CN114735840A - Visual fenton reaction system - Google Patents

Visual fenton reaction system Download PDF

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Publication number
CN114735840A
CN114735840A CN202210187850.1A CN202210187850A CN114735840A CN 114735840 A CN114735840 A CN 114735840A CN 202210187850 A CN202210187850 A CN 202210187850A CN 114735840 A CN114735840 A CN 114735840A
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China
Prior art keywords
assembly
conditioning
control
reagent
fenton reaction
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Pending
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CN202210187850.1A
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Chinese (zh)
Inventor
郭润泽
付明
潘亮
覃文政
赵云斌
郭振江
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Shenzhen Shuangrui Environmental Energy Technology Co ltd
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Shenzhen Shuangrui Environmental Energy Technology Co ltd
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Priority to CN202210187850.1A priority Critical patent/CN114735840A/en
Publication of CN114735840A publication Critical patent/CN114735840A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/72Treatment of water, waste water, or sewage by oxidation
    • C02F1/722Oxidation by peroxides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5281Installations for water purification using chemical agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

The invention relates to a visual Fenton reaction system, which comprises: the device comprises a visual control mechanism, a Fenton reaction mechanism, a feeding mechanism, a conditioning mechanism and a precipitation mechanism; the visual control mechanism is respectively in control connection with the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism and is used for treating industrial organic wastewater; the feeding mechanism is connected with the Fenton reaction mechanism and can provide a reaction reagent and wastewater to be treated for the interior of the Fenton reaction mechanism; the Fenton reaction mechanism is also connected with the conditioning mechanism and can discharge the primary treated water subjected to the Fenton reaction into the conditioning mechanism so as to condition the pH value of the primary treated water; the conditioning mechanism is also connected with the precipitation mechanism and can discharge the conditioned treated water into the precipitation mechanism for sludge precipitation treatment so as to obtain qualified treated water. The system provided by the invention has high automation degree and excellent controllability, and effectively realizes the purposes of economy, high efficiency and safe production.

Description

Visual fenton reaction system
Technical Field
The invention belongs to the technical field of wastewater treatment, and particularly relates to a visual Fenton reaction system.
Background
The Fenton reaction, an inorganic chemical reaction, is a process of hydrogen peroxide (H)2O2) With ferrous iron ion Fe2+The mixed solution of (a) oxidizes many known organic compounds such as carboxylic acids, alcohols, esters into an inorganic state. The reaction has high capability of removing organic pollutants which are difficult to degrade, and is widely applied to the treatment of printing and dyeing wastewater, oily wastewater, phenol-containing wastewater, coking wastewater, nitrobenzene-containing wastewater, diphenylamine wastewater and other wastewater.
However, the existing fenton reaction system has the problems of low automation degree and poor controllability in the reaction working process, and further the safety and the working efficiency of the system cannot meet the requirements of safety and economy.
Disclosure of Invention
Technical problem to be solved
Aiming at the existing technical problems, the invention provides a visual Fenton reaction system which is high in automation degree and excellent in controllability and effectively achieves the purposes of economy, high efficiency and safe production.
(II) technical scheme
In order to achieve the purpose, the invention adopts the main technical scheme that:
a visual fenton reaction system comprising: the device comprises a visual control mechanism, a Fenton reaction mechanism, a feeding mechanism, a conditioning mechanism and a precipitation mechanism;
the visual control mechanism is respectively in control connection with the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism and is used for treating industrial organic wastewater;
the feeding mechanism is connected with the Fenton reaction mechanism and can provide a reaction reagent and wastewater to be treated for the interior of the Fenton reaction mechanism;
the Fenton reaction mechanism is also connected with the conditioning mechanism, and can discharge the primary treated water subjected to the Fenton reaction into the conditioning mechanism so as to condition the pH value of the primary treated water;
the conditioning mechanism is also connected with the precipitation mechanism and can discharge the conditioned treated water into the precipitation mechanism for sludge precipitation treatment so as to obtain qualified treated water.
Preferably, the visual control mechanism comprises: a control assembly and a detection assembly;
the control assembly is arranged in the control chamber and is connected with the detection assembly;
the detection assembly can collect the working state data of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism respectively and send the detected working state data to the control assembly.
Preferably, the control assembly comprises: a control host and a display device;
the control host is connected with the display equipment;
the control host is also respectively in control connection with the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism, the precipitation mechanism and the detection assembly;
the control host is also connected with a factory power supply and a factory intranet;
the display equipment can display the working state information of the reaction system to workers;
the staff can send out a control instruction through the display equipment according to the displayed working state information;
the control instruction is used for controlling the work of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism, the precipitation mechanism and the detection assembly.
Preferably, the fenton reaction mechanism includes: a reaction vessel pool and a reagent addition assembly;
the reaction container pool and the reagent adding assembly are both connected with the visual control mechanism;
the reagent adding assembly is connected with the reaction container pool and can add reaction reagents into the reaction container pool under the control of the visual control mechanism;
the reaction container pool is also connected with the feeding mechanism and the conditioning mechanism respectively;
wherein the feeding mechanism can add industrial organic wastewater into the reaction container pool under the control of the visual control mechanism;
the reaction container pool can discharge the primary treatment water after Fenton reaction treatment under the control of the visual control mechanism into the conditioning mechanism to condition the acidity and alkalinity of the primary treatment water.
Preferably, the reagent addition assembly comprises: a sulfuric acid reagent tank, a ferrous sulfate reagent tank and a hydrogen peroxide reagent tank;
the sulfuric acid reagent tank, the ferrous sulfate reagent tank and the hydrogen peroxide reagent tank are all connected with the reaction container pool;
the sulfuric acid reagent tank, the ferrous sulfate reagent tank and the hydrogen peroxide reagent tank can orderly add reasonable reagent amount to the reaction container pool under the control of the visual control mechanism so as to complete the primary Fenton treatment of the wastewater.
Preferably, the feed mechanism includes: a waste water storage assembly and a waste water pumping assembly;
the wastewater pumping assembly is connected with the visual control mechanism;
the waste water storage assembly is connected with the reaction container pool;
the waste water pumping assembly is arranged on the waste water storage assembly;
the wastewater pumping assembly can pump wastewater in the wastewater storage assembly into the reaction container pool under the control of the visual control mechanism.
Preferably, the conditioning mechanism comprises: a conditioning tank assembly and a conditioning reagent tank;
the conditioning reagent tank is respectively connected with the visual control mechanism and the conditioning tank assembly;
the reaction container pool is connected with the conditioning tank assembly and can discharge primary treatment water into the conditioning tank assembly;
the conditioning tank assembly is also connected with the settling assembly.
Preferably, an alkaline reagent is arranged in the conditioning reagent tank, and the alkaline reagent can be added into the conditioning tank assembly under the control of the visual control mechanism so as to neutralize and condition the primary treated water in the conditioning tank assembly.
Preferably, the precipitation mechanism comprises: a sedimentation tank assembly and a sedimentation reagent tank assembly;
the sedimentation reagent tank assembly is respectively connected with the visual control mechanism and the sedimentation tank assembly;
the sedimentation reagent tank assembly can add sedimentation reagent into the sedimentation tank assembly under the control of the visual control mechanism, so that the treated water after conditioning is subjected to sludge sedimentation treatment, and qualified treated water is obtained.
Preferably, the detection assembly comprises: the device comprises an acid-base detection unit, a water quantity detection unit, a water quality detection unit, a reagent quantity detection unit and a visual detection unit;
the acid-base detection unit, the water quantity detection unit, the water quality detection unit, the reagent quantity detection unit and the visual detection unit are all connected with the visual control mechanism;
the acid-base detection unit, the water quantity detection unit, the water quality detection unit, the reagent amount detection unit and the visual detection unit can respectively detect the working state data of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism, and can send the detected working state data to the visual control mechanism.
(III) advantageous effects
The invention has the beneficial effects that: the visual Fenton reaction system provided by the invention has the following beneficial effects:
the automation degree is high, the controllability is excellent, and the purposes of economy, high efficiency and safe production are effectively considered.
Drawings
Fig. 1 is a schematic structural diagram of a visual fenton reaction system provided by the present invention;
fig. 2 is a schematic partial structural diagram of a visual fenton reaction system provided by the present invention;
fig. 3 is a schematic structural diagram of a visual control mechanism of a visual fenton reaction system according to the present invention.
Detailed Description
For the purpose of better explaining the present invention and to facilitate understanding, the present invention will be described in detail by way of specific embodiments with reference to the accompanying drawings.
As shown in fig. 1 and 2: the embodiment discloses a visual fenton reaction system, includes: the device comprises a visual control mechanism, a Fenton reaction mechanism, a feeding mechanism, a conditioning mechanism and a precipitation mechanism;
the visual control mechanism is respectively in control connection with the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism and is used for treating industrial organic wastewater; the feeding mechanism is connected with the Fenton reaction mechanism and can provide a reaction reagent and wastewater to be treated for the interior of the Fenton reaction mechanism; the Fenton reaction mechanism is also connected with the conditioning mechanism, and can discharge the primary treated water subjected to the Fenton reaction into the conditioning mechanism so as to condition the pH value of the primary treated water; the conditioning mechanism is also connected with the precipitation mechanism and can discharge the conditioned treated water into the precipitation mechanism for sludge precipitation treatment so as to obtain qualified treated water.
It should be noted that: the staff can be with the help of visual control mechanism whole journey detects each detail of fenton's reaction degradation organic matter, and the guarantee is handled industrial waste water safely high-efficiently, makes it reach the discharge standard of regulation.
The visual control mechanism described in this embodiment includes: a control component and a detection component; the control assembly is arranged in the control chamber and is connected with the detection assembly; the detection assembly can respectively collect the working state data of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism, and sends the detected working state data to the control assembly.
The detection assembly can collect the change data of the working state of each step in the whole system in real time, and sends the corresponding data to the control assembly for scientific and effective optimization control.
The control assembly described in this embodiment includes: a control host and a display device; the control host is connected with the display equipment; the control host is also respectively in control connection with the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism, the precipitation mechanism and the detection assembly; the control host is also connected with a factory power supply and a factory intranet; the display equipment can show the working state information of the reaction system to the staff.
The working personnel can send out a control instruction through the display equipment according to the displayed working state information; the control instruction is used for controlling the work of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism, the precipitation mechanism and the detection assembly. The operational information includes, but is not limited to, data collected by the detection component.
Specifically, the fenton reaction mechanism in this embodiment includes: a reaction vessel pool and a reagent addition assembly; the reaction container pool and the reagent adding assembly are both connected with the visual control mechanism; the reagent adding assembly is connected with the reaction container pool and can add reaction reagents into the reaction container pool under the control of the visual control mechanism; the reaction container pool is also connected with the feeding mechanism and the conditioning mechanism respectively.
Wherein the feeding mechanism can add industrial organic wastewater into the reaction container pool under the control of the visual control mechanism; the reaction container pool can discharge the primary treatment water after Fenton reaction treatment under the control of the visual control mechanism into the conditioning mechanism to condition the acidity and alkalinity of the primary treatment water.
Because the acidity of the primary treatment water in the reaction tank is too high, the acidity and the alkalinity of the primary treatment water need to be further adjusted to reach a reasonable discharge range.
The reagent addition assembly described in this embodiment includes: a sulfuric acid reagent tank, a ferrous sulfate reagent tank and a hydrogen peroxide reagent tank; the sulfuric acid reagent tank, the ferrous sulfate reagent tank and the hydrogen peroxide reagent tank are all connected with the reaction container pool.
The sulfuric acid reagent tank, the ferrous sulfate reagent tank and the hydrogen peroxide reagent tank can orderly add reasonable reagent amount to the reaction container pool under the control of the visual control mechanism so as to complete the primary Fenton treatment of the wastewater.
The feed mechanism in this embodiment includes: a waste water storage assembly and a waste water pumping assembly; the wastewater pumping assembly is connected with the visual control mechanism; the waste water storage assembly is connected with the reaction container pool; the waste water pumping assembly is arranged on the waste water storage assembly; the wastewater pumping assembly can pump wastewater in the wastewater storage assembly into the reaction container pool under the control of the visual control mechanism.
The conditioning mechanism described in this embodiment includes: a conditioning tank assembly and a conditioning reagent tank; the conditioning reagent tank is respectively connected with the visual control mechanism and the conditioning tank assembly; the reaction container pool is connected with the conditioning tank assembly and can discharge primary treatment water into the conditioning tank assembly; the conditioning tank assembly is also connected with the settling assembly.
In detail, the conditioning reagent tank in this embodiment is provided with an alkaline reagent, and the alkaline reagent can be added into the conditioning tank assembly under the control of the visual control mechanism, so as to neutralize and condition the primary treated water in the conditioning tank assembly.
The precipitation mechanism in this embodiment includes: the sedimentation tank assembly and the sedimentation reagent tank assembly are arranged in the sedimentation tank;
the sedimentation reagent tank assembly is respectively connected with the visual control mechanism and the sedimentation tank assembly; the sedimentation reagent tank assembly can add sedimentation reagent into the sedimentation tank assembly under the control of the visual control mechanism, so that the prepared treated water is subjected to sludge sedimentation treatment, and qualified treated water is obtained.
As shown in fig. 3: the detection assembly described in this embodiment includes: the device comprises an acid-base detection unit, a water quantity detection unit, a water quality detection unit, a reagent quantity detection unit and a visual detection unit; the acid-base detection unit, the water quantity detection unit, the water quality detection unit, the reagent quantity detection unit and the visual detection unit are all connected with the visual control mechanism.
The acid-base detection unit, the water quantity detection unit, the water quality detection unit, the reagent amount detection unit and the visual detection unit can respectively detect the working state data of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism, and can send the detected working state data to the visual control mechanism.
The detection unit provides powerful data support for the operation of the control assembly.
The technical principles of the present invention have been described above in connection with specific embodiments, which are intended to explain the principles of the present invention and should not be construed as limiting the scope of the present invention in any way. Based on the explanations herein, those skilled in the art will be able to conceive of other embodiments of the present invention without inventive efforts, which shall fall within the scope of the present invention.

Claims (10)

1. A visual fenton reaction system, comprising: the device comprises a visual control mechanism, a Fenton reaction mechanism, a feeding mechanism, a conditioning mechanism and a precipitation mechanism;
the visual control mechanism is respectively in control connection with the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism and is used for treating industrial organic wastewater;
the feeding mechanism is connected with the Fenton reaction mechanism and can provide a reaction reagent and wastewater to be treated for the interior of the Fenton reaction mechanism;
the Fenton reaction mechanism is also connected with the conditioning mechanism, and can discharge the primary treated water subjected to the Fenton reaction into the conditioning mechanism so as to condition the pH value of the primary treated water;
the conditioning mechanism is also connected with the precipitation mechanism and can discharge the conditioned treated water into the precipitation mechanism for sludge precipitation treatment so as to obtain qualified treated water.
2. A Fenton reaction system according to claim 1,
the visual control mechanism includes: a control component and a detection component;
the control assembly is arranged in the control chamber and is connected with the detection assembly;
the detection assembly can collect the working state data of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism respectively and send the detected working state data to the control assembly.
3. A Fenton reaction system according to claim 2,
the control assembly includes: a control host and a display device;
the control host is connected with the display equipment;
the control host is also respectively in control connection with the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism, the precipitation mechanism and the detection assembly;
the control host is also connected with a factory power supply and a factory intranet;
the display equipment can display the working state information of the reaction system to workers;
the staff can send out a control instruction through the display equipment according to the displayed working state information;
the control instruction is used for controlling the work of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism, the precipitation mechanism and the detection assembly.
4. A Fenton reaction system according to claim 3,
the Fenton reaction mechanism comprises: a reaction vessel pool and a reagent addition assembly;
the reaction container pool and the reagent adding assembly are both connected with the visual control mechanism;
the reagent adding assembly is connected with the reaction container pool and can add reaction reagents into the reaction container pool under the control of the visual control mechanism;
the reaction container pool is also connected with the feeding mechanism and the conditioning mechanism respectively;
wherein the feeding mechanism can add industrial organic wastewater into the reaction container pool under the control of the visual control mechanism;
the reaction container pool can discharge the primary treatment water after Fenton reaction treatment under the control of the visual control mechanism into the conditioning mechanism to condition the acidity and alkalinity of the primary treatment water.
5. A Fenton reaction system according to claim 4,
the reagent addition assembly comprises: a sulfuric acid reagent tank, a ferrous sulfate reagent tank and a hydrogen peroxide reagent tank;
the sulfuric acid reagent tank, the ferrous sulfate reagent tank and the hydrogen peroxide reagent tank are all connected with the reaction container pool;
the sulfuric acid reagent tank, the ferrous sulfate reagent tank and the hydrogen peroxide reagent tank can orderly add reasonable reagent amount to the reaction container pool under the control of the visual control mechanism so as to complete the primary Fenton treatment of the wastewater.
6. A Fenton reaction system according to claim 5,
the feed mechanism includes: a waste water storage assembly and a waste water pumping assembly;
the wastewater pumping assembly is connected with the visual control mechanism;
the waste water storage assembly is connected with the reaction container pool;
the waste water pumping assembly is arranged on the waste water storage assembly;
the wastewater pumping assembly can pump wastewater in the wastewater storage assembly into the reaction container pool under the control of the visual control mechanism.
7. A Fenton reaction system according to claim 6,
the conditioning mechanism includes: a conditioning tank assembly and a conditioning reagent tank;
the conditioning reagent tank is respectively connected with the visual control mechanism and the conditioning tank assembly;
the reaction container pool is connected with the conditioning tank assembly and can discharge primary treatment water into the conditioning tank assembly;
the conditioning tank assembly is also connected with the settling assembly.
8. A Fenton reaction system according to claim 7,
and an alkaline reagent is arranged in the conditioning reagent tank and can be added into the conditioning tank assembly under the control of the visual control mechanism so as to neutralize and condition the primary treated water in the conditioning tank assembly.
9. A Fenton reaction system according to claim 8,
the precipitation mechanism includes: a sedimentation tank assembly and a sedimentation reagent tank assembly;
the sedimentation reagent tank assembly is respectively connected with the visual control mechanism and the sedimentation tank assembly;
the sedimentation reagent tank assembly can add sedimentation reagent into the sedimentation tank assembly under the control of the visual control mechanism, so that the treated water after conditioning is subjected to sludge sedimentation treatment, and qualified treated water is obtained.
10. A Fenton reaction system according to claim 2,
the detection assembly comprises: the device comprises an acid-base detection unit, a water quantity detection unit, a water quality detection unit, a reagent quantity detection unit and a visual detection unit;
the acid-base detection unit, the water quantity detection unit, the water quality detection unit, the reagent quantity detection unit and the visual detection unit are all connected with the visual control mechanism;
the acid-base detection unit, the water quantity detection unit, the water quality detection unit, the reagent amount detection unit and the visual detection unit can respectively detect the working state data of the Fenton reaction mechanism, the feeding mechanism, the conditioning mechanism and the precipitation mechanism, and can send the detected working state data to the visual control mechanism.
CN202210187850.1A 2022-02-28 2022-02-28 Visual fenton reaction system Pending CN114735840A (en)

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Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN205953724U (en) * 2016-08-26 2017-02-15 南京格洛特环境工程股份有限公司 Fenton reaction recombination reaction ware
US20170044036A1 (en) * 2014-02-19 2017-02-16 Nanjing University Fenton fluidized bed treatment apparatus and wastewater treatment method thereof
CN207276283U (en) * 2017-08-08 2018-04-27 苏州市东方环境工程有限公司 A kind of Fenton oxidation pilot plant of novel integrated
CN108178281A (en) * 2018-02-11 2018-06-19 吉林建筑大学 Handle the Fenton oxidation reactor automaton and method of lignite upgrading waste water
CN211339117U (en) * 2019-12-27 2020-08-25 张燕 High COD difficult degradation effluent treatment plant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20170044036A1 (en) * 2014-02-19 2017-02-16 Nanjing University Fenton fluidized bed treatment apparatus and wastewater treatment method thereof
CN205953724U (en) * 2016-08-26 2017-02-15 南京格洛特环境工程股份有限公司 Fenton reaction recombination reaction ware
CN207276283U (en) * 2017-08-08 2018-04-27 苏州市东方环境工程有限公司 A kind of Fenton oxidation pilot plant of novel integrated
CN108178281A (en) * 2018-02-11 2018-06-19 吉林建筑大学 Handle the Fenton oxidation reactor automaton and method of lignite upgrading waste water
CN211339117U (en) * 2019-12-27 2020-08-25 张燕 High COD difficult degradation effluent treatment plant

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