CN115058651A - Forged steel cold-rolling working roll with roll mark resistance and manufacturing method thereof - Google Patents

Forged steel cold-rolling working roll with roll mark resistance and manufacturing method thereof Download PDF

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Publication number
CN115058651A
CN115058651A CN202210717958.7A CN202210717958A CN115058651A CN 115058651 A CN115058651 A CN 115058651A CN 202210717958 A CN202210717958 A CN 202210717958A CN 115058651 A CN115058651 A CN 115058651A
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percent
roll
treatment
forged steel
steel cold
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CN115058651B (en
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鞠贤琴
李北玉
陈伟
张青
崔海峰
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Baosteel Roll Science & Technology Co ltd
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Baosteel Roll Science & Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/02Shape or construction of rolls
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/06Surface hardening
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/004Heat treatment of ferrous alloys containing Cr and Ni
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/005Heat treatment of ferrous alloys containing Mn
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/008Heat treatment of ferrous alloys containing Si
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00Heat treatment of ferrous alloys
    • C21D6/04Hardening by cooling below 0 degrees Celsius
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/38Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for roll bodies
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/44Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/40Ferrous alloys, e.g. steel alloys containing chromium with nickel
    • C22C38/46Ferrous alloys, e.g. steel alloys containing chromium with nickel with vanadium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Geometry (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The invention discloses a forged steel cold rolling working roll with roll mark resistance and a manufacturing method thereof, and the method comprises the steps of smelting and forging a roll blank according to chemical components and weight percentages, performing preliminary heat treatment and performing final heat treatment; the chemical components and the weight percentage are as follows: 0.88 to 1.05 percent of carbon, 0.50 to 0.90 percent of silicon, 0.10 to 0.70 percent of manganese, less than or equal to 0.020 percent of phosphorus, less than or equal to 0.015 percent of sulfur, 2.60 to 3.20 percent of chromium, 0.60 to 0.90 percent of nickel, 0.10 to 0.60 percent of molybdenum, 0.05 to 0.40 percent of vanadium, and the balance of iron and inevitable impurities; the final heat treatment comprises surface quenching treatment at 910-950 ℃, subzero treatment at-180-160 ℃ for 4-6 h, and low-temperature tempering treatment at 80-150 ℃ for 60-150 h. According to the invention, on one hand, the alloy content is optimized (mainly the Ni content of the conventional Cr3 material is increased), and on the other hand, the heat treatment process is optimized (mainly the cryogenic treatment temperature is selected and the cryogenic treatment time is prolonged), so that the forged steel cold rolling working roll of the Cr3 material with the matrix hardness of more than 65HRC can be finally prepared, and the roll mark resistance requirement can be met.

Description

Forged steel cold-rolling working roll with roll mark resistance and manufacturing method thereof
Technical Field
The invention belongs to the technical field of forged steel cold rolling working rolls, and particularly relates to a forged steel cold rolling working roll with roll mark resistance and a manufacturing method thereof.
Background
At present, the method for solving the problems of roll marks and scratches of the plates mainly aims at controlling relevant factors. For example, methods of controlling the pressing of the roll system, controlling the tension deviation of each stand, adding a dedicated baffle to the rolling mill, cleaning the nozzle, and the like; in addition, methods such as controlling the grinding of the roll and texturing may be employed to further reduce the occurrence of roll marks and scratches.
However, many of the above methods cannot be effectively implemented considering the different actual use conditions of each steel mill, and some methods may work in a certain steel mill but may not work in another steel mill.
The hardness of the matrix of the forged steel cold rolling working roll with the roll mark resistance is required to be more than 65HRC, and the hardness of the matrix of the existing forged steel cold rolling working roll made of Cr3 material is difficult to meet the requirement. Therefore, the work rolls for cold rolling of forged steel having rolling mark resistance are basically made of Cr5 (documents 1 to 2) or Cr6 (documents 3 to 5).
Therefore, the technical problem to be solved in the field is to improve the matrix hardness of the forged steel cold rolling working roll made of Cr3 material to enable the forged steel cold rolling working roll to have the rolling mark resistance.
Document 1: chinese patent document CN102644026A, published 2012, 8, 22.
Document 2: chinese patent document CN104195450A, published 2014, 12 months and 10 days.
Document 3: chinese patent document CN101481776A, published 2009, 7/15.
Document 4: chinese patent document CN103614635A, published 3/5/2014.
Document 5: chinese patent document CN106734805A, published 2017, 5 and 31.
Disclosure of Invention
The invention aims to solve the problems and provides a forged steel cold rolling work roll which is made of Cr3 material and has the rolling mark resistance and the matrix hardness of 65HRC or more and a manufacturing method thereof, so as to fill the blank in the field.
The technical scheme for realizing the purpose of the invention is as follows: a method for manufacturing a forged steel cold rolling working roll with roll mark resistance comprises the steps of smelting and forging a roll blank according to chemical components and weight percentages, performing preliminary heat treatment and performing final heat treatment.
The chemical components and the weight percentage are as follows: 0.88 to 1.05 percent of carbon, 0.50 to 0.90 percent of silicon, 0.10 to 0.70 percent of manganese, less than or equal to 0.020 percent of phosphorus, less than or equal to 0.015 percent of sulfur, 2.60 to 3.20 percent of chromium, 0.60 to 0.90 percent of nickel, 0.10 to 0.60 percent of molybdenum, 0.05 to 0.40 percent of vanadium, and the balance of iron and inevitable impurities.
The preliminary heat treatment comprises quenching and tempering at 880-920 ℃ for 8-10 hours and high-temperature tempering at 600-650 ℃ for 10-30 hours.
The final heat treatment comprises surface quenching treatment at 910-950 ℃, subzero treatment at-180-160 ℃ for 4-6 h, and low-temperature tempering treatment at 80-150 ℃ for 60-150 h.
At present, the conventional time of subzero treatment at the temperature of below 150 ℃ below zero is 2-3 h, and the applicant finds that the subzero treatment time is prolonged by 1 time, namely 4-6 h, so that the hardness of a matrix can be effectively improved and the depth of higher matrix hardness can be increased.
Before quenching, the deformation of the roller is ensured to be within 3mm through thermal straightening.
The invention has the following positive effects: according to the invention, on one hand, by optimizing the alloy content (mainly increasing the Ni content of the conventional Cr3 material) and on the other hand, by optimizing the heat treatment process (mainly selecting the cryogenic treatment temperature and prolonging the cryogenic treatment time), the forged steel cold rolling working roll of the Cr3 material with the matrix hardness of more than 65HRC can be finally prepared, so that the roll mark resistance requirement can be met.
Detailed Description
(example 1)
The forged steel cold rolling work roll (having a gauge of Φ 435mm × 1420mm × 3400 mm) having roll mark resistance of the present example was produced by the following method:
smelting and forging a roller blank by a conventional method according to the following chemical components in percentage by weight: 0.95 percent of carbon, 0.70 percent of silicon, 0.40 percent of manganese, less than or equal to 0.020 percent of phosphorus, less than or equal to 0.015 percent of sulfur, 2.90 percent of chromium, 0.75 percent of nickel, 0.35 percent of molybdenum, 0.20 percent of vanadium, and the balance of iron and inevitable impurities.
② preliminary heat treatment.
Comprises quenching and tempering at 900 +/-5 ℃ for 9 hours and tempering at 620 +/-5 ℃ for 20 hours.
And thirdly, final heat treatment.
Comprises surface quenching treatment at 930 +/-5 ℃, deep cooling treatment at-170 +/-5 ℃ for 5h and low-temperature tempering treatment at 120 +/-5 ℃ for 96 h.
Before quenching, the deformation of the roller is ensured to be within 3mm through hot straightening.
(examples 2 to 3)
The manufacturing method of the forged steel cold rolling working roll with the rolling mark resistance of each example is the same as that of example 1, except for the chemical components and the weight percentage, which is shown in table 1.
(examples 4 to 5)
The forged steel cold rolling working roll with the rolling mark resistance of each example has the same chemical components and weight percentages as those of example 1, except for the final heat treatment process parameters, which are shown in table 1.
TABLE 1
Example 1 Example 2 Example 3 Example 4 Example 5
Carbon (C) 0.95% 0.90% 1.00% 0.95% 0.95%
Silicon 0.70% 0.55% 0.85% 0.70% 0.70%
Manganese oxide 0.40% 0.20% 0.60% 0.40% 0.40%
Phosphorus (P) ≤0.020% ≤0.020% ≤0.020% ≤0.020% ≤0.020%
Sulfur ≤0.015% ≤0.015% ≤0.015% ≤0.015% ≤0.015%
Chromium (III) 2.90% 2.70% 3.10% 2.90% 2.90%
Nickel (II) 0.75% 0.65% 0.85% 0.75% 0.75%
Molybdenum (Mo) 0.35% 0.15% 0.55% 0.35% 0.35%
Vanadium oxide 0.20% 0.10% 0.35% 0.20% 0.20%
Temperature of surface hardening 930±5℃ 930±5℃ 930±5℃ 920±5℃ 940±5℃
Temperature of cryogenic treatment -170±5℃ -170±5℃ -170±5℃ -175±5℃ -165±5℃
Time of cryogenic treatment 5h 5h 5h 4.5h 5.5h
Hardness of matrix 65.6HRC 65.3HRC 65.7HRC 65.4HRC 65.5HRC
Surface hardness 97~98HSD 96~97HSD 97~98HSD 96~97HSD 97~98HSD
(comparative example 1 to comparative example 2)
The production process of each comparative forged steel cold-rolled work roll was the same as in example 1, except for the nickel content, as specified in table 2.
(comparative examples 3 to 4)
The chemical components and weight percentages of the forged steel cold rolling working rolls in each proportion are the same as those of the working roll in the example 1, except for the cryogenic treatment process parameters, which are shown in the table 2.
TABLE 2
Example 1 Comparative example 1 Comparative example 2 Comparative example 3 Comparative example 4
Nickel (II) 0.75% 0.20% 0.40% 0.75% 0.75%
Temperature of cryogenic treatment -170±5℃ -170±5℃ -170±5℃ -170±5℃ -100±5℃
Time of cryogenic treatment 5h 5h 5h 2.5h 5h
Hardness of matrix 65.6HRC 62.8HRC 63.5HRC 64.3HRC 62.7HRC
Surface hardness 97~98HSD 96~97HSD 96~97HSD 97~98HSD 95~96HSD

Claims (5)

1. A manufacturing method of a forged steel cold rolling working roll with roll mark resistance comprises the steps of smelting and forging a roll blank according to chemical components and weight percentages, performing preliminary heat treatment and performing final heat treatment; the method is characterized in that: the chemical components and the weight percentage are as follows: 0.88 to 1.05 percent of carbon, 0.50 to 0.90 percent of silicon, 0.10 to 0.70 percent of manganese, less than or equal to 0.020 percent of phosphorus, less than or equal to 0.015 percent of sulfur, 2.60 to 3.20 percent of chromium, 0.60 to 0.90 percent of nickel, 0.10 to 0.60 percent of molybdenum, 0.05 to 0.40 percent of vanadium, and the balance of iron and inevitable impurities.
2. The method for manufacturing a forged steel cold-rolled work roll having roll mark resistance according to claim 1, wherein: the preliminary heat treatment comprises quenching and tempering at 880-920 ℃ for 8-10 hours and high-temperature tempering at 600-650 ℃ for 10-30 hours.
3. The method for manufacturing a forged steel cold-rolled work roll having roll mark resistance according to claim 1, wherein: the final heat treatment comprises surface quenching treatment at 910-950 ℃, subzero treatment at-180-160 ℃ for 4-6 h, and low-temperature tempering treatment at 80-150 ℃ for 60-150 h.
4. The method for manufacturing a forged steel cold-rolled work roll having roll mark resistance according to claim 2, wherein: the final heat treatment comprises surface quenching treatment at 910-950 ℃, subzero treatment at-180-160 ℃ for 4-6 h, and low-temperature tempering treatment at 80-150 ℃ for 60-150 h.
5. A forged steel cold rolled work roll having roll mark resistance properties made by the method of any one of claims 1 to 4.
CN202210717958.7A 2022-06-23 2022-06-23 Forged steel cold rolling working roll with roll mark resistance and manufacturing method thereof Active CN115058651B (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61147815A (en) * 1984-12-21 1986-07-05 Kawasaki Steel Corp Production of roll having high hardened depth
JPS6456826A (en) * 1987-08-27 1989-03-03 Kawasaki Steel Co Production of operating roll for high-load cold rolling mill having great case depth
JPH07145449A (en) * 1993-11-19 1995-06-06 Japan Steel Works Ltd:The High wear resistant cold rolled working roll
CN101265554A (en) * 2008-04-25 2008-09-17 常州宝隆冶金设备制造有限公司 Modified roller material
CN101481776A (en) * 2009-02-13 2009-07-15 宝钢集团常州轧辊制造公司 Cold rolling working roll with anti-rollar mark and high-wearing resistance and manufacturing method thereof
CN104032117A (en) * 2014-05-12 2014-09-10 宜兴市永昌轧辊有限公司 Heat treatment method for ultra-high-hardness nonferrous-metal cold roll
CN105063502A (en) * 2015-07-25 2015-11-18 宜兴市永昌轧辊有限公司 Improved cold roller and preparation method thereof
CN105256245A (en) * 2015-10-15 2016-01-20 中钢集团邢台机械轧辊有限公司 Cold rolling roller with ultra-deep hardening layer and manufacturing method of cold rolling roller
CN108220775A (en) * 2017-12-29 2018-06-29 中钢集团邢台机械轧辊有限公司 A kind of copper foil operation roll of mill
CN109554612A (en) * 2018-12-10 2019-04-02 宜兴市永昌轧辊有限公司 A kind of novel cold rolling working roll and preparation method thereof

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61147815A (en) * 1984-12-21 1986-07-05 Kawasaki Steel Corp Production of roll having high hardened depth
JPS6456826A (en) * 1987-08-27 1989-03-03 Kawasaki Steel Co Production of operating roll for high-load cold rolling mill having great case depth
JPH07145449A (en) * 1993-11-19 1995-06-06 Japan Steel Works Ltd:The High wear resistant cold rolled working roll
CN101265554A (en) * 2008-04-25 2008-09-17 常州宝隆冶金设备制造有限公司 Modified roller material
CN101481776A (en) * 2009-02-13 2009-07-15 宝钢集团常州轧辊制造公司 Cold rolling working roll with anti-rollar mark and high-wearing resistance and manufacturing method thereof
CN104032117A (en) * 2014-05-12 2014-09-10 宜兴市永昌轧辊有限公司 Heat treatment method for ultra-high-hardness nonferrous-metal cold roll
CN105063502A (en) * 2015-07-25 2015-11-18 宜兴市永昌轧辊有限公司 Improved cold roller and preparation method thereof
CN105256245A (en) * 2015-10-15 2016-01-20 中钢集团邢台机械轧辊有限公司 Cold rolling roller with ultra-deep hardening layer and manufacturing method of cold rolling roller
CN108220775A (en) * 2017-12-29 2018-06-29 中钢集团邢台机械轧辊有限公司 A kind of copper foil operation roll of mill
CN109554612A (en) * 2018-12-10 2019-04-02 宜兴市永昌轧辊有限公司 A kind of novel cold rolling working roll and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
唐广银;杨国平;: "一种新型抗辊印轧辊的研制" *
李北玉等: "不同材质的锻钢冷轧工作辊耐磨性试验研究" *

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