CN115073115A - Inorganic special self-leveling mortar technology - Google Patents

Inorganic special self-leveling mortar technology Download PDF

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Publication number
CN115073115A
CN115073115A CN202210695116.6A CN202210695116A CN115073115A CN 115073115 A CN115073115 A CN 115073115A CN 202210695116 A CN202210695116 A CN 202210695116A CN 115073115 A CN115073115 A CN 115073115A
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CN
China
Prior art keywords
self
leveling mortar
cement
gypsum
sand
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CN202210695116.6A
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Chinese (zh)
Inventor
高雪梅
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Guangxi Huansheng New Material Technology Co ltd
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Guangxi Huansheng New Material Technology Co ltd
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Priority to CN202210695116.6A priority Critical patent/CN115073115A/en
Publication of CN115073115A publication Critical patent/CN115073115A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • C04B28/145Calcium sulfate hemi-hydrate with a specific crystal form
    • C04B28/146Calcium sulfate hemi-hydrate with a specific crystal form alpha-hemihydrate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B24/00Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
    • C04B24/24Macromolecular compounds
    • C04B24/38Polysaccharides or derivatives thereof
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention provides an inorganic special self-leveling mortar technology, wherein a rheological additive is added to the self-leveling mortar on the basis of an inorganic gel material, a filler, sand, redispersible latex powder and cellulose ether, and the self-leveling mortar comprises the following components in percentage by mass: 35-42% of inorganic gel, 15-20% of filler, 35-45% of sand, 1-3% of redispersible latex powder, 0.05-0.1% of cellulose ether and 0.03-0.05% of rheological aid, wherein the rheological aid is prepared from any two of modified bentonite, modified montmorillonite, guar gum and xanthan gum according to the mass ratio of 1-2: 1, and further the inorganic gel comprises the following components in percentage by mass: 20-25% of ordinary silicate cement, 11-12% of aluminate cement and 4-5% of gypsum. [08] Furthermore, the strength grade of the ordinary silicate cement is P.O42.5, the aluminate cement is one or two of sulpho-alumina cement and high-alumina cement, and the gypsum is anhydrous gypsum, semi-hydrated gypsum and synthetic self-leveling mortar.

Description

Inorganic special self-leveling mortar technology
Technical Field
The invention belongs to the technical field of building materials, and particularly relates to inorganic special self-leveling mortar.
Background
The self-leveling mortar is developed in the seventies and eighties of the twentieth century, consists of cement-based cementing material, selected aggregate and various additives, is mixed with water to form a self-leveling foundation material with strong flowability and high plasticity, is uniformly mixed with water according to a set water-cement ratio when in use, and forms a flat and smooth surface by self-flowing of the mortar under the action of self-weight after pumping or manual pouring. The self-leveling mortar material has the advantages of easy flowing, stable performance, easy construction, small labor intensity, thin mortar thickness, flatness, smoothness, high strength, good water resistance, acid resistance, erosion resistance and the like, is an ideal material for decorating the ground in large parking lots, warehouses, markets, supermarkets, workshops and the like, is also a development direction of a new technology for constructing indoor and outdoor ground, and has great market potential.
At present, the self-leveling mortar has great problems in application, one is that the requirement on water consumption is accurate, the flow degree is insufficient due to too little water, the requirement on construction cannot be met, and bleeding phenomenon is generated due to too much water, so that the surface strength is too low, so that the harsh condition that the requirement on the water consumption of the self-leveling mortar is accurate brings great inconvenience to the actual construction process, and the self-leveling mortar is greatly hindered in the actual popularization process. Therefore, there is a need to develop a self-leveling mortar that can maintain excellent performance over a wide range of water usage.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide the self-leveling mortar with wide water consumption, and compared with the common leveling mortar, the self-leveling mortar with wide water consumption is added with a rheological aid on the basis of inorganic gel materials, fillers, sand, redispersible latex powder and cellulose ether.
Specifically, the invention provides self-leveling mortar which comprises the following components in percentage by mass: 35-42% of inorganic gel, 15-20% of filler, 35-45% of sand, 1-3% of redispersible latex powder, 0.05-0.1% of cellulose ether and 0.03-0.05% of rheological additive.
Further, the rheological aid is composed of any two of modified bentonite, modified montmorillonite, guar gum and xanthan gum according to the mass ratio of 1-2: 1.
Further, the inorganic gel agent comprises the following components in percentage by mass: 20-25% of ordinary silicate cement, 11-12% of aluminate cement and 4-5% of gypsum.
Furthermore, the strength grade of the ordinary silicate cement is P.042.5, the aluminate cement is one or two of sulpho-alumina cement and high-alumina cement, and the gypsum is one or more of anhydrous gypsum, semi-hydrated gypsum and natural dihydrate gypsum.
Furthermore, the filler is one or more of heavy calcium carbonate powder, talcum powder, silica fume, zeolite powder, fly ash or metakaolin, and the fineness of the filler is 200-400 meshes.
Furthermore, the sand is one or two of washing sand, carborundum or quartz sand, and the grain size of the sand is 0-0.236 mm continuous gradation.
Further, the redispersible latex powder is one or more of polyvinyl acetate, acrylate copolymer and styrene-acrylic redispersible latex powder.
Further, the cellulose ether is one or two of hydroxypropyl methyl cellulose ether and hydroxyethyl methyl cellulose ether, and the viscosity is 400-600 mPa.s.
The self-leveling mortar also comprises the following components in percentage by mass: 0.1-0.15% of water reducing agent, 0.05-0.1% of defoaming agent, 0.02-0.1% of retarder and 0.02-0.05% of coagulant.
Preferably, the water reducing agent is one or more of lignosulfonate, naphthalenesulfonate, sulfamate and polycarboxylate, the defoaming agent is one or more of polyethers, organosilicones and phosphates, the retarder is one or more of tartaric acid, sodium gluconate and citric acid, and the coagulant is one or two of lithium sulfate, lithium chloride and lithium carbonate.
The invention has the beneficial effects that: according to the invention, the rheological additive with the functions of suspension, anti-settling, anti-sagging and the like is added into the self-leveling mortar, so that the self-leveling mortar can be ensured to be uniformly distributed in a certain wider range of water consumption, the self-leveling mortar with the water consumption in the wider range greatly improves the fault tolerance of workers in the construction process, and great convenience is provided for the construction process. Therefore, the self-leveling mortar provided by the invention is very high in practicability and has a great popularization value.
Detailed Description
In order to more clearly illustrate the technical solution of the present invention, the technical solution of the present invention will be further illustrated with reference to the following specific embodiments:
in a specific embodiment of the invention, the invention provides a self-leveling mortar, which comprises the following components in percentage by mass: 35-42% of inorganic gel, 15-20% of filler, 35-45% of sand, 1-3% of redispersible latex powder, 0.05-0.1% of cellulose ether and 0.03-0.05% of rheological additive.
The self-leveling mortar is added with rheological additives on the basis of inorganic gel materials, fillers, sand, redispersible latex powder and cellulose ether. Rheology additives, which are inherently key components of paint and ink coatings, control the delicate properties and characteristics of the fluid product, and "run off" like water without these media. The paint can splash everywhere in the coating process, the covering capacity is reduced, the storage life is shortened, the fluidity of the paint can be adjusted by adopting the rheological aid, the dripping and splashing generated in the roll coating or brush coating process can be reduced, the viscosity of the paint can be rapidly and controllably increased, so that the sagging resistance is improved, the rheological aid can prevent the pigment in the formula from settling in the coating transportation or storage process, and the consistency of the final product, the durability and the good coating characteristic are balanced in a rational manner.
The invention adds the rheological additive with the functions of suspension, anti-sedimentation, anti-sagging and the like into the self-leveling mortar, so that the self-leveling mortar can still keep the performance unchanged under the condition of excessive water consumption, because the filler and the sand with higher density can be sedimented when the water consumption of the self-leveling mortar is excessive, the self-leveling mortar generates the layering phenomenon, namely the surface is redundant water, and the bottom layer is the filler and the sand with higher density, so that the surface bleeding of the self-leveling mortar has no strength and can not meet the requirements of subsequent construction, the rheological additive has the effects of suspension and anti-sedimentation, and after the rheological additive is added, the filler and the sand with higher density in the self-leveling mortar can be suspended in the mortar without sedimentation, so that the upper layer and the lower layer in the self-leveling mortar can be uniformly distributed. The rheological additive is added, so that the effect of uniform distribution of the self-leveling mortar can be ensured within a certain wide range of water consumption, the fault tolerance of workers in the construction process is greatly improved, and great convenience is provided for the construction process.
The rheological additive is composed of any two of modified bentonite, modified montmorillonite, guar gum and xanthan gum according to the mass ratio of 1-2: 1. The components and the rheological additive have the functions of suspension and anti-settling, so that the fluidity of the self-leveling mortar can be increased and the leveling property can be improved under the condition of low water consumption, and bleeding phenomenon can not be generated even under the condition of excessive water consumption, namely the self-leveling mortar can still keep the same performance within a wider water consumption range.
The inorganic gel consists of the following components in percentage by mass: 20-25% of ordinary silicic acid cement, 11-12% of aluminate 4 cement and 4-5% of gypsum. The common portland cement has the functions of providing the mortar with middle and later strength, increasing the early strength of aluminate quickly and hardening the mortar for subsequent construction, and the gypsum in the self-leveling mortar is mainly helpful for expanding the mortar and preventing cracking after construction.
The strength grade of the common silicate cement is P.042.5, the aluminate cement is one or two of sulpho-alumina cement and high-alumina cement, and the gypsum is one or more of anhydrous gypsum, semi-hydrated gypsum and natural dihydrate gypsum.
The filler is one or more of heavy calcium carbonate powder, talcum powder, silica fume, zeolite powder, fly ash or metakaolin, and the fineness of the filler is 200-400 meshes. The filler can improve the workability and the compactness of the mortar, is beneficial to improving the mechanical property, and can also improve the fluidity, the stability and the later strength of the mortar.
The sand is one or two of washing sand, carborundum or quartz sand, and the grain size of the sand is 0-0.236 mm continuous gradation. One or two of washing sand, carborundum and quartz sand are mixed to serve as the aggregate of the cement binder, so that the volume deformation of cementing materials such as cement and the like during hydration can be effectively limited, the bonding strength of the self-leveling mortar can be remarkably improved, and the flexural strength and the compressive strength of the mortar are improved.
The redispersible latex powder is one or more of polyvinyl acetate, acrylate copolymer and styrene-acrylic redispersible latex powder. The redispersible latex powder as a high molecular polymer can effectively form a film in the leveling mortar, reduce the elastic modulus, modify the rigidity of cement, improve the cohesion of the mortar, increase the bonding strength, the wear resistance, the toughness, the impermeability and the impact resistance of the mortar, improve the construction performance and reduce the drying shrinkage, and has certain effects.
The cellulose ether is one or two of hydroxypropyl methyl cellulose ether and hydroxyethyl methyl cellulose ether, and the viscosity is 400-600 mPa.s. The cellulose ether can endow the mortar with thixotropic consistency, reduce the evaporation and absorption of moisture, and is beneficial to prolonging the operable time and improving the stability. Cellulose ether is a high molecular polymer with a three-dimensional network structure, and a plurality of hydrophilic groups exist on a crosslinked network structure, and can be associated with moisture to form hydrogen bonds, hold a large amount of free water and play roles in water retention and thickening.
The self-leveling mortar also comprises the following components in percentage by mass: 0.1-0.15% of water reducing agent, 0.05-0.1% of defoaming agent, 0.02-0.1% of retarder and 0.02-0.05% of coagulant. Although the proportion of the above-mentioned auxiliaries in the self-leveling mortar is very low, each proportion plays an indispensable role.
Preferably, the water reducing agent is one or more of lignosulfonate, naphthalene sulfonate, sulfamate and polycarboxylate, the defoaming agent is one or more of polyethers, organosilicones and phosphate esters, the retarder is one or more of tartaric acid, sodium gluconate and citric acid, and the coagulant is one or two of lithium sulfate, lithium chloride and lithium carbonate.
The water reducing agent has the effects of improving the fluidity of mortar under the condition of low water-cement ratio, reducing the mixing water consumption under the condition of not reducing the fluidity, improving the compactness of a cement hardened body structure and improving the mechanical property. The defoaming agent can eliminate bubbles in the mortar introduced by mechanical stirring and a surfactant, so that the strength is improved, and the surface flatness is improved. In addition, after the bubbles are eliminated, a certain amount of free water can be released, and therefore, the defoaming agent also plays a certain role in water reduction. The retarder has the functions of delaying cement hydration, reducing the loss of fluidity of the self-leveling mortar over time and ensuring the sufficient operation time of the mortar. The coagulant can accelerate the hydration of cement and improve the early strength of mortar, so that the subsequent construction can be carried out.
The following examples further illustrate the above embodiments, but do not therefore limit the invention within the scope of the examples described. The experimental methods without specifying specific conditions in the following examples were selected according to the conventional methods and conditions, or according to the commercial instructions.
The materials referred to in the examples are all commercially available directly.
The inorganic special self-leveling mortar comprises the following components in percentage by mass: 40% of inorganic gel, 15% of filler, 43% of sand, 1.5% of redispersible latex powder, 0.1% of cellulose ether, 0.03% of rheological additive, 0.12% of water reducing agent, 0.1% of defoaming agent, 0.1% of retarder, 0.05% of coagulant and the balance of water.
Wherein, the inorganic gel comprises the following components in percentage by mass: 25% of ordinary portland cement, 11% of sulphoaluminate cement and 4% of alpha hemihydrate gypsum.
The filler is mixed by coarse whiting and talcum powder according to the mass ratio of 1: 1, and the fineness is 325 meshes.
The sand is washed sand, and the particle size of the sand is 0-0.236 mm.
The re-dispersible latex powder is polyvinyl acetate.
The cellulose ether is hydroxypropyl methyl cellulose ether and has a viscosity of 500 mPa.s.
The rheological additive consists of modified montmorillonite and guar gum in a mass ratio of 1: 1.
The water reducing agent is a polycarboxylic acid water reducing agent, the defoaming agent is organosilicone, the retarder is a mixture of tartaric acid and sodium gluconate, and the coagulant is lithium carbonate.
Example 2
The self-leveling mortar comprises the following components in percentage by mass: 35% of inorganic gel, 16% of filler, 45% of sand, 2% of redispersible latex powder, 0.08% of cellulose ether, 0.04% of rheological additive, 0.15% of water reducing agent, 0.05% of defoaming agent, 0.05% of retarder, 0.04% of coagulant and the balance of water.
Wherein, the inorganic gel comprises the following components in percentage by mass: 20% of ordinary portland cement, 11% of high aluminate cement and 4% of alpha hemihydrate gypsum.
The filler is prepared by mixing silica fume and fly ash according to the mass ratio of 1: 1, and the fineness of the filler is 325 meshes.
The sand is carborundum, and the particle size of the sand is 0-0.236 mm.
The redispersible latex powder is an acrylate copolymer.
The cellulose ether is hydroxyethyl methyl cellulose ether and has a viscosity of 400 mPa.s.
The rheological additive consists of guar gum and xanthan gum in a mass ratio of 1: 1.
The water reducing agent is melamine water reducing agent, the defoaming agent is organic siloxane, the retarder is a mixture of tartaric acid and sodium gluconate, and the coagulant is lithium carbonate.

Claims (4)

1. The inorganic special self-leveling mortar is characterized by comprising the following components in percentage by mass: 35-42% of inorganic gel, 15-20% of filler, 35-45% of sand, 1-3% of redispersible latex powder, 0.05-0.1% of cellulose ether and 0.03-0.05% of rheological additive, wherein the self-leveling mortar is characterized in that the rheological additive is composed of any two of modified bentonite, modified montmorillonite, guar gum and xanthan gum according to the mass ratio of 1-2: 1.
a. The self-leveling mortar is characterized in that the inorganic gel comprises the following components in percentage by mass: 20-25% of ordinary silicate cement, 11-12% of aluminate cement and 4-5% of gypsum.
b. The self-leveling mortar is characterized in that the strength grade of common silicate cement is P.O42.5, the aluminate cement is one or two of sulpho-aluminum cement and high-aluminum cement, and the gypsum is one or more of anhydrous gypsum, semi-hydrated gypsum and natural dihydrate gypsum.
C. The self-leveling mortar is characterized in that the filler is one or more of heavy calcium carbonate powder, talcum powder, silica fume, zeolite powder, fly ash or metakaolin, and the fineness of the filler is 200-400 meshes.
d. The self-leveling mortar is characterized in that the sand is one or two of washing sand, carborundum or quartz sand, and the grain size of the sand is 0-0.236 mm in continuous gradation.
C. The self-leveling mortar is characterized in that the inorganic gel comprises the following components in percentage by mass: 20-25% of ordinary silicate cement, 11-12% of aluminate cement and 4-5% of gypsum.
2. The self-leveling mortar of claim 1, wherein the cellulose ether is one or both of hydroxypropyl methyl cellulose ether and hydroxyethyl methyl cellulose ether and has a viscosity of 400 to 600 mPa.s.
3. The self-leveling mortar according to claim 3, further comprising the following components in percentage by mass: 0.1-0.15% of water reducing agent, 0.05-0.1% of defoaming agent, 0.02-0.1% of retarder and 0.02-0.05% of coagulant.
4. The self-leveling mortar according to claim C, wherein the inorganic gelling agent consists of the following components in percentage by mass: 20-25% of common silicic acid cement, 11-12% of aluminate cement and 4-5% of gypsum.
CN202210695116.6A 2022-05-18 2022-05-18 Inorganic special self-leveling mortar technology Pending CN115073115A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115626792A (en) * 2022-09-29 2023-01-20 中国铁道科学研究院集团有限公司铁道建筑研究所 Rebound inhibitor for sprayed concrete

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107963867A (en) * 2017-12-27 2018-04-27 北京宝辰联合科技股份有限公司 A kind of gravity flowing levelling mortar

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107963867A (en) * 2017-12-27 2018-04-27 北京宝辰联合科技股份有限公司 A kind of gravity flowing levelling mortar

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115626792A (en) * 2022-09-29 2023-01-20 中国铁道科学研究院集团有限公司铁道建筑研究所 Rebound inhibitor for sprayed concrete
CN115626792B (en) * 2022-09-29 2023-06-16 中国铁道科学研究院集团有限公司铁道建筑研究所 Rebound inhibitor for sprayed concrete

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