CN115078240A - Oil gas pipeline corrosion monitoring test device - Google Patents

Oil gas pipeline corrosion monitoring test device Download PDF

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Publication number
CN115078240A
CN115078240A CN202210915791.5A CN202210915791A CN115078240A CN 115078240 A CN115078240 A CN 115078240A CN 202210915791 A CN202210915791 A CN 202210915791A CN 115078240 A CN115078240 A CN 115078240A
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China
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hanging piece
corrosion
test
temperature
weightlessness
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CN202210915791.5A
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吴林霜
廖柯熹
覃敏
王敏安
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Southwest Petroleum University
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Southwest Petroleum University
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N17/00Investigating resistance of materials to the weather, to corrosion, or to light
    • G01N17/006Investigating resistance of materials to the weather, to corrosion, or to light of metals
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N17/00Investigating resistance of materials to the weather, to corrosion, or to light
    • G01N17/02Electrochemical measuring systems for weathering, corrosion or corrosion-protection measurement

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
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Abstract

The invention discloses an oil and gas pipeline corrosion monitoring test device, and relates to the field of oil and gas pipeline corrosion monitoring. The invention provides an oil-gas pipeline corrosion monitoring test device aiming at the problems that the existing oil-gas pipeline corrosion test can not truly restore the on-site working condition of a pipeline and can not further study the corrosion conditions of different positions and different directions of the pipeline wall. Not only the on-site flowing state of the oil-gas pipeline is reduced, but also the corrosion conditions of different positions and different directions of the pipe wall can be tested, and an electrochemical test and a corrosion weight loss test can be simultaneously carried out, so that the on-site corrosion condition of the oil-gas pipeline can be effectively predicted.

Description

Oil gas pipeline corrosion monitoring test device
Technical Field
The invention relates to an oil and gas pipeline corrosion monitoring test device, and relates to the field of oil and gas pipeline corrosion monitoring.
Background
More and more acid gas fields enter the development line worldwide, H 2 S、CO 2 And serious pipeline corrosion is caused by various corrosive media, so that a plurality of safety accidents are caused, and the normal production order of the oil and gas field is seriously influenced. Therefore, a series of corrosion monitoring and detecting technologies, corrosion control technologies and the like are generated and applied to corrosion prevention of oil and gas fields, and play an important role. The corrosion monitoring is carried out on the pipeline, the potential failure risk is found in time, the economic loss and the environmental pollution caused by the pipeline leakage are avoided, and the method has important significance.
At present, hanging piece monitoring and probe monitoring are the most widely applied monitoring methods in oil and gas fields. The corrosion coupon method is the most traditional corrosion monitoring means, namely, the corrosion coupon is inserted into a medium and taken out after a period of time, and the corrosion degree is evaluated by measuring the change of the mass of a test piece and accumulating the change of the mass of a material caused by corrosion in unit time. The technical knowledge required by the probe for monitoring is simple, the monitoring period is short, the result analysis difficulty is general, and the probe is mainly used for measuring the uniform corrosion rate of metal.
In order to reasonably predict the corrosion condition of the natural gas pipeline, the flow conditions of the site, including gas concentration, liquid temperature and the like, need to be reduced. However, most of the existing oil and gas pipeline corrosion test is carried out in a reaction kettle, the flowing state of the pipeline cannot be really reduced, the method is far away from the flowing working condition of the pipeline on site, and the corrosion conditions of different positions and different directions of the pipeline wall cannot be further researched, so that the test result of the reaction kettle and the corrosion conditions on site have larger errors, and the pipeline is difficult to be accurately predicted in a corrosion mode.
Disclosure of Invention
The purpose of the invention is as follows: aiming at the problems in the prior art, the invention aims to provide an oil and gas pipeline corrosion monitoring test device which can reduce the flow state of gas-liquid two-phase flow of pipelines in an oil and gas station and effectively monitor the corrosion condition of the pipelines under different working conditions. An oil and gas pipeline corrosion monitoring test device is composed of a liquid storage tank 1, a centrifugal pump 2, a gas cylinder pressure reducing valve 3, a high-pressure gas cylinder 4, a liquid control valve 5, a reference electrode 6, an auxiliary electrode 7, an electrode placing rod 8, a first hanger rack 9, a second hanger rack 10, a third hanger rack 11, a working electrode 12, a first weightlessness hanger 13, a second weightlessness hanger 14, a third weightlessness hanger 15, an electrochemical workstation 16, a terminal processor 17, a corrosion test pipe section 18, a liquid outlet control valve 19, a hanger probe rack prying device 20, a controller 21, an electromagnetic flowmeter 22, a temperature detector 23, a gas concentration detector 24, an electric heating rod 25, a refrigerating pipe 26 and a pipeline connecting the devices.
The device is characterized by comprising a temperature detector 23, a gas concentration detector 24, an electric heating rod 25 and a refrigerating pipe 26 which are arranged in the liquid storage tank 1, wherein gas in the high-pressure gas cylinder 4 enters the liquid storage tank 1 through a gas cylinder reducing valve 3. The liquid in the liquid storage tank 1 passes through the centrifugal pump 2 and the liquid control valve 5 and then is input into the corrosion test pipe section 18, flows out of the liquid outlet control valve 19, is metered by the electromagnetic flowmeter 22 and then is input back into the liquid storage tank 1. A reference electrode 6, an auxiliary electrode 7, a working electrode 12, a weightless hanging piece I13, a weightless hanging piece II 14 and a weightless hanging piece III 15 are sequentially arranged in a corrosion test pipe section 18, the auxiliary electrode 7 is arranged on the corrosion test pipe section 18 by depending on an electrode placing rod 8, and the weightless hanging piece I13, the weightless hanging piece II 14 and the weightless hanging piece III 15 are respectively arranged on the corrosion test pipe section 18 by depending on a hanging piece frame I9, a hanging piece frame II 10 and a hanging piece frame III 11. The electrode placing rod 8, the first film hanging frame 9, the second film hanging frame 10 and the third film hanging frame 11 are all fixed by a film hanging probe rack prying device 20. The reference electrode 6, the auxiliary electrode 7 and the working electrode 12 are all connected to an electrochemical workstation 16, and the electrochemical workstation 16 is connected to a terminal processor 17.
The corrosion test pipe section 18 can simultaneously carry out electrochemical corrosion test and corrosion weight loss test, the reference electrode 6, the auxiliary electrode 7 and the working electrode 12 are connected to the electrochemical workstation 16, and can carry out open-circuit potential, electrochemical impedance spectrum and polarization curve test to realize the calculation of real-time corrosion rate. And the weightlessness hanging piece I13, the weightlessness hanging piece II 14 and the weightlessness hanging piece III 15 are used in a matching way, the average corrosion rate is calculated through a weightlessness formula, and after the experiment is finished, the corrosion product can be represented through a scanning electron microscope and an X-ray diffractometer after testing.
The two ends of the corrosion test pipe section 18 are provided with angle scales, and the corrosion test of 360-degree different directions of the pipe wall can be carried out by rotating the specific scales.
The hanging piece probe rack prying device 20 is composed of a prying base 26, a fixing rod 27, a telescopic knob 28, a scale rod 29, a fixing clamp rod 30 and a fixing clamp 31, and can read the insertion depth of each sample in a corrosion test pipe section through the scale shown by the scale rod 29 so as to carry out corrosion tests with different insertion depths.
The controller 21 is connected with a centrifugal pump 2, a temperature detector 23, a gas concentration detector 24, an electric heating rod 25 and a refrigerating pipe 26. The centrifugal pump 2 is adjusted through the controller 21 to achieve the rotating speed required by the test, and the temperature detector 23 and the gas concentration detector 24 can transmit and display the temperature and liquid concentration data to the controller 21 in real time, so that the working condition information in the liquid storage tank 1 can be conveniently mastered at any time. Once the liquid temperature is lower than the set temperature through the temperature setting on the controller, the controller 21 sends a signal to the electric heating rod 25 for heating until the temperature reaches the experimental temperature; when the liquid temperature is higher than the set temperature, the controller 21 sends a signal to the refrigeration pipe 26 to store liquid and refrigerate, so as to achieve the purpose of reducing the temperature.
Due to the adoption of the technical scheme, the invention can achieve the following beneficial effects:
the used experimental liquid circulates through the liquid storage tank 1, the centrifugal pump 2, the liquid control valve 5, the liquid outlet control valve 19 and the electromagnetic flow meter 22, the ion concentration in the whole experimental process is basically kept constant, and the experimental device has the characteristics of economy and practicability.
The temperature detector 23, the gas concentration detector 24, the electric heating rod 25 and the refrigerating pipe 26 are arranged in the liquid storage tank 1, the temperature detector 23 and the gas concentration detector 24 can transmit and display temperature and liquid concentration data to the controller 21 in real time, and working condition information in the liquid storage tank 1 can be conveniently mastered at any time. Once the liquid temperature is lower than the set temperature, the controller 21 sends a signal to the electrical bar 25 until the temperature reaches the experimental temperature, by temperature setting on the controller; when the liquid temperature is higher than the set temperature, the controller 21 sends a signal to the refrigerating pipe 26 to achieve the purpose of cooling, so that the phenomenon that the liquid medium is overheated due to the environment temperature or the overlong starting time of the centrifugal pump 2 is prevented, the test safety is guaranteed, the liquid temperature is controlled at the set temperature of the test all the time, and the test accuracy is improved.
The corrosion test pipe section 18 can simultaneously perform an electrochemical corrosion test and a corrosion weight loss test, and can refer to the corrosion data results mutually so as to make a more accurate prediction, reduce the corrosion test time and save test resources.
The corrosion test tube segment 18 is rotatable 360 degrees about the central axis of the pipe to perform corrosion tests at different angular orientations, with the scale specifying the sample insertion angle.
The coupon probe holder skid-mounted device 20 can fix the coupon and the probe holder, and can accurately read the insertion depth of the coupon probe in the corrosion test pipe section 18 so as to perform corrosion tests with different insertion depths.
Drawings
FIG. 1 is a schematic structural diagram of an oil and gas pipeline corrosion monitoring test device provided by the invention.
In the figure, a liquid storage tank 1, a centrifugal pump 2, a gas cylinder pressure reducing valve 3, a high-pressure gas cylinder 4, a liquid control valve 5, a reference electrode 6, an auxiliary electrode 7, an electrode placing rod 8, a first hanging piece frame 9, a second hanging piece frame 10, a third hanging piece frame 11, a working electrode 12, a first weightless hanging piece 13, a second weightless hanging piece 14, a third weightless hanging piece 15, an electrochemical workstation 16, a terminal processor 17, a corrosion test pipe section 18, a liquid outlet control valve 19, a hanging piece probe frame skid device 20, a controller 21, an electromagnetic flowmeter 22, a temperature detector 23, a gas concentration detector 24, an electric heating rod 25 and a refrigerating pipe 26 are arranged.
FIG. 2 is a schematic diagram of a hanger probe holder skid-mounted device of the oil-gas pipeline corrosion monitoring test device, which shows the structural composition of the hanger probe holder skid-mounted device.
The drawing shows a prying base 26, a fixing rod 27, a telescopic knob 28, a scale rod 29, a fixing clamp rod 30 and a fixing clamp 31.
Detailed Description
The present invention will be further described with reference to the accompanying drawings, but the present invention is not limited to the following embodiments.
The invention relates to an oil and gas pipeline corrosion monitoring test device which comprises a liquid storage tank 1, a centrifugal pump 2, a gas cylinder pressure reducing valve 3, a high-pressure gas cylinder 4, a liquid control valve 5, a reference electrode 6, an auxiliary electrode 7, an electrode placing rod 8, a first hanging piece frame 9, a second hanging piece frame 10, a third hanging piece frame 11, a working electrode 12, a first weightless hanging piece 13, a second weightless hanging piece 14, a third weightless hanging piece 15, an electrochemical workstation 16, a terminal processor 17, a corrosion test pipe section 18, a liquid outlet control valve 19, a hanging piece probe rack device prying device 20, a controller 21, an electromagnetic flowmeter 22, a temperature detector 23, a gas concentration detector 24, an electric heating rod 25, a refrigerating pipe 26 and a pipeline connected with the equipment.
The specific implementation mode is as follows:
firstly, after a weightless hanging piece I13, a weightless hanging piece II 14 and a weightless hanging piece III 15 are respectively fixed on a hanging piece frame I9, a hanging piece frame II 10 and a hanging piece frame III 11, and a working electrode 12 is arranged on an electrode placing rod 8, a reference electrode 6, an auxiliary electrode 7, the working electrode 12, the weightless hanging piece I13, the weightless hanging piece II 14 and the weightless hanging piece III 15 are sequentially hung from left to right through a fixing clamp 31 in a hanging piece probe frame skid-mounting device 20. The length of the scale rod 29 is adjusted through the telescopic knob 28, the position, which is flush with the upper end of the corrosion test pipe section 18, of the bottom end of the film hanger or the electrode placing rod is recorded as scale 1, the depth of insertion required by the experiment is recorded as scale 2 after the scale 1 is added, and the telescopic knob 28 is screwed and fixed after the telescopic knob 29 is adjusted to the scale 2.
And step two, pouring the prepared experimental solution into the liquid storage tank 1. And (3) opening the controller 21, setting the temperature to be the temperature required by the experiment, immediately starting heating by the electric heating rod 25, opening the gas cylinder pressure reducing valve 3, introducing the gas in the gas cylinder into the liquid storage tank 1, and completely discharging the air in the liquid storage tank 1.
And thirdly, opening the centrifugal pump 2, the liquid control valve 5 and the liquid outlet control valve 19 to enable the test solution to enter the corrosion test pipe section 11, closing the centrifugal pump 2, the liquid control valve 5 and the liquid outlet control valve 19 in sequence after the corrosion test pipe section 18 reaches a full liquid state, and discharging all air in the corrosion test pipe section 18 after a period of time.
And fourthly, opening the liquid control valve 5, the liquid outlet control valve 19 and the electromagnetic flow meter 22 to enable the liquid to flow under the driving of the gas.
And fifthly, setting the rotating speed of the centrifugal pump on the controller 21, and displaying the gas concentration and the medium temperature by a gas concentration detector 24 through a temperature detector 23. After the gas concentration, the liquid medium temperature and the data displayed by the electromagnetic flowmeter 22 are stable, the electrochemical workstation 16 and the terminal processor 17 are started, the electrochemical workstation is connected to the reference electrode 6, the auxiliary electrode 7 and the working electrode 12 after preheating, the electrochemical testing steps are controlled on the terminal processor 17, and the tests of open-circuit potential, electrochemical impedance spectrum, polarization curve and the like are completed in sequence.
And sixthly, closing the centrifugal pump 2, the controller 21, the gas cylinder reducing valve 3, the electrochemical workstation 16, the liquid control valve 5 and the liquid outlet control valve 19 after the electrochemical test is finished.
And seventhly, taking out the reference electrode 6, the auxiliary electrode 7, the working electrode 12, the first weightlessness hanging piece 13, the second weightlessness hanging piece 14 and the third weightlessness hanging piece 15.
And eighthly, calculating the weight loss rate by using the first weight loss hanging piece 13, the second weight loss hanging piece 14 and the third weight loss hanging piece 15.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the present invention. Any modification, equivalent replacement, and improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (4)

1. The utility model provides an oil gas pipeline corrosion monitoring test device, its characterized in that is equipped with temperature detector (23) in including liquid storage pot (1), gas concentration detector (24), electric bar (25), refrigeration pipe (26), and the gas in high-pressure gas cylinder (4) passes through gas cylinder relief pressure valve (3) and gets into in liquid storage pot (1). Liquid in the liquid storage tank (1) passes through the centrifugal pump (2) and the liquid control valve (5) and then is input into the corrosion test pipe section (18), and the liquid flows out of the liquid outlet control valve (19) and is metered by the electromagnetic flowmeter (22) and then is transmitted back into the liquid storage tank (1). A reference electrode (6), an auxiliary electrode (7), a working electrode (12), a weightlessness hanging piece I (13), a weightlessness hanging piece II (14) and a weightlessness hanging piece III (15) are sequentially arranged in a corrosion test pipe section (18), the auxiliary electrode (7) is arranged on the corrosion test pipe section (18) by depending on an electrode placing rod (8), and the weightlessness hanging piece I (13), the weightlessness hanging piece II (14) and the weightlessness hanging piece III (15) are respectively mounted on a hanging piece frame I (9), a hanging piece frame II (10) and a hanging piece frame III (11) by depending on a hanging piece frame I (9), a hanging piece frame II (10) and a hanging piece frame III (11) and are arranged on the corrosion pipe section test (18). The electrode placing rod (8), the first hanging piece rack (9), the second hanging piece rack (10) and the third hanging piece rack (11) are fixed by a hanging piece probe rack skid-mounted device (20). The reference electrode (6), the auxiliary electrode (7) and the working electrode (12) transmit data to the terminal processor (17) through connecting an electrochemical workstation (16). The corrosion test pipe section (18) can simultaneously carry out electrochemical corrosion test and corrosion weight loss test, the reference electrode (6), the auxiliary electrode (7) and the working electrode (12) are connected to the electrochemical workstation (16), open-circuit potential, electrochemical impedance spectrum and polarization curve test can be carried out, and real-time corrosion rate calculation is realized. And a weightlessness hanging piece I (13), a weightlessness hanging piece II (14) and a weightlessness hanging piece III (15) are used in a matching way, the average corrosion rate is calculated through a weightlessness formula, and after the experiment is finished, the corrosion product can be represented after the test of a scanning electron microscope and an X-ray diffractometer.
2. The oil and gas pipeline corrosion monitoring test device of claim 1, characterized in that: the two ends of the corrosion test pipe section (18) are provided with angle scales, and 360-degree corrosion tests in different directions of the pipe wall can be performed by rotating the specific scales.
3. The oil and gas pipeline corrosion monitoring test device of claim 1, characterized in that: the hanging piece probe rack prying device (20) is composed of a prying base (26), a fixing rod (27), a telescopic knob (28), a scale rod (29), a fixing clamping rod (30) and a fixing clamp (31), and can read out the insertion depth of each sample in a corrosion test pipe section through scales shown by the scale rod (29) so as to carry out corrosion tests with different insertion depths.
4. The oil and gas pipeline corrosion monitoring test device of claim 1, characterized in that: the controller (21) is connected with a centrifugal pump (2), a temperature detector (23), a gas concentration detector (24), an electric heating rod (25) and a refrigerating pipe (26). Centrifugal pump (2) is adjusted through controller (21) to reach the required rotational speed of experiment, temperature detector (23) and gas concentration detector (24) can be with temperature and liquid concentration data real-time transmission and show to controller (21) on, the operating mode information in liquid storage pot (1) is conveniently mastered at any time. Once the temperature of the liquid is lower than the set temperature through temperature setting on the controller, the controller (21) sends a signal to the electric heating rod (25) for heating until the temperature reaches the experimental temperature; when the liquid temperature is higher than the set temperature, the controller (21) sends a signal to the refrigerating pipe (26) for liquid storage and refrigeration so as to achieve the purpose of temperature reduction.
CN202210915791.5A 2022-08-01 2022-08-01 Oil gas pipeline corrosion monitoring test device Pending CN115078240A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201594066U (en) * 2009-12-21 2010-09-29 钢铁研究总院青岛海洋腐蚀研究所 Simulated petrochemical pipeline erosion-corrosion monitoring test device
US20130186168A1 (en) * 2011-12-14 2013-07-25 Exxonmobil Research And Engineering Company System and method for enhancing corrosion rate determination in process equipment using a telescoping/rotating sensor
CN109100295A (en) * 2018-10-18 2018-12-28 西南石油大学 A kind of adjustable autoclave film hangers
CN209014438U (en) * 2018-10-18 2019-06-21 西南石油大学 A kind of adjustable autoclave film hangers
CN111624153A (en) * 2020-07-09 2020-09-04 西南石油大学 Mountain region moisture pipeline gas-liquid two-phase flow corrosion test device
CN113740240A (en) * 2021-09-09 2021-12-03 中国石油化工股份有限公司 Corrosion inhibition performance testing device and method of corrosion inhibitor and application

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201594066U (en) * 2009-12-21 2010-09-29 钢铁研究总院青岛海洋腐蚀研究所 Simulated petrochemical pipeline erosion-corrosion monitoring test device
US20130186168A1 (en) * 2011-12-14 2013-07-25 Exxonmobil Research And Engineering Company System and method for enhancing corrosion rate determination in process equipment using a telescoping/rotating sensor
CN109100295A (en) * 2018-10-18 2018-12-28 西南石油大学 A kind of adjustable autoclave film hangers
CN209014438U (en) * 2018-10-18 2019-06-21 西南石油大学 A kind of adjustable autoclave film hangers
CN111624153A (en) * 2020-07-09 2020-09-04 西南石油大学 Mountain region moisture pipeline gas-liquid two-phase flow corrosion test device
CN113740240A (en) * 2021-09-09 2021-12-03 中国石油化工股份有限公司 Corrosion inhibition performance testing device and method of corrosion inhibitor and application

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