CN1151174A - Lubricant composition - Google Patents
Lubricant composition Download PDFInfo
- Publication number
- CN1151174A CN1151174A CN95193446A CN95193446A CN1151174A CN 1151174 A CN1151174 A CN 1151174A CN 95193446 A CN95193446 A CN 95193446A CN 95193446 A CN95193446 A CN 95193446A CN 1151174 A CN1151174 A CN 1151174A
- Authority
- CN
- China
- Prior art keywords
- lubricant compositions
- alkyl
- component
- aforesaid right
- requiring according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
- C10M105/08—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound containing oxygen
- C10M105/32—Esters
- C10M105/38—Esters of polyhydroxy compounds
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/04—Hydroxy compounds
- C10M129/10—Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
- C10M129/32—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms monocarboxylic
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- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/26—Carboxylic acids; Salts thereof
- C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M129/30—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms
- C10M129/34—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 7 or less carbon atoms polycarboxylic
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- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
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- C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
- C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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- C10M129/42—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms polycarboxylic
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- C10M129/48—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring
- C10M129/52—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring polycarboxylic
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- C10M129/68—Esters
- C10M129/70—Esters of monocarboxylic acids
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- C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M133/12—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
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- C10M133/30—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms containing a nitrogen-to-oxygen bond
- C10M133/32—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms containing a nitrogen-to-oxygen bond containing a nitro group
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- C10M133/38—Heterocyclic nitrogen compounds
- C10M133/40—Six-membered ring containing nitrogen and carbon only
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- C10M133/44—Five-membered ring containing nitrogen and carbon only
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- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/02—Sulfurised compounds
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- C10M135/06—Esters, e.g. fats
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- C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
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- C10M137/08—Ammonium or amine salts
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Abstract
A lubricant composition suitable as a helicopter transmission lubricant comprises a synthetic base stock of viscosity in the range 5.0 to 10.0 cSt at 100 DEG C, an antioxidant component, a neutral organic phosphate component, a dicarboxylic acid component, a monocarboxylic acid component, a triazole component and a phosphorus containing extreme pressure additive.
Description
The present invention is about a kind of lubricant compositions, particularly about being suitable for for example a kind of transmission lubricant of vertisplane transmission system.
The development that new transmission system for example is suitable for the transmission system of vertisplane causes being used for the load that can satisfy strictness day by day of these purposes and the lubricant agent special of anticorrosion standard.For example the specification requirement that is proposed by U.K. Ministry of Defence and United States Navy need be satisfied by new special-purpose vertisplane transmission lubricant, and can not be reached by existing aero-turbine lubricant.Therefore for these purposes, need the new improved lubricant compositions of exploitation.The present invention attempts to satisfy this requirement.
Therefore, the invention provides a kind of lubricant compositions, comprising:
A) comprise the base stock (basecomponent) of one or more synthetic basic raw materials (base stock), the viscosity of this base stock is between 5.0 to 10.0cst in the time of 100 ℃;
B) at least a oxidation inhibitor that is selected from aromatic amine and Hinered phenols;
C) at least a neutral organophosphate, its general formula is (R
1O)
3PO, wherein R
1Be tolyl, phenyl, xylyl, alkyl or cycloalkyl, alkyl or cycloalkyl can be had at most 10 carbon atoms;
D) at least a saturated and/or undersaturated dicarboxylic acid, its general formula is:
Wherein x+y+z is 2 to 22 integer, comprises 2 and 22, and R wherein
1To R
5Have at least one to be the carboxylic acid group in the group, and R
1To R
5In remaining group be selected from alkyl, hydroxyl, nitro, amino, carboxyl, hydrogen or its alkyl derivative, wherein alkyl is the short-chain alkyl of 5 carbon atoms the most nearly; And/or the dicarboxylic acid of one of following general formula
R wherein
1' be-COOH, alkyl, hydroxyl, nitro, amino, hydrogen or its alkyl derivative; R
2' be-COOH; And work as R
1' be-during COOH, n is 1 to 4 integer, comprises 1 and 4, or works as R
1' be not-during COOH, n is 2 to 4 integer, comprises 2 and 4;
E) the saturated or undersaturated monocarboxylic acid of at least a straight chain and/or side chain, its optional sulfuration reaches the amount of the highest by 35% (weight); And/or this acid esters; With
F) triazole of at least a following general formula:
R wherein
1" be-COOH or its alkyl derivative, or reach the short-chain alkyl of 5 carbon atoms most; N is 0 or 1 to 3 integer, comprises 1 and 3; And R
2" be the derivative that hydrogen, morpholino, alkyl, amido, amino, hydroxyl or alkyl or its aryl replace; Or be selected from following triazole: 1,2,4-triazole, 1,2,3-triazoles, 5-phenylamino-1,2,3,4-thiatriazole, 3-amino-1,2,4-triazole, 1-H-benzotriazole-1-base-methyl isocyanide, methylene radical-two-benzotriazole and aphthotriazoles; With
G) at least a phosphorous extreme pressure additive.
In above-mentioned component (d), two ring structure formulas mean radicals R
2Can be connected on any one of two aromatic rings or on two.
At least a basic raw material of base stock is this raw material of synthetic ester base, particularly polyol ester basic raw material preferably.Preferred group becomes the synthesis for polyol ester of a kind of basic raw material of lubricant compositions of the present invention can be by C
5To C
12Monocarboxylic acid and polyvalent alcohol or polyol ethers, for example neopentyl glycol, dihydroxy methylpropane, TriMethylolPropane(TMP), tetramethylolmethane or Dipentaerythritol esterification and get.These are conventional these raw materials of synthetic ester base.Preferred ester is that those are described in the United States Patent (USP) 4826633.
Viscosity can be adjusted in the scope of needs by adding one or more viscosity index improvers.
For obtaining the enough performances as transmission lubricant, the base stock preferred viscosities is between 8.5 to 9.5cst in the time of 100 ℃, and more preferably 8.75 to 9.25cst.Base stock can comprise single polyol ester, but more generally is the mixture of polyol ester, and for example viscosity is about the polyol ester of 4.0cst and viscosity is about the polyol ester of 12.0cst in the time of 100 ℃ mixture in the time of 100 ℃.Preferred synthesis for polyol ester is tetramethylolmethane and/or TriMethylolPropane(TMP) and contains C
5To C
10The reaction product of the acid mixture of straight chain and branched acids.
Oxidation inhibitor component b) can be Hinered phenols antioxidant, butylated hydroxytoluene for example, it accounts for 0.01 to 5% of lubricant compositions weight aptly, and preferred 0.4 to 0.8%.In addition, or in addition, component b) can comprise aromatic amine oxidation inhibitor, for example list-octyl phenyl-alpha-naphthylamine or p, the p-dioctyl diphenylamine, they can use or mix use separately.Amine oxidation inhibitor component accounts for 0.01 to 5% of lubricant compositions weight aptly, and more preferably 0.5 to 1.5%.
General formula c in the composition preparation) the neutral organophosphate of component can account for 0.01 to 4% of composition weight, preferred 1.5 to 2.5%.Neutral organophosphate still is the conventional ingredient of lubricant compositions, and can adopt any of this neutral organophosphate that satisfies aforementioned formula.Tritolyl Phosphate is to be used for the preferred phosphoric acid ester of the present invention.
Component d), e) and f) be intended to provide a kind of rot-resistant three component system.It is found that this mixture can make acquisition can pass through the lubricant compositions of United States Navy's requirement for anticorrosion (Ball Corrosion Test-ARP4249), wherein 50% result of not corroding sample just is considered to satisfied requirement for anticorrosion.
The dicarboxylic acid of forming anti-rotten mixture first component can be and satisfies any dicarboxylic acid that the front has been given definition.Dicarboxylic acid accounts for the ratio of composition weight can be up to 0.15%.Yet it should be noted, even exist other to satisfy the dicarboxylic acid of above-mentioned definition, also wish in composition, always to contain sebacic acid or its suitable thing, this is that for example Man Yi anti-lead corrosion (lead corrosion) requires necessary because sebacic acid or its suitable thing are to satisfy the part except the ball corrosion test in the specification.
The example that can be used for the diprotic acid except that sebacic acid of the present invention is hexanodioic acid, nonane diacid, dodecandioic acid, 3-methyl hexanodioic acid, 3-nitrophthalic acid, 1,10-decane dicarboxylic acid and fumaric acid.
Second component of anti-rotten mixture is for can choose sulfuration wantonly up to the straight or branched of 35% (weight), saturated or unsaturated monocarboxylic or its ester.Preferred acid is C
4To C
22The straight chain unsaturated monocarboxylic.The preferred concentration of this additive is to account for 0.001% to 0.35% of lubricant compositions gross weight.Preferred monocarboxylic acid is a sulfurized oleic acid.Yet other suitable raw material is oleic acid itself, valeric acid and erucic acid.
The 3rd component of anti-rotten mixture is the triazole of aforementioned definitions.Triazole should be used with 0.005% to 0.25% concentration of composition gross weight.Preferred triazole is a benzotriazole.
The component g of composition) comprises at least a phosphorated extreme pressure additive.The example of examples of such additives is the phosphorylation thing extreme pressure additive of amine, for example known commodity IRGALUBE349 by name and/or the anti-extreme pressure/anti-wear additive of triphenyl thiophosphatephosphorothioate, and for example known commodity are called IRGALUBE TPPT.The phosphorylation thing of this amine accounts for 0.01 to 2% of lubricant compositions weight aptly, and is preferred 0.2 to 0.6%, and this thiophosphatephosphorothioate accounts for 0.01 to 3% of lubricant compositions weight aptly, and preferred 0.5 to 1.5%.The preferred phosphorylation thing of amine and the mixture of thiophosphatephosphorothioate of adopting.
For the lubricant of vertisplane transmission mechanism is provided, the amount of additive is selected like this: meeting United States Navy is 200 requirement (relative value to the experiment of the Reed gear 100 ℃ time the (Ryder gear test) value, % Herco A is as the reference fluid, 6 times mean value).
Following example is intended to illustrate preferred emollient composition of the present invention.
% weight
List-octyl phenyl-alpha-naphthylamine 0.5%
Butylated hydroxytoluene 0.5%
Benzotriazole 0.1%
Sulfuration oleic acid 0.05%
Sebacic acid 0.01%
Trimethylphenyl phosphoric acid ester 2.0%
The phosphorylation thing 0.4% of amine
Triphenyl thiophosphatephosphorothioate 1.0%
Silicone antifoam agent 2ppm
Making composition viscosity is 8.75 to 9.25cst's
Basic synthetic ester fluid mixture 95.44%
The composition that discovery obtains is tested (relative value, % Herco A) at 100 ℃ of Reed gears value is 204.7 and has passed through the quota of ball corrosion test (Ball Corrosion Test) (according to ARP method 4249).
Claims (17)
1. lubricant compositions comprises:
A) comprise the base stock (basecomponent) of one or more synthetic basic raw materials (base stock), the viscosity of this base stock is between 5.0 to 10.0cst in the time of 100 ℃;
B) at least a oxidation inhibitor that is selected from aromatic amine and Hinered phenols;
C) at least a neutral organophosphate, its general formula is (R
1O)
3PO, wherein R
1Be tolyl, phenyl, xylyl, alkyl or cycloalkyl, alkyl or cycloalkyl can be had at most 10 carbon atoms;
D) at least a saturated and/or undersaturated dicarboxylic acid, its general formula is:
Wherein x+y+z is 2 to 22 integer, comprises 2 and 22, and R wherein
1To R
5Have at least one to be the carboxylic acid group in the group, and R
1To R
5In remaining group be selected from alkyl, hydroxyl, nitro, amino, carboxyl, hydrogen or its alkyl derivative, wherein alkyl is the short-chain alkyl of 5 carbon atoms the most nearly; And/or the dicarboxylic acid of one of following general formula
R wherein
1' be-COOH, alkyl, hydroxyl, nitro, amino, hydrogen or its alkyl derivative; R
2' be-COOH; And work as R
1' be-during COOH, n is 1 to 4 integer, comprises 1 and 4, or works as R
1' be not-during COOH, n is 2 to 4 integer, comprises 2 and 4;
E) the saturated or undersaturated monocarboxylic acid of at least a straight chain and/or side chain, its optional sulfuration reaches the amount of the highest by 35% (weight); And/or this acid esters; With
F) triazole of at least a following general formula:
R wherein
1" be-COOH or its alkyl derivative, or reach the short-chain alkyl of 5 carbon atoms most; N is 0 or 1 to 3 integer, comprises 1 and 3; And R
2" be the derivative that hydrogen, morpholino, alkyl, amido, amino, hydroxyl or alkyl or its aryl replace; Or be selected from following triazole: 1,2,4-triazole, 1,2,3-triazoles, 5-phenylamino-1,2,3,4-thiatriazole, 3-amino-1,2,4-triazole, 1-H-benzotriazole-1-base-methyl isocyanide, methylene radical-two-benzotriazole and aphthotriazoles; With
G) at least a phosphorous extreme pressure additive.
2. according to the lubricant compositions of claim 1, wherein the basic raw material of at least a base stock is a polyol ester.
3. according to the lubricant compositions of claim 2, a wherein polyol ester based raw material packet contains by one or more C of one or more polyvalent alcohols or polyol ethers esterification
5To C
12Monocarboxylic acid.
4. according to any one lubricant compositions in the claim 1 to 3, wherein the viscosity of base stock is between 8.5 to 9.5cst in the time of 100 ℃.
5. the lubricant compositions of any one in requiring according to aforesaid right, wherein oxidation inhibitor comprises the Hinered phenols antioxidant that accounts for composition weight 0.4 to 0.8%.
6. the lubricant compositions of any one in requiring according to aforesaid right, wherein oxidation inhibitor comprises the aromatic amine oxidation inhibitor that accounts for composition weight 0.5 to 1.5%.
7. the lubricant compositions of any one in requiring according to aforesaid right, wherein neutral organophosphate accounts for 1.5 to 2.5% of composition weight.
8. what the lubricant compositions of any one in requiring according to aforesaid right, wherein saturated and/or unsaturated dicarboxylic acid component (d) accounted for composition weight is up to 0.15%.
9. the lubricant compositions of any one in requiring according to aforesaid right, wherein saturated and/or unsaturated dicarboxylic acid component (d) comprises sebacic acid.
10. the lubricant compositions of any one in requiring according to aforesaid right, wherein monocarboxylic acid and component (e) account for 0.001 to 0.35% of composition weight.
11. the lubricant compositions of any one in requiring according to aforesaid right, wherein monocarboxylic acid component (e) comprises sulfurized oleic acid.
12. the lubricant compositions of any one in requiring according to aforesaid right, wherein triazole component (f) accounts for 0.005 to 0.25% of composition weight.
13. the lubricant compositions of any one in requiring according to aforesaid right, wherein triazole component (f) comprises benzotriazole.
14. the lubricant compositions of any one in requiring according to aforesaid right, wherein extreme pressure additive component (g) comprises the phosphorylation thing extreme pressure additive of the amine that accounts for composition weight 0.2 to 0.6%.
15. the lubricant compositions of any one in requiring according to aforesaid right, wherein extreme pressure additive component (g) comprises the thiophosphatephosphorothioate extreme pressure additive that accounts for composition weight 0.5 to 1.5%.
16. a vertisplane transmission lubricant comprises in the aforesaid right requirement any one described component (a) to (g).
17. according to a kind of vertisplane transmission lubricant of claim 16, wherein select the amount of component (b) to (g) like this for use: to meet United States Navy is 200 requirement under 100 ℃ to Reed gear experiment (Ryder gear test).(relative value, % Herco A is as the reference fluid).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9408235A GB9408235D0 (en) | 1994-04-26 | 1994-04-26 | Lubricant composition |
GB9408235.1 | 1994-04-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1151174A true CN1151174A (en) | 1997-06-04 |
CN1043053C CN1043053C (en) | 1999-04-21 |
Family
ID=10754127
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN95193446A Expired - Fee Related CN1043053C (en) | 1994-04-26 | 1995-04-25 | Lubricant composition |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP0757712B1 (en) |
JP (1) | JP3780323B2 (en) |
KR (1) | KR100339777B1 (en) |
CN (1) | CN1043053C (en) |
AT (1) | ATE190997T1 (en) |
AU (1) | AU695511B2 (en) |
CA (1) | CA2188936A1 (en) |
DE (1) | DE69515861T2 (en) |
DK (1) | DK0757712T3 (en) |
ES (1) | ES2148513T3 (en) |
GB (1) | GB9408235D0 (en) |
GR (1) | GR3033741T3 (en) |
NZ (1) | NZ284520A (en) |
PT (1) | PT757712E (en) |
WO (1) | WO1995029214A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100334188C (en) * | 2002-03-04 | 2007-08-29 | 卢布里佐尔公司 | Lubricating compositions with good thermal stability and demulsibility properties |
CN100357409C (en) * | 2002-11-15 | 2007-12-26 | 英国石油国际有限公司 | Method of reducing particulate emissions |
CN106590869A (en) * | 2016-11-28 | 2017-04-26 | 广西大学 | Total synthesis four-bar linkage rocking block mechanism thermomotor lubricant composition |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6043199A (en) * | 1997-08-26 | 2000-03-28 | Exxon Research And Engineering Co. | Corrosion inhibiting additive combination for turbine oils |
US5955403A (en) * | 1998-03-24 | 1999-09-21 | Exxon Research And Engineering Company | Sulphur-free, PAO-base lubricants with excellent anti-wear properties and superior thermal/oxidation stability |
JP2000169871A (en) * | 1998-12-08 | 2000-06-20 | Nippon Mitsubishi Oil Corp | Lubricant oil composition |
US6074992A (en) * | 1999-02-02 | 2000-06-13 | Union Carbide Chemicals & Plastics Technology Corporation | Functional fluid compositions |
EP1201734B1 (en) * | 2000-02-09 | 2006-06-14 | Citizen Watch Co. Ltd. | Use of a LUBRICATING OIL COMPOSITION in a watch AND WATCH CONTAINING THE SAME |
US7648948B2 (en) | 2005-04-08 | 2010-01-19 | Exxonmobil Chemical Patents Inc. | Additive system for lubricants |
US20080139427A1 (en) * | 2006-12-11 | 2008-06-12 | Hutchison David A | Lubricating composition |
JP5827782B2 (en) | 2009-05-08 | 2015-12-02 | 出光興産株式会社 | Biodegradable lubricating oil composition |
JP6669343B2 (en) * | 2015-02-27 | 2020-03-18 | 出光興産株式会社 | Biodegradable lubricating oil composition |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2051665A1 (en) * | 1969-07-10 | 1971-04-09 | Ethyl Corp | |
BE754710A (en) * | 1969-08-12 | 1971-02-11 | Stauffer Chemical Co | COMPOSITION OF SYNTHETIC LUBRICANT |
FR2215462A1 (en) * | 1973-01-25 | 1974-08-23 | Exxon Research Engineering Co | |
CN1030934A (en) * | 1987-07-30 | 1989-02-08 | 钱江宁 | Speed car braking fluid and production method thereof |
US4981602A (en) * | 1988-06-13 | 1991-01-01 | The Lubrizol Corporation | Lubricating oil compositions and concentrates |
CN1070679A (en) * | 1991-09-17 | 1993-04-07 | 岳江 | Synthetic brake oil and method for making thereof |
GB2272000B (en) * | 1992-10-30 | 1997-03-26 | Castrol Ltd | A method of inhibiting corrosion |
-
1994
- 1994-04-26 GB GB9408235A patent/GB9408235D0/en active Pending
-
1995
- 1995-04-25 CA CA002188936A patent/CA2188936A1/en not_active Abandoned
- 1995-04-25 AT AT95916764T patent/ATE190997T1/en not_active IP Right Cessation
- 1995-04-25 NZ NZ284520A patent/NZ284520A/en not_active IP Right Cessation
- 1995-04-25 DE DE69515861T patent/DE69515861T2/en not_active Expired - Lifetime
- 1995-04-25 WO PCT/GB1995/000941 patent/WO1995029214A1/en active IP Right Grant
- 1995-04-25 JP JP52748095A patent/JP3780323B2/en not_active Expired - Fee Related
- 1995-04-25 AU AU23135/95A patent/AU695511B2/en not_active Ceased
- 1995-04-25 DK DK95916764T patent/DK0757712T3/en active
- 1995-04-25 ES ES95916764T patent/ES2148513T3/en not_active Expired - Lifetime
- 1995-04-25 EP EP95916764A patent/EP0757712B1/en not_active Expired - Lifetime
- 1995-04-25 KR KR1019960705962A patent/KR100339777B1/en not_active IP Right Cessation
- 1995-04-25 PT PT95916764T patent/PT757712E/en unknown
- 1995-04-25 CN CN95193446A patent/CN1043053C/en not_active Expired - Fee Related
-
2000
- 2000-06-21 GR GR20000401436T patent/GR3033741T3/en unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100334188C (en) * | 2002-03-04 | 2007-08-29 | 卢布里佐尔公司 | Lubricating compositions with good thermal stability and demulsibility properties |
CN100357409C (en) * | 2002-11-15 | 2007-12-26 | 英国石油国际有限公司 | Method of reducing particulate emissions |
CN106590869A (en) * | 2016-11-28 | 2017-04-26 | 广西大学 | Total synthesis four-bar linkage rocking block mechanism thermomotor lubricant composition |
Also Published As
Publication number | Publication date |
---|---|
KR100339777B1 (en) | 2002-11-13 |
EP0757712B1 (en) | 2000-03-22 |
AU2313595A (en) | 1995-11-16 |
CA2188936A1 (en) | 1995-11-02 |
DK0757712T3 (en) | 2000-08-28 |
JP3780323B2 (en) | 2006-05-31 |
WO1995029214A1 (en) | 1995-11-02 |
NZ284520A (en) | 1997-09-22 |
GR3033741T3 (en) | 2000-10-31 |
DE69515861D1 (en) | 2000-04-27 |
ATE190997T1 (en) | 2000-04-15 |
AU695511B2 (en) | 1998-08-13 |
ES2148513T3 (en) | 2000-10-16 |
JPH10503535A (en) | 1998-03-31 |
CN1043053C (en) | 1999-04-21 |
GB9408235D0 (en) | 1994-06-15 |
PT757712E (en) | 2000-09-29 |
EP0757712A1 (en) | 1997-02-12 |
DE69515861T2 (en) | 2000-12-07 |
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