CN114836695A - 180 MPa-grade non-leakage plating ultralow-carbon hot-dip galvanized steel strip and production method thereof - Google Patents

180 MPa-grade non-leakage plating ultralow-carbon hot-dip galvanized steel strip and production method thereof Download PDF

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CN114836695A
CN114836695A CN202210589204.8A CN202210589204A CN114836695A CN 114836695 A CN114836695 A CN 114836695A CN 202210589204 A CN202210589204 A CN 202210589204A CN 114836695 A CN114836695 A CN 114836695A
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冯帆
刘帅
尹翠兰
张磊
王鹏
康华伟
丁明凯
何召东
孙冰
程威
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SD Steel Rizhao Co Ltd
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    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
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    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
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    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/02Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
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    • C21D8/0236Cold rolling
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    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
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    • C22C38/00Ferrous alloys, e.g. steel alloys
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    • C22C38/14Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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Abstract

The invention discloses a 180 MPa-grade non-plating-leakage ultra-low carbon hot-dip galvanized steel strip and a production method thereof, wherein the steel strip comprises the following chemical components in percentage by mass: less than or equal to 0.0035 percent, Si: less than or equal to 0.03 percent, Mn: 0.30% -0.50%, P: 0.03% -0.05%, S: less than or equal to 0.010 percent, Alt: 0.020% -0.060%, Ti: 0.02% -0.04%, Nb: 0.020% -0.035%, B: 0.0005% -0.0015%, N: less than or equal to 0.004 percent, and the balance of Fe, inevitable impurities and residual elements. The steel strip is obtained through the following steps, hot rolling is carried out, the heating time of a plate blank in a heating furnace is divided according to a furnace loading mode, a plate blank state and a furnace temperature state, the hot material is 140-260 min, the cold material is 170-280 min, the plate blank discharging temperature is divided according to the types of rolled steel, the temperature of high-strength ultra-low carbon steel is set to be 1180-1220 ℃, and the generation amount of iron oxide scales is reduced by controlling the plate blank discharging temperature; acid rolling, namely adopting three-section type turbulent acid washing, and controlling the temperature of acid liquor at 70-90 ℃; the pickling speed is 100 m/min-170 m/min; galvanizing, and continuously annealing, wherein the soaking temperature is set to be 810-830 ℃, the slow cooling temperature is 680-700 ℃, and the fast cooling temperature is 480-500 ℃.

Description

180 MPa-grade non-leakage plating ultralow-carbon hot-dip galvanized steel strip and production method thereof
Technical Field
The invention belongs to the technical field of steel rolling, and particularly relates to a 180 MPa-level non-leakage plating ultralow-carbon hot-dip galvanized steel strip and a production method thereof.
Background
At present, high-strength ultra-low carbon hot-dip galvanized steel sheets are widely applied to industries such as automobiles, household electrical appliances and the like due to good appearance and corrosion resistance. With the continuous improvement of the surface quality of a hot-dip galvanized steel plate, customers have higher and higher requirements on the surface of the hot-dip galvanized steel plate, and skip plating is a common defect in the production of the hot-dip galvanized steel plate, which not only affects the product appearance, but also reduces the corrosion resistance of the steel plate, thereby affecting the service life of the product, so that the reduction of the skip plating defect is the key for improving the surface quality of the hot-dip galvanized substrate.
In "a hot-dip galvanized high-strength IF steel for 340MPa class car spare tire bottom plate and a preparation method thereof" with patent number CN 113528934A, 340MPa class hot-dip galvanized high-strength IF steel is obtained by adopting a low-silicon and high-manganese component system, but the surface requirement of no plating leakage of steel produced by the component system is not shown.
The patent No. CN 113106328A discloses a production method for obtaining 180 MPa-grade hot-galvanized high-strength IF steel by adopting a Nb + Ti composite component system, the silicon content and the curling temperature of the patent are higher, the atmosphere of an annealing furnace is not described, and the risk of plating leakage is increased.
The high-strength ultra-low carbon hot-dip galvanized steel is prepared by adding solid solution strengthening elements on the basis of ultra-low carbon steel, the produced steel plate has good formability and high strength, can meet the requirements of stamping of complex automobile parts and manufacturing of stamping parts with high strength, and the thickness of the automobile stamping parts can be properly reduced by using the steel plate so as to reduce the self weight of automobiles and carbon emission and obtain good economic benefits.
With the continuous improvement of the capability of producing high-quality automobiles in China, the automobile manufacturing industry in China puts forward higher requirements on the coating performance and the corrosion resistance of the surface quality of the automobiles and the surface quality of steel plates. Under the double pressure of carbon emission reduction and increasingly higher steel production cost competition, the total weight of the automobile is always developed towards light weight. With the proposal of light weight of automobiles, the reduction of the supply thickness and the improvement of the performance of a non-leakage plating high-strength ultra-low carbon hot-dip galvanized steel strip serving as an automobile substrate are trends of production and development, and higher requirements are put forward for the production of steel supply enterprises. How to provide a steel plate with stable strength, no plating leakage defect and good surface quality on the premise of reducing the cost is a common problem for steel supply enterprises.
Disclosure of Invention
The invention aims to provide a 180 MPa-grade non-leakage plating ultralow-carbon hot-dip galvanized steel strip and a production method thereof.
The technical scheme adopted by the invention for solving the technical problems is as follows: a180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip comprises the following chemical components in percentage by mass: less than or equal to 0.0035 percent, Si: less than or equal to 0.03 percent, Mn: 0.30% -0.50%, P: 0.03% -0.05%, S: less than or equal to 0.010%, Alt: 0.020% -0.060%, Ti: 0.02% -0.04%, Nb: 0.020% -0.035%, B: 0.0005% -0.0015%, N: less than or equal to 0.004 percent, and the balance of Fe, inevitable impurities and residual elements.
A production method of 180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip comprises the following steps:
1) hot rolling, namely dividing the heating time of the plate blank in a heating furnace according to a furnace loading mode, a plate blank state and a furnace temperature state, dividing hot materials for 140-260 min and cooling materials for 170-280 min, dividing the plate blank discharging temperature according to various types of rolled steel, setting the temperature of high-strength ultra-low carbon steel to be 1180-1220 ℃, and reducing the generation amount of iron scale by controlling the plate blank discharging temperature;
2) acid rolling, namely adopting three-section type turbulent acid washing, and controlling the temperature of acid liquor at 70-90 ℃; the pickling speed is 100 m/min-170 m/min;
3) galvanizing, and continuously annealing, wherein the soaking temperature is set to 810-830 ℃, the slow cooling temperature is 680-700 ℃, and the fast cooling temperature is 480-500 ℃.
Specifically, the pressure of a descaling system in hot rolling is more than or equal to 25MPa, and descaling passes are not matched according to obvious scale on the surface.
Specifically, the finish rolling temperature in the hot rolling is 920 +/-15 ℃, the finish rolling is carried out in an austenite region, and a 100% uniform ferrite structure is obtained through rolling.
Specifically, the hot rolling medium coiling adopts high-temperature U-shaped coiling, the coiling temperature of the middle part is 700 +/-15 ℃, and the coiling temperature of the head and the tail is 730 +/-15 ℃.
Specifically, the acid rolling is carried out by adopting a five-frame six-roller rolling mill, and the total cold rolling reduction rate is 60-85%.
Specifically, the method comprises the following steps of preheating, heating, soaking section, slow cooling and fast cooling section dew point in an annealing furnace in the galvanizing process: at most-35 ℃, equilibrium section dew point: at most-25 ℃, furnace nose dew point: -10 ℃ to 0 ℃.
Specifically, the galvanized steel coil is subjected to leveling treatment, and the leveling elongation is set to be 1.0% +/-0.1%.
The invention has the following beneficial effects:
1) the 180 MPa-grade non-plating-leaking ultralow-carbon hot-dip galvanized coil produced by the method has high strength, good surface quality and better stamping performance, is not easy to have the problem of zinc layer falling off in the deep processing processes of blanking forming, stamping and the like of users, and meets the use characteristics of being used as a structural steel plate.
2) The 180 MPa-grade non-plating-leaking ultralow-carbon hot-dip galvanized steel strip produced by the method has the low-silicon high-manganese component design, the lower slab tapping temperature and the lower annealing furnace atmosphere design, so that the problem that the substrate wettability is poor due to the oxidation of the surface of the steel sheet at the post-annealing stage (fast cooling, slow cooling and furnace nose) in the furnace is reduced, and the plating leakage is caused due to the poor adhesion of a zinc layer and the substrate.
Drawings
FIG. 1 is a diagram of the golden phase of the present invention.
FIG. 2 is the second diagram of the golden phase of the present invention.
FIG. 3 is a surface topography of a steel strip.
FIG. 4 is a cross-sectional view of a zinc layer.
Detailed Description
The present invention will now be described in further detail with reference to the accompanying drawings.
A180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip and a production method thereof ensure that the galvanized products meet the steel plate with yield of more than or equal to 180MPa, tensile strength of more than or equal to 340MPa, no leakage plating defect and good product surface and performance by reasonably designing the chemical components of the products and the production processes of hot rolling, cold rolling and zinc plating.
A180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip adopts a low-carbon, low-silicon and high-manganese component system, and comprises the following main chemical components in percentage by mass: c: less than or equal to 0.0035 percent, Si: less than or equal to 0.03 percent, Mn: 0.30% -0.50%, P: 0.03-0.05%, S: less than or equal to 0.010 percent, Alt: 0.020% -0.060%, Ti: 0.02% -0.04%, Nb: 0.020% -0.035%, B: 0.0005% -0.0015%, N: less than or equal to 0.004 percent, and the balance of Fe, inevitable impurities and residual elements.
A production method of a non-skip-plating high-strength ultralow-carbon hot-dip galvanized steel strip specifically comprises the following steps:
1) hot rolling, wherein a 230mm thick plate blank is divided according to a furnace loading mode, a plate blank state and a furnace temperature state in a heating furnace, and a hot material: 140-260 min; cooling: 170-280 min; the tapping temperature of the plate blank is divided according to the types of rolled steel, the temperature of the high-strength ultra-low carbon steel is set to 1180-1220 ℃, and the generation amount of iron scale is reduced by controlling the tapping temperature of the plate blank; the pressure of the descaling system is more than or equal to 25MPa, and descaling passes are determined according to the situation, so that no obvious scale on the upper surface is ensured; the finish rolling temperature is 920 +/-15 ℃, the finish rolling is ensured to be rolled in an austenite region, and 100 percent of uniform ferrite structure can be obtained through the rolling process; the high-temperature U-shaped curling is adopted for curling, in order to reduce the load of a coiler and the occurrence of internal oxidation phenomenon and simultaneously consider the precipitation size of second phase particles, the middle coiling temperature is set to be 700 +/-15 ℃, and the head and tail curling temperature is set to be 730 +/-15 ℃.
2) Acid rolling, wherein three-section turbulent acid washing is adopted during acid rolling, and the temperature of the acid liquor is controlled to be 70-90 ℃; the pickling speed is 100 m/min-170 m/min; and (3) carrying out cold continuous rolling by adopting a five-frame six-roller rolling mill, wherein the total rolling reduction rate of cold rolling is 60-85%, and the rolling reduction rate model of each frame is automatically calculated.
3) Galvanizing, continuously annealing the steel strip after acid rolling, setting the soaking temperature to be 810-830 ℃, the slow cooling temperature to be 680-700 ℃ and the fast cooling temperature to be 480-500 ℃; because the furnace zone atmosphere has great influence on the surface wettability of the strip steel, the atmosphere in the annealing furnace is controlled, and the dew points of the preheating, heating, soaking section, slow cooling and fast cooling sections are as follows: at most-35 ℃, the dew point of the equilibrium section: at most-25 ℃, furnace nose dew point: -10 ℃ to 0 ℃; and (3) carrying out leveling treatment on the galvanized steel coil, wherein the leveling elongation is set to be 1.0 +/-0.1%.
The invention finally obtains the 180 MPa-level steel strip without surface plating leakage through reasonable chemical component design, hot rolling process and cold rolling process control, and the obtained hot-dip galvanized steel strip has the performance meeting the requirements and meets the actual use requirements of being used as a high-strength stamping steel plate.
Examples 1 to 3
In each example, molten steel having required chemical compositions was obtained by KR desulfurization, converter smelting and RH refining, and the specific compositions of each example are shown in table 1.
Figure BDA0003664421660000041
TABLE 1 Main chemical composition Table of molten steel in examples 1 to 3
The main process parameters of hot rolling of each example are shown in table 2.
Figure BDA0003664421660000042
TABLE 2 Hot Rolling parameters in examples 1-3
The specific acid rolling and temper rolling process parameters for each example are shown in table 3.
Figure BDA0003664421660000043
TABLE 3 parameters of the acid rolling process in examples 1-3
The specific annealing and galvanizing process parameters for each example are shown in table 4.
Figure BDA0003664421660000044
TABLE 4 annealing and galvanizing process parameters of examples 1-3
The 180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel product can be produced by controlling the process parameters, the product is sampled and analyzed, the performance result is shown in Table 5, and the microstructure is shown in figures 1-2.
Yield strength/MPa Tensile strength/MPa Whether the surface is under plating or not
The invention 180~240 340~390 Whether or not
Example 1 215 353 Whether or not
Example 2 214 354 Whether or not
Example 3 205 361 Whether or not
TABLE 5 Properties of the products of examples 1-3
The prepared steel strip is observed by a scanning electron microscope, and the effect graphs are shown in figures 3 and 4.
According to the invention, through the design of the main chemical components in percentage by mass of the 180 MPa-level non-leakage plating ultralow-carbon hot-dip galvanized steel strip, the silicon content is reduced on the basis of the traditional component design, and the influence of silicon on the surface quality of a zinc layer during hot-dip galvanizing is reduced.
The specific production process of the 180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip adopts the crimping temperature of 700 +/-15 ℃, reduces the load of a coiler and the phenomenon of internal oxidation, and simultaneously gives consideration to the precipitation size of second phase particles; the generation amount of iron scale is reduced by adopting lower plate blank tapping temperature (1200 +/-20 ℃); in addition, the lower annealing furnace atmosphere reduces the defect of plating leakage caused by the oxidation of the surface of the steel plate at the later annealing stage (fast cooling, slow cooling and furnace nose) in the furnace.
The present invention is not limited to the above embodiments, and any structural changes made under the teaching of the present invention shall fall within the scope of the present invention, which is similar or similar to the technical solutions of the present invention.
The techniques, shapes, and configurations not described in detail in the present invention are all known techniques.

Claims (8)

1. A180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip comprises the following chemical components in percentage by mass: less than or equal to 0.0035 percent, Si: less than or equal to 0.03 percent, Mn: 0.30% -0.50%, P: 0.03% -0.05%, S: less than or equal to 0.010 percent, Alt: 0.020% -0.060%, Ti: 0.02% -0.04%, Nb: 0.020% -0.035%, B: 0.0005% -0.0015%, N: less than or equal to 0.004 percent, and the balance of Fe, inevitable impurities and residual elements.
2. A production method of 180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip is characterized by comprising the following steps:
1) hot rolling, namely dividing the heating time of the plate blank in a heating furnace according to a furnace loading mode, a plate blank state and a furnace temperature state, dividing hot materials for 140-260 min and cooling materials for 170-280 min, dividing the plate blank discharging temperature according to various types of rolled steel, setting the temperature of high-strength ultra-low carbon steel to be 1180-1220 ℃, and reducing the generation amount of iron scale by controlling the plate blank discharging temperature;
2) acid rolling, namely adopting three-section type turbulent acid washing, and controlling the temperature of acid liquor at 70-90 ℃; the pickling speed is 100 m/min-170 m/min;
3) galvanizing, and continuously annealing, wherein the soaking temperature is set to 810-830 ℃, the slow cooling temperature is 680-700 ℃, and the fast cooling temperature is 480-500 ℃.
3. The production method of the 180 MPa-grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip as claimed in claim 2, characterized in that the pressure of a descaling system in hot rolling is more than or equal to 25MPa, and descaling passes are matched according to no obvious scale on the surface.
4. The method for producing the 180MPa grade non-leakage plating ultra-low carbon hot dip galvanized steel strip is characterized in that the finish rolling temperature in the hot rolling is 920 +/-15 ℃, the finish rolling is carried out in an austenite region, and a uniform ferrite structure with the concentration of 100% is obtained through rolling.
5. The method for producing the 180MPa grade non-leakage plating ultra-low carbon hot dip galvanized steel strip according to claim 2, characterized in that the hot rolling medium coil adopts high temperature U-shaped coil, the middle coil temperature is 700 +/-15 ℃, and the head and tail coil temperature is 730 +/-15 ℃.
6. The production method of the 180 MPa-grade non-leakage plating ultra-low carbon hot galvanized steel strip as claimed in claim 2, characterized in that the acid rolling is carried out by adopting a five-stand six-roller mill for cold continuous rolling, and the total cold rolling reduction rate is 60-85%.
7. The production method of the 180MPa grade non-leakage plating ultra-low carbon hot dip galvanized steel strip as claimed in claim 2, characterized in that the dew point of the preheating, heating, soaking, slow cooling and fast cooling sections in the annealing furnace in the galvanizing is as follows: at most-35 ℃, equilibrium section dew point: at most-25 ℃, furnace nose dew point: -10 ℃ to 0 ℃.
8. The method for producing 180MPa grade non-leakage plating ultra-low carbon hot-dip galvanized steel strip according to claim 2, characterized in that the galvanized steel strip is subjected to leveling treatment, and the leveling elongation is set to be 1.0% ± 0.1%.
CN202210589204.8A 2022-05-26 2022-05-26 180 MPa-grade non-leakage plating ultralow-carbon hot-dip galvanized steel strip and production method thereof Pending CN114836695A (en)

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Citations (5)

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JP2004232065A (en) * 2003-01-31 2004-08-19 Sumitomo Metal Ind Ltd Hot dip galvanized steel sheet, and production method therefor
CN101684533A (en) * 2008-09-27 2010-03-31 鞍钢股份有限公司 High strength cold-rolled plate with excellent formability and production method thereof
CN110592492A (en) * 2019-10-17 2019-12-20 山东钢铁集团日照有限公司 Production method of ultra-deep drawing hot-dip galvanized steel for automobile roof
WO2020195012A1 (en) * 2019-03-25 2020-10-01 日本製鉄株式会社 Steel sheet for hot stamping use
CN114107806A (en) * 2021-10-29 2022-03-01 马鞍山钢铁股份有限公司 450 MPa-grade hot-galvanized dual-phase steel with high work hardening rate and surface quality and production method thereof

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CN101684533A (en) * 2008-09-27 2010-03-31 鞍钢股份有限公司 High strength cold-rolled plate with excellent formability and production method thereof
WO2020195012A1 (en) * 2019-03-25 2020-10-01 日本製鉄株式会社 Steel sheet for hot stamping use
CN110592492A (en) * 2019-10-17 2019-12-20 山东钢铁集团日照有限公司 Production method of ultra-deep drawing hot-dip galvanized steel for automobile roof
CN114107806A (en) * 2021-10-29 2022-03-01 马鞍山钢铁股份有限公司 450 MPa-grade hot-galvanized dual-phase steel with high work hardening rate and surface quality and production method thereof

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Application publication date: 20220802