CN115011783A - Water-bath heat treatment method for special steel wire for high-strength reinforced steel shot - Google Patents

Water-bath heat treatment method for special steel wire for high-strength reinforced steel shot Download PDF

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Publication number
CN115011783A
CN115011783A CN202111624570.4A CN202111624570A CN115011783A CN 115011783 A CN115011783 A CN 115011783A CN 202111624570 A CN202111624570 A CN 202111624570A CN 115011783 A CN115011783 A CN 115011783A
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China
Prior art keywords
steel wire
heat treatment
treatment
solution
water
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Pending
Application number
CN202111624570.4A
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Chinese (zh)
Inventor
王梦茜
王瑞
王奇
冯艳华
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Jiangsu Tonglue Metal Products Co ltd
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Jiangsu Tonglue Metal Products Co ltd
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Priority to CN202111624570.4A priority Critical patent/CN115011783A/en
Publication of CN115011783A publication Critical patent/CN115011783A/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/52Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
    • C21D9/525Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length for wire, for rods
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/56General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
    • C21D1/60Aqueous agents
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F17/00Multi-step processes for surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by subclass C21D or C22F or class C25
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)

Abstract

The invention relates to the technical field of preparation of reinforced steel balls, and provides a water-bath heat treatment method for a steel wire special for a high-strength reinforced steel ball, which comprises the following steps: step 1: fixing two ends of a steel wire to be processed, and then expanding the two ends of the fixed steel wire to keep the steel wire in a tensioning state; step 2: fixing the steel wire in a tensioned state in a cleaning tank, and then spraying cleaning solution to the steel wire fixed in the cleaning tank, wherein the steel wire is subjected to dirt treatment by the cleaning solution; and step 3: transferring the steel wire in the tensioning state to a heat treatment furnace, and then heating the steel wire in the tensioning state to 800-900 ℃, wherein the heating time is 3-4 min; and 4, step 4: and after the steel wire in the heating state is fully austenitized, immersing the steel wire in a quenching agent solution of a water bath for 3-5 seconds, wherein the temperature of the quenching agent solution is 80-100 ℃.

Description

Water bath heat treatment method for special steel wire for high-strength reinforced steel ball
Technical Field
The invention relates to the technical field of shoe production, in particular to a water bath heat treatment method for a special high-strength reinforced steel ball steel wire.
Background
Steel wire is an indispensable raw material for manufacturing steel shots, and steel shots are widely applied in various industries. Heat treatment is an important step in the production of steel wire. Because the steel wire is generally used for applying tensile force, the steel wire is required to have stronger tensile strength and higher mechanical property, and the purpose is achieved by carrying out heat treatment on the steel wire; meanwhile, certain internal stress or structural stress can be generated among tissues in the steel wire manufacturing process, the steel wire is used in a reaction mode, and the internal stress can be eliminated through heat treatment.
The steel wire is subjected to intermediate heat treatment in a mode of more heat treatment, but the intermediate heat treatment process is unreasonable in link arrangement, so that the problems of low production efficiency, high production cost and low steel wire cost and quality exist. Particularly, in the process of heat treatment, the surface phosphating process is improper in selection, such as unreasonable arrangement of total acidity, free acidity, acid ratio, phosphating temperature, phosphating time and the like, so that the surface corrosion resistance and lubricity of the steel wire are not high, and the requirements of steel wire rope heat treatment wire drawing production cannot be well met.
Therefore, a method for performing water bath heat treatment on the steel wire special for the high-strength reinforced steel shot is needed.
Disclosure of Invention
Aiming at the defects in the prior art, the invention aims to provide a method for carrying out water bath heat treatment on a steel wire special for a high-strength reinforced steel shot so as to solve the problems in the background technology.
In order to achieve the purpose, the invention is realized by the following technical scheme: a water bath heat treatment method for a steel wire special for a high-strength reinforced steel shot comprises the following steps:
step 1: fixing two ends of a steel wire to be processed, and then spreading the two ends of the fixed steel wire to keep the steel wire in a tensioning state;
step 2: fixing the steel wire in a tensioned state in a cleaning tank, and then spraying cleaning solution to the steel wire fixed in the cleaning tank, wherein the cleaning solution finishes the dirt treatment on the steel wire;
and step 3: transferring the steel wire in the tensioning state to a heat treatment furnace, and then heating the steel wire in the tensioning state to 800-900 ℃, wherein the heating time is 3-4 min;
and 4, step 4: after the steel wire in the heating state is fully austenitized, immersing the steel wire in a quenching agent solution of a water bath for 3-5 seconds, wherein the temperature of the quenching agent solution is 80-100 ℃;
e) acid washing and rinsing treatment: selecting acetic acid for pickling for 2-3min, and washing with water for 5-6 min;
f) zinc series phosphating treatment: the zinc phosphating solution has total acidity of 80-115 points, free acidity of 12-20 points, acid ratio of 5-8, temperature of 80-90 deg.C, and phosphating time of 40-50s
g) Washing and saponification treatment: washing with water for 5-6min at 70-80 deg.C; h) And (3) drying treatment: drying is carried out by adopting a drying box, the drying temperature is 220-235 ℃, and the drying time is 0.8-1.2 min.
Further, the quenching agent solution in the step 4 is a sodium polyacrylate solution with the concentration of 3-8%.
The invention has the beneficial effects that:
according to the method for the water bath heat treatment of the steel wire special for the high-strength reinforced steel shot, the quenching agent water bath quenching replaces the original lead bath quenching, so that the harm to the body of workers and the pollution to the environment are greatly reduced, and the energy consumption is reduced; meanwhile, the heating is carried out in a sectional heating mode, and the influence of environmental change on the organization structure can be reduced by reasonably controlling the furnace temperature of each section, so that the quality and the stability of the product are guaranteed; meanwhile, the tensile strength of the steel wire is effectively improved, and the fatigue life of the steel wire rope is prolonged; and the heat treatment processing method is simple and convenient to implement and low in production cost, so that the production cost is saved.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further described with the specific embodiments.
In this application, unless expressly stated or limited otherwise, the terms "connected" and "fixed" are to be construed broadly, e.g., as meaning either a fixed connection or a removable connection, or an integral part; can be mechanically or electrically connected; either directly or indirectly through intervening media, either internally or in any other relationship. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
The invention provides a water bath heat treatment method of a steel wire special for high-strength reinforced steel balls, which comprises the following steps:
step 1: fixing two ends of a steel wire to be processed, and then spreading the two ends of the fixed steel wire to keep the steel wire in a tensioning state;
step 2: fixing the steel wire in a tensioned state in a cleaning tank, and then spraying cleaning solution to the steel wire fixed in the cleaning tank, wherein the steel wire is subjected to dirt treatment by the cleaning solution;
and step 3: transferring the steel wire in the tensioning state to a heat treatment furnace, and then heating the steel wire in the tensioning state to 800-900 ℃, wherein the heating time is 3-4 min;
and 4, step 4: after the steel wire in the heating state is fully austenitized, immersing the steel wire in a quenching agent solution of a water bath for 3-5 seconds, wherein the temperature of the quenching agent solution is 80-100 ℃; i) Acid washing and washing treatment: selecting acetic acid for pickling for 2-3min, and washing with water for 5-6 min;
j) zinc series phosphating treatment: the zinc phosphating solution has total acidity of 80-115 points, free acidity of 12-20 points, acid ratio of 5-8, temperature of 80-90 deg.C, and phosphating time of 40-50s
k) Washing and saponification treatment: washing with water for 5-6min at 70-80 deg.C; l) drying treatment: drying is carried out by adopting a drying box, the drying temperature is 220-.
The cooling liquid is prepared from the following components in percentage by weight: 97% of water and 3% of copper sulfate form electrolyte, and then 5% of polymer additive acrylic acid, 1% of sodium nitrite, 2% of sodium chloride and 0.1% of OP-07 emulsifier by weight of the electrolyte are added into the electrolyte and evenly stirred to obtain the electrolyte.
Further, the quenching agent solution in the step 4 is a sodium polyacrylate solution with the concentration of 3-8%.
Tests prove that the strength of the steel wire quenched by the method is not obviously different from that of the traditional lead bath, the toughness is slightly improved compared with lead-dissolved quenching, the torsion value of the steel wire is improved by 1-3 times, the phenomenon that the steel wire is coated with lead is fundamentally solved, no requirement is imposed on a lubricant carried on the surface of the rough-drawn steel wire in production, and the difficulty in producing the rough-drawn steel wire is effectively reduced.
While there have been shown and described what are at present considered the fundamental principles and essential features of the invention and its advantages, it will be apparent to those skilled in the art that the invention is not limited to the details of the foregoing exemplary embodiments, but is capable of other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (2)

1. A water bath heat treatment method for a steel wire special for a high-strength reinforced steel shot comprises the following steps:
step 1: fixing two ends of a steel wire to be processed, and then spreading the two ends of the fixed steel wire to keep the steel wire in a tensioning state;
and 2, step: fixing the steel wire in a tensioned state in a cleaning tank, and then spraying cleaning solution to the steel wire fixed in the cleaning tank, wherein the steel wire is subjected to dirt treatment by the cleaning solution;
and step 3: transferring the steel wire in the tensioning state to a heat treatment furnace, and then heating the steel wire in the tensioning state to 800-900 ℃, wherein the heating time is 3-4 min;
and 4, step 4: after the steel wire in the heating state is fully austenitized, immersing the steel wire in a quenching agent solution of a water bath for 3-5 seconds, wherein the temperature of the quenching agent solution is 80-100 ℃;
a) acid washing and rinsing treatment: selecting acetic acid for pickling for 2-3min, and washing with water for 5-6min
b) Zinc series phosphating treatment: the total acidity of zinc phosphating solution is 80-115 points, the free acidity is 12-20 points, the acid ratio is 5-8, the temperature is 80-90 ℃, and the phosphating time is 40-50s
c) Washing and saponification treatment: washing with water for 5-6min at 70-80 deg.C;
d) and (3) drying treatment: drying is carried out by adopting a drying box, the drying temperature is 220-.
2. The method for the water bath heat treatment of the steel wire special for the high-strength reinforced steel shot according to claim 1, characterized in that: in the step 4, the quenching agent solution is a sodium polyacrylate solution with the concentration of 3-8%.
CN202111624570.4A 2021-12-28 2021-12-28 Water-bath heat treatment method for special steel wire for high-strength reinforced steel shot Pending CN115011783A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111624570.4A CN115011783A (en) 2021-12-28 2021-12-28 Water-bath heat treatment method for special steel wire for high-strength reinforced steel shot

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Application Number Priority Date Filing Date Title
CN202111624570.4A CN115011783A (en) 2021-12-28 2021-12-28 Water-bath heat treatment method for special steel wire for high-strength reinforced steel shot

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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102676791A (en) * 2012-05-16 2012-09-19 冯伟年 Steel wire induction heating treatment device and method, tire steel cord and silicon chip cutting wire
CN102912109A (en) * 2012-11-21 2013-02-06 江苏赛福天钢索股份有限公司 Thermal treatment technique of steel wire
WO2018040536A1 (en) * 2016-08-30 2018-03-08 龙南县格林庭园用品有限公司 Method for preparing composite hot-galvanized steel wire
CN108034802A (en) * 2018-01-11 2018-05-15 江苏神猴钢绳开发有限公司 The heat treatment method and its production equipment of a kind of steel wire
KR101913076B1 (en) * 2018-05-30 2018-10-29 조하식 Method of high strength galvanized wire rod having excellent anti-corrosion for vehicle
CN108866315A (en) * 2018-06-29 2018-11-23 柳州市横阳机械有限公司 A kind of water-bath quenching heat treatment method of steel wire
CN109576468A (en) * 2018-12-25 2019-04-05 重庆强劲金属制品有限责任公司 A kind of production quenching technical of steel wire

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102676791A (en) * 2012-05-16 2012-09-19 冯伟年 Steel wire induction heating treatment device and method, tire steel cord and silicon chip cutting wire
CN102912109A (en) * 2012-11-21 2013-02-06 江苏赛福天钢索股份有限公司 Thermal treatment technique of steel wire
WO2018040536A1 (en) * 2016-08-30 2018-03-08 龙南县格林庭园用品有限公司 Method for preparing composite hot-galvanized steel wire
CN108034802A (en) * 2018-01-11 2018-05-15 江苏神猴钢绳开发有限公司 The heat treatment method and its production equipment of a kind of steel wire
KR101913076B1 (en) * 2018-05-30 2018-10-29 조하식 Method of high strength galvanized wire rod having excellent anti-corrosion for vehicle
CN108866315A (en) * 2018-06-29 2018-11-23 柳州市横阳机械有限公司 A kind of water-bath quenching heat treatment method of steel wire
CN109576468A (en) * 2018-12-25 2019-04-05 重庆强劲金属制品有限责任公司 A kind of production quenching technical of steel wire

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