CN114773022A - High-efficiency water-dispersion-resistant synchronous grouting slurry and preparation method thereof - Google Patents

High-efficiency water-dispersion-resistant synchronous grouting slurry and preparation method thereof Download PDF

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Publication number
CN114773022A
CN114773022A CN202210248636.2A CN202210248636A CN114773022A CN 114773022 A CN114773022 A CN 114773022A CN 202210248636 A CN202210248636 A CN 202210248636A CN 114773022 A CN114773022 A CN 114773022A
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China
Prior art keywords
water
synchronous grouting
slurry
stirring
grouting slurry
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Pending
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CN202210248636.2A
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Chinese (zh)
Inventor
许维青
高昆
古艳旗
孙建
陈强
张敬玲
赵宝锋
刘建平
王燚
孔翠杰
刘志龙
孙卓
李斌
万俊男
李永江
李静
张振强
张泽民
黄旭光
付枭枭
张锐
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China Railway Tunnel Group Erchu Co Ltd
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China Railway Tunnel Group Erchu Co Ltd
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Priority to CN202210248636.2A priority Critical patent/CN114773022A/en
Publication of CN114773022A publication Critical patent/CN114773022A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/24Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
    • C04B28/26Silicates of the alkali metals
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)

Abstract

The invention relates to a high-efficiency water-dispersion-resistant synchronous grouting slurry and a preparation method thereof, wherein the synchronous grouting slurry comprises the following components: the preparation method of the synchronous grouting slurry comprises the following steps of portland cement, fly ash, fine sand, tap water, bentonite, an expanding agent, magnesium oxide, calcium oxide, a flocculating agent, water glass, a polycarboxylic acid water reducing agent, hydroxypropyl methyl cellulose and calcium formate, wherein the preparation method of the synchronous grouting slurry comprises the following steps: step 1, placing portland cement, fly ash, fine sand, bentonite and tap water into a slurry mixing cylinder for primary mechanical mixing and stirring, step 2, after primary mechanical mixing and stirring, adding an expanding agent, magnesium oxide, calcium formate and hydroxypropyl methyl cellulose into the slurry mixing cylinder for secondary mechanical mixing and stirring, and step 3, after secondary mechanical mixing and stirring, adding a polycarboxylic acid water reducing agent, water glass and a flocculating agent into the slurry mixing cylinder for tertiary mechanical mixing and stirring to obtain the synchronous grouting slurry, wherein the synchronous grouting slurry has water dispersion resistance.

Description

High-efficiency water-dispersion-resistant synchronous grouting slurry and preparation method thereof
Technical Field
The invention belongs to the technical field of shield tunnel construction, and particularly relates to high-efficiency water-dispersion-resistant synchronous grouting slurry and a preparation method thereof.
Background
With the planning and implementation of underground space, the shield method is mostly applied to urban rail transit, hydraulic engineering, cable tunnels, railway engineering, pipeline laying and other projects due to the characteristics of higher degree of automation and automation, higher tunneling speed and the like, and is widely applied to the implementation of urban underground space and the construction of crossing river and transoceanic tunnels due to the characteristics of smaller safety and influence and the like.
At present, in the field of shield construction, synchronous grouting slurry is divided into single-liquid mortar, cement and water glass double-liquid slurry and inert slurry, wherein in the process of shield construction of the single-liquid mortar, the slurry is quickly diluted by underground water under the action of the underground water, and is accelerated in loss of cementing materials in an underground water rich region to cause segregation and non-solidification, and the segregation and non-solidification cannot be solidified around a duct piece in time, so that quality risks such as ground surface settlement exceeding the standard, irregular floating of the duct piece, duct piece dislocation, exceeding of ovality and the like are caused; the main materials of the cement and water glass double-liquid slurry are cement and water glass, and the double-liquid slurry is injected for a long time, so that the slurry can wrap the shield tail brush, the quality of the shield tail brush and the contact effect of the shield tail brush and the outer wall of the duct piece are influenced, and the overall quality of the shield tail brush is influenced; the main materials of the inert slurry are fly ash, sand, bentonite and water, and the purposes of filling in a short time and enhancing the stability of the stratum cannot be achieved for weak surrounding rock and the stratum with poor self-stability.
The Chinese patent application No. 202010173814.0 discloses a light slurry for shield synchronous grouting, which comprises 300 parts of cement 200-.
Based on the above, a synchronous grouting slurry with high-efficiency water dispersion resistance is required to be introduced, so that the consolidation rate and strength are guaranteed, a certain water dispersion resistance is maintained, and the stability of a stratum after grouting is enhanced.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides high-efficiency synchronous grouting slurry with water dispersibility resistance, which comprises the following components in parts by weight: 200-250kg of Portland cement, 400-500kg of fly ash, 740kg of fine sand, 1200-1400kg of water, 100-120kg of bentonite, 12-18kg of expanding agent, 40-50kg of magnesium oxide, 45-55kg of calcium oxide, 20-30kg of flocculating agent, 30-40kg of water glass, 20-40kg of polycarboxylic acid water reducing agent, 30-38kg of hydroxypropyl methyl cellulose and 50-60kg of calcium formate.
Further, the synchronous grouting slurry comprises the following components in parts by weight: 225kg of portland cement, 450kg of fly ash, 720kg of fine sand, 1300kg of water, 110kg of bentonite, 15kg of an expanding agent, 45kg of magnesium oxide, 50kg of calcium oxide, 25kg of a flocculating agent, 35kg of water glass, 30kg of a polycarboxylic acid water reducing agent, 34kg of hydroxypropyl methyl cellulose and 55kg of calcium formate.
Furthermore, the Portland cement is 42.5-grade ordinary Portland cement, and the specific surface area is 339m2Per kg, the stability is 4.8.
Further, the fly ash is F-class II-grade fly ash, the fineness is 17.2%, the water demand ratio is 99%, and the loss on ignition is 5.89%.
Furthermore, the fineness modulus of the fine sand is 1.4, and the mud content is 1.2%.
Further, the bentonite is sodium bentonite, and the density of the bentonite is 200-300 kg/m3The pulping rate is 8m3T, the balance of the wet sieve is 3.3 percent.
Further, the expanding agent is a low-alkali concrete expanding agent, and the specific surface area is 370m2/kg。
Furthermore, the water glass is colloidal, and the baume degree is 5 degrees.
Further, the flocculating agent is formed by mixing 30 parts of polymeric aluminum hydroxide, 45 parts of carbonate, 20 parts of rheological agent, 15 parts of dispersing agent and 20 parts of early strength agent.
Further, the carbonate is CaCO3、Ca(HCO3)2、FeCO3、MgCa(CO3)2、ZnCO3、MgCO3、Na2CO3、 NaHCO3One or more mixtures of (a).
Further, the polycarboxylic acid water reducing agent consists of an enol polyether macromonomer, acrylic acid, maleic anhydride, deionized water and persulfate according to the mass ratio of 100:0.9:0.5:50: 150.
Further, the enol polyether macromonomer is any one of allyl alcohol polyoxyethylene ether, isobutenol polyoxyethylene ether or prenol polyoxyethylene ether.
Further, the magnesium oxide is a heavy-burned magnesium oxide industrial product, and the Bosch specific surface area is 280-350m2Kg, purity 90%.
The invention also provides a preparation method of the high-efficiency water-dispersion-resistant synchronous grouting slurry, which comprises the following steps:
step 1, putting 225kg of Portland cement, 450kg of fly ash, 720kg of fine sand, 110kg of bentonite and 1300kg of water into a slurry mixing cylinder for first mechanical mixing and stirring, wherein the time of the first mechanical mixing and stirring is 10-20 min;
step 2, after the first mechanical mixing and stirring, adding 15kg of expanding agent, 45kg of magnesium oxide, 50kg of calcium oxide, 55kg of calcium formate and 34kg of hydroxypropyl methyl cellulose into a slurry mixing cylinder for second mechanical mixing and stirring, wherein the time for the second mechanical mixing and stirring is 25-25min, and the rotating speed for the second mechanical mixing and stirring is 750-800 r/min;
and 3, after the second mechanical mixing and stirring, adding 30kg of polycarboxylic acid water reducing agent, 35kg of water glass and 25kg of flocculating agent into a slurry mixing cylinder for third mechanical mixing and stirring to obtain the synchronous grouting slurry, wherein the third mechanical mixing and stirring time is 20-30 min.
Further, the setting time of the synchronous grouting slurry in the step 3 is 270min, the bleeding rate is 6%, the consistency is 11.3cm, and the fluidity is 20.1 mm.
Compared with the prior art, the invention has the beneficial effects that: the synchronous grouting slurry has the advantages of good stability, high water dispersion resistance, quick initial setting time and the like, unstable floating drop of the duct piece is reduced in the shield tunneling process, the stratum is quickly stabilized, and the synchronous grouting slurry is ensured to have smaller loss amount under the conditions of pore diving, confined aquifer, supply, runoff and drainage of rivers, the synchronous grouting slurry prevents the duct piece from floating upwards after being solidified, protects the duct piece from excessive underground water pressure, and ensures certain safety and quality in tunnel tunneling.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described in detail below with reference to specific embodiments.
The invention provides high-efficiency synchronous grouting slurry with water dispersibility resistance, which comprises the following components in parts by weight: 200-250kg of Portland cement, 400-500kg of fly ash, 740kg of fine sand, 1200-1400kg of water, 100-120kg of bentonite, 12-18kg of expanding agent, 40-50kg of magnesium oxide, 45-55kg of calcium oxide, 20-30kg of flocculant, 30-40kg of water glass, 20-40kg of polycarboxylic acid water reducer, 30-38kg of hydroxypropyl methyl cellulose and 50-60kg of calcium formate.
Further, the synchronous grouting slurry comprises the following components in parts by weight: 225kg of portland cement, 450kg of fly ash, 720kg of fine sand, 1300kg of water, 110kg of bentonite, 15kg of an expanding agent, 45kg of magnesium oxide, 50kg of calcium oxide, 25kg of a flocculating agent, 35kg of water glass, 30kg of a polycarboxylic acid water reducing agent, 34kg of hydroxypropyl methyl cellulose and 55kg of calcium formate.
Further, the Portland cement is 42.5-grade ordinary Portland cement, and the specific surface area is 339m2Kg, stability 4.8.
Further, the fly ash is F-class II-grade fly ash, the fineness is 17.2%, the water demand ratio is 99%, and the loss on ignition is 5.89%.
Furthermore, the fineness modulus of the fine sand is 1.4, and the mud content is 1.2%.
Further, the bentonite is sodium bentonite, and the density of the bentonite is 200-300 kg/m3The pulping rate is 8m3T, the balance of the wet sieve is 3.3 percent.
Furthermore, the expanding agent is a low-alkali concrete expanding agent with the specific surface area of 370m2/kg。
Furthermore, the water glass is colloidal, and the baume degree is 5 degrees.
Further, the flocculating agent is formed by mixing 30 parts of polymeric aluminum hydroxide, 45 parts of carbonate, 20 parts of rheological agent, 15 parts of dispersing agent and 20 parts of early strength agent.
Further, the carbonate is CaCO3、Ca(HCO3)2、FeCO3、MgCa(CO3)2、ZnCO3、MgCO3、Na2CO3、 NaHCO3One or more mixtures of (a).
Further, the polycarboxylic acid water reducing agent consists of an enol polyether macromonomer, acrylic acid, maleic anhydride, deionized water and persulfate according to the mass ratio of 100:0.9:0.5:50: 150.
Further, the enol polyether macromonomer is any one of allyl alcohol polyoxyethylene ether, isobutenol polyoxyethylene ether or prenol polyoxyethylene ether.
Further, the magnesium oxide is a heavy-burned magnesium oxide industrial product, and the Bosch specific surface area is 280-350m2Kg, purity 90%.
The invention also provides a preparation method of the high-efficiency water-dispersion-resistant synchronous grouting slurry, which comprises the following steps:
step 1, putting 225kg of portland cement, 450kg of fly ash, 720kg of fine sand, 110kg of bentonite and 1300kg of water into a slurry mixing cylinder for first mechanical mixing and stirring, wherein the time for the first mechanical mixing and stirring is 10-20 min;
step 2, after the first mechanical mixing and stirring, adding 15kg of expanding agent, 45kg of magnesium oxide, 50kg of calcium oxide, 55kg of calcium formate and 34kg of hydroxypropyl methyl cellulose into a slurry mixing cylinder for second mechanical mixing and stirring, wherein the time for the second mechanical mixing and stirring is 25-25min, and the rotating speed for the second mechanical mixing and stirring is 750-800 r/min;
and 3, after the second mechanical mixing and stirring, adding 30kg of polycarboxylic acid water reducing agent, 35kg of water glass and 25kg of flocculant into the slurry mixing cylinder, and performing third mechanical mixing and stirring to obtain the synchronous grouting slurry, wherein the third mechanical mixing and stirring time is 20-30 min.
Further, the setting time of the synchronous grouting slurry in the step 3 is 270min, the bleeding rate is 6%, the consistency is 11.3cm, and the fluidity is 20.1 mm.
Finally, it should be understood that the above-mentioned embodiments are merely preferred embodiments of the present invention, and not intended to limit the present invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. The high-efficiency synchronous grouting slurry with the water dispersibility resisting property is characterized by comprising the following components in parts by weight: 200-250kg of Portland cement, 400-500kg of fly ash, 740kg of fine sand, 1200-1400kg of water, 100-120kg of bentonite, 12-18kg of expanding agent, 40-50kg of magnesium oxide, 45-55kg of calcium oxide, 20-30kg of flocculant, 30-40kg of water glass, 20-40kg of polycarboxylic acid water reducer, 30-38kg of hydroxypropyl methyl cellulose and 50-60kg of calcium formate.
2. The high-efficiency water-dispersivity synchronous grouting slurry as claimed in claim 1, wherein the synchronous grouting slurry comprises the following components in parts by weight: 225kg of portland cement, 450kg of fly ash, 720kg of fine sand, 1300kg of water, 110kg of bentonite, 15kg of an expanding agent, 45kg of magnesium oxide, 50kg of calcium oxide, 25kg of a flocculating agent, 35kg of water glass, 30kg of a polycarboxylic acid water reducing agent, 34kg of hydroxypropyl methyl cellulose and 55kg of calcium formate.
3. The high-efficiency water-dispersion-resistant synchronous grouting slurry as claimed in claim 1, wherein the portland cement is 42.5-grade ordinary portland cement, and the specific surface area is 339m2Kg, stability 4.8.
4. The high-efficiency water-dispersivity synchronous grouting slurry as claimed in claim 1, wherein the fly ash is class F class II fly ash, the fineness is 17.2%, the water demand ratio is 99%, and the loss on ignition is 5.89%.
5. The synchronous grouting slurry with high efficiency and water dispersivity performance of claim 1, wherein the fineness modulus of the fine sand is 1.4, and the mud content is 1.2%.
6. The high-efficiency water-dispersivity synchronous grouting slurry as claimed in claim 1, wherein the bentonite is sodium bentonite, and the slurry making rate is 8m3T, the balance of the wet sieve is 3.3 percent.
7. The high-efficiency water-dispersibility-resistant synchronous grouting slurry as claimed in claim 1, wherein the expanding agent is a low-alkali concrete expanding agent, and the specific surface area of the expanding agent is 370m2/kg。
8. The high-efficiency water-dispersivity synchronous grouting slurry as claimed in claim 2, wherein the flocculating agent is formed by mixing 30 parts of polymeric aluminum hydroxide, 45 parts of carbonate, 20 parts of rheological agent, 15 parts of dispersing agent and 20 parts of early strength agent.
9. The high-efficiency water-resistant dispersion property synchronous grouting slurry as claimed in claim 2, wherein the polycarboxylate water reducer is composed of an enol polyether macromonomer, acrylic acid, maleic anhydride, deionized water and persulfate according to a mass ratio of 100:0.9:0.5:50: 150.
10. The preparation method of the high-efficiency water-dispersion-resistant synchronous grouting slurry as claimed in claim 1, characterized by comprising the following steps:
step 1, putting 225kg of Portland cement, 450kg of fly ash, 720kg of fine sand, 110kg of bentonite and 1300kg of water into a slurry mixing cylinder for first mechanical mixing and stirring, wherein the time of the first mechanical mixing and stirring is 10-20 min;
step 2, after the first mechanical mixing and stirring, adding 15kg of expanding agent, 45kg of magnesium oxide, 50kg of calcium oxide, 55kg of calcium formate and 34kg of hydroxypropyl methyl cellulose into a slurry mixing cylinder for second mechanical mixing and stirring, wherein the time of the second mechanical mixing and stirring is 25-25min, and the rotating speed of the second mechanical mixing and stirring is 750-800 r/min;
and 3, after the second mechanical mixing and stirring, adding 30kg of polycarboxylic acid water reducing agent, 35kg of water glass and 25kg of flocculating agent into a slurry mixing cylinder for third mechanical mixing and stirring to obtain the synchronous grouting slurry, wherein the third mechanical mixing and stirring time is 20-30 min.
CN202210248636.2A 2022-03-14 2022-03-14 High-efficiency water-dispersion-resistant synchronous grouting slurry and preparation method thereof Pending CN114773022A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101891413A (en) * 2010-06-18 2010-11-24 中国水利水电第三工程局有限公司 Flocculating agent for cement high pressure jet grouting and preparation method and application thereof
CN103880372A (en) * 2014-03-04 2014-06-25 北京纽维逊建筑工程技术有限公司 Cement-based grouting material used for strengthening repairing as well as preparation method and application thereof
US20180290923A1 (en) * 2017-04-07 2018-10-11 Jiahuan Yu Underwater Non-Dispersible Quick-Setting and Rapid-Hardening Cement-Based Composite Material and Preparation Method and Application Thereof
CN113003999A (en) * 2021-02-22 2021-06-22 中铁隧道集团二处有限公司 Synchronous grouting slurry for shield construction of water-rich stratum and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101891413A (en) * 2010-06-18 2010-11-24 中国水利水电第三工程局有限公司 Flocculating agent for cement high pressure jet grouting and preparation method and application thereof
CN103880372A (en) * 2014-03-04 2014-06-25 北京纽维逊建筑工程技术有限公司 Cement-based grouting material used for strengthening repairing as well as preparation method and application thereof
US20180290923A1 (en) * 2017-04-07 2018-10-11 Jiahuan Yu Underwater Non-Dispersible Quick-Setting and Rapid-Hardening Cement-Based Composite Material and Preparation Method and Application Thereof
CN113003999A (en) * 2021-02-22 2021-06-22 中铁隧道集团二处有限公司 Synchronous grouting slurry for shield construction of water-rich stratum and preparation method thereof

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Application publication date: 20220722