CN115025750A - Water ecological coenzyme and preparation method thereof - Google Patents

Water ecological coenzyme and preparation method thereof Download PDF

Info

Publication number
CN115025750A
CN115025750A CN202210715283.2A CN202210715283A CN115025750A CN 115025750 A CN115025750 A CN 115025750A CN 202210715283 A CN202210715283 A CN 202210715283A CN 115025750 A CN115025750 A CN 115025750A
Authority
CN
China
Prior art keywords
coenzyme
water
ion solution
modified
modified nano
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN202210715283.2A
Other languages
Chinese (zh)
Other versions
CN115025750B (en
Inventor
倪海燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Lingshui Technology Co ltd
Original Assignee
Zhejiang Lingshui Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Lingshui Technology Co ltd filed Critical Zhejiang Lingshui Technology Co ltd
Priority to CN202210715283.2A priority Critical patent/CN115025750B/en
Publication of CN115025750A publication Critical patent/CN115025750A/en
Application granted granted Critical
Publication of CN115025750B publication Critical patent/CN115025750B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • C02F3/342Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/08Radiation
    • A61L2/10Ultraviolet radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/10Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing sonic or ultrasonic vibrations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/12Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Microbiology (AREA)
  • Toxicology (AREA)
  • Analytical Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Hydrology & Water Resources (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Inorganic Chemistry (AREA)
  • Electromagnetism (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Physical Water Treatments (AREA)

Abstract

The invention relates to a water ecological coenzyme, which comprises the following components in parts by weight: 0.0001-1 part of modified nano silicon dioxide, 0.001-1 part of calcium ion solution, 0.001-0.5 part of magnesium ion solution and 8-12 parts of deionized water; wherein the modified nano-silica, the calcium ion solution and the magnesium ion solution are treated to form a modified material. The invention provides a water ecological coenzyme and a preparation method thereof, the water ecological coenzyme dissolves modified nano silicon dioxide in water, then magnesium ions and calcium ions are added, finally the water ecological coenzyme is modified by electromagnetism and ultrasonic waves, and the water ecological coenzyme has the characteristics of strong adsorbability and the like, thereby playing a role of a bridge when biological enzyme is combined with a substrate, further improving the biological enzyme activity of organisms in water, obviously improving the removal efficiency of pollutants in water, improving the self-cleaning capability of water, improving the sewage purification efficiency and enhancing the sewage treatment effect.

Description

Water ecological coenzyme and preparation method thereof
Technical Field
The invention relates to the technical field of water pollution treatment, in particular to water ecological coenzyme and a preparation method thereof.
Background
Water pollution is the reduction or loss of the use value of water caused by harmful chemical substances, water polluting the environment, acid, alkali and oxidant in sewage, compounds such as copper, cadmium, mercury, arsenic and the like, organic poisons such as benzene, dichloroethane, ethylene glycol and the like can kill aquatic organisms and affect the drinking water source and scenic spot landscape, oxygen in water is consumed when organic matters in the sewage are decomposed by microorganisms to affect the life of the aquatic organisms, and after dissolved oxygen in the water is exhausted, the organic matters are subjected to anaerobic decomposition to generate unpleasant gases such as hydrogen sulfide, mercaptan and the like, so that the water quality is further deteriorated. Most of the existing water pollution treatment methods are to add chemical purifying agents into water to treat and purify water, but the chemical purifying agents can generate some toxic gases such as hydrogen sulfide, ammonia gas and the like after purification, so that secondary pollution is caused to water bodies, the purification effect is poor, and the purification efficiency is low.
Disclosure of Invention
The invention aims to overcome the problems in the prior art and provides an aquatic ecological coenzyme and a preparation method thereof.
In order to achieve the technical purpose and achieve the technical effect, the invention is realized by the following technical scheme:
the invention provides a water ecological coenzyme, which comprises the following components in parts by weight: 0.0001-1 part of modified nano silicon dioxide, 0.001-1 part of calcium ion solution, 0.001-0.5 part of magnesium ion solution and 8-12 parts of deionized water;
wherein the modified nano-silica, the calcium ion solution and the magnesium ion solution are processed to form a modified material.
In one embodiment of the invention, the water ecological coenzyme comprises the following components in parts by weight: 0.5 part of modified nano silicon dioxide, 0.05 part of calcium ion solution, 0.09 part of magnesium ion solution and 10 parts of deionized water.
In one embodiment of the invention, the modified silica is physically modified nanosilica.
The invention also provides a preparation method of the water ecological coenzyme, which comprises the following steps:
modifying nano silicon dioxide to obtain the modified nano silicon dioxide;
performing electromagnetic treatment on the modified nano-silica, adding the deionized water to form a modified nano-silica solution, adding the calcium ion solution and the magnesium ion solution to the modified nano-silica solution, and performing ultrasonic and electromagnetic treatment to form a modified material;
and (3) carrying out ultraviolet disinfection on the formed modified material to form the water ecological coenzyme.
In one embodiment of the invention, the concentration of the modified nanosilica solution is from 1 to 100000 ppm.
In one embodiment of the invention, the concentration of the calcium ion solution is 10 to 100000 ppm.
In one embodiment of the invention, the magnesium ion concentration is 10-50000 ppm.
In conclusion, the invention provides the water ecological coenzyme and the preparation method thereof, the water ecological coenzyme dissolves the modified nano silicon dioxide in water, then magnesium ions and calcium ions are added, finally the water ecological coenzyme is subjected to electromagnetic and ultrasonic modification treatment, and the water ecological coenzyme has the characteristics of strong adsorbability and the like, so that the water ecological coenzyme has a bridge function when biological enzymes and substrates are combined, the biological enzyme activity of organisms in water is further improved, the removal efficiency of pollutants in water can be obviously improved, the sewage purification efficiency is improved, and the sewage treatment effect is enhanced.
Detailed Description
The present invention will be described in detail with reference to examples.
The invention provides an aquatic ecological coenzyme which can improve the quality of sewage. Specifically, the component of the water ecological coenzyme comprises 0.0001-1 part of modified nano silicon dioxide by weight, for example, 0.5 part. The type of the modified nano-silica is not limited in the present application, and in one embodiment of the present invention, the modified nano-silica may be nano-silica modified by physical methods such as electromagnetic methods.
The water ecological coenzyme also comprises 0.01-1 part of calcium ion solution, 0.01-0.5 part of magnesium ion solution and 8-12 parts of deionized water according to parts by weight. Wherein the calcium ion solution, the magnesium ion solution and the modified nano silicon dioxide are treated to form the modified material. In one embodiment of the present invention, the calcium ion solution may be, for example, 0.05 parts, the magnesium ion solution may be, for example, 0.09 parts, and the deionized water may be, for example, 10 parts.
The invention also provides a preparation method of the water ecological coenzyme, which comprises the following steps of S1-S3:
s1, modifying the nano silicon dioxide to obtain the modified nano silicon dioxide. Specifically, the method for modifying nano-silica is not limited in the present application, and in one embodiment of the present invention, nano-silica may be modified by a physical method, for example, silica may be modified by ultrasonic waves.
S2, performing electromagnetic treatment on the modified nano-silica, adding the modified nano-silica into the deionized water to form a modified nano-silica solution, adding the calcium ion solution and the magnesium ion solution into the modified nano-silica solution, and performing ultrasonic and electromagnetic treatment to form a modified material. In one embodiment of the invention, the concentration of the modified nanosilica solution may be in the range of 1-100000ppm, for example may be 1ppm, 200ppm, 1000ppm, 5000ppm or 100000 ppm. The concentration of the calcium ion solution may be 10 to 100000ppm, and for example, may be 10ppm, 500ppm, 5000ppm or 100000 ppm. The magnesium ion concentration may be 10-50000ppm, for example 10ppm, 500ppm, 25000ppm or 50000 ppm. The calcium ion solution of the present application may be a calcium chloride solution, but is not limited thereto. The magnesium ion solution may be a magnesium chloride solution, but is not limited thereto.
S3, ultraviolet disinfection is carried out on the modified material to form the water ecological coenzyme. Specifically, the modified material may be sterilized by an ultraviolet sterilizing lamp, and the sterilizing time of the ultraviolet sterilizing lamp may be, for example, 1 to 2 hours, and may be, for example, 1.5 hours.
The method comprises the following steps of purifying and treating sewage of the same water body by using the water ecological coenzyme prepared by the method, the coenzyme without adding the modified nano silicon dioxide and the coenzyme without performing ultrasonic and electromagnetic treatment under the same condition, wherein the sewage is divided into a group A, a group B and a group C, specifically, the sewage treatment temperature is 30 ℃, the adding amount of a water quality modifier is 1g, pollutants in the sewage are detected by a detector at the same time node, the detection time nodes are 0min, 30min, 60min, 90min and 120min, and the specific data are as follows:
Figure BDA0003708578890000051
in conclusion, the invention provides the water ecological coenzyme and the preparation method thereof, the water ecological coenzyme dissolves the modified nano silicon dioxide in water, then magnesium ions and calcium ions are added, finally the water ecological coenzyme is modified by electromagnetism and ultrasonic waves, and the water ecological coenzyme has the characteristics of strong adsorbability and the like, thereby playing a bridge role when biological enzyme is combined with a substrate, further improving the biological enzyme activity of organisms in water, obviously improving the removal efficiency of pollutants in water, improving the sewage purification efficiency and enhancing the sewage treatment effect. Group A can know after group B and group C contrast, the aquatic attitude coenzyme of this application can improve and purify sewage efficiency and reinforcing sewage treatment effect.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed.

Claims (7)

1. The aquatic ecological coenzyme is characterized by comprising the following components in parts by weight: 0.0001-1 part of modified nano silicon dioxide, 0.001-1 part of calcium ion solution, 0.001-0.5 part of magnesium ion solution and 8-12 parts of deionized water;
wherein the modified nano-silica, the calcium ion solution and the magnesium ion solution are processed to form a modified material.
2. The aquatic ecological coenzyme according to claim 1, wherein the aquatic ecological coenzyme comprises the following components in parts by weight: 0.5 part of modified nano silicon dioxide, 0.05 part of calcium ion solution, 0.09 part of magnesium ion solution and 10 parts of deionized water.
3. The aquatic coenzyme of claim 1, wherein the modified silica is a nanosilica that is physically modified.
4. A method for preparing an aquatic coenzyme according to any of claims 1 to 3, comprising the steps of:
modifying nano silicon dioxide to obtain the modified nano silicon dioxide;
performing electromagnetic treatment on the modified nano-silica, adding the deionized water to form a modified nano-silica solution, adding the calcium ion solution and the magnesium ion solution to the modified nano-silica solution, and performing ultrasonic and electromagnetic treatment to form a modified material;
and (3) carrying out ultraviolet disinfection on the formed modified material to form the water ecological coenzyme.
5. The method for producing an aquatic coenzyme according to claim 4, characterized in that: the concentration of the modified nano silicon dioxide solution is 1-100000 ppm.
6. The method for producing an aquatic coenzyme according to claim 4, characterized in that: the concentration of the calcium ion solution is 10-100000 ppm.
7. The method for producing an aquatic coenzyme according to claim 4, characterized in that: the concentration of the magnesium ions is 10-50000 ppm.
CN202210715283.2A 2022-06-22 2022-06-22 Water ecological coenzyme and preparation method thereof Active CN115025750B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210715283.2A CN115025750B (en) 2022-06-22 2022-06-22 Water ecological coenzyme and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210715283.2A CN115025750B (en) 2022-06-22 2022-06-22 Water ecological coenzyme and preparation method thereof

Publications (2)

Publication Number Publication Date
CN115025750A true CN115025750A (en) 2022-09-09
CN115025750B CN115025750B (en) 2024-06-11

Family

ID=83126620

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210715283.2A Active CN115025750B (en) 2022-06-22 2022-06-22 Water ecological coenzyme and preparation method thereof

Country Status (1)

Country Link
CN (1) CN115025750B (en)

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU7602887A (en) * 1986-07-22 1988-01-28 Commonwealth Scientific And Industrial Research Organisation Coating photoactive metal oxides onto substrates
JPH02227196A (en) * 1989-03-01 1990-09-10 Kansai Eng:Kk Treatment material for heavy metal and heavy metal ion
JP2007175568A (en) * 2005-12-27 2007-07-12 Kn Platz:Kk Liquid purification system, liquid purification method, and settling accelerator
CN101734777A (en) * 2008-11-24 2010-06-16 财团法人工业技术研究院 Method for reducing silicon dioxide in water
JP2010247122A (en) * 2009-04-20 2010-11-04 J Top Kk Method and device for removing adhesion substance from porous adsorbent
CN109110835A (en) * 2018-09-12 2019-01-01 南京途酷信息科技有限公司 A kind of new chemical water treatment agent
CN110002607A (en) * 2019-04-16 2019-07-12 上海泰缘生物科技股份有限公司 A kind of Tiny ecosystem activation system and its Tiny ecosystem of preparation activate bag
CN110526355A (en) * 2018-05-26 2019-12-03 王忠厚 A kind of Novel pollution-free water purification agent prescription and preparation method thereof
CN110642343A (en) * 2019-11-08 2020-01-03 北京林业大学 Preparation and application of magnetic flocculant for removing suspended particles in water
CN113087038A (en) * 2021-04-07 2021-07-09 神美科技有限公司 Ammonia nitrogen remover for sewage treatment

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU7602887A (en) * 1986-07-22 1988-01-28 Commonwealth Scientific And Industrial Research Organisation Coating photoactive metal oxides onto substrates
JPH02227196A (en) * 1989-03-01 1990-09-10 Kansai Eng:Kk Treatment material for heavy metal and heavy metal ion
JP2007175568A (en) * 2005-12-27 2007-07-12 Kn Platz:Kk Liquid purification system, liquid purification method, and settling accelerator
CN101734777A (en) * 2008-11-24 2010-06-16 财团法人工业技术研究院 Method for reducing silicon dioxide in water
JP2010247122A (en) * 2009-04-20 2010-11-04 J Top Kk Method and device for removing adhesion substance from porous adsorbent
CN110526355A (en) * 2018-05-26 2019-12-03 王忠厚 A kind of Novel pollution-free water purification agent prescription and preparation method thereof
CN109110835A (en) * 2018-09-12 2019-01-01 南京途酷信息科技有限公司 A kind of new chemical water treatment agent
CN110002607A (en) * 2019-04-16 2019-07-12 上海泰缘生物科技股份有限公司 A kind of Tiny ecosystem activation system and its Tiny ecosystem of preparation activate bag
CN110642343A (en) * 2019-11-08 2020-01-03 北京林业大学 Preparation and application of magnetic flocculant for removing suspended particles in water
CN113087038A (en) * 2021-04-07 2021-07-09 神美科技有限公司 Ammonia nitrogen remover for sewage treatment

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
崔月梅等: "纳米SiO2的修饰改性及其在吸附剂中的应用", 《硅谷》, vol. 22, pages 1 *

Also Published As

Publication number Publication date
CN115025750B (en) 2024-06-11

Similar Documents

Publication Publication Date Title
CN111762880B (en) Method for biologically and intensively treating refractory organic pollutants based on light-excited holes as electron acceptors
CN110697934B (en) Method for reducing disinfection by-products of drinking water
CN1879946A (en) Biological method for simultaneously removing SO2,NOX,heavy metal and granule from gas
CN105753248A (en) Evaporation pretreatment method of reverse osmosis concentrated saline solution
CN114014432A (en) Method for removing organic pollutants in water by activating persulfate through nutrition-enhanced soybean bud-based biochar
CN111484158A (en) Pretreatment method of glyphosate production wastewater
CN116571072B (en) Malodorous waste gas water-based composite absorbent and preparation method and application thereof
CN115025750B (en) Water ecological coenzyme and preparation method thereof
CN112473360A (en) Method for anaerobic treatment of chlorobenzene waste gas by using microbial electrolysis cell
CN112452145A (en) Treatment method of ammonia-containing waste gas
CN104150678A (en) Treatment method for nitrogen-containing organic wastewater
Rajab Beiki et al. Effect of metal nanoparticles on biological denitrification process: a review
CN104860455A (en) Methylene dithiocyanate wastewater treatment method
CN104609545B (en) Method and apparatus for biochemical treatment of high concentration nitrate wastewater
CN108640257B (en) Method for removing bisphenol compounds by using citrate-enhanced FeS and microorganism composite system
CN111249871A (en) Method for treating VOCs and malodorous gases generated in sucralose production process
CN107673459A (en) A kind of method of antifebrin in removal waste water
CN113683246B (en) Purifying treatment method for wastewater containing cyanide
CN218951190U (en) Production wastewater treatment device
CN111392847B (en) Water treatment method for promoting trace copper ions to generate Cu (III) by using background pollutants
CN116119875B (en) Medical wastewater treatment method
CN114772812A (en) Method for degrading chloramphenicol based on ultraviolet/sulfite system
CN118724153A (en) Method for degrading sulfamethoxazole by activating peroxyacetic acid with ultraviolet light and product
CN116730554A (en) Advanced treatment process for leaching liquor of garbage incineration plant
Dai Removal of Disinfection Byproducts in Drinking Water Using Biological Filtration

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant