CN115109637B - Hard water resistant and low COD concentrated solution for hydraulic support and preparation method thereof - Google Patents
Hard water resistant and low COD concentrated solution for hydraulic support and preparation method thereof Download PDFInfo
- Publication number
- CN115109637B CN115109637B CN202210870310.3A CN202210870310A CN115109637B CN 115109637 B CN115109637 B CN 115109637B CN 202210870310 A CN202210870310 A CN 202210870310A CN 115109637 B CN115109637 B CN 115109637B
- Authority
- CN
- China
- Prior art keywords
- concentrated solution
- hard water
- hydraulic support
- cod
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000008233 hard water Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 24
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 24
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 19
- 239000003755 preservative agent Substances 0.000 claims abstract description 19
- 230000002335 preservative effect Effects 0.000 claims abstract description 19
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 18
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 17
- 150000007942 carboxylates Chemical class 0.000 claims abstract description 14
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 11
- 238000006243 chemical reaction Methods 0.000 claims abstract description 11
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 7
- 239000000022 bacteriostatic agent Substances 0.000 claims abstract description 5
- 239000000243 solution Substances 0.000 claims description 68
- 238000010438 heat treatment Methods 0.000 claims description 18
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 16
- 239000012964 benzotriazole Substances 0.000 claims description 16
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 16
- 229910052700 potassium Inorganic materials 0.000 claims description 14
- KGBNEVNDPXWACX-UHFFFAOYSA-N [O-]C(CC[S+]=C(CCC(O)=O)O)=O Chemical compound [O-]C(CC[S+]=C(CCC(O)=O)O)=O KGBNEVNDPXWACX-UHFFFAOYSA-N 0.000 claims description 13
- -1 polyoxyethylene Polymers 0.000 claims description 13
- 239000011259 mixed solution Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 7
- 229930195729 fatty acid Natural products 0.000 claims description 7
- 239000000194 fatty acid Substances 0.000 claims description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 5
- 239000013530 defoamer Substances 0.000 claims description 4
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- MGIYRDNGCNKGJU-UHFFFAOYSA-N isothiazolinone Chemical compound O=C1C=CSN1 MGIYRDNGCNKGJU-UHFFFAOYSA-N 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims 3
- 229920001296 polysiloxane Polymers 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 14
- 230000007797 corrosion Effects 0.000 abstract description 9
- 238000005260 corrosion Methods 0.000 abstract description 9
- 239000002994 raw material Substances 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 4
- 230000000052 comparative effect Effects 0.000 description 32
- 239000012530 fluid Substances 0.000 description 25
- 239000000344 soap Substances 0.000 description 21
- 230000002829 reductive effect Effects 0.000 description 15
- 238000011156 evaluation Methods 0.000 description 10
- 239000000203 mixture Substances 0.000 description 7
- 239000000654 additive Substances 0.000 description 6
- 239000008139 complexing agent Substances 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 6
- 239000000314 lubricant Substances 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 239000003245 coal Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical group CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 4
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 3
- 229920005830 Polyurethane Foam Polymers 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910001424 calcium ion Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- MXBMZMIQYRQONB-UHFFFAOYSA-N decanedioic acid;2-(2-hydroxyethylamino)ethanol Chemical compound OCCNCCO.OC(=O)CCCCCCCCC(O)=O MXBMZMIQYRQONB-UHFFFAOYSA-N 0.000 description 3
- 230000001050 lubricating effect Effects 0.000 description 3
- 229910001425 magnesium ion Inorganic materials 0.000 description 3
- 238000010907 mechanical stirring Methods 0.000 description 3
- 239000011496 polyurethane foam Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000008399 tap water Substances 0.000 description 3
- 235000020679 tap water Nutrition 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- ICLYJLBTOGPLMC-KVVVOXFISA-N (z)-octadec-9-enoate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCC\C=C/CCCCCCCC(O)=O ICLYJLBTOGPLMC-KVVVOXFISA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 229960001484 edetic acid Drugs 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 2
- WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical class CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 229940117013 triethanolamine oleate Drugs 0.000 description 2
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005536 corrosion prevention Methods 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 229940095098 glycol oleate Drugs 0.000 description 1
- 229940100242 glycol stearate Drugs 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000012669 liquid formulation Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
- 229940082004 sodium laurate Drugs 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/109—Polyethers, i.e. containing di- or higher polyoxyalkylene groups esterified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/221—Six-membered rings containing nitrogen and carbon only
- C10M2215/222—Triazines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
- C10M2219/085—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms containing carboxyl groups; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2221/04—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/047—Siloxanes with specific structure containing alkylene oxide groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/04—Detergent property or dispersant property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/18—Anti-foaming property
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/08—Hydraulic fluids, e.g. brake-fluids
Abstract
The invention discloses a hard water resistant and low COD concentrated solution for a hydraulic support and a preparation method thereof, wherein the concentrated solution for the hydraulic support comprises the following components in percentage by mass: 4 to 6 percent of multifunctional surfactant, 1 to 3 percent of nonionic surfactant, 10 to 15 percent of antirust preservative, 0.3 to 1.0 percent of bacteriostatic agent, 0.08 to 0.12 percent of defoaming agent and the balance of water; the multifunctional surfactant is one or the combination of more than two of fatty alcohol polyoxyethylene ether sulfate, fatty acid methyl ester ethoxylate sulfonate and fatty alcohol polyoxyethylene ether carboxylate. The concentrated solution for the hydraulic support has extremely high hard water resistance, lower COD value and better rust resistance and corrosion resistance; the preparation method of the concentrated solution for the hydraulic support is simple in process, simple in production equipment, low in raw material cost, mild in reaction condition and suitable for industrial mass production.
Description
Technical Field
The invention belongs to the field of transmission media for hydraulic supports of coal mines, and particularly relates to a hard water resistant and low COD concentrated solution for a hydraulic support and a preparation method thereof.
Background
The concentrated solution for the hydraulic support is a substance which can be dissolved in water to form solution type diluent, and generally consists of water, water-soluble antirust agent, anticorrosive agent, lubricant and other additives. The hydraulic support is matched with mine water with the mass ratio of more than 95% to form high-water-content hydraulic fluid as a transmission medium of the hydraulic support to realize the actions of lifting, lowering, pushing, sliding, moving and the like of the hydraulic support. At present, concentrated solution for hydraulic supports usually contains organic carboxylic acid soap (such as oleic acid soap), and the additive is easy to react with calcium and magnesium ions in mine water to generate hard soap which is insoluble in water and separate out, so that a hydraulic system is blocked, and the hydraulic supports cannot normally operate.
In order to prevent precipitation of organic carboxylic acid soap and mine water-insoluble calcium magnesium soap, a certain amount of complexing agent such as EDTA (ethylene diamine tetraacetic acid) is usually compounded in the concentrated solution according to the hardness of mine water so as to avoid precipitation of calcium magnesium soap of organic carboxylic acid. However, the mine water hardness often has larger fluctuation, when the mine water hardness is increased and exceeds the complexing capacity of the high-water-content hydraulic fluid of the hydraulic support, the high-water-content hydraulic fluid is caused to be soapy, floccules and sediments are generated, a hydraulic system is blocked, the hydraulic support cannot normally operate, and the hydraulic support is blocked by the high-water-content hydraulic fluid at present.
Chemical Oxygen Demand (COD) is an important environmental protection index for monitoring mine sewage discharge, and is a comprehensive index for measuring the concentration of reducing pollutants in sewage. The lower the COD value, the lower the content of pollutants in the water. The COD value of the concentrated solution of the hydraulic support is usually very high and above 16000mg/L, so that the reduction of the COD value of the concentrated solution of the hydraulic support is an important requirement for meeting the environmental protection requirement and protecting the underground water quality of a mining area.
Disclosure of Invention
The invention aims to provide a concentrated solution for a hydraulic support, which is resistant to hard water and low in COD and a preparation method thereof. The concentrated solution for the hydraulic support meets the requirements of the coal industry standard MT/T76-2011 of emulsified oil and concentrated solution for the hydraulic support and high-water-content hydraulic fluid thereof, has excellent hard water resistance and lower COD value; in addition, the preparation method of the concentrated solution is simple, has lower cost and meets the requirement of industrialized mass production.
In order to achieve the above purpose, the embodiment of the present invention adopts the following technical scheme:
the embodiment of the invention provides a concentrated solution for a hydraulic support, which is resistant to hard water and low in COD, and comprises the following components in percentage by mass:
the multifunctional surfactant is one or the combination of more than two of fatty alcohol polyoxyethylene ether sulfate, fatty acid methyl ester ethoxylate sulfonate and fatty alcohol polyoxyethylene ether carboxylate.
According to the embodiment of the invention, the formula of the concentrated solution for the hydraulic support is reasonably constructed and designed, so that the problem of soap separation is fundamentally solved, and meanwhile, the COD value of the concentrated solution for the hydraulic support can be obviously reduced, and pollution is reduced. Firstly, the multifunctional surfactant is adopted in the concentrated solution for the hydraulic support, so that the concentrated solution has the lubricating and rust-preventing functions of the organic carboxylic acid soap, and calcium magnesium soap is also generated after the concentrated solution meets hard water, but the generated calcium magnesium soap cannot be separated out to block a hydraulic system due to the existence of ethoxy, so that the concentrated solution has stronger hard water resistance; secondly, due to the introduction of the multifunctional surfactant, the total content of other additives in the concentrated solution of the hydraulic support is reduced, and under the conditions that the hard water resistance is enhanced and other performances are not reduced, the COD value of the concentrated solution of the hydraulic support is obviously reduced, so that pollution to mine water is obviously reduced; in addition, the nonionic surfactant is adopted in the concentrated solution for the hydraulic support, the nonionic surfactant has good solubility in a hard water system, soap separation phenomenon is avoided, and other additives such as an antirust preservative, a bacteriostatic agent, a defoaming agent and the like are not reacted with calcium and magnesium ions to separate out, so that the hard water resistance of the hydraulic support solution is fundamentally enhanced, and the lubricating and antirust functions of the concentrated solution can be enhanced by compounding the multifunctional surfactant.
In some embodiments, the fatty alcohol-polyoxyethylene ether sulfate has a molecular formula of RO (C 2 H 4 O) n SO 4 M, wherein: r is C8-C18 alkyl, n=8-15, M is K or Na; the fatty acid methyl ester ethoxylate sulfonate has a molecular formula of RO (C) 2 H 4 O) n CH(SO 3 M)COOCH 3 Wherein: r is C8-C16 alkyl, n=8-15, M is K or Na; the molecular general formula of the fatty alcohol polyoxyethylene ether carboxylate is RO (C) 2 H 4 O) n CH 2 COOM, wherein: r is C8-C16 alkyl, n=8-15, M is K or Na.
In some embodiments, the multifunctional surfactant is preferably a mixture of fatty acid methyl ester ethoxylate sulfonate and fatty alcohol polyoxyethylene ether carboxylate, wherein the mass ratio of fatty acid methyl ester ethoxylate sulfonate to fatty alcohol polyoxyethylene ether carboxylate is 1:1.
In some embodiments, the nonionic surfactant is a polyoxyethylene alkylamide or a polyethylene glycol fatty acid ester.
In some embodiments, the rust inhibitive preservative comprises S-carboxyethyl thiosuccinic acid, diethanolamine, and benzotriazole; wherein the mass ratio of the S-carboxyethyl thiosuccinic acid to the diethanolamine to the benzotriazole is (4-7): (8-15): (0.1-0.3).
In some embodiments, the bacteriostatic agent is any one of s-triazine, isothiazolinone.
In some embodiments, the defoamer is a polyether modified siloxane.
The embodiment of the invention also provides a preparation method of the concentrated solution for the hydraulic support, which comprises the following steps:
(1) Adding the antirust preservative into water according to a certain proportion, heating and stirring to obtain a mixed solution;
(2) And (3) adding a multifunctional surfactant, a nonionic surfactant, a bacteriostat and a defoaming agent into the mixed solution obtained in the step (1), and heating for reaction to obtain the concentrated solution for the hard water resistant and low-COD hydraulic bracket.
The preparation method of the concentrated solution for the hydraulic support has the advantages of simple process, simple production equipment, lower raw material cost, mild reaction conditions and low energy consumption, is suitable for industrial mass production, and the prepared concentrated solution for the hydraulic support has excellent hard water resistance, rust prevention and corrosion resistance, has a lower COD value and reduces environmental pollution.
In some embodiments, in step (1), the temperature of the heating and stirring is 20-40 ℃ and the stirring time is 5-20 min.
In some embodiments, in step (2), the heating reaction is performed at a temperature of 40 to 50 ℃ for a reaction time of 20 to 60 minutes.
The invention has the advantages and beneficial effects that:
1) The raw materials of the concentrated solution for the hydraulic support adopt multifunctional surfactants, and the concentrated solution has extremely high hard water resistance and better rust resistance; and the nonionic surfactant is adopted, so that the nonionic surfactant has good solubility in a hard water system, does not generate soap separation phenomenon, and further enhances the hard water resistance of the concentrated solution for the hydraulic support.
2) According to the concentrated solution for the hydraulic support, the multifunctional surfactant is introduced, so that the total content of other additives in the raw material of the concentrated solution for the hydraulic support is reduced, the COD value of the concentrated solution for the hydraulic support is obviously reduced, and the pollution to mine water is obviously reduced.
3) The preparation method of the concentrated solution for the hydraulic support has the advantages of simple process, simple production equipment, low raw material cost, mild reaction conditions and low energy consumption, is suitable for industrial mass production, and the prepared concentrated solution for the hydraulic support has excellent hard water resistance, rust prevention and corrosion resistance and has low COD value.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more clear, the technical solutions of the embodiments of the present invention will be clearly and completely described below. It will be apparent that the described embodiments are some, but not all, embodiments of the invention. All other embodiments, which can be obtained by a person skilled in the art without creative efforts, based on the described embodiments of the present invention belong to the protection scope of the present invention.
Unless defined otherwise, technical or scientific terms used herein should be given the ordinary meaning as understood by one of ordinary skill in the art to which this invention belongs.
The embodiment of the invention provides a concentrated solution for a hydraulic support, which is resistant to hard water and low in COD, and comprises the following components in percentage by mass:
the multifunctional surfactant is one or the combination of more than two of fatty alcohol polyoxyethylene ether sulfate, fatty acid methyl ester ethoxylate sulfonate and fatty alcohol polyoxyethylene ether carboxylate.
According to the embodiment of the invention, the formula of the concentrated solution for the hydraulic support is reasonably constructed, so that the concentrated solution still can meet the requirements of coal industry standard MT/T76-2011, emulsified oil and concentrated solution for the hydraulic support and high-water-content hydraulic fluid thereof under a high hard water system (manual hardness classification 40), and has good hard water resistance, rust prevention and corrosion resistance; and the COD value is lower, so that the pollution to the environment can be reduced.
In some embodiments, the fatty alcohol-polyoxyethylene ether sulfate has a molecular formula of RO (C 2 H 4 O) n SO 4 M, wherein: r is C8-C18 alkyl, n=8-15, M is K or Na; fatty acid methyl ester ethoxylate sulfonate has a molecular formula of RO (C 2 H 4 O) n CH(SO 3 M)COOCH 3 Wherein: r is C8-C16 alkyl, n=8-15, M is K or Na; the molecular general formula of the fatty alcohol polyoxyethylene ether carboxylate is RO (C) 2 H 4 O) n CH 2 COOM, wherein: r is C8-C16 alkyl, n=8-15, M is K or Na.
In some embodiments, the fatty alcohol in the fatty alcohol-polyoxyethylene ether sulfate, fatty alcohol-polyoxyethylene ether carboxylate is preferably one of lauryl alcohol, decyl alcohol, octyl alcohol; the fatty acid in the fatty acid methyl ester ethoxylate sulfonate is preferably lauric acid, i.e. the fatty acid methyl ester ethoxylate sulfonate is lauric acid methyl ester ethoxylate sulfonate.
In some embodiments, the multifunctional surfactant is preferably a mixture of fatty acid methyl ester ethoxylate sulfonate and fatty alcohol polyoxyethylene ether carboxylate, wherein the mass ratio of fatty acid methyl ester ethoxylate sulfonate to fatty alcohol polyoxyethylene ether carboxylate is 1:1.
In some embodiments, the nonionic surfactant is polyoxyethylene alkylamide or polyethylene glycol fatty acid ester, the nonionic surfactant has better solubility in a hard water system, no soap separation phenomenon occurs, and the nonionic surfactant can enhance the lubrication and rust prevention functions of the concentrated solution after being compounded with the multifunctional surfactant.
In some embodiments, the alkyl group in the polyoxyethylene alkylamide is preferably one of decyl, dodecyl, tetradecyl, i.e., the polyoxyethylene alkylamide is one of polyoxyethylene decane ylamide, polyoxyethylene dodecylamide, polyoxyethylene tetradecylamide.
In some embodiments, the fatty acid in the polyethylene glycol fatty acid ester is preferably one of oleic acid, stearic acid, lauric acid, i.e., the polyethylene glycol fatty acid ester is one of polyethylene glycol oleate, polyethylene glycol stearate, polyethylene glycol laurate.
In some embodiments, rust inhibitors include S-carboxyethyl thiosuccinic acid, diethanolamine, and benzotriazole; wherein the mass ratio of the S-carboxyethyl thiosuccinic acid to the diethanolamine to the benzotriazole is (4-7): (8-15): (0.1-0.3).
In some embodiments, the bacteriostatic agent is any one of s-triazine, isothiazolinone.
In some embodiments, the defoamer is a polyether modified siloxane.
The embodiment of the invention also provides a preparation method of the concentrated solution for the hydraulic support, which comprises the following steps:
(1) Adding S-carboxyethyl thiosuccinic acid, diethanolamine and benzotriazole into water according to a certain proportion, heating and stirring to obtain a mixed solution;
(2) And (3) adding a multifunctional surfactant, a nonionic surfactant, a bacteriostat and a defoaming agent into the mixed solution obtained in the step (1), and heating for reaction to obtain the concentrated solution for the hard water resistant and low-COD hydraulic bracket.
The preparation method of the concentrated solution for the hydraulic support has the advantages of simple process, simple production equipment, lower raw material cost, mild reaction conditions and low energy consumption, is suitable for industrial mass production, and the prepared concentrated solution for the hydraulic support has excellent hard water resistance, rust prevention and corrosion resistance, has a lower COD value and reduces environmental pollution.
In some embodiments, in step (1), the temperature of the heating and stirring is 20-40 ℃ and the stirring time is 5-20 min.
In some embodiments, in step (2), the heating reaction is carried out at a temperature of 40 to 50℃for a reaction time of 20 to 60 minutes.
The present invention will be described in further detail with reference to specific examples.
Example 1
A concentrated solution for a hard water resistant and low COD hydraulic support comprises the following components in percentage by mass:
wherein the multifunctional surfactant is formed by compounding sodium laureth sulfate and sodium laurate ethoxylate sulfonate according to a mass ratio of 2:1.
Wherein the rust-proof preservative is formed by compounding S-carboxyethyl thiosuccinic acid, diethanolamine and benzotriazole according to a mass ratio of 7:15:0.3.
The specific preparation method of the concentrated solution for the hydraulic support comprises the following steps:
(1) Adding S-carboxyethyl thiosuccinic acid, diethanolamine and benzotriazole into water according to the component proportion of the rust-proof preservative, and stirring for 10min at 35 ℃ to obtain a mixed solution;
(2) And (2) adding a multifunctional surfactant, a nonionic surfactant, a bacteriostat and a defoaming agent into the mixed solution obtained in the step (1), heating to 40 ℃ and preserving heat for 30min to obtain the modified polyurethane foam.
Example 2
A concentrated solution for a hard water resistant and low COD hydraulic support comprises the following components in percentage by mass:
wherein the multifunctional surfactant is potassium decyl alcohol polyoxyethylene ether carboxylate.
Wherein the rust-proof preservative is formed by compounding S-carboxyethyl thiosuccinic acid, diethanolamine and benzotriazole according to a mass ratio of 6:12:0.2.
The specific preparation method of the concentrated solution for the hydraulic support comprises the following steps:
(1) Adding S-carboxyethyl thiosuccinic acid, diethanolamine and benzotriazole into water according to the component proportion of the rust-proof preservative, and stirring for 10min at 25 ℃ to obtain a mixed solution;
(2) And (2) adding a multifunctional surfactant, a nonionic surfactant, a bacteriostat and a defoaming agent into the mixed solution obtained in the step (1), heating to 45 ℃ and preserving heat for 40min to obtain the modified polyurethane foam.
Example 3
A concentrated solution for a hard water resistant and low COD hydraulic support comprises the following components in percentage by mass:
wherein the multifunctional surfactant is formed by compounding octanol polyoxyethylene ether sodium sulfate, methyl laurate ethoxylate potassium sulfonate and decyl alcohol polyoxyethylene ether carboxylic acid potassium according to the mass ratio of 1:1:1.
Wherein the rust-proof preservative is formed by compounding S-carboxyethyl thiosuccinic acid, diethanolamine and benzotriazole according to a mass ratio of 5:10:0.1.
The specific preparation method of the concentrated solution for the hydraulic support comprises the following steps:
(1) Adding S-carboxyethyl thiosuccinic acid, diethanolamine and benzotriazole into water according to the component proportion of the rust-proof preservative, and stirring for 10min at 30 ℃ to obtain a mixed solution;
(2) And (2) adding a multifunctional surfactant, a nonionic surfactant, a bacteriostat and a defoaming agent into the mixed solution obtained in the step (1), heating to 50 ℃ and preserving heat for 50min to obtain the modified polyurethane foam.
Comparative example 1
A typical concentrated solution for a hydraulic support comprises the following components in percentage by mass:
wherein the rust-proof preservative is compounded by diethanolamine sebacate, diethanolamine and benzotriazole according to a mass ratio of 5:10:0.1.
The specific preparation method of the concentrated solution for the hydraulic support of the comparative example comprises the following steps: adding a complexing agent into tap water, opening mechanical stirring, sequentially adding a lubricant, a nonionic surfactant and an antirust preservative, heating to 75 ℃ and preserving heat for 30min; then cooling to 45 ℃, and adding a bacteriostat and a defoaming agent.
Comparative example 2
A typical concentrated solution for a hydraulic support comprises the following components in percentage by mass:
wherein the lubricant is compounded by triethanolamine oleate and sulfonated ricinoleic acid potassium soap according to the mass ratio of 1:2.
Wherein the rust-proof preservative is compounded by diethanolamine sebacate, diethanolamine and benzotriazole according to a mass ratio of 5:10:0.1.
The specific preparation method of the concentrated solution for the hydraulic support of the comparative example comprises the following steps: adding a complexing agent into tap water, opening mechanical stirring, sequentially adding a lubricant, a nonionic surfactant and an antirust preservative, heating to 75 ℃ and preserving heat for 30min; then cooling to 45 ℃, and adding a bacteriostat and a defoaming agent.
Comparative example 3
A typical concentrated solution for a hydraulic support comprises the following components in percentage by mass:
wherein the lubricant is compounded by triethanolamine oleate and sulfonated ricinoleic acid potassium soap according to the mass ratio of 1:2.
Wherein the rust-proof preservative is compounded by diethanolamine sebacate, diethanolamine and benzotriazole according to a mass ratio of 5:10:0.1.
The specific preparation method of the concentrated solution for the hydraulic support of the comparative example comprises the following steps: adding a complexing agent into tap water, opening mechanical stirring, sequentially adding a lubricant, a nonionic surfactant and an antirust preservative, heating to 75 ℃ and preserving heat for 30min; then cooling to 45 ℃, and adding a bacteriostat and a defoaming agent.
The samples obtained in examples 1 to 3 and comparative examples 1 to 3 were subjected to raw liquid property evaluation according to coal industry standard MT/T76-2011 "emulsified oil for Hydraulic support, concentrated liquid and high water content hydraulic liquid", and the evaluation results are shown in Table 1. As can be seen from Table 1, the respective test results of the sample stock solutions obtained in examples 1 to 3 and comparative examples 1 to 3 all meet the standard requirements.
Table 1 results of evaluation of stock solutions samples of examples and comparative examples
The high-water-content hydraulic fluids obtained in examples 1-3 and comparative examples 1-3 were evaluated according to coal industry standard MT/T76-2011, each sample high-water-content hydraulic fluid was formulated according to a mass concentration of 5%, and the formulation was artificial hard water, and the hardness grades were 10, 20, 30 and 40, respectively. The evaluation results of the high water hydraulic fluids of the samples of examples 1 to 3 and comparative examples 1 to 3 are shown in tables 2, 3, 4 and 5, respectively, according to the hardness level of artificial hard water.
Table 2 evaluation results of examples and comparative examples of high aqueous hydraulic fluid samples (hardness grade of artificial hard water 10)
As can be seen from Table 2, the test results of the high water content hydraulic fluid samples of examples 1-3 and comparative examples 1-3 all meet the standard requirements with the artificial hard water formulation having a hardness rating of 10.
Table 3 evaluation results of examples and comparative examples of high aqueous hydraulic fluid samples (Artificial hard Water hardness grade 20)
As can be seen from Table 3, each of the test results of the high water content hydraulic fluid samples of examples 1 to 3, comparative example 2 and comparative example 3 satisfies the standard requirement by using the artificial hard water formulation with hardness grade of 20, but the high water content hydraulic fluid sample of comparative example 1 exhibits soap precipitation phenomenon, and the rust resistance and corrosion resistance do not satisfy the requirements.
Table 4 evaluation results of examples and comparative examples of high aqueous hydraulic fluid samples (Artificial hard Water hardness grade 30)
/>
As is clear from Table 4, each test result of the high water content hydraulic fluid samples of examples 1 to 3 and comparative example 3 satisfies the standard requirement by using the artificial hard water formulation with hardness grade of 30, but the high water content hydraulic fluid samples of comparative example 1 and comparative example 2 exhibit soap precipitation phenomenon, and the rust resistance and corrosion resistance do not satisfy the requirements.
Table 5 evaluation results of examples and comparative examples of high aqueous hydraulic fluid samples (Artificial hard Water hardness grade 40)
/>
As can be seen from Table 5, with the artificial hard water formulation of hardness grade 40, each test result of the high water content hydraulic fluid samples of examples 1 to 3 satisfies the standard requirements, but the high water content hydraulic fluid samples of comparative examples 1 to 3 all exhibit soap precipitation, and the rust resistance and corrosion resistance do not satisfy the requirements.
As is clear from the above tables 2 to 5, the concentrated liquid samples obtained in examples 1 to 3 of the present invention all have good hard water resistance, do not cause soap separation phenomenon with the increase of the hardness level of the liquid formulation water, and have excellent rust resistance and corrosion resistance. While the complexing agent is adopted to shield calcium and magnesium ions in hard water in the sample of the comparative example, soap is separated out in the sample of the comparative example when the hardness level of the liquid preparation water exceeds the complexing capability of the complexing agent; meanwhile, the rust prevention and corrosion prevention capabilities and the lubricating capability of the comparative sample are obviously reduced due to precipitation of soap.
The samples of examples 1 to 3 and comparative examples 1 to 3 of the present invention were respectively prepared with high water content hydraulic fluid at a mass concentration of 5% using artificial hard water having a hardness of 10, and COD of the high water content hydraulic fluid was detected according to HJ 828-2017 "Potassium dichromate method for determination of Water quality chemical oxygen demand", the detection results of which are shown in Table 6. As can be seen from Table 6, the COD values of the high water content hydraulic fluid samples of examples 1 to 3 of the present invention were significantly lower than those of the high water content hydraulic fluid samples of comparative examples 1 to 3. The main reason is that the multifunctional surfactant is introduced into the raw materials of the concentrated solution for the hydraulic support in the embodiments 1-3, so that the content of other additives (such as rust-proof preservative, bacteriostat and defoamer) can be reduced, and the COD value of the concentrated solution sample in the embodiments 1-3 is also reduced; the raw material cost is also reduced, so that the production cost is reduced, the preparation process of the concentrated solution is simpler, the used equipment is simple, the reaction condition is mild, the energy consumption is lower, and the industrialized mass production is easy to realize.
Table 6 COD values and production cost evaluation results of examples and comparative examples of high aqueous hydraulic fluid samples
| Evaluation item | Example 1 | Example 2 | Example 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| COD value, mg/L | 8200 | 8600 | 9000 | 16000 | 20000 | 25000 |
| Production cost | Low and low | Low and low | Low and low | High height | High height | High height |
For purposes of this disclosure, the terms "one embodiment," "some embodiments," "example," "a particular example," or "some examples," etc., mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, schematic representations of the above terms are not necessarily directed to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, the different embodiments or examples described in this specification and the features of the different embodiments or examples may be combined and combined by those skilled in the art without contradiction.
While embodiments of the present invention have been shown and described above, it will be understood that the above embodiments are illustrative and not to be construed as limiting the invention, and that variations, modifications, alternatives and variations may be made to the above embodiments by one of ordinary skill in the art within the scope of the invention.
Claims (8)
1. The concentrated solution for the hard water resistant and low-COD hydraulic support is characterized by comprising the following components in percentage by mass:
the multifunctional surfactant is one or the combination of more than two of fatty alcohol polyoxyethylene ether sulfate, fatty acid methyl ester ethoxylate sulfonate and fatty alcohol polyoxyethylene ether carboxylate; the fatty alcohol polyoxyethylene ether sulfate has a molecular formula of RO (C) 2 H 4 O) n SO 4 M, wherein: r is C8-C18 alkyl, n=8-15, M is K or Na; the fatty acid methyl ester ethoxylate sulfonate has a molecular formula of RO (C) 2 H 4 O) n CH(SO 3 M)COOCH 3 Wherein: r is C8-C16 alkyl, n=8-15, M is K or Na; the fatty alcohol polyoxyethylene ether carboxylate has a molecular general formula of RO (C) 2 H 4 O) n CH 2 COOM, wherein: r is C8-C16 alkyl, n=8-15, M is K or Na;
the nonionic surfactant is polyoxyethylene alkylamide or polyethylene glycol fatty acid ester;
the rust-proof preservative comprises S-carboxyethyl thiosuccinic acid, diethanolamine and benzotriazole.
2. The concentrated solution for the hard water resistant and low-COD hydraulic support, according to claim 1, wherein the multifunctional surfactant is prepared from fatty acid methyl ester ethoxylate sulfonate and fatty alcohol polyoxyethylene ether carboxylate according to a mass ratio of 1:1.
3. The hard water resistant and low COD hydraulic stent concentrate according to claim 1, wherein the mass ratio of the S-carboxyethylthiosuccinic acid to the diethanolamine and the benzotriazole is (4 to 7): (8-15): (0.1-0.3).
4. The hard water resistant, low COD hydraulic stent concentrate of claim 1, wherein the bacteriostatic agent is any one of s-triazine and isothiazolinone.
5. The hard water resistant, low COD hydraulic stent concentrate of claim 1 wherein the defoamer is a polyether modified silicone.
6. The method for preparing the hard water resistant and low-COD concentrated solution for the hydraulic support as claimed in any one of claims 1 to 5, which is characterized by comprising the following steps:
(1) Adding the antirust preservative into water according to a certain proportion, heating and stirring to obtain a mixed solution;
(2) And (3) adding a multifunctional surfactant, a nonionic surfactant, a bacteriostat and a defoaming agent into the mixed solution obtained in the step (1), and heating for reaction to obtain the concentrated solution for the hard water resistant and low-COD hydraulic bracket.
7. The method for producing a concentrated solution for a hard water resistant and low COD hydraulic support according to claim 6, wherein in the step (1), the temperature of the heating and stirring is 20 to 40℃and the stirring time is 5 to 20 minutes.
8. The method for preparing a concentrated solution for a hard water resistant and low COD hydraulic support according to claim 6, wherein in the step (2), the heating reaction temperature is 40-50 ℃ and the reaction time is 20-60 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210870310.3A CN115109637B (en) | 2022-07-22 | 2022-07-22 | Hard water resistant and low COD concentrated solution for hydraulic support and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210870310.3A CN115109637B (en) | 2022-07-22 | 2022-07-22 | Hard water resistant and low COD concentrated solution for hydraulic support and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115109637A CN115109637A (en) | 2022-09-27 |
| CN115109637B true CN115109637B (en) | 2023-10-24 |
Family
ID=83334617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210870310.3A Active CN115109637B (en) | 2022-07-22 | 2022-07-22 | Hard water resistant and low COD concentrated solution for hydraulic support and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115109637B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104531323A (en) * | 2014-12-30 | 2015-04-22 | 奎克化学（中国）有限公司 | Nitrite-free concentrated solution for rapidly biodegrading mine prop and preparation method |
| CN112852534A (en) * | 2021-01-25 | 2021-05-28 | 奎克化学（中国）有限公司 | Mine support solution and preparation method thereof |
-
2022
- 2022-07-22 CN CN202210870310.3A patent/CN115109637B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104531323A (en) * | 2014-12-30 | 2015-04-22 | 奎克化学（中国）有限公司 | Nitrite-free concentrated solution for rapidly biodegrading mine prop and preparation method |
| CN112852534A (en) * | 2021-01-25 | 2021-05-28 | 奎克化学（中国）有限公司 | Mine support solution and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王泽云,刘心建.环境友好洗涤产品创新之路.《中国洗涤用品工业》.2018,(第undefined期),63-67. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115109637A (en) | 2022-09-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111662773B (en) | Long-acting total-synthesis magnesium alloy cutting fluid and processing method | |
| CN108929666B (en) | Efficient blocking remover for sulfur-containing gas well | |
| CN104073333B (en) | Water-ethylene glycol nonflame hydraulic fluid and preparation method thereof | |
| CN101029273B (en) | Liquefied concentrate for hydraulic stand | |
| CN104531323B (en) | Nitrite-free concentrated solution for rapidly biodegrading mine prop and preparation method | |
| CN113652294A (en) | Low-carbon footprint micro-emulsified biodegradable metal working fluid and preparation method and application thereof | |
| CN110564378B (en) | Environment-friendly lubricant for drilling fluid and preparation method and application thereof | |
| CN110467960B (en) | Emulsified oil complexing agent, preparation method thereof, emulsified oil prepared from emulsified oil complexing agent and application of emulsified oil | |
| CN108998183B (en) | Smart phone frame synthetic type high-light cutting fluid and preparation method thereof | |
| CN102031186A (en) | Expanding oil and preparation method thereof | |
| CN108219911A (en) | Fully synthetic type hydraulic support concentrate and preparation method thereof | |
| CN115109637B (en) | Hard water resistant and low COD concentrated solution for hydraulic support and preparation method thereof | |
| CN112852534A (en) | Mine support solution and preparation method thereof | |
| CN114381319B (en) | Emulsified oil for copper and copper alloy wire drawing and preparation method thereof | |
| CN111253996B (en) | Biodegradable fully-mechanized mining support electro-hydraulic control concentrated solution and hydraulic fluid containing same | |
| CN112940833A (en) | Long-life environment-friendly cutting fluid and preparation method thereof | |
| CN116397233A (en) | Environment-friendly inter-process water-based antirust liquid and preparation method thereof | |
| CN111088096B (en) | Graphene oxide grafted modified oleic soap, concentrated solution for hydraulic support, preparation method and application | |
| CN113355150B (en) | Microemulsion cutting fluid and preparation method and application thereof | |
| CN108485788A (en) | A kind of long-life type water-glycol fire-retardand hydraulic fluid | |
| CN111635809B (en) | Water-soluble metal multi-wire cutting fluid | |
| CN112899061A (en) | Special water-based grinding fluid for hard alloy and preparation method thereof | |
| CN108048194B (en) | Emulsion for fine processing of steel workpiece with water solution hardness of more than 200ppm, preparation method and post-treatment process thereof | |
| CN112646655A (en) | High-quality low-oil-mist plant base oil micro-emulsified cutting fluid and preparation method thereof | |
| CN108559600B (en) | Emulsion for fine processing of steel workpiece, preparation method and post-treatment process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |