Disclosure of Invention
The invention provides a cleaning agent for an airplane vacuum closestool system, which has good cleaning and removing effects on dirt in the airplane closestool system, does not cause adverse effects such as corrosion on various metal and nonmetal materials on an airplane and various coatings and surface treatment layers of the materials, and is safe and reliable; the cleaning agent can be used for cleaning toilets and pipelines in an airplane vacuum toilet system, meets the requirements of a plurality of airworthiness standards, and is safe, reliable and environment-friendly to use.
The technical scheme adopted by the invention for solving the technical problems is as follows: the cleaning agent for the airplane vacuum toilet system comprises the following components in percentage by mass: 5 to 20 percent of organic chelating agent, 0.2 to 3 percent of composite surfactant, 0.5 to 5 percent of corrosion inhibitor, 0.1 to 2 percent of other additives and the balance of pure water.
Further, the organic chelating agent is one or a mixture of more of diethylenetriaminepentaacetic acid, diethylenetriaminepentaacetic acid pentapotassium, dicarboxymethylalanine and dicarboxymethylalanine trisodium.
Further, the composite surfactant is a mixture of more than two of fatty alcohol polyoxyethylene ether AEO-9, isomeric tridecanol polyoxyethylene ether 1309, cocamidopropyl betaine and dodecyl dimethyl amine oxide.
Further, the corrosion inhibitor is one or a mixture of two of octyl phosphoric acid, decanoic acid and nonanoic acid.
Further, the other auxiliary agents comprise essence and pigment.
The invention has the advantages that: the invention provides a cleaning agent for an airplane vacuum toilet system, which has the following advantages:
the cleaning agent provided by the invention takes water as a solvent, is compounded by adopting a plurality of assistants such as an organic chelating agent, a composite surfactant, a corrosion inhibitor and the like, has good wall-hanging property, has good cleaning and removing effects on dirt in an airplane closestool system, does not cause adverse effects such as corrosion on various metal and nonmetal materials on an airplane and various coatings and surface treatment layers of the materials, and is safe and reliable; the effects of sterilization and bacteriostasis can be realized, fresh smell is released, and the environment is kept comfortable; the cleaning agent can be used for cleaning toilets and pipelines in an airplane vacuum toilet system, meets a plurality of seaworthiness standard requirements, and is safe, reliable and environment-friendly to use.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the accompanying drawings, and it should be understood that the described embodiments are some, but not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that unless otherwise explicitly specified or limited, the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of description and simplicity of description, and do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance, and the terms "mounted," "connected," and "connected" are to be construed broadly and may be, for example, fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Example 1:
the invention provides a cleaning agent for an airplane vacuum toilet system, which comprises the following components in percentage by mass: 10% of diethylenetriaminepentaacetic acid, 8% of dicarboxymethylalanine trisodium, 8% of fatty alcohol polyoxyethylene ether AEO-91%, 2% of cocamidopropyl betaine, 0.5% of octyl phosphoric acid, 0.1% of lemon essence, 0.01% of brilliant blue element and the balance of pure water, and the preparation method comprises the following steps: adding pure water into the reaction kettle at room temperature, and starting stirring; adding diethylenetriamine pentaacetic acid, dicarboxymethyl alanine trisodium, fatty alcohol polyoxyethylene ether AEO-9, cocamidopropyl betaine and octyl phosphoric acid into a reaction kettle in sequence and stirring until the materials are completely dissolved; and adding lemon essence and brilliant blue essence, and stirring uniformly to obtain the cleaning agent for the vacuum toilet system of the airplane, wherein the stirring speed of each step is 50-150 r/min, and the composite surfactant fatty alcohol-polyoxyethylene ether AEO-9 has the effect of reducing the surface tension, can accelerate the spreading speed of a chelating agent on scale, improves the scale dissolving speed, has the effect of emulsifying and cleaning organic oil stains, and improves the cleaning efficiency of the cleaning agent. The composite surfactant cocoamidopropyl betaine is a cationic surfactant, has the functions of sterilization and thickening, and endows the cleaning agent with certain viscosity and sterilization and bacteriostasis effects, and octyl phosphoric acid is a good corrosion inhibitor for metals such as aluminum alloy and the like, so that the metals are effectively protected.
Example 2:
the invention provides a cleaning agent for an airplane vacuum toilet system, which comprises the following components in percentage by mass: 5% of diethylenetriaminepentaacetic acid pentapotassium, 10% of dicarboxymethylalanine, 13091% of isomeric tridecanol polyoxyethylene ether, 2% of dodecyl dimethyl amine oxide, 3% of dodecanoic acid, 0.1% of lemon essence, 0.01% of brilliant blue pigment and the balance of water, and the preparation method comprises the following steps: adding pure water into the reaction kettle at room temperature, and starting stirring; adding diethylene triamine pentaacetic acid pentapotassium, dicarboxymethylalanine, isomeric tridecanol polyoxyethylene ether 1309 and dodecyl dimethyl amine oxide into a reaction kettle in sequence and stirring until the diethylene triamine pentaacetic acid pentapotassium, the dicarboxymethylalanine, the isomeric tridecanol polyoxyethylene ether and the dodecyl dimethyl amine oxide are completely dissolved; and adding lemon essence and brilliant blue essence, and stirring uniformly to obtain the cleaning agent for the vacuum toilet system of the airplane, wherein the stirring speed of each step is 50-150 r/min.
The cleaning agent of the invention adopts organic chelating agent (diethylenetriaminepentaacetic acid, dicarboxymethylalanine trisodium, etc.) which can effectively chelate and disperse dirt and dirt at the cleaned part. The chelating agent adopted by the invention has good safety to various materials of the airplane and better safety to personnel on the premise of ensuring a certain cleaning and descaling effect.
The proportion in the embodiment is determined after comprehensive testing of the using effect, the safety of the airplane material (qualified to be detected by airworthiness certification) and the stability of the product, and the corrosion degree of the embodiment of the invention to the metal and non-metal materials of the airplane is tested by a test center of the central office of civil aviation:
1. test of the Effect on rubber:
the results of tests carried out according to the standard test methods for rubber properties-liquid impact ASTM D471, using test pieces which meet the 3.2.3.6 standard for the American SAE Standard aerospace Material Standard SAE AMS1454, after 30 days of rubber retention in a stock solution of the cleaning agent sample at room temperature, are shown in the following table:
the test proves that the sample stock solution of the cleaning agent does not cause the phenomenon of staining, discoloring or obvious degradation of the test piece, and the performance of the test piece is not reduced.
2. Effect test on plastics
The test results after 30 days of retention of the plastics in the stock solution of the cleaning agent sample at room temperature using test pieces which meet 3.2.3.6 in the standard SAE standard aerospace Material Standard SAE AMS1454 are shown in the following table:
the test proves that the sample stock solution of the cleaning agent does not cause the test piece to have the phenomenon of color change or obvious degradation.
3. Adhesive force test of the adhesive tape: the test is carried out according to the standard requirement of ASTM D1000, the adhesive tape is soaked into the stock solution of the cleaning agent sample, the 180-degree peeling strength of the adhesive tape is reduced by 3.4 percent, and the edge of the adhesive tape is not warped.
The test results all meet the requirements of airworthiness standards, and the cleaning agent has good safety to the rubber material of the airplane body and can not corrode non-metallic materials on the airplane and various coatings and surface treatment layers of the materials.
4. Polycarbonate stress crazing test: the test is carried out according to the standard requirement of ASTM F484, a polycarbonate test piece which accords with AMS-P-83310 is used, the action is carried out for 30min +/-2 min under the external stress condition of 2000psi, and the test piece has no silver streak and no discoloration phenomenon under the soaking of a cleaning agent sample stock solution at the temperature of 25 +/-2 ℃.
5. Polyacrylate stress crazing test: the test is carried out according to the standard requirement of ASTM F484, a polyacrylate test piece which meets MIL-P-25690 is used, the test piece is acted for 8 hours under the external stress condition of 4500psi, and the original solution of the cleaning agent sample does not cause the test piece to generate silver streaks and discoloration.
The test shows that the polycarbonate and polyacrylate stress crazing test for the airplane is qualified, the test piece has no material crazing, and the cleaning agent has higher safety on the machine plastic material.
6. Storage stability test: the test was performed as per 3.2.1.2.1 in SAE AMS1454 and no skinning, precipitation or delamination of the cleaner sample stock occurred after five freeze-thaw cycles.
7. Temperature stability test: the test was carried out as required by 3.2.3.4 in SAE AMS1454, and no precipitation, delamination, or skinning occurred, and the original state was restored.
8. Accelerated stability testing: the test is carried out according to the standard requirement of ASTM F1104, the stock solution of the cleaning agent sample is kept for 15 days at minus 8 +/-2 ℃, then is taken out and kept for 15 days at 49 +/-10 ℃, and the sample does not have the phenomena of precipitation and delamination and can be restored to the original state.
According to the test results, the cleaning agent has good storage stability, temperature stability and acceleration stability, and all accord with the airworthiness standard.
Aircraft are special vehicles, and safety is the most important requirement. Various maintenance cleaning chemicals used on the airplane have special technical requirements, have essential difference with the traditional used toilet cleaning agent, and have detailed and strict airworthiness standard requirements, such as: boeing D6-17487T, SAE AMS1454A, etc., which give specific specifications for cleaning agents for aircraft toilets and their plumbing. As a cleaning agent for sewage pipeline maintenance, the cleaning agent has no corrosion or adverse effect on various metal and non-metal materials of a pipeline system, so as to ensure the safety and reliability of an airplane and meet the requirement of seaworthiness. Therefore, the cleaning agent has necessary corrosion inhibitor and protective agent to meet the safety requirement of the material, and the cleaning agent meets the airworthiness standard requirements of Boeing D6-17487T and SAE AMS1454A through the test of civil aviation departments, and the test mode is as follows:
interlayer corrosion test: the test was carried out as per ASTM F1110, using test pieces which should not corrode more than the water control board of ASTM D119 IV.
Test piece: a. a titanium alloy meeting the aerospace material standard SAE AMS 4911;
b. an aluminum alloy meeting the aerospace material standard SAE AMS 4049;
c. stainless steel meeting the aerospace material standard SAE AMS 5501;
d. carrying out anodic oxidation treatment on the aluminum alloy meeting the aerospace material standard SAE AMS4045 according to the aluminum anodic oxidation standard MIL-A-8625I type;
the test results are shown in the following table:
the tests show that the cleaning agent can not corrode titanium alloy, 4049 aluminum alloy, 5051 stainless steel and anodized 4049 aluminum alloy, and has good safety to various materials of airplanes;
the cleaning agents of the examples of the present invention were tested for performance according to the requirements of the American SAE Standard aerospace materials Standard SAE AMS1454A aviation Standard, with specific test results as shown in the following Table:
the cleaning agent has certain viscosity, certain retention time on the pipeline wall is ensured, meanwhile, the viscosity of the cleaning agent is not easy to be too high, so that the cleaning agent is adhered to the pipeline wall and is not easy to wash and measure, relevant data and standards are comprehensively referred, the viscosity is determined to be more appropriate between 450-plus-600 mPa & s, the examples 1 and 2 have more appropriate viscosity and good wall-hanging property, and the test results show that the descaling force of each example is more than 98%, so that the cleaning and removing effect is good;
the interlayer corrosion, the full immersion corrosion, the influence on the unpainted surface, the influence on the painted surface and the influence on rubber, the adhesive tape adhesion test, the polyacrylate stress crack and the polycarbonate stress crack of each embodiment of the invention are all qualified, and the cleaning agent has no adverse influence such as corrosion on metal and nonmetal materials of an airplane and a surface treatment layer, and is safe and reliable to use.
Therefore, the cleaning agent can be used in an airplane vacuum station system, particularly used for cleaning toilets and pipelines in an airplane vacuum toilet system, and has the advantages of good cleaning and descaling effects, safe and reliable use and environmental protection.
In order to achieve a good sterilization effect, the cocoamidopropyl betaine is added in the example 1, the component has low irritation and sterilization performance and obvious thickening performance, the sterilization effect can be effectively improved, the example 1 and a comparative example (the cocoamidopropyl betaine is not added, and the rest is consistent with the example) are prepared according to the effect, the sterilization and bacteriostasis effects of the cleaning agent are compared by adopting a bacteria testing sheet, and the specific antibacterial performance testing method comprises the following steps: the method adopts the German Shumei bacteria testing sheet to test the antibacterial performance of the mould and bacteria at the same time, and comprises the following specific steps: unscrewing a cover of a test tube to take out a test piece, taking toilet wastewater, respectively adding 5% of cleaning agents of the embodiment 1 and the comparative example, uniformly mixing, immersing the test piece into a preparation liquid for 1 minute, placing the test piece into the test tube, sealing the test tube, placing the test piece in the test tube at room temperature for 24 hours, observing the bacterial growth condition on the surface of the test piece, comparing the test pieces of the embodiment 1 and the comparative example simultaneously, and determining the order of magnitude of bacteria and mould, wherein the test piece is a cleaning agent test piece added with a cocamidopropyl betaine component in fig. 1, the test piece is a cleaning agent test piece without a cocamidopropyl betaine component in fig. 2, and the result is shown in fig. 1 and fig. 2.
Finally, it should be noted that: the above embodiments are only used to illustrate the technical solution of the present invention, and not to limit the same; while the invention has been described in detail and with reference to the foregoing embodiments, it will be understood by those skilled in the art that: the technical solutions described in the foregoing embodiments may still be modified, or some or all of the technical features may be equivalently replaced; and the modifications or the substitutions do not make the essence of the corresponding technical solutions depart from the scope of the technical solutions of the embodiments of the present invention.