CN114846165A - High-strength steel sheet having excellent workability and method for producing same - Google Patents
High-strength steel sheet having excellent workability and method for producing same Download PDFInfo
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- CN114846165A CN114846165A CN202080088513.6A CN202080088513A CN114846165A CN 114846165 A CN114846165 A CN 114846165A CN 202080088513 A CN202080088513 A CN 202080088513A CN 114846165 A CN114846165 A CN 114846165A
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- steel sheet
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 144
- 239000010959 steel Substances 0.000 title claims abstract description 144
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 26
- 238000005452 bending Methods 0.000 claims abstract description 52
- 238000000034 method Methods 0.000 claims abstract description 22
- 229910001566 austenite Inorganic materials 0.000 claims description 87
- 238000001816 cooling Methods 0.000 claims description 86
- 230000000717 retained effect Effects 0.000 claims description 53
- 229910000734 martensite Inorganic materials 0.000 claims description 51
- 238000010438 heat treatment Methods 0.000 claims description 48
- 229910052710 silicon Inorganic materials 0.000 claims description 45
- 229910052782 aluminium Inorganic materials 0.000 claims description 44
- 229910000859 α-Fe Inorganic materials 0.000 claims description 41
- 229910001563 bainite Inorganic materials 0.000 claims description 27
- 238000005098 hot rolling Methods 0.000 claims description 22
- 229910052748 manganese Inorganic materials 0.000 claims description 19
- 238000000137 annealing Methods 0.000 claims description 18
- 239000010960 cold rolled steel Substances 0.000 claims description 16
- 238000005097 cold rolling Methods 0.000 claims description 15
- 239000012535 impurity Substances 0.000 claims description 13
- 238000005096 rolling process Methods 0.000 claims description 13
- 229910052759 nickel Inorganic materials 0.000 claims description 10
- 229910052735 hafnium Inorganic materials 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 229910052750 molybdenum Inorganic materials 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 9
- 229910052698 phosphorus Inorganic materials 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 229910052718 tin Inorganic materials 0.000 claims description 9
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 31
- 239000010703 silicon Substances 0.000 description 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 30
- 239000011572 manganese Substances 0.000 description 30
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 21
- 230000000694 effects Effects 0.000 description 19
- 229910052761 rare earth metal Inorganic materials 0.000 description 15
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 14
- 229910052799 carbon Inorganic materials 0.000 description 14
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 13
- 239000010949 copper Substances 0.000 description 13
- 239000011777 magnesium Substances 0.000 description 13
- 239000010955 niobium Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 12
- 239000010936 titanium Substances 0.000 description 12
- 239000011575 calcium Substances 0.000 description 11
- 239000011651 chromium Substances 0.000 description 11
- 229910052727 yttrium Inorganic materials 0.000 description 11
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 11
- 229910045601 alloy Inorganic materials 0.000 description 9
- 239000000956 alloy Substances 0.000 description 9
- 238000005554 pickling Methods 0.000 description 8
- 230000009466 transformation Effects 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 6
- 229910052802 copper Inorganic materials 0.000 description 6
- 238000007747 plating Methods 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 229910052787 antimony Inorganic materials 0.000 description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 229910052791 calcium Inorganic materials 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000010941 cobalt Substances 0.000 description 5
- 229910017052 cobalt Inorganic materials 0.000 description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 5
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 5
- 229910052719 titanium Inorganic materials 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 229910001562 pearlite Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910001567 cementite Inorganic materials 0.000 description 2
- 230000001186 cumulative effect Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 239000013585 weight reducing agent Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 229910000794 TRIP steel Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000005269 aluminizing Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229910001568 polygonal ferrite Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 229910052706 scandium Inorganic materials 0.000 description 1
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 description 1
- 238000010583 slow cooling Methods 0.000 description 1
- 210000004872 soft tissue Anatomy 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/22—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
- B21B1/24—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D6/00—Heat treatment of ferrous alloys
- C21D6/008—Heat treatment of ferrous alloys containing Si
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
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- C—CHEMISTRY; METALLURGY
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0263—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment following hot rolling
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- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
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- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/008—Ferrous alloys, e.g. steel alloys containing tin
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/22—Ferrous alloys, e.g. steel alloys containing chromium with molybdenum or tungsten
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/34—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of silicon
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/001—Austenite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/002—Bainite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
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Abstract
The present invention relates to a steel sheet that can be used for automobile parts and the like, and to a steel sheet that has an excellent balance between strength and ductility, an excellent balance between strength and hole expandability, and excellent bending workability, and a method for manufacturing the same.
Description
Technical Field
The present invention relates to a steel sheet that can be used for automobile parts and the like, and to a steel sheet having high strength characteristics and excellent workability, and a method for manufacturing the same.
Background
In recent years, in order to protect the global environment, the automobile industry is paying attention to a method for ensuring the stability of passengers while achieving weight reduction of materials. In order to satisfy such requirements for stability and weight reduction, the use of high-strength steel sheets is sharply increasing. In general, it is known that the workability of a steel sheet decreases as the strength of the steel sheet increases. Therefore, in steel sheets for automobile parts, steel sheets having high strength characteristics and excellent workability such as ductility, bending workability, and hole expansibility are required.
As a technique for improving workability of a steel sheet, patent documents 1 and 2 disclose a method using tempered martensite. Since tempered martensite produced by tempering hard martensite is soft martensite, the tempered martensite has a strength different from that of existing untempered martensite (fresh martensite). Therefore, workability can be increased when the formation of tempered martensite is suppressed by the formation of new martensite.
However, in the techniques disclosed in patent documents 1 and 2, the balance (TS × El) between the tensile strength and the elongation cannot satisfy 22000 MPa% or more, which means that it is difficult to secure a steel sheet excellent in both strength and ductility.
In order to obtain high strength and excellent workability of steel sheets for automobile parts, Transformation Induced Plasticity (TRIP) steels have been developed which utilize Transformation Induced Plasticity of retained austenite. Patent document 3 discloses a TRIP steel excellent in strength and workability.
Patent document 3 attempts to improve ductility and workability by including polygonal ferrite, retained austenite, and martensite, but it is known that high strength cannot be ensured because the main phase is bainite, and the balance (TS × El) between tensile strength and elongation cannot satisfy 22000 Mpa% or more.
That is, there is a demand for a steel sheet having high strength and excellent workability such as ductility, bending workability, and hole expansibility.
(Prior art document)
(patent document 1) Korean laid-open patent publication No. 10-2006-0118602
(patent document 2) Japanese laid-open patent publication No. 2009-019258
(patent document 3) Korean laid-open patent publication No. 10-2014-0012167
Disclosure of Invention
Technical problem to be solved by the invention
According to an aspect of the present invention, it is possible to provide a high-strength steel sheet having excellent ductility, bending workability, and hole expansibility by optimizing the composition and microstructure of the steel sheet, and a method for manufacturing the same.
The technical problem of the present invention is not limited to the above. Additional technical problems of the present invention are described throughout the specification, and those skilled in the art can easily understand the additional technical problems of the present invention from the contents described in the specification of the present invention.
Means for solving the problems
The high-strength steel sheet excellent in workability according to one aspect of the present invention may include, in wt%: c: 0.25-0.75%, Si: 4.0% or less, Mn: 0.9-5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: 0.03% or less, and the balance of Fe and unavoidable impurities, and the fine structure may include tempered martensite, bainite, residual austenite, ferrite, and an unavoidable structure, and may satisfy the following [ relational formula 1] and [ relational formula 2 ].
[ relational expression 1]
1.1≤[Si+Al] F /[Si+Al] γ ≤3.0
In the above relational expression 1, [ Si + Al] F Is the average total content (wt%) of Si and Al contained in the ferrite, [ Si + Al%] γ Is the average total content (wt%) of Si and Al contained in the retained austenite.
[ relational expression 2]
T(γ)/V(γ)≥0.1
In the relational expression 2, T (γ) is a fraction (vol%) of tempered residual austenite of the steel sheet, and V (γ) is a fraction (vol%) of residual austenite of the steel sheet.
The steel sheet may further include any one or more of the following (1) to (9).
(1) Ti: 0-0.5%, Nb: 0-0.5% and V: 0-0.5% of one or more of,
(2) cr: 0-3.0% and Mo: 0-3.0% of one or more of,
(3) cu: 0-4.5% and Ni: 0-4.5% of one or more of,
(4)B：0-0.005％，
(5) ca: 0-0.05%, REM except Y: 0-0.05% and Mg: 0-0.05% of one or more of,
(6) w: 0-0.5% and Zr: 0-0.5% of one or more of,
(7) sb: 0-0.5% and Sn: 0-0.5% of one or more of,
(8) y: 0-0.2% and Hf: 0-0.2% of one or more of,
(9)Co：0-1.5％。
the total content of the Si and the Al (Si + Al) may be 1.0 to 6.0 wt%.
The fine structure of the steel sheet may include 30-70 vol% of tempered martensite, 10-45 vol% of bainite, 10-40 vol% of retained austenite, and 3-20 vol% of ferrite.
The high-strength steel sheet having excellent workability is represented by the following [ relational expression 3]]Balance of tensile Strength and elongation (B) T·E ) 22000 (MPa%) or more, and is represented by the following relational expression 4]Balance of tensile Strength and hole expansion ratio (B) T·H ) Is 7 x 10 6 (MPa 2 ％ 1/2 ) From the above, the following [ relationshipFormula 5]Indicated bending ratio (B) R ) Is 0.5 to 3.0.
[ relational expression 3]
B T·E Not [ tensile strength (TS, MPa) ]]Elongation [ El,% ]]
[ relational expression 4]
B T·H Not [ tensile strength (TS, MPa) ]] 2 [ hole expansion ratio (HER%)] 1/2
[ relational expression 5]
B R ＝R/t
In the relational expression 5, R represents the minimum bending radius (mm) at which no crack is generated after the 90 DEG bending test, and t represents the thickness (mm) of the steel plate.
The method of manufacturing a high-strength steel sheet excellent in workability according to another aspect of the present invention may include the steps of: providing a cold rolled steel sheet comprising, in weight%: c: 0.25-0.75%, Si: 4.0% or less, Mn: 0.9-5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: less than 0.03%, and the balance of Fe and inevitable impurities; heating the cold-rolled steel sheet to a temperature range of Ac1 or more and less than Ac3 (primary heating), and holding for 50 seconds or more (primary holding); cooling (primary cooling) at an average cooling rate of 1 ℃/second or more to a temperature range of 600-850 ℃ (primary cooling termination temperature); cooling (secondary cooling) to a temperature range of 300-500 ℃ at an average cooling rate of 2 ℃/second or more, and keeping for 5 seconds or more (secondary keeping) within the temperature range; cooling (tertiary cooling) to a temperature range of 100-300 ℃ (secondary cooling termination temperature) at an average cooling rate of 2 ℃/second or higher; heating to the temperature range of 300-500 ℃ (secondary heating), and keeping the temperature range for more than 50 seconds (three times of keeping); and cooling to ambient temperature (four cools).
The cold-rolled steel sheet may further include any one or more of the following (1) to (9).
(1) Ti: 0-0.5%, Nb: 0-0.5% and V: 0-0.5% of one or more of,
(2) cr: 0-3.0% and Mo: 0-3.0% of one or more of,
(3) cu: 0-4.5% and Ni: 0-4.5% of one or more of,
(4)B：0-0.005％，
(5) ca: 0-0.05%, REM except Y: 0-0.05% and Mg: 0-0.05% of one or more of,
(6) w: 0-0.5% and Zr: 0-0.5% of one or more of,
(7) sb: 0-0.5% and Sn: 0-0.5% of one or more,
(8) y: 0-0.2% and Hf: 0-0.2% of one or more of,
(9)Co：0-1.5％。
the total content of the Si and the Al (Si + Al) contained in the cold-rolled steel sheet may be 1.0 to 6.0 wt%.
The cold rolled steel sheet may be provided by: heating the steel billet to 1000-1350 ℃; performing hot finish rolling within the temperature range of 800-; rolling the hot rolled steel plate within the temperature range of 300-600 ℃; carrying out hot rolling annealing heat treatment on the coiled steel plate within the temperature range of 650-850 ℃ for 600-1700 seconds; and cold rolling the hot-rolled annealed steel sheet at a reduction ratio of 30 to 90%.
The cooling rate of the primary cooling (Vc1) and the cooling rate of the secondary cooling (Vc2) may satisfy the relationship Vc1< Vc 2.
Effects of the invention
According to a preferred aspect of the present invention, it is possible to provide a steel sheet having excellent strength and workability such as ductility, bending workability, and hole expansibility, and thus being particularly suitable for use as a steel sheet for automobile parts.
Best mode for carrying out the invention
The present invention relates to a high-strength steel sheet having excellent workability and a method for producing the same, and preferred embodiments of the present invention will be described below. The embodiments of the present invention may be modified into various forms and should not be construed as limiting the scope of the present invention to the embodiments described below. This embodiment is provided to explain the present invention in more detail to those skilled in the art.
The present inventors have recognized that in transformation induced plasticity (TRIP) steel including bainite, tempered martensite, retained austenite, and ferrite, when stabilization of the retained austenite is achieved and the ratio of specific components included in the retained austenite and ferrite is controlled within a certain range, the difference in the inter-phase hardness between the retained austenite and ferrite is reduced, so that workability and strength of a steel sheet can be ensured at the same time. The present inventors have studied this and have devised a method for improving the ductility and workability of high-strength steel, and have completed the present invention.
Hereinafter, a high-strength steel sheet having excellent workability according to one aspect of the present invention will be described in detail.
The high-strength steel sheet excellent in workability according to one aspect of the present invention may include, in wt%: c: 0.25-0.75%, Si: 4.0% or less, Mn: 0.9-5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: 0.03% or less, and the balance of Fe and unavoidable impurities, and the fine structure may include tempered martensite, bainite, residual austenite, ferrite, and an unavoidable structure, and may satisfy the following [ relational formula 1] and [ relational formula 2 ].
[ relational expression 1]
1.1≤[Si+Al] F /[Si+Al] γ ≤3.0
In the above relational expression 1, [ Si + Al] F Is the average total content (wt%) of Si and Al contained in the ferrite, [ Si + Al%] γ Is the average total content (wt%) of Si and Al contained in the retained austenite.
[ relational expression 2]
T(γ)/V(γ)≥0.1
In the relational expression 2, T (γ) is a fraction (vol%) of tempered residual austenite of the steel sheet, and V (γ) is a fraction (vol%) of residual austenite of the steel sheet.
The steel composition of the present invention will be described in more detail below. Hereinafter, unless otherwise specified,% indicating the content of each element is based on weight.
The high-strength steel sheet excellent in workability according to one aspect of the present invention includes, in weight%: c: 0.25-0.75%, Si: 4.0% or less, Mn: 0.9-5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: less than 0.03%, and the balance Fe and inevitable impurities. Further, the steel sheet may further include: ti: 0.5% or less (including 0%), Nb: 0.5% or less (including 0%), V: 0.5% or less (including 0%), Cr: 3.0% or less (including 0%), Mo: 3.0% or less (including 0%), Cu: 4.5% or less (including 0%), Ni: 4.5% or less (including 0%), B: 0.005% or less (including 0%), Ca: 0.05% or less (including 0%), REM excluding Y: 0.05% or less (including 0%), Mg: 0.05% or less (including 0%), W: 0.5% or less (including 0%), Zr: 0.5% or less (including 0%), Sb: 0.5% or less (including 0%), Sn: 0.5% or less (including 0%), Y: 0.2% or less (including 0%), Hf: 0.2% or less (including 0%), Co: 1.5% or less (including 0%). And, the total content of Si and Al (Si + Al) may be 1.0-6.0%.
Carbon (C): 0.25-0.75%
Carbon (C) is an element essential to ensure the strength of the steel sheet, and is an element that stabilizes retained austenite contributing to improvement in ductility of the steel sheet. Therefore, in order to achieve the above-described effects, carbon (C) may be contained in an amount of 0.25% or more in the present invention. The preferable carbon (C) content may exceed 0.25%, and may be 0.27% or more, 0.30% or more. The more preferable carbon (C) content may be 0.31% or more. On the other hand, when the carbon (C) content exceeds a certain level, cold rolling may be difficult due to an excessive increase in strength. Therefore, in the present invention, the upper limit of the carbon (C) content may be limited to 0.75%. The carbon (C) content may be 0.70% or less, and more preferably 0.67% or less.
Silicon (Si): below 4.0% (except 0%)
Silicon (Si) is an element that contributes to strength enhancement by solid-solution strengthening, and is also an element that improves workability by strengthening ferrite and making the structure uniform. Silicon (Si) is an element that contributes to the formation of residual austenite by suppressing the precipitation of cementite. Therefore, in order to achieve the above-described effects, silicon (Si) must be added in the present invention. The preferable content of silicon (Si) may be 0.02% or more, and the more preferable content of silicon (Si) may be 0.05% or more. However, when the content of silicon (Si) exceeds a certain level, plating defects such as unplating are caused in the plating process and weldability of the steel sheet may be lowered, so the upper limit of the content of silicon (Si) may be limited to 4.0% in the present invention. The upper limit of the preferable silicon (Si) content may be 3.8%, and the upper limit of the more preferable silicon (Si) content may be 3.5%.
Aluminum (Al): below 5.0% (except 0%)
Aluminum (Al) is an element that acts as a deoxidizing agent by binding with oxygen in steel. Further, like silicon (Si), aluminum (Al) is an element that stabilizes residual austenite by suppressing precipitation of cementite. Therefore, in order to achieve the above-described effects, aluminum (Al) must be added in the present invention. The preferable aluminum (Al) content may be 0.05% or more, and the more preferable aluminum (Al) content may be 0.1% or more. On the other hand, when too much aluminum (Al) is added, inclusions of the steel sheet increase and workability of the steel sheet may be lowered, so the upper limit of the aluminum (Al) content may be limited to 5.0% in the present invention. The upper limit of the preferable aluminum (Al) content may be 4.75%, and the upper limit of the more preferable aluminum (Al) content may be 4.5%.
In addition, the total content of silicon (Si) and aluminum (Al) (Si + Al) is preferably 1.0 to 6.0%. Since silicon (Si) and aluminum (Al) are components that affect the formation of a microstructure and affect ductility, bending workability, and hole expansibility in the present invention, the total content of silicon (Si) and aluminum (Al) is preferably 1.0 to 6.0%. The more preferable total content of silicon (Si) and aluminum (Al) (Si + Al) may be 1.5% or more, and may be 4.0% or less.
Manganese (Mn): 0.9 to 5.0 percent
Manganese (Mn) is a useful element for improving both strength and ductility. Therefore, in order to achieve the effects as described above, the lower limit of the manganese (Mn) content may be limited to 0.9% in the present invention. The lower limit of the preferred manganese (Mn) content may be 1.0%, and the lower limit of the more preferred manganese (Mn) content may be 1.1%. On the other hand, when manganese (Mn) is excessively added, since the bainite transformation time increases, the enrichment of carbon (C) in austenite is insufficient, and thus there is a problem that a desired austenite fraction cannot be secured. Therefore, in the present invention, the upper limit of the manganese (Mn) content may be limited to 5.0%. The upper limit of the preferred manganese (Mn) content may be 4.7%, and the upper limit of the more preferred manganese (Mn) content may be 4.5%.
Phosphorus (P): less than 0.15% (including 0%)
Phosphorus (P) is an element that is contained as an impurity and deteriorates impact toughness. Therefore, the content of phosphorus (P) is preferably controlled to 0.15% or less.
Sulfur (S): less than 0.03% (including 0%)
Sulfur (S) is an element that is contained as an impurity and forms MnS in a steel sheet to deteriorate ductility. Therefore, the content of sulfur (S) is preferably 0.03% or less.
Nitrogen (N): less than 0.03% (including 0%)
Nitrogen (N) is an element that is contained as an impurity and forms a nitride during continuous casting to cause cracking of a slab. Therefore, the content of nitrogen (N) is preferably 0.03% or less.
The steel sheet of the present invention has an alloy composition that can be further contained in addition to the above alloy components, and this will be described in detail below.
Titanium (Ti): 0-0.5%, niobium (Nb): 0-0.5% and vanadium (V): 0-0.5% of more than one
Titanium (Ti), niobium (Nb), and vanadium (V) are elements that form precipitates to refine crystal grains and also contribute to improvement in strength and impact toughness of the steel sheet, and therefore, in the present invention, one or more of titanium (Ti), niobium (Nb), and vanadium (V) may be added to achieve the above-described effects. However, when the respective contents of titanium (Ti), niobium (Nb), and vanadium (V) exceed a certain level, excessive precipitates are formed to lower impact toughness and also to increase manufacturing cost, so that the contents of titanium (Ti), niobium (Nb), and vanadium (V) may be limited to 0.5% or less, respectively, in the present invention.
Chromium (Cr): 0-3.0% and molybdenum (Mo): 0-3.0%
Chromium (Cr) and molybdenum (Mo) inhibit austenite decomposition at the time of alloying treatment, and are elements that stabilize austenite like manganese (Mn), and therefore, one or more of chromium (Cr) and molybdenum (Mo) may be added in the present invention for the effect as described above. However, when the contents of chromium (Cr) and molybdenum (Mo) exceed a certain level, the enrichment amount of carbon (C) in austenite is insufficient due to an increase in bainite transformation time, and thus a desired fraction of residual austenite cannot be secured. Therefore, in the present invention, the contents of chromium (Cr) and molybdenum (Mo) may be limited to 3.0% or less, respectively.
Copper (Cu): 0-4.5% and nickel (Ni): 0-4.5% of more than one
Copper (Cu) and nickel (Ni) are elements that stabilize austenite and inhibit corrosion. In addition, copper (Cu) and nickel (Ni) are elements that are concentrated on the surface of the steel sheet and prevent the intrusion of hydrogen that migrates into the steel sheet to suppress hydrogen-induced delayed fracture. Therefore, in the present invention, one or more of copper (Cu) and nickel (Ni) may be added for the above-described effects. However, when the contents of copper (Cu) and nickel (Ni) exceed a certain level, excessive characteristic effects are caused and the manufacturing cost is increased, so that the contents of copper (Cu) and nickel (Ni) may be respectively limited to 4.5% or less in the present invention.
Boron (B): 0 to 0.005 percent
Boron (B) is an element that improves strength by improving hardenability, and is also an element that suppresses nucleation of grain boundaries. Therefore, boron (B) may be added in the present invention for the effect described above. However, when the content of boron (B) exceeds a certain level, excessive characteristic effects are caused and the production cost is increased, so that the content of boron (B) may be limited to 0.005% or less in the present invention.
Calcium (Ca): 0-0.05%, magnesium (Mg): 0-0.05% and rare earth elements (REM) other than yttrium (Y): 0-0.05%
Among them, rare earth elements (REM) refer to scandium (Sc), yttrium (Y), and lanthanoid elements. Since the rare earth elements (REM) other than calcium (Ca), magnesium (Mg), and yttrium (Y) are elements that contribute to improvement of ductility of the steel sheet by spheroidizing sulfides, one or more of the rare earth elements (REM) other than calcium (Ca), magnesium (Mg), and yttrium (Y) may be added in the present invention to achieve the above-described effects. However, since the content of the rare earth element (REM) other than calcium (Ca), magnesium (Mg) and yttrium (Y) exceeds a certain level, an excessive characteristic effect is caused and the production cost is increased, the content of the rare earth element (REM) other than calcium (Ca), magnesium (Mg) and yttrium (Y) may be limited to 0.05% or less in the present invention.
Tungsten (W): 0-0.5% and zirconium (Zr): 0-0.5% of one or more
Tungsten (W) and zirconium (Zr) are elements that increase the strength of the steel sheet by improving hardenability, and therefore, in the present invention, one or more of tungsten (W) and zirconium (Zr) may be added for the effects described above. However, when the contents of tungsten (W) and zirconium (Zr) exceed a certain level, excessive characteristic effects are caused and this may cause an increase in manufacturing cost, so that the contents of tungsten (W) and zirconium (Zr) may be limited to 0.5% or less, respectively, in the present invention.
Antimony (Sb): 0-0.5% and tin (Sn): 0-0.5% of more than one
Antimony (Sb) and tin (Sn) are elements that improve plating wettability and plating adhesion of the steel sheet, and therefore, in the present invention, one or more of antimony (Sb) and tin (Sn) may be added for the effects described above. However, when the contents of antimony (Sb) and tin (Sn) exceed a certain level, the brittleness of the steel sheet increases, and cracks may be generated at the time of hot working or cold working, so the contents of antimony (Sb) and tin (Sn) may be limited to 0.5% or less, respectively, in the present invention.
Yttrium (Y): 0-0.2% and hafnium (Hf): 0-0.2% of more than one
Since yttrium (Y) and hafnium (Hf) are elements that improve the corrosion resistance of the steel sheet, one or more of yttrium (Y) and hafnium (Hf) may be added in the present invention for the above-described effects. However, when the contents of yttrium (Y) and hafnium (Hf) exceed a certain level, the ductility of the steel sheet may be deteriorated, and thus the contents of yttrium (Y) and hafnium (Hf) may be limited to 0.2% or less, respectively, in the present invention.
Cobalt (Co): 0 to 1.5 percent
Since cobalt (Co) is an element that increases the TRIP effect by promoting bainite transformation, cobalt (Co) may be added in the present invention for the purpose of the above-described effect. However, when the content of cobalt (Co) exceeds a certain level, weldability and ductility of the steel sheet may be deteriorated, and thus the content of cobalt (Co) may be limited to 1.5% or less in the present invention.
The high-strength steel sheet having excellent workability according to one aspect of the present invention may contain Fe and other inevitable impurities in addition to the above components in the balance. However, impurities which are not necessary are inevitably mixed from the raw materials or the surrounding environment in a general manufacturing process, and thus cannot be completely excluded. These impurities are well known to those skilled in the art and therefore not all of them are specifically mentioned in this specification. Further, further addition of active ingredients other than the above ingredients is not completely excluded.
In the high-strength steel sheet excellent in workability according to one aspect of the present invention, the microstructure may include tempered martensite, bainite, residual austenite, and ferrite. As a preferable example, the high-strength steel sheet excellent in workability according to one aspect of the present invention may include, in volume fraction, 30 to 70% of tempered martensite, 10 to 45% of bainite, 10 to 40% of retained austenite, 3 to 20% of ferrite, and an unavoidable microstructure. The unavoidable structure of the present invention may include Fresh Martensite (Fresh martentite), pearlite, island Martensite (Martensite-Austenite Constituent (M-a)), and the like. When too much new martensite or pearlite is formed, workability of the steel sheet is reduced, or the fraction of retained austenite may be reduced.
In the high-strength steel sheet excellent in workability according to one aspect of the present invention, the following [ relational formula 1]]The average total content of silicon (Si) and aluminum (Al) contained in the ferrite ([ Si + Al)] F Weight%) and the average total content of silicon (Si) and aluminum (Al) contained in the retained austenite ([ Si + Al) ([ Si + Al ])] γ Weight%) may satisfy the range of 1.1 to 3.0, as the following [ relational formula 2]]As shown, the ratio of the tempered retained austenite fraction (T (γ), vol%) of the steel sheet to the retained austenite fraction (V (γ), vol%) of the steel sheet may be 0.1 or more.
[ relational expression 1]
1.1≤[Si+Al] F /[Si+Al] γ ≤3.0
[ relational expression 2]
T(γ)/V(γ)≥0.1
In the high-strength steel sheet excellent in workability according to one aspect of the present invention, the steel sheet is formed by the following [ relational expression 3]]Balance of tensile Strength and elongation (B) T·E ) 22000 (MPa%) or more, and is represented by the following relational expression 4]Balance of tensile Strength and hole expansion ratio (B) T·H ) Is 7 x 10 6 (MPa 2 ％ 1/2 ) Above, is represented by the following [ relational expression 5]]Indicated bending ratio (B) R ) Satisfies the range of 0.5 to 3.0, and thus the steel sheet may have an excellent balance of strength and ductility and a balance of strength and hole expansibility, and may have excellent bending workability.
[ relational expression 3]
B T·E Not [ tensile strength (TS, MPa) ]]Elongation (El,%)]
[ relational expression 4]
B T·H Not [ tensile strength (TS, MPa) ]] 2 [ hole expansion ratio (HER%)] 1/2
[ relational expression 5]
B R ＝R/t
In the relational expression 5, R represents the minimum bending radius (mm) at which no crack is generated after the 90 DEG bending test, and t represents the thickness (mm) of the steel plate.
The present invention is directed to ensuring high strength characteristics and excellent ductility and bendability at the same time, and therefore it is important to stabilize the retained austenite of the steel sheet. In order to stabilize the residual austenite, it is necessary to enrich carbon (C) and manganese (Mn) in the austenite in ferrite, bainite, and tempered martensite of the steel sheet. However, when carbon (C) is concentrated in austenite using ferrite, the strength of the steel sheet may be insufficient due to the low strength characteristics of ferrite, and an excessive difference in phase hardness occurs, thereby possibly decreasing the Hole Expansion Ratio (HER). Therefore, in the present invention, carbon (C) and manganese (Mn) are enriched in austenite by using bainite and tempered martensite.
When the contents of silicon (Si) and aluminum (Al) in the residual austenite are limited within a certain range, a large amount of carbon (C) and manganese (Mn) can be enriched in the residual austenite from bainite and tempered martensite, and thus the residual austenite can be effectively stabilized. Further, as the contents of silicon (Si) and aluminum (Al) in austenite are limited to a certain range, the contents of silicon (Si) and aluminum (Al) in ferrite may be increased. As the contents of silicon (Si) and aluminum (Al) in ferrite increase, the hardness of ferrite increases, and the difference in the hardness between ferrite, which is a soft structure, and tempered martensite, bainite, and retained austenite, which is a hard structure, can be effectively reduced.
Therefore, in the present invention, the average total content ([ Si + Al ") of silicon (Si) and aluminum (Al) contained in ferrite is set] F Weight%) and the average total content of silicon (Si) and aluminum (Al) contained in the retained austenite ([ Si + Al) ([ Si + Al ])] γ And wt.%) is limited to 1.1 or more, so that the difference in hardness between the soft tissue and the hard tissue can be effectively reduced. On the other hand, when the contents of silicon (Si) and aluminum (Al) in ferrite are too large, the ferrite is rather hardened excessively, resulting in a reduction in workability, and therefore, it is not possible to simultaneously secure a desired balance (TS × El) between tensile strength and elongation and a desired balance (TS) between tensile strength and hole expansion ratio 2 ×HER 1/2 ) And a bending ratio (R/t). Therefore, in the present invention, the average total content ([ Si + Al ") of silicon (Si) and aluminum (Al) contained in ferrite can be adjusted] F Weight%) and the average total content of silicon (Si) and aluminum (Al) contained in the retained austenite ([ Si + Al) ([ Si + Al ])] γ Weight%) is limited to 3.0 or less.
In addition, tempered residual austenite among the residual austenite is heat-treated at the bainite formation temperature so that the average size thereof is increased, and transformation of austenite into martensite is suppressed, so that workability of the steel sheet can be improved. That is, in order to improve the ductility and workability of the steel sheet, it is preferable to increase the fraction of tempered retained austenite in the retained austenite.
Therefore, in the high-strength steel sheet excellent in workability according to one aspect of the present invention, the ratio of the fraction (T (γ), vol%) of tempered retained austenite of the steel sheet to the fraction (V (γ), vol%) of retained austenite of the steel sheet may be limited to 0.1 or more. When the ratio of the fraction (T (γ), vol%) of tempered retained austenite to the fraction (V (γ), vol%) of retained austenite of the steel sheet is less than 0.1, the bending workability (R/T) cannot satisfy 0.5 to 3.0, and thus there is a problem that desired workability cannot be secured.
The steel sheet including the retained austenite has excellent ductility and bending workability due to transformation induced plasticity generated when austenite is transformed into martensite in working. When the fraction of retained austenite is less than a certain level, the balance of tensile strength and elongation (TS × El) is less than 22000 MPa%, or the bending workability (R/t) may exceed 3.0. In addition, when the fraction of the retained austenite exceeds a certain level, Local Elongation (Local Elongation) may be reduced. Therefore, in the present invention, in order to obtain a steel sheet excellent in the balance (TS × El) of tensile strength and elongation and the bending workability (R/t), the fraction of retained austenite may be limited to the range of 10 to 40 vol%.
In addition, both untempered martensite (fresh martensite) and tempered martensite are fine structures that improve the strength of the steel sheet. However, the newly grown martensite has a characteristic of greatly reducing the ductility and hole expansibility of the steel sheet, as compared with tempered martensite. This is because the fine structure of the tempered martensite is softened by the tempering heat treatment. Therefore, in the present invention, tempered martensite is preferably used in order to provide a steel sheet excellent in balance of strength and ductility, balance of strength and hole expansibility, and bending workability. When the fraction of tempered martensite is less than a certain level, it is difficult to secure a balance (TS × El) of tensile strength and elongation of 22000 MPa% or more or 7 × 10 6 (MPa 2 ％ 1/2 ) The balance between tensile Strength and hole expansibility (TS) 2 ×HER 1/2 ) When the fraction of tempered martensite exceeds a certain level, ductility and workability are lowered, and therefore the balance (TS × El) of tensile strength and elongation is less than 22000 MPa%, or the bending workability (R/t) exceeds 3.0, which is not preferable. Therefore, in the present invention, in order to obtain the balance of tensile strength and elongation (TS × El), and the balance of tensile strength and hole expansion (TS:) 2 ×HER 1/2 ) And a steel sheet having an excellent bending workability (R/t) and capable of forming tempered martensiteThe number is limited to the range of 30-70 vol%.
To improve the balance between tensile strength and elongation (TS × El) and the balance between tensile strength and hole expansion (TS) 2 ×HER 1/2 ) And a bending workability (R/t), and the microstructure preferably contains bainite as appropriate. Only when the bainite fraction is a certain level or more, the balance (TS. times.El) between tensile strength and elongation of 22000 MPa% or more and 7. times.10 6 (MPa 2 ％ 1/2 ) The balance between tensile Strength and hole expansibility (TS) 2 ×HER 1/2 ) And a bending ratio (R/t) of 0.5 to 3.0. On the other hand, when the bainite fraction is too large, the tempered martensite fraction inevitably decreases, and therefore, the balance (TS × El) between the tensile strength and the elongation and the balance (TS) between the tensile strength and the hole expansion ratio, which are desired in the present invention, cannot be finally secured 2 ×HER 1/2 ) And a bending ratio (R/t). Therefore, in the present invention, the fraction of bainite may be limited to a range of 10 to 45 vol%.
Ferrite is an element contributing to improvement of ductility, and therefore, only when the fraction of ferrite is a certain level or more, the balance (TS × El) of tensile strength and elongation desired in the present invention can be ensured. However, when the fraction of ferrite is too large, the difference in hardness between phases increases, and the Hole Expansion Ratio (HER) may decrease, so that the balance (TS) between the tensile strength and the hole expansion ratio desired in the present invention cannot be secured 2 ×HER 1/2 ). Therefore, the fraction of ferrite in the present invention may be limited to the range of 3 to 20 vol%.
Hereinafter, an example of a method for manufacturing the steel sheet of the present invention will be described in detail.
The method of manufacturing a high-strength steel sheet excellent in workability according to one aspect of the present invention may include the steps of: providing a cold-rolled steel sheet having a predetermined composition; heating the cold-rolled steel sheet to a temperature range of Ac1 or more and less than Ac3 (primary heating), and holding for 50 seconds or more (primary holding); cooling (primary cooling) at an average cooling rate of 1 ℃/second or more to a temperature range of 600-850 ℃ (primary cooling termination temperature); cooling (secondary cooling) to a temperature range of 300-500 ℃ at an average cooling rate of 2 ℃/second or more, and keeping for 5 seconds or more (secondary keeping) within the temperature range; cooling (tertiary cooling) to a temperature range of 100-300 ℃ (secondary cooling termination temperature) at an average cooling rate of 2 ℃/second or higher; heating to the temperature range of 300-500 ℃ (secondary heating), and keeping the temperature range for more than 50 seconds (three times of keeping); and cooling to ambient temperature (four cools).
Further, the cold rolled steel sheet of the present invention may be provided by: heating the steel billet to 1000-1350 ℃; performing hot finish rolling within the temperature range of 800-; rolling the hot rolled steel plate within the temperature range of 300-600 ℃; carrying out hot rolling annealing heat treatment on the coiled steel plate within the temperature range of 650-850 ℃ for 600-1700 seconds; and cold rolling the hot-rolled annealed steel sheet at a reduction ratio of 30 to 90%.
Preparation and heating of billets
A billet having a predetermined composition is prepared. Since the billet of the present invention has an alloy composition corresponding to the alloy composition of the steel sheet, the description of the alloy composition of the steel sheet is used instead of the description of the alloy composition of the billet.
The prepared billet can be heated to a certain temperature range, and the heating temperature of the billet can be in the range of 1000-1350 ℃. This is because, when the heating temperature of the slab is less than 1000 ℃, hot rolling may be performed in a temperature range of a desired finish hot rolling temperature range or less, and when the heating temperature of the slab exceeds 1350 ℃, the melting point of the steel may be reached and the steel may be melted.
Hot rolling and winding
The heated slab may be hot-rolled to provide a hot-rolled steel sheet. The finish hot rolling temperature during hot rolling is preferably in the range of 800-. This is because, when the finish hot rolling temperature is less than 800 ℃, an excessive rolling load may be a problem, and when the finish hot rolling temperature exceeds 1000 ℃, coarse crystal grains of the hot rolled steel sheet are formed, which may cause a reduction in physical properties of the final steel sheet.
The hot rolled steel sheet, which has completed the hot rolling, may be cooled at an average cooling rate of 10 deg.C/sec or more, and may be wound at a temperature of 300-600 deg.C. This is because, when the rolling temperature is less than 300 ℃, rolling is not easy, and when the rolling temperature exceeds 600 ℃, surface scale (scale) is formed to the inside of the hot rolled steel sheet, and thus pickling may be difficult.
Hot rolling annealing heat treatment
In order to facilitate pickling and cold rolling as subsequent processes after rolling, it is preferable to perform a hot rolling annealing heat treatment process. The hot-rolling annealing heat treatment can be carried out within the temperature range of 650-850 ℃ for 600-1700 seconds. When the hot-rolling annealing heat treatment temperature is less than 650 ℃ or the hot-rolling annealing heat treatment time is less than 600 seconds, the strength of the hot-rolling annealed steel sheet is high, and thus subsequent cold rolling may not be easily performed. On the other hand, when the hot rolling annealing heat treatment temperature exceeds 850 ℃ or the hot rolling annealing heat treatment time exceeds 1700 seconds, pickling may not be easily performed due to scale formed deep inside the steel sheet.
Pickling and cold rolling
After the hot-rolling annealing heat treatment, pickling may be performed and cold-rolling may be performed in order to remove scale formed on the surface of the steel sheet. In the present invention, the pickling and cold rolling conditions are not particularly limited, but it is preferable to perform cold rolling at a cumulative reduction of 30 to 90%. When the cumulative reduction of cold rolling exceeds 90%, it may be difficult to perform cold rolling in a short time due to high strength of the steel sheet.
The cold rolled steel sheet may be formed into an uncoated cold rolled steel sheet through an annealing heat treatment process, or may be formed into a coated steel sheet through a coating process in order to impart corrosion resistance. The plating may be performed by a plating method such as hot dip galvanizing, electrogalvanizing, or hot dip aluminizing, and the method and kind thereof are not particularly limited.
Annealing heat treatment
In the present invention, an annealing heat treatment process is performed in order to simultaneously secure the strength and workability of the steel sheet.
The cold-rolled steel sheet is heated to a temperature range of Ac1 or more and less than Ac3 (two-phase region) (primary heating), and is held in this temperature range for 50 seconds or more (primary holding). When the temperature is once heated or once maintained as Ac3 so as toIn the above (single phase region), the desired ferrite structure cannot be realized, and thus the desired level of [ Si + Al cannot be realized] F /[Si+Al] γ And balance of tensile strength and hole expansion (TS) 2 ×HER 1/2 ). In addition, when the temperature at one time of heating or at one time of holding is in a temperature range lower than Ac1, sufficient heating cannot be performed, and the desired fine structure of the present invention may not be achieved even by the subsequent heat treatment. The average temperature increase rate in the first heating may be 5 ℃/sec or more.
When the primary holding time is less than 50 seconds, the structure may not be sufficiently homogenized, and thus the physical properties of the steel sheet may be degraded. The upper limit of the primary holding time is not particularly limited, but the primary heating time is preferably limited to 1200 seconds or less in order to prevent the toughness from being lowered due to coarsening of crystal grains.
After the primary holding, it is preferable to perform cooling (primary cooling) at an average cooling rate of 1 ℃/sec or more to a temperature range of 600-850 ℃ (primary cooling termination temperature). The upper limit of the average cooling rate of the primary cooling is not particularly limited, but is preferably limited to 100 ℃/sec or less. When the primary cooling termination temperature is less than 600 ℃, too much ferrite is formed and the residual austenite is insufficient, so that [ Si + Al may be reduced] F /[Si+Al] γ And the balance of tensile strength and elongation (TS × El). Further, the upper limit of the primary cooling end temperature is preferably 30 ℃ lower than the primary holding temperature, and thus the upper limit of the primary cooling end temperature may be limited to 850 ℃.
After the primary cooling, it is preferable to perform cooling (secondary cooling) at an average cooling rate of 2 ℃/sec or more to a temperature range of 300 ℃ to 500 ℃ and to hold it within the temperature range for 5 seconds or more (secondary holding). When the average cooling rate of the secondary cooling is less than 2 c/sec, too much ferrite is formed and the residual austenite is insufficient, so that [ Si + Al ] may be reduced] F /[Si+Al] γ And the balance of tensile strength and elongation (TS × El). The upper limit of the average cooling rate of the secondary cooling is not particularly limited, but is preferably limited to 100 ℃/sec or less. In addition, when the secondary retention temperature exceeds 500 ℃, the retained austenite is insufficientTherefore, [ Si + Al ] may be reduced] F /[Si+Al] γ T (gamma)/V (gamma), the balance of tensile strength and elongation (TS × El), and the bending workability (R/T). In addition, when the secondary holding temperature is lower than 300 DEG C
In the case of this, T (γ)/V (γ) and the bending ratio (R/T) may be lowered due to a low heat treatment temperature. When the secondary holding time is less than 5 seconds, the heat treatment time is insufficient, and thus T (γ)/V (γ) and the bending workability (R/T) may be reduced. On the other hand, the upper limit of the secondary holding time is not particularly required to be defined, but is preferably 600 seconds or less.
Further, the average cooling rate (Vc1) of the primary cooling is preferably smaller than the average cooling rate (Vc2) of the secondary cooling (Vc1< Vc 2).
After the secondary holding, it is preferable to perform cooling (tertiary cooling) at an average cooling rate of 2 ℃/sec or more to a temperature range of 100 ℃ to 300 ℃ (secondary cooling termination temperature). When the average cooling rate of the tertiary cooling is less than 2 c/sec, the [ Si + Al ] of the steel sheet may be lowered due to the slow cooling] F /[Si+Al] γ T (gamma)/V (gamma) and a bending ratio (R/T). The upper limit of the average cooling rate of the third cooling is not particularly limited, but is preferably limited to 100 ℃/sec or less. In addition, when the secondary cooling termination temperature exceeds 300 DEG C
In the case where bainite is excessively formed and tempered martensite is insufficient, T (γ)/V (γ) and the balance (TS × El) of tensile strength and elongation may be lowered. On the other hand, when the secondary cooling end temperature is less than 100 ℃, tempered martensite is excessively formed and residual austenite is insufficient, so that [ Si + Al ] may be reduced] F /[Si+Al] γ T (gamma)/V (gamma), the balance of tensile strength and elongation (TS × El), and the bending workability (R/T).
After the three-time cooling, it is preferably heated to a temperature range of 300-500 ℃ (secondary heating) and held in this temperature range for 10 seconds or more (three-time holding). When the three-time holding temperature exceeds 550 ℃, the retained austenite is insufficient, and therefore [ Si + Al ] may be decreased] F /[Si+Al] γ T (gamma)/V (gamma), the balance of tensile strength and elongation (TS × El), and the bending workability (R/T). On the other hand, when it is maintained three timesWhen the temperature is lower than 350 ℃, the retained temperature is low and the retained austenite is insufficient, so that the [ Si + Al ] may be reduced] F /[Si+Al] γ T (gamma)/V (gamma), the balance of tensile strength and elongation (TS × El), and the bending workability (R/T). When the tertiary holding time is less than 50 seconds, excessively tempered martensite is formed and the residual austenite is insufficient, so that [ Si + Al ] may be reduced] F /[Si+Al] γ T (gamma)/V (gamma), the balance of tensile strength and elongation (TS × El), and the bending workability (R/T). The upper limit of the tertiary holding time is not particularly limited, but the tertiary holding time may be preferably 1800 seconds or less.
After the three times of holding, it is preferable to cool to room temperature at an average cooling rate of 1 ℃/sec or more (four times of cooling).
In the high-strength steel sheet having excellent workability manufactured by the above manufacturing method, the microstructure may include tempered martensite, bainite, retained austenite, and ferrite, and as a preferred example, the microstructure may include 30 to 70% of tempered martensite, 10 to 45% of bainite, 10 to 40% of retained austenite, 3 to 20% of ferrite, and an unavoidable microstructure in terms of volume fraction.
In addition, in the high-strength steel sheet with excellent workability manufactured by the manufacturing method, the following [ relational expression 1]]The average total content of silicon (Si) and aluminum (Al) contained in the ferrite ([ Si + Al)] F Weight%) and the average total content of silicon (Si) and aluminum (Al) contained in the retained austenite ([ Si + Al) ([ Si + Al ])] γ Weight%) may satisfy the range of 1.1 to 3.0, and is as follows [ relational formula 2%]As shown, the ratio of the tempered retained austenite fraction (T (γ), vol%) of the steel sheet to the retained austenite fraction (V (γ), vol%) of the steel sheet may be 0.1 or more.
[ relational expression 1]
1.1≤[Si+Al] F /[Si+Al] γ ≤3.0
[ relational expression 2]
T(γ)/V(γ)≥0.1
The high-strength steel sheet having excellent workability produced by the above production method is represented by the following [ relational expression 3]]Pulling of the representationBalance of tensile Strength and elongation (B) T·E ) Can be 22000 (MPa%) or more, and is represented by the following [ relational expression 4]]Balance of tensile Strength and hole expansion ratio (B) T·H ) Can be 7 x 10 6 (MPa 2 ％ 1/2 ) Above, is represented by the following [ relational expression 5]]Indicated bending ratio (B) R ) The range of 0.5 to 3.0 may be satisfied.
[ relational expression 3]
B T·E Not [ tensile strength (TS, MPa) ]]Elongation (El,%)]
[ relational expression 4]
B T·H Not [ tensile strength (TS, MPa) ]] 2 [ hole expansion ratio (HER%)] 1/2
[ relational expression 5]
B R ＝R/t
In the relational expression 5, R represents the minimum bending radius (mm) at which no crack is generated after the 90 DEG bending test, and t represents the thickness (mm) of the steel plate.
Detailed Description
Hereinafter, a high-strength steel sheet excellent in workability according to one aspect of the present invention and a method for manufacturing the same will be described in more detail with reference to specific examples. It should be noted that the following examples are only for understanding the present invention, and are not intended to limit the scope of the present invention. The scope of the invention is to be determined by the content of the claims and the reasonable derivations thereof.
(examples)
Slabs having a thickness of 100mm and having alloy compositions (balance Fe and unavoidable impurities) described in table 1 below were produced, heated at 1200 ℃, and then finish hot rolled at 900 ℃. Thereafter, the steel sheet was cooled at an average cooling rate of 30 ℃/sec and wound at the winding temperatures of tables 2 and 3, thereby producing a hot-rolled steel sheet having a thickness of 3 mm. The hot rolled steel sheets were subjected to hot rolling annealing heat treatment according to the conditions of tables 2 and 3. Thereafter, pickling was performed to remove surface scale, and then cold rolling was performed to a thickness of 1.5 mm.
Thereafter, heat treatment was performed according to the annealing heat treatment conditions of tables 2 to 7, thereby manufacturing steel sheets.
The microstructure of the steel sheet manufactured as described above was observed, and the results are shown in tables 8 and 9. The cross section of the polished test piece was etched with a nital solution, and then ferrite (F), bainite (B), Tempered Martensite (TM), and pearlite (P) in the microstructure were observed by SEM. Among them, bainite and tempered martensite which are difficult to be distinguished are subjected to expansion evaluation, and then the fraction is calculated using an expansion curve. In addition, the newly grown martensite (FM) and the retained austenite (retained γ) are also difficult to distinguish, and thus a value obtained by subtracting the fraction of the retained austenite calculated by the X-ray diffraction method from the fraction of the martensite and the retained austenite observed by the SEM is determined as the newly grown martensite fraction.
In addition, [ Si + Al ] for steel sheet] F /[Si+Al] γ T (gamma)/V (gamma), balance of tensile strength and elongation (TS × El), and balance of tensile strength and hole expansion (TS ×) 2 ×HER 1/2 ) The results of the observation of the bending reduction ratio (R/t) are shown in tables 10 and 11.
The average total content of silicon (Si) and aluminum (Al) contained in the residual austenite ([ Si + Al) was measured using an Electron Probe Microanalyzer (EPMA)] γ Weight%) and the average total content of silicon (Si) and aluminum (Al) contained in the ferrite ([ Si + Al)] F Wt.%). Further, the fraction (V (γ)) of the retained austenite of the steel sheet is determined as an area measured in the retained austenite by a Phase Map (Phase Map) of EPMA.
The Tensile Strength (TS) and the elongation (El) were evaluated by a tensile test, and the Tensile Strength (TS) and the elongation (El) were measured by taking a test piece according to JIS5 standard and evaluating it with respect to a direction of 90 ° with respect to the rolling direction of a rolled plate material. The bending reduction ratio (R/t) was evaluated by a V-bend test, and was calculated by taking a test piece with reference to a direction of 90 ° with respect to the rolling direction of the rolled plate material and determining the minimum bending radius R at which no crack occurred after the 90 ° bend test by dividing the value by the thickness t of the plate material. The Hole Expansion Ratio (HER) was evaluated by a hole expansion test in the formation of
After punching (die inner diameter of 10.3mm, clearance of 12.5%), a conical punch having an apex angle of 60 ° was inserted into the punched hole in a direction in which a burr (burr) of the punched hole was outside, and the peripheral portion of the punched hole was pressed and expanded at a moving speed of 20 mm/min, and then the following [ relational expression 6] was used]And (4) performing calculation.
[ relational expression 6]
Hole expansion ratio (HER,%) { (D-D) 0 )/D 0 }×100
In the above relational expression 6, D represents the hole diameter (mm) when the crack penetrates the steel sheet in the thickness direction, and D 0 Indicating the initial pore size (mm).
[ Table 1]
[ Table 2]
[ Table 3]
[ Table 4]
[ Table 5]
[ Table 6]
[ Table 7]
[ Table 8]
[ Table 9]
[ Table 10]
[ Table 11]
As shown in tables 1 to 11, it is understood that [ Si + Al ] satisfies the conditions of the present invention] F /[Si+Al] γ The value (D) satisfies the range of 1.1 to 3.0, T (gamma)/V (gamma) is 0.1 or more, the balance of tensile strength and elongation (TS × El) is 22000 MPa% or more, and the balance of tensile strength and hole expansion (TS) 2 ×HER 1/2 ) Is 7 x 10 6 (MPa 2 ％ 1/2 ) Above, the bending workability (R/t) satisfies the range of 0.5 to 3.0, thereby having both excellent strength and workability.
The composition ranges of the alloys of the present invention overlap with the test pieces 2 to 5, but the hot rolling annealing temperature and time are out of the ranges of the present invention, and thus it was confirmed that pickling failure occurred or fracture occurred during cold rolling.
In the test piece 6, the primary heating or holding temperature during the annealing heat treatment after the cold rolling exceeded the range limited by the present invention, and therefore the formation amount of ferrite was insufficient. As a result, it was confirmed that [ Si + Al ] of the test piece 6 was present] F /[Si+Al] γ A value of less than 1.1, a balance of tensile strength and hole expansion ratio (TS) 2 ×HER 1/2 ) Less than 7 x 10 6 (MPa 2 ％ 1/2 )。
In the test piece 8, the primary cooling termination temperature was low, so that too much ferrite was formed and a small amount of retained austenite was formed. Knot of itAs a result, it was confirmed that [ Si + Al ] of the test piece 8 was present] F /[Si+Al] γ The value of (A) exceeds 3.0 and the balance (TS. times.El) between tensile strength and elongation is less than 22000 MPa%.
In test piece 9, the average cooling rate of the secondary cooling was low, so that too much ferrite was formed and a small amount of retained austenite was formed. As a result, it was confirmed that [ Si + Al ] of the test piece 9 was present] F /[Si+Al] γ The value of (A) exceeds 3.0 and the balance (TS. times.El) between tensile strength and elongation is less than 22000 MPa%.
In the test piece 12, the secondary holding temperature was high, and therefore a small amount of retained austenite was formed. As a result, it was confirmed that [ Si + Al ] of the test piece 12 was present] F /[Si+Al] γ More than 3.0, T (gamma)/V (gamma) less than 0.5, a balance (TS x El) between tensile strength and elongation less than 22000MPa, and a bending workability (R/T) more than 3.0.
In the test piece 13, since the secondary holding temperature was low, it was confirmed that T (γ)/V (γ) was less than 0.1 and the bending ratio (R/T) was more than 3.0, and in the test piece 14, since the secondary holding time was short, it was confirmed that T (γ)/V (γ) was less than 0.1 and the bending ratio (R/T) was more than 3.0.
In test piece 15, [ Si + Al ] was confirmed because the average cooling rate of the tertiary cooling was low] F /[Si+Al] γ Is more than 3.0, T (gamma)/V (gamma) is less than 0.5, and the bending workability (R/T) is more than 3.0.
In test piece 16, since the secondary cooling termination temperature was high, bainite was excessively formed and tempered martensite was formed in a small amount. As a result, it was confirmed that T (. gamma.)/V (. gamma.) of the test piece 16 was less than 0.1 and the balance (TS. times.El) between the tensile strength and the elongation was less than 22000 MPa%.
In the test piece 17, the secondary cooling termination temperature was low, so that tempered martensite was excessively formed and a small amount of retained austenite was formed. As a result, it was confirmed that [ Si + Al ] of the test piece 17 was present] F /[Si+Al] γ More than 3.0, T (gamma)/V (gamma) less than 0.1, a balance (TS x El) between tensile strength and elongation less than 22000MPa, and a bending workability (R/T) more than 3.0.
In the test piece 18, the temperature was kept high three times, and thus a small amount of retained austenite was formed. As a result, the [ S ] of the test piece 18 can be confirmedi+Al] F /[Si+Al] γ More than 3.0, T (gamma)/V (gamma) less than 0.1, a balance (TS x El) between tensile strength and elongation less than 22000MPa, and a bending workability (R/T) more than 3.0.
In the test piece 19, [ Si + Al ] was confirmed because the temperature was kept low for three times] F /[Si+Al] γ More than 3.0, T (gamma)/V (gamma) less than 0.1, a balance (TS x El) between tensile strength and elongation less than 22000MPa, and a bending workability (R/T) more than 3.0.
In the test piece 20, the three retention times were short, so that excessive tempered martensite was formed and a small amount of retained austenite was formed. As a result, it was confirmed that [ Si + Al ] of the test piece 20 was present] F /[Si+Al] γ More than 3.0, T (gamma)/V (gamma) less than 0.1, a balance (TS x El) between tensile strength and elongation less than 22000MPa, and a bending workability (R/T) more than 3.0.
The test pieces 43 to 51 satisfy the manufacturing conditions proposed in the present invention but are not within the range of the alloy composition proposed in the present invention. In these cases, it was confirmed that [ Si + Al ] which could not satisfy the present invention at the same time] F /[Si+Al] γ T (γ)/V (γ), balance of tensile strength and elongation (TS × El), 7 × 10 6 (MPa 2 ％ 1/2 ) Balance of tensile strength and hole expansion ratio (TS) 2 ×HER 1/2 ) And the bending ratio (R/t). In addition, in the test piece 45, when the total content of aluminum (Al) and silicon (Si) is less than 1.0%, it was confirmed that [ Si + Al ] is not satisfied] F /[Si+Al] γ And the balance of tensile strength and elongation (TS × El), and the bending workability (R/t).
The present invention has been described in detail with reference to the embodiments, but other embodiments may be included. Therefore, the technical spirit and scope of the claims are not limited to the embodiments.
Claims (10)
1. A high-strength steel sheet having excellent workability, comprising, in wt.%: c: 0.25-0.75%, Si: 4.0% or less, Mn: 0.9-5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: less than 0.03%, and the balance of Fe and inevitable impurities,
the microstructure comprises tempered martensite, bainite, retained austenite, ferrite and unavoidable microstructure,
and satisfies the following [ relational expression 1] and [ relational expression 2],
[ relational expression 1]
1.1≤[Si+Al] F /[Si+Al] γ ≤3.0
In the above relational expression 1, [ Si + Al] F Is the average total content (wt%) of Si and Al contained in the ferrite, [ Si + Al%] γ Is an average total content (wt%) of Si and Al contained in the retained austenite,
[ relational expression 2]
T(γ)/V(γ)≥0.1
In the relational expression 2, T (γ) is a fraction (vol%) of tempered residual austenite of the steel sheet, and V (γ) is a fraction (vol%) of residual austenite of the steel sheet.
2. The high-strength steel sheet excellent in workability according to claim 1, further comprising any one or more of the following (1) to (9):
(1) ti: 0-0.5%, Nb: 0-0.5% and V: 0-0.5% of one or more of,
(2) cr: 0-3.0% and Mo: 0-3.0% of one or more of,
(3) cu: 0-4.5% and Ni: 0-4.5% of one or more of,
(4)B：0-0.005％，
(5) ca: 0-0.05%, REM except Y: 0-0.05% and Mg: 0-0.05% of one or more of,
(6) w: 0-0.5% and Zr: 0-0.5% of one or more of,
(7) sb: 0-0.5% and Sn: 0-0.5% of one or more of,
(8) y: 0-0.2% and Hf: 0-0.2% of one or more of,
(9)Co：0-1.5％。
3. the high-strength steel sheet excellent in workability according to claim 1, wherein the total content of Si and Al (Si + Al) is 1.0 to 6.0 wt%.
4. The high-strength steel sheet excellent in workability according to claim 1, wherein the fine structure of the steel sheet comprises 30 to 70 vol% of tempered martensite, 10 to 45 vol% of bainite, 10 to 40 vol% of retained austenite, and 3 to 20 vol% of ferrite.
5. The high-strength steel sheet excellent in workability according to claim 1, wherein the steel sheet is formed from [ relational formula 3]]Balance of tensile Strength and elongation (B) T·E ) 22000 (MPa%) or more, and is represented by the following relational expression 4]Balance of tensile Strength and hole expansion ratio (B) T·H ) Is 7 x 10 6 (MPa 2 ％ 1/2 ) Above, is represented by the following [ relational expression 5]]Indicated bending ratio (B) R ) Is in the range of 0.5 to 3.0,
[ relational expression 3]
B T·E Not [ tensile strength (TS, MPa) ]]Elongation (El,%)]
[ relational expression 4]
B T·H Not [ tensile strength (TS, MPa) ]] 2 [ hole expansion ratio (HER%)] 1/2
[ relational expression 5]
B R ＝R/t
In the relational expression 5, R represents the minimum bending radius (mm) at which no crack is generated after the 90 DEG bending test, and t represents the thickness (mm) of the steel plate.
6. A method of manufacturing a high-strength steel sheet excellent in workability, comprising the steps of:
providing a cold rolled steel sheet comprising, in weight%: c: 0.25-0.75%, Si: 4.0% or less, Mn: 0.9-5.0%, Al: 5.0% or less, P: 0.15% or less, S: 0.03% or less, N: less than 0.03%, and the balance of Fe and inevitable impurities;
heating the cold-rolled steel sheet to a temperature range of Ac1 or more and less than Ac3 (primary heating), and holding for 50 seconds or more (primary holding);
cooling (primary cooling) at an average cooling rate of 1 ℃/second or more to a temperature range of 600-850 ℃ (primary cooling termination temperature);
cooling (secondary cooling) to a temperature range of 300-500 ℃ at an average cooling rate of 2 ℃/second or more, and keeping for 5 seconds or more (secondary keeping) within the temperature range;
cooling (tertiary cooling) to a temperature range of 100-300 ℃ (secondary cooling termination temperature) at an average cooling rate of 2 ℃/second or higher;
heating to the temperature range of 300-500 ℃ (secondary heating), and keeping the temperature range for more than 50 seconds (three times of keeping); and
cool to room temperature (four times cool).
7. The method for manufacturing a high-strength steel sheet excellent in workability according to claim 6, wherein the cold-rolled steel sheet further comprises any one or more of the following (1) to (9):
(1) ti: 0-0.5%, Nb: 0-0.5% and V: 0-0.5% of one or more,
(2) cr: 0-3.0% and Mo: 0-3.0% of one or more of,
(3) cu: 0-4.5% and Ni: 0-4.5% of one or more of,
(4)B：0-0.005％，
(5) ca: 0-0.05%, REM except Y: 0-0.05% and Mg: 0-0.05% of one or more of,
(6) w: 0-0.5% and Zr: 0-0.5% of one or more of,
(7) sb: 0-0.5% and Sn: 0-0.5% of one or more of,
(8) y: 0-0.2% and Hf: 0-0.2% of one or more of,
(9)Co：0-1.5％。
8. the method for manufacturing a high-strength steel sheet excellent in workability according to claim 6, wherein the total content of the Si and the Al contained in the cold-rolled steel sheet (Si + Al) is 1.0 to 6.0% by weight.
9. The method for manufacturing a high-strength steel sheet excellent in workability according to claim 6, wherein the cold-rolled steel sheet is provided by:
heating the steel billet to 1000-1350 ℃;
performing hot finish rolling within the temperature range of 800-;
rolling the hot rolled steel plate within the temperature range of 300-600 ℃;
carrying out hot rolling annealing heat treatment on the coiled steel plate within the temperature range of 650-850 ℃ for 600-1700 seconds; and
cold rolling the hot-rolled annealed steel sheet at a reduction ratio of 30 to 90%.
10. The method for manufacturing a high-strength steel sheet excellent in workability according to claim 6, wherein the cooling rate of the primary cooling (Vc1) and the cooling rate of the secondary cooling (Vc2) satisfy a relationship of Vc1< Vc 2.
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| KR10-2019-0169610 | 2019-12-18 | ||
| PCT/KR2020/016849 WO2021125604A1 (en) | 2019-12-18 | 2020-11-25 | High strength steel sheet having excellent workability and method for manufacturing same |
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| WO2021125604A1 (en) | 2021-06-24 |
| EP4079894A4 (en) | 2023-05-10 |
| JP7442645B2 (en) | 2024-03-04 |
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| KR102348529B1 (en) | 2022-01-07 |
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