CN114849678A - Sulfur-containing saturated activated carbon desorption regeneration system - Google Patents
Sulfur-containing saturated activated carbon desorption regeneration system Download PDFInfo
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- CN114849678A CN114849678A CN202210446011.7A CN202210446011A CN114849678A CN 114849678 A CN114849678 A CN 114849678A CN 202210446011 A CN202210446011 A CN 202210446011A CN 114849678 A CN114849678 A CN 114849678A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 108
- 238000003795 desorption Methods 0.000 title claims abstract description 58
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 48
- 239000011593 sulfur Substances 0.000 title claims abstract description 48
- 238000011069 regeneration method Methods 0.000 title claims abstract description 28
- 230000008929 regeneration Effects 0.000 title claims abstract description 23
- 238000000746 purification Methods 0.000 claims abstract description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000002912 waste gas Substances 0.000 claims abstract description 27
- 239000007789 gas Substances 0.000 claims abstract description 13
- 238000010521 absorption reaction Methods 0.000 claims abstract description 12
- 238000005086 pumping Methods 0.000 claims abstract description 8
- 238000000605 extraction Methods 0.000 claims abstract description 5
- 229910001873 dinitrogen Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 13
- 238000010438 heat treatment Methods 0.000 abstract description 10
- 229910052799 carbon Inorganic materials 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 abstract description 5
- 239000001301 oxygen Substances 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 238000011084 recovery Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 10
- 239000002156 adsorbate Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000012855 volatile organic compound Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009279 wet oxidation reaction Methods 0.000 description 1
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/3416—Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/34—Regenerating or reactivating
- B01J20/345—Regenerating or reactivating using a particular desorbing compound or mixture
- B01J20/3458—Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
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- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Treating Waste Gases (AREA)
Abstract
The invention provides a desorption regeneration system for sulfur-containing saturated activated carbon, which comprises a desorption tank, an air extraction pipeline, an air inlet pipeline, a high-temperature maintaining pipeline, a condenser, a sulfur liquefaction collector, a first waste gas purification pipeline, an activated carbon tank, a second waste gas purification pipeline and an absorption tank, wherein the absorption tank is arranged in the desorption tank; one end of the air pumping pipeline is connected with the desorption tank, and the other end of the air pumping pipeline is connected with the vacuum pump; the desorption tank is also connected with the air outlet end of the air inlet pipeline, and the air inlet end of the air inlet pipeline is connected with an air source pipeline; and the air inlet pipeline is provided with a heater. According to the invention, the actual temperature of the carbon layer of the saturated activated carbon reaches 500 ℃ or higher through vacuum low-oxygen nitrogen heating, the recovery rate of the saturated activated carbon can be effectively improved, residual non-condensable sulfur vapor is absorbed by the sulfur dissolving agent after secondary adsorption of the activated carbon, the tail gas directly reaches the standard and is discharged, secondary pollution can be avoided, and the requirements of environmental protection are met.
Description
Technical Field
The invention relates to the technical field of activated carbon regeneration, in particular to a desorption regeneration system for sulfur-containing saturated activated carbon.
Background
The active carbon is a product which consumes a large amount of resources in the environmental protection industry, has very good and effective adsorption removal effect on most volatile organic compounds, has stable removal rate before saturation, and is widely used in the market. At present, most of enterprises adopting activated carbon to adsorb and remove VOC have the defects that most of activated carbon is treated as solid waste after being saturated, the activated carbon is not recycled, great resource waste is caused, and other environmental protection problems are caused. Because the manufacturing of the activated carbon can also generate serious environmental protection problems, the regeneration of the saturated activated carbon is particularly important, the secondary pollution can be avoided by recycling, and the cost for purchasing the activated carbon again is reduced. The regeneration process is divided into chemical method, biological regeneration method, wet oxidation method, electrolytic oxidation method, heating regeneration method and the like. The heating regeneration method is the regeneration method with the longest development history and the most extensive application, and the heating regeneration process is to make the adsorbate desorbed at high temperature by utilizing the characteristic that the adsorbate in the adsorption saturated activated carbon can be desorbed from the activated carbon pores at high temperature, thereby opening the originally blocked pores of the activated carbon and recovering the adsorption performance of the activated carbon. After high temperature is applied, molecular vibration energy is increased, the adsorption equilibrium relationship is changed, and adsorbate molecules are separated from the surface of the activated carbon and enter a gas phase. Heating regeneration is a mainstream regeneration method because it can decompose various adsorbates, and thus has versatility and thorough regeneration.
The saturated activated carbon heating regeneration desorption system used in the market at present adopts aerobic low-temperature desorption, the temperature of a carbon layer is generally about 120 ℃, most of the saturated activated carbon heating regeneration desorption system is still at a heating temperature rather than the temperature of the carbon layer in actual use, and the temperature of the carbon layer is not yet 120 ℃, so that the desorption effect is poor, and the activated carbon can be rapidly invalid in a plurality of cycles. And when the existing desorption system desorbs the active carbon containing sulfur, the sulfur is often unqualified to be treated, and the secondary pollution is easily caused when the active carbon is discharged into the air.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide a desorption regeneration system for sulfur-containing saturated activated carbon, wherein the desorption process is safe, energy-saving and efficient by heating in vacuum and low-oxygen nitrogen, residual non-condensable sulfur steam is absorbed by a sulfur dissolving agent after being secondarily adsorbed by activated carbon, tail gas is directly discharged after reaching the standard, and secondary pollution can be avoided.
In order to achieve the purpose, the invention adopts the following technical scheme:
a desorption regeneration system for sulfur-containing saturated activated carbon comprises a desorption tank, an air extraction pipeline, an air inlet pipeline, a high-temperature maintaining pipeline, a condenser, a sulfur liquefaction collector, a first waste gas purification pipeline, an activated carbon tank, a second waste gas purification pipeline and an absorption tank;
one end of the air pumping pipeline is connected with the desorption tank, and the other end of the air pumping pipeline is connected with the vacuum pump;
the desorption tank is also connected with the air outlet end of the air inlet pipeline, and the air inlet end of the air inlet pipeline is connected with an air source pipeline;
a heater is arranged on the air inlet pipeline;
the desorption tank is also connected with the air inlet end of the high-temperature maintaining pipeline, and the air outlet end of the high-temperature maintaining pipeline is connected with the inlet of the condenser;
the outlet of the condenser is connected with the sulfur liquefaction collector;
the sulfur liquefaction collector is also connected with the air inlet end of the first waste gas purification pipeline;
the air outlet end of the first waste gas purification pipeline is connected with the activated carbon tank;
the activated carbon tank is also connected with the air inlet end of the second waste gas purification pipeline;
and the air outlet end of the second waste gas purification pipeline is connected with the absorption tank.
Preferably, the desorption tank, the sulfur liquefaction collector and the activated carbon tank are all provided with drain valves.
Preferably, the gas source pipeline comprises a nitrogen gas source pipeline, and a nitrogen gas valve is arranged on the nitrogen gas source pipeline.
Preferably, a vacuum valve is arranged on the air exhaust pipeline.
Preferably, the first exhaust gas purification pipeline and the second exhaust gas purification pipeline are both provided with exhaust valves
The invention has the beneficial effects that: the desorption regeneration system of the sulfur-containing saturated activated carbon of the invention heats the saturated activated carbon layer to reach the actual temperature of 500 ℃ or higher by vacuum low-oxygen nitrogen, continuously introduces high-temperature inert gas nitrogen in the whole process, keeps micro-positive pressure in the system all the time, ensures that the desorption work is safely and efficiently carried out, and has the advantages of safety, energy conservation, high efficiency and the like.
The desorption regeneration system for the sulfur-containing saturated activated carbon can effectively improve the recovery rate of the saturated activated carbon, residual non-condensable sulfur steam is absorbed by a sulfur dissolving agent after secondary absorption of the activated carbon, tail gas is directly discharged up to the standard, secondary pollution can be avoided, and the requirements of environmental protection are met.
Drawings
Fig. 1 is a schematic structural view of the present invention, wherein the direction of arrows indicates the direction of medium flow.
In the figure, 1-desorption tank, 2-air suction line, 21-vacuum pump, 22-vacuum valve, 3-air inlet line, 31-heater, 32-nitrogen source line, 33-nitrogen valve, 4-high temperature maintaining line, 5-condenser, 6-sulfur liquefaction collector, 7-first waste gas purification line, 8-activated carbon tank, 9-second waste gas purification line, 10-absorption tank, 11-liquid discharge valve, 12-exhaust valve.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the accompanying drawings and embodiments, and it is to be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
As shown in fig. 1: a desorption regeneration system for sulfur-containing saturated activated carbon comprises a desorption tank 1, an air extraction pipeline 2, an air inlet pipeline 3, a high-temperature maintaining pipeline 4, a condenser 5, a sulfur liquefaction collector 6, a first waste gas purification pipeline 7, an activated carbon tank 8, a second waste gas purification pipeline 9 and an absorption tank 10;
one end of the air pumping pipeline 2 is connected with the desorption tank 1, the other end of the air pumping pipeline is connected with a vacuum pump 21, and the vacuum pump 21 is used for vacuumizing the desorption tank 1;
the desorption tank 1 is also connected with the air outlet end of the air inlet pipeline 3, and the air inlet end of the air inlet pipeline 3 is connected with an air source pipeline;
the air inlet pipeline 3 is provided with a heater 31 for heating an introduced air source;
the desorption tank 1 is also connected with the air inlet end of the high-temperature maintaining pipeline 4, and the air outlet end of the high-temperature maintaining pipeline 4 is connected with the inlet of the condenser 5;
the outlet of the condenser 5 is connected with the sulfur liquefaction collector 6;
the sulfur liquefaction collector 6 is also connected with the air inlet end of the first waste gas purification pipeline 7;
the air outlet end of the first waste gas purification pipeline 7 is connected with the activated carbon tank 8;
the activated carbon tank 8 is also connected with the air inlet end of the second exhaust gas purification pipeline 9;
the outlet end of the second exhaust gas purification pipeline 9 is connected with the absorption tank 10.
Further, the desorption tank 1, the sulfur liquefaction collector 6 and the activated carbon tank 8 are all provided with a liquid discharge valve 11 for discharging liquid in the container; the gas source pipeline comprises a nitrogen source pipeline 32, and a nitrogen valve 33 is arranged on the nitrogen source pipeline 32; a vacuum valve 22 is arranged on the air suction pipeline 2; the first exhaust gas purification pipeline 7 and the second exhaust gas purification pipeline 9 are both provided with exhaust valves 12.
The working principle of the invention is as follows: the desorption regeneration system of the sulfur-containing saturated activated carbon comprises the following concrete implementation processes:
(1) desorption and desorption operation: loading the used sulfur-containing saturated activated carbon into a desorption tank 1, closing the desorption tank 1, starting a vacuum pump 21, opening a vacuum valve 22, and carrying out deoxidization treatment on the activated carbon; when the oxygen content in the desorption tank 1 reaches the desorption requirement (the oxygen content is lower than 5%), the vacuum pump 21 and the vacuum valve 22 are closed;
opening a nitrogen valve 33, opening exhaust valves 12 on the first waste gas purification pipeline 7 and the second waste gas purification pipeline 9, starting a heater 31, continuously injecting heated nitrogen into the desorption tank 1, keeping the desorption tank 1 at micro-positive pressure all the time, continuously increasing the temperature of the activated carbon, gasifying sulfur when the temperature is more than or equal to 425 ℃, continuously discharging the gasified sulfur by continuously introduced inert gas nitrogen, entering a high-temperature maintaining pipeline 4, then passing through a condenser 5, cooling and liquefying, and then flowing into a sulfur liquefaction collector 6; the sulfur liquefaction collector 6 is a constant temperature container with the temperature of 120-160 ℃, so when sulfur steam flows into the condenser 5, the temperature is reduced to below 160 ℃ to be liquefied, and then the sulfur steam flows into the sulfur liquefaction collector 6 to be collected; the temperature in the sulfur liquefaction collector 6 is always kept at 160 ℃ below zero, so that the liquefied sulfur can be prevented from being solidified;
a small amount of sulfur vapor which is not liquefied enters an activated carbon tank 8 through a first waste gas purification pipeline 7 to be secondarily adsorbed, and in the process, residual waste gas enters an absorption tank 10 through a second waste gas purification pipeline 9 to be dissolved by a solvent in the tank and then is discharged in a qualified manner; a sulfur dissolving agent or caustic soda is stored in the absorption tank 10;
by the desorption and desorption operation, when the temperature of the activated carbon layer reaches the set temperature (500 ℃), desorption and desorption are completed.
(2) Cooling activated carbon: after desorption, the heater 31 is closed, nitrogen continues to be continuously introduced, and the activated carbon is naturally cooled to the specified temperature after a period of time; the residual water vapor molecules are taken away while the activated carbon layer is cooled, so that the optimal adsorption state of the activated carbon/activated carbon particles is ensured.
(3) The dried activated carbon is taken out of the desorption tank 1, and then the saturated activated carbon containing sulfur is loaded for the next desorption process.
Finally, it should be noted that the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, and although the present invention has been described in detail with reference to examples, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made on the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, which should be covered by the claims of the present invention.
Claims (5)
1. A desorption regeneration system for sulfur-containing saturated activated carbon is characterized in that: the device comprises a desorption tank (1), an air extraction pipeline (2), an air inlet pipeline (3), a high-temperature maintaining pipeline (4), a condenser (5), a sulfur liquefaction collector (6), a first waste gas purification pipeline (7), an activated carbon tank (8), a second waste gas purification pipeline (9) and an absorption tank (10);
one end of the air pumping pipeline (2) is connected with the desorption tank (1), and the other end of the air pumping pipeline is connected with a vacuum pump (21);
the desorption tank (1) is also connected with the air outlet end of the air inlet pipeline (3), and the air inlet end of the air inlet pipeline (3) is connected with an air source pipeline;
a heater (31) is arranged on the air inlet pipeline (3);
the desorption tank (1) is also connected with the air inlet end of the high-temperature maintaining pipeline (4), and the air outlet end of the high-temperature maintaining pipeline (4) is connected with the inlet of the condenser (5);
the outlet of the condenser (5) is connected with the sulfur liquefaction collector (6);
the sulfur liquefaction collector (6) is also connected with the air inlet end of the first waste gas purification pipeline (7);
the air outlet end of the first waste gas purification pipeline (7) is connected with the activated carbon tank (8);
the activated carbon tank (8) is also connected with the air inlet end of the second waste gas purification pipeline (9);
the air outlet end of the second waste gas purification pipeline (9) is connected with the absorption tank (10).
2. The desorption regeneration system for sulfur-containing saturated activated carbon according to claim 1, wherein: and the desorption tank (1), the sulfur liquefaction collector (6) and the activated carbon tank (8) are all provided with a liquid discharge valve (11).
3. The desorption regeneration system for sulfur-containing saturated activated carbon according to claim 1, wherein: the gas source pipeline comprises a nitrogen gas source pipeline (32), and a nitrogen gas valve (33) is arranged on the nitrogen gas source pipeline (32).
4. The desorption regeneration system for sulfur-containing saturated activated carbon according to claim 1, wherein: and a vacuum valve (22) is arranged on the air extraction pipeline (2).
5. The desorption regeneration system for sulfur-containing saturated activated carbon according to claim 1, wherein: and exhaust valves (12) are arranged on the first waste gas purification pipeline (7) and the second waste gas purification pipeline (9).
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CN202210446011.7A CN114849678A (en) | 2022-04-26 | 2022-04-26 | Sulfur-containing saturated activated carbon desorption regeneration system |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3634028A (en) * | 1966-10-27 | 1972-01-11 | Metallgesellschaft Ag | Process for removing sulfur from gases |
JP2003210933A (en) * | 2001-11-13 | 2003-07-29 | Ngk Insulators Ltd | Method for removing hydrogen sulfide |
CN104958995A (en) * | 2015-06-23 | 2015-10-07 | 江苏中远环保科技有限公司 | Technology and device for treating organic waste gas with activated carbon by means of nitrogen heating and vacuum desorption |
CN204816149U (en) * | 2015-06-23 | 2015-12-02 | 江苏中远环保科技有限公司 | Active carbon organic waste gas that nitrogen gas adds thermal vacuum desorption administers device |
CN106178813A (en) * | 2016-07-08 | 2016-12-07 | 中山市道享节能技术服务有限公司 | A kind of coal high-efficiency clean utilization system based on activated coke dry FGD process technology |
KR102201983B1 (en) * | 2019-11-06 | 2021-01-12 | (주)윈텍글로비스 | Equipment for regeneration activated carbon with superheated steam and low temperature air |
CN112791717A (en) * | 2020-12-08 | 2021-05-14 | 浙江宜可欧环保科技有限公司 | Continuous activation and regeneration method for waste activated carbon |
CN217341409U (en) * | 2022-04-26 | 2022-09-02 | 无锡市赢江环保科技有限公司 | Sulfur-containing saturated activated carbon desorption regeneration system |
-
2022
- 2022-04-26 CN CN202210446011.7A patent/CN114849678A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3634028A (en) * | 1966-10-27 | 1972-01-11 | Metallgesellschaft Ag | Process for removing sulfur from gases |
JP2003210933A (en) * | 2001-11-13 | 2003-07-29 | Ngk Insulators Ltd | Method for removing hydrogen sulfide |
CN104958995A (en) * | 2015-06-23 | 2015-10-07 | 江苏中远环保科技有限公司 | Technology and device for treating organic waste gas with activated carbon by means of nitrogen heating and vacuum desorption |
CN204816149U (en) * | 2015-06-23 | 2015-12-02 | 江苏中远环保科技有限公司 | Active carbon organic waste gas that nitrogen gas adds thermal vacuum desorption administers device |
CN106178813A (en) * | 2016-07-08 | 2016-12-07 | 中山市道享节能技术服务有限公司 | A kind of coal high-efficiency clean utilization system based on activated coke dry FGD process technology |
KR102201983B1 (en) * | 2019-11-06 | 2021-01-12 | (주)윈텍글로비스 | Equipment for regeneration activated carbon with superheated steam and low temperature air |
CN112791717A (en) * | 2020-12-08 | 2021-05-14 | 浙江宜可欧环保科技有限公司 | Continuous activation and regeneration method for waste activated carbon |
CN217341409U (en) * | 2022-04-26 | 2022-09-02 | 无锡市赢江环保科技有限公司 | Sulfur-containing saturated activated carbon desorption regeneration system |
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