CN114806729A - Preparation method of carbon deposition cleaning agent for vehicle - Google Patents

Preparation method of carbon deposition cleaning agent for vehicle Download PDF

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Publication number
CN114806729A
CN114806729A CN202210493315.9A CN202210493315A CN114806729A CN 114806729 A CN114806729 A CN 114806729A CN 202210493315 A CN202210493315 A CN 202210493315A CN 114806729 A CN114806729 A CN 114806729A
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parts
agent
cleaning agent
vehicle
cleaning
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黄文俊
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Chexiaohu Shanghai Technology Co ltd
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Chexiaohu Shanghai Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00Details of bottles or jars not otherwise provided for
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D23/00Details of bottles or jars not otherwise provided for
    • B65D23/04Means for mixing or for promoting flow of contents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D41/00Caps, e.g. crown caps or crown seals, i.e. members having parts arranged for engagement with the external periphery of a neck or wall defining a pouring opening or discharge aperture; Protective cap-like covers for closure members, e.g. decorative covers of metal foil or paper
    • B65D41/02Caps or cap-like covers without lines of weakness, tearing strips, tags, or like opening or removal devices
    • B65D41/04Threaded or like caps or cap-like covers secured by rotation
    • B65D41/0435Threaded or like caps or cap-like covers secured by rotation with separate sealing elements
    • B65D41/0442Collars or rings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D53/00Sealing or packing elements; Sealings formed by liquid or plastics material
    • B65D53/02Collars or rings
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/14Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/18Hydrocarbons
    • C11D3/182Hydrocarbons branched
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2034Monohydric alcohols aromatic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/30Amines; Substituted amines ; Quaternized amines
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/3409Alkyl -, alkenyl -, cycloalkyl - or terpene sulfates or sulfonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/362Phosphates or phosphites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/123Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/34Derivatives of acids of phosphorus
    • C11D1/345Phosphates or phosphites
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/42Amino alcohols or amino ethers
    • C11D1/44Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
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    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/20Industrial or commercial equipment, e.g. reactors, tubes or engines

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  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
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  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a preparation method of a carbon deposition cleaning agent for a vehicle, which comprises the following raw materials in parts by weight: 4-6 parts of mixed tetramethylbenzene, 10-14 parts of high-efficiency surfactant, 6-8 parts of nonylphenol polyoxyethylene ether, 10-14 parts of isopropanol, 1.2-1.8 parts of builder, 6-8 parts of friction agent, 2-4 parts of antioxidant, 1.0-1.4 parts of antiwear agent, 1.2-1.6 parts of dispersant and 3-5 parts of corrosion inhibitor. The invention can physically rub the inner wall of the engine during cleaning, thereby accelerating the cleaning speed of the carbon deposit, improving the cleaning effect, further playing a role in physical cleaning, playing a role in lubricating to a certain extent, providing certain protection for the engine, reducing the abrasion degree of the inner wall during cleaning, and further ensuring the service life of the equipment.

Description

Preparation method of carbon deposition cleaning agent for vehicle
Technical Field
The invention relates to the technical field of carbon deposition cleaning agents, in particular to a preparation method of a carbon deposition cleaning agent for a vehicle.
Background
The fuel oil and air in the combustion chamber of the engine are mixed and then combusted, because of factors such as atomization effect, part of smoke generated after combustion is discharged, the other part of smoke forms carbon deposit and is deposited on an object, when the smoke is deposited on the surface of the object with lower temperature (such as nearby a swirler and a nozzle), soft carbon deposit can be generated, and when the smoke is deposited on the surface of the object with higher temperature (such as the wall surface of certain high-temperature area of a flame tube in the combustion chamber), hard carbon deposit can be formed through coking.
For example, Chinese patent publication No. CN102965206A discloses a carbon deposition cleaning agent applied to an engine, which comprises the following components in parts by weight: 5-20 parts of surfactant, 5-10 parts of penetrating agent, 5-15 parts of dispersant, 5-20 parts of emulsifier and 35-80 parts of organic solvent. The cleaning agent has the advantages of high efficiency, cleanness, safety, applicability, environmental protection and the like, but the cleaning of the carbon deposit can be completed in a long time, so that the cleaning time is prolonged, and partial carbon deposit is remained in a small amount, so that the cleaning is not thorough enough.
For example, chinese patent publication No. CN111117789A discloses a carbon deposition cleaning agent for an engine, which comprises the following raw materials in parts by weight: 10-20 parts of surfactant, 1-10 parts of carbon deposition microbial inoculum particles, 1-5 parts of compatilizer, 1-5 parts of active additive, 2-12 parts of friction agent and 20-60 parts of base oil, and the surfactant is used for chemical emulsification to loosen the carbon deposition; the carbon deposit is physically rubbed by using a rubbing agent to fall off; the carbon deposition microbial inoculum particles are used for carrying out biodegradation on the carbon deposition, thereby thoroughly cleaning the engine. But the physical friction mode is adopted to make the carbon deposit fall off, the cleaning effect is better, the abrasion of the inner wall of the engine is easy to accelerate, the service life of the engine is further influenced, and the equipment damage is accelerated.
Therefore, a carbon deposition cleaning agent which can shorten the cleaning time and simultaneously avoid the abrasion of the inner wall of the engine is lacked.
Disclosure of Invention
The invention aims to provide a preparation method of a carbon deposition cleaning agent for a vehicle, which aims to solve the problems in the background technology.
The technical scheme of the invention is realized as follows:
according to one aspect of the invention, a carbon deposit cleaning agent for a vehicle is provided.
The carbon deposit cleaning agent for the vehicle comprises the following raw materials in parts by weight:
4-6 parts of mixed tetramethylbenzene, 10-14 parts of high-efficiency surfactant, 6-8 parts of nonylphenol polyoxyethylene ether, 10-14 parts of isopropanol, 1.2-1.8 parts of builder, 6-8 parts of friction agent, 2-4 parts of antioxidant, 1.0-1.4 parts of antiwear agent, 1.2-1.6 parts of dispersant and 3-5 parts of corrosion inhibitor.
Further, the high-efficiency surfactant is one or a mixture of dioctyl sodium sulfosuccinate, polypropylene glycol, nonylphenol polyoxypropylene ether amine, alcohol ether phosphate or fatty alcohol-polyoxyethylene ether.
Further, the builder comprises the following raw materials in parts by weight: 0.6-0.9 part of sodium tripolyphosphate and 0.6-0.9 part of phosphorus-containing chelating agent.
Furthermore, the friction agent is one or a mixture of several of nano titanium dioxide, aluminum oxide and zirconium dioxide.
Further, the anti-wear agent is triglyceride; the dispersing agent is sodium dodecyl sulfate; the corrosion inhibitor is hexadecylamine.
Further, the antioxidant is one or a mixture of more of 4,4' -dioctyl diphenylamine, tri (2, 4-di-tert-butyl) phenyl phosphite, butylated hydroxytoluene and 2, 6-di-tert-butylphenol.
According to another aspect of the invention, a preparation method of a carbon deposit cleaning agent for a vehicle is provided, which comprises the following steps:
step S101: weighing the raw materials required by the carbon deposition cleaning agent for the vehicle according to the parts by weight;
step S103: adding mixed tetramethylbenzene into the mixture for reaction and stirring, sequentially adding a high-efficiency surfactant, nonylphenol polyoxyethylene ether, isopropanol, sodium tripolyphosphate and a phosphorus-containing chelating agent, and fully mixing and stirring for 15-25min to obtain a mixture A;
step S105: grinding and screening the friction agent, adding triglyceride into the ground friction agent, fully soaking and absorbing the triglyceride, and enabling the triglyceride to enter the micropores of the friction agent for temporary adsorption to obtain a material A;
step S107: adding the material A into the mixture A, mixing and stirring for 5-8min, sequentially adding sodium dodecyl sulfate and hexadecylamine, and fully mixing for 15-20min to obtain a mixture B;
step S109: and adding the antioxidant into the mixture B, and mixing and stirring for 6-12min to obtain the carbon deposit cleaning agent for the vehicle.
Further, the particle size of the abrasive after grinding and screening is 30-40 nm.
According to another aspect of the invention, the storage bottle for the vehicle carbon deposition cleaning agent comprises a bottle body, the interior of the bottle body is equidistantly divided into storage cavities through partition plates, sealing layers are arranged at the opening ends of the storage cavities, a rotary sealing pipe is rotatably arranged at the opening end of the bottle body, a baffle is arranged in the rotary sealing pipe through a fixing groove, a liquid outlet is formed in the baffle and corresponds to the storage cavities, a supporting plate is arranged below the baffle and located below the liquid outlet, and a bottle cover is arranged on the bottle body through the opening end through threads.
Further, sealed draw-in groove has been seted up to bottle open end equidistance, all is equipped with the sealing washer in the sealed draw-in groove to two sealing washers all are connected with rotary seal pipe.
The raw material components adopted by the invention are explained as follows:
sodium dioctyl succinate: an anionic surfactant, wetting agent is also called wetting reversal agent. Refers to a substance that reverses the wettability of a solid surface. According to the mechanism of action, the method can be divided into two types: one is to change the wettability of a solid surface by reducing adsorption of surface energy; another is to change the wettability of the solid surface by reaction;
alcohol ether phosphate ester: the special name is lauryl alcohol ether phosphate which is anionic, is usually compounded with nonionic, anionic and zwitterionic, has excellent decontamination, emulsification, dispersion, cleaning, wetting, antistatic and antirust performances and has stronger degreasing force and good stability. Acid resistance, alkali resistance, high temperature resistance, hard water resistance, inorganic salt resistance, mildness and no harm to the environment;
fatty alcohol polyoxyethylene ether: also called polyoxyethylene fatty alcohol ether, is the variety with the fastest development and the largest dosage in the nonionic surfactant. This type of surfactant is an ether formed by the condensation of polyethylene glycol with a fatty alcohol; ether bonds in molecules are not easy to be damaged by acid and alkali, so the stability is high, the water solubility is good, the electrolyte resistance is high, the biodegradation is easy, and the foam is small;
nano titanium dioxide: the cleaning agent is white loose powder, has strong ultraviolet shielding effect and good dispersibility and weather resistance, and can be matched with a cleaning agent to perform material friction cleaning and improve the cleaning effect;
nano alumina: the catalyst has high porosity, strong heat resistance, good formability, strong surface acidity and certain surface alkalinity, and is widely applied as a new green chemical material such as a catalyst, a catalyst carrier and the like. The nano aluminum oxide is white and fluffy powder, and can be matched with a cleaning agent to perform material friction cleaning, so that the cleaning effect is improved;
nano zirconium dioxide: the nanometer zirconium dioxide is nontoxic and tasteless white powder, can be divided into monoclinic phase, tetragonal phase and cubic phase according to different sintering temperatures and contents of stabilizing substances such as yttrium oxide and the like, and is dissolved in sulfuric acid and hydrofluoric acid. The nano zirconia has good dispersibility, good thermochemical stability, high-temperature conductivity, higher strength and toughness, good mechanical, thermal, electrical and optical properties, small particle size, strong stability, acid resistance, alkali resistance, corrosion resistance and high temperature resistance, can be matched with a cleaning agent to perform material friction cleaning, and improves the cleaning effect;
polyoxyethylene nonyl phenyl ether: the nonionic surfactant which is prepared by condensation reaction of nonyl phenol and ethylene oxide under the action of a catalyst is used as a cleaning agent in industries such as metal, machinery, textile and the like, and can quickly and efficiently permeate into carbon deposition of an engine to react with the carbon deposition, so that the cleaning effect is achieved;
isopropyl alcohol: the organic compound is an isomer of n-propanol, is a colorless transparent liquid, has a smell similar to a mixture of ethanol and acetone, is used in combination with the n-propanol, has excellent dissolving performance and adsorption performance on high-cohesiveness carbon deposit, decomposes colloid substances in the carbon deposit into smaller particles, increases the contact area of a dissolving agent and the colloid substances, and synergistically increases the removal effect on the carbon deposit;
sodium tripolyphosphate: the sodium tripolyphosphate has the functions of chelating, suspending, dispersing, peptizing, emulsifying, pH buffering and the like, and can be used as a main auxiliary agent of a synthetic detergent to improve the cleaning effect on carbon deposition;
a phosphorus-containing chelating agent: common cleaning aids improve the cleaning effect on the carbon deposit;
triglyceride: glycerides formed by esterification of 3 hydroxyl groups of glycerol with 3 fatty acid molecules. The cleaning agent is a non-polar substance, can play a certain lubricating role, can provide certain protection for an engine, reduces the abrasion degree of the inner wall during cleaning, and further ensures the service life of equipment;
sodium lauryl sulfate: is white or light yellow powder, is easily soluble in water, and is not sensitive to alkali and hard water. The cleaning agent has the advantages of decontamination, emulsification and excellent foaming power, can assist in cleaning the carbon deposit, can ensure that a friction agent and the like are uniformly dispersed in the cleaning agent, and ensures the cleaning effect, so that the carbon deposit can not be agglomerated, can be dispersed in an organic solvent and can be directly discharged to the outside of an engine;
hexadecylamine: the corrosion inhibitor is a common corrosion inhibitor, can prevent or slow down the corrosion of materials, and effectively prolongs the service life of equipment.
Compared with the prior art, the invention has the beneficial effects that:
(1) the friction agent added into the carbon deposit cleaning agent can physically rub the inner wall of the engine during cleaning, so that the cleaning speed of the carbon deposit is increased, the cleaning effect is improved, and the physical cleaning effect is further achieved;
(2) the cleaning agent disclosed by the invention can rapidly and efficiently permeate into the deposited carbon of the engine to act with the deposited carbon through the high-efficiency surfactant, the nonylphenol polyoxyethylene ether and the builder added into the deposited carbon cleaning agent, so that the cleaning effect is achieved, the cleaning agent has the advantages of high cleaning speed, good effect and capability of thoroughly cleaning the deposited carbon in a combustion chamber, and the addition of strong alkaline substances is abandoned, so that the cleaning agent is free from corrosion to various parts of the engine and safe to a human body;
(3) the dispersant can ensure that the friction agent and the like are uniformly dispersed in the cleaning agent, the cleaning effect is ensured, the carbon deposition can be prevented from caking, the carbon deposition can be dispersed in the organic solvent and can be directly discharged to the outside of an engine, isopropanol is added into the cleaning agent and is matched with the cleaning agent for use, the cleaning agent has excellent dissolving performance and adsorption performance on the high-cohesiveness carbon deposition, colloidal substances in the carbon deposition are decomposed into smaller particles, the contact area of the dissolving agent and the colloidal substances is increased, the removal effect on the carbon deposition is synergistically increased, the corrosion inhibitor can prevent or slow down the corrosion of materials, and the service life of equipment is effectively prolonged;
(4) through the baffle that is equipped with in bottle inside, can deposit cleaner top ration respectively, the convenient interpolation when follow-up use is used, can improve the storage capacity of the inside cleaner of bottle, places and deposits intracavity portion with the volume of a traditional bottle, can practice thrift the material of bottle production on the one hand, practices thrift manufacturing cost, and on the other hand can conveniently carry and deposit, can solve traditional needs and carry many bottles, occupation space once adds a whole bottle, guarantees the accuracy nature of interpolation.
Drawings
FIG. 1 is a schematic flow chart of a preparation method of a carbon deposition cleaning agent for a vehicle according to the present invention;
FIG. 2 is a schematic view of the internal structure of a storage bottle for carbon deposition cleaning agent for vehicles according to the present invention;
FIG. 3 is a schematic structural diagram of a storage bottle for a carbon deposition cleaning agent for a vehicle according to the present invention;
FIG. 4 is a schematic structural diagram of a rotary sealing tube and a baffle in a storage bottle for a carbon deposition cleaning agent for a vehicle according to the present invention;
fig. 5 is a schematic structural diagram of a partition board in a storage bottle for a carbon deposition cleaning agent for a vehicle according to the present invention.
Fig. 6 is a data chart of the cleaning standing time and the cleaning effect experiment between the cleaning agent and the conventional cleaning agent in embodiment 2 of the present invention.
In the figure: 1. a bottle body; 2. rotating the sealing tube; 3. a partition plate; 4. a seal ring; 5. sealing the clamping groove; 6. A baffle plate; 7. a sealing layer; 8. a liquid outlet; 9. a bottle cap; 10. fixing grooves; 11. and a support plate.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be obtained by a person skilled in the art without making any creative effort based on the embodiments in the present invention, belong to the protection scope of the present invention.
According to one aspect of the invention, a carbon deposit cleaning agent for a vehicle is provided.
The carbon deposit cleaning agent for the vehicle comprises the following raw materials in parts by weight:
4-6 parts of mixed tetramethylbenzene, 10-14 parts of high-efficiency surfactant, 6-8 parts of nonylphenol polyoxyethylene ether, 10-14 parts of isopropanol, 1.2-1.8 parts of builder, 6-8 parts of friction agent, 2-4 parts of antioxidant, 1.0-1.4 parts of antiwear agent, 1.2-1.6 parts of dispersant and 3-5 parts of corrosion inhibitor.
The builder comprises the following raw materials in parts by mass: 0.6-0.9 part of sodium tripolyphosphate and 0.6-0.9 part of phosphorus-containing chelating agent.
In order to clearly understand the technical scheme of the invention, the technical scheme of the invention is described in detail through specific examples.
Example one
The vehicle carbon deposit cleaning agent comprises the following raw materials in parts by weight:
4g of mixed tetramethylbenzene, 10g of high-efficiency surfactant, 6g of nonylphenol polyoxyethylene ether, 10g of isopropanol, 1.2g of builder, 6g of friction agent, 2g of antioxidant, 1.0g of antiwear agent, 1.2g of dispersant and 3g of corrosion inhibitor.
The builder comprises the following raw materials in parts by mass: 0.6g of sodium tripolyphosphate and 0.6g of phosphorus-containing chelating agent.
The preparation method of the carbon deposit cleaning agent for the vehicle comprises the following steps:
step S101: weighing the raw materials required by the carbon deposition cleaning agent for the vehicle according to the parts by weight;
step S103: adding 4g of mixed tetramethylbenzene into the mixture to be reacted and stirred, sequentially adding 10g of high-efficiency surfactant, 6g of nonylphenol polyoxyethylene ether, 10g of isopropanol, 0.6g of sodium tripolyphosphate and 0.6g of phosphorus-containing chelating agent, and fully mixing and stirring for 15-25min to obtain a mixture A;
step S105: grinding and screening 6g of a friction agent, adding 1.0g of triglyceride into the ground friction agent, fully soaking and absorbing the triglyceride, and enabling the triglyceride to enter the micropores of the friction agent for temporary adsorption to obtain a material A;
step S107: adding the material A into the mixture A, mixing and stirring for 5-8min, sequentially adding 1.2g of sodium dodecyl sulfate and 3g of hexadecylamine, and fully mixing for 15-20min to obtain a mixture B;
step S109: and adding 2g of antioxidant into the mixture B, and mixing and stirring for 6-12min to obtain the carbon deposit cleaning agent for the vehicle.
Example two:
the vehicle carbon deposit cleaning agent comprises the following raw materials in parts by weight:
5g of mixed tetramethylbenzene, 12g of high-efficiency surfactant, 7g of nonylphenol polyoxyethylene ether, 12g of isopropanol, 1.5g of builder, 7g of abrasive, 3g of antioxidant, 1.2g of antiwear agent, 1.4g of dispersant and 4g of corrosion inhibitor.
The builder comprises the following raw materials in parts by mass: 0.75g of sodium tripolyphosphate and 0.75g of phosphorus-containing chelating agent.
The preparation method of the carbon deposit cleaning agent for the vehicle comprises the following steps:
step S101: weighing the raw materials required by the carbon deposition cleaning agent for the vehicle according to the parts by weight;
step S103: adding 5g of mixed tetramethylbenzene into the mixture to be reacted and stirred, sequentially adding 12g of high-efficiency surfactant, 7g of nonylphenol polyoxyethylene ether, 12g of isopropanol, 0.75g of sodium tripolyphosphate and 0.75g of phosphorus-containing chelating agent, and fully mixing and stirring for 15-25min to obtain a mixture A;
step S105: grinding and screening 7g of a friction agent, adding 1.2g of triglyceride into the ground friction agent, fully soaking and absorbing the triglyceride, and enabling the triglyceride to enter the micropores of the friction agent for temporary adsorption to obtain a material A;
step S107: adding the material A into the mixture A, mixing and stirring for 5-8min, then sequentially adding 1.4g of sodium dodecyl sulfate and 4g of hexadecylamine, and fully mixing for 15-20min to obtain a mixture B;
step S109: and adding 3g of antioxidant into the mixture B, and mixing and stirring for 6-12min to obtain the carbon deposit cleaning agent for the vehicle.
Example three:
the vehicle carbon deposit cleaning agent comprises the following raw materials in parts by weight:
6g of mixed tetramethylbenzene, 14g of high-efficiency surfactant, 8g of nonylphenol polyoxyethylene ether, 14g of isopropanol, 1.8g of builder, 8g of friction agent, 4g of antioxidant, 1.4g of antiwear agent, 1.6g of dispersant and 5g of corrosion inhibitor.
The builder comprises the following raw materials in parts by mass: 0.9g of sodium tripolyphosphate and 0.9g of phosphorus-containing chelating agent.
The preparation method of the carbon deposit cleaning agent for the vehicle comprises the following steps:
step S101: weighing the raw materials required by the carbon deposition cleaning agent for the vehicle according to the parts by weight;
step S103: adding 6g of mixed tetramethylbenzene into the mixture to be reacted and stirred, sequentially adding 14g of high-efficiency surfactant, 8g of nonylphenol polyoxyethylene ether, 14g of isopropanol, 0.9g of sodium tripolyphosphate and 0.9g of phosphorus-containing chelating agent, and fully mixing and stirring for 15-25min to obtain a mixture A;
step S105: grinding and screening 8g of a friction agent, adding 1.4g of triglyceride into the ground friction agent, fully soaking and absorbing the triglyceride, and enabling the triglyceride to enter the micropores of the friction agent for temporary adsorption to obtain a material A;
step S107: adding the material A into the mixture A, mixing and stirring for 5-8min, sequentially adding 1.6g of sodium dodecyl sulfate and 5g of hexadecylamine, and fully mixing for 15-20min to obtain a mixture B;
step S109: and adding 4g of antioxidant into the mixture B, and mixing and stirring for 6-12min to obtain the carbon deposit cleaning agent for the vehicle.
According to another aspect of the invention, the storage bottle for the vehicle carbon deposition cleaning agent comprises a bottle body 1, the interior of the bottle body 1 is equidistantly divided into storage cavities through partition plates 3, the number of the storage cavities can be 4, 6 or 8, different usage amounts can be customized according to different vehicle types, the storage cavities are more convenient to use, sealing layers 7 are arranged at the opening ends of the storage cavities, a rotary sealing pipe 2 is rotatably arranged at the opening end of the bottle body 1, a baffle 6 is arranged inside the rotary sealing pipe 2 through a fixing groove 10, a liquid outlet 8 is formed in the baffle 6, the liquid outlet 8 corresponds to the storage cavities, a supporting plate 11 is arranged below the baffle 6 and a bottle cap 9 is arranged on the bottle body 1 through threads at the opening end.
In order to increase the storage amount of the bottle body 1, the material produced in the bottle body 1 is reduced, the production cost is saved, the portable bottle is convenient to carry and store, the problem that a plurality of bottles are required to be carried in the prior art is solved, the occupied space is occupied, one whole bottle is added at a time, the amount of the storage cavity is one bottle, the adding accuracy is guaranteed, the confusion can be avoided, and the use safety is guaranteed.
Wherein, 1 open end equidistance of bottle has seted up sealed draw-in groove 5, all is equipped with sealing washer 4 in sealed draw-in groove 5 to two sealing washers 4 all are connected with rotary seal pipe 2.
In order to improve the sealing performance in use, avoid leakage, improve the use safety and avoid waste.
Experimental data of the cleaning time and cleaning effect of the cleaning agent and the conventional cleaning agent (vehicle slave gasoline and diesel engine internal cleaning agent, automobile engine oil carbon removal cleaning greasy dirt removal honest series) in embodiment 2 of the present invention are shown in table 1 and fig. 6 below, wherein the horizontal axis represents the standing time (min) and the vertical axis represents the carbon removal rate (%) (wherein the carbon removal rate test method employs an infrared method to detect the carbon content of the diesel engine before and after the addition of the cleaning agent and calculate the carbon removal rate).
Figure BDA0003632578190000101
TABLE 1
As can be seen from the above table 1, compared with the conventional cleaning agent, the cleaning agent provided by the invention can achieve a removal rate of 97% in 15 minutes, so that the standing time after the cleaning agent is injected is greatly shortened, and the removal rate of carbon deposition is greatly improved.
The theory of operation, when using, through unscrewing bottle lid 9, when using, at first prick out one of them sealing layer 7 of depositing the chamber, can add the use with the 1 inside cleaner of bottle this moment, and when needing to deposit the cleaner of intracavity to other, through rotating rotatory sealing tube 2, sealing washer 4 is at 5 internal rotations of sealed draw-in groove, can improve the leakproofness, liquid outlet 8 rotates to next and deposits the chamber top this moment, repeated above-mentioned operation can pour the use with the cleaner, solve traditional needs and carry many bottles, occupation space, once add a whole bottle, and the volume of depositing the chamber is the volume of a bottle, guarantee the accuracy nature of interpolation, can also avoid taking place to obscure, guarantee the safety of using.
In conclusion, by means of the technical scheme of the invention, the carbon deposit cleaning agent for the vehicle can be invented, the friction agent added in the carbon deposit cleaning agent can physically rub the inner wall of the engine during cleaning, so that the cleaning speed of the carbon deposit is accelerated, the cleaning effect is improved, the physical cleaning effect is further achieved, meanwhile, the abrasion resistant agent is matched, the lubricating effect can be achieved to a certain extent, the engine can be protected to a certain extent, the abrasion degree of the inner wall during cleaning is reduced, the service life of equipment is further ensured, the cleaning agent can rapidly and efficiently permeate into the carbon deposit of the engine to achieve the effect of cleaning through the efficient surfactant, the nonylphenol polyoxyethylene ether and the builder added in the carbon deposit cleaning agent, the cleaning agent can rapidly and efficiently permeate into the carbon deposit of the engine to achieve the effect of cleaning, and has the advantages of high cleaning speed, good effect and capability of thoroughly cleaning the carbon deposit in a combustion chamber, and abandons the addition of strong alkaline substances, so the cleaning agent has no corrosion to all parts of the engine and is safe to human bodies, the dispersant can ensure that the friction agent and the like are uniformly dispersed in the cleaning agent to ensure the cleaning effect, simultaneously, the carbon deposit can not agglomerate and can be dispersed in an organic solvent and can be directly discharged to the outside of the engine, isopropanol is added into the cleaning agent for matching use, the cleaning agent has excellent dissolving performance and adsorption performance to the high-adhesion carbon deposit, the colloid substance in the carbon deposit is decomposed into smaller particles, the contact area of the dissolving agent and the colloid substance is increased, the removal effect to the carbon deposit is synergistically increased, the corrosion inhibitor can prevent or slow down the corrosion of the material, the service life of the equipment is effectively prolonged, after the carbon deposit is cleaned, the inside of the engine is cleaned again by a brush soaked in gasoline by workers, on one hand, the residual cleaning agent can be cleaned, on the other hand, the interior of the cleaning agent can be cleaned again, the removal efficiency of the carbon deposition is improved, and the subsequent use is ensured.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.

Claims (10)

1. The vehicle carbon deposit cleaning agent is characterized by comprising the following raw materials in parts by mass:
4-6 parts of mixed tetramethylbenzene, 10-14 parts of high-efficiency surfactant, 6-8 parts of nonylphenol polyoxyethylene ether, 10-14 parts of isopropanol, 1.2-1.8 parts of builder, 6-8 parts of friction agent, 2-4 parts of antioxidant, 1.0-1.4 parts of antiwear agent, 1.2-1.6 parts of dispersant and 3-5 parts of corrosion inhibitor.
2. A carbon deposit cleaning agent for a vehicle as defined in claim 1, which is characterized in that: the high-efficiency surfactant is one or a mixture of dioctyl sodium sulfosuccinate, polypropylene glycol, nonylphenol polyoxypropylene ether amine, alcohol ether phosphate or fatty alcohol-polyoxyethylene ether.
3. A carbon deposit cleaning agent for a vehicle as defined in claim 1, which is characterized in that: the builder comprises the following raw materials in parts by mass: 0.6-0.9 part of sodium tripolyphosphate and 0.6-0.9 part of phosphorus-containing chelating agent.
4. The carbon deposit cleaning agent for the vehicle as claimed in claim 1, wherein: the friction agent is one or a mixture of several of nano titanium dioxide, aluminum oxide and zirconium dioxide.
5. A carbon deposit cleaning agent for a vehicle as defined in claim 1, which is characterized in that: the anti-wear agent is triglyceride; the dispersing agent is sodium dodecyl sulfate; the corrosion inhibitor is hexadecylamine.
6. A carbon deposit cleaning agent for a vehicle as defined in claim 1, which is characterized in that: the antioxidant is one or a mixture of more of 4,4' -dioctyl diphenylamine, tri (2, 4-di-tert-butyl) phenyl phosphite, butylated hydroxytoluene and 2, 6-di-tert-butylphenol.
7. A preparation method of a vehicle carbon deposition cleaning agent is characterized by being used for preparing the vehicle carbon deposition cleaning agent as claimed in any one of claims 1 to 6, and comprising the following steps of:
step S101: weighing the raw materials required by the carbon deposition cleaning agent for the vehicle according to the parts by weight;
step S103: adding mixed tetramethylbenzene into the mixture for reaction and stirring, sequentially adding a high-efficiency surfactant, nonylphenol polyoxyethylene ether, isopropanol, sodium tripolyphosphate and a phosphorus-containing chelating agent, and fully mixing and stirring for 15-25min to obtain a mixture A;
step S105: grinding and screening the friction agent, adding triglyceride into the ground friction agent, fully soaking and absorbing the triglyceride, and enabling the triglyceride to enter the micropores of the friction agent for temporary adsorption to obtain a material A;
step S107: adding the material A into the mixture A, mixing and stirring for 5-8min, sequentially adding sodium dodecyl sulfate and hexadecylamine, and fully mixing for 15-20min to obtain a mixture B;
step S109: .
8. The preparation method of the carbon deposition cleaning agent for the vehicle as claimed in claim 6, wherein the cleaning agent comprises the following components: wherein the particle size of the abrasive after grinding and screening is 30-40 nm.
9. The utility model provides a bottle is deposited to automobile-used carbon deposit cleaner, a serial communication port, be used for according to claim 1-6 deposit of automobile-used carbon deposit cleaner, including bottle (1), bottle (1) is inside to separate into through baffle (3) equidistance and deposit the chamber, it all is equipped with sealing layer (7) to deposit the chamber open end, bottle (1) open end rotates and is equipped with rotary seal pipe (2), rotary seal pipe (2) are inside to be equipped with baffle (6) through fixed slot (10), liquid outlet (8) have been seted up on baffle (6), liquid outlet (8) with it is corresponding to deposit the chamber, and baffle (6) are located the below of liquid outlet (8) is equipped with backup pad (11), bottle (1) is equipped with bottle lid (9) through the screw thread through the open end.
10. The vehicle carbon deposit cleaning agent storage bottle as claimed in claim 9, wherein the opening end of the bottle body (1) is equidistantly provided with sealing clamping grooves (5), sealing rings (4) are arranged in the sealing clamping grooves (5), and the two sealing rings (4) are connected with the rotary sealing pipe (2).
CN202210493315.9A 2022-05-07 2022-05-07 Preparation method of carbon deposition cleaning agent for vehicle Pending CN114806729A (en)

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TWM475426U (en) * 2013-11-12 2014-04-01 Univ Ling Tung Container bottle capable of controlling pour amount
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