CN114890719A - Environment-friendly chemical slurry for hard-cutting secant pile retaining wall and preparation method thereof - Google Patents

Environment-friendly chemical slurry for hard-cutting secant pile retaining wall and preparation method thereof Download PDF

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Publication number
CN114890719A
CN114890719A CN202210424207.6A CN202210424207A CN114890719A CN 114890719 A CN114890719 A CN 114890719A CN 202210424207 A CN202210424207 A CN 202210424207A CN 114890719 A CN114890719 A CN 114890719A
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parts
weight
fly ash
stirring
retaining wall
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Inventor
李慧生
寇举安
刘鹏飞
陈国志
周齐勇
周清权
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Shenzhen Beidouyun Information Technology Co ltd
Horizon Geotechnical Engineering Co ltd Guangzhou
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Shenzhen Beidouyun Information Technology Co ltd
Horizon Geotechnical Engineering Co ltd Guangzhou
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Publication of CN114890719A publication Critical patent/CN114890719A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/001Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/023Chemical treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
    • C09K8/504Compositions based on water or polar solvents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The application relates to the technical field of pile foundation construction, in particular to environment-friendly chemical slurry for hard-cutting secant pile retaining walls and a preparation method thereof. The chemical slurry comprises the following components in parts by weight: 500-600 parts of water; 20-30 parts of bentonite; 0.8-1.4 parts of soda ash; 0.1-0.3 parts of ferrochrome sodium lignosulfonate; 1-2 parts of lignocellulose; 1-2 parts of paper pulp; 20-30 parts of fly ash; the preparation method comprises the following steps: s1: adding 0.8-1.4 parts by weight of soda ash into 600 parts by weight of water, and stirring and dissolving to obtain a mixed solution; s2: adding 20-30 parts by weight of bentonite and 20-30 parts by weight of fly ash into the mixed solution, stirring for 1-2h, standing for 23-24h, and continuing stirring for 1-2 h; s3: dissolving 0.1-0.3 part by weight of ferrochrome sodium lignosulfonate, adding into the mixed solution, adding 1-2 parts of lignocellulose and 1-2 parts of paper pulp, and stirring for 1-2 hours to obtain the chemical slurry. The chemical mud of this application has the advantage that reduces mud film thickness and reduce cost.

Description

Environment-friendly chemical slurry for hard-cutting secant pile retaining wall and preparation method thereof
Technical Field
The application relates to the technical field of pile foundation construction, in particular to environment-friendly chemical slurry for hard-cutting secant pile retaining walls and a preparation method thereof.
Background
The retaining wall slurry is one kind of slurry capable of forming mud skin on the wall of the hole to reinforce the wall and prevent collapse during the hole forming construction of mechanical hole forming pile and grouting pile or excavating underground impervious wall and to stabilize the water level inside the hole. The wall protection mud is usually a mixed slurry formed by adding water and stirring bentonite (or clay) and additives. In the process of mechanical pore-forming construction or underground excavation construction, the wall protection slurry is circularly conveyed, and the water pressure is controlled by utilizing the pressure difference between the wall protection slurry and underground water, so that the wall protection slurry can form a mud skin on the wall of the hole to reinforce the wall of the hole and prevent the wall of the hole from collapsing. In addition, the wall protection slurry with certain viscosity can also stabilize the water level in the hole. In addition, the wall mud also has the effect of cooling and lubricating the drill bit and carrying out rock debris. The quality of the retaining wall slurry has a crucial influence on the bearing capacity of the pile end and the integrity of the pile body, and the quality of the retaining wall slurry determines the final construction quality of the cast-in-place pile and the underground diaphragm wall.
The bentonite is a mineral, the distribution of the bentonite has regionality, bentonite is not produced in many areas in China at present, the bentonite is used for preparing the wall protection slurry and needs to be purchased from other places, the transportation distance is long, and the preparation cost of the wall protection slurry is increased, so that the problem of how to reduce the consumption of the bentonite and simultaneously improve the waterproof performance and the mud film thickness of the slurry wall protection is solved.
Disclosure of Invention
The application provides environment-friendly chemical slurry for hard cutting secant pile retaining wall and a preparation method thereof.
In a first aspect, the application provides an environment-friendly chemical slurry for hard cutting secant pile retaining wall, which adopts the following technical scheme:
an environment-friendly chemical slurry for hard cutting secant pile retaining wall comprises the following components in parts by weight:
500-600 parts of water;
20-30 parts of bentonite;
0.8-1.4 parts of soda ash;
0.1-0.3 parts of ferrochrome sodium lignosulfonate;
1-2 parts of lignocellulose;
1-2 parts of paper pulp;
20-30 parts of fly ash.
Preferably, the emulsion powder also comprises 0.8 to 1.2 parts by weight of vinyl acetate-ethylene versatate copolymer redispersible emulsion powder.
Preferably, the fly ash is modified fly ash, and the preparation method of the modified fly ash comprises the following steps: dissolving 0.2-0.4 part by weight of silane coupling agent in 10-20 parts by weight of water, then adding 60-80 parts by weight of fly ash, grinding for 10-20h at 25 ℃ in a ball mill, and then drying at 25 ℃ to obtain the modified fly ash.
Preferably, the mesh number of the fly ash is 300-400 meshes.
Preferably, the starch also comprises 1-2 parts by weight of starch.
In a second aspect, the application provides a preparation method of environment-friendly chemical slurry for hard cutting secant pile retaining wall, which adopts the following technical scheme:
a preparation method of environment-friendly chemical slurry for hard cutting bite pile retaining wall comprises the following steps of S1: adding 0.8-1.4 parts by weight of soda ash into 600 parts by weight of water, and stirring and dissolving to obtain a mixed solution; s2: adding 20-30 parts by weight of bentonite and 20-30 parts by weight of fly ash into the mixed solution, stirring for 1-2h, standing for 23-24h, and continuing stirring for 1-2 h;
s3: dissolving 0.1-0.3 part by weight of ferrochrome sodium lignosulfonate, adding into the mixed solution, adding 1-2 parts of lignocellulose and 1-2 parts of paper pulp, and stirring for 1-2 hours to obtain the chemical slurry.
Preferably, in the step of S3, 0.8-1.2 parts by weight of vinyl acetate-vinyl versatate copolymer re-dispersible latex powder and 1-2 parts by weight of starch are also added.
In summary, the present application has the following beneficial effects:
1. the wall protection slurry prepared by the invention meets the national relevant standards, can be applied to actual engineering construction, has moderate viscosity and small water loss, and avoids the situation that the slurry water content is reduced after repeated circulation and the construction effect is greatly reduced.
2. The mud film formed by the wall protection mud prepared by the invention has small thickness, the waterproof performance is not reduced along with the reduction of the mud film thickness, the mud film thickness is obviously reduced after the modified fly ash is used, and a better waterproof effect is obtained.
3. The modified fly ash is used for replacing bentonite, so that the use of the bentonite is effectively reduced, and the cost is obviously reduced.
Detailed Description
The present application will be described in further detail with reference to examples.
Examples
Example 1
A preparation method of environment-friendly chemical slurry for hard cutting secant pile retaining wall comprises the following steps,
s1: adding 0.8 part by weight of soda ash into 600 parts by weight of water, and stirring by using a hydraulic stirrer to dissolve the soda ash into the water to obtain a mixed solution of the soda ash and the water;
s2: mixing 25 parts by weight of bentonite and 30 parts by weight of fly ash together, fully mixing, adding into the mixed solution, stirring for 1 hour by using a hydraulic stirrer, standing for 23.5 hours after stirring, and continuing stirring for 2 hours after standing;
s3: dissolving 0.1 part by weight of ferrochrome sodium lignosulfonate and 1.2 parts by weight of vinyl acetate-vinyl versatate copolymer redispersible emulsion powder, adding the dissolved solution into the mixed solution, fully stirring and mixing the solution, then adding 1 part by weight of lignocellulose, 1.5 parts by weight of starch and 2 parts by weight of paper pulp, and stirring the mixture for 1.5 hours by using a hydraulic stirrer to obtain the chemical slurry.
Example 2
A preparation method of environment-friendly chemical slurry for hard cutting secant pile retaining wall comprises the following steps,
s1: adding 1.1 parts by weight of soda ash into 500 parts by weight of water, and stirring by using a hydraulic stirrer to dissolve the soda ash into the water to obtain a mixed solution of the soda ash and the water;
s2: mixing 30 parts by weight of bentonite and 25 parts by weight of fly ash together, fully mixing, adding into the mixed solution, stirring for 2 hours by using a hydraulic stirrer, standing for 24 hours after stirring is finished, and continuing stirring for 1 hour after standing is finished;
s3: dissolving 0.3 part by weight of ferrochrome sodium lignosulphonate and 1 part by weight of vinyl acetate-vinyl versatate copolymer redispersible latex powder, adding the obtained solution into the mixed solution, fully stirring and mixing, then adding 1.5 parts by weight of lignocellulose, 2 parts by weight of starch and 1 part by weight of paper pulp, and stirring for 1 hour by using a hydraulic stirrer to obtain the chemical slurry.
Example 3
A preparation method of environment-friendly chemical slurry for hard cutting secant pile retaining wall comprises the following steps,
s1: adding 1.4 parts by weight of soda ash into 550 parts by weight of water, and stirring by using a hydraulic stirrer to dissolve the soda ash into the water to obtain a mixed solution of the soda ash and the water;
s2: mixing 20 parts by weight of bentonite and 20 parts by weight of fly ash together, fully mixing, adding into the mixed solution, stirring for 1.5h by using a hydraulic stirrer, standing for 23h after stirring is finished, and continuing stirring for 1.5h after standing is finished;
s3: dissolving 0.2 part by weight of ferrochrome sodium lignosulfonate and 0.8 part by weight of vinyl acetate-vinyl versatate copolymer redispersible emulsion powder, adding the dissolved solution into the mixed solution, fully stirring and mixing the solution, then adding 2 parts by weight of lignocellulose, 1 part by weight of starch and 1.5 parts by weight of paper pulp, and stirring the mixture for 2 hours by using a hydraulic stirrer to obtain the chemical slurry.
Example 4
A preparation method of environment-friendly chemical slurry for hard cutting secant pile retaining wall comprises the following steps,
s1: adding 1.1 parts by weight of soda ash into 500 parts by weight of water, and stirring by using a hydraulic stirrer to dissolve the soda ash into the water to obtain a mixed solution of the soda ash and the water;
s2: mixing 30 parts by weight of bentonite and 25 parts by weight of fly ash together, fully mixing, adding into the mixed solution, stirring for 2 hours by using a hydraulic stirrer, standing for 24 hours after stirring is finished, and continuing stirring for 1 hour after standing is finished;
s3: dissolving 0.3 part by weight of ferrochrome sodium lignosulfonate and 1 part by weight of vinyl acetate-vinyl versatate copolymer redispersible emulsion powder, adding the dissolved solution into the mixed solution, fully stirring and mixing the solution, then adding 1.5 parts by weight of lignocellulose, 2 parts by weight of starch and 1 part by weight of paper pulp, and stirring the mixture for 1 hour by using a hydraulic stirrer to obtain the chemical slurry.
The preparation method of the modified fly ash comprises the following steps: dissolving 0.2 part by weight of silane coupling agent in 15 parts by weight of water, adding 60 parts by weight of fly ash with the mesh number range of 400 meshes, grinding for 20 hours in a ball mill at 25 ℃, and drying at 25 ℃ to obtain the modified fly ash.
Example 5
A preparation method of environment-friendly chemical slurry for hard cutting secant pile retaining wall comprises the following steps,
s1: adding 1.1 parts by weight of soda ash into 500 parts by weight of water, and stirring by using a hydraulic stirrer to dissolve the soda ash into the water to obtain a mixed solution of the soda ash and the water;
s2: mixing 30 parts by weight of bentonite and 25 parts by weight of fly ash together, fully mixing, adding into the mixed solution, stirring for 2 hours by using a hydraulic stirrer, standing for 24 hours after stirring is finished, and continuing stirring for 1 hour after standing is finished;
s3: dissolving 0.3 part by weight of ferrochrome sodium lignosulfonate and 1 part by weight of vinyl acetate-vinyl versatate copolymer redispersible emulsion powder, adding the dissolved solution into the mixed solution, fully stirring and mixing the solution, then adding 1.5 parts by weight of lignocellulose, 2 parts by weight of starch and 1 part by weight of paper pulp, and stirring the mixture for 1 hour by using a hydraulic stirrer to obtain the chemical slurry.
The preparation method of the modified fly ash comprises the following steps: dissolving 0.3 part by weight of silane coupling agent in 20 parts by weight of water, adding 70 parts by weight of fly ash with 350 meshes, grinding for 10 hours at 25 ℃ in a ball mill, and drying at 25 ℃ to obtain the modified fly ash.
Example 6
A preparation method of environment-friendly chemical slurry for hard cutting secant pile retaining wall comprises the following steps,
s1: adding 1.1 parts by weight of soda ash into 500 parts by weight of water, and stirring by using a hydraulic stirrer to dissolve the soda ash into the water to obtain a mixed solution of the soda ash and the water;
s2: mixing 30 parts by weight of bentonite and 25 parts by weight of fly ash together, fully mixing, adding into the mixed solution, stirring for 2 hours by using a hydraulic stirrer, standing for 24 hours after stirring is finished, and continuing stirring for 1 hour after standing is finished;
s3: dissolving 0.3 part by weight of ferrochrome sodium lignosulphonate and 1 part by weight of vinyl acetate-vinyl versatate copolymer redispersible latex powder, adding the obtained solution into the mixed solution, fully stirring and mixing, then adding 1.5 parts by weight of lignocellulose, 2 parts by weight of starch and 1 part by weight of paper pulp, and stirring for 1 hour by using a hydraulic stirrer to obtain the chemical slurry.
The preparation method of the modified fly ash comprises the following steps: dissolving 0.4 part by weight of silane coupling agent in 10 parts by weight of water, adding 80 parts by weight of fly ash with the mesh number range of 300 meshes, grinding for 15 hours at 25 ℃ in a ball mill, and drying at 25 ℃ to obtain the modified fly ash.
Performance test
According to the requirements of the national standard 'construction Standard of Foundation of building foundation' (GB51004-2015), the viscosity, specific gravity, water loss and mud film thickness of the wall protection mud are tested.
TABLE 1 comprehensive properties testing table for mud
Viscosity/s Specific gravity of Water loss/ml Thickness of mud film/mm
Example 1 16 1.11 11 2.3
Example 2 15 1.09 12 2.4
Example 3 15 1.12 10 2.4
Example 4 14 1.10 8 2.0
Example 5 13 1.12 9 2.1
Example 6 14 1.11 8 1.9
According to the detection data in the table 1, the wall protection slurry prepared by the invention meets the national relevant standards, can be applied to actual engineering construction, has moderate viscosity and small water loss, and avoids the situations that the water content of the slurry is reduced after repeated circulation and the construction effect is greatly reduced.
Moreover, the mud film formed by the wall protection slurry prepared by the invention has small thickness, the waterproof performance is not reduced along with the reduction of the mud film thickness, and the mud film thickness is obviously reduced after the modified fly ash is used, so that a better waterproof effect is obtained.
And the fly ash is used for replacing bentonite, so that the use of the bentonite can be effectively reduced, and the cost is obviously reduced.
The specific embodiments are only for explaining the present application and are not limiting to the present application, and those skilled in the art can make modifications to the embodiments without inventive contribution as required after reading the present specification, but all the embodiments are protected by patent law within the scope of the claims of the present application.

Claims (7)

1. The environment-friendly chemical slurry for the hard cutting occlusive pile retaining wall is characterized by comprising the following components in parts by weight:
500-600 parts of water;
20-30 parts of bentonite;
0.8-1.4 parts of soda ash;
0.1-0.3 parts of ferrochrome sodium lignosulfonate;
1-2 parts of lignocellulose;
1-2 parts of paper pulp;
20-30 parts of fly ash.
2. The environmentally friendly chemical grout for hard cut bite pile retaining wall according to claim 1, wherein: also comprises 0.8 to 1.2 weight portions of vinyl acetate-ethylene versatate copolymer re-dispersible latex powder.
3. The environmentally friendly chemical grout for hard cut bite pile retaining wall according to claim 1, wherein: the fly ash is modified fly ash, and the preparation method of the modified fly ash comprises the following steps: dissolving 0.2-0.4 part by weight of silane coupling agent in 10-20 parts by weight of water, then adding 60-80 parts by weight of fly ash, grinding for 10-20h at 25 ℃ in a ball mill, and then drying at 25 ℃ to obtain the modified fly ash.
4. An environmentally friendly chemical grout for the dado of hard cut bite piles according to claim 3, wherein: the mesh range of the fly ash is 300-400 meshes.
5. The environmentally friendly chemical grout for hard cut bite pile retaining wall according to claim 1, wherein: also comprises 1-2 parts of starch by weight.
6. The method for preparing the environmentally friendly chemical grout for the retaining wall of the hard cutting bite pile as claimed in any one of claims 1 to 5, wherein: comprises the following steps of (a) carrying out,
s1: adding 0.8-1.4 parts by weight of soda ash into 600 parts by weight of water, and stirring and dissolving to obtain a mixed solution;
s2: adding 20-30 parts by weight of bentonite and 20-30 parts by weight of fly ash into the mixed solution, stirring for 1-2h, standing for 23-24h, and continuing stirring for 1-2 h;
s3: dissolving 0.1-0.3 part by weight of ferrochrome sodium lignosulfonate, adding into the mixed solution, adding 1-2 parts of lignocellulose and 1-2 parts of paper pulp, and stirring for 1-2 hours to obtain the chemical slurry.
7. The method for preparing the environment-friendly chemical slurry for the hard cutting secant pile retaining wall as claimed in claim 6, is characterized in that: in the step S3, 0.8-1.2 parts by weight of vinyl acetate-ethylene versatate copolymer re-dispersible latex powder and 1-2 parts by weight of starch are also added.
CN202210424207.6A 2022-04-22 2022-04-22 Environment-friendly chemical slurry for hard-cutting secant pile retaining wall and preparation method thereof Pending CN114890719A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386485A (en) * 2008-10-09 2009-03-18 江南大学 Fly ash surface modification method and application in water-proof mortar
CN109867494A (en) * 2019-04-19 2019-06-11 重庆建工第二建设有限公司 A kind of machinery rotary digging pile wall slurrying method
CN109942243A (en) * 2019-04-16 2019-06-28 重庆建工建材物流有限公司 A kind of retaining wall slurry powder based on high calcium high-sulfur cinder of burned coal

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101386485A (en) * 2008-10-09 2009-03-18 江南大学 Fly ash surface modification method and application in water-proof mortar
CN109942243A (en) * 2019-04-16 2019-06-28 重庆建工建材物流有限公司 A kind of retaining wall slurry powder based on high calcium high-sulfur cinder of burned coal
CN109867494A (en) * 2019-04-19 2019-06-11 重庆建工第二建设有限公司 A kind of machinery rotary digging pile wall slurrying method

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Application publication date: 20220812