve the signal-to-noise ratio; detect the chemical bonding state of β-Ga 2 O 3 epitaxial wafers before and after N ion irradiation by XPS, and use a monochromatic aluminum target X-ray source and a standard carbon element binding energy calibrated at 284.8 eV as a reference.
1.3、对步骤1.2中得到的实验数据进行总结,并分析N离子辐照前后β-Ga2O3外延晶片的变化,确定β-Ga2O3外延晶片产生的点缺陷,其中,图2为N离子辐照前后β-Ga2O3外延晶片的PL光谱,和在不同粒子注量条件下拟合的结果,图2中a)为辐照前后的PL广谱,从图中可以看出β-Ga2O3外延晶片显示出跨度为300-600nm的发光峰,对β-Ga2O3外延晶片的发光峰拟合出365nm(3.39eV)的UV PL带和410nm(3.02eV)的蓝色PL带。结合Quoc等人使用第一性原理计算的光学跃迁能级的结果,UV带峰归因于自陷激子,由GaO4四面体配合物和自陷空穴组成;蓝色发光峰则来源于施主杂质中的电子和受主杂质中的空穴的施主-受主对(DAP)复合发光带,其中施主带由Vo组成,受主带由VGa2 1-组成。图2中b)和图2中c)分别为在粒子注量为5×1015ions/cm2和5×1017ions/cm2条件下PL拟合结果,从图中可以看出,PL强度随着辐照粒子注量的变化而产生变化,低粒子注量情况下N粒子辐照时PL峰显著增加,但随着粒子注量的增加,PL峰的发光强度反而有所下降。这主要是由于,在低粒子注量条件下,引起蓝色发光的单空位缺陷如Vo和VGa2 1-的浓度会显著增加,从而导致PL峰的强度增加,然而,随着粒子注量的增加,大量的N离子会进入材料并参与键合,此时不稳定的Vo缺陷有可能被N离子取代形成No1-缺陷,而Vo缺陷的衍化过程会引起淬火效应,导致PL峰的强度有所下降。图3为N离子辐照前后β-Ga2O3外延晶片中N1s的XPS拟合结果,其中图3中a)为未辐照条件下和离子注量为5×1015ions/cm2条件下的结果,图3中b)为注量为5×1017ions/cm2条件下的结果,从图3可以看出,图3中a)和图3中b)中均有3个子峰,其中398.4nm附近的峰是N原子的峰,另外两个峰分别对应Ga-N和No1-缺陷,随着粒子通量的增加,一部分N离子取代Vo缺陷,此结果与图2中所示PL结果相符,进一步证明了粒子注量对β-Ga2O3外延晶片中缺陷的影响。1.3. Summarize the experimental data obtained in step 1.2, analyze the changes of the β-Ga 2 O 3 epitaxial wafer before and after N ion irradiation, and determine the point defects generated by the β-Ga 2 O 3 epitaxial wafer. The PL spectra of β-Ga 2 O 3 epitaxial wafers before and after N ion irradiation, and the fitting results under different particle fluence conditions, a) in Figure 2 is the PL broad spectrum before and after irradiation, as can be seen from the figure The β-Ga 2 O 3 epitaxial wafer showed luminescence peaks spanning 300-600 nm, and the luminescence peaks of β-Ga 2 O 3 epitaxial wafers were fitted with a UV PL band at 365 nm (3.39 eV) and a UV PL band at 410 nm (3.02 eV). Blue PL band. Combined with the results of optical transition energy levels calculated by Quoc et al. using first-principles, the UV band peak is attributed to self-trapped excitons, which consist of GaO tetrahedral complexes and self-trapped holes; the blue emission peak is derived from Donor-acceptor pair (DAP) composite emission band of electrons in donor impurities and holes in acceptor impurities, where the donor band consists of V o and the acceptor band consists of V Ga2 1- . b) in Fig. 2 and c) in Fig. 2 are the PL fitting results under the conditions of particle fluence of 5×10 15 ions/cm 2 and 5×10 17 ions/cm 2 , respectively. It can be seen from the figure that PL The intensity varies with the fluence of irradiated particles. Under the condition of low particle fluence, the PL peak increases significantly when irradiated by N particles, but with the increase of particle fluence, the luminescence intensity of the PL peak decreases. This is mainly due to that, under low particle fluence conditions, the concentration of single-vacancy defects such as Vo and V Ga2 1- that cause blue emission increases significantly, resulting in an increase in the intensity of the PL peak, however, with the particle fluence With the increase of , a large number of N ions will enter the material and participate in the bonding. At this time, the unstable Vo defects may be replaced by N ions to form No 1- defects, and the derivatization process of Vo defects will cause a quenching effect, resulting in PL peaks strength has decreased. Fig. 3 shows the XPS fitting results of N1s in β-Ga 2 O 3 epitaxial wafers before and after N ion irradiation, in which a) in Fig. 3 is the unirradiated condition and the ion fluence of 5×10 15 ions/cm 2 Figure 3 b) is the result under the condition that the fluence is 5×10 17 ions/cm 2 , it can be seen from Figure 3 that there are 3 sub-peaks in both a) in Figure 3 and b) in Figure 3 , in which the peak near 398.4 nm is the peak of N atoms, and the other two peaks correspond to Ga-N and No 1- defects, respectively. With the increase of particle flux, a part of N ions replace Vo defects. This result is the same as that in Fig. 2. The PL results shown are consistent, further demonstrating the effect of particle fluence on defects in β - Ga2O3 epitaxial wafers.
1.4、从silvaco TCAD半导体仿真软件的模拟实例中找到β-Ga2O3MOSFET模型,利用trap参数引入Vo、VGa2 1和No1-缺陷,其中语句中的e.level用来设置分立陷阱能级,degen.fac用来定义陷阱能级的退化因子,也可以用来计算密度,sign和sigp用来定义对于电子或空穴的陷阱捕获横截部分,输出引入缺陷前后β-Ga2O3 MOSFET模型的电化学性能曲线,如图4所示,其中,图4中a)为转移特性曲线,图4中b)为输出特性曲线。从图中可以看出,引入点缺陷后转移特性曲线出现了明显的负漂移,且No1-的漂移度明显大于VGa 1和Vo;另外,缺陷发生后,β-Ga2O3 MOSFET的输出特性明显提高,使β-Ga2O3 MOSFET器件可以在较低的栅极电压VGS下开启。1.4. Find the β-Ga 2 O 3 MOSFET model from the simulation example of silvaco TCAD semiconductor simulation software, and use trap parameters to introduce V o , V Ga2 1 and No 1- defects, where e.level in the statement is used to set discrete traps Energy level, degen.fac is used to define the degradation factor of the trap energy level, and can also be used to calculate the density, sign and sigp are used to define the trap trapping cross section for electrons or holes, and output β-Ga 2 O before and after the introduction of defects 3 The electrochemical performance curve of the MOSFET model is shown in Figure 4, where a) in Figure 4 is the transfer characteristic curve, and b) in Figure 4 is the output characteristic curve. It can be seen from the figure that the transfer characteristic curve has an obvious negative drift after the introduction of point defects, and the drift of No 1- is significantly larger than that of V Ga 1 and V o ; in addition, after the defect occurs, β-Ga 2 O 3 MOSFET The output characteristics of β-Ga 2
通过仿真模拟可以发现,点缺陷的引入对β-Ga2O3 MOSFET器件的电性能存在很大的负面影响,如降低阈值电压会增加器件的静态功耗,器件在一定幅度的VGS信号下本应处于关断状态,但在出现缺陷后可以开启,引起相关逻辑错误,增加泄露风险,甚至导致整个系统出现故障。Through simulation, it can be found that the introduction of point defects has a great negative impact on the electrical properties of β-Ga 2 O 3 MOSFET devices. For example, reducing the threshold voltage will increase the static power consumption of the device. It should be in the off state, but can be turned on after a defect occurs, causing related logic errors, increasing the risk of leakage, and even causing the entire system to fail.
因此,通过本发明实施例提供的重离子辐照影响β-Ga2O3 MOSFET器件电学性能的模拟方法可以得出由重离子辐照引起的点缺陷会导致β-Ga2O3MOSFET器件的阈值负向偏移,且外在缺陷No1-的影响最为严重,该模拟方法对β-Ga2O3 MOSFET器件电化学性能的研究和其在空间环境中的应用具有明显的作用。Therefore, according to the simulation method for the influence of heavy ion irradiation on the electrical performance of β-Ga 2 O 3 MOSFET device provided in the embodiment of the present invention, it can be concluded that the point defects caused by heavy ion irradiation will lead to the β-Ga 2 O 3 MOSFET device. The threshold value is negatively shifted, and the influence of the external defect No 1- is the most serious. The simulation method has obvious effects on the electrochemical performance of β-Ga 2 O 3 MOSFET devices and its application in space environment.
虽然本公开披露如上,但本公开的保护范围并非仅限于此。本领域技术人员在不脱离本公开的精神和范围的前提下,可进行各种变更与修改,这些变更与修改均将落入本发明的保护范围。Although the present disclosure is disclosed above, the scope of protection of the present disclosure is not limited thereto. Those skilled in the art can make various changes and modifications without departing from the spirit and scope of the present disclosure, and these changes and modifications will fall within the protection scope of the present invention.
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