CN114853437A - Phosphogypsum-based light plastering gypsum for hollow internal mold metal net wall - Google Patents

Phosphogypsum-based light plastering gypsum for hollow internal mold metal net wall Download PDF

Info

Publication number
CN114853437A
CN114853437A CN202210563068.5A CN202210563068A CN114853437A CN 114853437 A CN114853437 A CN 114853437A CN 202210563068 A CN202210563068 A CN 202210563068A CN 114853437 A CN114853437 A CN 114853437A
Authority
CN
China
Prior art keywords
parts
gypsum
phosphogypsum
agent
internal mold
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202210563068.5A
Other languages
Chinese (zh)
Inventor
周世斌
周佳霖
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yunnan Teya Building Materials Technology Co ltd
Original Assignee
Yunnan Teya Building Materials Technology Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yunnan Teya Building Materials Technology Co ltd filed Critical Yunnan Teya Building Materials Technology Co ltd
Priority to CN202210563068.5A priority Critical patent/CN114853437A/en
Publication of CN114853437A publication Critical patent/CN114853437A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/52Sound-insulating materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The phosphogypsum-based light plastering gypsum for the hollow internal mold metal mesh wall comprises, by mass, 50-450 parts of a gypsum high-strength agent, 50-450 parts of a gypsum water-resistant agent, 50-120 parts of sodium bentonite, 50-250 parts of vitrified micro bubbles or 50-200 parts of calcined ceramic particles, 50-200 parts of an anti-sagging agent, 1800 parts of calcined phosphogypsum, 1-8 parts of a thixotropic lubricant, 10-80 parts of hydroxypropyl methyl cellulose, 5-50 parts of an anti-cracking reinforcing agent, 1-30 parts of starch ether and 1-50 parts of an inorganic toughening agent. The plastering gypsum base has the advantages of light weight, high strength, stable and reliable product and low manufacturing cost, can meet the requirements of different strengths, different sound insulation and heat preservation and different regional climates of building design, effectively reduces the weight of the hollow internal mold metal mesh wall body due to light weight, and improves the shock resistance and the heat preservation of the building.

Description

Phosphogypsum-based light plastering gypsum for hollow internal mold metal mesh wall
Technical Field
The invention relates to the technical field of building plastering materials, in particular to a phosphogypsum-based light plastering gypsum for a hollow internal mold metal mesh wall.
Background
The hollow internal mold metal net wall is formed by spraying plastering gypsum on a steel mesh and then plastering, is widely applied to partition walls of high-rise buildings such as airports, schools, hospitals and the like due to good earthquake resistance, and is used in the traditional hollow internal mold metal net wallThe cement mortar is prepared by spraying a metal net, and the weight of each square meter of the net wall reaches 120-140 kilograms, so that the building is weighed too much. For this reason, some manufacturers have tried to reduce the amount of cement used, and have used cement plaster to spray metal mesh, which can improve the shock resistance of the hollow metal mesh partition wall, but because of the heavy weight of the added cement, the amount of cement used on the hollow internal mold metal mesh wall reaches 100kg/m 2, Therefore, the weight bearing capacity of the whole building is greatly increased, and the light effect cannot be achieved; compared with the traditional cement plastering material, the plastering gypsum has the characteristics of light weight, no hollowing cracking, good hygroscopicity, good volume stability, excellent fire resistance and the like and is widely applied, but the traditional plastering gypsum has stronger corrosivity to the metal mesh of the hollow internal mold metal mesh wall and is not easy to be used for the hollow internal mold metal mesh wall.
Phosphogypsum is used as a byproduct in the production of high-concentration phosphorus compound fertilizer and phosphoric acid industry, and is accumulated in a large amount, so that land resources are occupied, and environment and underground water are seriously polluted due to the fact that the phosphogypsum contains a large amount of harmful impurities. However, the phosphogypsum has the advantages of light weight, low cost and the like, and if the phosphogypsum can be fully utilized to manufacture the hollow inner mold metal net wall, a large amount of accumulated phosphogypsum can be consumed to reduce resource waste and environmental pollution, and the hollow inner mold metal net wall with light weight and excellent performance can be provided to meet the requirements of the building market. However, unlike desulfurized gypsum, phosphogypsum has unstable performance, and particularly has low utilization rate due to high impurity content, so that no one can successfully prepare a plastering product for manufacturing a hollow internal mold metal mesh wall by using the phosphogypsum.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the phosphogypsum-based light plastering gypsum for the hollow internal mold metal mesh wall body, which has the advantages of light weight, high strength, stable and reliable product quality and low manufacturing cost, and is used for reducing the weight of the hollow internal mold metal mesh wall body and improving the heat insulation performance of a building.
The purpose of the invention is realized by the following technical scheme:
the phosphogypsum-based light plastering gypsum for the hollow internal mold metal mesh wall comprises, by mass, 50-450 parts of a gypsum high-strength agent, 50-450 parts of a gypsum water-resistant agent, 50-120 parts of sodium bentonite, 50-250 parts of vitrified micro bubbles, 50-200 parts of an anti-sagging agent, 1800 parts of calcined phosphogypsum, 1-8 parts of a thixotropic lubricant, 10-80 parts of hydroxypropyl methyl cellulose, 5-50 parts of an anti-cracking reinforcing agent, 1-30 parts of starch ether and 1-50 parts of an inorganic toughening agent.
The phosphogypsum-based light plastering gypsum for the hollow internal mold metal mesh wall comprises, by mass, 50-450 parts of a gypsum high-strength agent, 50-450 parts of a gypsum water-resistant agent, 50-120 parts of sodium bentonite, 50-200 parts of calcined ceramic particles, 50-200 parts of an anti-sagging agent, 1800 parts of calcined phosphogypsum, 1-8 parts of a thixotropic lubricant, 10-80 parts of hydroxypropyl methyl cellulose, 5-50 parts of an anti-cracking reinforcing agent, 1-30 parts of starch ether and 1-50 parts of an inorganic toughening agent.
Further, the calcined phosphogypsum is calcined building gypsum, the content of CaSO 4.0.5H 2O is more than 60 percent, the breaking strength of 2H is more than or equal to 3MPa, the compressive strength of 2H is more than or equal to 6MPa, and the fineness is 120-200 meshes.
Further, the fineness of the sodium bentonite is 200-300 meshes.
Furthermore, the fineness of the vitrified micro bubbles is 40-200 meshes.
Furthermore, the fineness of the calcined pottery grains is 20-60 meshes.
In the formula of the invention, the gypsum reinforcing agent can improve the strength and the surface hardness of the plastering gypsum. The gypsum water-resistant agent can form a hydrophobic film on the surface of the plastering gypsum to play a role in water resistance, and also has a certain air entraining function, micro-bubbles are formed inside the plastering gypsum to block a pore passage, so that water molecules are prevented from entering the plastering gypsum, and the water resistance is further improved. The thixotropic lubricant can prolong the opening time of the plastering gypsum, improve the construction lubricity, improve the thixotropy, the anti-sagging property and the yield value of the plastering gypsum and reduce the resistance during flowing. The anti-sagging agent can improve the anti-sagging performance of the plastering gypsum. The expanding agent can make the plastering gypsum expand in a certain volume; the sodium bentonite and the phosphogypsum form a grain grading effect, and are filled in the pores of the phosphogypsum and the vitrified micro bubbles, so that the compactness of gypsum plaster is increased, and the strength and the water resistance of the plaster are improved.
The invention has the following advantages:
1. the plaster gypsum of the invention is not added with cement, and the added vitrified micro bubbles effectively reduce the weight of the phosphogypsum-based light heat-preservation plaster gypsum to 50kg/m 3 The light plastering gypsum which is far lower than the national standard is less than or equal to 100kg/m 3 The amount of the hollow internal mold metal net wall is 18-30kg/m 2 The dosage of the exterior wall is 100kg/m 2 And the vitrified micro bubbles are used as lightweight aggregate, so that the flowability and the self-resistance strength of the plastering gypsum are improved, the material shrinkage rate is reduced, the comprehensive performance of the product is improved, the comprehensive production cost is reduced, the water resistance and the construction performance are improved, and the vitrified micro bubbles have certain particle strength due to surface vitrification, strong aging resistance and weather resistance, and excellent heat insulation, fire prevention, sound absorption and other properties.
2. The matching of the gypsum high-strength agent, the gypsum water-resistant agent, the inorganic toughening agent and the starch ether changes that the traditional plastering gypsum can not be used in the hollow internal mold metal net wall body due to poor strength and water resistance; the gelatinization toughening changes the corrosion of the traditional plastering gypsum to the metal mesh, and is the plastering gypsum special for the hollow internal mold metal mesh wall; the calcined ceramic particles added according to the design requirements meet different engineering requirements of strength and moisture retention; the mineral thixotropic lubricant can greatly improve the construction performance of the plastering gypsum and has smoother construction hand feeling.
3. The building gypsum calcined by the industrial byproduct phosphogypsum is used as a raw material, so that solid waste is utilized to the maximum extent, the high-strength agent generates a chemical reaction after the phosphogypsum-based light heat-preservation plastering gypsum is added with water, the activity of the phosphogypsum is greatly excited, and the strength of the phosphogypsum-based light heat-preservation plastering gypsum is improved.
The gypsum high-strength agent, the gypsum water-resistant agent, the sodium bentonite, the glass vitrified micro bubbles, the anti-sagging agent, the thixotropic lubricant, the anti-cracking reinforcing agent, the starch ether, the inorganic toughening agent and the calcined pottery granules are all directly purchased and sold mature products.
Detailed Description
The present invention will be further illustrated with reference to the following examples.
Example 1
The phosphogypsum-based light plastering gypsum for the hollow inner mold metal mesh wall comprises, by mass, 100 parts of a gypsum high-strength agent, 80 parts of a gypsum water-resistant agent, 90 parts of sodium bentonite, 100 parts of vitrified micro bubbles, 60 parts of a sagging prevention agent, 700 parts of phosphorite gypsum powder, 8 parts of a thixotropic lubricant, 70 parts of hydroxypropyl methyl cellulose, 45 parts of an anti-cracking reinforcing agent, 25 parts of starch ether and 30 parts of an inorganic toughening agent.
Example 2
The phosphogypsum-based light plastering gypsum for the hollow inner mold metal mesh wall comprises, by mass, 50 parts of a gypsum high-strength agent, 100 parts of a gypsum water-resistant agent, 60 parts of sodium bentonite, 50 parts of vitrified micro bubbles, 50 parts of an anti-sagging agent, 500 parts of phosphorite gypsum powder, 6 parts of a thixotropic lubricant, 50 parts of hydroxypropyl methyl cellulose, 20 parts of an anti-cracking reinforcing agent, 15 parts of starch ether and 40 parts of an inorganic toughening agent.
Example 3
The phosphogypsum-based light plastering gypsum for the hollow inner mold metal mesh wall comprises, by mass, 90 parts of a gypsum high-strength agent, 120 parts of a gypsum water-resistant agent, 70 parts of sodium bentonite, 50 parts of calcined ceramic particles, 100 parts of an anti-sagging agent, 400 parts of phosphorite gypsum powder, 5 parts of a thixotropic lubricant, 40 parts of hydroxypropyl methyl cellulose, 30 parts of an anti-cracking reinforcing agent, 10 parts of starch ether and 10 parts of an inorganic toughening agent.
Example 4
The phosphogypsum-based light plastering gypsum for the hollow internal mold metal mesh wall comprises, by mass, 150 parts of a gypsum high-strength agent, 120 parts of a gypsum water-resistant agent, 110 parts of sodium bentonite, 200 parts of calcined ceramic particles, 80 parts of an anti-sagging agent, 600 parts of phosphorite gypsum powder, 5 parts of a thixotropic lubricant, 80 parts of hydroxypropyl methyl cellulose, 30 parts of an anti-cracking reinforcing agent, 35 parts of starch ether and 40 parts of an inorganic toughening agent.
The phosphogypsum-based light plastering gypsum for the hollow internal mold metal net wall prepared in the embodiments 1 to 4 meets the requirements of national standard plastering gypsum GBT28627-2012 and relevant standards through performance tests, is light and high in strength, and is low in usage amount per square meter on the hollow internal mold metal net wall, so that the weight of the hollow internal mold metal net wall is reduced, the heat conductivity coefficient is low, and the heat preservation performance of a building is improved.
The raw materials of the building gypsum calcined by the phosphogypsum are wide and easy to obtain, and the formula is adjusted within the proportioning range of the invention according to different requirements of engineering on strength, heat preservation or water resistance to meet the requirements of different regional climates and building designs when actually selected.

Claims (6)

1. The phosphogypsum-based light plastering gypsum for the hollow internal mold metal mesh wall is characterized by comprising, by mass, 50-450 parts of a gypsum high-strength agent, 50-450 parts of a gypsum water-resistant agent, 50-120 parts of sodium bentonite, 50-250 parts of vitrified micro bubbles, 50-200 parts of an anti-sagging agent, 1800 parts of calcined phosphogypsum, 1-8 parts of a thixotropic lubricant, 10-80 parts of hydroxypropyl methyl cellulose, 5-50 parts of an anti-cracking reinforcing agent, 1-30 parts of starch ether and 1-50 parts of an inorganic toughening agent.
2. The phosphogypsum-based light plastering gypsum for the hollow internal mold metal mesh wall is characterized by comprising 50-450 parts of gypsum high-strength agent, 50-450 parts of gypsum water-resistant agent, 50-120 parts of sodium bentonite, 50-200 parts of calcined ceramic particles, 50-200 parts of anti-sagging agent, 1800 parts of calcined phosphogypsum, 1-8 parts of thixotropic lubricant, 10-80 parts of hydroxypropyl methyl cellulose, 5-50 parts of anti-cracking reinforcing agent, 1-30 parts of starch ether and 1-50 parts of inorganic toughening agent by mass.
3. The phosphogypsum-based lightweight plastering gypsum for the hollow internal mold metal net wall according to claim 1 or 2, characterized in that: the calcined phosphogypsum is calcined building gypsum, the content of CaSO4 & 0.5H2O is more than 60%, the rupture strength for 2H is more than or equal to 3MPa, the compressive strength for 2H is more than or equal to 6MPa, and the fineness is 120-mesh and 200-mesh.
4. The phosphogypsum-based lightweight plastering gypsum for the hollow internal mold metal net wall according to claim 1 or 2, characterized in that: the fineness of the sodium bentonite is 200-300 meshes.
5. The phosphogypsum-based light plastering gypsum for the hollow internal mold metal net wall according to claim 1, which is characterized in that: the fineness of the vitrified micro bubbles is 40-200 meshes.
6. The phosphogypsum-based light plastering gypsum for the hollow internal mold metal net wall body according to claim 2, is characterized in that: the fineness of the calcined pottery particles is 20-60 meshes.
CN202210563068.5A 2022-05-23 2022-05-23 Phosphogypsum-based light plastering gypsum for hollow internal mold metal net wall Pending CN114853437A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210563068.5A CN114853437A (en) 2022-05-23 2022-05-23 Phosphogypsum-based light plastering gypsum for hollow internal mold metal net wall

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210563068.5A CN114853437A (en) 2022-05-23 2022-05-23 Phosphogypsum-based light plastering gypsum for hollow internal mold metal net wall

Publications (1)

Publication Number Publication Date
CN114853437A true CN114853437A (en) 2022-08-05

Family

ID=82639600

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210563068.5A Pending CN114853437A (en) 2022-05-23 2022-05-23 Phosphogypsum-based light plastering gypsum for hollow internal mold metal net wall

Country Status (1)

Country Link
CN (1) CN114853437A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109025296A (en) * 2018-08-22 2018-12-18 上海中绿建材有限公司 A kind of lightweight plastering gupsum and facing putty integrated construction technique
CN110451912A (en) * 2019-08-13 2019-11-15 武汉理工大学 A kind of light thermal-insulation water proof type plastering ardealite material
CN110526658A (en) * 2019-06-24 2019-12-03 中建材料技术研究成都有限公司 A kind of spray phosphogypsum light plastering mortar preparation of machine and construction method
CN112624642A (en) * 2020-12-31 2021-04-09 湖北聚海环境科技有限公司 Device for exercising and regenerating phosphogypsum by using high-temperature ceramsite and use method thereof
CN113582651A (en) * 2021-08-13 2021-11-02 江苏蓝圈新材料股份有限公司 Light plastering gypsum mortar with strong bonding force and preparation method thereof
CN114105597A (en) * 2021-12-15 2022-03-01 上海宝冶工程技术有限公司 Lightweight plastering gypsum material
CN114276107A (en) * 2021-12-24 2022-04-05 泰山石膏有限公司 Quick-calcined light plastering gypsum and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109025296A (en) * 2018-08-22 2018-12-18 上海中绿建材有限公司 A kind of lightweight plastering gupsum and facing putty integrated construction technique
CN110526658A (en) * 2019-06-24 2019-12-03 中建材料技术研究成都有限公司 A kind of spray phosphogypsum light plastering mortar preparation of machine and construction method
CN110451912A (en) * 2019-08-13 2019-11-15 武汉理工大学 A kind of light thermal-insulation water proof type plastering ardealite material
CN112624642A (en) * 2020-12-31 2021-04-09 湖北聚海环境科技有限公司 Device for exercising and regenerating phosphogypsum by using high-temperature ceramsite and use method thereof
CN113582651A (en) * 2021-08-13 2021-11-02 江苏蓝圈新材料股份有限公司 Light plastering gypsum mortar with strong bonding force and preparation method thereof
CN114105597A (en) * 2021-12-15 2022-03-01 上海宝冶工程技术有限公司 Lightweight plastering gypsum material
CN114276107A (en) * 2021-12-24 2022-04-05 泰山石膏有限公司 Quick-calcined light plastering gypsum and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
赵云龙: "《石膏干混建材生产及应用技术》", 30 November 2016, 中国建材出版社 *
赵云龙: "《石膏应用技术问答》", 30 September 2016, 中国建材出版社 *

Similar Documents

Publication Publication Date Title
CN103508712B (en) High-performance cast-in-place foam concrete and preparation method thereof
CN100586894C (en) High-performance heat insulating building block and its production process
CN102060460B (en) Inorganic cement capillary crystalline waterproofing agent and production process thereof
WO2013048351A1 (en) Gypsum-based composition for construction material and system
CN101580365B (en) Wall material of polystyrene aeroconcrete
CN104446295A (en) Humid-environment-resistance autoclaved aerated concrete block and preparation method thereof
CN108467246A (en) Mortar is built in a kind of spray of fire-retardant type thermal insulation sound-insulation wall
CN103058619A (en) Mineral powder-doped polymer waterproof mortar and using method thereof
CN103833309A (en) Desulfurized gypsum-based heat-preserving moisture-adjusting plastering gypsum material
CN110776334A (en) Cement-based wallboard with large hollow rate and ultrahigh toughness and preparation method thereof
CN103936378A (en) Phosphogypsum-base foaming concrete
CN113213788A (en) Composite cement with few silicate clinker components and preparation method thereof
CN104119097A (en) Lightweight corrosion-resistant aerated brick and preparation method thereof
CN112225519A (en) Method for improving strength of gypsum building material product
CN114031340A (en) Plastering mortar containing recycled aggregate of waste clay brick
CN101255032B (en) Powder composition
CN114105597A (en) Lightweight plastering gypsum material
CN114057463A (en) Anti-crack gypsum mortar capable of effectively filling cracks or cavities and preparation method thereof
CN113185248A (en) Lightweight plastering gypsum and preparation method thereof
CN101811846B (en) Polymer vitrified microsphere building heat-insulating mortar
CN113548854A (en) Concrete light energy-saving composite wallboard and preparation method thereof
CN104193240B (en) Corrosion-resistant aerated bricks of a kind of cracking resistance and preparation method thereof
CN112811870A (en) Concrete wall material blended with iron tailings, fly ash and polystyrene and preparation method thereof
CN110304882B (en) Phosphogypsum-based polymer iron tailing sand concrete and preparation method thereof
CN114853437A (en) Phosphogypsum-based light plastering gypsum for hollow internal mold metal net wall

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20220805