CN114940723A - Super-waterproof fluorinated self-cleaning anti-reflection coating material and preparation method thereof - Google Patents
Super-waterproof fluorinated self-cleaning anti-reflection coating material and preparation method thereof Download PDFInfo
- Publication number
- CN114940723A CN114940723A CN202210628580.3A CN202210628580A CN114940723A CN 114940723 A CN114940723 A CN 114940723A CN 202210628580 A CN202210628580 A CN 202210628580A CN 114940723 A CN114940723 A CN 114940723A
- Authority
- CN
- China
- Prior art keywords
- parts
- coating material
- super
- cleaning
- waterproof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a super-waterproof fluorinated self-cleaning anti-reflection coating material and a preparation method thereof, belonging to the technical field of functional materials; the coating material comprises the following raw materials in parts by weight: 30-50 parts of methyl methacrylate, 20-30 parts of butyl acrylate, 5-10 parts of a silicon monomer, 10-20 parts of a fluorine monomer, 1-5 parts of a chlorinated initiator and 50-100 parts of propylene carbonate; weighing and mixing the raw materials, and heating for reaction to obtain the coating material; the fluorinated self-cleaning anti-reflection coating material provided by the invention has good hydrophobic property and anti-reflection property, excellent water resistance and self-cleaning property, simple preparation process, low cost and no toxic substance, and is suitable for wide popularization.
Description
Technical Field
The invention belongs to the technical field of functional materials, and particularly relates to a super-waterproof fluorinated self-cleaning anti-reflection coating material and a preparation method thereof.
Background
"carbon Peak" and "carbon neutralization" not only enhance environmental CO 2 Absorption of (2) also reduces CO 2 And (4) discharging. Solar energy is used as a new energy source to gradually replace the traditional energy source, and the photovoltaic field is also splendid in the future. In outdoor environments, traditional clear coatings are particularly susceptible to contamination (water stains, dust, etc.) thereby reducing light transmission, and the costs spent annually on routine maintenance of photovoltaic solar panels greatly increase the cost of photovoltaic power generation.
The low surface energy materials prepared at present mainly rely on hydrophobic groups on the surface to reduce the surface energy thereof so as to achieve the hydrophobic effect, and when the surface is damaged, the materials lose the hydrophobic property. Therefore, abrasion resistance, water resistance, adhesion and hardness are extremely important for transparent hydrophobic films for outdoor use.
The use of more transparent hydrophobic coatings now mostly using silicones or organofluorine as hydrophobic group provides hydrophobic effect, however organofluorine monomers have been limited in their industrial application due to the problem of surface enrichment of fluorinated groups. The surface enrichment of the fluorinated groups can cause the amphiphilic structure with hydrophilic and hydrophobic phases to appear on the surface of the coating, so that the coating has excellent hydrophobic property and achieves the purpose of self-cleaning. However, in an aqueous environment, fluorinated groups enriched on the surface of the traditional organic fluorine modified acrylic resin are rearranged, so that the resin coating is changed into white, the light transmittance and the hydrophobic property of the resin coating are influenced, and the self-cleaning property of the coating is greatly reduced.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides a super-waterproof fluorinated self-cleaning anti-reflection coating material and a preparation method thereof.
In order to achieve the purpose, the invention provides the following technical scheme:
the invention provides a super-waterproof fluorinated self-cleaning anti-reflection coating material which comprises the following raw materials in parts by weight: 30-50 parts of methyl methacrylate, 20-30 parts of butyl acrylate, 5-10 parts of silicon monomer, 10-20 parts of fluorine monomer, 1-5 parts of chlorinated initiator and 50-100 parts of propylene carbonate.
Further, the silicon monomer is a silane coupling agent including gamma-methacryloxypropyltrimethoxysilane (KH570) and/or vinyltrimethoxysilane (a 171).
Further, the fluoromonomer comprises perfluorooctyl ethyl methacrylate.
Further, the preparation method of the chlorinated initiator comprises the following steps: adding 10-20 parts of micro-nano particles and 0.5-1 part of catalyst diethanolamine into 400-500 parts of solvent, cooling to 0 ℃, adding 0.5-1.5 parts of initiator intermediate 2-chloropropionyl chloride, and reacting at 0 ℃ for 24 hours to obtain the chlorinated initiator.
Further, the solvent comprises propylene carbonate or xylene, and the micro-nano particles comprise SiO 2 、TiO 2 Or Al 2 O 3 。
The invention also provides a preparation method of the super-waterproof fluorinated self-cleaning anti-reflection coating material, which comprises the following steps: weighing and mixing the raw materials to obtain a mixed solution, and heating for reaction to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Further, the reaction temperature is 90-120 ℃, and the reaction time is 12 hours.
In the invention, when KH570 is adopted as a silicon monomer, the reaction principle for preparing the super-waterproof fluorinated self-cleaning anti-reflection coating material is as follows:
the invention also provides application of the super-waterproof fluorinated self-cleaning anti-reflection coating material in underwater detection equipment.
Compared with the prior art, the invention has the following beneficial effects:
the fluorinated self-cleaning anti-reflection coating material has good hydrophobic property and anti-reflection property, excellent water resistance and self-cleaning property, simple preparation process, low cost, no toxic substance and suitability for wide popularization.
The super-water-resistant performance of the fluorinated self-cleaning anti-reflection coating material is represented as follows: the novel chlorine substituted in-situ polymerization initiator is adopted as a polymerization initiator, so that each monomer is polymerized in situ on the surface of the initiator, and the organic/inorganic interface energy is reduced; in addition, the organic fluorine chain is extremely easy to enrich on the surface of the fluorinated polymer so that the fluorinated polymer has very low surface energy, and the fluorinated self-cleaning coating disclosed by the invention can effectively separate fluorinated groups by utilizing in-situ polymerization and steric hindrance effects and avoid the fluorinated groups from enriching on the surface of the polymer, so that the aim of inhibiting the rearrangement of the fluorinated groups is fulfilled, and the obtained fluorinated self-cleaning coating has excellent water resistance and has a wide prospect in the application aspect of underwater detection equipment.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings required in the embodiments will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is an infrared spectrum of a super-water-resistant fluorinated self-cleaning anti-reflection coating material obtained in example 1;
FIG. 2 shows the visible light transmittance measured by spraying the super water-resistant fluorinated self-cleaning anti-reflective coating material obtained in example 1 on a glass carrier (corresponding to the coating + glass in the figure) and the visible light transmittance of the glass carrier itself;
FIG. 3 is a schematic view of a static water contact angle of a coating prepared by using the super water-resistant fluorinated self-cleaning antireflective coating material obtained in example 2;
FIG. 4 is a diagram of a coating prepared by using the super water-resistant fluorinated self-cleaning anti-reflective coating material obtained in example 3.
Detailed Description
Reference will now be made in detail to various exemplary embodiments of the invention, the detailed description should not be construed as limiting the invention but as a more detailed description of certain aspects, features and embodiments of the invention. It is to be understood that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention.
Further, for numerical ranges in this disclosure, it is understood that each intervening value, between the upper and lower limit of that range, is also specifically disclosed. Every smaller range between any stated value or intervening value in a stated range and any other stated or intervening value in a stated range is encompassed within the invention. The upper and lower limits of these smaller ranges may independently be included or excluded in the range.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Although only preferred methods and materials are described herein, any methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present invention. All documents mentioned in this specification are incorporated by reference herein for the purpose of disclosing and describing the methods and/or materials associated with the documents. In case of conflict with any incorporated document, the present specification will control.
It will be apparent to those skilled in the art that various modifications and variations can be made in the specific embodiments of the present disclosure without departing from the scope or spirit of the disclosure. Other embodiments will be apparent to those skilled in the art from consideration of the specification. The description and examples are intended to be illustrative only.
As used herein, the terms "comprising," "including," "having," "containing," and the like are open-ended terms that mean including, but not limited to.
The "parts" in the present invention are in parts by weight unless otherwise specified.
In the following examples and comparative examples, the chlorinated initiators used were prepared by the following method:
adding 15 parts of nano Al into a double-layer jacket reaction bottle 2 O 3 Fully and uniformly stirring particles (with the particle size range of 100-500 nm), 0.7 part of diethanol amine and 450 parts of xylene to form turbid liquid. And (3) communicating circulating cooling water, reducing the temperature of the suspension liquid to 0 ℃, slowly dripping 1 part of 2-chloropropionyl chloride, and continuously stirring and reacting at the temperature of 0 ℃ for 24 hours to obtain a light green suspension liquid. And centrifuging the light green suspension, washing the obtained solid with deionized water and ethanol for 2 times respectively, and drying at 60 ℃ for 24 hours to prepare the chlorinated initiator.
The description will not be repeated below.
Example 1
100 parts of propylene carbonate, 30 parts of methyl methacrylate, 20 parts of butyl acrylate, 10 parts of perfluorooctyl ethyl methacrylate, 5 parts of KH570 and 1 part of chlorinated initiator are added into a three-neck flask and stirred uniformly to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 90 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
An infrared spectrum of the super-waterproof fluorinated self-cleaning anti-reflection coating material prepared in the embodiment is shown in fig. 1, and can be seen from fig. 1: 2964cm -1 And 2865cm -1 The peak is the stretching vibration peak of C-H. 1728cm -1 The peak is C ═ O stretching vibration peak at 1075cm -1 The nearby peak is caused by stretching vibration of Si-O. 1150-1240 cm -1 The peak is the stretching vibration peak of C-O-C and C-F, and is 660cm -1 A rocking vibration of C-F occurs. The above results show that each monomer successfully participates in the polymerization reaction.
Example 2
100 parts of propylene carbonate, 50 parts of methyl methacrylate, 30 parts of butyl acrylate, 17 parts of perfluorooctyl ethyl methacrylate, 10 parts of KH570 and 5 parts of chlorinated initiator are added into a three-neck flask and uniformly stirred to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 120 ℃ under continuous stirring, and reacting for 12 hours to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Example 3
90 parts of propylene carbonate, 40 parts of methyl methacrylate, 30 parts of butyl acrylate, 15 parts of perfluorooctyl ethyl methacrylate, 8 parts of KH570 and 3 parts of chlorinated initiator are added into a three-neck flask and stirred uniformly to obtain a mixed solution. Connecting a condensation reflux device to a three-neck flask, heating to 110 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Example 4
50 parts of propylene carbonate, 30 parts of methyl methacrylate, 30 parts of butyl acrylate, 20 parts of perfluorooctyl ethyl methacrylate, 5 parts of KH570 and 3 parts of chlorinated initiator are added into a three-neck flask and stirred uniformly to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 100 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Example 5
50 parts of propylene carbonate, 30 parts of methyl methacrylate, 20 parts of butyl acrylate, 10 parts of perfluorooctyl ethyl methacrylate, 5 parts of A171 and 1 part of chlorinated initiator are added into a three-neck flask and stirred uniformly to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 120 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Example 6
80 parts of propylene carbonate, 40 parts of methyl methacrylate, 20 parts of butyl acrylate, 15 parts of perfluorooctyl ethyl methacrylate, 5 parts of A171 and 2 parts of chlorinated initiator are added into a three-neck flask and stirred uniformly to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 100 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Example 7
100 parts of propylene carbonate, 50 parts of methyl methacrylate, 20 parts of butyl acrylate, 20 parts of perfluorooctyl ethyl methacrylate, 10 parts of A171 and 5 parts of chlorinated initiator are added into a three-neck flask and uniformly stirred to obtain a mixed solution. Connecting a condensation reflux device to a three-neck flask, heating to 110 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Example 8
50 parts of propylene carbonate, 30 parts of methyl methacrylate, 20 parts of butyl acrylate, 10 parts of perfluorooctyl ethyl methacrylate, 10 parts of A171 and 1.5 parts of chlorinated initiator are added into a three-neck flask and stirred uniformly to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 90 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Comparative example 1
100 parts of propylene carbonate, 30 parts of methyl methacrylate, 20 parts of butyl acrylate, 10 parts of perfluorooctyl ethyl methacrylate, 5 parts of KH570 and 1 part of azobisisobutyronitrile are added into a three-neck flask and stirred uniformly to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 90 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Comparative example 2
100 parts of propylene carbonate, 30 parts of methyl methacrylate, 20 parts of butyl acrylate, 10 parts of perfluorooctyl ethyl methacrylate, 5 parts of KH570 and 1 part of benzoyl peroxide are added into a three-neck flask and stirred uniformly to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 90 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Comparative example 3
100 parts of propylene carbonate, 30 parts of methyl methacrylate, 20 parts of butyl acrylate, 10 parts of perfluorooctyl ethyl methacrylate, 5 parts of KH570 and 1 part of potassium persulfate are added into a three-neck flask and uniformly stirred to obtain a mixed solution. Connecting a condensation reflux device to the three-neck flask, heating to 90 ℃ under continuous stirring, and reacting for 12h to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
Effect verification
The coating materials prepared in the embodiments 1-8 and the comparative examples 1-3 are coated on glass, and the specific coating method comprises the following steps: and (3) spraying the obtained super-waterproof fluorinated self-cleaning anti-reflection coating material onto an acetone deoiled glass plate by adopting a spraying mode (the air pressure is 4bar, the caliber of a spray gun is 0.8mm, and the spraying distance is 20cm), and drying at room temperature for 3 days to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating. Wherein, the visible light transmittance measured by spraying the coating material of example 1 on the glass plate and the visible light transmittance of the glass carrier are shown in fig. 2, and the "coating + glass" in fig. 2 represents the visible light transmittance measured by coating the coating material of example 1 on the glass plate, as can be seen from fig. 2: after the coating material obtained in example 1 was coated on the glass plate, the glass plate coated with the coating material obtained in example 1 had better light transmittance in the visible light region than the glass plate itself, which indicates that the coating material obtained in example 1 had an anti-reflection function for the glass plate.
A schematic diagram of a static water contact angle of a coating prepared by using the super water-resistant fluorinated self-cleaning anti-reflection coating material obtained in example 2 is shown in fig. 3. A real object diagram of a coating prepared from the super water-resistant fluorinated self-cleaning anti-reflection coating material obtained in example 3 is shown in fig. 4, wherein the same glass sheet is shown in fig. 4, a black solid line is used as a boundary, and a layer material is not sprayed on the left side of the glass sheet and is not covered by the coating; the right side is sprayed with the super-waterproof fluorinated self-cleaning anti-reflection coating material obtained in the example 3, and a coating is covered.
The static water contact angle, the visible light transmittance, the adhesion, the pencil hardness and the static water contact angle of the obtained coating after being polished by No. 2000 abrasive paper are tested, wherein the adhesion is tested by adopting a lattice drawing method according to GB/T9286 plus 1998 color paint and varnish paint film lattice drawing test, and the obtained results are shown in Table 1. All the materials are soaked in water for 90 days, then taken out, naturally dried, and tested again for static water contact angle and visible light transmittance, and the results are shown in table 1.
TABLE 1
Therefore, the fluorinated self-cleaning anti-reflection coating prepared by the embodiment of the method has good hydrophobic property and light transmittance, and good stability in an underwater environment, and through a 90-day soaking experiment, the reduction range of the contact angle and the light transmittance of the coating is small, and the anti-fouling self-cleaning requirement is still met. Compared with the existing fluorinated amphiphilic polymer, the coating obtained by the invention has outstanding water resistance.
The above description is only for the preferred embodiment of the present invention, and the protection scope of the present invention is not limited thereto, and any person skilled in the art should be able to cover the technical scope of the present invention, the technical solution and the inventive concept of the present invention equivalent or change within the technical scope of the present invention.
Claims (7)
1. The super-waterproof fluorinated self-cleaning anti-reflection coating material is characterized by comprising the following raw materials in parts by weight: 30-50 parts of methyl methacrylate, 20-30 parts of butyl acrylate, 5-10 parts of silicon monomer, 10-20 parts of fluorine monomer, 1-5 parts of chlorinated initiator and 50-100 parts of propylene carbonate.
2. The super-water-resistant fluorinated self-cleaning antireflective coating material of claim 1, wherein the silicon monomer is a silane coupling agent comprising gamma-methacryloxypropyltrimethoxysilane and/or vinyltrimethoxysilane.
3. The super water resistant fluorinated self-cleaning antireflective coating material of claim 1, wherein the fluoromonomer comprises perfluorooctyl ethyl methacrylate.
4. The super-water-resistant fluorinated self-cleaning antireflective coating layer according to claim 1, wherein the preparation method of the chlorinated initiator comprises the following steps: adding 10-20 parts of micro-nano particles and 0.5-1 part of catalyst diethanolamine into 400-500 parts of solvent, cooling to 0 ℃, adding 0.5-1.5 parts of initiator intermediate 2-chloropropionyl chloride, and reacting at 0 ℃ for 24 hours to obtain the chlorinated initiator.
5. A preparation method of the super-waterproof fluorinated self-cleaning anti-reflection coating material as claimed in any one of claims 1 to 4, characterized by comprising the following steps: weighing and mixing the raw materials to obtain a mixed solution, and heating for reaction to obtain the super-waterproof fluorinated self-cleaning anti-reflection coating material.
6. The preparation method according to claim 5, wherein the reaction temperature is 90-120 ℃ and the reaction time is 12 h.
7. Use of the super-water-resistant fluorinated self-cleaning anti-reflection coating material as claimed in any one of claims 1 to 4 in underwater detection equipment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210628580.3A CN114940723B (en) | 2022-06-06 | 2022-06-06 | Super-waterproof fluorinated self-cleaning anti-reflection coating material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210628580.3A CN114940723B (en) | 2022-06-06 | 2022-06-06 | Super-waterproof fluorinated self-cleaning anti-reflection coating material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114940723A true CN114940723A (en) | 2022-08-26 |
| CN114940723B CN114940723B (en) | 2023-06-27 |
Family
ID=82908445
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210628580.3A Active CN114940723B (en) | 2022-06-06 | 2022-06-06 | Super-waterproof fluorinated self-cleaning anti-reflection coating material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114940723B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104069753A (en) * | 2014-07-15 | 2014-10-01 | 哈尔滨工业大学（威海） | Preparation method for pollution-resistant polymer membrane |
| KR20180101797A (en) * | 2017-03-06 | 2018-09-14 | 서울화인테크 주식회사 | Curable coating composition and optical material using the same |
| CN114292485A (en) * | 2022-02-18 | 2022-04-08 | 常州大学 | Antibacterial adhesion-resistant hydrophobic anti-reflection material and preparation method and application thereof |
-
2022
- 2022-06-06 CN CN202210628580.3A patent/CN114940723B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104069753A (en) * | 2014-07-15 | 2014-10-01 | 哈尔滨工业大学（威海） | Preparation method for pollution-resistant polymer membrane |
| KR20180101797A (en) * | 2017-03-06 | 2018-09-14 | 서울화인테크 주식회사 | Curable coating composition and optical material using the same |
| CN114292485A (en) * | 2022-02-18 | 2022-04-08 | 常州大学 | Antibacterial adhesion-resistant hydrophobic anti-reflection material and preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 丰少伟;朱本峰;刘姣;张昭;: "氟/硅丙烯酸树脂防污涂层的制备及性能研究", 化工新型材料 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114940723B (en) | 2023-06-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107995907B (en) | Scratch-resistant easy-to-clean coating, method for the production thereof and use thereof | |
| CN106967191B (en) | A kind of environment-friendly preparation method thereof of super-amphiphobic fluoropolymer nano material | |
| CN107254054B (en) | Preparation method and application of solvent type hydrophobic and oleophobic nano hybrid fluorosilicone resin | |
| US6787585B2 (en) | Coating material for multifunctional superphobic layers | |
| KR0165844B1 (en) | Primer | |
| CN111574899B (en) | Organic-inorganic hybrid antifogging coating and preparation method thereof | |
| CN112094588B (en) | Fingerprint-preventing and anti-glare coating, protective film comprising same and preparation method of protective film | |
| CN101805434A (en) | Super hydrophobic silicon-fluorine polymer/nanometer silica hybridization nanometer material and preparation method thereof | |
| CN109665719A (en) | A kind of high anti-reflection coating solution of automatically cleaning and preparation method thereof and the high anti-reflection solar energy glass of automatically cleaning | |
| JPH04106161A (en) | Primer and article having a plurality of coating layers | |
| CN110760256A (en) | High-hardness wear-resistant anti-fingerprint nano coating for PC material and preparation method thereof | |
| CN116535585B (en) | Fluorine-containing epoxy acrylate polymer, photocuring transparent super-hydrophobic coating and preparation method | |
| CN111393942A (en) | Super-hydrophobic coating agent, transparent super-hydrophobic coating, and preparation method and application thereof | |
| JPH0546394B2 (en) | ||
| JP4866811B2 (en) | Antireflection film | |
| CN112521822B (en) | Polyacrylate composition, water-based paint and preparation method thereof | |
| CN114940723B (en) | Super-waterproof fluorinated self-cleaning anti-reflection coating material and preparation method thereof | |
| CN113527977A (en) | Silicone-acrylic resin coating and preparation method and application thereof | |
| CN112521851A (en) | Super-hydrophobic super-wear-resistant anti-fog coating composition and application thereof | |
| CN111849086A (en) | Preparation method of fluorine-free super-hydrophobic latex pigment with controllable hue | |
| CN112300393A (en) | Polysiloxane resins, coating compositions containing them and their use | |
| CN111234091A (en) | POSS (polyhedral oligomeric silsesquioxane) and fluorine-silicon synergistically modified waterborne polyacrylate antifouling resin as well as preparation method and application thereof | |
| CN110564187A (en) | Anti-reflection fluorine-free super-hydrophobic self-cleaning nano film and preparation method thereof | |
| CN111154025B (en) | Fluorine-containing resin, coating and preparation method | |
| CN110229610A (en) | A kind of anti-lixivium and preparation method thereof, anti-grey coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |