CN115069186A - Double-phase flow molecular reactor skid-mounted system - Google Patents
Double-phase flow molecular reactor skid-mounted system Download PDFInfo
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- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
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Abstract
The invention discloses a skid-mounted system of a double-phase flow molecular reactor, which can create an instant micro mixing system and achieve mixing and reaction of molecular scale. The system comprises a raw material storage tank, a high-pressure plunger metering pump, a double-phase flow atomizer, a high-pressure gas source, a digital gas flowmeter, a special-shaped five-way reactor, a high-speed flat centrifuge, a rotational flow gas-liquid separator and a time delay reaction kettle; high low temperature interface, exhaust fan tail gas recovery processing system and PLC control system. The special-shaped five-way reactor is conical and is provided with a temperature control jacket, high-speed double-phase flow can form vortex in the special-shaped five-way reactor, and the discharge speed, the atomization effect, the fluid mixing effect and the chemical reaction rate among materials of the materials in the reactor are controlled by adjusting the flow ratio of liquid to gas; the four double-phase flow atomizers at the center of the reaction zone spray high-speed double-phase flows to be quickly mixed to achieve the effect of instantaneous reaction, and the outflow speed is high. The reaction system has broad-spectrum applicability to most chemical reactions.
Description
Technical Field
The invention relates to a skid-mounted system of a double-phase flow molecular reactor.
Background
The microreactor, namely a microchannel reactor, is a microreactor which is manufactured by utilizing a precision machining technology and has a characteristic dimension of 10-300 micrometers (or 1000 micrometers), wherein the 'micro' of the microreactor indicates that a channel of a process fluid is in a micrometer level, and does not indicate that the external dimension of a microreactor device is small or the yield of a product is small. Millions of microchannels can be contained in the microreactor, thus also achieving high throughput. The microchannel reactor can shorten the reaction time of common chemical reaction from several hours to tens of hours to several seconds to several minutes, and simultaneously solves the problems of large amount of heat and a large amount of byproducts released in the reaction. The microchannel reactor can accurately control the reaction temperature, and for the strong exothermic reaction, if the mixing and heat exchange efficiency is not high, the phenomenon of local overheating is easy to occur. And the interior of the microchannel has good heat transfer and mass transfer characteristics, so that the reaction temperature cannot be excessively accumulated, and the reaction temperature is accurately controlled within a certain range. The microchannel reactor technology is easy to popularize and produce safely, and potential hidden production hazards can be reduced due to good temperature control capability, so that the safe implementation of projects is ensured. And because the reactants in the microreactor belong to the micro-scale, even if byproducts are generated, a lot of byproducts are not generated, thereby realizing the intrinsic safety. The advantages of the reactor based on the microchannel are as follows:
(1) large specific surface area, high transfer rate, short contact time and less by-products
The characteristic dimension of the micro-reaction channel is small, and the heat transfer capacity, the mass transfer capacity and the reaction rate of the unit volume area are obviously enhanced. The specific surface area of the microchannel equipment can reach 1000-5000 m 2 /m 3 The heat transfer coefficient is up to 2000-20000W/(m) 2 ·K)。
(2) Rapid, direct amplification
The traditional amplification process has amplification effect, the amplification purpose is achieved by increasing the volume and the scale of production equipment, and the process is time-consuming and labor-consuming. The micro-reaction system is in a multi-channel structure, each channel is equivalent to an independent reactor, and the micro-reactors do not need to be subjected to scale amplification during the expansion production, and only the number of the micro-reactors needs to be increased, namely the number amplification.
(3) And is highly safe
A large amount of heat can be removed in time, so that the reaction temperature is maintained within a set range, and the possibility of accidents is reduced to the maximum extent.
(4) Good operability
The micro-reaction system has a modular structure, is good in portability, can realize dispersed construction in product use places and on-site production and supply, can adjust production by increasing or decreasing the number of channels and replacing modules according to market conditions, and has high operation flexibility.
Therefore, the microchannel reactor technology is receiving wide attention and is a trend of developing chemical synthesis equipment in the future. However, microchannel reactors also have disadvantages, which are mainly four-fold in comparison with conventional tank reactors.
The micro-channel is easy to block and difficult to clean
At present, a plurality of researches are carried out to prepare nano materials by utilizing a microreactor, and the microreactor has the characteristic of narrow distribution of particle sizes of obtained particles due to very high mixing efficiency. The micro-channel in the micro-reactor has small size and complex structure, solid materials can not pass through the micro-channel, if a large amount of solids are generated in the reaction, the micro-channel is extremely easy to block, so that the production can not be continuously carried out, and the micro-channel is difficult to clean. The problem of plugging of the microreactors has been the biggest obstacle to replacing batch reactors with microreactors.
Second pulsation problem of the pump
The microchannel reactor generally drives fluid through a mechanical pump, but most of the mechanical pumps generate pulsating flow, so that the fluid in the microreactor is unstable. One solution that currently enables a stable continuous flow is electroosmotic flow.
The corrosion problem of equipment
Corrosion of the microreactor channels by the fluids involved in the reaction is also a great problem. Due to the high specific surface area and the small microchannel characteristic dimension of the microreactor, even a tiny corrosion degradation effect has a very obvious effect on the microreactor, so that the microreactor has a high corrosion prevention requirement on the material of the channel, the manufacturing cost of the microreactor is undoubtedly increased, and the large-scale industrial application of the microreactor is limited.
Fourth step of industrial realization
The micro-reactor adopts 'number increasing amplification' to enlarge the capacity, and although the amplification cost can be effectively reduced, the processing capacity is greatly limited. Second, the amplification of microreactors appears simple, but is a significant challenge to achieve. When the number of the micro-reactors is greatly increased, the complexity of monitoring and controlling the micro-reactors is greatly increased, and the operation cost is greatly increased for the actual production.
When the microchannel reactor technology is applied to high-viscosity fluid mixing or used as a microreactor to prepare nano particles, a large amount of solid particles are generated instantaneously in the fluid mixing and reaction processes, so that the microchannel reactor can be blocked immediately, and the reaction is terminated.
Disclosure of Invention
The invention aims to solve the technical problem that a microchannel reactor in the prior art is easy to block, and provides a skid-mounted system of a double-phase flow molecular reactor. The double-phase flow molecular reactor is an important method for realizing the rapid mixing of reaction materials in submicron droplets, and a skid-mounted system of the double-phase flow molecular reactor is a device for realizing the instantaneous mixing reaction of double-phase flow smoke. The reaction process in the skid-mounted system of the double-phase flow molecular reactor is that four high-pressure jet flows oppositely flow and impact and mix after leaving an atomizer, a highly turbulent reaction zone is formed between a gas phase and a liquid phase in the form of aerosol (the particle size is 1-1.2 microns) in the reactor, materials enter the reactor in the form of steam molecules under the action of high-pressure gas flow and the atomizer, the mean free path of the steam molecules of reactants is larger than the highly turbulent reaction zone of different materials, and theoretically, different materials are subjected to rapid mixing reaction on the molecular scale; the axial velocity of the material in the highly turbulent reaction zone tends to zero, and the material is instantaneously converted into radial flow after being highly mixed. The reaction form of the two-phase flow has the transmission force of gas, and the material transmission resistance is greatly reduced compared with that of a micro-channel reactor; the high-speed moving two-phase flow has the mass transfer effect of liquid, and the mass transfer process of the material is strengthened, so that the external resistance in the transfer process can be effectively reduced, the mass transfer reaction and the heat and mass transfer are strengthened, and the material mixing reaction is promoted.
The invention solves the technical problems through the following technical scheme:
the invention provides a skid-mounted system of a double-phase flow molecular reactor, which comprises two raw material storage tanks, two high-pressure plunger metering pumps, four double-phase flow atomizers, a high-pressure gas source, a digital gas flowmeter, a special-shaped five-way reactor, a high-speed flat centrifuge, a rotational flow gas-liquid separator, a time delay reaction kettle, a high-low temperature interface, an exhaust fan tail gas recovery processing system and a PLC (programmable logic controller) control system;
preferably, the raw material storage tank is a 50L anticorrosion storage tank, is provided with a weighing module and a liquid level meter, and is made of hastelloy, glass lining and carbon steel/stainless steel spray-coated polytetrafluoroethylene; the 4 double-phase flow atomizers are uniformly arranged on the section 1/3 away from the top of the special-shaped five-way reactor cylinder, the material spraying speed of the double-phase flow atomizers is 100-200 m/s, and the size of fog drops is 1-1.2 microns; the materials in the raw material storage tank can form a smoke-shaped reaction area in the special-shaped five-way reactor by a double-phase flow atomizer; the discharge speed and the atomization effect of the materials, the fluid mixing effect in the reaction zone and the chemical reaction rate among the materials can be controlled by adjusting the flow ratio of the high-pressure plunger metering pump to the digital gas flowmeter, wherein the gas-liquid flow ratio is 300: 1-10: 1;
preferably, a single high-pressure plunger metering pump supplies materials to the adjacent double-phase flow atomizer, the maximum flow rate of the high-pressure plunger metering pump is 180L/h, and the output pressure is 3 Mpa; uniformly supplying gas to 4 double-phase flow atomizers by a high-pressure gas source through a digital gas flowmeter, wherein the gas pressure range is 2-30 Mpa, and the gas flow is 50-200L/min; the high-pressure gas source is inert gas such as high-purity nitrogen or argon;
preferably, the upper part of the special-shaped five-way reactor is cylindrical, and the height-diameter ratio of the cylinder is 2: 1; the bottom is conical, and the height of the cone is 1/3 of the total height of the special-shaped five-way reactor; the diameter of the cylindrical area is 273 mm; the special-shaped five-way reactor is provided with a temperature control jacket; the discharge hole at the bottom of the special-shaped five-way reactor cylinder body is in seamless connection with the high-speed flat centrifuge;
preferably, the high-speed plate centrifuge is provided with a weighing module and a relay, and the high-speed plate centrifuge is used as the contentWhen the material reaches a certain weight, starting a centrifugal machine to carry out solid-liquid-gas centrifugal separation; the separated gas-liquid is connected with a cyclone gas-liquid separator through a discharge valve at the bottom of the centrifuge; the rotating speed of a working motor of the high-speed flat plate centrifuge is 3000rpm, and the filtering capacity is 7.5m 3 H; the upper part of the cover of the high-speed flat plate centrifuge is provided with a safety valve, when the internal air pressure of the centrifuge reaches 0.4Mpa, the safety valve is automatically opened, and an exhaust port of the safety valve is connected with a tail gas recovery processing system of an exhaust fan;
preferably, the liquid outlet of the rotational flow gas-liquid separator is connected with the bottom delay reaction kettle; the exhaust port of the gas-liquid separator is connected with an exhaust fan tail gas recovery processing system; the volume of the time-delay reaction kettle is 100L;
preferably, all accessory equipment is mounted to the I-steel frame with a PLC control system.
On the basis of the common knowledge in the field, the above preferred conditions can be combined randomly to obtain the preferred embodiments of the invention.
The invention has the beneficial effects that:
the two-phase flow molecular reactor skid-mounted system of the invention utilizes the materials of four double-phase fluid to form instant mixing and rapid reaction of molecular scale in the contact zone, and the two-phase flow atomized flow effectively combines the transmission force of gas and the mass transfer force of liquid, thereby improving the promotion effect of the two-phase flow molecular reactor skid-mounted system on the mixing and chemical reaction of reaction material fluid, leading the two-phase flow molecular reactor skid-mounted system to be applied to the chemical reaction, even the reaction generated by solid particles can be smoothly carried out, and being the supplement to the chemical reaction which can not be applied to generate solid substances by a microchannel reactor. The reaction is also suitable for a gas-liquid reaction system, and the dual-phase flow atomizer can enable gas-liquid reaction materials to form smoke with the particle size of about 1.2 microns in a reaction zone, so that the effective contact area of gas and liquid is greatly increased, the gas-liquid materials are enabled to react efficiently, and the conversion rate of the reaction is increased.
1. The method has the advantages of fast reaction, high yield, high product purity, low energy consumption, environmental protection, safety, continuous online synthesis and automatic control;
2. the skid-mounted system has wide applicable reaction types, and is suitable for liquid-liquid reaction, gas-liquid reaction and chemical reaction with solid particle generation; the reaction product does not need post-treatment, and the product can be directly applied subsequently;
3. the method has simple process and high repeatability, and can realize industrial production.
Drawings
FIG. 1 is a schematic view of a two-phase flow molecular reactor skid-mounted system of the present invention
In the figure: 11-12 parts of raw material storage tank, 21-22 parts of high-pressure plunger metering pump, 31-34 parts of double-phase flow atomizer, 41 parts of high-pressure gas source, 42 parts of digital gas flowmeter, 51 parts of special-shaped five-way reactor, 52 parts of high-speed flat centrifuge, 53 parts of rotational flow gas-liquid separator, 54 parts of time-delay reaction kettle, 61 parts of high-low temperature interface, 71 parts of exhaust fan tail gas recovery processing system, 81 parts of PLC control system.
Detailed Description
The following description will be given to the preferred embodiments of the present invention with reference to the accompanying drawings, in order to explain the technical solutions of the present invention in detail, but not to limit the present invention within the scope of the embodiments.
Example 1:
as shown in fig. 1, the skid-mounted system of the two-phase flow molecular reactor of this embodiment includes two raw material storage tanks 11-12, two high-pressure plunger metering pumps 21-22, four two-phase flow atomizers 31-34, a high-pressure gas source 41, a digital gas flow meter 42, a special-shaped five-way reactor 51, a high-speed flat centrifuge 52, a cyclone gas-liquid separator 53 and a time delay reactor 54; a high-low temperature interface 61 and an exhaust fan tail gas recovery processing system 71; a PLC control system 81; the special-shaped five-way reactor 51 is provided with a temperature control jacket, the upper part of the special-shaped five-way reactor is cylindrical, and the height-diameter ratio of the cylinder is 2: 1; the bottom is conical, and the height of the cone is 1/3 of the total height of the special-shaped five-way reactor. The special-shaped five-way reactor 51 is provided with a high-low temperature interface 61, a discharge hole at the bottom of a cylinder body is in seamless connection with the high-speed flat centrifuge 52, a discharge valve at the bottom of the flat centrifuge 52 is connected with the cyclone gas-liquid separator 53, a liquid outlet of the cyclone gas-liquid separator 53 is connected with the bottom delay reaction kettle 54, and an exhaust port of the cyclone gas-liquid separator 53 is connected with the exhaust fan tail gas recovery processing system 71.
The special-shaped five-way reactor 51 is provided with 4 double-phase flow atomizers, and the 4 double-phase flow atomizers are uniformly arranged on the section at 1/3 distance from the top of the special-shaped five-way reactor cylinder. The two-phase flow atomizer is connected with the raw material storage tank and the high-pressure gas source, and the reaction materials enter the special-shaped five-way reactor 51 after being atomized by the two-phase flow atomizer. The material spraying speed of the double-phase flow atomizer is 100m/s, the droplet size is 1-1.2 microns, the material in the raw material storage tank is atomized by the double-phase flow atomizer and forms a smog-shaped reaction area in the special five-way reactor, the four double-phase flow atomizers spray high-speed double-phase flows at the center of the reaction area, the high-speed double-phase flows are quickly mixed, the effect of instantaneous reaction is achieved, and the outflow speed is high. The discharge speed and the atomization effect of materials, the fluid mixing effect in a reaction zone and the chemical reaction rate among the materials can be controlled by adjusting the flow ratio of the high-pressure plunger metering pump to the digital gas flowmeter, and the gas-liquid flow ratio is set to be 300: 1-10: 1. The raw material storage tanks 11 and 12 are respectively connected with the double-phase flow atomizers through high-pressure plunger metering pumps 21 and 22, a single high-pressure plunger metering pump supplies materials to the adjacent double-phase flow atomizers, a high-pressure gas source is inert gas such as high-purity nitrogen or argon, and the like, and uniformly supplies gas to 4 double-phase flow atomizers through a digital gas flowmeter 42.
The high-speed flat plate centrifuge 52 is provided with a weighing module and a relay, and when the materials in the high-speed flat plate centrifuge 52 reach a certain weight, the centrifuge is started to carry out solid-liquid-gas centrifugal separation; the upper part of the machine cover of the high-speed flat plate centrifuge 52 is provided with a safety valve, when the air pressure in the centrifuge reaches 0.4Mpa, the safety valve is automatically opened, and an exhaust port of the safety valve is connected with an exhaust fan tail gas recovery processing system 71, so that the production safety point of the device is ensured, and the pollution to the environment is avoided.
All accessory equipment of the reactor skid-mounted system are arranged on the I-shaped steel frame and are provided with a PLC control system, and the control of the reactor skid-mounted system is realized through the PLC control system.
The skid-mounted equipment of the invention has the following operation processes: adding a certain amount of reaction materials A, B into raw material storage tanks 11 and 12, starting high-pressure plunger pumps 21 and 22, synchronously starting a digital gas flowmeter 42, atomizing the reaction materials and gas at high pressure by a two-phase flow atomizer 31-34 to form 1.2 micron aerosol, instantly and completely mixing the two reaction materials in a special-shaped five-way reactor 51 so as to perform rapid reaction, feeding the mixed system after reaction into a high-speed flat-plate centrifuge 52 for solid-liquid-gas separation, intercepting solid substances in the high-speed flat-plate centrifuge 52, feeding the gas-liquid mixture into a cyclone gas-liquid separator 53, feeding liquid products into a delayed reaction kettle 54, feeding the gas into an exhaust fan tail gas recovery processing system 71, and finishing the reaction.
The following describes an example of the application of the two-phase flow molecular reactor skid-mounted system of the present embodiment to a gas-liquid reaction type. The gas-liquid reaction requires the gas and liquid components to be fully and rapidly contacted and mixed and react. In this case, the materials used for the mixing reaction are respectively 2-chloro-1, 3, 2-dioxolane (CUP) solution with a density of 1.46g/mL and a purity of more than or equal to 99.0% and oxygen to synthesize 2-chloro-2-oxo-1, 3, 2-dioxolane by oxidation reaction, and toluene, benzene and acetonitrile are used as solvents or without solvents.
In this case, a CUP solution with a mass concentration of 30% is prepared, the solvent is benzene, the prepared reaction solution is added into the raw material storage tanks 11 and 12, the flow rates of the high-pressure plunger pumps 21 and 22 are set to be 120L/h, high-purity oxygen is used as a high-pressure gas source, the flow rate of the digital gas flow meter 42 is adjusted to be 120L/min, and the temperature of the special-shaped five-way reactor 51 is controlled to be about 75 ℃ in the mixing reaction process. The product generated after the mixing reaction is 2-chlorine-2-oxygen-1, 3, 2-dioxaphospholane.
Meanwhile, in the comparative case, the same mixing reaction was carried out using a microchannel reactor (liquid hold-up of 1050mL) and a tank reactor. In the micro-channel reaction, the flow rate of a plunger pump is 120L/h, and the gas flow rate is 120L/min; the tank reaction is 30% CUP reaction solution, aeration is carried out to the reaction tank with 12L/min gas for stirring reaction, the reaction temperature is controlled at 75 ℃, reaction liquid is collected after the reaction is finished, and the product is purified and analyzed by a reduced pressure distillation method, as shown in table 1, the effect data of the mixing reaction carried out by the embodiment is shown. Compared with the conventional kettle type reaction and microchannel reactor, the skid-mounted system of the double-phase flow molecular reactor can improve the yield and the conversion rate of products under the same condition, and the productivity is 24 times that of the conventional kettle type reactor.
TABLE 1 comparison of COP product yields using the two-phase flow molecular reaction, microchannel reactor and tank reactor of this example
| Example 1 | Micro-channel reactor | Kettle type reactor | |
| CUP(kg) | 100 | 100 | 100 |
| Duration of reaction (min) | 150 | 300 | 1481 |
| Reaction residence time (S) | 3 | 64 | 88860 |
| The product yield is% | 98％ | 75％ | 40％ |
| Capacity kg/h | 45 | 17 | 1.8 |
Example 2:
the case of the two-phase flow molecular reactor skid system of this example applied to a reaction with solid material generation will be described. In this case, the material for the mixing reaction was a mixed system of 35% strength 2-chloro-2-oxo-1, 3, 2-dioxolane and triethylamine with hydroxyethyl methacrylate, and the solvent of the system was acetonitrile. The contents of the components of the reaction mass a are expressed in mass percent as follows: 35.0% of 2-chloro-2-oxo-1, 3, 2-dioxaphospholane and 65.0% of acetonitrile; the contents of the components of the reaction material B are expressed in mass percent as follows: 30.8% of triethylamine, 36.0% of hydroxyethyl methacrylate and 33.2% of acetonitrile.
In this case, a 35% by mass solution of 2-chloro-2-oxo-1, 3, 2-dioxaphospholane is prepared, the solvent is acetonitrile, which is the reaction solution A, and the volume is 60L; then preparing reaction liquid B, 30.8 percent of triethylamine, 36.0 percent of hydroxyethyl methacrylate and 33.2 percent of acetonitrile. Adding the prepared reaction solution A into a raw material storage tank 11, adding the reaction solution B into a raw material storage tank 12, setting the flow rates of high-pressure plunger pumps 21 and 22 to be 120L/h, using high-purity nitrogen as a high-pressure gas source, adjusting the flow rate of a digital gas flowmeter 42 to be 120L/min, and controlling the temperature of the special-shaped five-way reactor 51 to be about 65 ℃ in the mixing reaction process. The product generated after the mixing reaction is 2-alkyl-2-oxo-1, 3, 2-dioxaphospholane, and the reaction time is 30 min.
Meanwhile, in the comparative case, the same mixing reaction was performed using a tank reactor. Adding the reaction solution B into a reaction kettle, slowly pumping the reaction solution A into the reaction kettle by using a plunger pump, controlling the temperature to be 20 ℃ below zero, controlling the flow of the plunger pump to be 0.18L/h, controlling the dropping time of the material to be 333min, delaying the reaction for 180min after the dropping of the material is finished, and controlling the total reaction time to be 513 min; after the tank reaction, the mixture is filtered by a plate centrifuge, the filtrate is collected, and the product of the filtrate is analyzed, as shown in table 2, the effect data of the mixing reaction performed in the present case is shown. It can be seen that the skid-mounted system of the double-phase flow molecular reactor can greatly accelerate the reaction time and improve the reaction conversion rate, and the products do not need to be post-treated, thereby saving the cost and improving the working efficiency. Compared with the conventional kettle type reaction and microchannel reactor, the skid-mounted system of the double-phase flow molecular reactor is more efficient, low-energy and environment-friendly, and the skid-mounted system of the double-phase flow molecular reactor is 17 times of that of the kettle type reactor in terms of productivity.
TABLE 2 comparison of the results of the synthesis reaction with solid matter using this example and a tank reactor
| Example 2 | Micro-channel reactor | Kettle type reactor | |
| 2-chloro-2-oxo-1, 3, 2-dioxaphospholane (kg) | 20 | / | 20 |
| Duration of reaction (min) | 30 | / | 513 |
| Reaction temperature of | 65 | / | -20 |
| The product yield is% | 99％ | The blockage can not be carried out | 99％ |
| Capacity kg/h | 66 | / | 3.9 |
While specific embodiments of the invention have been described above, it will be appreciated by those skilled in the art that these are by way of example only, and that the scope of the invention is defined by the appended claims. Various changes and modifications to these embodiments may be made by those skilled in the art without departing from the spirit and scope of the invention, and these changes and modifications are within the scope of the invention.
Claims (7)
1. A skid-mounted system of a double-phase flow molecular reactor is characterized in that: the skid-mounted system of the reactor comprises a raw material storage tank, a high-speed flat centrifuge (52), a rotational flow gas-liquid separator (53), a time delay reaction kettle (54) and an exhaust fan tail gas recovery processing system (71), wherein the bottom of the flat centrifuge (52) is connected with the rotational flow gas-liquid separator (53); a liquid outlet of the rotational flow gas-liquid separator (53) is connected with the bottom delayed reaction kettle (54), and an exhaust port of the rotational flow gas-liquid separator (53) is connected with an exhaust fan tail gas recovery processing system (71); the special-shaped five-way reactor (51) is further included, a double-phase flow atomizer is arranged on the special-shaped five-way reactor (51), the double-phase flow atomizer is connected with the raw material storage tank and the high-pressure air source, and the reaction materials enter the special-shaped five-way reactor (51) after being atomized by the double-phase flow atomizer.
2. The skid-mounted system of the two-phase flow molecular reactor according to claim 1, wherein 4 two-phase flow atomizers are provided, the 4 two-phase flow atomizers are uniformly arranged on the cross section at 1/3 from the top of the special five-way reactor cylinder, the material spraying speed of the two-phase flow atomizers is 100m/s, and the size of the fog drops is 1-1.2 microns; materials in the raw material storage tank are atomized by the double-phase flow atomizer and then form a smoke-shaped reaction area in the special-shaped five-way reactor, the discharge speed, the atomization effect, the fluid mixing effect in the reaction area and the chemical reaction rate among the materials are controlled by adjusting the flow ratio of the high-pressure plunger metering pump to the digital gas flow meter, and the gas-liquid flow ratio is 300: 1-10: 1.
3. The skid-mounted system of the dual-phase flow molecular reactor according to claim 1, wherein two raw material storage tanks are provided and are respectively connected with the dual-phase flow atomizer through high-pressure plunger metering pumps, and a single high-pressure plunger metering pump supplies materials to the adjacent dual-phase flow atomizer; the high-pressure gas source uniformly supplies gas to the 4 double-phase flow atomizers through a digital gas flowmeter (42); the high pressure gas source is a high purity inert gas including, but not limited to, nitrogen or argon.
4. The two-phase flow molecular reactor skid-mounted system as set forth in claim 2, wherein the upper part of the special-shaped five-way reactor (51) is cylindrical, and the height-diameter ratio of the cylinder is 2: 1; the bottom is conical, and the height of the cone is 1/3 of the total height of the special-shaped five-way reactor; the special-shaped five-way reactor (51) is provided with a temperature control jacket; the discharge hole at the bottom of the cylinder body of the special-shaped five-way reactor (51) is connected with the high-speed flat centrifuge (52) in a seamless way.
5. The dual-phase flow molecular reactor skid system as set forth in claim 1, wherein the high-speed flat centrifuge (52) is equipped with a weighing module and a relay, and when the material in the high-speed flat centrifuge (52) reaches a certain weight, the centrifuge is started to perform solid-liquid-gas centrifugal separation; the upper part of the machine cover of the high-speed flat plate centrifuge (52) is provided with a safety valve, when the air pressure in the centrifuge reaches 0.4Mpa, the safety valve is automatically opened, and the exhaust port of the safety valve is connected with an exhaust fan tail gas recovery processing system (71).
6. The skid-mounted system for the two-phase flow molecular reactor as set forth in claim 4, wherein the special-shaped five-way reactor (51) is provided with a high-temperature and low-temperature interface (61).
7. A two-phase flow molecular reactor skid system as set forth in any of claims 1-6, wherein all the fittings of the reactor skid system are mounted on the I-beam frame and have a PLC control system (81).
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| US20080250715A1 (en) * | 2007-04-12 | 2008-10-16 | Cefco, Llc | Process and apparatus for carbon capture and elimination of multi-pollutants in fuel gas from hydrocarbon fuel sources and recovery of multiple by-products |
| CN203750407U (en) * | 2014-06-06 | 2014-08-06 | 中国重型机械研究院股份公司 | Device for desulfurizing and deflurinating smoke of movable bed |
| CN108251286A (en) * | 2016-12-28 | 2018-07-06 | 云南师范大学 | A kind of gas-liquid atomization high-efficiency bioreactor |
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