CN114735975B - Flame-retardant corrosion-resistant plate and preparation method thereof - Google Patents
Flame-retardant corrosion-resistant plate and preparation method thereof Download PDFInfo
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- CN114735975B CN114735975B CN202210555779.8A CN202210555779A CN114735975B CN 114735975 B CN114735975 B CN 114735975B CN 202210555779 A CN202210555779 A CN 202210555779A CN 114735975 B CN114735975 B CN 114735975B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/26—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/2611—Polyalkenes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/28—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B24/283—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/23—Acid resistance, e.g. against acid air or rain
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
The invention discloses a flame-retardant corrosion-resistant plate and a preparation method thereof. The composite material is prepared from the following raw materials in parts by weight: 50-120 parts of cement, 10-40 parts of inorganic fibers, 20-60 parts of natural mineral aggregate, 10-20 parts of resin, 1-3 parts of water reducer, 2-5 parts of curing agent, 1-6 parts of flame retardant and 20-60 parts of water. The flame-retardant plate prepared by the invention has good corrosion resistance, the mineral combination of the hydroxy-boron-magnesium stone and the lycra stone is added in the components, the mechanical property of the material is enhanced, and the acid-base resistance of the material is enhanced by adding the poly-2, 5-furandicarboxylic acid glycol ester and the polyisobutene.
Description
Technical Field
The invention belongs to the technical field of building materials, and particularly relates to a flame-retardant corrosion-resistant plate and a preparation method thereof.
Background
With the increasing demand of people for building materials, natural boards such as marble and other resources are increasingly exhausted, and more artificial boards are developed and utilized. The artificial boards include plywood, carpentry board, fiber board, honeycomb board, gypsum board, calcium silicate board, aluminum plastic board, chopping board, bookable board, decorative board, baoli board, etc.
The artificial boards made of wood materials such as plywood, woodworking board, fiber board and the like have poor flame retardance and are easy to burn to cause fire, and the aluminum plastic board, the chopping board, the stapable board, the decorative board, the Baoli board and the like have poor corrosion resistance and the gypsum board and the calcium silicate board have poor mechanical properties.
Disclosure of Invention
The invention aims to provide a flame-retardant corrosion-resistant plate and a preparation method thereof.
A flame-retardant corrosion-resistant plate is prepared from the following raw materials in parts by weight: 50-120 parts of cement, 10-40 parts of inorganic fibers, 20-60 parts of natural mineral aggregate, 10-20 parts of resin, 1-3 parts of water reducer, 2-5 parts of curing agent, 1-6 parts of flame retardant and 20-60 parts of water.
The inorganic fiber is one or a mixture of more of glass fiber, basalt fiber, boron fiber and ceramic fiber.
The natural mineral materials are the diborite and the lycra according to the mass ratio of 1: 1.
The resin is polyethylene 2, 5-furandicarboxylic acid glycol ester and polyisobutylene according to the mass ratio of 1: 1.
The water reducer is one or a mixture of more of polycarboxylic acid, melamine, aminobenzene sulfonate and lignin sulfonate.
The curing agent is one or a mixture of more of hexamethylenetetramine, tert-butyl peroxy-2-ethylhexanoate, tert-butyl peroxybenzoate and benzoyl peroxide.
The flame retardant is one or a mixture of more of ammonium polyphosphate, borax, magnesium hydroxide, phosphate and phosphorus pentoxide.
The preparation method of the flame-retardant corrosion-resistant plate comprises the following steps:
(1) According to the weight portions, 50 to 120 portions of cement, 10 to 40 portions of inorganic fiber, 20 to 60 portions of natural mineral aggregate, 10 to 20 portions of resin, 1 to 3 portions of water reducer, 2 to 5 portions of curing agent, 1 to 6 portions of flame retardant and 20 to 60 portions of water are taken, stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming mold frame, erasing bubbles by a spatula and receiving light to form a material blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
And a release film is preset in the forming die frame.
The invention has the beneficial effects that: the flame-retardant plate prepared by the invention has good corrosion resistance, the mineral combination of the hydroxy-boron-magnesium stone and the lycra stone is added in the components, the mechanical property of the material is enhanced, and the acid-base resistance of the material is enhanced by adding the poly-2, 5-furandicarboxylic acid glycol ester and the polyisobutene.
Detailed Description
The present invention will be described more fully hereinafter in order to facilitate an understanding of the present invention. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.
Example 1
A flame-retardant corrosion-resistant plate is prepared from the following raw materials in parts by weight: 80 parts of cement, 20 parts of glass fiber, 40 parts of natural mineral aggregate, 15 parts of resin, 2 parts of polycarboxylic acid, 4 parts of hexamethylenetetramine, 4 parts of ammonium polyphosphate and 40 parts of water; the natural mineral materials are the diborite and the lycra according to the mass ratio of 1: 1; the resin is polyethylene 2, 5-furandicarboxylic acid glycol ester and polyisobutylene according to the mass ratio of 1: 1.
The preparation method of the flame-retardant corrosion-resistant plate comprises the following steps:
(1) According to the weight portions, 80 portions of cement, 20 portions of glass fiber, 40 portions of natural mineral aggregate, 15 portions of resin, 2 portions of polycarboxylic acid, 4 portions of hexamethylenetetramine, 4 portions of ammonium polyphosphate and 40 portions of water are taken and stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming die frame, presetting a release film in the forming die frame, erasing bubbles by a spatula and receiving light to form a blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
Example 2
A flame-retardant corrosion-resistant plate is prepared from the following raw materials in parts by weight: 55 parts of cement, 12 parts of basalt fiber, 22 parts of natural mineral aggregate, 10 parts of resin, 1 part of aminobenzenesulfonate, 2 parts of tert-butyl peroxy-2-ethylhexanoate, 2 parts of borax and 25 parts of water; the natural mineral materials are the diborite and the lycra according to the mass ratio of 1: 1; the resin is polyethylene 2, 5-furandicarboxylic acid glycol ester and polyisobutylene according to the mass ratio of 1: 1.
The preparation method of the flame-retardant corrosion-resistant plate comprises the following steps:
(1) According to the weight portions, the cement is 55 portions, basalt fiber is 12 portions, natural mineral aggregate is 22 portions, resin is 10 portions, aminobenzene sulfonate is 1 portion, tert-butyl peroxy-2-ethylhexanoate is 2 portions, borax is 2 portions, and water is 25 portions, and the materials are stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming die frame, presetting a release film in the forming die frame, erasing bubbles by a spatula and receiving light to form a blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
Example 3
A flame-retardant corrosion-resistant plate is prepared from the following raw materials in parts by weight: 110 parts of cement, 20 parts of boron fiber, 20 parts of ceramic fiber, 60 parts of natural mineral aggregate, 20 parts of resin, 3 parts of lignosulfonate, 5 parts of tert-butyl peroxybenzoate, 6 parts of magnesium hydroxide and 60 parts of water; the natural mineral materials are the diborite and the lycra according to the mass ratio of 1: 1; the resin is polyethylene 2, 5-furandicarboxylic acid glycol ester and polyisobutylene according to the mass ratio of 1: 1.
The preparation method of the flame-retardant corrosion-resistant plate comprises the following steps:
(1) According to the weight portions, 110 portions of cement, 20 portions of boron fiber, 20 portions of ceramic fiber, 60 portions of natural mineral aggregate, 20 portions of resin, 3 portions of lignosulfonate, 5 portions of tert-butyl peroxybenzoate, 6 portions of magnesium hydroxide and 60 portions of water are taken, stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming die frame, presetting a release film in the forming die frame, erasing bubbles by a spatula and receiving light to form a blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
Comparative example 1
A flame-retardant corrosion-resistant plate is prepared from the following raw materials in parts by weight: 80 parts of cement, 20 parts of glass fiber, 40 parts of hydroxy-boron-magnesia, 15 parts of resin, 2 parts of polycarboxylic acid, 4 parts of hexamethylenetetramine, 4 parts of ammonium polyphosphate and 40 parts of water; the resin is polyethylene 2, 5-furandicarboxylic acid glycol ester and polyisobutylene according to the mass ratio of 1: 1.
The preparation method of the flame-retardant corrosion-resistant plate comprises the following steps:
(1) According to the weight portions, 80 portions of cement, 20 portions of glass fiber, 40 portions of hydroxy boron magnesium stone, 15 portions of resin, 2 portions of polycarboxylic acid, 4 portions of hexamethylenetetramine, 4 portions of ammonium polyphosphate and 40 portions of water are taken and stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming die frame, presetting a release film in the forming die frame, erasing bubbles by a spatula and receiving light to form a blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
Comparative example 2
A flame-retardant corrosion-resistant plate is prepared from the following raw materials in parts by weight: 80 parts of cement, 20 parts of glass fiber, 40 parts of lycra, 15 parts of resin, 2 parts of polycarboxylic acid, 4 parts of hexamethylenetetramine, 4 parts of ammonium polyphosphate and 40 parts of water; the resin is polyethylene 2, 5-furandicarboxylic acid glycol ester and polyisobutylene according to the mass ratio of 1: 1.
The preparation method of the flame-retardant corrosion-resistant plate comprises the following steps:
(1) According to the weight portions, 80 portions of cement, 20 portions of glass fiber, 40 portions of lycra stone, 15 portions of resin, 2 portions of polycarboxylic acid, 4 portions of hexamethylenetetramine, 4 portions of ammonium polyphosphate and 40 portions of water are taken and stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming die frame, presetting a release film in the forming die frame, erasing bubbles by a spatula and receiving light to form a blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
Comparative example 3
A flame-retardant corrosion-resistant plate is prepared from the following raw materials in parts by weight: 80 parts of cement, 20 parts of glass fiber, 40 parts of natural mineral aggregate, 15 parts of polyethylene 2, 5-furandicarboxylate, 2 parts of polycarboxylic acid, 4 parts of hexamethylenetetramine, 4 parts of ammonium polyphosphate and 40 parts of water; the resin is polyisobutylene with the mass ratio of 1: 1.
The preparation method of the flame-retardant corrosion-resistant plate comprises the following steps:
(1) According to the weight portions, 80 portions of cement, 20 portions of glass fiber, 40 portions of natural mineral aggregate, 15 portions of polyethylene 2, 5-furandicarboxylate, 2 portions of polycarboxylic acid, 4 portions of hexamethylenetetramine, 4 portions of ammonium polyphosphate and 40 portions of water are taken and stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming die frame, presetting a release film in the forming die frame, erasing bubbles by a spatula and receiving light to form a blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
Comparative example 4
A flame-retardant corrosion-resistant plate is prepared from the following raw materials in parts by weight: 80 parts of cement, 20 parts of glass fiber, 40 parts of natural mineral aggregate, 15 parts of polyisobutene, 2 parts of polycarboxylic acid, 4 parts of hexamethylenetetramine, 4 parts of ammonium polyphosphate and 40 parts of water; the natural mineral materials are the diborite and the lycra according to the mass ratio of 1: 1.
The preparation method of the flame-retardant corrosion-resistant plate comprises the following steps:
(1) According to the weight portions, 80 portions of cement, 20 portions of glass fiber, 40 portions of natural mineral aggregate, 15 portions of polyisobutene, 2 portions of polycarboxylic acid, 4 portions of hexamethylenetetramine, 4 portions of ammonium polyphosphate and 40 portions of water are taken and stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming die frame, presetting a release film in the forming die frame, erasing bubbles by a spatula and receiving light to form a blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
Experimental example:
the flame retardant and corrosion resistant plates prepared in examples 1 to 3 and comparative examples 1 to 4 were measured for quality performance parameters by the methods of artificial stone-JCT 908-2013 and DB44/T1601-2015, and the measurement results are shown in tables 1 to 2.
TABLE 1
Note that: * Representing p <0.05 compared to example 1.
TABLE 2
The above examples illustrate only a few embodiments of the invention, which are described in detail and are not to be construed as limiting the scope of the invention. It should be noted that it will be apparent to those skilled in the art that several variations and modifications can be made without departing from the spirit of the invention, which are all within the scope of the invention. Accordingly, the scope of protection of the present invention is to be determined by the appended claims.
Claims (7)
1. The flame-retardant corrosion-resistant plate is characterized by being prepared from the following raw materials in parts by weight: 50-120 parts of cement, 10-40 parts of inorganic fibers, 20-60 parts of natural mineral aggregate, 10-20 parts of resin, 1-3 parts of water reducer, 2-5 parts of curing agent, 1-6 parts of flame retardant and 20-60 parts of water;
the natural mineral materials are the diborite and the lycra according to the mass ratio of 1: 1;
the resin is polyethylene 2, 5-furandicarboxylic acid glycol ester and polyisobutylene according to the mass ratio of 1: 1.
2. The flame-retardant and corrosion-resistant sheet material according to claim 1, wherein the inorganic fiber is one or a mixture of several of glass fiber, basalt fiber, boron fiber and ceramic fiber.
3. The flame-retardant and corrosion-resistant sheet material according to claim 1, wherein the water reducing agent is one or a mixture of several of polycarboxylic acid, melamine, aminobenzene sulfonate and lignin sulfonate.
4. The flame-retardant corrosion-resistant sheet material according to claim 1, wherein the curing agent is one or a mixture of a plurality of hexamethylenetetramine, tert-butyl peroxy-2-ethylhexanoate, tert-butyl peroxybenzoate or benzoyl peroxide.
5. The flame-retardant corrosion-resistant sheet material according to claim 1, wherein the flame retardant is one or a mixture of more of ammonium polyphosphate, borax, magnesium hydroxide, phosphate and phosphorus pentoxide.
6. The method for preparing the flame-retardant and corrosion-resistant plate as claimed in claim 1, which is characterized by comprising the following steps:
(1) According to the weight portions, 50 to 120 portions of cement, 10 to 40 portions of inorganic fiber, 20 to 60 portions of natural mineral aggregate, 10 to 20 portions of resin, 1 to 3 portions of water reducer, 2 to 5 portions of curing agent, 1 to 6 portions of flame retardant and 20 to 60 portions of water are taken, stirred and mixed uniformly;
(2) Putting the material obtained in the step (1) into a forming mold frame, erasing bubbles by a spatula and receiving light to form a material blank;
(3) And solidifying and forming the blank at room temperature, and demoulding to obtain the flame-retardant corrosion-resistant plate.
7. The method for producing a flame retardant corrosion resistant sheet material according to claim 6, wherein a release film is provided in advance in the molding frame.
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| CN202210555779.8A CN114735975B (en) | 2022-05-20 | 2022-05-20 | Flame-retardant corrosion-resistant plate and preparation method thereof |
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| CN202210555779.8A CN114735975B (en) | 2022-05-20 | 2022-05-20 | Flame-retardant corrosion-resistant plate and preparation method thereof |
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| CN114735975B true CN114735975B (en) | 2023-05-26 |
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Citations (2)
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| CN102911369A (en) * | 2011-08-04 | 2013-02-06 | 北京化工大学 | Isobutylene/tetrahydrofuran block copolymer and preparation method thereof |
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| AU2002363844A1 (en) * | 2001-12-22 | 2003-07-15 | Henkel Kgaa | Method for coating a cement-containing molding piece |
| DE50303577D1 (en) * | 2002-03-04 | 2006-07-06 | Basf Ag | PROCESS FOR PREPARING ISOBUTEN POLYMERS |
| CN1611564A (en) * | 2003-10-28 | 2005-05-04 | 张育生 | Toughened modified furan resin anticorrosive material composition |
| US8354469B2 (en) * | 2005-11-25 | 2013-01-15 | Solvay Solexis, Inc. | Perfluoropolymer composition |
| ITMI20121999A1 (en) * | 2012-11-26 | 2014-05-27 | Sintostamp S P A | MULTILAYER LAMINATE FOR THE MANUFACTURE OF INSULATED PANELS |
| CN103350535B (en) * | 2013-06-25 | 2016-04-13 | 江苏海龙核科技股份有限公司 | A kind of preparation method of novel composite fireproof plate |
| CN107793067A (en) * | 2017-11-24 | 2018-03-13 | 朱冠军 | A kind of quartzy sheet material and its preparation technology with flame-retardant high-elasticity performance |
| CN111517736B (en) * | 2020-04-29 | 2022-02-11 | 廊坊市北辰创业树脂材料股份有限公司 | Light non-combustible sound insulation board and preparation method thereof |
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| CN113444327A (en) * | 2021-07-23 | 2021-09-28 | 江苏正扬门窗有限公司 | Preparation method of borosilicate flame-retardant wall insulation board |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1097543A (en) * | 1977-08-02 | 1981-03-17 | Erion, George L., Iii | Method for preserving porous inorganic substrates |
| CN102911369A (en) * | 2011-08-04 | 2013-02-06 | 北京化工大学 | Isobutylene/tetrahydrofuran block copolymer and preparation method thereof |
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| "聚异丁烯基弹性体的研究进展";任纪文等;《合成橡胶工业》;第400-406页 * |
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