CN114703671A - Light-weight high-puncture-resistance surfing board material and preparation method thereof - Google Patents

Light-weight high-puncture-resistance surfing board material and preparation method thereof Download PDF

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Publication number
CN114703671A
CN114703671A CN202210185411.7A CN202210185411A CN114703671A CN 114703671 A CN114703671 A CN 114703671A CN 202210185411 A CN202210185411 A CN 202210185411A CN 114703671 A CN114703671 A CN 114703671A
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layer
resin
temperature
polycarbonate
coating
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CN202210185411.7A
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Chinese (zh)
Inventor
林贤州
郑美乾
蔡朋楷
郑华周
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Fujian Enmet New Materials Co ltd
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Fujian Enmet New Materials Co ltd
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Priority to CN202210185411.7A priority Critical patent/CN114703671A/en
Publication of CN114703671A publication Critical patent/CN114703671A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0034Polyamide fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/121Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyesters, polycarbonates, alkyds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00Properties of the materials
    • D06N2209/10Properties of the materials having mechanical properties
    • D06N2209/103Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2213/00Others characteristics
    • D06N2213/03Fibrous web coated on one side with at least two layers of the same polymer type, e.g. two coatings of polyolefin

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Moulding By Coating Moulds (AREA)

Abstract

The invention discloses a light-weight high-puncture-resistance surfboard material and a preparation method thereof, wherein the light-weight high-puncture-resistance surfboard material comprises a space cloth layer, a first paste layer, a second paste layer and a polycarbonate layer are symmetrically and sequentially arranged on two surfaces of the space cloth layer from inside to outside, the space cloth layer is formed by aramid fiber material, the total gram weight is 380-420gsm, and the first paste layer and the second paste layer are formed by PU resin; the polycarbonate layer is made of a basf polycarbonate TPU material. The surfboard material disclosed by the invention realizes light weight of the material, improves the puncture resistance of the material through material structure change, and has good market prospect.

Description

Light-weight high-puncture-resistance surfing board material and preparation method thereof
Technical Field
The invention relates to the field of surfboard materials, in particular to a lightweight high-puncture-resistance surfboard material and a preparation method thereof.
Background
The current surfing board materials have the following disadvantages: (1) the gram weight of the material is over 2200gsm, and the material is heavy, so that a person can hardly bear one surfboard. (2) The common TPU surfing board material has poor puncture resistance fed back by the market.
Disclosure of Invention
The invention aims to provide a light-weight high-puncture-resistance surfing board material and a preparation method thereof, aiming at the defects of the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
a lightweight high puncture-resistant surfboard material comprises a space cloth layer, wherein a first paste layer, a second paste layer and a polycarbonate layer are symmetrically and sequentially arranged on two surfaces of the space cloth layer from inside to outside;
the space cloth layer is formed by aramid fiber materials, 500D materials are used for weaving, the middle wire drawing material is woven by 300D materials, and the total gram weight is 380-420 gsm;
the first paste layer and the second paste layer are both formed by PU resin, the PU resin is provided by Jiangsu Kunshan Gangding, and the brand is CX-6950;
the polycarbonate layer is made of a basf polycarbonate TPU material and specifically comprises the following components in parts by weight: 100 parts of polycarbonate TPU and 3-5 parts of color master batch.
The preparation method of the light-weight high-puncture-resistance surfing board material comprises the following steps:
1) coating PU resin on two surfaces of the space cloth layer in a scraping way, wherein the viscosity of the PU resin is 1.0-1.5wcps, the temperature of a coating machine is 130-160 ℃, the speed of the coating machine is 20-25m/min, and the gram weight of the PU resin coated on each surface is 50 +/-3 gsm, so that first paste layers marked as material A are respectively formed on the two surfaces of the space cloth layer;
2) coating PU resin on two surfaces of the material A in a blade mode, wherein the viscosity of the PU resin is 3.5-4.0wcps, the temperature of a coating machine is 130-160 ℃, the speed of the coating machine is 15-20m/min, and the gram weight of the PU resin coated on each surface is 50 +/-3 gsm, so that second paste layers are respectively formed on the two surfaces of the material A and are marked as material B;
3) casting the polycarbonate TPU onto the two surfaces of the material B by using a casting process on the two surfaces of the material B, wherein the gram weight of the polycarbonate TPU on each surface is 400 +/-10 gsm, the temperature of a feeding section of a casting machine is 140-170 ℃, the temperature of a melting section is 185-195 ℃, the temperature of a homogenizing section is 185-195 ℃, the temperature of an elbow and a mold is 185-195 ℃, the pressure is 5-10mpa, and the speed is 5-8m/min to obtain a material C;
in addition, it should be noted that when the material B enters the casting process, the material B is placed in an oven to activate the second paste layer, the temperature of the oven is 150-;
4) and cutting, blade coating and forming the material C according to the shape of the surfboard to obtain a finished product.
By adopting the technical scheme, the surfboard material is changed in a light weight manner, and the gram weight is below 1500 gsm. The invention has the following advantages:
(1) the basis weight is reduced by 100gsm through switching of the base cloth, the high-strength polyester mesh cloth is generally used in the market, the base cloth is made of 1000D and 3000D materials, the 500D material is used as the middle wire drawing material, the basis weight can be reduced from 500gsm to 450gsm, the used 500D material is made up into 1000D strength through the aramid fiber material through the tissue density, the former 1000D 20 multiplied by 20 tissue is changed into the aramid fiber 500D25 multiplied by 25 material, and the strength of the base cloth is consistent with that of the former 1000D high-strength polyester mesh cloth through the change of the material tissue.
(2) According to the invention, the stripping strength and the air tightness of the material are increased by a secondary blade coating mode, PU resin is fully permeated into the base fabric for the first time to increase the air tightness of the material, and the increase of the thickness of the TPU film is reduced. The second time of scraping the PU resin on the surface of the material by increasing the viscosity of the PU resin ensures the peeling of the material, and simultaneously, the first layer and the second layer are compatible so that the PU resin is fully bonded together to increase the peeling force of the material.
(3) The invention greatly reduces the gram weight of the TPU film and realizes the light weight of the material.
(4) According to the invention, the puncture resistance of the material is improved through changing the material structure, and the puncture resistance is improved through changing polyurethane TPU into polycarbonate TPU.
Detailed Description
Example 1
A lightweight high puncture-resistant surfboard material comprises a space cloth layer, wherein a first paste layer, a second paste layer and a polycarbonate layer are symmetrically and sequentially arranged on two surfaces of the space cloth layer from inside to outside;
the space cloth layer is formed by aramid fiber materials, 500D materials are used for weaving, the middle wire drawing material is woven by 300D materials, and the total gram weight is 400 gsm;
the first paste layer and the second paste layer are both formed by PU resin, the PU resin is provided by Jiangsu Kunshan Gangding, and the brand is CX-6950;
the polycarbonate layer is made of a basf polycarbonate TPU material and specifically comprises the following components in parts by weight: 100 parts of polycarbonate TPU and 4 parts of color master batch.
The preparation method of the light-weight high-puncture-resistance surfing board material comprises the following steps:
1) coating PU resin on two surfaces of the space cloth layer in a blade mode, wherein the viscosity of the PU resin is 1.25wcps, the temperature of a coating machine is 145 ℃, the speed of the coating machine is 20-25m/min, and the gram weight of the PU resin coated on each surface is 50gsm, so that first paste layers marked as material A are formed on the two surfaces of the space cloth layer respectively;
2) coating PU resin on two surfaces of the material A in a knife coating mode, wherein the viscosity of the PU resin is 3.75wcps, the temperature of a coating machine is 145 ℃, the speed of the coating machine is 17.5m/min, and the gram weight of the PU resin coated on each surface is 50gsm, so that second paste layers marked as material B are formed on the two surfaces of the material A respectively;
3) casting polycarbonate TPU on two surfaces of the material B by using a casting process, wherein the gram weight of the polycarbonate TPU on each surface is 400gsm, the temperature of a feeding section of a casting machine is 155 ℃, the temperature of a melting section is 190 ℃, the temperature of a homogenizing section is 190 ℃, the temperature of an elbow and a mould is 190 ℃, the pressure is 7.5 mpa, and the speed is 6.5 m/min to obtain a material C;
in addition, when the material B enters a casting process, the material B is placed in an oven, the second paste layer is activated, the temperature of the oven is 155 ℃, the speed is 6.5 m/min synchronous with that of the casting machine, and the length of the oven is 6 m;
4) and cutting, blade coating and forming the material C according to the shape of the surfboard to obtain a finished product.
Example 2
A lightweight high puncture-resistant surfboard material comprises a space cloth layer, wherein a first paste layer, a second paste layer and a polycarbonate layer are symmetrically and sequentially arranged on two surfaces of the space cloth layer from inside to outside;
the space cloth layer is formed by aramid fiber materials, 500D materials are used for weaving, the middle wire drawing materials are used for weaving 300D materials, and the total gram weight is 380 gsm;
the first paste layer and the second paste layer are both formed by PU resin, the PU resin is provided by Jiangsu Kunshan Gangding, and the brand is CX-6950;
the polycarbonate layer is made of a basf polycarbonate TPU material and specifically comprises the following components in parts by weight: 100 parts of polycarbonate TPU and 3 parts of color master batch.
The preparation method of the light-weight high-puncture-resistance surfing board material comprises the following steps:
1) coating PU resin on two surfaces of the space cloth layer in a blade mode, wherein the viscosity of the PU resin is 1.0wcps, the temperature of a coating machine is 130 ℃, the speed of the coating machine is 20m/min, and the gram weight of the PU resin coated on each surface is 47gsm, so that first paste layers marked as material A are formed on the two surfaces of the space cloth layer respectively;
2) coating PU resin on two surfaces of the material A in a blade mode, wherein the viscosity of the PU resin is 3.5wcps, the temperature of a coating machine is 130 ℃, the speed of the coating machine is 15m/min, and the gram weight of the PU resin coated on each surface is 47gsm, so that second paste layers marked as material B are formed on the two surfaces of the material A respectively;
3) casting polycarbonate TPU on two surfaces of the material B by using a casting process, wherein the gram weight of the polycarbonate TPU on each surface is 390gsm, the temperature of a feeding section of a casting machine is 140 ℃, the temperature of a melting section is 185 ℃, the temperature of a homogenizing section is 185 ℃, the temperature of an elbow and a mould is 185 ℃, the pressure is 5mpa, and the speed is 5m/min to obtain a material C;
in addition, when the material B enters a casting process, the material B is placed in an oven, the second paste layer is activated, the temperature of the oven is 150 ℃, the speed is 5m/min synchronous with that of the casting machine, and the length of the oven is 6 m;
4) and cutting, blade coating and forming the material C according to the shape of the surfboard to obtain a finished product.
Example 3
A lightweight high puncture-resistant surfboard material comprises a space cloth layer, wherein a first paste layer, a second paste layer and a polycarbonate layer are symmetrically and sequentially arranged on two surfaces of the space cloth layer from inside to outside;
the space cloth layer is formed by aramid fiber materials, 500D materials are used for weaving, the middle wire drawing material is woven by 300D materials, and the total gram weight is 420 gsm;
the first paste layer and the second paste layer are both formed by PU resin, the PU resin is provided by Jiangsu Kunshan Gangding, and the brand is CX-6950;
the polycarbonate layer is made of a basf polycarbonate TPU material and specifically comprises the following components in parts by weight: 100 parts of polycarbonate TPU and 5 parts of color master batch.
The preparation method of the light-weight high-puncture-resistance surfing board material comprises the following steps:
1) coating PU resin on two surfaces of the space cloth layer in a blade mode, wherein the viscosity of the PU resin is 1.5wcps, the temperature of a coating machine is 160 ℃, the speed of the coating machine is 25m/min, and the gram weight of the PU resin coated on each surface is 53gsm, so that first paste layers marked as material A are formed on the two surfaces of the space cloth layer respectively;
2) coating PU resin on two surfaces of the material A in a scraping mode, wherein the viscosity of the PU resin is 4.0wcps, the temperature of a coating machine is 160 ℃, the speed of the coating machine is 20m/min, and the gram weight of the PU resin coated on each surface is 53gsm, so that second paste layers marked as material B are formed on the two surfaces of the material A respectively;
3) casting polycarbonate TPU on two surfaces of the material B by using a casting process, wherein the gram weight of the polycarbonate TPU on each surface is 410gsm, the temperature of a feeding section of a casting machine is 170 ℃, the temperature of a melting section is 195 ℃, the temperature of a homogenizing section is 195 ℃, the temperature of an elbow and a mould is 195 ℃, the pressure is 10mpa, and the speed is 8m/min to obtain a material C;
in addition, when the material B enters a casting process, the material B is placed in an oven, the second paste layer is activated, the temperature of the oven is 160 ℃, the speed is 8m/min synchronous with that of the casting machine, and the length of the oven is 6 m;
4) and cutting, blade coating and forming the material C according to the shape of the surfboard to obtain a finished product.

Claims (7)

1. A lightweight high puncture-resistant surfing board material is characterized by comprising a space cloth layer, wherein a first paste layer, a second paste layer and a polycarbonate layer are symmetrically and sequentially arranged on two surfaces of the space cloth layer from inside to outside;
the space cloth layer is formed by aramid fiber materials, and the total gram weight is 380-420 gsm;
the first paste layer and the second paste layer are both formed by PU resin, the PU resin is provided by Jiangsu Kunshan Gangding, and the brand is CX-6950;
the polycarbonate layer is prepared from the following components in parts by weight: 100 parts of polycarbonate TPU and 3-5 parts of color master batch.
2. A lightweight high puncture resistant surfing board material as claimed in claim 1, wherein said aramid material is formed by weaving 500D material and the middle wire-pulling material is woven by 300D material.
3. A method for making a lightweight high puncture resistant surfing board material as claimed in claim 1, comprising the steps of:
1) coating PU resin on two surfaces of the space cloth layer in a scraping mode, wherein the temperature of a coating machine is 130-160 ℃, and the speed of the coating machine is 20-25m/min, so that first paste layers are respectively formed on the two surfaces of the space cloth layer and are marked as material A;
2) coating PU resin on two surfaces of the material A in a scraping way, wherein the temperature of a coating machine is 130-160 ℃, and the speed of the coating machine is 15-20m/min, so that second paste layers are respectively formed on the two surfaces of the material A and are marked as material B;
3) casting the polycarbonate TPU onto the two surfaces of the material B by using a casting process on the two surfaces of the material B, wherein the temperature of a feeding section of the casting machine is 140-170 ℃, the temperature of a melting section of the casting machine is 185-195 ℃, the temperature of a homogenizing section of the casting machine is 185-195 ℃, the temperature of an elbow and a mold of the casting machine is 185-195 ℃, the pressure of the casting machine is 5-10mpa, and the speed of the casting machine is 5-8m/min to obtain a material C;
4) and cutting, blade coating and forming the material C according to the shape of the surfboard to obtain a finished product.
4. A method for preparing a lightweight high puncture-resistant surfing board material as claimed in claim 3, wherein in step 1), the viscosity of the PU resin is 1.0-1.5wcps, and the gram weight of the PU resin coated on each side is 50 ± 3 gsm.
5. A method for preparing a lightweight high puncture-resistant surfing board material as claimed in claim 3, wherein in step 2), the viscosity of the PU resin is 3.5-4.0wcps, and the gram weight of the PU resin coated on each side is 50 ± 3 gsm.
6. A method of making a lightweight high puncture resistant surfing board material as claimed in claim 3 wherein in step 3) the polycarbonate TPU grammage of each side is 400 ± 10 gsm.
7. A method for preparing a lightweight surfboard material with high puncture resistance as claimed in claim 3, wherein in step 3), the material B is placed in an oven at a temperature of 150 ℃ and 160 ℃ at a speed of 5-8m/min in synchronization with the casting machine while the material B is subjected to the casting process, and the second paste layer is activated.
CN202210185411.7A 2022-02-28 2022-02-28 Light-weight high-puncture-resistance surfing board material and preparation method thereof Pending CN114703671A (en)

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CN202210185411.7A CN114703671A (en) 2022-02-28 2022-02-28 Light-weight high-puncture-resistance surfing board material and preparation method thereof

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CN101973153A (en) * 2010-08-27 2011-02-16 上海晋飞复合材料科技有限公司 Composite molding technology
CN102285185A (en) * 2011-05-17 2011-12-21 中纺新材料科技有限公司 High-adhesion airtight TPU (thermoplastic polyurethanes) coated fabric and preparation method thereof
CN103757911A (en) * 2013-12-12 2014-04-30 福建思嘉环保材料科技有限公司 Modified polyester fiber mesh cloth, PVC film structure material, and preparation method of modified polyester fiber mesh cloth and PVC film structure material
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CN104527190A (en) * 2014-12-09 2015-04-22 福州大学 TPU composite material for oil storage bag
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CN107310238A (en) * 2017-06-23 2017-11-03 福建思嘉环保材料科技有限公司 A kind of preparation method of reinforced space netted fabric compound material
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CN110077089A (en) * 2017-06-23 2019-08-02 福建思嘉环保材料科技有限公司 A kind of preparation method of wear-resisting plain weave type wire drawing screen cloth composite material
CN110561865A (en) * 2019-10-10 2019-12-13 福建恩迈特新材料有限公司 inflatable surfboard composite material and preparation method thereof
CN110667223A (en) * 2019-10-10 2020-01-10 福建恩迈特新材料有限公司 Flame-retardant environment-friendly TPU composite material for automobile leather and preparation method thereof
CN110682639A (en) * 2019-10-10 2020-01-14 福建恩迈特新材料有限公司 Environment-friendly inflatable surfboard composite material and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101973153A (en) * 2010-08-27 2011-02-16 上海晋飞复合材料科技有限公司 Composite molding technology
CN102285185A (en) * 2011-05-17 2011-12-21 中纺新材料科技有限公司 High-adhesion airtight TPU (thermoplastic polyurethanes) coated fabric and preparation method thereof
CN103757911A (en) * 2013-12-12 2014-04-30 福建思嘉环保材料科技有限公司 Modified polyester fiber mesh cloth, PVC film structure material, and preparation method of modified polyester fiber mesh cloth and PVC film structure material
CN104108211A (en) * 2014-06-30 2014-10-22 铱格斯曼航空科技集团有限公司 Light-weight high-strength pneumatic membrane material and preparation method thereof
CN104527190A (en) * 2014-12-09 2015-04-22 福州大学 TPU composite material for oil storage bag
CN106218043A (en) * 2016-07-20 2016-12-14 奉化市天盾防水材料有限公司 Surfboard canvas and preparation method thereof
CN107310238A (en) * 2017-06-23 2017-11-03 福建思嘉环保材料科技有限公司 A kind of preparation method of reinforced space netted fabric compound material
CN110077089A (en) * 2017-06-23 2019-08-02 福建思嘉环保材料科技有限公司 A kind of preparation method of wear-resisting plain weave type wire drawing screen cloth composite material
CN108790333A (en) * 2018-05-10 2018-11-13 浙江蒙泰特种材料科技有限公司 A kind of the tencel composite material and its production method of high-peeling strength
CN109130256A (en) * 2018-07-20 2019-01-04 福建思嘉环保材料科技有限公司 A kind of preparation method of compound wear-resisting space cloth
CN110561865A (en) * 2019-10-10 2019-12-13 福建恩迈特新材料有限公司 inflatable surfboard composite material and preparation method thereof
CN110667223A (en) * 2019-10-10 2020-01-10 福建恩迈特新材料有限公司 Flame-retardant environment-friendly TPU composite material for automobile leather and preparation method thereof
CN110682639A (en) * 2019-10-10 2020-01-14 福建恩迈特新材料有限公司 Environment-friendly inflatable surfboard composite material and preparation method thereof

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