CN115011032A - Preparation method of polypropylene composite material with low glossiness and high toughness - Google Patents
Preparation method of polypropylene composite material with low glossiness and high toughness Download PDFInfo
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- CN115011032A CN115011032A CN202210548271.5A CN202210548271A CN115011032A CN 115011032 A CN115011032 A CN 115011032A CN 202210548271 A CN202210548271 A CN 202210548271A CN 115011032 A CN115011032 A CN 115011032A
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- -1 polypropylene Polymers 0.000 title claims abstract description 68
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 58
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 58
- 239000002131 composite material Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 229920001971 elastomer Polymers 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 24
- 239000004593 Epoxy Substances 0.000 claims abstract description 19
- 239000005060 rubber Substances 0.000 claims abstract description 17
- 125000000524 functional group Chemical group 0.000 claims abstract description 16
- 239000000178 monomer Substances 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 13
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 13
- 239000000806 elastomer Substances 0.000 claims abstract description 12
- 239000002245 particle Substances 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 239000011159 matrix material Substances 0.000 claims abstract description 10
- 229920002943 EPDM rubber Polymers 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 229920000459 Nitrile rubber Polymers 0.000 claims abstract description 3
- 229920001577 copolymer Polymers 0.000 claims abstract description 3
- 230000003287 optical effect Effects 0.000 claims abstract description 3
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 16
- 238000012545 processing Methods 0.000 claims description 7
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 5
- 239000006224 matting agent Substances 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 239000005977 Ethylene Substances 0.000 claims description 2
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 2
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000004945 silicone rubber Substances 0.000 abstract 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 230000008569 process Effects 0.000 description 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 4
- 239000011256 inorganic filler Substances 0.000 description 4
- 229910003475 inorganic filler Inorganic materials 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- NMHTWXYFOWTMJH-UHFFFAOYSA-N oxiran-2-ylmethyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.CC(=C)C(=O)OCC1CO1 NMHTWXYFOWTMJH-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical group CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
Abstract
The invention provides a preparation method of a low-gloss and high-toughness polypropylene composite material, which is prepared by uniformly stirring 40-90 parts by mass of polypropylene resin, 5-30 parts by mass of inorganic rigid particles, 5-30 parts by mass of a flatting agent and 0.2-0.4 part by mass of an antioxidant in a stirrer, and extruding and granulating the mixture by a double-screw extruder, wherein the flatting agent is polymer graft rubber with an epoxy functional group, the graft phase of the polymer graft rubber is a polymer with an epoxy functional group monomer molecule, a copolymer with one of the epoxy functional group monomer molecules and a monomer molecule without an epoxy optical group, and the rubber matrix of the polymer graft rubber is one of ethylene propylene diene monomer, ethylene-octylene elastomer, ethylene-butylene elastomer, styrene-butadiene rubber, nitrile rubber and silicone rubber. The low-gloss polypropylene composite material is prepared by adding the flatting agent, and the modified polypropylene not only has lower gloss, but also has higher impact toughness and excellent comprehensive mechanical property.
Description
Technical Field
The invention relates to a preparation method of modified polypropylene, in particular to a preparation method of a polypropylene composite material with low glossiness and high toughness.
Background
Polypropylene (PP) has low density, excellent mechanical properties, good stress cracking resistance, fatigue yield resistance, chemical resistance, low cost, easy processing and forming, easy recovery, and recycling, and has been widely used, especially in the automotive industry, home appliances, and machinery fields. However, polypropylene materials have poor low temperature resistance and low rigidity, and cannot meet the use requirements of automobile interior and exterior parts, so that the polypropylene materials need to be modified. The main modification method of polypropylene is elastomer toughening polypropylene modification; modifying the inorganic filler filled reinforced polypropylene; and the research on the modification of the toughening and strengthening polypropylene by utilizing the combined action of the polypropylene, the inorganic filler and the elastomer.
With the development of the automobile industry, people put higher demands on automobiles: light weight, energy conservation, beauty, safety, environmental protection and the like, and the requirement on the comfort in the cab is higher and higher. If the gloss of the trim in the cockpit is high, there will be a strong reflection of light, thus affecting the comfort of the driver. Therefore, the automotive upholstery is required to have low glossiness. The method of removing gloss by surface embossing has been put into practice but requires a separate step, increasing costs, and the subsequent abrasion also removes the embossed matte surface, thereby allowing gloss reproduction.
In addition, low gloss can be obtained by spraying a matte paint on the surface of the product, but the production cost is high, the use requirement cannot be met sometimes, and the product may need to be reprocessed along with the prolonging of the production time.
Researches show that the glossiness of the polypropylene composite material can be reduced by adding a finely-divided filler such as silica, silicate, aluminate or other inorganic fillers, however, the glossiness is not obviously reduced due to less adding amount of the inorganic fillers, and the use requirement cannot be met; too much addition will result in a decrease in the physical properties of the article, especially a more pronounced decrease in impact strength, with a corresponding heat change.
Disclosure of Invention
1. The technical problem to be solved is as follows:
the polypropylene material has poor low-temperature resistance and low rigidity, cannot meet the use requirements of automotive interior and exterior trim parts, can obtain low glossiness by spraying the matte paint on the surface of a product, but has high production cost, sometimes cannot meet the use requirements, and may need to be reprocessed along with the extension of production time.
2. The technical scheme is as follows:
in order to solve the problems, the invention provides a preparation method of a low-gloss and high-toughness polypropylene composite material, which comprises the steps of uniformly stirring 40-90 parts by mass of polypropylene resin, 5-30 parts by mass of inorganic rigid particles, 5-30 parts by mass of a delustering agent and 0.2-0.4 part by mass of an antioxidant in a stirrer, and then extruding and granulating at the processing temperature of 180-230 ℃ through a double-screw extruder to prepare the low-gloss and high-toughness polypropylene composite material, wherein the delustering agent is polymer grafted rubber with epoxy functional groups.
50-80 parts by mass of polypropylene resin; 10-25 parts by mass of inorganic rigid particles; the matting agent is 10 to 25 parts by mass.
The grafted rubber with the epoxy functional group polymer has a grafted phase which is a copolymer of a polymer with epoxy functional group monomer molecules, one of the epoxy functional group monomer molecules and a monomer molecule without an epoxy optical group, and a rubber matrix which is one of ethylene propylene diene monomer, ethylene-octylene elastomer, ethylene-butylene elastomer, styrene butadiene rubber, butadiene acrylonitrile rubber and silicon rubber.
The monomer with the epoxy functional group is any one of glycidyl acrylate, glycidyl methacrylate and alkyl glycidyl ether; the monomer without epoxy functional group is any one of ethylene and propylene.
The particle size of the rubber matrix is 0.05 microns to 30 microns.
The particle size of the rubber matrix is 0.05 to 10 microns.
3. Has the advantages that:
the low-gloss polypropylene composite material is prepared by adding the flatting agent, and the modified polypropylene not only has lower gloss, but also has higher impact toughness and excellent comprehensive mechanical property.
Detailed Description
The present invention will be described in detail with reference to examples.
A preparation method of a low-gloss and high-toughness polypropylene composite material comprises the steps of uniformly stirring 40-90 parts by mass of polypropylene resin, 5-30 parts by mass of inorganic rigid particles, 5-30 parts by mass of a delustering agent and 0.2-0.4 part by mass of an antioxidant in a stirrer, and then extruding and granulating at the processing temperature of 180-230 ℃ through a double-screw extruder, wherein the delustering agent is polymer grafted rubber with epoxy functional groups.
According to the invention, the method optimizes the advantages that the addition of the flatting agent is less, so that the reduction of the glossiness is less, the flatting requirement cannot be met, the cost is increased when the addition of the flatting agent is more, and the physical property of the polypropylene composite material is reduced.
In the following examples, the polypropylene is K8003 from yanshan petrochemical production; the inorganic rigid particles are talcum powder produced by Aihai talcum powder Limited of sea cities of Liaoning province, and the antioxidant is antioxidant 1010 produced by Nicoti Xinxiu chemical products Limited; the elastomer is POE8137 produced by the Dow chemical method; the delustering agent 1 is an acrylate-glycidyl methacrylate grafted ethylene-octene elastomer; the flatting agent 2 is glycidyl methacrylate grafted butadiene-styrene rubber; the delustering agent 3 is alkyl glycidyl ether grafted ethylene propylene diene monomer.
Flexural properties were measured according to GB/T9341-2000, impact properties GB/T1843-1996, tensile properties GB1040-92, melt flow rate GB/T3682-2000, gloss was measured at ambient temperature using a Konika-Menten multigloss 268 gloss Meter (60 ℃).
The grafting process comprises the following steps:
the delustering agent 1 is an acrylate-glycidyl methacrylate grafted ethylene-octene elastomer: fully and uniformly mixing 30 parts by mass of acrylic ester-glycidyl methacrylate, 70 parts by mass of an ethylene-octene elastomer matrix, 0.3 part by mass of initiator dicumyl peroxide, 3 parts by mass of co-grafting monomer styrene and 1 part by mass of cross-linking inhibitor triphenyl phosphite, and extruding the mixture through a double-screw extruder at the processing temperature of 160-200 ℃ to obtain a grafted product.
The matting agent 2 is glycidyl methacrylate grafted butadiene-styrene rubber: fully and uniformly mixing 30 parts by mass of glycidyl methacrylate, 70 parts by mass of a butadiene-styrene rubber matrix, 0.3 part by mass of dicumyl peroxide as an initiator, 3 parts by mass of co-grafting monomer styrene and 1 part by mass of triphenyl phosphite as a crosslinking inhibitor, and extruding the mixture through a double-screw extruder at the processing temperature of 160-200 ℃ to obtain a grafted product.
The delustering agent 3 is alkyl glycidyl ether grafted ethylene propylene diene monomer: 30 parts by mass of alkyl glycidyl ether, 70 parts by mass of an ethylene propylene diene monomer matrix, 0.3 part by mass of dicumyl peroxide as an initiator, 3 parts by mass of a co-grafting monomer styrene and 1 part by mass of triphenyl phosphite as a crosslinking inhibitor are fully and uniformly mixed, and then the mixture is extruded by a double-screw extruder at a processing temperature of 160-200 ℃ to obtain a grafted product.
Example 1
Mixing 90 parts by mass of polypropylene resin, 20 parts by mass of talcum powder, 10 parts by mass of flatting agent 1 and 0.3 part by mass of antioxidant in a high-speed mixer for 5 minutes, and then extruding and granulating on a double-screw extruder, wherein the temperature of the extruder is as follows: the polypropylene composite material with low glossiness and high toughness is extruded and molded at the temperature of 185 ℃ in a first interval, 195 ℃ in a second interval, 195 ℃ in a third interval, 200 ℃ in a fourth interval, a fifth interval, a sixth interval, a seventh interval and an eighth interval and 195 ℃ in a ninth interval.
The polypropylene composite material with low glossiness and high toughness is prepared by the process. The properties are shown in Table 1.
Example 2
Mixing 70 parts by mass of polypropylene resin, 5 parts by mass of talcum powder, 5 parts by mass of flatting agent 1 and 0.3 part by mass of antioxidant in a high-speed mixer for 5 minutes, and then extruding and granulating on a double-screw extruder, wherein the temperature of the extruder is as follows: the polypropylene composite material with low glossiness and high toughness is extruded and molded at the temperature of 185 ℃ in a first interval, 195 ℃ in a second interval, 195 ℃ in a third interval, 200 ℃ in a fourth interval, a fifth interval, a sixth interval, a seventh interval and an eighth interval and 195 ℃ in a ninth interval.
The polypropylene composite material with low glossiness and high toughness is prepared by the process. The properties are shown in Table 1.
EXAMPLE 3
Mixing 65 parts by mass of polypropylene resin, 20 parts by mass of talcum powder, 15 parts by mass of flatting agent 1 and 0.3 part by mass of antioxidant in a high-speed mixer for 5 minutes, and then extruding and granulating on a double-screw extruder, wherein the temperature of the extruder is as follows: the first interval is 185 ℃, the second interval and the third interval are 195 ℃, the fourth interval, the fifth interval, the sixth interval, the seventh interval and the eighth interval are 200 ℃ and the ninth interval is 195 ℃, and the polypropylene composite material with low glossiness and high toughness is formed by extrusion.
The polypropylene composite material with low glossiness and high toughness is prepared by the process. The properties are shown in Table 1.
Example 4
Mixing 60 parts by mass of polypropylene resin, 10 parts by mass of talcum powder, 20 parts by mass of flatting agent 1 and 0.4 part by mass of antioxidant in a high-speed mixer for 5 minutes, and then extruding and granulating on a double-screw extruder, wherein the temperature of the extruder is as follows: the polypropylene composite material with low glossiness and high toughness is extruded and molded at the temperature of 185 ℃ in a first interval, 195 ℃ in a second interval, 195 ℃ in a third interval, 200 ℃ in a fourth interval, a fifth interval, a sixth interval, a seventh interval and an eighth interval and 195 ℃ in a ninth interval.
The polypropylene composite material with low glossiness and high toughness is prepared by the process. The properties are shown in Table 1.
Example 5
Mixing 40 parts by mass of polypropylene resin, 30 parts by mass of talcum powder, 30 parts by mass of flatting agent 1 and 0.3 part by mass of antioxidant in a high-speed mixer for 5 minutes, and then extruding and granulating on a double-screw extruder, wherein the temperature of the extruder is as follows: the polypropylene composite material with low glossiness and high toughness is extruded and molded at the temperature of 185 ℃ in a first interval, 195 ℃ in a second interval, 195 ℃ in a third interval, 200 ℃ in a fourth interval, a fifth interval, a sixth interval, a seventh interval and an eighth interval and 195 ℃ in a ninth interval.
The polypropylene composite material with low glossiness and high toughness is prepared by the process. The properties are shown in Table 1.
Example 6
Mixing 80 parts by mass of polypropylene resin, 15 parts by mass of talcum powder, 10 parts by mass of flatting agent 2 and 0.3 part by mass of antioxidant in a high-speed mixer for 5 minutes, and then extruding and granulating on a double-screw extruder, wherein the temperature of the extruder is as follows: the first interval is 185 ℃, the second interval and the third interval are 195 ℃, the fourth interval, the fifth interval, the sixth interval, the seventh interval and the eighth interval are 200 ℃ and the ninth interval is 195 ℃, and the polypropylene composite material with low glossiness and high toughness is formed by extrusion.
The polypropylene composite material with low glossiness and high toughness is prepared by the process. The properties are shown in Table 1.
Example 7
Mixing 50 parts by mass of polypropylene resin, 25 parts by mass of talcum powder, 25 parts by mass of flatting agent 3 and 0.4 part by mass of antioxidant in a high-speed mixer for 5 minutes, and then extruding and granulating on a double-screw extruder, wherein the temperature of the extruder is as follows: the first interval is 185 ℃, the second interval and the third interval are 195 ℃, the fourth interval, the fifth interval, the sixth interval, the seventh interval and the eighth interval are 200 ℃ and the ninth interval is 195 ℃, and the polypropylene composite material with low glossiness and high toughness is formed by extrusion.
Comparative example:
mixing 70 parts by mass of polypropylene resin, 20 parts by mass of talcum powder, 10 parts by mass of POE and 0.3 part by mass of antioxidant in a high-speed mixer for 5 minutes, and then extruding and granulating on a double-screw extruder, wherein the temperature of the extruder is as follows: the first interval is 185 ℃, the second interval and the third interval are 195 ℃, the fourth interval, the fifth interval, the sixth interval, the seventh interval and the eighth interval are 200 ℃ and the ninth interval is 195 ℃, and the low-glossiness polypropylene composite material is formed by extrusion.
The low-gloss polypropylene composite material is prepared by the process. The properties are shown in Table 1.
Table 1: performance data.
As can be seen from the table above, the polypropylene composite material with low glossiness and high toughness prepared by the invention has soft glossiness. The low-gloss and high-toughness polypropylene composite material prepared by the invention has an outstanding extinction effect, has high impact toughness, and well maintains physical properties such as flexural modulus, tensile strength and the like, and can be widely applied to the fields of automobiles, electronic appliances and the like.
The main investigation indexes are glossiness and impact toughness, and the lower the glossiness resin is, the lower the glossiness is, the better the effect is; as can be seen from Table 1, examples 1-7 all had lower gloss than the comparative examples, and example 5 had the lowest gloss, but the decay in physical properties was more severe overall, and example 3 was the most effective in view of the combination of gloss and physical properties. It can be seen that the present invention has lower gloss than the prior art.
Claims (6)
1. A preparation method of a polypropylene composite material with low glossiness and high toughness is characterized by comprising the following steps: uniformly stirring 40-90 parts by mass of polypropylene resin, 5-30 parts by mass of inorganic rigid particles, 5-30 parts by mass of a delustering agent and 0.2-0.4 part by mass of an antioxidant in a stirrer, and then extruding and granulating at the processing temperature of 180-230 ℃ through a double-screw extruder to obtain the low-gloss and high-toughness polypropylene composite material, wherein the delustering agent is polymer grafted rubber with epoxy functional groups.
2. The method of claim 1, wherein: 50-80 parts by mass of polypropylene resin; 10 to 25 parts by mass of inorganic rigid particles; the matting agent is 10 to 25 parts by mass.
3. The method of claim 1, wherein; the grafted rubber with the epoxy functional group polymer has a grafted phase which is a copolymer of a polymer with epoxy functional group monomer molecules, one of the epoxy functional group monomer molecules and a monomer molecule without an epoxy optical group, and a rubber matrix which is one of ethylene propylene diene monomer, ethylene-octylene elastomer, ethylene-butylene elastomer, styrene butadiene rubber, butadiene acrylonitrile rubber and silicon rubber.
4. The method of claim 3, wherein: the monomer with the epoxy functional group is any one of glycidyl acrylate, glycidyl methacrylate and alkyl glycidyl ether; the monomer without epoxy functional group is any one of ethylene and propylene.
5. The method of claim 3 or 4, wherein: the particle size of the rubber matrix is 0.05 microns to 30 microns.
6. The method of claim 5, wherein: the particle size of the rubber matrix is 0.05 to 10 microns.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786768A (en) * | 2012-08-09 | 2012-11-21 | 南京金杉汽车工程塑料有限责任公司 | Low-glossiness ABS (acrylonitrile butadiene styrene) resin and preparation method of low-glossiness ABS resin |
| CN104558810A (en) * | 2014-12-30 | 2015-04-29 | 南京金杉汽车工程塑料有限责任公司 | Low-gloss polypropylene composite and preparation method thereof |
| CN108948707A (en) * | 2017-05-25 | 2018-12-07 | 合肥杰事杰新材料股份有限公司 | A kind of low-luster polycarbonate/acrylonitrile-butadiene-styrene alloy material for automobile interiors |
| CN110607060A (en) * | 2019-08-23 | 2019-12-24 | 武汉金发科技有限公司 | Thermoplastic resin composition, preparation method and application thereof |
-
2022
- 2022-05-20 CN CN202210548271.5A patent/CN115011032A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102786768A (en) * | 2012-08-09 | 2012-11-21 | 南京金杉汽车工程塑料有限责任公司 | Low-glossiness ABS (acrylonitrile butadiene styrene) resin and preparation method of low-glossiness ABS resin |
| CN104558810A (en) * | 2014-12-30 | 2015-04-29 | 南京金杉汽车工程塑料有限责任公司 | Low-gloss polypropylene composite and preparation method thereof |
| CN108948707A (en) * | 2017-05-25 | 2018-12-07 | 合肥杰事杰新材料股份有限公司 | A kind of low-luster polycarbonate/acrylonitrile-butadiene-styrene alloy material for automobile interiors |
| CN110607060A (en) * | 2019-08-23 | 2019-12-24 | 武汉金发科技有限公司 | Thermoplastic resin composition, preparation method and application thereof |
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