CN115024317A

CN115024317A - Efficient flying-prevention aid and preparation method and application thereof

Info

Publication number: CN115024317A
Application number: CN202210766710.XA
Authority: CN
Inventors: 闵加礼; 付萍萍; 刘伟; 于福利; 郭海鹏
Original assignee: Shaanxi Yinong Shangpin Agriculture Co ltd
Current assignee: Shaanxi Yinong Shangpin Agriculture Co ltd
Priority date: 2022-07-01
Filing date: 2022-07-01
Publication date: 2022-09-09
Anticipated expiration: 2042-07-01
Also published as: CN115024317B

Abstract

The invention relates to a high-efficiency flight control assistant which comprises the following raw materials in parts by weight: 100 parts of water, 8-14 parts of an anti-drift agent, 6-9 parts of polyoxyethylene ether phosphate, 3-5 parts of gemini sulfonate surfactant, 4-7 parts of an organic silicon wetting agent, 1-3 parts of a viscosity regulator, 1-5 parts of an antifreezing agent and 3-5 parts of a settling agent. The flying prevention auxiliary agent is highly stable and can keep stable for a long time in a wide range of pH6.5-8.4. The flying prevention auxiliary agent provided by the invention has excellent comprehensive performance, excellent drift prevention performance and evaporation resistance. Can adopt unmanned aerial vehicle etc. to spray crops high-efficiently, effective performance flies to prevent the utility.

Description

Efficient flight control auxiliary agent and preparation method and application thereof

Technical Field

The invention relates to the technical field of pesticide auxiliary agents, and particularly relates to a high-efficiency flight control auxiliary agent and a preparation method and application thereof.

Background

China is a big agricultural country, and modern agricultural production is a large-scale and integrated production mode. At present, the modern automatic or semi-automatic production mode is used. At present, the unmanned aerial vehicle is used for preventing and treating diseases and pests in agriculture and forestry, and can also be called aerial plant protection, namely flying prevention for short. In the past, the agriculture and forestry operation production mainly depends on each farmer to prevent and control the diseases and insect pests, and the efficiency is not high. At present, large-scale agriculture and forestry have shown certain development situation, and the production mode taking farmers as units is changing to the modernized agricultural production mode of large-scale, group, large-scale and automation in the past with small area. The flight control plant protection has important scientific research value and implementation and application significance at present.

However, the main problems of the current flight control aids are that: 1) the product is unstable, the problem of layering/precipitation is easy to occur in the storage process, the prevention and treatment effect is poor, and even a spray head can be blocked in serious cases; 2) fog drops are easy to drift in the spraying process, harm to surrounding crops, people and livestock can be caused, the utilization efficiency of pesticides is reduced, the drift phenomenon is mainly reduced by adding an anti-drift agent at present, but the dispersion of liquid medicine can be influenced by adding the anti-drift agent; 3) the applicability of the flight control adjuvant to pesticides, a flight control adjuvant which has good solubilization, stability, volatilization resistance and absorption and permeation promotion to common pesticides on the market is not available at present, and the flight control adjuvant needs to be specially prepared according to different pesticide types and types, but more than one pesticide can be applied to field control at present, and if the flight control adjuvant needs to be prepared separately for each pesticide, inconvenience is caused, popularization is not facilitated, and application is limited; 4) at present, non-flight control plant protection in China is mainly realized by a small unmanned aerial vehicle, the small fixed wing aircraft can not be used for spraying in farmland areas such as America, Canada and the like, the drug-loading capacity of the unmanned aerial vehicle is small, so that the liquid medicine has the characteristics of low dilution multiple, high concentration and small spraying amount, which provides higher requirements for the release drift property of the flight control auxiliary agent and the stability of the liquid medicine under high concentration,

CN109601531A discloses a multifunctional flying-proof auxiliary agent, which comprises polyethylene glycol, polyglycerol ester, wetting agent, styrene-acrylic emulsion, ethylene glycol diacetate, ethoxy modified polytrisiloxane and glycerol as components. Has good drift resistance and volatility resistance. However, the components are mainly polyether and polyester components, so that the stability of the auxiliary agent is insufficient while the drift resistance and volatility are improved.

CN108935459A discloses a modified vegetable oil flying prevention aid, wherein modified rosin oil is adopted, the layering or precipitation phenomenon in the storage process of the flying prevention aid is improved, the liquid medicine fog drop performance is improved, but precipitation can still be generated in water with high hardness.

CN109644998A discloses a flying prevention aid, which uses fluorocarbon surfactant, although the specific gravity and droplet particle size of the liquid medicine are improved, it has better anti-drift property. But the use of fluorocarbon surfactants can have undesirable effects on some crops. And if the fluorocarbon surfactant is excessive, serious potential safety hazard exists.

Disclosure of Invention

Based on the fact that the current flying prevention auxiliary agent is not excellent enough in comprehensive performance, cannot adapt to water quality with different hardness and pH value, is not enough in compatibility stability of pesticide and fertilizer, has certain contradiction between the anti-drift performance and the diffusion, wetting and permeation of crops, and easily causes the defect of considering the deviation. The invention provides a high-efficiency flight control assistant and a preparation method thereof. According to the invention, through compounding of the components, the gemini sulfonate surfactant is prepared, and the flight control assistant with excellent comprehensive performance is obtained under the condition of low addition of the surfactant, so that the flight control assistant can maintain good stability under various test conditions, and has obviously improved drift resistance and evaporation resistance.

The invention aims to provide a high-efficiency flight control aid, which comprises the following raw materials in parts by weight: 100 parts of water, 8-14 parts of an anti-drift agent, 6-9 parts of polyoxyethylene ether phosphate, 3-5 parts of gemini sulfonate surfactant, 4-7 parts of an organic silicon wetting agent, 1-3 parts of a viscosity regulator, 1-5 parts of an antifreezing agent and 3-5 parts of a settling agent.

The preparation method of the gemini sulfonate surfactant comprises the following steps:

(T1) dissolving 4-hydroxycinnamic acid in an organic solvent, adding a long-chain alkyl alcohol solution, carrying out esterification reaction under the conditions of a catalyst and water diversion reflux, drying, and recrystallizing to obtain an esterified intermediate product;

(T2) reacting the esterified intermediate product obtained in the step (T1) with polyethylene glycol diglycidyl ether at the temperature of 110-140 ℃ for 10-15h under the inert atmosphere and the condition of a basic catalyst;

(T3) adding a sulfonating agent to the mixture obtained after the reaction to conduct sulfonation, and then adjusting the pH to 7-9 with a base.

Further, in the step (T1), the organic solvent is selected from at least one of toluene, benzene and dichloromethane, and the solvent used for the long-chain alkyl alcohol solution is selected from at least one of toluene, benzene and dichloromethane; preferably, the solvent that dissolves the 4-hydroxycinnamic acid and the solvent that dissolves the long chain alkyl alcohol are the same solvent, such as methylene chloride. The catalyst is at least one of p-toluenesulfonic acid and heteropoly acid, and the amount of the catalyst is 3-5% of the mass of the 4-hydroxycinnamic acid. Reacting for 4-8h under the reflux condition, calculating the esterification rate through the acid value to judge the reaction, and stopping the reaction when the esterification rate reaches the maximum. The drying process is well known in the art, and generally vacuum rotary evaporation is adopted, and the product obtained after drying is recrystallized to obtain the esterified intermediate product, and the recrystallization solvent is at least one of ethanol, isopropanol and ethyl acetate.

Further, in the step (T1), the long-chain alkyl alcohol is a linear alkyl alcohol having 12 to 18 carbon atoms, and is specifically at least one selected from the group consisting of dodecanol, tridecanol, tetradecanol, hexadecanol, and octadecanol.

Further, in the step (T1), the number average molecular weight of the polyethylene glycol diglycidyl ether is 600-.

Further, in the step (T2), the inert atmosphere is at least one of nitrogen and argon, and air is removed. The alkaline catalyst is at least one of potassium hydroxide and sodium hydroxide, and the dosage of the catalyst is 5-10% of the mass of the polyethylene glycol diglycidyl ether.

Further, in the step (T3), the sulfonating agent is a compound of sodium bisulfite and chlorosulfonic acid according to a molar ratio of 2-3: 2-3. Wherein sodium bisulfite is the sulfonation of unsaturated double bonds of carbon and carbon, and chlorosulfonic acid is the sulfonation of p-phenyl.

Further, the sulfonation of step (T3) is divided into two steps, including the steps of:

(T3-a) adding sodium bisulfite and a phase transfer catalyst, heating to 80-100 ℃, and reacting for 4-6 h;

(T3-b) cooling the mixture of step (T3-a), slowly adding dropwise chlorosulfonic acid solution under ice salt bath condition, reacting at 0-5 deg.C for 10-15h, and neutralizing with alkali to pH 7-9.

Further, the phase transfer catalyst is cetyl trimethyl ammonium bromide, and the addition amount of the phase transfer catalyst is 1-2% of the mass of the sodium bisulfite.

Sulfonation, post-treatment after neutralization is well known in the art and, in one embodiment of the invention, is vacuum drying, washing, and oven drying to give a brown solid. The washing was with acetone.

Further, in the preparation method, the molar ratio of the 4-hydroxycinnamic acid to the long-chain alkyl alcohol to the polyethylene glycol diglycidyl ether to the sodium bisulfite to the chlorosulfonic acid is 1: 1.2-1.5: 0.4-0.5: 2-4: 1-1.2.

The synthesis route of the gemini sulfonate surfactant may be as follows:

wherein ROH is long-chain alkyl alcohol, and M is Na or K.

The anti-drift agent is selected from at least one of polyacrylamide, guar gum, xanthan gum, lecithin and derivatives thereof; preferably, the weight ratio of polyacrylamide to guar gum is 4-7: 2-3, wherein the polyacrylamide is linear polyacrylamide with a molecular weight of 500-1000 ten thousand. The organosilicon wetting agent is at least one selected from Silwet 408 and Silwet L-77; the viscosity regulator is at least one of hydroxymethyl cellulose and xanthan gum; the antifreezing agent is at least one of ethylene glycol and propylene glycol, and the settling agent is urea.

The second purpose of the invention is to provide a preparation method of the high-efficiency flight control assistant, which comprises the following steps: adding polyoxyethylene ether phosphate and gemini sulfonate surfactant into water, continuously adding the anti-drift agent, the organic silicon wetting agent and the anti-freezing agent under the stirring condition, finally adding a proper amount of viscosity regulator according to the viscosity required by the flight control assistant, and uniformly stirring to obtain the product.

The third purpose of the invention is to provide the application of the high-efficiency flight control assistant, which is characterized in that the flight control assistant is diluted by 500 times and used by 1000 times.

The invention also provides a composition for flying prevention, which comprises a pesticide active ingredient and the high-efficiency flying prevention auxiliary agent. The pesticide active ingredients comprise herbicides, insecticides and bactericides.

Preferably, the herbicide is selected from the group consisting of fluoroglycofen-ethyl, quizalofop-ethyl, thifensulfuron-methyl, cyhalofop-butyl, clethodim, atrazine, imazapic, glufosinate, propyza sativaAt least one of an ester, glyphosate, penoxsulam, mesosulfuron, bentazone, bispyribac-sodium, sulcotrione, nicosulfuron, glyphosate, penoxsulam, diquat, mesotrione, quizalofop-P-ethyl, dicamba, acetochlor, bispyribac, pendimethalin, florasulam, terbuthylazine, clodinafop-methyl, mesosulfuron, fenoxaprop-p-ethyl, tribenuron-methyl, 2, 4-D dimethylamine salt, acifluorfen-ethyl, rimsulfuron, quizalofop-p-ethyl, butralin, diquat, benazolin, quinclorac, clopyralid, fomesafen and imazapyr; the pesticide is selected from imidacloprid, dinotefuran, indoxacarb, acetamiprid, thiamethoxam, etoxazole, bifenazate, matrine, abamectin, bifenthrin, buprofezin, chlorfenapyr, chlorfluazuron, chlorpyrifos, clofentezine, clothianidin, cyfluthrin, lambda-cyhalothrin, cypermethrin, fenvalerate, fenpropathrin, deltamethrin, pymetrozine _、 At least one of cyromazine, diafenthiuron, diflubenzuron, emamectin benzoate, ethiprole, chlorpyrifos, ethofenprox, hexaflumuron, indoxacarb, hexythiazox, nitenpyram, propargite, pyriproxyfen, rotenone, bacillus thuringiensis, spinetoram, spirodiclofen, spirotetramat, pyridaben, propargite and azocyclotin; the bactericide is selected from at least one of fluopyram, pyraclostrobin, azoxystrobin, trifloxystrobin, kresoxim-methyl, prochloraz, difenoconazole, chlorothalonil, propamocarb, fluopicolide, oxine-copper, metalaxyl, dimethomorph, famoxadone, cymoxanil, propiconazole, tebuconazole, iprodione, dimethomorph, triadimefon, captan, thifluzamide, boscalid, epoxiconazole, zhongshengmycin, kasugamycin, benziothiazolinone, epoxiconazole, flusilazole, myclobutanil, carbendazim, mancozeb, thiophanate-methyl, hexaconazole and fluazinam.

Compared with the prior art, the invention has the following beneficial effects:

firstly, the flying preventive auxiliary of the invention is highly stable, can keep long-term stability in a wide range of pH6.5-8.4, and can keep high stability in hard water and heating conditions.

The flying prevention auxiliary agent provided by the invention is simple in component, good in applicability to various pesticide active ingredients, and capable of being widely applied to various pesticides, such as herbicides, insecticides and bactericides.

And thirdly, the flying prevention auxiliary agent provided by the invention has excellent comprehensive performance, excellent drift prevention performance and excellent evaporation resistance. Can adopt unmanned aerial vehicle etc. to spray crops high-efficiently, effective performance flies to prevent the utility.

Drawings

FIG. 1 is a photograph of a stability test of the flying guard auxiliary of examples 1 to 5 diluted 100 times under conventional conditions (25. + -. 2 ℃ C., 60. + -. 5% RH) for 10 days;

fig. 2 is a photograph of stability tests of the flying guard aids of examples 1-5 diluted 100 times at pH6.5 for 3 d;

fig. 3 is a photograph of stability tests of the flying guard aids of examples 1-5 diluted 100 times at pH 8.4 for 3 d;

FIG. 4 is a photograph of a stability test of the flying guard auxiliary of examples 1 to 5 diluted 100 times in hard water (calcium carbonate/magnesium content of 342mg/L) for 3 d;

FIG. 5 is a photograph of a stability test of the flying preventive aids of examples 1 to 5 diluted 100 times and left under heating (60 ℃ C.) for 24 hours;

FIG. 6 is a photograph of a wettability test on scindapsus aureus leaf after 1000-fold dilution of the flying preventive adjuvant of example 1;

fig. 7 is a photograph of a field test of the flying-preventive adjuvant of the present invention.

Detailed Description

The present application is further illustrated by the following examples.

In the examples of the present invention, the terms "part(s)" and "part(s)" are parts by weight and the terms "%" are mass percentages, unless otherwise specified. The reagents used in the present invention are commercially available.

The linear polyacrylamide has a heavy molecular weight of about 5.6 ten thousand.

Preparation example 1

(T1) dissolving p-4-hydroxycinnamic acid in toluene, adding a toluene solution of dodecanol, adding p-toluenesulfonic acid with the mass of 5% of that of the 4-hydroxycinnamic acid, carrying out esterification reaction for 8 hours under the condition of water-dividing reflux, ensuring that the acid value is not reduced any more, completing the reaction, carrying out vacuum rotary solvent removal, and recrystallizing with absolute ethyl alcohol to obtain an esterified intermediate product;

(T2) introducing nitrogen into the container to remove air, dissolving the esterified intermediate product obtained in the step (T1) and polyethylene glycol diglycidyl ether with the number average molecular weight of 800 in DMF, adding potassium hydroxide accounting for 8.5 percent of the mass of the polyethylene glycol diglycidyl ether, and reacting for 12 hours at 130 ℃;

(T3) adding sodium hydrogen sulfite and cetyltrimethylammonium bromide in an amount of 1% by mass of the sodium hydrogen sulfite to the resultant mixture after the reaction, and reacting at 80 ℃ for 6 hours; after the reaction is finished, the obtained mixture is cooled, 20 wt% of DMF solution of chlorosulfonic acid is slowly dripped in an ice salt bath, the dripping is finished within 2h, the reaction temperature is maintained within the range of 0-5 ℃, the reaction is carried out for 12h, and then the pH of the system is neutralized to 8 by ethanol solution of sodium hydroxide. Vacuum drying at 133Pa, 60 deg.C, washing the obtained product with acetone three times to obtain brown powder product as Gemini sulfonate surfactant.

Wherein the mol ratio of the 4-hydroxycinnamic acid to the long-chain alkyl alcohol to the polyethylene glycol diglycidyl ether to the sodium bisulfite to the chlorosulfonic acid is 1: 1.3: 0.5: 2.5: 1.1

Preparation example 2

Other conditions and methods were the same as in the preparation examples except that the number average molecular weight of polyethylene glycol diglycidyl ether was 500.

Preparation example 3

Other conditions and methods were the same as in the preparation examples except that the number average molecular weight of polyethylene glycol diglycidyl ether was 1200.

Preparation example 4

Other conditions and methods were the same as in the preparation examples except that the number average molecular weight of polyethylene glycol diglycidyl ether was 1500.

Example 1

Adding 6 parts of polyoxyethylene ether phosphate and 5 parts of gemini sulfonate surfactant prepared in preparation example 1 into 100 parts of tap water, and continuously adding 7 parts of linear polyacrylamide, 3 parts of guar gum, 6 parts of Silwet 408, 3 parts of ethylene glycol, 3 parts of urea and 4 parts of hydroxymethyl cellulose under the stirring condition. Fully stirring and uniformly dispersing to obtain stable emulsion.

Example 2

Other conditions and methods were the same as those in preparation example except that gemini sulfonate surfactant was prepared for preparation example 2.

Example 3

Other conditions and methods were the same as those in preparation example except that gemini sulfonate surfactant was prepared as in preparation example 3.

Example 4

Other conditions and methods were the same as those in preparation example except that gemini sulfonate surfactant was prepared for preparation example 4.

Example 5

Adding 6 parts of polyoxyethylene ether phosphate and 5 parts of the gemini sulfonate surfactant prepared in preparation example 1 into 100 parts of water, and continuously adding 8 parts of linear polyacrylamide, 4 parts of guar gum, 7 parts of Silwet L-77, 3 parts of ethylene glycol, 3 parts of urea and 4 parts of hydroxymethyl cellulose under the stirring condition. Fully stirring and uniformly dispersing to obtain stable emulsion.

Application example 1Stability test

The emulsion was diluted 100 times and placed in a measuring cylinder with a plug and the stability of the emulsion was evaluated in terms of the time for which oil slick, separation, foaming, suspended matter, or clouding occurred, in accordance with GB/T1603-2001. The evaluation criteria are as follows:

in addition, conditions were also varied and tested at different pH (pH adjusted with acetic acid or sodium carbonate), and stability in hard water and after heating. Wherein, the hard water is prepared by standard hard water with calcium carbonate/magnesium content of 342mg/L (in the embodiment, the standard hard water is used for replacing tap water) when preparing the flight control auxiliary agent; the heating stability is the time for which the flying preventive auxiliary agent can be observed to be stable in a water bath condition at 60 ℃. The results are shown in table 1 below:

TABLE 1 stability testing

	General conditions	pH＝6.5	pH＝8.4	Hard water	Heating of
						Example 1	A	A	A	B	A
Example 2	A	A	B	C	C
						Example 3	A	B	B	B	A
Example 4	A	A	A	B	B
						Example 5	A	A	A	B	A

Fig. 1 to 5 are photographs of examples 1 to 5 respectively, which were kept under conventional conditions (25 ± 2 ℃, 60 ± 5% RH), pH6.5, pH 8.4, hard water (calcium carbonate/magnesium content of 342mg/L), and heat (60 ℃) for the same time. Wherein the standing time under the conventional condition is 10d, the pH value is 6.5, the pH value is 8.4, and the standing time under the hard water condition is 3 d; the heating condition standing time is 24 h.

As can be seen from the results of Table 1 and FIGS. 1-5, the flight control aid emulsions prepared according to the present invention are stable, and maintain a satisfactory degree of stability under a wide range of pH conditions, as well as hard water, and heating conditions. Wherein, the preparation example 2 adopts polyethylene glycol diglycidyl ether with shorter chain segment, which causes the hydrophilicity of the intermediate chain of the Gemini surfactant to be insufficient and the stability of the auxiliary agent to be slightly insufficient.

Application example 2Indoor drift prevention performance test

The flying-prevention aid obtained in the example is placed indoors, natural wind is simulated through an electric fan, a backpack electric sprayer sprays 1000 times diluted flying-prevention aid, and fogdrops are collected through water-sensitive paper. The anti-drift performance is evaluated through the volume particle size of the fog drops, the coverage rate of the fog drops and the deposition amount of the fog drops in unit area.

And (3) testing conditions are as follows: adjusting the power of the electric fan to enable the wind speed to be 4m/s, placing the water-sensitive paper on the ground with the front side of the fan being 0.5m, starting spraying at the position 1.5m above the water-sensitive paper, enabling the spray head and the fan to be equal in height, enabling the wind direction of the fan to be horizontal to the ground, enabling the spraying direction to vertically face the ground, collecting the water-sensitive paper after spraying, naturally airing, and analyzing fog drop parameters of photos through Depositscan software. The results are shown in table 2 below:

TABLE 2 droplet index

Application example 3Test for Evaporation resistance

100. mu.L of the flying preventive adjuvant of the example diluted 1000 times was taken with a precision pipette, placed on a Teflon watch dish, and the time (25 ℃, 65 RH%) taken for the 1000-fold diluted flying preventive adjuvant to evaporate 0.002g was recorded on a high-precision electronic balance with a stopwatch. The results are shown in table 3 below:

TABLE 3 Evaporation resistance test

	Evaporation of 0.002g of time(s)
		Example 1	542
Example 2	466
		Example 3	535
Example 4	564
		Example 5	548

Application example 4Wetting Properties

1mL of the flying prevention aid diluted 1000 times and obtained in the examples 1 to 5 is dripped on the scindapsus aureus leaves by a dropper, and the increase rate of the wetting area of the scindapsus aureus leaves by the flying prevention aid is tested relative to clear water by taking the clear water as a control. Each set of experiments was performed on 7 closely-area scindapsus aureus leaves, and the area increase rates were averaged. FIG. 6 is a photograph of a wettability test of the weather resistant additive diluted 1000 times in example 1 on scindapsus aureus leaves. The results are shown in Table 4 below.

Table 4 wetting test

	Increase rate of wetted area
		Example 1	136.4％
Example 2	123.5％
		Example 3	132.6％
Example 4	128.2％
		Example 5	131.2％

Application example 5Field test

The use case of wheat spraying three proofings:

the medicament combination A is as follows: 430g/l tebuconazole 20 ml/mu + 2.5% lambda-cyhalothrin 30 ml/mu + 98% monopotassium phosphate 50 g/mu.

The commercially available flight control auxiliary agent comprises: a special flying defense auxiliary agent produced by a certain company.

The test agents are shown in table 5 below:

TABLE 5

The flight parameters of the drone are shown in table 6 below:

TABLE 6

After the control test treatment was performed on three fields, the statistical results of the control effect are shown in table 7:

TABLE 7

Three field test results all show that the treatment with the addition of the auxiliary agent has better results in pest control and disease control than the treatment without the addition of the auxiliary agent, and the effect of the addition of the high-efficiency flying prevention auxiliary agent in the embodiment 1 is obviously higher than that of the commercial auxiliary agent.

Claims

1. The efficient flight control auxiliary agent is characterized by comprising the following raw materials in parts by weight: 100 parts of water, 8-14 parts of an anti-drift agent, 6-9 parts of polyoxyethylene ether phosphate, 3-5 parts of gemini sulfonate surfactant, 4-7 parts of an organic silicon wetting agent, 1-3 parts of a viscosity regulator, 1-5 parts of an antifreezing agent and 3-5 parts of a settling agent.

2. The efficient flight control aid as claimed in claim 1, wherein the preparation method of the gemini sulfonate surfactant comprises the following steps:

(T1) dissolving 4-hydroxycinnamic acid in an organic solvent, adding a long-chain alkyl alcohol solution, carrying out esterification reaction under the conditions of a catalyst and water diversion reflux, drying, and recrystallizing to obtain an esterification intermediate product;

3. The high-efficiency aircraft protection additive according to claim 2, wherein in the step (T1), the organic solvent is selected from at least one of toluene, benzene and dichloromethane, and the solvent for the long-chain alkyl alcohol solution is selected from at least one of toluene, benzene and dichloromethane; the catalyst is selected from at least one of p-toluenesulfonic acid and heteropoly acid, and the using amount of the catalyst is 3-5% of the mass of the 4-hydroxycinnamic acid; the long-chain alkyl alcohol is a linear alkyl alcohol with 12 to 18 carbon atoms; preferably at least one of dodecanol, tridecanol, tetradecanol, hexadecanol and octadecanol; the number average molecular weight of the polyethylene glycol diglycidyl ether is 600-1500, preferably 800-1200; the alkaline catalyst is at least one of potassium hydroxide and sodium hydroxide, and the dosage of the catalyst is 5-10% of the mass of the polyethylene glycol diglycidyl ether.

4. The high-efficiency flight control aid according to claim 2, wherein in the step (T3), the sulfonation reagent is a compound of sodium bisulfite and chlorosulfonic acid in a molar ratio of 2-3: 2-3; preferably, the sulfonation of step (T3) is divided into two steps, comprising the steps of:

(T3-b) the mixture of step (T3-a) is cooled, chlorosulfonic acid solution is slowly added dropwise under ice salt bath condition, reaction is carried out for 10-15h under 0-5 ℃, and pH is neutralized to 7-9 with alkali.

5. The high-efficiency flight control aid according to claim 4, wherein the phase transfer catalyst is cetyl trimethyl ammonium bromide, and the addition amount of the phase transfer catalyst is 1-2% of the mass of the sodium bisulfite.

6. The high-efficiency flight control aid according to claim 2, wherein the molar ratio of 4-hydroxycinnamic acid, long-chain alkyl alcohol, polyethylene glycol diglycidyl ether, sodium bisulfite and chlorosulfonic acid is 1: 1.2-1.5: 0.4-0.5: 2-4: 1-1.2.

7. The high efficiency aviation control aid of claim 1 wherein the anti-drift agent is selected from at least one of polyacrylamide, guar gum, xanthan gum, lecithin and derivatives thereof; preferably, the weight ratio of polyacrylamide to guar gum is 4-7: 2-3, wherein the polyacrylamide is linear polyacrylamide with the molecular weight of 500-1000 ten thousand; the organosilicon wetting agent is at least one selected from Silwet 408 and Silwet L-77; the viscosity regulator is at least one of hydroxymethyl cellulose and xanthan gum; the antifreezing agent is at least one of ethylene glycol and propylene glycol, and the settling agent is urea.

8. The preparation method of the high-efficiency flying prevention aid as claimed in any one of claims 1 to 7, which is characterized by comprising the following steps: adding polyoxyethylene ether phosphate and gemini sulfonate surfactant into water, continuously adding the anti-drift agent, the organic silicon wetting agent and the anti-freezing agent under the stirring condition, finally adding a proper amount of viscosity regulator according to the viscosity required by the flight control assistant, and uniformly stirring to obtain the product.

9. The application of the high-efficiency flight control aid as claimed in any one of claims 1 to 7 in field control, wherein the flight control aid is diluted by 500-fold and used by 1000-fold.

10. A composition for flying prevention comprising an agriculturally active ingredient and the high-efficiency flying prevention aid of any one of claims 1 to 7; the agricultural components comprise herbicides, insecticides, bactericides; preferably, the herbicide is selected from at least one of carboxyflurane, quizalofop-ethyl, thifensulfuron-methyl, cyhalofop-butyl, clethodim, atrazine, imazapyr, glufosinate, clodinafop-propargyl, glyphosate, penoxsulam, mesosulfuron-methyl, bentazon, bispyribac-sodium, sulcotrione, nicosulfuron, glyphosate, penoxsulam, diquat-methyl, quizalofop-p-ethyl, dicamba, acetochlor, bispyribac, pendimethalin, florasulam, terbuthylazine, clodinate, mesosulfuron-methyl, fenoxaprop-p-ethyl, tribenuron-methyl, 2, 4-d-dimethyamine salt, tricarboxyfen-ethyl, sulam, quizalofop-ethyl, butralin, alachlor, diclofop-methyl, quine, bromoxynil, clopyralid, fomesafen and imazapic acid; the pesticide is selected from imidacloprid, dinotefuran, indoxacarb, acetamiprid, thiamethoxam, etoxazole, bifenazate, matrine, abamectin, bifenthrin, buprofezin, chlorfenapyr, chlorfluazuron, chlorpyrifos, clofentezine, clothianidin, cyfluthrin, lambda-cyhalothrin, cypermethrin, fenvalerate, fenpropathrin, deltamethrin, pymetrozine _、 At least one of cyromazine, diafenthiuron, diflubenzuron, emamectin benzoate, ethiprole, chlorpyrifos, ethofenprox, hexaflumuron, indoxacarb, hexythiazox, nitenpyram, propargite, pyriproxyfen, rotenone, bacillus thuringiensis, spinetoram, spirodiclofen, spirotetramat, pyridaben, propargite and azocyclotin; the bactericide is selected from fluopyram, pyraclostrobin, azoxystrobin, trifloxystrobin, kresoxim-methyl, prochloraz, difenoconazole, chlorothalonil, propamocarb, fluopicolide, oxine-copper, metalaxyl, dimethomorph, famoxadone, cymoxanil, propiconazole, tebuconazole, iprodione, dimethomorph, triadimefon, captan, thifluzamide, boscalid, epoxiconazole, fenoxanil, zhongshengmycin, kasugamycin, benziothiazolinone, epoxiconazole, fluopyramAt least one of flusilazole, myclobutanil, carbendazim, mancozeb, thiophanate-methyl, hexaconazole, and fluazinam.