CN115072881A - Biological sewage treating method by soil condensation - Google Patents

Biological sewage treating method by soil condensation Download PDF

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Publication number
CN115072881A
CN115072881A CN202210195702.4A CN202210195702A CN115072881A CN 115072881 A CN115072881 A CN 115072881A CN 202210195702 A CN202210195702 A CN 202210195702A CN 115072881 A CN115072881 A CN 115072881A
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soil
condensation
sewage
microorganisms
activated
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CN202210195702.4A
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金泰峰
李会娜
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Shanghai Nipton Environmental Technology Co ltd
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Shanghai Nipton Environmental Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/008Sludge treatment by fixation or solidification
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/301Aerobic and anaerobic treatment in the same reactor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/02Odour removal or prevention of malodour
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2305/00Use of specific compounds during water treatment
    • C02F2305/06Nutrients for stimulating the growth of microorganisms

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Water Supply & Treatment (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention provides a biological sewage treatment method by utilizing soil condensation, belonging to the field of sewage treatment. The method comprises the steps of adding a soil condensation unit into the existing sewage biological treatment system, placing humus soil containing activated soil minerals and soil microorganisms and metabolites thereof in the soil condensation unit, generating condensation intermediate products by utilizing the condensation effect of the soil microorganisms and activating the microorganisms in the sludge. The mixed liquid containing the activated microorganisms, the soil microorganisms and the condensation intermediate products flows into a sewage biochemical tank to carry out biochemical reactions such as decomposition, condensation, polycondensation, condensation and the like to remove pollutants in the sewage, improve the sewage treatment efficiency, reduce the output of excess sludge, stabilize the excess sludge and reduce the number of pathogenic bacteria in the sewage. The invention can reduce the biological treatment process of sewage and sludge and reduce the specification of the corresponding treatment unit.

Description

Biological sewage treating method by soil condensation
Technical Field
The invention relates to a biological sewage treatment method by utilizing soil condensation, belonging to the technical field of sewage treatment.
Background
The existing sewage biological treatment technology is based on various application technologies of an activated sludge method and a biofilm method, and comprises a traditional activated sludge method, a biological filter method, MBR, MBBR and the like, wherein the technologies mainly decompose pollutants in sewage into small molecular substances such as carbon dioxide, water, nitrogen and the like through microbial groups and purify the sewage through microbial proliferation. Although the existing sewage biological treatment technology can efficiently remove pollutants, the biochemical tank has the characteristics of long retention time, poor sludge-water separation performance, high content of easily degradable substances, large output of residual sludge, high sanitation indexes of pathogenic bacteria and the like. Therefore, the existing biological sewage treatment technology needs to be matched with corresponding treatment systems to discharge sewage and sludge up to the standard, such as large-volume biochemical tanks, secondary sedimentation tanks, filter tanks and other sludge-water separation systems, sludge concentration, dehydration, drying and other sludge reduction systems, composting, incineration and other sludge stabilization or treatment systems, disinfection systems and the like.
The soil is used as an important circulating unit in the natural substance circulating process, stable, fluffy and complex humus soil is formed by decomposing organic matters in animal and plant residues by abundant and various microorganisms until carbon dioxide is discharged to the atmosphere, condensing decomposition products or microbial metabolites and the like, and an intermediate product generated in the condensing process has a sterilizing effect, so that the healthy growth of the soil and a surface biological system thereof is ensured. Different soil minerals, soil microorganisms and humus soil inoculated under environmental conditions determine the properties of the soil, such as laterite, black soil, loess and the like.
The existing sewage biological treatment technology focuses on decomposition and transfer of organic matters, namely, decomposing the organic matters into micromolecular carbon dioxide, water, nitrogen and the like and generating excess sludge, and the decomposition process is similar to the decomposition process of soil, so that the condensation effect of the soil is integrated in the sewage treatment technology, pollutants and extracellular polymers in the sewage are condensed to reduce the pollutant load, improve the sludge-water separation performance and stabilize the excess sludge, the sterilization engineering of condensation intermediate products is utilized to strengthen the sewage sanitation index, and the corresponding treatment process in the sewage treatment process can be simplified or the corresponding unit specification can be reduced.
Disclosure of Invention
The invention provides a biological sewage treatment method utilizing soil condensation, aiming at the problems of long hydraulic retention time of a biochemical pool and a sludge-water separation unit in the existing biological sewage treatment technology, poor dehydration performance of residual sludge, high content of easily degradable organic matters and the like, low biological sewage treatment efficiency and difficult sludge treatment. The condensation capacity of soil microorganisms and metabolites thereof can reduce pollution load, reduce the yield of excess sludge, stabilize the excess sludge through a humification process, and inhibit the growth of pathogenic bacteria through the bactericidal capacity of the metabolites. Therefore, the corresponding treatment process in the existing sewage treatment process can be simplified or the corresponding unit specification can be reduced by utilizing the soil condensation effect.
To achieve the above technical object, the processing method of the present invention is as follows:
the sewage biological treatment method utilizing soil condensation is characterized in that a soil condensation unit is arranged in the existing sewage biological treatment system, sludge flows back to the water inlet end of a biochemical pool or the water inlet end of an adjusting pool and passes through the soil condensation unit, a condensation intermediate product is generated by utilizing the condensation effect of soil microorganisms, the microorganisms in the sludge are activated, and mixed liquid containing the activated microorganisms, the soil microorganisms and the condensation intermediate product flows into a sewage biochemical pool and is used for removing pollutants in sewage together with conventional sewage treatment microorganisms. Under the action of soil microbes and condensation intermediate products, the polymer between pollutants in the sewage and the returned sludge is rapidly condensed, the pollutant load of a sewage treatment system is reduced, and the sludge settling performance is improved.
The soil microorganism and the condensation intermediate product are released to a sewage treatment system through placing activated soil minerals and humus soil containing the soil microorganism and metabolites thereof in the soil condensation unit, and the two placed materials can be slow-release materials or can be added to the soil condensation unit through respective adding systems. The slow release speed or the adding amount of the activated soil minerals and the humus soil containing soil microorganisms is determined according to the scale of sewage treatment to be treated and the water quality, and the reaction rate in a soil condensation unit is matched with the corresponding sewage treatment process.
The soil condensation unit is a unit for activating soil microorganisms in a humus soil environment of activated soil minerals and soil microorganism metabolites, and can release the soil microorganisms and the soil microorganism metabolites into materials. The hydraulic retention of the soil condensation unit is only 0.1-1h, the specific retention time is determined according to the quality of sewage, an air blower is adopted for aeration for 24h, the reaction unit is used for supplying oxygen and stirring to activate soil microorganisms and release activated soil minerals and soil microorganism metabolites into water, the aeration air is not directly contacted with the materials placed in the soil condensation unit as far as possible, and a perforated pipe aeration mode is adopted.
The activated soil mineral adopted by the soil condensation unit is a substance containing activated silicate, preferably volcanic soil rock or powder such as andesite, rhyolite, pumice, volcanic ash, diatomite, zeolite, pumice, clay and granite substance, preferably the soil mineral also contains iron and aluminum metallic elements and other common metallic elements and trace metallic elements beneficial to the growth of soil microorganisms, so that the adsorption of pollutants, metal chelation/precipitation reaction and the growth of microorganisms in the sewage treatment process are facilitated, and the synthetic substance is a synthetic substance obtained by adding the metallic elements such as iron and the like into the artificial active silicate.
The humus soil containing soil microorganisms used in the soil condensation unit includes a soil microorganism metabolic condensation intermediate and microorganisms such as aerobic soil microorganisms and facultative soil microorganisms, and is preferably underground high-quality soil such as fertile marsh lands, or low-quality soil such as common marsh lands and fields, for example, humus soil, peat, coal, and the like.
The amount of the activated soil minerals participating in the reaction process in the soil condensation unit is 5-60% of the amount of humus soil containing soil microorganisms, namely the mass ratio of the two materials when the two materials are slowly released or externally added.
Soil microorganisms participating in the reaction in the soil condensation reaction are facultative or anaerobic soil microorganisms containing lactobacillus, pediococcus, streptococcus, bacillus and the like, and can perform the condensation reaction to generate condensation intermediate products such as humic precursor substances and the like.
The pollutants and the condensation intermediate products polymerized in the sludge in the condensation sewage treatment process are microbial metabolites and secretion containing phenolic compounds, oxidases of phenyl oxidase, quinone compounds, polysaccharides, amino acids and the like, and the substances have the functions of sterilization and condensation of small molecular pollutants to form humus.
From the above description, it can be seen that the present invention has the following advantages:
1. the condensation effect of the soil condensation unit can reduce the pollutant load of the whole sewage biochemical pool and reduce the hydraulic retention time of the sewage biochemical pool.
2. The condensation effect of the soil condensation unit of the invention condenses sludge extracellular polymeric substances, improves sludge mud-water separation performance and reduces the volume of mud-water separation facilities.
3. The invention reduces the solid amount of the excess sludge by reducing the pollutant load and improving the sludge-water separation performance, improves the sludge dewatering performance, can stabilize the excess sludge, and is beneficial to the subsequent treatment and disposal process of the excess sludge.
4. The sterilization effect and the medium and small molecule condensation capability of the condensation intermediate product improve the sanitation index of the sewage and reduce the odor in the sewage biological treatment process.
5. The method can be conveniently added to the existing sewage biological treatment system, and has little interference to the original system.
6. The method of the invention is simple and convenient to operate and control.
Drawings
The invention will be described in more detail hereinafter on the basis of embodiments and with reference to the accompanying drawings. Wherein:
FIG. 1 is a schematic view of a conventional sewage treatment process.
FIG. 2 is a schematic view of a biological sewage treatment process using soil condensation according to the present invention.
Detailed Description
The following examples are provided to further illustrate embodiments of the present invention. It should be noted that the description of the embodiments is provided to help understanding of the present invention, but the present invention is not limited thereto. In addition, the technical features involved in the embodiments of the present invention described below may be combined with each other as long as they do not conflict with each other.
Example 1
The embodiment is a modification of the original sewage treatment process, wherein the sewage is domestic sewage, and the sewage treatment scale is 10m 3 And d, the sewage treatment process adopted before the modification is the treatment process of adding a secondary sedimentation tank into the AO process of the traditional activated sludge process, and is shown in figure 1. The quality of the sewage inlet water is COD Cr 150-300mg/L,NH 3 20-30mg/L of-N, 25-35mg/L of TN, 1-2mg/L of TP and 150mg/L of SS 100, the effluent standard meets the first-level B discharge standard, and the effluent quality is COD Cr 40-50,NH 3 -N 1-5mg/L,TN 10-20mg/L,TP 0.3-0.8mg/L,SS 15-20mg/L。
The improved sewage treatment process is shown in figure 2, in the embodiment, a soil condensation unit is additionally arranged on a bypass of an original system, and sludge in a sludge tank flows back to enter a biochemical tank after passing through a soil condensation reactor. The soil condensation reactor is provided with andesite powder and high-quality soil at 10-20m underground of a fertile marsh land which are bonded to form two mud blocks, and the release amount of andesite is 30% of that of high-quality soil. The reactor was aerated with perforated pipes and the hydraulic retention time was 1 h.
In the process of accumulative operation and treatment for 60 days, the effluent quality is continuously improved, after the whole sewage treatment system is stabilized, the effluent quality reaches the first-level A discharge standard for 42 days continuously, and the quality of the papermulberry fruit is COD Cr 35-50,NH 3 N1-5 mg/L, TN 10-15mg/L, TP 0.3-0.5mg/L, and SS 7-10 mg/L. The residual sludge properties are also improved significantly: the solid reduction of the residual sludge is more than 20 percent, the sludge overlapping and spiral dehydrating performance is obviously improved, and the water content of the dehydrated sludge is reduced to 75-80 percent from the original 80-83 percent; the residual sludge is stabilized, no odor is generated when the sludge is simply stacked, and no insect or fly harm is caused. The method can effectively solve the problems of secondary pollution in the existing sewage biological treatment process.
It should be understood that the detailed description of the invention is merely illustrative of the invention and is not intended to limit the invention to the specific embodiments described. It will be appreciated by those skilled in the art that the present invention may be modified or substituted equally as well to achieve the same technical result; as long as the use requirements are met, the method is within the protection scope of the invention.

Claims (8)

1. The biological sewage treating method with soil condensation features that in available biological sewage treating system, soil condensation unit is set, sludge is made to flow back to the water inlet of biochemical pond or regulating pond and through the soil condensation unit, and the condensation of soil microbes to produce intermediate condensation product and activate microbes in sludge.
2. The soil condensation unit according to claim 1, wherein activated soil minerals and humus soil containing soil microorganisms and metabolites thereof are placed in the soil condensation unit, the two placed materials are slow release materials or are added to the soil condensation unit through a dosing system, and the slow release speed or the dosing amount of the activated soil minerals and the humus soil containing soil microorganisms is determined according to the scale of the sewage to be treated and the water quality.
3. The soil condensation unit according to claim 1, wherein the hydraulic retention time of the soil condensation unit is between 0.1 and 1h, the specific retention time being determined according to the quality of the wastewater; and aerating for 24 hours by adopting an air blower, wherein the aeration air is not in direct contact with the materials placed in the soil condensation unit as much as possible, and a perforated pipe aeration mode is adopted.
4. The activated soil mineral according to claim 2, wherein the activated soil mineral is a substance containing activated silicate, preferably volcanic soil rock or powder including andesite, rhyolite, pumice, volcanic ash, diatomaceous earth, zeolite, pumice, clay, granite substance, and the like, preferably the soil mineral further comprises iron, aluminum metal and other common metal elements and trace metal elements beneficial to soil microorganism growth, beneficial to pollutant adsorption, metal chelation/precipitation reaction and microorganism growth in sewage treatment process, and less preferably a synthetic substance of metal elements such as iron added to artificial activated silicate.
5. The soil microorganism-containing humus soil according to claim 2, wherein the soil microorganism-containing humus soil comprises a soil microorganism metabolic condensation intermediate and microorganisms such as aerobic soil microorganisms and facultative soil microorganisms, preferably underground high-quality soil such as fertile marshland, inferior low-quality soil such as general marshland, fields and the like, such as humus soil, peat, coal and the like.
6. The activated-soil-mineral-and-soil-microorganism-containing humus soil according to claim 2, wherein the amount of the activated soil mineral when participating in the reaction process in the soil condensation unit is 5% to 60% of the amount of the humus soil containing soil microorganisms.
7. The soil microorganism according to claim 2, wherein the soil microorganism is a facultative or anaerobic soil microorganism containing bacteria of the genus Lactobacillus, the genus Pediococcus, the genus Streptococcus, the genus Bacillus, and the like, and is capable of undergoing a condensation reaction to produce a condensation intermediate such as a humic precursor.
8. The condensation intermediate according to claim 7, wherein the condensation intermediate is a microbial metabolite or secretion containing a phenolic compound, an oxidase of a phenyl oxidase, a quinone compound, a polysaccharide, an amino acid, and the like, which has a sterilizing function and a function of condensing a small molecule contaminant to form humus.
CN202210195702.4A 2022-03-02 2022-03-02 Biological sewage treating method by soil condensation Withdrawn CN115072881A (en)

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19980082123A (en) * 1998-08-27 1998-11-25 임동혁 Batch Natural Purification Method of Organic Sewage and Wastewater and Its Apparatus
CN1290663A (en) * 1999-06-25 2001-04-11 株式会社韩美 Deep processing method for deodorizing waste water by soll microorganism
CN1974441A (en) * 2005-11-28 2007-06-06 尹军 Reinforced sewage treating method and apparatus
KR100850677B1 (en) * 2008-05-09 2008-08-07 주식회사 한미엔텍 Method for treating sludge of sewage or organicwastewater
CN102358674A (en) * 2011-09-23 2012-02-22 南京中世环境科技股份有限公司 Sewage treatment method capable of sludge quantitative reduction
CN105271618A (en) * 2015-11-10 2016-01-27 北京沐萱鑫业环保技术有限公司 Sewage enhanced treatment system and method
CN112279367A (en) * 2020-11-28 2021-01-29 长春天皓环境科技有限公司 Humic activated sludge process for sewage treatment

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR19980082123A (en) * 1998-08-27 1998-11-25 임동혁 Batch Natural Purification Method of Organic Sewage and Wastewater and Its Apparatus
CN1290663A (en) * 1999-06-25 2001-04-11 株式会社韩美 Deep processing method for deodorizing waste water by soll microorganism
CN1974441A (en) * 2005-11-28 2007-06-06 尹军 Reinforced sewage treating method and apparatus
KR100850677B1 (en) * 2008-05-09 2008-08-07 주식회사 한미엔텍 Method for treating sludge of sewage or organicwastewater
CN102358674A (en) * 2011-09-23 2012-02-22 南京中世环境科技股份有限公司 Sewage treatment method capable of sludge quantitative reduction
CN105271618A (en) * 2015-11-10 2016-01-27 北京沐萱鑫业环保技术有限公司 Sewage enhanced treatment system and method
CN112279367A (en) * 2020-11-28 2021-01-29 长春天皓环境科技有限公司 Humic activated sludge process for sewage treatment

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张艳: "腐殖土活性污泥技术中的填料研究", 中国非金属矿工业导刊, vol. 2018, no. 1, pages 58 - 59 *

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