CN115094297A - Production method of thick Q420Q steel - Google Patents

Production method of thick Q420Q steel Download PDF

Info

Publication number
CN115094297A
CN115094297A CN202210487842.9A CN202210487842A CN115094297A CN 115094297 A CN115094297 A CN 115094297A CN 202210487842 A CN202210487842 A CN 202210487842A CN 115094297 A CN115094297 A CN 115094297A
Authority
CN
China
Prior art keywords
steel
thick
water
percent
casting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210487842.9A
Other languages
Chinese (zh)
Inventor
刘志国
李鑫
丁晓志
王宏盛
李文艺
宋立全
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Baotou Iron and Steel Group Co Ltd
Original Assignee
Baotou Iron and Steel Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Baotou Iron and Steel Group Co Ltd filed Critical Baotou Iron and Steel Group Co Ltd
Priority to CN202210487842.9A priority Critical patent/CN115094297A/en
Publication of CN115094297A publication Critical patent/CN115094297A/en
Pending legal-status Critical Current

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/04Making ferrous alloys by melting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • B22D11/114Treating the molten metal by using agitating or vibrating means
    • B22D11/115Treating the molten metal by using agitating or vibrating means by using magnetic fields
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • B22D11/116Refining the metal
    • B22D11/117Refining the metal by treating with gases
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/002Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Continuous Casting (AREA)

Abstract

The invention discloses a production method of thick Q420Q steel, which adopts technical measures on a casting machine, replaces a high-efficiency nozzle, reforms a fan-shaped section water inlet pipe, optimizes the electromagnetic stirring installation position, properly reduces the stirring force, formulates specific process parameters, and ensures that the surface quality of the prepared casting blank is good, the center segregation of the casting blank is light, and the negative segregation 'white and bright band' is weakened, thereby providing a precondition guarantee for rolling the steel plate with excellent quality and over 60mm thickness.

Description

Production method of thick Q420Q steel
Technical Field
The invention relates to the field of continuous casting in the metallurgical industry, in particular to a production method of thick Q420Q steel.
Background
In recent years, with the development of large span and high strength of highway bridges, the construction conditions are more and more complex, and new higher requirements are provided for the quality of steel, and the stress characteristics and the load of the highway bridges are different from those of railway bridges, particularly the production difficulty of the highway bridges with the thickness of more than 60mm is large, and the main expression is as follows: 1) cracking on the surface of the steel plate. The thick bridge steel has more component alloys and strong crack sensitivity, and even if slight cracks exist on the surface of a casting blank due to large rolling thickness, the cracks can not be welded after the thick steel plate is rolled, so that the steel plate is degraded or even rejected. 2) Flaw detection of the steel plate is not qualified. The thick specification, especially the bridge steel with the rolling thickness of more than 60mm, is required to meet the new energy flaw detection standard, a proper continuous casting process is required to be established to ensure the good metallurgical quality of a plate blank, the control of center segregation is the key point in the production process, for rolling an extra-thick steel plate, the small compression ratio is a great test for ensuring the qualified flaw detection, and when the center segregation of a casting blank is serious, segregants such as C, Mn, S and the like exist in the center corresponding to the rolling thickness, so that the flaw detection process cannot pass; on the other hand, the electromagnetic stirring position and parameters at the steel plate thickness 1/4 are not properly used, so that a serious negative segregation phenomenon appears at the casting blank thickness 1/4, equiaxed crystal bands which are regularly arranged like a mirror surface appear on a negative segregation white bright band, and during ultrasonic flaw detection, ultrasonic waves are reflected back, so that flaw detection is not successful. Therefore, the casting of qualified casting blanks is a prerequisite for obtaining steel plates with excellent quality.
The Chinese patent with the application number of 201811306461.6 discloses a low yield ratio Q420qNH steel plate and a preparation method thereof, and the prepared steel plate has the advantages of low yield ratio, good corrosion resistance, low-temperature toughness and the like, simple process flow, short production period and low production cost through reasonable component design and optimized heating and rolling processes. However, there is no description of how to improve the quality of the cast slab from the start of casting and obtain a steel sheet of acceptable quality.
The Chinese patent with the application number of 201310083385.8 discloses a continuous casting 80mm thick bridge steel Q420qE and a preparation process thereof, the document ensures the cleanliness of steel through reasonable component design and LF + VD process, adopts a high-temperature reactor cooling process to effectively avoid residual stress in the rapid cooling process, simultaneously reduces the hydrogen content in a steel plate, fully realizes the diffusion effect, and improves the flaw detection defect of the steel plate. The steel plate with various performances and qualified quality is obtained on the premise of excellent casting blank quality, but the document does not describe the steel plate.
The Chinese patent with the application number of 202110746594.0 discloses a Q420qENH heat-treatment-free steel plate for bridges and a manufacturing method thereof, measures are taken from smelting, refining, RH, continuous casting, heating and rolling links, heat treatment is not needed, and the Q420qENH steel plate for bridges with the thickness of less than 70mm can be rolled. However, the casting blank prepared in the continuous casting link of the document needs to be cleaned by flame, which indicates that the surface quality problem is not solved.
Disclosure of Invention
The invention aims to provide a production method of thick Q420Q steel, which casts a slab with qualified surface quality and internal quality by improving the technological parameters and equipment conditions of a casting machine and provides a precondition guarantee for rolling the slab into an ultra-thick steel plate with excellent quality of more than 60 mm.
In order to solve the technical problems, the invention adopts the following technical scheme:
the invention relates to a production method of thick Q420Q steel, which comprises the following chemical components in percentage by mass: 0.08 to 0.10 percent of C, 0.25 to 0.35 percent of Si, 1.5 to 1.6 percent of Mn, less than or equal to 0.015 percent of P, less than or equal to 0.005 percent of S, 0.017 to 0.027 percent of Als, 0.0008 to 0.0025 percent of Ca, 0.035 to 0.045 percent of Nb, 0.03 to 0.04 percent of V, 0.006 to 0.016 percent of Ti, and the balance of Fe and inevitable impurities; the specific production process comprises the following steps:
the casting section is 2200 mm by 300 mm;
during casting, water must be uniformly distributed, and the phenomenon of nozzle blockage cannot occur;
properly reducing the electromagnetic stirring intensity during casting, wherein the current value is 300A, and the frequency is 5 Hz; meanwhile, the electromagnetic stirring position is arranged between the 3-section outlet and the 4-section inlet;
smelting the molten steel to ensure that the nitrogen content is less than or equal to 40ppm, and installing a ladle down nozzle argon blowing device on the basis of adopting secondary protective casting by a casting machine, wherein the argon blowing device ensures that the periphery of the ladle down nozzle keeps an argon atmosphere, so that oxygen and nitrogen in the air are prevented from being sucked into the molten steel;
confirm control sector section radian and opening degree includes:
A. the radian error of the roller in the sector section and between the sections is less than or equal to 0.3 mm;
B. and calibrating and adjusting the opening degree of the sector section, and ensuring that the error is not more than 1 mm.
Further, guarantee that fan-shaped section nozzle does not have the jam, adopt the fourth generation novel high-efficient air water atomizing nozzle of smelting company in Beijing, the model: ZYGXPZ-91.
Further, install two cold water additional at fan-shaped section water pipe diameter 1/2 center and spray a parent tube automatic water diversion device, intake before flowing into the parent tube, for two the tunnel via the water distribution piece evenly distributed of parent tube water diversion device entry 1/2 department to equivalent flow direction both sides, guarantee the terminal shape in the inside liquid cavity of casting blank through the evenly distributed of cooling water, show improvement casting blank surface and internal quality.
Further, the superheat degree of the molten steel is controlled to be 15-30 ℃.
Further, the pulling speed is stabilized at 0.8 m/min.
Further, the water quantity of the wide side of the crystallizer is set to 4800L/min, and the water inlet temperature is set to 35-38 ℃; the secondary cooling water temperature is set to be 25-28 ℃, and the specific water amount is set to be 0.62L/kg steel.
Further, the mold flux was of a Stobber 34S-PA1-PE type.
Furthermore, after the casting blank is cut, the casting blank needs to be intensively stacked and slowly cooled for more than 48 hours.
Compared with the prior art, the invention has the beneficial technical effects that:
the invention adopts technical measures on the casting machine, changes the high-efficiency nozzle, reforms the fan-shaped section water inlet pipe, optimizes the electromagnetic stirring installation position and properly reduces the stirring force, formulates targeted process parameters, and ensures that the prepared casting blank has good surface quality, light center segregation of the casting blank and weakened negative segregation white bright band, thereby providing precondition guarantee for rolling the casting blank into an ultra-thick steel plate with excellent quality of more than 60 mm.
Drawings
The invention is further illustrated in the following description with reference to the drawings.
FIG. 1 is a low-magnification result chart of a cast slab of example 1.
FIG. 2 is a low-magnification result chart of the cast slab of example 2.
FIG. 3 is a low-magnification result chart of the cast slab of example 3.
FIG. 4 is a manual flaw detection pattern for the steel plate of example 1.
FIG. 5 is a manual flaw detection map of the steel plate of example 2.
FIG. 6 is a manual flaw detection map of a steel plate of example 3.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention more apparent, the technical solutions of the present invention will be described in detail and fully below with reference to the embodiments.
In order to evenly distribute water and not block the nozzle, the improved fan-shaped section nozzle is a fourth generation novel high-efficiency air-water atomizing nozzle (model: ZYGXPZ-91) of Beijing Zhongmei company; reform transform fan-shaped section inlet tube: the center of a water inlet pipe diameter 1/2 of the fan-shaped section is additionally provided with two cold water spraying strip base pipe automatic water distribution devices; the electromagnetic stirring positions are set at the 3-stage outlet and the 4-stage inlet, and meanwhile, the weaker stirring force is adopted, the current value is 300A, and the frequency is 5 Hz.
Accurately adjusting the radian and the opening degree of a sector section before casting: the radian error of the roller in the sector section and between the sections is less than or equal to 0.3mm, and the opening degree of the sector section is calibrated and adjusted, so that the error is not more than 1 mm.
Example 1:
the casting section is 2200 multiplied by 300, the crystallizer water is set to be 4800L/min during casting, and the water inlet temperature is 35 ℃; the secondary cooling water has the temperature of 25 ℃ and the specific water amount of 0.62L/kg steel; the superheat degree is controlled to be 15-20 ℃, and the pulling speed is stabilized at 0.8 m/min; the mold flux adopts Sidoberg 34S-PA1-PE mold flux; taking a tundish sample, wherein the nitrogen content is 36 ppm; and after the casting blank is cut, the casting blanks are integrally stacked and slowly cooled for more than 48 hours. The chemical composition is shown in Table 1. The center segregation of the casting blank prepared in the embodiment is graded as C1.0 according to YB/T4003-1997, and FIG. 1 is a result graph of the center segregation of the casting blank in the embodiment. No cracks were observed on the surface of the cast slab obtained in this example by surface inspection.
The steel plate with the thickness of 60mm rolled by the casting blank prepared by the embodiment has good surface quality and qualified performance, and is qualified according to the flaw detection standard of new energy. FIG. 4 is a manual flaw detection map of the present example.
Example 2:
the casting section is 2200 multiplied by 300, the crystallizer water is set to be 4800L/min during casting, and the water inlet temperature is 38 ℃; the secondary cooling water has the temperature of 28 ℃ and the specific water amount of 0.62L/kg steel; the superheat degree is controlled to be 25-30 ℃, and the pulling speed is stabilized at 0.8 m/min; the mold flux adopts Sidoberg 34S-PA1-PE mold flux; taking a tundish sample, wherein the nitrogen content is 43 ppm; and after the casting blank is cut, the casting blanks are integrally stacked and slowly cooled for more than 48 hours. The chemical composition is shown in table 1. The center segregation of the casting blank prepared in the embodiment is graded as C2.0 according to YB/T4003-1997, and FIG. 2 is a result graph of the center segregation of the casting blank in the embodiment. No cracks were observed on the surface of the cast slab obtained in this example by surface inspection.
The steel plate with the thickness of 80mm rolled by the casting blank prepared by the embodiment has good surface quality and qualified various performances, and is qualified according to the flaw detection standard of new energy. FIG. 5 is a manual flaw detection map of the present example.
Example 3:
the casting section is 2200 multiplied by 300, the crystallizer water is set to be 4800L/min during casting, and the water inlet temperature is 36 ℃; the secondary cooling water has the temperature of 27 ℃, and the specific water amount is set to be 0.62L/kg steel; the superheat degree is controlled to be 20-25 ℃, and the pulling speed is stabilized at 0.8 m/min; the mold flux adopts Sidoberg 34S-PA1-PE mold flux; taking a tundish sample, wherein the nitrogen content is 32 ppm; and after the casting blank is cut, the casting blanks are integrally stacked and slowly cooled for more than 48 hours. The chemical composition is shown in table 1. The center segregation of the casting blank prepared in the embodiment is graded as C0.5 according to YB/T4003-1997, and FIG. 3 is a result graph of the center segregation of the casting blank in the embodiment. No cracks were observed on the surface of the cast slab obtained in this example by surface inspection.
The steel plate with the thickness of 100mm rolled by the casting blank prepared by the embodiment has good surface quality and qualified performance, and is qualified according to the flaw detection standard of new energy. FIG. 6 is a manual flaw detection map of the present example.
TABLE 1 chemical composition of each example
Examples Steel grade C Si Mn P S Alt Als Ca Nb V Ti
Example 1 Q420q 0.091 0.29 1.54 0.012 0.003 0.022 0.019 0.0012 0.041 0.033 0.01
Example 2 Q420q 0.082 0.25 1.51 0.011 0.002 0.02 0.018 0.0009 0.035 0.031 0.007
Example 3 Q420q 0.098 0.34 1.59 0.014 0.004 0.029 0.027 0.0023 0.044 0.038 0.015
Therefore, the Q420Q bridge steel is cast according to the control method of the invention, the surface quality of the prepared casting blank is crack-free, the center segregation is reduced, the negative segregation white bright band is reduced, the surface quality of the casting blank is excellent after the casting blank is rolled into an extra-thick steel plate with the thickness of more than 60mm, all the performances are qualified, and the new energy flaw detection standard is met.
The above-described embodiments are merely illustrative of the preferred embodiments of the present invention, and do not limit the scope of the present invention, and various modifications and improvements of the technical solution of the present invention can be made by those skilled in the art without departing from the spirit of the present invention, and the technical solution of the present invention is defined by the claims.

Claims (8)

1. The production method of the thick Q420Q steel is characterized in that the thick Q420Q steel comprises the following chemical components in percentage by mass: 0.08 to 0.10 percent of C, 0.25 to 0.35 percent of Si, 1.5 to 1.6 percent of Mn, less than or equal to 0.015 percent of P, less than or equal to 0.005 percent of S, 0.017 to 0.027 percent of Als, 0.0008 to 0.0025 percent of Ca, 0.035 to 0.045 percent of Nb, 0.03 to 0.04 percent of V, 0.006 to 0.016 percent of Ti, and the balance of Fe and inevitable impurities; the specific production process comprises the following steps:
the casting section is 2200 mm by 300 mm;
during casting, water must be uniformly distributed, and the phenomenon of nozzle blockage cannot occur;
properly reducing the electromagnetic stirring intensity during casting, wherein the current value is 300A, and the frequency is 5 Hz; meanwhile, the electromagnetic stirring position is arranged between the 3-section outlet and the 4-section inlet;
smelting and treating the molten steel to enable the nitrogen content to be less than or equal to 40ppm, installing a ladle lower nozzle argon blowing device on the basis of adopting secondary protection casting by a casting machine, and enabling the argon blowing device to keep an argon atmosphere around the ladle lower nozzle so as to prevent oxygen and nitrogen in the air from being sucked into the molten steel;
confirm control fan-shaped section radian and opening degree, include:
A. the radian error of the roller in the sector section and between the sections is less than or equal to 0.3 mm;
B. and calibrating and adjusting the opening degree of the sector section, and ensuring that the error is not more than 1 mm.
2. The method for producing the thick Q420Q steel according to claim 1, wherein the non-clogging of the fan-shaped nozzle is ensured, and a fourth-generation novel high-efficiency gas-water atomizing nozzle of Beijing Zhongmei company is adopted, the model is as follows: ZYGXPZ-91.
3. The method for producing the thick Q420Q steel according to claim 1, wherein two cold water spray strip base pipe automatic water diversion devices are additionally installed at the center of a water inlet pipe diameter 1/2 of the segment, inlet water is uniformly distributed into two paths through water diversion pieces at inlets 1/2 of the base pipe water diversion devices before flowing into the base pipe, the two paths flow to two sides in equal amount, the shape of the tail end of a liquid cavity inside the casting blank is guaranteed through uniform distribution of cooling water, and the surface quality and the internal quality of the casting blank are remarkably improved.
4. The method for producing the thick Q420Q steel as claimed in claim 1, wherein the superheat degree of the molten steel is controlled to be 15-30 ℃.
5. The method of producing thick gauge Q420Q steel according to claim 1, wherein the pull rate is stabilized at 0.8 m/min.
6. The method for producing the thick Q420Q steel according to claim 1, wherein the amount of water on the wide side of the crystallizer is set at 4800L/min, and the temperature of inlet water is set at 35-38 ℃; the secondary cooling water temperature is set to be 25-28 ℃, and the specific water amount is set to be 0.62L/kg steel.
7. The method for producing thick Q420Q steel according to claim 1, wherein the mold flux is of the type Stedberg 34S-PA 1-PE.
8. The method for producing the thick Q420Q steel according to claim 1, wherein the slab requires intensive stacking and slow cooling for more than 48 hours after the slab is cut.
CN202210487842.9A 2022-05-06 2022-05-06 Production method of thick Q420Q steel Pending CN115094297A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210487842.9A CN115094297A (en) 2022-05-06 2022-05-06 Production method of thick Q420Q steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210487842.9A CN115094297A (en) 2022-05-06 2022-05-06 Production method of thick Q420Q steel

Publications (1)

Publication Number Publication Date
CN115094297A true CN115094297A (en) 2022-09-23

Family

ID=83287038

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210487842.9A Pending CN115094297A (en) 2022-05-06 2022-05-06 Production method of thick Q420Q steel

Country Status (1)

Country Link
CN (1) CN115094297A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101513695A (en) * 2009-04-03 2009-08-26 燕山大学 Welding method of Q420qE grade ultra-low-carbon bainite steel for bridges
CN103572023A (en) * 2013-10-24 2014-02-12 南京钢铁股份有限公司 Method for producing ultra-fine grains on surface layer of thick/ultra-thick low-alloy steel plate
CN108330399A (en) * 2018-01-09 2018-07-27 唐山钢铁集团有限责任公司 A kind of low-cost and high-performance bridge steel and its production method
CN114054707A (en) * 2021-10-11 2022-02-18 包头钢铁(集团)有限责任公司 Method for reducing center segregation of pipeline steel continuous casting billet
CN114346194A (en) * 2021-12-16 2022-04-15 包头钢铁(集团)有限责任公司 Q1100D ultrahigh-strength steel casting method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101513695A (en) * 2009-04-03 2009-08-26 燕山大学 Welding method of Q420qE grade ultra-low-carbon bainite steel for bridges
CN103572023A (en) * 2013-10-24 2014-02-12 南京钢铁股份有限公司 Method for producing ultra-fine grains on surface layer of thick/ultra-thick low-alloy steel plate
CN108330399A (en) * 2018-01-09 2018-07-27 唐山钢铁集团有限责任公司 A kind of low-cost and high-performance bridge steel and its production method
CN114054707A (en) * 2021-10-11 2022-02-18 包头钢铁(集团)有限责任公司 Method for reducing center segregation of pipeline steel continuous casting billet
CN114346194A (en) * 2021-12-16 2022-04-15 包头钢铁(集团)有限责任公司 Q1100D ultrahigh-strength steel casting method

Similar Documents

Publication Publication Date Title
CN103160734B (en) A kind of pressurized vessel P460NL1 (L2) super-thick steel plate and production method thereof
CN111636034B (en) Production method of corrosion-resistant rare earth high-performance bridge steel Q500qE wide and thick steel plate
CN113145816B (en) Control method for reducing medium carbon steel structure defects
CN115418559B (en) High-strength and high-toughness hot rolled H-shaped steel for building and preparation method thereof
CN113046652B (en) 420 MPa-grade weather-proof bridge steel and manufacturing method thereof
CN113832296A (en) Rapid desulfurization method of slab steel in LF refining furnace
CN111118257A (en) Heat treatment method for improving impact toughness of boron-containing thick hydroelectric steel plate core
CN115011878A (en) Round steel with high sulfuric acid dew point corrosion resistance and preparation method thereof
CN111471821A (en) Production method of pure steel capable of avoiding unqualified flaw detection
CN114346194A (en) Q1100D ultrahigh-strength steel casting method
CN115094297A (en) Production method of thick Q420Q steel
CN118186292A (en) Production method of large-wall-thickness pipeline steel with improved carbon dioxide corrosion resistance and toughness
CN106825463A (en) A kind of method that billet caster produces low-carbon (LC) Ni Mo steel alloys
CN113699431A (en) Method for reducing surface cracks of low alloy steel
CN106825473B (en) Method for improving surface quality of high-strength weather-resistant H-shaped steel
CN112743053A (en) Crystallizer for solving peritectic steel continuous casting slab surface cracks and control method
CN104084550A (en) Continuous casting plate blank production control method for rolled thick plate
CN105149521A (en) Subway internal steel frame casting and production technology thereof
CN112743052A (en) Slab crystallizer for solving casting blank narrow surface cracks and control method
CN108286020B (en) Super-thick high-strength high-density steel plate for manufacturing large structural component and manufacturing method thereof
CN113732258B (en) Method for reducing incidence rate of transverse cracks of microalloyed special-shaped blank
CN117047059B (en) Continuous casting billet for wind tower steel and central quality control method thereof
CN112605361B (en) Control method for transverse crack defect on surface of 75Cr1 steel
CN115351254B (en) Method for improving flaw detection qualification rate of low-alloy medium plate formed by continuous casting head and tail blanks
CN114438396B (en) Production method of round steel for high-strength bolt for severe cold resistant power transmission tower

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20220923