CN115123456B - Installation method of underwater sightseeing window - Google Patents

Installation method of underwater sightseeing window Download PDF

Info

Publication number
CN115123456B
CN115123456B CN202210815770.6A CN202210815770A CN115123456B CN 115123456 B CN115123456 B CN 115123456B CN 202210815770 A CN202210815770 A CN 202210815770A CN 115123456 B CN115123456 B CN 115123456B
Authority
CN
China
Prior art keywords
window
parts
installation
adhesive
cover plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202210815770.6A
Other languages
Chinese (zh)
Other versions
CN115123456A (en
Inventor
李楚杰
吴廷光
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangdong K Link Ship And Boat Co ltd
Original Assignee
Guangdong K Link Ship And Boat Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangdong K Link Ship And Boat Co ltd filed Critical Guangdong K Link Ship And Boat Co ltd
Priority to CN202210815770.6A priority Critical patent/CN115123456B/en
Publication of CN115123456A publication Critical patent/CN115123456A/en
Application granted granted Critical
Publication of CN115123456B publication Critical patent/CN115123456B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B19/00—Arrangements or adaptations of ports, doors, windows, port-holes, or other openings or covers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B73/00—Building or assembling vessels or marine structures, e.g. hulls or offshore platforms
    • B63B73/40—Building or assembling vessels or marine structures, e.g. hulls or offshore platforms characterised by joining methods
    • B63B73/46—Gluing; Taping; Cold-bonding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B63—SHIPS OR OTHER WATERBORNE VESSELS; RELATED EQUIPMENT
    • B63B—SHIPS OR OTHER WATERBORNE VESSELS; EQUIPMENT FOR SHIPPING 
    • B63B73/00—Building or assembling vessels or marine structures, e.g. hulls or offshore platforms
    • B63B73/40—Building or assembling vessels or marine structures, e.g. hulls or offshore platforms characterised by joining methods
    • B63B73/49—Building or assembling vessels or marine structures, e.g. hulls or offshore platforms characterised by joining methods by means of threaded members, e.g. screws, threaded bolts or nuts
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/12—Ships
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00—Adapting or protecting infrastructure or their operation
    • Y02A30/24—Structural elements or technologies for improving thermal insulation
    • Y02A30/249—Glazing, e.g. vacuum glazing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00—Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/22—Glazing, e.g. vaccum glazing

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Ocean & Marine Engineering (AREA)
  • Architecture (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention relates to the technical field of glass windows, in particular to an installation method of an underwater sightseeing window, which comprises the following steps of: s1, uniformly drilling bolt holes on a window frame and a cover plate of a hull mechanism; s2, altering the silane structural adhesive at the window frame of the hull mechanism before installation; s3, after installation, compacting the bulletproof glass window by using a temporary pressing block, filling the corner joint between the bulletproof glass window edge and the window frame with modified silane structural adhesive, placing for 3-5 days after finishing the adhesive, and coating a thin adhesive layer on the outer surface of the bulletproof glass window after the adhesive is solidified; s4, finally closing the cover plate, fixing the cover plate and the window frame through lock bolts screwed in the bolt holes, finishing installation, and detecting air tightness. The underwater sightseeing window replaces the conventional toughened laminated glass with the novel bulletproof glass window layer, optimizes and improves the original single adhesive fixing mode, and solves the potential safety hazard of the underwater sightseeing window.

Description

Installation method of underwater sightseeing window
Technical Field
The invention relates to the technical field of glass windows, in particular to an installation method of an underwater sightseeing window.
Background
The underwater sightseeing window is used for two sides of a ship cabin, the high-light-transmittance toughened laminated glass is adopted, passengers can see through the sightseeing window to see through the underwater sightseeing, the toughened laminated glass of the sightseeing window is widely applied to the fields of buildings, automobiles, ships, aviation and the like, the existing laminated glass of the sightseeing window is mainly two layers and is mainly used above a ship waterline, the adhesive is adopted for fixation, and the type and the installation of the sightseeing window have the following defects:
1. the conventional two-layer toughened laminated glass is not suitable for underwater sightseeing ships, the thickness of the glass is insufficient to bear underwater pressure for a long time, the glass is easy to break, water is introduced into a passenger cabin, and the ship operation is dangerous;
2. the conventional mounting mode of sightseeing window is fixed for the viscose, and this kind of mounting mode is too single, considers boats and ships and can have the corruption at long-term operation in-process sightseeing window viscose, and the sightseeing window can bond infirm in case corrode under water, and the passenger cabin can intake, can cause very big hidden danger for operation safety like this.
Disclosure of Invention
In order to overcome the defects and shortcomings in the prior art, the invention aims to provide an installation method of an underwater sightseeing window, wherein a novel bulletproof glass window layer is used for replacing conventional toughened laminated glass, an original single adhesive fixing mode is optimized and improved, the glass is large in thickness and good in strength, the light transmittance is extremely high, and meanwhile, the potential safety hazard of the underwater sightseeing window is solved after the installation fixing mode is optimized.
The aim of the invention is achieved by the following technical scheme: the installation method of the underwater sightseeing window comprises the sightseeing window, wherein the sightseeing window comprises a window frame, a cover plate and a bulletproof glass window, and the bulletproof glass window comprises a first glass layer, a first PVB interlayer, a second glass layer, a second PVB interlayer and a third glass layer which are sequentially pressed together;
the sightseeing window installation method comprises the following steps:
s1, uniformly drilling bolt holes on a window frame and a cover plate of a hull mechanism;
s2, altering the silane structural adhesive at the window frame of the hull mechanism before installation;
s3, after installation, compacting the bulletproof glass window by using a temporary pressing block, filling the corner joint between the bulletproof glass window edge and the window frame with modified silane structural adhesive, placing for 3-5 days after finishing the adhesive, and coating a thin adhesive layer on the outer surface of the bulletproof glass window after the adhesive is solidified;
s4, finally closing the cover plate, and fixing the cover plate and the window frame through a lock bolt which is screwed in the bolt hole to finish the installation;
s5, finally, detecting the air tightness of the sightseeing window after the installation.
The underwater sightseeing window replaces the conventional toughened laminated glass with the novel bulletproof glass window layer, optimizes and improves the original single viscose glue fixing mode, and the glass of the type has large thickness, good strength and extremely high light transmittance, and solves the potential safety hazard of the underwater sightseeing window after the fixing mode is optimized. In the installation process of the sightseeing window, a frame is required to be welded around the installation opening of the sightseeing window and used as a window frame of the sightseeing window, and enough gaps are reserved between the window frame and the opening edge of the window so as to ensure the lap joint strength of the sightseeing window; the method comprises the steps of firstly tapping bolt holes on a window frame of a ship body mechanism so as to be fixed with a cover plate lock bolt at the later stage, prefabricating an outer cover plate of the sightseeing window in advance, and tapping the bolt holes on the cover plate so as to be fixed with the window frame lock bolt at the later stage; and after the sightseeing window is installed, a cover plate is installed around the outer surface, and the cover plate and the window frame are fixed by bolts, so that the installation stability and air tightness of the sightseeing window can be further improved.
Preferably, the thickness of the second glass layer and the third glass layer of the first glass layer is 13-17mm.
Preferably, the first PVB interlayer and the second PVB interlayer have a thickness of from 2.56mm to 2.96mm.
According to the invention, the structural strength of the bulletproof glass window can be further improved by controlling the thicknesses of the second glass layer and the third glass layer of the first glass layer and the first PVB interlayer and the second PVB interlayer, so that the sightseeing window with the bulletproof function is obtained.
Preferably, the modified silane structural adhesive comprises the following raw materials in parts by weight: 20-40 parts of matrix resin, 4-8 parts of MS polymer, 10-15 parts of plasticizer, 1-5 parts of graphene oxide, 1-3 parts of coupling agent, 1-3 parts of adhesion promoter, 0.5-1.5 parts of water scavenger, 1-5 parts of filler and 2-6 parts of polytetrafluoroethylene micro powder wax; the MS polymer is preferably SAT350 manufactured by KaNEKA corporation of Japan.
The modified silane structural adhesive is prepared from the raw materials, has good adhesion, elasticity, strength, tensile strength and elongation at break, has ultraviolet resistance, ageing resistance and stable performance, is non-sticky on the surface after solidification, and has very good elastic recovery rate. The graphene oxide adopted improves the tensile strength and tensile shear strength of the modified silane structural adhesive; the added filler and polytetrafluoroethylene micro powder wax can further assist in improving the performances of wear resistance, water resistance, solvent resistance, weather resistance and the like of the modified silane structural adhesive, and the adopted MS polymer has good adhesion capability to metal and plastic base materials, has no side effect on artificial health, and has lasting adhesion strength and good weather resistance.
Preferably, the matrix resin is one or more of polyester resin, organosilicon modified polyester resin, acrylic resin, organosilicon modified acrylic resin, silane modified polyether resin and organosilicon modified alkyd resin.
Preferably, the plasticizer is one or more of phthalate, diphenyl isodecyl phosphate, aliphatic diacid ester and pentadecyl phenyl sulfonate; the coupling agent is epoxy silane coupling agent 6040.
Preferably, the adhesion promoter is a mixture of gamma-aminopropyl triethoxysilane, N-phenyl-gamma-aminopropyl trimethoxysilane and gamma-mercaptopropyl trimethoxysilane in a weight ratio of 0.6-1.0:0.8-1.2:0.4-0.8.
The adhesion promoter with the specific composition can effectively improve the adhesion on various base materials, greatly increase the adhesion fastness and has good effect. Has good bonding effect on matrix resin.
Preferably, the water scavenger is one or more of vinyl trimethoxy silane, anhydrous calcium chloride, calcium oxide, trimethyl orthoformate, trimethyl orthoacetate and vinyl trimethoxy silane.
Preferably, the filler is one or more of aluminum hydroxide, magnesium hydroxide, antimony trioxide, calcium carbonate and stannous octoate; more preferably, the filler is a mixture of aluminum hydroxide, calcium carbonate and stannous octoate in a weight ratio of 0.8-1.2:0.6-1.0:0.4-0.8.
The self-adsorption moisture in the filler with the specific proportion adopted in the invention can realize synchronous solidification inside and outside the colloid, has the advantage of quick deep solidification, reduces the density and improves the fluidity of the sealant.
Preferably, the modified silane structural adhesive is prepared by the following steps:
1) Adding matrix resin and MS polymer into a reaction kettle according to parts by weight, heating to 90-95 ℃ and vacuumizing, and controlling the vacuum pressure to be 0.06-0.1MPa for later use;
2) Adding a plasticizer and a water scavenger into the reaction kettle in the step 1), drying at 80-100 ℃, cooling to 50 ℃, adding graphene oxide, a coupling agent, a filler and polytetrafluoroethylene micro powder wax, mixing and stirring, and continuously stirring under a vacuum condition to obtain a mixture for later use;
3) And (2) adding an adhesion promoter into the mixture obtained in the step (2), stirring under vacuum, cooling, returning nitrogen, and discharging from a kettle to obtain the modified silane structural adhesive.
The modified silane structural adhesive is prepared by the method, and the modified silane structural adhesive prepared by the method has the performances of tensile stress, elongation at break, shear strength, ultraviolet resistance and aging resistance. The vacuum pressure in the step 1) needs to be strictly controlled in the preparation process, so that the dispersion and mixing of the matrix resin and the MS polymer can be well ensured, meanwhile, the infiltration of moisture in the air can be effectively reduced, and the comprehensive performance of the finally prepared modified silane structural adhesive is ensured.
The invention has the beneficial effects that: the underwater sightseeing window replaces the conventional toughened laminated glass with the novel bulletproof glass window layer, optimizes and improves the original single viscose glue fixing mode, and the glass of the type has large thickness, good strength and extremely high light transmittance, and solves the potential safety hazard of the underwater sightseeing window after the fixing mode is optimized.
Drawings
FIG. 1 is a schematic cross-sectional view of a sightseeing window mounting node of the present invention;
FIG. 2 is a schematic cross-sectional view of another mounting node of the sightseeing window of the present invention;
FIG. 3 is a test chart of the air tightness detection of the sightseeing window of the present invention.
The reference numerals are: 1-sightseeing window, 11-window frame, 12-apron, 13-bullet-proof glass window, 131-first glass layer, 132-first PVB intermediate layer, 133-second glass layer, 134-second PVB intermediate layer, 135-third glass layer, 2-box, 3-hose, 4-shrouding, 5-reinforced flat aluminum, 6-hull mechanism, 7-modified silane structural adhesive, 8-thin adhesive, 9-locking bolt, 10-water filling port.
Detailed Description
The present invention is further described below with reference to examples and figures 1-3, which are not intended to be limiting, for the purpose of facilitating understanding of those skilled in the art.
Example 1
The installation method of the underwater sightseeing window comprises a sightseeing window 1, wherein the sightseeing window 1 comprises a window frame 11, a cover plate 12 and a bulletproof glass window 13, and the bulletproof glass window 13 comprises a first glass layer 131, a first PVB interlayer 132, a second glass layer 133, a second PVB interlayer 134 and a third glass layer 135 which are sequentially pressed together;
the sightseeing window 1 installing method comprises the following steps:
s1, uniformly drilling bolt holes on a window frame 11 and a cover plate 12 of a ship body mechanism 6;
s2, altering the silane structural adhesive 7 at the window frame 11 of the hull mechanism 6 before installation;
s3, after installation, firstly compacting the bulletproof glass window 13 by using a temporary pressing block, then filling the corner joint between the side of the bulletproof glass window 13 and the window frame 11 with modified silane structural adhesive, after finishing the adhesive, firstly standing for 3 days, and after the adhesive is solidified, coating a thin adhesive layer 8 on the outer surface of the bulletproof glass window 13;
s4, finally closing the cover plate 12, and fixing the cover plate 12 and the window frame 11 through a lock bolt 9 which is screwed in the bolt hole to finish the installation;
s5, finally, detecting the air tightness of the sightseeing window 1 after the installation is finished.
The thickness of the first glass layer 131, the second glass layer 133 and the third glass layer 135 is 13mm.
The thickness of the first PVB interlayer 132 and the second PVB interlayer 134 is 2.56mm.
The modified silane structural adhesive comprises the following raw materials in parts by weight: 20 parts of matrix resin, 4 parts of MS polymer, 10 parts of plasticizer, 1 part of graphene oxide, 1 part of coupling agent, 1 part of adhesion promoter, 0.5 part of water scavenger, 1 part of filler and 2 parts of polytetrafluoroethylene micro powder wax; the MS polymer is preferably SAT350 produced by KaNEKA corporation of Japan, and the polytetrafluoroethylene micro powder wax is 3920F, which is supplied by Shanghai's new material Co., ltd.
The matrix resin is polyester resin. The plasticizer is phthalate; the coupling agent is epoxy silane coupling agent 6040.
The adhesion promoter is a mixture composed of gamma-aminopropyl triethoxysilane, N-phenyl-gamma-aminopropyl trimethoxysilane and gamma-mercaptopropyl trimethoxysilane according to the weight ratio of 0.6:0.8:0.4.
The water scavenger is vinyl trimethoxy silane. The filler is a mixture of aluminum hydroxide, calcium carbonate and stannous octoate according to the weight ratio of 0.8:0.6:0.4.
The modified silane structural adhesive is prepared by the following steps:
1) Adding matrix resin and MS polymer into a reaction kettle according to parts by weight, heating to 90 ℃ and vacuumizing, and controlling the vacuum pressure to be 0.06MPa for later use;
2) Adding a plasticizer and a water scavenger into the reaction kettle in the step 1), drying at 80 ℃, cooling to 50 ℃, adding graphene oxide, a coupling agent, a filler and polytetrafluoroethylene micro powder wax, mixing and stirring, and continuously stirring under a vacuum condition to obtain a mixture for later use;
3) And (2) adding an adhesion promoter into the mixture obtained in the step (2), stirring under vacuum, cooling, returning nitrogen, and discharging from a kettle to obtain the modified silane structural adhesive.
Example 2
The installation method of the underwater sightseeing window comprises a sightseeing window 1, wherein the sightseeing window 1 comprises a window frame 11, a cover plate 12 and a bulletproof glass window 13, and the bulletproof glass window 13 comprises a first glass layer 131, a first PVB interlayer 132, a second glass layer 133, a second PVB interlayer 134 and a third glass layer 135 which are sequentially pressed together;
the sightseeing window 1 installing method comprises the following steps:
s1, uniformly drilling bolt holes on a window frame 11 and a cover plate 12 of a ship body mechanism 6;
s2, altering the silane structural adhesive 7 at the window frame 11 of the hull mechanism 6 before installation;
s3, after installation, firstly compacting the bulletproof glass window 13 by using a temporary pressing block, then filling the corner joint between the side of the bulletproof glass window 13 and the window frame 11 with modified silane structural adhesive, after finishing the adhesive, firstly standing for 3 days, and after the adhesive is solidified, coating a thin adhesive layer 8 on the outer surface of the bulletproof glass window 13;
s4, finally closing the cover plate 12, and fixing the cover plate 12 and the window frame 11 through a lock bolt 9 which is screwed in the bolt hole to finish the installation;
s5, finally, detecting the air tightness of the sightseeing window 1 after the installation is finished.
The thickness of the first glass layer 131, the second glass layer 133 and the third glass layer 135 was 14mm.
The thickness of the first PVB interlayer 132 and the second PVB interlayer 134 is 2.66mm.
The modified silane structural adhesive comprises the following raw materials in parts by weight: 25 parts of matrix resin, 5 parts of MS polymer, 11 parts of plasticizer, 2 parts of graphene oxide, 1.5 parts of coupling agent, 1.5 parts of adhesion promoter, 0.8 part of water scavenger, 2 parts of filler and 3 parts of polytetrafluoroethylene micro powder wax; the MS polymer is preferably SAT350 produced by KaNEKA corporation of Japan, and the polytetrafluoroethylene micro powder wax is 3920F, which is supplied by Shanghai's new material Co., ltd.
The matrix resin is acrylic resin. The plasticizer is diphenyl isodecyl phosphate; the coupling agent is epoxy silane coupling agent 6040.
The adhesion promoter is a mixture composed of gamma-aminopropyl triethoxysilane, N-phenyl-gamma-aminopropyl trimethoxysilane and gamma-mercaptopropyl trimethoxysilane according to the weight ratio of 0.7:0.9:0.5.
The water scavenger is anhydrous calcium chloride.
The filler is a mixture of aluminum hydroxide, calcium carbonate and stannous octoate according to the weight ratio of 0.9:0.7:0.5.
The modified silane structural adhesive is prepared by the following steps:
1) Adding matrix resin and MS polymer into a reaction kettle according to parts by weight, heating to 92 ℃ and vacuumizing, and controlling the vacuum pressure to be 0.07MPa for later use;
2) Adding a plasticizer and a water scavenger into the reaction kettle in the step 1), drying at 85 ℃, cooling to 50 ℃, adding graphene oxide, a coupling agent, a filler and polytetrafluoroethylene micro powder wax, mixing and stirring, and continuously stirring under a vacuum condition to obtain a mixture for later use;
3) And (2) adding an adhesion promoter into the mixture obtained in the step (2), stirring under vacuum, cooling, returning nitrogen, and discharging from a kettle to obtain the modified silane structural adhesive.
Example 3
The installation method of the underwater sightseeing window comprises a sightseeing window 1, wherein the sightseeing window 1 comprises a window frame 11, a cover plate 12 and a bulletproof glass window 13, and the bulletproof glass window 13 comprises a first glass layer 131, a first PVB interlayer 132, a second glass layer 133, a second PVB interlayer 134 and a third glass layer 135 which are sequentially pressed together;
the sightseeing window 1 installing method comprises the following steps:
s1, uniformly drilling bolt holes on a window frame 11 and a cover plate 12 of a ship body mechanism 6;
s2, altering the silane structural adhesive 7 at the window frame 11 of the hull mechanism 6 before installation;
s3, after installation, firstly compacting the bulletproof glass window 13 by using a temporary pressing block, then filling the corner joint between the side of the bulletproof glass window 13 and the window frame 11 with modified silane structural adhesive, after finishing the adhesive, firstly placing for 4 days, and after the adhesive is solidified, coating a thin adhesive layer 8 on the outer surface of the bulletproof glass window 13;
s4, finally closing the cover plate 12, and fixing the cover plate 12 and the window frame 11 through a lock bolt 9 which is screwed in the bolt hole to finish the installation;
s5, finally, detecting the air tightness of the sightseeing window 1 after the installation is finished; specifically, after all the sightseeing window 1 is installed according to the procedure, the installation tightness of the sightseeing window 1 is verified according to the attached figure 3, the sightseeing window 1 is under water for 1m, the tightness test is carried out according to 5 times of the actual pressure, the whole sealing plate 4 is firstly arranged at the peripheral structure of the inner surface of the sightseeing window 1 to form a closed box body 2, the sealing plate 4 is additionally provided with a reinforced flat aluminum 5, meanwhile, a hose 3 with the length of 5 meters is installed on the box body 2, the test is started by injecting water into the box body 2 through the water filling port 10, the water leakage and the phenomenon outside the sightseeing window 1 are checked in the test process, the pressure is stabilized for 10 minutes after the water overflows from the water outlet pipe in the box body 2, the test is ended if the water leakage phenomenon is not generated in the time, and the installation of the sightseeing window 1 is according to the operation requirement.
The thickness of the first glass layer 131, the second glass layer 133 and the third glass layer 135 is 15mm.
The thickness of the first PVB interlayer 132 and the second PVB interlayer 134 is 2.76mm.
The modified silane structural adhesive comprises the following raw materials in parts by weight: 30 parts of matrix resin, 6 parts of MS polymer, 13 parts of plasticizer, 3 parts of graphene oxide, 2 parts of coupling agent, 2 parts of adhesion promoter, 1.0 part of water scavenger, 3 parts of filler and 4 parts of polytetrafluoroethylene micro powder wax; the MS polymer is preferably SAT350 produced by KaNEKA corporation of Japan, and the polytetrafluoroethylene micro powder wax is 3920F, which is supplied by Shanghai's new material Co., ltd.
The matrix resin is polyester resin. The plasticizer is pentadecyl sulfophenyl ester; the coupling agent is epoxy silane coupling agent 6040.
The adhesion promoter is a mixture composed of gamma-aminopropyl triethoxysilane, N-phenyl-gamma-aminopropyl trimethoxysilane and gamma-mercaptopropyl trimethoxysilane according to the weight ratio of 0.8:1.0:0.6.
The water scavenger is calcium oxide. The filler is a mixture of aluminum hydroxide, calcium carbonate and stannous octoate according to the weight ratio of 1.0:0.8:0.6.
The modified silane structural adhesive is prepared by the following steps:
1) Adding matrix resin and MS polymer into a reaction kettle according to parts by weight, heating to 93 ℃, vacuumizing, and controlling the vacuum pressure to be 0.08MPa for later use;
2) Adding a plasticizer and a water scavenger into the reaction kettle in the step 1), drying at 90 ℃, cooling to 50 ℃, adding graphene oxide, a coupling agent, a filler and polytetrafluoroethylene micro powder wax, mixing and stirring, and continuously stirring under a vacuum condition to obtain a mixture for later use;
3) And (2) adding an adhesion promoter into the mixture obtained in the step (2), stirring under vacuum, cooling, returning nitrogen, and discharging from a kettle to obtain the modified silane structural adhesive.
Example 4
The installation method of the underwater sightseeing window comprises a sightseeing window 1, wherein the sightseeing window 1 comprises a window frame 11, a cover plate 12 and a bulletproof glass window 13, and the bulletproof glass window 13 comprises a first glass layer 131, a first PVB interlayer 132, a second glass layer 133, a second PVB interlayer 134 and a third glass layer 135 which are sequentially pressed together;
the sightseeing window 1 installing method comprises the following steps:
s1, uniformly drilling bolt holes on a window frame 11 and a cover plate 12 of a ship body mechanism 6;
s2, altering the silane structural adhesive 7 at the window frame 11 of the hull mechanism 6 before installation;
s3, after installation, firstly compacting the bulletproof glass window 13 by using a temporary pressing block, then filling the corner joint between the side of the bulletproof glass window 13 and the window frame 11 with modified silane structural adhesive, after finishing the adhesive, firstly placing for 4 days, and after the adhesive is solidified, coating a thin adhesive layer 8 on the outer surface of the bulletproof glass window 13;
s4, finally closing the cover plate 12, and fixing the cover plate 12 and the window frame 11 through a lock bolt 9 which is screwed in the bolt hole to finish the installation;
s5, finally, detecting the air tightness of the sightseeing window 1 after the installation is finished.
The thickness of the first glass layer 131, the second glass layer 133 and the third glass layer 135 was 16mm.
The thickness of the first PVB interlayer 132 and the second PVB interlayer 134 is 2.86mm.
The modified silane structural adhesive comprises the following raw materials in parts by weight: 35 parts of matrix resin, 7 parts of MS polymer, 14 parts of plasticizer, 4 parts of graphene oxide, 2.5 parts of coupling agent, 2.5 parts of adhesion promoter, 1.3 parts of water scavenger, 4 parts of filler and 5 parts of polytetrafluoroethylene micro powder wax; the MS polymer is preferably SAT350 produced by KaNEKA corporation of Japan, and the polytetrafluoroethylene micro powder wax is 3920F, which is supplied by Shanghai's new material Co., ltd.
The matrix resin is polyester resin. The plasticizer is phthalate; the coupling agent is epoxy silane coupling agent 6040.
The adhesion promoter is a mixture composed of gamma-aminopropyl triethoxysilane, N-phenyl-gamma-aminopropyl trimethoxysilane and gamma-mercaptopropyl trimethoxysilane according to the weight ratio of 0.9:1.1:0.7.
The water scavenger is vinyl trimethoxy silane. The filler is a mixture of aluminum hydroxide, calcium carbonate and stannous octoate according to the weight ratio of 1.1:0.9:0.7.
The modified silane structural adhesive is prepared by the following steps:
1) Adding matrix resin and MS polymer into a reaction kettle according to parts by weight, heating to 94 ℃, vacuumizing, and controlling the vacuum pressure to be 0.09MPa for later use;
2) Adding a plasticizer and a water scavenger into the reaction kettle in the step 1), drying at 95 ℃, cooling to 50 ℃, adding graphene oxide, a coupling agent, a filler and polytetrafluoroethylene micro powder wax, mixing and stirring, and continuously stirring under a vacuum condition to obtain a mixture for later use;
3) And (2) adding an adhesion promoter into the mixture obtained in the step (2), stirring under vacuum, cooling, returning nitrogen, and discharging from a kettle to obtain the modified silane structural adhesive.
Example 5
The installation method of the underwater sightseeing window comprises a sightseeing window 1, wherein the sightseeing window 1 comprises a window frame 11, a cover plate 12 and a bulletproof glass window 13, and the bulletproof glass window 13 comprises a first glass layer 131, a first PVB interlayer 132, a second glass layer 133, a second PVB interlayer 134 and a third glass layer 135 which are sequentially pressed together;
the sightseeing window 1 installing method comprises the following steps:
s1, uniformly drilling bolt holes on a window frame 11 and a cover plate 12 of a ship body mechanism 6;
s2, altering the silane structural adhesive 7 at the window frame 11 of the hull mechanism 6 before installation;
s3, after installation, firstly compacting the bulletproof glass window 13 by using a temporary pressing block, then filling the corner joint between the side of the bulletproof glass window 13 and the window frame 11 with modified silane structural adhesive, after finishing the adhesive, firstly standing for 5 days, and after the adhesive is solidified, coating a thin adhesive layer 8 on the outer surface of the bulletproof glass window 13;
s4, finally closing the cover plate 12, and fixing the cover plate 12 and the window frame 11 through a lock bolt 9 which is screwed in the bolt hole to finish the installation;
s5, finally, detecting the air tightness of the sightseeing window 1 after the installation is finished.
The thickness of the first glass layer 131, the second glass layer 133 and the third glass layer 135 was 17mm.
The thickness of the first PVB interlayer 132 and the second PVB interlayer 134 is 2.96mm.
The modified silane structural adhesive comprises the following raw materials in parts by weight: 40 parts of matrix resin, 8 parts of MS polymer, 15 parts of plasticizer, 5 parts of graphene oxide, 3 parts of coupling agent, 3 parts of adhesion promoter, 1.5 parts of water scavenger, 5 parts of filler and 6 parts of polytetrafluoroethylene micro powder wax; the MS polymer is preferably SAT350 produced by KaNEKA corporation of Japan, and the polytetrafluoroethylene micro powder wax is 3920F, which is supplied by Shanghai's new material Co., ltd.
The matrix resin is polyester resin. The plasticizer is phthalate; the coupling agent is epoxy silane coupling agent 6040.
The adhesion promoter is a mixture composed of gamma-aminopropyl triethoxysilane, N-phenyl-gamma-aminopropyl trimethoxysilane and gamma-mercaptopropyl trimethoxysilane according to the weight ratio of 1.0:1.2:0.8.
The water scavenger is vinyl trimethoxy silane.
The filler is a mixture of aluminum hydroxide, calcium carbonate and stannous octoate according to the weight ratio of 1.2:1.0:0.8.
The modified silane structural adhesive is prepared by the following steps:
1) Adding matrix resin and MS polymer into a reaction kettle according to parts by weight, heating to 95 ℃ and vacuumizing, and controlling the vacuum pressure to be 0.1MPa for later use;
2) Adding a plasticizer and a water scavenger into the reaction kettle in the step 1), drying at 100 ℃, cooling to 50 ℃, adding graphene oxide, a coupling agent, a filler and polytetrafluoroethylene micro powder wax, mixing and stirring, and continuously stirring under a vacuum condition to obtain a mixture for later use;
3) And (2) adding an adhesion promoter into the mixture obtained in the step (2), stirring under vacuum, cooling, returning nitrogen, and discharging from a kettle to obtain the modified silane structural adhesive.
Comparative example 1
This comparative example differs from example 1 described above in that: in this comparative example, a commercially available epoxy polymeric gum was used in place of the modified silane structural gum. The remainder of this comparative example is the same as in example 1 and will not be described here again.
Comparative example 2
This comparative example differs from example 3 above in that: MS polymer and polytetrafluoroethylene micro powder wax are not added into the raw materials of the modified silane structural adhesive of the comparative example. The remainder of this comparative example is the same as in example 3 and will not be described here again.
The modified silane structural adhesives prepared in comparative examples 2 of examples 1, 3 and 5 were tested for properties and the results are shown in Table 1:
the products prepared in the above example one, comparative example one and comparative example two were subjected to experimental determination of tensile strength and elongation at break, respectively, and tested as follows.
Tensile strength was evaluated according to GB/T528;
elongation at break was evaluated according to GB/T529;
shear strength was evaluated according to GB/T7124;
the elastic recovery rate was evaluated according to GB/T13477-2002;
the tack-free time was evaluated according to GB/T528 under a test environment of 20deg.C, 50% relative humidity;
shore A hardness was evaluated according to GB/T531;
tear strength was evaluated according to GB/T529.
TABLE 1
Project Example 1 Example 3 Example 5 Comparative example 2
Tensile Strength (MPa) 2 2.2 2.1 1.7
Elongation at break (%) 400 410 405 356
Shear strength (MPa) 2.5 2.7 2.6 1.8
Elastic recovery rate (%) 92 91 90 76
Time of surface drying (min) 42 43 40 70
Shore A hardness 45 43 44 40
Tear strength (N/mm) 15 16 15 12
From the above table, in examples 1, 3 and 5, the modified silane structural adhesive has good structural strength and mechanical properties, and the modified silane structural adhesive prepared by adding MS polymer and polytetrafluoroethylene micro powder wax has better comprehensive properties.
The above embodiments are preferred embodiments of the present invention, and besides, the present invention may be implemented in other ways, and any obvious substitution is within the scope of the present invention without departing from the concept of the present invention.

Claims (7)

1. The installation method of the underwater sightseeing window comprises the sightseeing window and is characterized in that: the sightseeing window comprises a window frame, a cover plate and a bulletproof glass window, wherein the bulletproof glass window comprises a first glass layer, a first PVB interlayer, a second glass layer, a second PVB interlayer and a third glass layer which are sequentially pressed together;
the sightseeing window installation method comprises the following steps:
s1, uniformly drilling bolt holes on a window frame and a cover plate of a hull mechanism;
s2, altering the silane structural adhesive at the window frame of the hull mechanism before installation;
s3, after installation, compacting the bulletproof glass window by using a temporary pressing block, filling the corner joint between the bulletproof glass window edge and the window frame with modified silane structural adhesive, placing for 3-5 days after finishing the adhesive, and coating a thin adhesive layer on the outer surface of the bulletproof glass window after the adhesive is solidified;
s4, finally closing the cover plate, and fixing the cover plate and the window frame through a lock bolt which is screwed in the bolt hole to finish the installation;
s5, finally, detecting the air tightness of the sightseeing window after the installation;
the modified silane structural adhesive comprises the following raw materials in parts by weight: 20-40 parts of matrix resin, 4-8 parts of MS polymer, 10-15 parts of plasticizer, 1-5 parts of graphene oxide, 1-3 parts of coupling agent, 1-3 parts of adhesion promoter, 0.5-1.5 parts of water scavenger, 1-5 parts of filler and 2-6 parts of polytetrafluoroethylene micro powder wax;
the adhesion promoter is a mixture composed of gamma-aminopropyl triethoxysilane, N-phenyl-gamma-aminopropyl trimethoxysilane and gamma-mercaptopropyl trimethoxysilane according to the weight ratio of 0.6-1.0:0.8-1.2:0.4-0.8;
the modified silane structural adhesive is prepared by the following steps:
1) Adding matrix resin and MS polymer into a reaction kettle according to parts by weight, heating to 90-95 ℃ and vacuumizing, and controlling the vacuum pressure to be 0.06-0.1MPa for later use;
2) Adding a plasticizer and a water scavenger into the reaction kettle in the step 1), drying at 80-100 ℃, cooling to 50 ℃, adding graphene oxide, a coupling agent, a filler and polytetrafluoroethylene micro powder wax, mixing and stirring, and continuously stirring under a vacuum condition to obtain a mixture for later use;
3) And (2) adding an adhesion promoter into the mixture obtained in the step (2), stirring under vacuum, cooling, returning nitrogen, and discharging from a kettle to obtain the modified silane structural adhesive.
2. The method for installing an underwater sightseeing window according to claim 1, wherein: the thicknesses of the first glass layer, the second glass layer and the third glass layer are 13-17mm.
3. The method for installing an underwater sightseeing window according to claim 1, wherein: the thickness of the first PVB interlayer and the second PVB interlayer is 2.56-2.96mm.
4. The method for installing an underwater sightseeing window according to claim 1, wherein: the matrix resin is one or more of polyester resin, organic silicon modified polyester resin, acrylic resin, organic silicon modified acrylic resin, silane modified polyether resin and organic silicon modified alkyd resin.
5. The method for installing an underwater sightseeing window according to claim 1, wherein: the plasticizer is one or more of phthalate, diphenyl isodecyl phosphate, aliphatic diacid esters and pentadecyl phenyl sulfonate; the coupling agent is an epoxy silane coupling agent.
6. The method for installing an underwater sightseeing window according to claim 1, wherein: the water scavenger is one or more of vinyl trimethoxy silane, anhydrous calcium chloride, calcium oxide, trimethyl orthoformate, trimethyl orthoacetate and vinyl trimethoxy silane.
7. The method for installing an underwater sightseeing window according to claim 1, wherein: the filler is one or more of aluminum hydroxide, magnesium hydroxide, antimony trioxide, calcium carbonate and stannous octoate.
CN202210815770.6A 2022-07-12 2022-07-12 Installation method of underwater sightseeing window Active CN115123456B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210815770.6A CN115123456B (en) 2022-07-12 2022-07-12 Installation method of underwater sightseeing window

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210815770.6A CN115123456B (en) 2022-07-12 2022-07-12 Installation method of underwater sightseeing window

Publications (2)

Publication Number Publication Date
CN115123456A CN115123456A (en) 2022-09-30
CN115123456B true CN115123456B (en) 2024-04-05

Family

ID=83383530

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210815770.6A Active CN115123456B (en) 2022-07-12 2022-07-12 Installation method of underwater sightseeing window

Country Status (1)

Country Link
CN (1) CN115123456B (en)

Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1594480A (en) * 2004-06-24 2005-03-16 淄博海特曼化工有限公司 Silicane modified polyurethane cementing sealing glue and method for making same
CN201186902Y (en) * 2008-03-14 2009-01-28 浙江西溪玻璃有限公司 Pistol bulletproof glass
CN202249570U (en) * 2011-08-25 2012-05-30 姚世昌 Novel bulletproof glass door/window
CN103057665A (en) * 2012-12-12 2013-04-24 武汉武船深海装备工程有限责任公司 Installation method of glass window
CN106515106A (en) * 2016-11-07 2017-03-22 江苏碧海安全玻璃科技股份有限公司 Novel bulletproof and anti-smash laminated glass
CN207875030U (en) * 2017-12-11 2018-09-18 深圳市泽亮玻璃有限公司 A kind of bulletproof glass of intelligent dimming
CN108587452A (en) * 2018-05-24 2018-09-28 林荣铨 A kind of fluid sealant primary coat liquid and the preparation method and application thereof
CN109592888A (en) * 2018-12-20 2019-04-09 六盘水鑫瑞达钢化玻璃有限公司 A kind of technique for the production of High-strength compression resistant tempered glass
CN110256974A (en) * 2019-07-19 2019-09-20 广州市高士实业有限公司 A kind of silane modified polyether seal glue and the preparation method and application thereof
CN110499136A (en) * 2019-08-21 2019-11-26 濮阳市万泉化工有限公司 A kind of automobile single-component silane-modified polyurethane sealant of weatherability
CN110885657A (en) * 2019-12-12 2020-03-17 福建省昌德胶业科技有限公司 Preparation method of single-component high-strength MS sealant
CN111100590A (en) * 2019-12-04 2020-05-05 湖南柯盛新材料有限公司 Silane modified polyether sealant and preparation method thereof
CN111454683A (en) * 2020-05-08 2020-07-28 四川省宏源防水工程有限公司 High-water-resistance low-modulus single-component MS sealant, preparation method and application thereof
CN112694862A (en) * 2020-12-09 2021-04-23 南京理工大学北方研究院 Graphene oxide modified polyurethane flame-retardant glass cement and preparation method thereof
CN112980375A (en) * 2021-01-27 2021-06-18 湖北回天新材料股份有限公司 Single-component silane modified polyether sealant and preparation method thereof
CN214786974U (en) * 2021-04-29 2021-11-19 江苏铁锚玻璃股份有限公司 Lightweight transparent display bulletproof glass
WO2021232819A1 (en) * 2020-05-21 2021-11-25 广州市白云化工实业有限公司 Single-component silane-modified polyether sealant for prefabricated buildings and preparation method therefor
CN114163970A (en) * 2021-12-23 2022-03-11 山东北方现代化学工业有限公司 High-strength anti-aging single-component modified sealant for bonding rubber and plastic composite materials and preparation method thereof

Patent Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1594480A (en) * 2004-06-24 2005-03-16 淄博海特曼化工有限公司 Silicane modified polyurethane cementing sealing glue and method for making same
CN201186902Y (en) * 2008-03-14 2009-01-28 浙江西溪玻璃有限公司 Pistol bulletproof glass
CN202249570U (en) * 2011-08-25 2012-05-30 姚世昌 Novel bulletproof glass door/window
CN103057665A (en) * 2012-12-12 2013-04-24 武汉武船深海装备工程有限责任公司 Installation method of glass window
CN106515106A (en) * 2016-11-07 2017-03-22 江苏碧海安全玻璃科技股份有限公司 Novel bulletproof and anti-smash laminated glass
CN207875030U (en) * 2017-12-11 2018-09-18 深圳市泽亮玻璃有限公司 A kind of bulletproof glass of intelligent dimming
CN108587452A (en) * 2018-05-24 2018-09-28 林荣铨 A kind of fluid sealant primary coat liquid and the preparation method and application thereof
CN109592888A (en) * 2018-12-20 2019-04-09 六盘水鑫瑞达钢化玻璃有限公司 A kind of technique for the production of High-strength compression resistant tempered glass
CN110256974A (en) * 2019-07-19 2019-09-20 广州市高士实业有限公司 A kind of silane modified polyether seal glue and the preparation method and application thereof
CN110499136A (en) * 2019-08-21 2019-11-26 濮阳市万泉化工有限公司 A kind of automobile single-component silane-modified polyurethane sealant of weatherability
CN111100590A (en) * 2019-12-04 2020-05-05 湖南柯盛新材料有限公司 Silane modified polyether sealant and preparation method thereof
CN110885657A (en) * 2019-12-12 2020-03-17 福建省昌德胶业科技有限公司 Preparation method of single-component high-strength MS sealant
CN111454683A (en) * 2020-05-08 2020-07-28 四川省宏源防水工程有限公司 High-water-resistance low-modulus single-component MS sealant, preparation method and application thereof
WO2021232819A1 (en) * 2020-05-21 2021-11-25 广州市白云化工实业有限公司 Single-component silane-modified polyether sealant for prefabricated buildings and preparation method therefor
CN112694862A (en) * 2020-12-09 2021-04-23 南京理工大学北方研究院 Graphene oxide modified polyurethane flame-retardant glass cement and preparation method thereof
CN112980375A (en) * 2021-01-27 2021-06-18 湖北回天新材料股份有限公司 Single-component silane modified polyether sealant and preparation method thereof
CN214786974U (en) * 2021-04-29 2021-11-19 江苏铁锚玻璃股份有限公司 Lightweight transparent display bulletproof glass
CN114163970A (en) * 2021-12-23 2022-03-11 山东北方现代化学工业有限公司 High-strength anti-aging single-component modified sealant for bonding rubber and plastic composite materials and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
硅烷改性聚醚密封胶的研究和应用进展;房成等;广州化工;第48卷(第16期);第1-4页 *
阻燃MS密封胶的研制及性能研究;冯巧等;中国胶粘剂;第29卷(第07期);第35-38页 *

Also Published As

Publication number Publication date
CN115123456A (en) 2022-09-30

Similar Documents

Publication Publication Date Title
CN104694065B (en) Automobile silicane-modified polyurethane fluid sealant and preparation method thereof
CN102504748B (en) Silane modified polyurethane sealing glue with quick surface dry as well as preparation and application thereof
CN109082260B (en) Single-component transparent corner-forming adhesive and preparation method thereof
CN101831271B (en) Hollow glass bi-component organosilicone sealant and preparation method and application thereof
CN104449534B (en) One exempts from primary coat polyurethane glass glue and preparation method thereof
MX2011012160A (en) Gunnable adhesive composition for use in construction membrane applications.
CN110105907A (en) A kind of vehicle glass quick assembling one-component silane modified polyether seal glue and preparation method thereof
CN110951435A (en) High-strength silane modified polyether sealant with equal proportion and preparation method thereof
CN106147694A (en) A kind of instant sealed silicon ketone seal gum and preparation method thereof
CN113372833B (en) Flame-retardant waterproof composite adhesive tape and preparation method thereof
CN106987223A (en) Polyether-modified structure sealant of high intensity and preparation method thereof
CN115123456B (en) Installation method of underwater sightseeing window
CN108102607B (en) Silane modified adhesive with fast surface drying, fast positioning and high strength and preparation method thereof
CN104672912A (en) Special single-component jointing and gap filling silicon rubber for curing EMAS at room temperature and preparation method of special single-component jointing and gap filling silicon rubber
CN105255431A (en) Flame retardant type silane end capping polyether sealant and preparing method thereof
CN107779168A (en) A kind of preparation method of laminated glass-use silicone two-component fluid sealant
CN108467706A (en) A kind of one pack system assembled architecture outer wall splicing seams MS fluid sealants and preparation method thereof
CN113684003B (en) Two-component room temperature vulcanized silicone rubber composition
CN112094581A (en) Solvent-free fast-curing reactive waterproof coating and preparation method thereof, and coil coating superposed waterproof structural system and construction method thereof
CN105238320A (en) High-elasticity silane-terminated polypropylene oxide sealant and preparation method thereof
CN108165224A (en) A kind of low TVOC coach plastic floorings bonding MS fluid sealants and preparation method thereof
CN114774072A (en) Preparation method of oil-leakage-free silicone sealant
CN114958267A (en) Bi-component silane modified polyether sealant and preparation method thereof
Khairullin et al. Sealants based on urethane-siloxane rubbers curable under the action of moisture
CN112143449A (en) Bi-component fireproof organic sealant and application method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant