CN114747820A - Droplet-blocking mask - Google Patents

Droplet-blocking mask Download PDF

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Publication number
CN114747820A
CN114747820A CN202110901472.4A CN202110901472A CN114747820A CN 114747820 A CN114747820 A CN 114747820A CN 202110901472 A CN202110901472 A CN 202110901472A CN 114747820 A CN114747820 A CN 114747820A
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Prior art keywords
mask
barrier
droplet
splash
mask body
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CN202110901472.4A
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Chinese (zh)
Inventor
朴弘慜
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Maggie Cooper Ltd
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Maggie Cooper Ltd
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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/05Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
    • A41D13/11Protective face masks, e.g. for surgical use, or for use in foul atmospheres
    • A41D13/1192Protective face masks, e.g. for surgical use, or for use in foul atmospheres with antimicrobial agent
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D27/00Details of garments or of their making
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41FGARMENT FASTENINGS; SUSPENDERS
    • A41F1/00Fastening devices specially adapted for garments
    • A41F1/002Magnetic fastening devices
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41FGARMENT FASTENINGS; SUSPENDERS
    • A41F1/00Fastening devices specially adapted for garments
    • A41F1/02Buttonholes; Eyelets for buttonholes
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B23/00Filters for breathing-protection purposes
    • A62B23/02Filters for breathing-protection purposes for respirators
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2300/00Details of garments
    • A41D2300/30Closures
    • A41D2300/32Closures using hook and loop-type fasteners
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2300/00Details of garments
    • A41D2300/30Closures
    • A41D2300/324Closures using snap fasteners
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D2500/00Materials for garments
    • A41D2500/50Synthetic resins or rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/08Metals
    • C08K2003/085Copper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Textile Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)

Abstract

The invention relates to a droplet barrier mask, comprising: a mask body part for providing a face receiving space; a mask band part extending from both side surfaces of the mask body part; and a splash barrier detachably coupled to an outer surface of the mask body, the splash barrier including a polymer resin and an antimicrobial agent dispersed in the polymer resin, the antimicrobial agent including copper, zinc oxide, and zeolite. The droplet blocking mask comprises the droplet blocking part combined with the mask body part, so that the droplet blocking mask has excellent droplet blocking performance and high antibacterial and antiviral properties.

Description

Droplet-blocking mask
Technical Field
The present invention relates to a droplet blocking mask, and more particularly, to a droplet blocking mask having excellent droplet blocking properties and high antiviral and antibacterial properties.
Background
Recently, the risk of diseases has increased with the emergence of highly contagious viruses, and thus, the demand for personal hygiene and antibacterial is sharply increasing in public places in which there is much contact with others. In addition, in order to prevent diseases transmitted by droplets, the demand for droplet blocking masks is continuously increasing.
Although various masks have been developed to prevent respiratory infectious diseases, conventional masks are generally made of cotton fabrics, non-woven fabrics, or the like, and have no antibacterial properties, and thus have a problem that they are easily contaminated with bacteria or viruses.
In addition, in order to effectively prevent respiratory infectious diseases, droplets secreted through human-to-human interaction, coughing, or the like need to be blocked, but conventional masks have a problem in that droplets are absorbed by the mask or permeate into the mask because it is difficult to completely block droplets from the outside.
Disclosure of Invention
In order to solve the above problems, an object of the present invention is to provide a droplet barrier mask which has excellent antibacterial properties, antiviral properties, and droplet barrier properties and can be used for a long time by replacing a droplet barrier portion.
In order to achieve the above technical object, the present invention provides a droplet blocking mask, comprising: a mask body for providing a face receiving space; a mask band part extending from both side surfaces of the mask body part; and a splash barrier detachably coupled to an outer surface of the mask body, the splash barrier including a polymer resin and an antimicrobial agent dispersed in the polymer resin, the antimicrobial agent including copper, zinc oxide, and zeolite (zeolite).
The droplet barrier mask of the present invention has excellent antibacterial properties, antiviral properties, and droplet barrier properties, and can be used for a long period of time by replacing the droplet barrier section.
Drawings
Fig. 1 is a front perspective view showing a droplet barrier mask of the present invention.
Fig. 2 is a back perspective view showing the droplet barrier mask of the present invention.
Fig. 3 is a diagram showing a separated state of the splash barrier mask of the present invention.
Fig. 4 is a front view of a mask band part according to an example of the present invention.
Fig. 5 is a view showing a method for measuring the droplet barrier property of the droplet barrier mask of the present invention.
Description of the reference numerals
100: droplet-blocking mask
10: mask body
11: gauze mask belt part
20: droplet shielding part
30: first snap fastener part
30': second snap fastener part
41: wearing belt
42: combining hole
43: joining member
Detailed Description
The present invention is not limited to the embodiments disclosed below, and can be implemented by various embodiments different from each other, however, the embodiments of the present invention are provided only for the purpose that the disclosure of the present invention becomes complete, so that those skilled in the art to which the present invention pertains can understand the scope of the present invention.
Unless otherwise defined, all terms (including technical and scientific terms) used in this specification have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. Also, unless a term defined in a commonly used dictionary is explicitly defined, it should not be interpreted in an ideal or excessive sense.
The size and thickness of each structure are arbitrarily shown for convenience of explanation, and the present invention is not limited to those shown in the drawings.
In addition, throughout the present specification, when it is described that a certain portion "includes" a certain structural element, unless there is a description to the contrary, it means that other structures may be included and other structural elements are not excluded.
Referring to fig. 1, a droplet blocking mask according to an embodiment of the present invention includes: a mask body part for providing a face receiving space; a mask band part extending from both side surfaces of the mask body part; and a splash barrier detachably coupled to an outer surface of the mask body, the splash barrier including a polymer resin and an antimicrobial agent dispersed in the polymer resin, the antimicrobial agent including copper, zinc oxide, and zeolite (zeolite).
In one embodiment of the present invention, the mask body 10 and the mask band 11 form the entire appearance of the mist barrier mask 100. In this case, unlike the conventional mask including the mask body and the mask band, the droplet isolation mask 100 of the present invention further includes the droplet isolation portion 20 including the antibacterial agent, so that not only the penetration of droplets from the outside of the mask to the inside of the mask body 10 can be isolated, but also bacteria and viruses can be effectively isolated.
The present invention relates to a splash-proof mask 100 including a mask body 10 and a mask band 11. According to an example, as shown in fig. 1, the mask band 11 is extended from both sides of the mask body and is integrally formed with the mask body, or as shown in fig. 4, the wearing part 41 is coupled to the coupling holes 42 provided in the mask body and the mist barrier 20 via the coupling member 43.
For example, the material of the mask body 10 and the mask band 11 is not particularly limited, and may be any material that is generally used in the art to which the present invention pertains.
For example, it may be one or more selected from the group consisting of woven fabric, non-woven fabric, polyester resin, seersucker, ultra fine fiber, poly spandex, Coolmax, cool yarn, saracol, virtual utility cube, polyester raw yarn (cotna) such as cotton, and ATB-UV (a composite of polyester and polyurethane). Preferably, it may be a polyester resin, and more preferably, it may be an askin (askin) or ATB-UV. The cool yarn (askin) and ATB-UV have an effect of blocking ultraviolet rays as functional fibers. Further, since the cool yarn is used as the cool material and ATB-UV has antibacterial property and quick-drying property, it has excellent wearing feeling when used for the mask body 10.
The mask body portion 10 of the present invention can be manufactured by a method generally used in the art to which the present invention pertains, and is not limited to the following manufacturing method. For example, the mask body portion 10 may be formed by a film molding method, an injection molding method, a hollow molding method, a duct molding method, a tube molding method, an outline molding method, a sheet molding method, or the like.
According to an example of the present invention, the splash barrier 20 may be formed of an antibacterial composition containing a polymer resin and an antibacterial agent dispersed in the polymer resin, and the antibacterial agent may contain copper, zinc oxide, and zeolite (zeolite).
The polymer resin described above can be used as a binder resin for linking the antibacterial agent by the base resin forming the mist barrier 20. The polymer resin can impart non-hygroscopicity, flexibility, and pathogen-barrier properties to the mist barrier section 20. The polymer resin can impart heat resistance, transparency, mechanical strength, chemical resistance, dimensional stability, moldability, and the like, depending on its kind, in addition to moisture absorption, flexibility, and pathogen-blocking property.
The polymer resin that can be used in the present invention is not particularly limited as long as it is a polymer resin generally known in the art to which the present invention pertains, and examples thereof include, but are not limited to, thermoplastic resins, thermoplastic elastomers, biodegradable polymers, and the like.
Specifically, the polymer resin may be, for example, a polyolefin resin (e.g., polyethylene such as Linear Low Density Polyethylene (LLDPE), Low Density Polyethylene (LDPE), High Density Polyethylene (HDPE), Ultra Low Density Polyethylene (ULDPE), polypropylene, etc.), Polystyrene (PS), acrylonitrile-butadiene-styrene resin (ABS resin), polyethylene terephthalate (PET), polyamide resin (e.g., nylon 66, nylon 6, etc.), Thermoplastic Polyurethane (TPU), polyvinyl chloride (PVC), Polycarbonate (PC), polymethyl methacrylate (PMMA), etc.; polyolefin elastomers (e.g., polyethylene elastomers (e.g., Very Low Density Polyethylene (VLDPE), etc.), polyethylene plastomers, polypropylene elastomers, polymethylpentene elastomers, etc.), thermoplastic elastomers such as Ethylene Vinyl Acetate (EVA), thermoplastic polyurethanes, etc.; polylactic Acid resin (PLA), Poly Lactic Acid resin (PAs), polyhydroxylated fatty Acid ester resin (PHA), Poly (hydroxyalkanoate) resin (PAs), Polyamides (PAs), polytrimethylene terephthalate (PTT), Poly (trimethylene terephthalate), polyethylene furan Acid ester (PEF), polyglycolic Acid resin (PGA), polycaprolactone resin (PCL), Poly (Caprolactone Acid), Poly (3-hydroxybutyrate) (PHB, D-3-hydroxybutyrate Acid), Polybutylene succinate (PBS, Polybutylene succinate Acid), Polybutylene adipate and butylene terephthalate resin (PBAT, butylene adipate-co-adipate), Polybutylene adipate (PBA, biodegradable polyester (SA)), Polybutylene succinate (PBAS), Polybutylene succinate-co-adipate (PBAT), Polybutylene succinate (TPS), etc., but is not limited thereto. These may be used alone or in combination of two or more. Preferably, the polymer resin may include one or more selected from the group consisting of polyethylene such as linear low density polyethylene, and the like, Ethylene Vinyl Acetate (EVA), and Thermoplastic Polyurethane (TPU).
In the above-mentioned droplet barrier section 20, the content of the above-mentioned polymer resin is not particularly limited, and for example, the content thereof may be in the range of about 95.5 weight percent to 99 weight percent based on the total weight of the corresponding antibacterial composition.
According to one example, the antimicrobial agent comprises copper, zinc oxide and zeolite (zeolite). In this case, the antibacterial activity against new coronaviruses such as Gram-positive (Gram (+)) bacteria and Gram-negative (Gram (-)) bacteria is excellent, unlike the case where copper, zinc oxide, and zeolite are used alone or as an antibacterial agent.
The copper is a metal having excellent antibacterial properties. The specific surface area of the copper is not particularly limited, and when the specific surface area is about 4000cm2G to 9000cm2In the range of/g, preferably 5000cm2G to 7500cm2In the range of/g, more preferably in the range of 6000cm2G to 7000cm2When the ratio is in the range of/g, the antibacterial activity against gram-positive bacteria can be further improved.
The shape of the copper is not particularly limited, but the shape of the copper is preferably a plate shape in order to maximize the antibacterial power. In this case, the length, width and thickness of the copper may be variously adjusted, for example, the length may be about 10 μm to 75 μm, the width may be about 10 μm to 75 μm, and the thickness may be about 3 μm to 10 μm. According to one example, the copper may have an aspect ratio (aspect ratio) of 1:1 to 1: 9. In this case, the thickness of the copper may be about 3 μm to 10 μm.
The content of the above copper is not particularly limited, and according to one example, the content thereof may be in the range of about 0.3 to 2 weight percent, preferably about 0.4 to 0.5 weight percent, based on the total weight of the corresponding antibacterial composition. According to another example, the ratio (mixing ratio) of copper and zinc oxide to be used may be a weight ratio of 67:33 to 57:43, preferably a weight ratio of 67:33 to 60:40, based on the total weight of copper and zinc oxide. According to another example, the ratio (mixing ratio) of copper, zinc oxide and zeolite (zeolite) may be 0.5 to 2.5:1:0.5 to 5 by weight, and preferably, may be mixed in a ratio of 1 to 2:1:1 to 5 by weight.
Further, the zinc oxide can impart not only excellent antibacterial properties but also deodorizing properties and Ultraviolet (UV) blocking properties to the mist barrier section 20 and impart ultra-water repellency thereto. In particular, in the present invention, zinc oxide can further provide antibacterial power against gram-negative bacteria.
When the zinc oxide is in a nano size, the antibacterial activity can be maximized by increasing the affinity with bacteria and the like. For example, the average diameter of the zinc oxide may be about 8nm to 100nm, preferably about 40nm to 80nm, and more preferably about 60nm to 75 nm.
The content of the above zinc oxide is not particularly limited, and according to one example, may be about 0.2 to 1 weight percent, preferably 0.2 to 0.3 weight percent, based on the total weight of the corresponding antibacterial composition. According to another example, the ratio (mixing ratio) of zinc oxide to zeolite may be 10:90 to 30:70 by weight, preferably 10:90 to 20:80 by weight, based on the total weight of zinc oxide to zeolite.
And, specifically, the above zeolite is an alkali metal and/or alkali metal-plated aluminum silicate (aluminum silicate) hydrate having (Si, Al) O as one basic unit4Tetrahedra share oxygen with other tetrahedra to form a three-dimensional network. The zeolite can impart antibacterial properties to the splash barrier 20.
The zeolite usable in the present invention is not particularly limited, and for example, ZSM-5 zeolite, zeolite A, zeolite X, zeolite Y, mordenite (M) can be usedordenite)、AlPO4Molecular sieves, SAPO molecular sieves, MeAlPO molecular sieves, SAPO-5 molecular sieves, XSM-5 molecular sieves, AIPO-5 molecular sieves, VPI-5 molecular sieves, MCM-41 molecular sieves, Chabazite (Chabazite), clinoptilolite (clinoptiolite), silica gel, zirconium, titanium, aluminum silicate and the like, which may be used alone or in admixture of two or more.
When the above zeolite is ion-exchanged with an antibacterial metal cation, the antibacterial property can be further maximized. The antimicrobial metal ion to be used is not particularly limited as long as it is a metal ion that can impart antimicrobial properties to the metal ion in general in the art to which the present invention pertains. As an example, the antibacterial metal ion may include one or more metal ions selected from the group consisting of zinc (Zn), silver (Ag), copper (Cu), tin (Sn), mercury (Hg), lead (Pb), bismuth (Bi), cadmium (Cd), chromium (Cr), calcium (Ca), sodium (Na), cesium (Cs), potassium (K), and magnesium (Mg).
The size (particle diameter), porosity and/or pore size of the zeolite are not particularly limited. As an example, the average diameter of the zeolite may be about 1 μm to 10 μm, preferably about 2 μm to 7 μm, and more preferably about 3 μm to 6 μm.
The content of the above zeolite is not particularly limited, and for example, may be about 0.5 to 1.5 weight percent, preferably about 0.8 to 1.2 weight percent, based on the total weight of the corresponding antibacterial composition.
In the antibacterial composition, the content of the antibacterial agent is not particularly limited, and for example, may be in the range of 1 to 4.5 weight percent based on the total weight of the corresponding antibacterial composition.
The above-mentioned antibacterial composition may optionally include additives commonly used in the art to which the present invention pertains, according to the purpose of use and the environment of use of the corresponding composition, in addition to the above-mentioned components, as required. For example, a dispersant, a hygroscopic agent, a stabilizer, etc., but is not limited thereto.
The content of the above-mentioned additives is not particularly limited and may be used within a general range known in the art to which the present invention pertains. For example, it may be about 0.001 to 10 weight percent, preferably about 0.01 to 5 weight percent, more preferably about 0.1 to 3 weight percent, based on the total weight of the corresponding antimicrobial composition.
The droplet-blocking section 20 formed of the antibacterial composition has an antibacterial activity value of 2 or more against gram-positive bacteria and gram-negative bacteria, respectively, and an antiviral activity value of 3 or more against a new coronavirus.
The above-mentioned antibacterial composition can be prepared by a method generally used in the art to which the present invention pertains. For example, the antibacterial composition can be prepared by mixing and stirring an antibacterial agent comprising a polymer resin, copper, zinc oxide and zeolite and selective additives at normal temperature or at an appropriate temperature using a mixing device such as a ball mill, a bead mill, a three-roll (3roll mill) basket (basketmill) mill, a nano mill (dyno mill), a planetary mill (planetary mill) or the like.
The splash barrier 20 of the present invention can be manufactured by a method generally used in the art to which the present invention pertains, and is not limited to the following manufacturing method. May be performed by modifying or selectively blending the steps of the respective processes according to the requirements. For example, after mixing (compounding) the antibacterial composition, the fly-barrier section 20 may be prepared by a processing method generally used in the art to which the present invention pertains, for example, a film molding method, an injection molding method, a hollow molding method, a pipe molding method, a tube molding method, an outline molding method, a sheet molding method, and the like.
According to one example, the splash barrier 20 can be produced by a single-layer blow coextrusion method after mixing (compounding) by a twin-screw mixer (twin screw mixer).
According to an embodiment of the present invention, at least one surface of the droplet barrier 20 may be a matt (matt) surface. The matt surface may be formed by a matt (matt) process, thereby imparting a unique feel or appearance to the splash barrier 20. According to one example, the droplet blocking section 20 may include a surface concave-convex pattern section.
According to an embodiment of the present invention, the droplet-blocking portion 20 may include an opening formed below the droplet-blocking portion 20 And the end is used for ventilation. The opening part is arranged at the lower end of the mask, so that the breathing can be smooth even if the mask is worn for a long time. In this case, the opening is located in the lower jaw of the user to block the spray. According to an example, the size of the opening is 3cm2To 15cm2Preferably 8cm2To 12cm2
According to an example of the present invention, the splash guard 20 is detachably coupled to the outer peripheral surface of the mask body 10. In this case, the entrainment barrier 20 can be separated from the outer face of the mask body 10 by a fastening member, and therefore, when the entrainment barrier 20 is contaminated, the mask body 10 can be reused by merely replacing the entrainment barrier 20 while keeping the same.
In the present invention, the material used as the fastening member in the mask for preventing splash is not particularly limited, and a fastening member that is generally used in the art to which the present invention pertains and that can be coupled and separated may be used. For example, the fastening member may be one selected from the group consisting of a button insertion hole, a snap, a fastener tape, and a magnet. As shown in fig. 3, according to an embodiment of the present invention, the droplet blocking part 20 and the mask body part 10 may be coupled or separated by the first snap fastener member 30 provided at the droplet blocking part 20 and the second snap fastener member 30' provided at the mask body part 10.
According to an example of the present invention, the mask body 10 and the splash-proof part 20 may have a protruding shape corresponding to the protruding shape of the face of the user. In order to manufacture the mask body 10 and the droplet shielding part 20 having the above-described shapes, a high-frequency sealing (sealing) process may be performed. When manufacturing the plastic mask having the above shape, although the sticker is used conventionally, the sticker may be detached when the mask is washed or used for a long time.
In contrast, the present invention utilizes a high frequency sealing (sealing) process when manufacturing the mask body 10 and the droplet blocking member 20. In one embodiment of the present invention, the left and right side portions of the mask body 10 and the mist barrier 20 are formed in a left-right symmetrical shape, and both side end portions of the left and right side portions are attached by a high frequency sealing process, thereby manufacturing a mask having a protruding shape. The mask manufactured through the high frequency sealing process can maintain the three-dimensional structure of the mask even when washed or used for a long time, and thus can be used semi-permanently.
In the present description, the mask body 10 and the mist barrier 20 are exemplified to have a single-layer structure, but the present invention is not limited thereto. In addition to the structures exemplified in the present specification, other structures may be included, for example, the mask body 10 and the entrainment separator 20 may have two or more layers, respectively.
The present invention will be described in further detail below with reference to examples. However, the following examples are merely illustrative of the present invention and do not limit the scope of the present invention.
Example manufacture of a splash baffle mask
1-1. manufacturing of mask body
The mask body provided with the mask band portion was manufactured using a fabric obtained by laminating a cool yarn (Askin) fabric (manufactured by Xiaoxing Co.) and ATB-UV (manufactured by Koron Co.). The thickness of the mask body was 400 μm.
1-2. manufacture of spray barriers
Based on the total weight of the antibacterial composition, by mixing 98.3 weight percent of Polyolefin (PO) resin and 0.45 weight percent of copper, 0.25 weight percent of zinc oxide, 1.00 weight percent of Zn2+Ion-exchanged zeolite to prepare an antibacterial composition. The average specific surface area of copper was 6500cm2(ii) in terms of/g. And the average diameter of zinc oxide was 70 nm. By Zn2+The average diameter of the ion-exchanged zeolite was 5 μm.
The above-described antibacterial composition was charged into a twin-screw mixer (twin screw mixer) comprising a hopper (hopper), a screw (screw), a barrel (barrel) surrounding the screw, and a die (die) at the outlet of the main body, and the splash barrier was produced by a single-layer extrusion casting method. The thickness of the manufactured splash guard was 200 μm.
1-3. manufacturing of droplet-obstructing mask
The second snap member was formed on the mask body part manufactured in the above example 1-1, and the first snap member was formed on the splash barrier manufactured in the above example 1-2. A splash-blocking part is arranged on the outer face of the mask body part, and the first snap fastener component and the second snap fastener component are combined to manufacture the splash-blocking mask.
Comparative example 1 production of general mask
A general mask composed of a mask body provided with a mask band portion was manufactured using a cool yarn (ashin) fabric (manufactured by xiaoxing corporation).
Comparative examples 2 to 5
Medical masks (disposable masks, available from the company Crosspartner), cold-proof masks (bamboo fiber masks, available from the company HD Medis), KF-94 masks (daily epidemic mask, available from the company Kleenex), and KF-AD masks (foam-blocking air mask, available from the company Kleenex) were used as the masks in comparative examples 2 to 5, respectively
Comparative example 6
A KF-AD mask was attached to the outside of a 3D mask (a cool and comfortable three-dimensional mask available from friendly daddy corporation) to manufacture a double mask.
Comparative example 7
A KF-94 mask was attached to the outside of a 3D mask (a cool and comfortable three-dimensional mask available from friendly daddy corporation) to manufacture a double mask.
Evaluation example 1 evaluation of flying foam Barrier Property
In order to measure the spray barrier properties of the masks manufactured in examples and comparative examples, the moisture reflectance (%), moisture absorption (%) and moisture permeability (%) were measured by the following methods.
The mask manufactured by the examples or comparative examples was worn on a human body model. As shown in FIG. 5, after a spray gun was set at a position 30cm from the phantom, 50g of water at 30 ℃ was sprayed for 60 seconds. In this case, the spray gun had a nozzle diameter of 1.8mm and a spray pressure of 3kgf/cm2The spray angle was 45 degrees. After 60 seconds passed after the completion of the spraying, the moisture reflectance (%), the moisture absorption (%) and the moisture permeability (%) were measured, and the results are shown in table 1 below. In this case, the sum of the above values should be 100%, but it is estimated from the moisture dispersion (%) that the evaporation in the air is causedDosage, etc., within 1% -5%.
1. Water content reflectance (%)
The moisture reflectance means a degree to which moisture sprayed from the spray gun is reflected again to the outside of the mask. The moisture reflectance may be calculated according to the following equation 1.
Equation 1
Figure BDA0003199929250000081
In this case, since the masks of comparative examples 1 to 5 have no outer skin, only the weight of water falling under the manikin was measured.
2. Water absorption rate (%)
The moisture absorption rate means a degree of absorption of moisture sprayed from the spray gun by the inner skin of the mask. The moisture absorption rate can be calculated according to the following equation 2.
Equation 2
Figure BDA0003199929250000082
3. Moisture permeability (%)
The moisture permeability refers to the degree of penetration of moisture sprayed from a spray gun into the interior of the mannequin. The moisture permeability can be calculated according to the following formula 3.
Equation 3
Figure BDA0003199929250000091
TABLE 1
Water content reflectance (%) Water absorption rate (%) Water permeability (%)
Examples 93 4 0
Comparative example 1 6 89 4
Comparative example 2 10 83 5
Comparative example 3 3 89 6
Comparative example 4 17 82 0
Comparative example 5 30 68 0
Comparative example 6 30 70 0
Comparative example 7 17 88 0
As shown in table 1 above, it was confirmed that the mask of the present invention has a moisture reflectance as high as 93%, a moisture absorptance as low as 4%, and a moisture permeability of 0% (example 1). In contrast, it was confirmed that the normal mask had a moisture reflectance of 30% or less and a moisture absorptance of 68% or more (comparative examples 1 to 5). Further, it was confirmed that the double mask made by combining the two masks had a moisture reflectance of 30% or less and a moisture absorptance of 70% or more (comparative examples 6 and 7).
As described above, it was confirmed that the mask of the present invention has excellent droplet barrier properties compared to the normal mask and the double mask of the comparative examples, since the mask further includes the droplet barrier portion including the polymer resin.
Evaluation example 2 evaluation of antiviral Properties and antibacterial Properties
Test pieces having a size of 5cm (transverse direction) × 5cm (longitudinal direction) were produced using the splash barrier of example 1, and the antibacterial property and antiviral property were measured according to JIS-Z-2801 and ISO-21702 standards, respectively.
As a result, the droplet barrier section of the present invention has excellent antibacterial and antiviral properties, and it has been confirmed that the droplet barrier section has an antibacterial property of 99.99% or more against staphylococcus aureus, an antibacterial property of 99.99% or more against escherichia coli, and an antiviral property of 99.99% or more against Bovine Coronavirus (BCoV, Bovine Coronavirus).

Claims (14)

1. A spray barrier mask, which is characterized in that,
the method comprises the following steps:
a mask body part for providing a face receiving space;
a mask band part extending from both side surfaces of the mask body part; and
a droplet blocking part detachably connected with the outer surface of the mask body part,
the splash barrier comprises a polymer resin and an antibacterial agent dispersed in the polymer resin,
the antibacterial agent comprises copper, zinc oxide and zeolite.
2. The entrainment barrier mask of claim 1 wherein said entrainment barrier is joined to said mask body by a fastening member attached to an outer surface of said mask body.
3. The droplet barrier mask of claim 1 wherein said fastening means is one selected from the group consisting of button insertion holes, snap fasteners, fastener strips and magnets.
4. The mask according to claim 1, wherein the droplet barrier is of a replaceable type.
5. The mask according to claim 1, wherein the mask comprises copper, zinc oxide and zeolite in a weight ratio of 0.5-2.5:1: 0.5-5.
6. The mask according to claim 1, wherein the polymer resin comprises at least one selected from the group consisting of thermoplastic resins, thermoplastic elastomers, and biodegradable polymer resins.
7. The splash-barrier mask according to claim 1, wherein the splash-barrier portion comprises an antibacterial composition comprising 95.5 to 99 wt% of a polymeric resin, 0.3 to 2 wt% of copper, 0.2 to 1 wt% of zinc oxide, and 0.5 to 1.5 wt% of zeolite, based on the total weight of the antibacterial composition.
8. The mask of claim 1 wherein at least one surface of said droplet barrier has a matte surface.
9. The mask of claim 1, wherein the droplet barrier portion comprises an opening formed at a lower end of the droplet barrier portion for ventilation.
10. The splash barrier mask as claimed in claim 1, wherein said mask body comprises a polyester resin.
11. The splash barrier mask of claim 10, wherein said polyester resin comprises one or more selected from the group consisting of a cool-feeling yarn and an ATB-UV resin.
12. The droplet barrier mask of claim 1,
satisfies one or more of the following (i) to (iii):
a moisture reflectance of 80% or more;
(ii) a moisture absorption rate of 10% or less;
(iii) a water permeability of 3% or less.
13. The splash-barrier mask according to claim 1, wherein the splash-barrier portion has an antibacterial activity of 99.99% or more against gram-positive bacteria and gram-negative bacteria according to JIS-Z-2801.
14. The droplet barrier mask of claim 1 wherein said droplet barrier has an antiviral activity of 99.99% or more against a new coronavirus according to ISO-21702 standard.
CN202110901472.4A 2021-01-08 2021-08-06 Droplet-blocking mask Pending CN114747820A (en)

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KR1020210002817A KR102641313B1 (en) 2021-01-08 2021-01-08 Mask for blocking splash

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JP2017101374A (en) * 2015-10-30 2017-06-08 株式会社ジムウェイ Antiviral hygienic mask
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CN111516183A (en) * 2020-04-03 2020-08-11 江苏理工学院 Recycling method of waste mask

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CN106255533B (en) * 2014-06-20 2019-12-10 东亚合成株式会社 Deodorant mask
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Publication number Priority date Publication date Assignee Title
JPH11246781A (en) * 1998-03-02 1999-09-14 Kanebo Ltd Antibacterial resin composition
CN1599556A (en) * 2001-10-15 2005-03-23 富士施乐株式会社 Inorganic antimicrobial agent, antimicrobial molded resin articles using the same and process for the production thereof
CN1467314A (en) * 2003-06-12 2004-01-14 东南大学 Antibiotic nanometer fibrous material and method for preparing the same
CN101005762A (en) * 2004-07-13 2007-07-25 出光技优股份有限公司 Antibacterial composition, antibacterial molding, solution containing antibacterial composition, detergent, surface of tatami mat and tatami mat
CN101272988A (en) * 2005-09-27 2008-09-24 株式会社品燃洁而美客 Antibacterial zeolite and antibacterial resin composition
JP2017101374A (en) * 2015-10-30 2017-06-08 株式会社ジムウェイ Antiviral hygienic mask
KR20200030332A (en) * 2018-09-12 2020-03-20 코오롱머티리얼 주식회사 mask
CN111516183A (en) * 2020-04-03 2020-08-11 江苏理工学院 Recycling method of waste mask

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