CN114916551B - Sterilization composition containing fludioxonil and iprodione and preparation method thereof - Google Patents
Sterilization composition containing fludioxonil and iprodione and preparation method thereof Download PDFInfo
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- CN114916551B CN114916551B CN202210725598.5A CN202210725598A CN114916551B CN 114916551 B CN114916551 B CN 114916551B CN 202210725598 A CN202210725598 A CN 202210725598A CN 114916551 B CN114916551 B CN 114916551B
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- iprodione
- fludioxonil
- shearing
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- stirring
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- 239000005867 Iprodione Substances 0.000 title claims abstract description 47
- ONUFESLQCSAYKA-UHFFFAOYSA-N iprodione Chemical compound O=C1N(C(=O)NC(C)C)CC(=O)N1C1=CC(Cl)=CC(Cl)=C1 ONUFESLQCSAYKA-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 239000005781 Fludioxonil Substances 0.000 title claims abstract description 37
- MUJOIMFVNIBMKC-UHFFFAOYSA-N fludioxonil Chemical compound C=12OC(F)(F)OC2=CC=CC=1C1=CNC=C1C#N MUJOIMFVNIBMKC-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 230000001954 sterilising effect Effects 0.000 title description 9
- 238000004659 sterilization and disinfection Methods 0.000 title description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 63
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 45
- 238000011068 loading method Methods 0.000 claims abstract description 38
- 239000000843 powder Substances 0.000 claims abstract description 33
- 239000002689 soil Substances 0.000 claims abstract description 24
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 21
- 241000894006 Bacteria Species 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 8
- 230000001737 promoting effect Effects 0.000 claims abstract description 8
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 239000003755 preservative agent Substances 0.000 claims abstract description 7
- 230000002335 preservative effect Effects 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims description 58
- 238000010008 shearing Methods 0.000 claims description 53
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 36
- 239000007788 liquid Substances 0.000 claims description 36
- 239000004576 sand Substances 0.000 claims description 34
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 24
- 244000060011 Cocos nucifera Species 0.000 claims description 24
- 238000000227 grinding Methods 0.000 claims description 23
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical group [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 21
- 238000002156 mixing Methods 0.000 claims description 21
- 229920001285 xanthan gum Polymers 0.000 claims description 21
- 229940082509 xanthan gum Drugs 0.000 claims description 21
- 235000010493 xanthan gum Nutrition 0.000 claims description 21
- 239000000230 xanthan gum Substances 0.000 claims description 21
- 239000012467 final product Substances 0.000 claims description 18
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 17
- 241000213948 Astragalus sinicus Species 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 7
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims description 4
- 235000011615 Pinus koraiensis Nutrition 0.000 claims description 2
- 240000007263 Pinus koraiensis Species 0.000 claims description 2
- 125000003827 glycol group Chemical group 0.000 claims 1
- 239000003899 bactericide agent Substances 0.000 abstract description 6
- 230000029087 digestion Effects 0.000 abstract description 4
- 241000233866 Fungi Species 0.000 description 18
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 14
- 239000003814 drug Substances 0.000 description 10
- 239000010903 husk Substances 0.000 description 10
- 241001061264 Astragalus Species 0.000 description 9
- 235000010110 Astragalus glycyphyllos Nutrition 0.000 description 9
- 235000006533 astragalus Nutrition 0.000 description 9
- 230000001580 bacterial effect Effects 0.000 description 9
- 239000002245 particle Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 5
- 235000015097 nutrients Nutrition 0.000 description 5
- 235000016709 nutrition Nutrition 0.000 description 5
- 239000000835 fiber Substances 0.000 description 4
- 239000003673 groundwater Substances 0.000 description 4
- 230000035764 nutrition Effects 0.000 description 4
- 238000007664 blowing Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- XZUAPPXGIFNDRA-UHFFFAOYSA-N ethane-1,2-diamine;hydrate Chemical compound O.NCCN XZUAPPXGIFNDRA-UHFFFAOYSA-N 0.000 description 3
- 230000000644 propagated effect Effects 0.000 description 3
- 229940079593 drug Drugs 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 238000000967 suction filtration Methods 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- IRTLROCMFSDSNF-UHFFFAOYSA-N 2-phenyl-1h-pyrrole Chemical compound C1=CNC(C=2C=CC=CC=2)=C1 IRTLROCMFSDSNF-UHFFFAOYSA-N 0.000 description 1
- 241000123650 Botrytis cinerea Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/08—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing solids as carriers or diluents
- A01N25/10—Macromolecular compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/32—Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/46—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=C=S groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The application relates to the field of bactericides, and particularly discloses a bactericidal composition containing fludioxonil and iprodione and a preparation method thereof. The bactericidal composition containing fludioxonil and iprodione is prepared from the following raw materials, by weight, 8% -12% of fludioxonil raw material, 27% -33% of iprodione, 4% -6% of dispersing agent, 0.9% -1.4% of viscosity regulator, 0.05% -0.15% of preservative, 3% -5% of antifreezing agent, 3% -7% of growth promoting decomposition component and the balance of water, wherein the growth promoting decomposition component comprises white harrow tooth bacteria powder and a loading agent for colony growth in soil, and the weight ratio of the white harrow tooth bacteria powder to the loading agent is (1-3): 2-4. The bactericidal composition can be used for preventing and treating gray mold, and has the advantages of accelerating the digestion speed of iprodione in soil and reducing the possibility of the iprodione polluting underground water.
Description
Technical Field
The application relates to the field of bactericides, in particular to a bactericidal composition containing fludioxonil and iprodione and a preparation method thereof.
Background
Agricultural bactericides are a type of pesticide used for preventing and treating plant diseases caused by various pathogenic microorganisms, wherein fludioxonil is used as a non-systemic phenylpyrrole bactericide, and the effect of treating gray mold is particularly remarkable. In the practical application process, the iprodione can effectively prevent and treat fungi with resistance to benzimidazole systemic bactericides, so that fludioxonil is often compounded with the iprodione to be used so as to enlarge the bactericidal spectrum of the bactericide.
The iprodione and fludioxonil are compounded to prevent and treat gray mold, and partial iprodione enters the soil during application, and the iprodione is digested slowly in the soil, so that if raining days are used during digestion, the iprodione enters the groundwater along with rainwater, thereby polluting the groundwater.
Disclosure of Invention
In order to accelerate the digestion speed of iprodione in soil and reduce the possibility of the iprodione polluting underground water, the application provides a bactericidal composition containing fludioxonil and iprodione and a preparation method thereof.
In a first aspect, the present application provides a bactericidal composition containing fludioxonil and iprodione, which adopts the following technical scheme:
the bactericidal composition containing fludioxonil and iprodione is prepared from the following raw materials, by weight, 8% -12% of fludioxonil raw material, 27% -33% of iprodione, 4% -6% of dispersing agent, 0.9% -1.4% of viscosity regulator, 0.05% -0.15% of preservative, 3% -5% of antifreezing agent, 3% -7% of growth promoting decomposition component and the balance of water, wherein the growth promoting decomposition component comprises white harrow tooth bacteria powder and a loading agent for colony growth in soil, and the weight ratio of the white harrow tooth bacteria powder to the loading agent is (1-3): 2-4.
By adopting the technical scheme, part of the sterilization composition falls on the soil, bacterial colonies are propagated on the loading agent, substances such as polysaccharide in the white harrow tooth fungus powder provide nutritional ingredients for bacterial colony growth in the process, and the fludioxonil and iprodione in the soil are decomposed in the bacterial colony growth process, so that the raw medicines remained in the soil are effectively reduced, the raw medicines entering underground water along with rainwater are reduced, and the pollution to the underground water is reduced.
Preferably, the loading agent comprises coco coir and astragalus sinicus pollen filled in the coco coir.
Through adopting above-mentioned technical scheme, the coconut husk plays certain adsorption to the former medicine, reduces the former medicine and diffuses in soil, contacts the milk vetch pollen in the coconut husk when the bacterium grows in the soil to further promote the bacterium growth in the soil, more be convenient for decompose the former medicine.
Preferably, the preparation method of the loading agent comprises the following steps of mixing ground astragalus sinicus pollen with coconut coir, wherein the grain diameter D of the astragalus sinicus pollen 90 The coconut coir mixed with the astragalus sinicus pollen is modified by ethylenediamine and then ground into the particle size D, wherein the particle size is less than or equal to 2 mu m 90 And the particle size is less than or equal to 10 mu m, so as to prepare the loading agent.
Through adopting above-mentioned technical scheme, with the milk vetch pollen filling in the coconut husk gap, after the ethylenediamine modification, the coconut husk fiber morphology changes to lock milk vetch pollen wherein, reduce the circumstances that milk vetch pollen deviate from in the coconut husk, improve loading agent stability.
Preferably, the dispersant comprises SC-3266 and 500LQ, and the weight ratio of the SC-3266 to the 500LQ is (3-5): 1.
by adopting the technical scheme, the fludioxonil technical and the iprodione technical are convenient to disperse to form a stable preparation.
Preferably, the viscosity modifier comprises magnesium aluminum silicate and xanthan gum, wherein the weight ratio of the magnesium aluminum silicate to the xanthan gum is (8-12): 1-2.
By adopting the technical scheme, the magnesium aluminum silicate and the xanthan gum form sol and gel in water, so that the viscosity of the sterilization composition is adjusted, and the stability of a sterilization composition system is improved.
Preferably, the preservative is pinus koraiensis.
By adopting the technical scheme, the stability of the sterilization composition system is ensured, so that the quality and life cycle of the sterilization composition are ensured.
Preferably, the antifreezing agent is ethylene glycol.
By adopting the technical scheme, the freeze-thawing stability of the sterilizing composition is improved, and the deterioration condition of the sterilizing composition is reduced.
In a second aspect, the present application provides a method for preparing a bactericidal composition containing fludioxonil and iprodione, which adopts the following technical scheme:
the preparation method of the bactericidal composition containing fludioxonil and iprodione comprises the following steps: s1, mixing a viscosity regulator with water, and shearing and stirring until the viscosity regulator is melted; s2, adding fludioxonilShearing and stirring the medicine, the iprodione raw medicine, the white harrow tooth fungus powder and the loading agent uniformly; s3, adding the preservative, the antifreezing agent and the dispersing agent heated in the water bath, and continuously shearing and uniformly stirring to obtain feed liquid; s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
By adopting the technical scheme, the raw materials are sequentially processed according to the steps, so that the bactericidal composition is prepared, the stability of a bactericidal composition system is effectively improved, and the performance of the bactericidal composition is improved.
In summary, the present application has the following beneficial effects:
1. according to the modified coconut coir powder loading method, the modified coconut coir powder loaded with the milk vetch pollen is used as a loading agent, so that on one hand, the diffusion of raw materials in soil is reduced, on the other hand, the white rake tooth fungus powder provides nutrition for the growth of bacteria in the soil, after the bacteria in the soil are propagated and are contacted with the modified coconut coir powder, the milk vetch pollen further provides nutrition for the growth of the bacteria, and therefore the bacteria are promoted to propagate on the modified coconut coir powder, the raw materials are further decomposed, the raw materials entering groundwater along with rainwater are effectively reduced, and the pollution to the groundwater is reduced.
2. In the preparation process of the loading agent, gaps of the coconut coir are utilized to fill the ground astragalus sinicus pollen therein, and the coconut coir fiber is changed by modifying with ethylenediamine, so that the astragalus sinicus pollen is clamped between the coconut coir fibers, the astragalus sinicus pollen falling from the coconut coir fibers in the subsequent processing process is effectively reduced, and the stability of the loading agent is improved.
Detailed Description
The present application is described in further detail below with reference to examples.
Preparation of the supporting agent
Preparation example 1
S1, grinding 10kg of astragalus sinicus pollen to a particle size D90 of less than or equal to 2 mu m, and then mixing with 15kg of coconut husk uniformly;
s2, soaking a mixture of the astragalus sinicus pollen and the coco coir into an ethylenediamine water solution with the mass fraction of 75%, stirring for 3 hours at 40 ℃, carrying out suction filtration at a stirring speed of 60r/min, cleaning for 3 times by using deionized water, and drying in a blowing drying oven at 80 ℃ to obtain the modified coco coir loaded with the astragalus sinicus pollen;
s3, grinding the modified coconut coir loaded with the astragalus sinicus pollen to the particle size D 90 And the particle size is less than or equal to 10 mu m, so as to prepare the loading agent.
Preparation example 2
S1, soaking coco coir into an ethylenediamine water solution with the mass fraction of 75%, stirring for 3 hours at 40 ℃, stirring at 60r/min, washing 3 times by using deionized water after suction filtration, and drying in a blowing drying oven at 80 ℃ to obtain modified coco coir;
s2, grinding the modified coconut coir to the grain diameter D 90 And the particle size is less than or equal to 10 mu m, so as to prepare the loading agent.
Preparation example 3
10kg of astragalus sinicus pollen is ground to a grain diameter D90 which is less than or equal to 2 mu m, soaked in an ethylenediamine water solution with the mass fraction of 75%, stirred for 3 hours at 40 ℃, stirred at 60r/min, filtered by suction, washed for 3 times by deionized water, and dried in a blowing drying oven at 80 ℃ to obtain the loading agent.
Examples
Example 1
S1, mixing 0.8kg of magnesium aluminum silicate, 0.1kg of xanthan gum and 66.35kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 8kg of fludioxonil technical, 27kg of iprodione technical, 1kg of white harrow teeth fungus powder and 2kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.05kg of kathon, 3kg of glycol and 3kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 2
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 46.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 1kg of white harrow teeth fungus powder and 2kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 3
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 45.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 1kg of white harrow teeth fungus powder and 3kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 4
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 44.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 1kg of white harrow teeth fungus powder and 4kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 5
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 45.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 2kg of white harrow teeth fungus powder and 2kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 6
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 44.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 2kg of white harrow teeth fungus powder and 3kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 7
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 43.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 2kg of white harrow teeth fungus powder and 4kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 8
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 44.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 3kg of white harrow teeth fungus powder and 2kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
S4、grinding the feed liquid by a grinding machine, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 9
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 43.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 3kg of white harrow teeth fungus powder and 3kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 10
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 42.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 3kg of white harrow teeth fungus powder and 4kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Example 11
S1, mixing 1.2kg of magnesium aluminum silicate, 0.2kg of xanthan gum and 35.45kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 12kg of fludioxonil technical, 33kg of iprodione technical, 3kg of white harrow teeth fungus powder and 4kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.15kg of kathon, 5kg of glycol and 5kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 Less than or equal to 5 μm to obtain the most effectiveAnd (5) final product.
Comparative example
Comparative example 1
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 47.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical and 2kg of white harrow teeth fungus powder, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Comparative example 2
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 46.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical and 3kg of the loading agent prepared in the preparation example 1, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Comparative example 3
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 49.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical and 30kg of iprodione technical, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Comparative example 4
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 44.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 2kg of white harrow teeth fungus powder and 3kg of the loading agent prepared in the preparation example 2, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Comparative example 5
S1, mixing 1kg of magnesium aluminum silicate, 0.15kg of xanthan gum and 44.75kg of water, and shearing and stirring until a viscosity regulator is melted;
s2, adding 10kg of fludioxonil technical, 30kg of iprodione technical, 2kg of white harrow teeth fungus powder and 3kg of the loading agent prepared in the preparation example 3, and shearing and stirring uniformly;
s3, adding 0.1kg of kathon, 4kg of glycol and 4kg of SC-3266 heated in a water bath, and continuously shearing and stirring 1kg of 500LQ heated in the water bath uniformly to prepare a feed liquid;
s4, sand grinding the feed liquid by a sand grinder, and controlling the grain diameter D 90 And (5) less than or equal to 5 mu m to prepare the final product.
Table 1 raw materials Table (kg) for examples and comparative examples
Performance test the fungicidal compositions of the present application were used for controlling botrytis cinerea, and each of examples and comparative examples was provided with a test area of 10m 2 The application rate is 50 g/mu, and the spray application is carried out. Samples were taken 1h,1d,3d,5d,7d,14d,21d,30d and 50d after dosing, using a five point sampling method, 10cm of soil was drilled each time for detection. Residual amount in soil is detected by using a gas chromatograph so as to be plotted backHalf-life was calculated by equation.
TABLE 2 data sheet of residual iprodione in soil
TABLE 3 data table of digestion rate and half-life of residual iprodione in soil
It can be seen from the combination of example 6, comparative example 1 and comparative example 3 and the combination of table 2 that only by adding the white rake powder, although a certain amount of nutrients can be provided for the bacterial reproduction, the raw materials are dispersed and the subsequent supply of nutrients cannot be continued, so that the bacterial reproduction cannot be continued in large quantities, thereby making the decomposition efficiency not high.
As can be seen from the combination of example 6, comparative example 2 and comparative example 3 and the combination of table 2, the lack of the white rake teeth powder provides the bacteria with nutrients required for the initial growth, the initial growth of the bacteria is slow, and the milk vetch pollen in the modified coconut husk is difficult to reach, so that the decomposition efficiency of the raw medicine is low.
As can be seen from the combination of example 6, comparative example 4 and comparative example 5 and the combination of table 2, the white rake teeth powder provides nutrients for the initial growth of bacteria in the soil, the bacteria in the soil are propagated in large quantity and contacted with the modified coconut husk, and then the milk vetch pollen further provides nutrients for the growth of bacteria, thereby promoting the further propagation of bacteria to decompose the original medicine.
As can be seen by combining examples 2-10 and table 2, the half-life time can also be effectively reduced by adjusting the addition of the white harrow teeth powder and the loading agent, the white harrow teeth powder provides nutrition for bacterial growth in soil, and after bacterial propagation in soil contacts with the modified coconut husk, the milk vetch pollen further provides nutrition for bacterial growth, thereby promoting bacterial propagation on the modified coconut husk and further decomposing the raw medicine.
The present embodiment is merely illustrative of the present application and is not intended to be limiting, and those skilled in the art, after having read the present specification, may make modifications to the present embodiment without creative contribution as required, but is protected by patent laws within the scope of the claims of the present application.
Claims (2)
1. The bactericidal composition containing fludioxonil and iprodione is characterized by being prepared from the following raw materials, by weight, 8% -12% of fludioxonil raw material, 27% -33% of iprodione, 4% -6% of dispersing agent, 0.9% -1.4% of viscosity regulator, 0.05% -0.15% of preservative, 3% -5% of antifreezing agent, 3% -7% of growth promoting decomposition component and the balance of water, wherein the growth promoting decomposition component is composed of white harrow tooth bacteria powder and a loading agent for colony growth in soil, and the weight ratio of the white harrow tooth bacteria powder to the loading agent is (1-3) (2-4);
the loading agent consists of coconut coir and astragalus sinicus pollen filled in the coconut coir;
the preparation method of the loading agent comprises the following steps of mixing the ground astragalus sinicus pollen with coco coir, wherein the grain diameter D90 of the astragalus sinicus pollen is less than or equal to 2 mu m, and grinding the coco coir mixed with the astragalus sinicus pollen to the grain diameter D90 of less than or equal to 10 mu m after being modified by ethylenediamine, so as to prepare the loading agent;
the dispersing agent is SC-3266 and 500LQ, and the weight ratio of the SC-3266 to the 500LQ is (3-5): 1, a step of;
the viscosity regulator is magnesium aluminum silicate and xanthan gum, and the weight ratio of the magnesium aluminum silicate to the xanthan gum is (8-12) (1-2);
the preservative is pinus koraiensis; the antifreezing agent is glycol.
2. The method for preparing the bactericidal composition containing fludioxonil and iprodione of claim 1, comprising the steps of: s1, mixing a viscosity regulator with water, and shearing and stirring until the viscosity regulator is melted; s2, adding a fludioxonil technical, an iprodione technical, white harrow teeth powder and a loading agent, and shearing and stirring uniformly; s3, adding the preservative, the antifreezing agent and the dispersing agent heated in the water bath, and continuously shearing and uniformly stirring to obtain feed liquid; s4, sand grinding the feed liquid by a sand mill, and controlling the grain diameter D90 to be less than or equal to 5 mu m to obtain a final product.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101005761A (en) * | 2004-08-25 | 2007-07-25 | 詹森药业有限公司 | Imazalil compositions comprising alkoxylated amines |
| CN101642126A (en) * | 2009-07-09 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Compound bactericidal composition containing fludioxonil |
| CN108902150A (en) * | 2018-05-28 | 2018-11-30 | 徐建自 | A kind of Synergistic bactericidal composition and its suspending agent containing cyprodinil and fludioxonil |
| CN109226251A (en) * | 2018-10-24 | 2019-01-18 | 邵亦飞 | The ex-situ repair system and method for oil-polluted soils |
| CN112772669A (en) * | 2020-12-31 | 2021-05-11 | 山东东合生物科技有限公司 | Iprodione and procymidone suspending agent and preparation method thereof |
| CN112899171A (en) * | 2021-04-02 | 2021-06-04 | 河南科技大学 | Rapex leucocytochys LL210, application thereof and biocontrol microbial inoculum |
-
2022
- 2022-06-24 CN CN202210725598.5A patent/CN114916551B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101005761A (en) * | 2004-08-25 | 2007-07-25 | 詹森药业有限公司 | Imazalil compositions comprising alkoxylated amines |
| CN101642126A (en) * | 2009-07-09 | 2010-02-10 | 深圳诺普信农化股份有限公司 | Compound bactericidal composition containing fludioxonil |
| CN108902150A (en) * | 2018-05-28 | 2018-11-30 | 徐建自 | A kind of Synergistic bactericidal composition and its suspending agent containing cyprodinil and fludioxonil |
| CN109226251A (en) * | 2018-10-24 | 2019-01-18 | 邵亦飞 | The ex-situ repair system and method for oil-polluted soils |
| CN112772669A (en) * | 2020-12-31 | 2021-05-11 | 山东东合生物科技有限公司 | Iprodione and procymidone suspending agent and preparation method thereof |
| CN112899171A (en) * | 2021-04-02 | 2021-06-04 | 河南科技大学 | Rapex leucocytochys LL210, application thereof and biocontrol microbial inoculum |
Non-Patent Citations (3)
| Title |
|---|
| 异菌脲在土壤中的降解和移动性研究;程冰峰等;《生态毒理学报》;304-310 * |
| 异菌脲在大白菜和土壤中的残留消解动态;邵燕;王良贵;韦祥庆;;浙江农业科学(08);全文 * |
| 白腐真菌修复多环芳烃污染土壤及其降解机理的研究进展;李烜桢;林先贵;;安全与环境学报(06);全文 * |
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