CN114834116A - Light-transmitting composite resin plate capable of being thermally repaired and preparation method thereof - Google Patents
Light-transmitting composite resin plate capable of being thermally repaired and preparation method thereof Download PDFInfo
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- CN114834116A CN114834116A CN202210252398.2A CN202210252398A CN114834116A CN 114834116 A CN114834116 A CN 114834116A CN 202210252398 A CN202210252398 A CN 202210252398A CN 114834116 A CN114834116 A CN 114834116A
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- plate
- resin plate
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47B—TABLES; DESKS; OFFICE FURNITURE; CABINETS; DRAWERS; GENERAL DETAILS OF FURNITURE
- A47B96/00—Details of cabinets, racks or shelf units not covered by a single one of groups A47B43/00 - A47B95/00; General details of furniture
- A47B96/20—Furniture panels or like furniture elements
- A47B96/205—Composite panels, comprising several elements joined together
- A47B96/206—Composite panels, comprising several elements joined together with laminates comprising planar, continuous or separate layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C63/00—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor
- B29C63/02—Lining or sheathing, i.e. applying preformed layers or sheathings of plastics; Apparatus therefor using sheet or web-like material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Lining Or Joining Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a light-transmitting composite resin plate capable of being thermally repaired and a preparation method thereof, wherein the light-transmitting composite resin plate capable of being thermally repaired is formed by fixing and compounding a resin plate layer and an acrylic plate layer through an adhesive; the acrylic plate layer adopts a transparent acrylic plate, a groove can be milled on the transparent acrylic plate, and a lamp strip is concealed so as to manufacture a lighting effect. A layer of adhesive is uniformly coated between the resin plate layer and the acrylic plate layer, and the thickness is 0.5 mm. The adhesive is double-component solvent-free polyurethane adhesive. The resin plate layer is a thermosetting resin plate capable of being thermally repaired. The invention also provides a preparation method of the heat-repairable light-transmitting composite resin plate. The heat-recoverable light-transmitting composite resin plate and the preparation method thereof provided by the invention not only keep the physical characteristics and the use experience of the heat-recoverable thermosetting resin plate, but also increase the physical characteristics of the transparent acrylic plate, and can also produce gorgeous lighting effects and enrich the application modes of materials.
Description
Technical Field
The invention relates to a healthy and environment-friendly composite board for home decoration and a preparation method thereof, in particular to a heat-repairable light-transmitting composite resin board and a preparation method thereof.
Background
In the field of decorative materials for the universal home, an important component is various table tops, in particular to table tops of various furniture, cabinet table tops, bathroom cabinet table tops and the like.
At present, marble, rock plates, toughened glass and the like are mostly adopted on various furniture table tops, cabinets and bathroom cabinet table tops in the market. With the rise of the extremely simple style in the domestic market and the popularity of personalized advanced customization, people have higher requirements on the home lighting atmosphere. The conventional materials such as marble, rock plate, toughened glass and the like cannot meet the household decoration requirements of high-definition people, so that more innovative development is needed.
Disclosure of Invention
The invention aims to provide a composite resin plate for various table tops in the field of home decoration materials and a preparation method thereof, which not only keep the physical characteristics and the use experience of a thermosetting resin plate capable of being thermally repaired, but also increase the physical characteristics of a transparent acrylic plate, can produce gorgeous lighting effects and enrich the application modes of materials.
In order to achieve the purpose, the invention provides a light-transmitting composite resin plate capable of being thermally repaired, wherein the composite plate is formed by fixing and compounding a resin plate layer and an acrylic plate layer through an adhesive; the acrylic plate layer adopts a transparent acrylic plate, a groove can be milled on the transparent acrylic plate, and a lamp strip is concealed so as to manufacture a lighting effect.
The light-transmitting composite resin plate capable of being thermally repaired is characterized in that a layer of adhesive is uniformly coated between the resin plate layer and the acrylic plate layer, and the thickness of the adhesive is 0.5 mm.
In the above thermally-repairable light-transmitting composite resin plate, the adhesive is a two-component solvent-free polyurethane adhesive.
The heat-recoverable light-transmitting composite resin plate is characterized in that the thickness of the resin plate layer is 2-2.5 mm, and the thickness of the acrylic plate layer is 5-7.5 mm.
The above-mentioned light-transmitting composite resin plate capable of being thermally repaired is characterized in that the resin plate layer is a thermosetting resin plate capable of being thermally repaired.
The invention also provides a preparation method of the light-transmitting composite resin plate capable of being thermally repaired, wherein the method comprises the following steps: step 1, selecting a transparent acrylic plate and a thermosetting resin plate capable of being thermally repaired, processing the transparent acrylic plate and the thermosetting resin plate into the same size, and respectively placing the transparent acrylic plate and the thermosetting resin plate flatly; step 2, cleaning the surfaces of the transparent acrylic plate and the resin plate respectively, and drying; step 3, coating an adhesive on the surface of one side to be bonded of the transparent acrylic plate, placing the resin plate on the adhesive, aligning and compounding; step 4, putting the composite plate on a cold press, pressurizing and maintaining pressure until the adhesive is completely dried; step 5, scraping the dried and solidified adhesive overflowing from the compounded plate to finish correction; and 6, performing heat sealing on the surface of the plate through a plastic film to protect the composite plate, and finally obtaining the heat-repairable light-transmitting composite resin plate.
In the step 2, the dirt on the surfaces to be bonded of the transparent acrylic plate and the resin plate is respectively cleaned by acetone or ethyl acetate, and then the transparent acrylic plate and the resin plate are air-dried or naturally air-dried.
In the step 3, a nylon brush is adopted to uniformly coat a layer of adhesive on the surface of one side of the transparent acrylic plate to be bonded.
In the step 4, the composite plate is placed on a workbench of a cold press, a 60-ton cold press with the specification of 2500 x 1250mm is adopted to pressurize to 5MPa, and the pressure is maintained for 12 hours until the adhesive is completely dried.
In the step 6, the polyethylene film is heat-sealed and shrunk to the surface of the plate to protect the composite plate.
The heat-repairable light-transmitting composite resin plate and the preparation method thereof provided by the invention have the following advantages:
(1) health, environmental protection, safety, sanitation, no radiation and no toxicity.
(2) The super-matte surface is soft and comfortable to touch and has no residual fingerprints.
(3) Slight scratches appear, and the surface of the plate can be repaired automatically by sprinkling and wiping the plate with hot water at 60-80 ℃.
(4) The light transmission surface is machined, grooves are milled, the lamp belt is hidden, and gorgeous lighting effects can be manufactured.
(5) Easy processing, can be cut into various patterns, and can drill holes, edge grind, mill grooves and the like.
Drawings
Fig. 1 is a schematic structural view of a light-transmitting composite resin plate capable of being thermally repaired according to the present invention.
Wherein, 1, a transparent acrylic plate; 2. a heat-repairable thermosetting resin sheet; 3. and (3) an adhesive.
Detailed Description
The following further describes embodiments of the present invention with reference to the drawings.
The invention provides a light-transmitting composite resin plate capable of being thermally repaired, which is formed by fixedly compounding a resin plate layer and an acrylic plate layer through an adhesive 3; the acrylic plate layer adopts a transparent acrylic plate 1.
A layer of adhesive 3 is uniformly coated between the resin plate layer and the acrylic plate layer, and the thickness is 0.5 mm. The adhesive is a two-component solvent-free polyurethane adhesive.
The double-component solvent-free polyurethane adhesive adopts low molecular weight polyol and polyisocyanate, or NCO-terminated prepolymer and polyol or polyamine, and is superior to an epoxy adhesive in the aspects of flexibility, absorbable stress, substrate bonding performance and the like.
The polyurethane adhesive refers to an adhesive containing urethane groups or isocyanate groups in molecular chains, and the polyurethane adhesive can be divided into a single component and a double component according to the using mode. The double-component polyurethane adhesive is generally composed of a component A and a component B, wherein the component A (main agent) is a component containing active hydrogen, and the component B (curing agent) is a polyurethane prepolymer component containing-NCO groups. The double-component polyurethane adhesive belongs to a reactive adhesive, and the two components are mixed to generate a crosslinking reaction to be cured and bonded.
Preferably, the thickness of the resin plate layer is 2-2.5 mm, and the thickness of the acrylic plate layer is 5-7.5 mm.
The resin plate layer adopts a thermosetting resin plate 2 which can be thermally repaired.
The invention also provides a preparation method of the heat-repairable light-transmitting composite resin plate, which comprises the following steps: step 1, selecting a transparent acrylic plate 1 and a thermosetting resin plate 2 capable of being thermally repaired, processing the transparent acrylic plate and the thermosetting resin plate into the same size, and respectively placing the transparent acrylic plate and the thermosetting resin plate flatly; step 2, cleaning the surfaces of the transparent acrylic plate and the resin plate respectively, and drying; step 3, coating an adhesive 3 on the surface of one side to be bonded of the transparent acrylic plate, then placing the resin plate on the adhesive, aligning and compounding; step 4, putting the composite plate on a cold press, pressurizing and maintaining pressure until the adhesive is completely dried; step 5, scraping off dried and solidified adhesive overflowing from the compounded plate to finish correction; and 6, performing heat sealing on the surface of the plate through a plastic film to protect the composite plate, and finally obtaining the heat-repairable light-transmitting composite resin plate.
And in the step 2, cleaning dirt on the surfaces to be bonded of the transparent acrylic plate and the resin plate respectively by using acetone or ethyl acetate, and then air-drying or naturally airing.
And 3, uniformly brushing a layer of adhesive on the surface of the side to be bonded of the transparent acrylic plate by using a high-quality nylon brush.
And 4, placing the composite plate on a workbench of a cold press, pressurizing to 5MPa by adopting a 60-ton cold press with the specification of 2500 x 1250mm, and maintaining the pressure for 12 hours until the adhesive is completely dried.
And 7, adopting a Polyethylene (PE) film for heat sealing and shrinking to the surface of the plate to protect the composite plate.
The production equipment and other process conditions employed in the present invention are known to those skilled in the art.
The following describes the heat-recoverable light-transmitting composite resin plate and the method for manufacturing the same in accordance with the present invention.
Example 1
A light-transmitting composite resin plate capable of being thermally repaired is formed by fixing and compounding a resin plate layer and an acrylic plate layer through an adhesive; the acrylic plate layer adopts a transparent acrylic plate.
A layer of adhesive is uniformly coated between the resin plate layer and the acrylic plate layer, and the thickness is 0.5 mm.
The adhesive is double-component solvent-free polyurethane adhesive.
The thickness of the resin plate layer is 2mm, and the thickness of the acrylic plate layer is 5 mm.
The resin plate layer is a thermosetting resin plate capable of being thermally repaired.
The embodiment also provides a preparation method of the heat-repairable light-transmitting composite resin plate, which comprises the following steps:
And 2, respectively cleaning the surfaces of the transparent acrylic plate and the resin plate, and drying.
Preferably, the dirt on the surfaces to be bonded of the transparent acrylic plate and the resin plate is respectively cleaned by acetone and then naturally dried.
And 3, uniformly brushing a layer of adhesive on the surface of one side to be bonded of the transparent acrylic plate by using a nylon brush, placing the resin plate on the adhesive, aligning and compounding.
And 4, placing the composite plate on a workbench of a cold press, pressurizing to 5MPa by adopting a 60-ton cold press with the specification of 2500 multiplied by 1250mm, and maintaining the pressure for 12 hours until the adhesive is completely dried.
And 5, scraping the dried and solidified adhesive overflowing from the compounded plate to finish correction.
Step 6, performing heat sealing on the surface of the plate through a plastic film to protect the composite plate; namely, a PE film is adopted to shrink to the surface of the plate through heat sealing, the composite plate is protected, and finally the light-transmitting composite resin plate capable of being thermally repaired is obtained.
Example 2
A light-transmitting composite resin plate capable of being thermally repaired is formed by fixing and compounding a resin plate layer and an acrylic plate layer through an adhesive; the acrylic plate layer adopts a transparent acrylic plate.
A layer of adhesive is uniformly coated between the resin plate layer and the acrylic plate layer, and the thickness is 0.5 mm.
The adhesive is double-component solvent-free polyurethane adhesive.
The thickness of the resin plate layer is 2.2mm, and the thickness of the acrylic plate layer is 6.8 mm.
The resin plate layer is a thermosetting resin plate capable of being thermally repaired.
The embodiment also provides a preparation method of the heat-repairable light-transmitting composite resin plate, which comprises the following steps:
And 2, respectively cleaning the surfaces of the transparent acrylic plate and the resin plate, and drying.
Preferably, the dirt on the surfaces to be bonded of the transparent acrylic plate and the resin plate is washed with ethyl acetate and then air-dried.
And 3, uniformly brushing a layer of adhesive on the surface of one side to be bonded of the transparent acrylic plate by using a nylon brush, placing the resin plate on the adhesive, aligning and compounding.
And 4, placing the composite plate on a workbench of a cold press, pressurizing to 5MPa by adopting a 60-ton cold press with the specification of 2500 multiplied by 1250mm, and maintaining the pressure for 12 hours until the adhesive is completely dried.
And 5, scraping the dried and solidified adhesive overflowing from the compounded plate to finish correction.
Step 6, performing heat sealing on the surface of the plate through a plastic film to protect the composite plate; namely, a PE film is adopted to shrink to the surface of the plate through heat sealing, the composite plate is protected, and finally the light-transmitting composite resin plate capable of being thermally repaired is obtained.
Example 3
A light-transmitting composite resin plate capable of being thermally repaired is formed by fixing and compounding a resin plate layer and an acrylic plate layer through an adhesive; the acrylic plate layer adopts a transparent acrylic plate, grooves are milled on the transparent acrylic plate, and lamp strips are concealed in the grooves to manufacture a lighting effect.
A layer of adhesive is uniformly coated between the resin plate layer and the acrylic plate layer, and the thickness is 0.5 mm.
The adhesive is double-component solvent-free polyurethane adhesive.
The thickness of the resin plate layer is 2.5mm, and the thickness of the acrylic plate layer is 7.5 mm.
The resin plate layer is a thermosetting resin plate capable of being thermally repaired.
The embodiment also provides a preparation method of the heat-repairable light-transmitting composite resin plate, which comprises the following steps:
And 2, respectively cleaning the surfaces of the transparent acrylic plate and the resin plate, and drying.
Preferably, the dirt on the surfaces to be bonded of the transparent acrylic plate and the resin plate is respectively cleaned by ethyl acetate and then naturally dried.
And 3, uniformly brushing a layer of adhesive on the surface of one side to be bonded of the transparent acrylic plate by using a nylon brush, placing the resin plate on the adhesive, aligning and compounding.
And 4, placing the composite plate on a workbench of a cold press, pressurizing to 5MPa by adopting a 60-ton cold press with the specification of 2500 multiplied by 1250mm, and maintaining the pressure for 12 hours until the adhesive is completely dried.
And 5, scraping the dried and solidified adhesive overflowing from the compounded plate to finish correction.
And 6, milling grooves on an acrylic plate layer formed by the transparent acrylic plate, and mounting a built-in lamp strip to manufacture a lighting effect.
Step 7, performing heat sealing on the surface of the plate through a plastic film to protect the composite plate; namely, a PE film is adopted to shrink to the surface of the plate through heat sealing, the composite plate is protected, and finally the light-transmitting composite resin plate capable of being thermally repaired is obtained.
The functional test is carried out on the composite board finished product obtained by the embodiment of the invention, and the result proves that the composite board is non-radiative and non-toxic, and no fingerprint is left on the surface of the super-matte surface. Slight scratch appears, and the surface of the plate can be automatically repaired by sprinkling and wiping the plate with hot water of 60-80 ℃.
According to the heat-recoverable light-transmitting composite resin plate and the preparation method thereof, provided by the invention, through the combination of the heat-recoverable thermosetting resin plate and the transparent acrylic plate, the physical characteristics and the use experience of the heat-recoverable thermosetting resin plate are kept, the physical characteristics of the transparent acrylic plate are enhanced, and through milling the grooves and embedding the lamp strips, the gorgeous lighting effect can be manufactured, and the application mode of the material is enriched.
While the present invention has been described in detail with reference to the preferred embodiments, it should be understood that the above description should not be taken as limiting the invention. Various modifications and alterations to this invention will become apparent to those skilled in the art upon reading the foregoing description. Accordingly, the scope of the invention should be determined from the following claims.
Claims (10)
1. The light-transmitting composite resin plate capable of being thermally repaired is characterized in that the composite plate is formed by fixedly compounding a resin plate layer and an acrylic plate layer through an adhesive; the acrylic plate layer adopts a transparent acrylic plate.
2. The thermally repairable light transmitting composite resin plate according to claim 1, wherein an adhesive is uniformly applied between the resin plate layer and the acrylic plate layer, and the thickness of the adhesive is 0.5 mm.
3. The thermally repairable light transmitting composite resin plate according to claim 2, wherein the adhesive is a two-component solvent-free polyurethane adhesive.
4. The thermally repairable light transmitting composite resin sheet according to claim 2, wherein the resin sheet layer has a thickness of 2 to 2.5mm and the acrylic sheet layer has a thickness of 5 to 7.5 mm.
5. The thermally repairable light transmitting composite resin sheet according to claim 4, wherein the resin sheet layer is a thermally repairable thermosetting resin sheet.
6. A method for preparing the heat-repairable light-transmitting composite resin plate according to any one of claims 1 to 5, wherein the method comprises:
step 1, selecting a transparent acrylic plate and a thermosetting resin plate capable of being thermally repaired, processing the transparent acrylic plate and the thermosetting resin plate into the same size, and respectively placing the transparent acrylic plate and the thermosetting resin plate flatly;
step 2, cleaning the surfaces of the transparent acrylic plate and the resin plate respectively, and drying;
step 3, coating an adhesive on the surface of one side to be bonded of the transparent acrylic plate, placing the resin plate on the adhesive, aligning and compounding;
step 4, putting the composite plate on a cold press, pressurizing and maintaining pressure until the adhesive is completely dried;
step 5, scraping off dried and solidified adhesive overflowing from the compounded plate to finish correction;
and 6, performing heat sealing on the surface of the plate through a plastic film to protect the composite plate, and finally obtaining the heat-repairable light-transmitting composite resin plate.
7. The method for preparing a heat-repairable light-transmitting composite resin plate according to claim 6, wherein in the step 2, the transparent acrylic plate and the resin plate are respectively cleaned with acetone or ethyl acetate to remove dirt on the surfaces to be bonded, and then air-dried or naturally air-dried.
8. The method for preparing a light-transmitting composite resin plate capable of being thermally repaired according to claim 6, wherein in the step 3, a nylon brush is used to uniformly brush a layer of adhesive on the surface of the transparent acrylic plate to be bonded.
9. The method for manufacturing a light-transmitting composite resin plate capable of being thermally repaired according to claim 6, wherein in the step 4, the composite plate is placed on a worktable of a cold press, a 60-ton cold press with a specification of 2500 x 1250mm is adopted to pressurize to 5MPa, and the pressure is maintained for 12 hours until the adhesive is completely dried.
10. The method for preparing a heat-repairable light-transmitting composite resin plate according to claim 6, wherein in the step 7, the polyethylene film is heat-sealed and shrunk to the surface of the plate to protect the composite plate.
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CN202210252398.2A CN114834116A (en) | 2022-03-15 | 2022-03-15 | Light-transmitting composite resin plate capable of being thermally repaired and preparation method thereof |
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CN202210252398.2A CN114834116A (en) | 2022-03-15 | 2022-03-15 | Light-transmitting composite resin plate capable of being thermally repaired and preparation method thereof |
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CN109910381A (en) * | 2019-03-07 | 2019-06-21 | 安徽迈明亚克力科技有限公司 | A kind of acrylic composite board production technology |
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2022
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CN102717564A (en) * | 2012-05-30 | 2012-10-10 | 常州星易迪商贸有限公司 | Acrylic composite decorating board and preparation technology thereof |
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CN104877309A (en) * | 2015-05-14 | 2015-09-02 | 广东药学院 | Self-healing composite material based on surface modification microencapsulation and preparation method thereof |
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