CN115074026A - Carbon fiber corona roller for lithium battery aluminum foil - Google Patents

Carbon fiber corona roller for lithium battery aluminum foil Download PDF

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Publication number
CN115074026A
CN115074026A CN202210770170.2A CN202210770170A CN115074026A CN 115074026 A CN115074026 A CN 115074026A CN 202210770170 A CN202210770170 A CN 202210770170A CN 115074026 A CN115074026 A CN 115074026A
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China
Prior art keywords
carbon fiber
roller
parts
lithium battery
aluminum foil
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Pending
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CN202210770170.2A
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Chinese (zh)
Inventor
杨传坤
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Ma'anshan Oukai New Material Technology Co ltd
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Ma'anshan Oukai New Material Technology Co ltd
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Priority to CN202210770170.2A priority Critical patent/CN115074026A/en
Publication of CN115074026A publication Critical patent/CN115074026A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a carbon fiber corona roller for a lithium battery aluminum foil, which belongs to the technical field of corona rollers and comprises a carbon fiber roller and a coating coated on the surface of the carbon fiber roller, wherein the coating is made of a rubber composition; the rubber composition comprises the following raw materials in parts by weight: 90-100 parts of methyl vinyl silicone rubber, 10-12 parts of stabilizer, 10-12 parts of white carbon black, 1-2 parts of silicone oil and 3-5 parts of vulcanizing agent, wherein a C-F bond is introduced into the stabilizer to improve the chemical stability of the product, fluorine atoms endow the rubber with excellent thermal stability, chemical stability and oxidation resistance, and octavinyl-POSS can be used as a nano filler to improve the mechanical property of the product, is added with silicone oil to facilitate dispersion, is convenient to combine with the silicone rubber in the later vulcanization process, improves the corona resistance of the corona roller, is not easy to puncture and has good aging resistance.

Description

Carbon fiber corona roller for lithium battery aluminum foil
Technical Field
The invention belongs to the technical field of corona rollers, and particularly relates to a carbon fiber corona roller for a lithium battery aluminum foil.
Background
Need carry out corona treatment in the lithium cell aluminium foil course of working, current corona roller surface rigidity is low, stand wear and tear poor, and the quality is big, inertia is big, inconvenient in processing and the use, restriction production efficiency, carbon-fibre composite compares with metal material and plastics, had both had the characteristic of general carbon material: the corona roller has the advantages of high temperature resistance, friction resistance, electric conduction, heat conduction, small expansion coefficient and the like, has the excellent characteristics of high specific strength specific modulus, fatigue resistance, good shock absorption performance, good damage safety performance, good forming process and the like, and is widely applied in various modern industrial fields, so the carbon fiber roller is used in the preparation process of the corona roller to reduce the quality of the corona roller.
Because the corona roller is used in a high-voltage electric field for a long time, the coating is required to have excellent electric insulation, arc resistance, electric aging resistance and the like, but the ideal effect cannot be achieved by the existing corona roller.
Disclosure of Invention
In order to solve the technical problems mentioned in the background technology, the invention provides a carbon fiber corona roller for a lithium battery aluminum foil.
The purpose of the invention can be realized by the following technical scheme:
a carbon fiber corona roller for a lithium battery aluminum foil comprises a carbon fiber roller and a coating coated on the surface of the carbon fiber roller, wherein the coating is made of a rubber composition;
the rubber composition comprises the following raw materials in parts by weight:
90-100 parts of methyl vinyl silicone rubber, 10-12 parts of stabilizer, 10-12 parts of white carbon black, 1-2 parts of silicone oil and 3-5 parts of vulcanizing agent;
the stabilizer is prepared by the following steps:
adding 2, 2, 2-trifluoro-N- (2-mercaptoethyl) acetamide, octavinyl-POSS and photoinitiator 2-hydroxy-2-methyl-1-phenyl-1-acetone into dispersant dichloromethane, stirring for 1h under the condition of ultraviolet wavelength of 365nm, and removing the dichloromethane after stirring to obtain the stabilizer.
Further, 2, 2, 2-trifluoro-N- (2-mercaptoethyl) acetamide, octavinyl-POSS, and 2-hydroxy-2-methyl-1-phenyl-1-propanone are used in a molar ratio of 1.5 to 1.6: 0.5: 0.6.
further, the vulcanizing agent is 2, 5-dimethyl-2, 5-bis (t-butylperoxy) hexane.
A carbon fiber corona roller for a lithium battery aluminum foil is prepared by the following steps:
step one, putting the rubber composition into a rubber mixing mill for mixing;
step two, uniformly coating the mixed rubber composition on a carbon fiber roller, wrapping the carbon fiber roller with cloth, and then putting the carbon fiber roller into a vulcanizing tank for vulcanization;
and step three, cooling to 20-30 ℃ after vulcanization, and grinding the surface of the coating until the thickness of the coating meets the requirement to obtain the carbon fiber corona roller for the lithium battery aluminum foil.
Furthermore, the vulcanization temperature is 160-.
Further, the coating thickness was 3.5. + -. 0.5 mm.
The invention has the beneficial effects that:
the invention provides a carbon fiber corona roller for a lithium battery aluminum foil and discloses a preparation method of the corona roller.
The C-F bond is introduced into the stabilizer, the chemical stability of the product is improved, fluorine atoms endow the rubber composition with excellent thermal stability, chemical stability and oxidation resistance, the octavinyl-POSS can be used as a nano filler for improving the mechanical property and wear resistance of the product, silicone oil is added to facilitate dispersion, and the octavinyl-POSS can be conveniently combined with silicone rubber in the later vulcanization process, so that the corona resistance of the corona roller is improved, the corona roller is not easy to puncture, and the aging resistance is good.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
Preparing a stabilizer:
adding 2, 2, 2-trifluoro-N- (2-mercaptoethyl) acetamide, 0.5mol octavinyl-POSS and photoinitiator 0.6mol 2-hydroxy-2-methyl-1-phenyl-1-acetone into dichloromethane serving as a dispersant, stirring for 1h under the condition that the ultraviolet wavelength is 365nm, and removing the dichloromethane after stirring to obtain the stabilizer.
Example 2
Preparing a stabilizer:
adding 1.6mol of 2, 2, 2-trifluoro-N- (2-mercaptoethyl) acetamide, 0.5mol of octavinyl-POSS and 0.6mol of photoinitiator 2-hydroxy-2-methyl-1-phenyl-1-acetone into dispersant dichloromethane, stirring for 1h under the condition of ultraviolet wavelength of 365nm, and removing the dichloromethane after stirring to obtain the stabilizer.
Example 3
A carbon fiber corona roller for a lithium battery aluminum foil comprises a carbon fiber roller and a coating coated on the surface of the carbon fiber roller, wherein the coating is made of a rubber composition; is prepared by the following steps:
step one, putting 90-100 parts by weight of methyl vinyl silicone rubber, 10-12 parts by weight of the stabilizer prepared in example 1, 10-12 parts by weight of white carbon black, 1-2 parts by weight of silicone oil and 3-5 parts by weight of 2, 5-dimethyl-2, 5-bis (tert-butylperoxy) hexane into a rubber mixing mill for mixing;
step two, uniformly coating the mixed rubber composition on a carbon fiber roller, wrapping the carbon fiber roller by using cloth, and then putting the carbon fiber roller into a vulcanizing tank for vulcanization, wherein the vulcanization temperature is 160-180 ℃, and the vulcanization time is 6-8 h;
and step three, cooling to 20-30 ℃ after vulcanization, and grinding the surface of the coating until the thickness of the coating is 3.5 +/-0.5 mm to obtain the carbon fiber corona roller for the lithium battery aluminum foil.
Example 4
A carbon fiber corona roller for a lithium battery aluminum foil comprises a carbon fiber roller and a coating coated on the surface of the carbon fiber roller, wherein the coating is made of a rubber composition; is prepared by the following steps:
step one, putting 90-100 parts by weight of methyl vinyl silicone rubber, 10-12 parts by weight of the stabilizer prepared in example 2, 10-12 parts by weight of white carbon black, 1-2 parts by weight of silicone oil and 3-5 parts by weight of 2, 5-dimethyl-2, 5-bis (tert-butylperoxy) hexane into a rubber mixing mill for mixing;
step two, uniformly coating the mixed rubber composition on a carbon fiber roller, wrapping the carbon fiber roller with cloth, and then putting the carbon fiber roller into a vulcanizing tank for vulcanization, wherein the vulcanization temperature is 160-180 ℃, and the vulcanization time is 6-8 h;
and step three, cooling to 20-30 ℃ after vulcanization, and grinding the surface of the coating until the thickness of the coating is 3.5 +/-0.5 mm to obtain the carbon fiber corona roller for the lithium battery aluminum foil.
Example 5
A carbon fiber corona roller for a lithium battery aluminum foil comprises a carbon fiber roller and a coating coated on the surface of the carbon fiber roller, wherein the coating is made of a rubber composition; is prepared by the following steps:
step one, putting 90-100 parts by weight of methyl vinyl silicone rubber, 10-12 parts by weight of the stabilizer prepared in example 2, 10-12 parts by weight of white carbon black, 1-2 parts by weight of silicone oil and 3-5 parts by weight of 2, 5-dimethyl-2, 5-bis (tert-butylperoxy) hexane into a rubber mixing mill for mixing;
step two, uniformly coating the mixed rubber composition on a carbon fiber roller, wrapping the carbon fiber roller with cloth, and then putting the carbon fiber roller into a vulcanizing tank for vulcanization, wherein the vulcanization temperature is 160-180 ℃, and the vulcanization time is 6-8 h;
and step three, cooling to 20-30 ℃ after vulcanization, and grinding the surface of the coating until the thickness of the coating is 3.5 +/-0.5 mm to obtain the carbon fiber corona roller for the lithium battery aluminum foil.
Comparative example 1
Compared with the example 4, the rest raw materials of the stabilizer are changed into white carbon black, and the preparation process is kept consistent with the example 4.
The samples prepared in examples 3 to 5 and comparative example 1 were tested and the average electrical aging life was recorded at a rated voltage of 10kV and the test results are shown in table 1 below:
TABLE 1
Example 3 Example 4 Example 5 Comparative example 1
3Un/h 204.6 205.1 205.8 125.1
2Un/h 1650.8 1651.4 1651.7 557.2
The thickness of the coating in the prepared sample is the same, and the sample prepared by the invention has longer electrical aging life.
In the description herein, references to the description of "one embodiment," "an example," "a specific example" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the invention. In this specification, the schematic representations of the terms used above do not necessarily refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples.
The foregoing is illustrative and explanatory only and is not intended to be exhaustive or to limit the invention to the precise embodiments described, and various modifications, additions, and substitutions may be made by those skilled in the art without departing from the scope of the invention or exceeding the scope of the claims.

Claims (6)

1. The carbon fiber corona roller for the lithium battery aluminum foil is characterized by comprising a carbon fiber roller and a coating coated on the surface of the carbon fiber roller, wherein the coating is made of a rubber composition;
the rubber composition comprises the following raw materials in parts by weight: 90-100 parts of methyl vinyl silicone rubber, 10-12 parts of stabilizer, 10-12 parts of white carbon black, 1-2 parts of silicone oil and 3-5 parts of vulcanizing agent;
the stabilizer is prepared by the following steps:
adding 2, 2, 2-trifluoro-N- (2-mercaptoethyl) acetamide, octavinyl-POSS and 2-hydroxy-2-methyl-1-phenyl-1-acetone into dichloromethane, stirring for 1h under the condition of ultraviolet wavelength of 365nm, and removing the dichloromethane after the stirring is finished to obtain the stabilizer.
2. The carbon fiber corona roller for aluminum foil of lithium battery as claimed in claim 1, wherein the molar ratio of the 2, 2, 2-trifluoro-N- (2-mercaptoethyl) acetamide, the octavinyl-POSS and the 2-hydroxy-2-methyl-1-phenyl-1-propanone is 1.5-1.6: 0.5: 0.6.
3. the carbon fiber corona roller for the aluminum foil of the lithium battery as claimed in claim 1, wherein the vulcanizing agent is 2, 5-dimethyl-2, 5-bis (t-butylperoxy) hexane.
4. The carbon fiber corona roller for the aluminum foil of the lithium battery as claimed in claim 1, which is prepared by the following steps:
step one, putting the rubber composition into a rubber mixing mill for mixing;
step two, uniformly coating the mixed rubber composition on a carbon fiber roller, wrapping the carbon fiber roller with cloth, and then putting the carbon fiber roller into a vulcanizing tank for vulcanization;
and step three, cooling to 20-30 ℃ after vulcanization, and grinding the surface of the coating until the thickness of the coating meets the requirement to obtain the carbon fiber corona roller for the lithium battery aluminum foil.
5. The carbon fiber corona roller for the aluminum foil of the lithium battery as claimed in claim 4, wherein the vulcanization temperature is 160 ℃ and 180 ℃ and the vulcanization time is 6-8 h.
6. The carbon fiber corona roller for aluminum foil of lithium battery as claimed in claim 4, wherein the coating thickness is 3.5 ± 0.5 mm.
CN202210770170.2A 2022-06-30 2022-06-30 Carbon fiber corona roller for lithium battery aluminum foil Pending CN115074026A (en)

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Application Number Priority Date Filing Date Title
CN202210770170.2A CN115074026A (en) 2022-06-30 2022-06-30 Carbon fiber corona roller for lithium battery aluminum foil

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU471798A1 (en) * 1973-12-07 1977-07-05 Предприятие П/Я В-8415 Rubber mixture on siloxane rubber basis
CN103694705A (en) * 2013-12-24 2014-04-02 王华兵 Corona roller and preparation method thereof
CN109206919A (en) * 2018-08-31 2019-01-15 芜湖市棠华建材科技有限公司 A kind of silicon rubber heat-insulating material and preparation method thereof
CN110643086A (en) * 2019-09-18 2020-01-03 宁波泰意德过滤技术有限公司 High-elasticity rubber and processing method thereof
CN111040454A (en) * 2019-12-30 2020-04-21 江苏天辰新材料股份有限公司 Novel high-temperature-resistant silicon rubber and preparation method thereof
CN113321935A (en) * 2021-07-02 2021-08-31 深圳市泰科科技有限公司 High-corrosion-resistance silicone rubber material and preparation method thereof
WO2022110493A1 (en) * 2020-11-27 2022-06-02 江苏澳盛复合材料科技有限公司 Carbon fiber rubber composite pipe and preparation method therefor

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU471798A1 (en) * 1973-12-07 1977-07-05 Предприятие П/Я В-8415 Rubber mixture on siloxane rubber basis
CN103694705A (en) * 2013-12-24 2014-04-02 王华兵 Corona roller and preparation method thereof
CN109206919A (en) * 2018-08-31 2019-01-15 芜湖市棠华建材科技有限公司 A kind of silicon rubber heat-insulating material and preparation method thereof
CN110643086A (en) * 2019-09-18 2020-01-03 宁波泰意德过滤技术有限公司 High-elasticity rubber and processing method thereof
CN111040454A (en) * 2019-12-30 2020-04-21 江苏天辰新材料股份有限公司 Novel high-temperature-resistant silicon rubber and preparation method thereof
WO2022110493A1 (en) * 2020-11-27 2022-06-02 江苏澳盛复合材料科技有限公司 Carbon fiber rubber composite pipe and preparation method therefor
CN113321935A (en) * 2021-07-02 2021-08-31 深圳市泰科科技有限公司 High-corrosion-resistance silicone rubber material and preparation method thereof

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Application publication date: 20220920

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