CN114657806A - Thickened insulating cardboard and production method thereof - Google Patents
Thickened insulating cardboard and production method thereof Download PDFInfo
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- CN114657806A CN114657806A CN202011540362.1A CN202011540362A CN114657806A CN 114657806 A CN114657806 A CN 114657806A CN 202011540362 A CN202011540362 A CN 202011540362A CN 114657806 A CN114657806 A CN 114657806A
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- pulper
- insulating paperboard
- pulp
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 18
- 239000011111 cardboard Substances 0.000 title description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 128
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000011087 paperboard Substances 0.000 claims abstract description 29
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical compound OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 235000013808 oxidized starch Nutrition 0.000 claims abstract description 24
- 239000001254 oxidized starch Substances 0.000 claims abstract description 24
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 claims abstract description 24
- 239000011122 softwood Substances 0.000 claims abstract description 24
- 235000019818 tetrasodium diphosphate Nutrition 0.000 claims abstract description 24
- 229920001577 copolymer Polymers 0.000 claims abstract description 23
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 18
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 18
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 18
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 17
- 238000000576 coating method Methods 0.000 claims description 48
- 239000011248 coating agent Substances 0.000 claims description 46
- 239000000123 paper Substances 0.000 claims description 42
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 32
- 239000004917 carbon fiber Substances 0.000 claims description 32
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 32
- 239000003365 glass fiber Substances 0.000 claims description 30
- 239000008213 purified water Substances 0.000 claims description 29
- 238000001223 reverse osmosis Methods 0.000 claims description 22
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 21
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 21
- 239000002994 raw material Substances 0.000 claims description 18
- 239000004744 fabric Substances 0.000 claims description 17
- 239000000835 fiber Substances 0.000 claims description 15
- 239000012535 impurity Substances 0.000 claims description 15
- 239000012528 membrane Substances 0.000 claims description 15
- 238000010009 beating Methods 0.000 claims description 14
- 150000003839 salts Chemical class 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 238000001914 filtration Methods 0.000 claims description 13
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 10
- 238000004537 pulping Methods 0.000 claims description 8
- 241000894006 Bacteria Species 0.000 claims description 7
- 241000700605 Viruses Species 0.000 claims description 7
- 238000005188 flotation Methods 0.000 claims description 7
- 235000019256 formaldehyde Nutrition 0.000 claims description 7
- 238000007731 hot pressing Methods 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 239000002366 mineral element Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000011265 semifinished product Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 4
- 230000003014 reinforcing effect Effects 0.000 claims 5
- 239000012466 permeate Substances 0.000 claims 2
- 239000011152 fibreglass Substances 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 238000005303 weighing Methods 0.000 claims 1
- 239000002655 kraft paper Substances 0.000 abstract description 16
- 239000011229 interlayer Substances 0.000 abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 3
- 238000005336 cracking Methods 0.000 abstract description 3
- -1 ethylhexyl ester Chemical class 0.000 abstract description 2
- 230000007774 longterm Effects 0.000 abstract description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 6
- 238000000227 grinding Methods 0.000 description 6
- 239000007921 spray Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000008719 thickening Effects 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 229920001131 Pulp (paper) Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H11/00—Pulp or paper, comprising cellulose or lignocellulose fibres of natural origin only
- D21H11/02—Chemical or chemomechanical or chemothermomechanical pulp
- D21H11/04—Kraft or sulfate pulp
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21B—FIBROUS RAW MATERIALS OR THEIR MECHANICAL TREATMENT
- D21B1/00—Fibrous raw materials or their mechanical treatment
- D21B1/04—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres
- D21B1/12—Fibrous raw materials or their mechanical treatment by dividing raw materials into small particles, e.g. fibres by wet methods, by the use of steam
- D21B1/30—Defibrating by other means
- D21B1/34—Kneading or mixing; Pulpers
- D21B1/345—Pulpers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21F—PAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
- D21F5/00—Dryer section of machines for making continuous webs of paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/03—Non-macromolecular organic compounds
- D21H17/05—Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
- D21H17/06—Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
- D21H17/24—Polysaccharides
- D21H17/28—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/36—Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/55—Polyamides; Polyaminoamides; Polyester-amides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
- D21H25/04—Physical treatment, e.g. heating, irradiating
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
本发明属于纸板生产领域,尤其是一种加厚绝缘纸板及其生产方法,针对现有绝缘纸板的层间结合力较弱,且抗张强度较低,使用时的防水防火性能较差的问题,现提出如下方案,其中加厚绝缘纸板包括未漂硫酸盐针叶木浆50‑70份,水20‑30份,聚乙二醇0.1‑0.6份,聚丙烯酰胺1‑5份,丙烯酸‑2‑乙基己脂与苯乙烯的共聚物1‑6份,氧化淀粉1‑10份,焦磷酸四钠1‑3份,甲醛0.1‑0.5份,对硝基酚0.3‑0.6份,防水薄膜1‑5份。本发明的加厚绝缘纸板的层间结合力较腔,且抗张强度较高,导电率较低,使用时的防水防火性能较好,长时间使用也可避免发生开裂,使用寿命更长。The invention belongs to the field of paperboard production, in particular to a thickened insulating paperboard and a production method thereof, aiming at the problems that the existing insulating paperboard has weak interlayer bonding force, low tensile strength and poor waterproof and fireproof performance during use. , the following scheme is now proposed, wherein the thickened insulating paperboard includes 50-70 parts of unbleached kraft softwood pulp, 20-30 parts of water, 0.1-0.6 parts of polyethylene glycol, 1-5 parts of polyacrylamide, acrylic acid-2 parts ‑1‑6 parts of copolymer of ethylhexyl ester and styrene, 1‑10 parts of oxidized starch, 1‑3 parts of tetrasodium pyrophosphate, 0.1‑0.5 parts of formaldehyde, 0.3‑0.6 parts of p-nitrophenol, 1 part of waterproof film ‑5 servings. The thickened insulating paperboard of the present invention has stronger interlayer bonding force, higher tensile strength, lower electrical conductivity, better waterproof and fireproof performance in use, and can avoid cracking during long-term use, and has a longer service life.
Description
技术领域technical field
本发明涉及纸板生产技术领域,尤其涉及一种加厚绝缘纸板及其生产方法。The invention relates to the technical field of paperboard production, in particular to a thickened insulating paperboard and a production method thereof.
背景技术Background technique
电气工业绝缘用纸板的总称,空气绝缘纸板还须有较高的紧度和耐电压强度,用未漂硫酸盐木浆为原料,经粘状打浆制成,用于电动机,电力仪表等中,通常有空气绝缘纸板和油绝缘纸板等,绝缘纸板又分为平板和卷筒纸板两种,厚度大于0.5mm的为平板纸板,厚度为0.5mm及以下者为卷筒纸板,绝缘纸板的原料是未漂硫酸盐木浆和棉浆,将两种原料分别打浆,生产必须使用净化水,管道,浆泵要清污,洗净,不得混有含导电成分的杂质,采用专门的绝缘纸板机进行抄造;The general term for insulating cardboard in the electrical industry. Air insulating cardboard must also have high tightness and withstand voltage strength. It is made of unbleached kraft wood pulp as raw material and is made by viscous beating. It is used in motors, power meters, etc. Usually there are air-insulated cardboard and oil-insulated cardboard, etc. Insulating cardboard is divided into two types: flat cardboard and reel cardboard. The thickness of more than 0.5mm is flat cardboard, and the thickness of 0.5mm and below is reel cardboard. The raw material of insulating cardboard is Unbleached kraft wood pulp and cotton pulp are pulped separately. Purified water must be used for production. The pipes and pulp pumps must be cleaned and washed, and impurities containing conductive components must not be mixed. copy;
然而现有的绝缘纸板的层间结合力较弱,且抗张强度较低,使用时的防水防火性能较差。However, the interlayer bonding force of the existing insulating paperboard is weak, the tensile strength is low, and the waterproof and fireproof performance during use is poor.
发明内容SUMMARY OF THE INVENTION
本发明的目的是为了解决现有技术中存在的缺点,而提出的一种加厚绝缘纸板及其生产方法。The purpose of the present invention is to propose a thickened insulating paperboard and a production method thereof in order to solve the shortcomings existing in the prior art.
为了实现上述目的,本发明采用了如下技术方案:In order to achieve the above object, the present invention adopts the following technical solutions:
一种加厚绝缘纸板,包括以下重量份的原料:未漂硫酸盐针叶木浆50-70份,水20-30份,聚乙二醇0.1-0.6份,聚丙烯酰胺1-5份,丙烯酸-2-乙基己脂与苯乙烯的共聚物1-6份,氧化淀粉1-10份,焦磷酸四钠1-3份,甲醛0.1-0.5份,对硝基酚0.3-0.6份,防水薄膜1-5份,玻璃纤维网格布1-5份,防火泥1-5份,网格状碳纤维加强筋板1-5份,防火涂层1-5份和UV耐磨涂层1-5份。A thickened insulating paperboard, comprising the following raw materials by weight: 50-70 parts of unbleached sulfate softwood pulp, 20-30 parts of water, 0.1-0.6 parts of polyethylene glycol, 1-5 parts of polyacrylamide, and acrylic acid -1-6 parts of copolymer of 2-ethylhexyl ester and styrene, 1-10 parts of oxidized starch, 1-3 parts of tetrasodium pyrophosphate, 0.1-0.5 parts of formaldehyde, 0.3-0.6 parts of p-nitrophenol, waterproof 1-5 parts of film, 1-5 parts of glass fiber mesh, 1-5 parts of fireproof mud, 1-5 parts of grid carbon fiber reinforced plate, 1-5 parts of fireproof coating and 1-5 parts of UV wear-resistant coating 5 servings.
优选的,包括以下重量份的原料:未漂硫酸盐针叶木浆50份,水20份,聚乙二醇0.1份,聚丙烯酰胺1份,丙烯酸-2-乙基己脂与苯乙烯的共聚物1份,氧化淀粉1份,焦磷酸四钠1份,甲醛0.1份,对硝基酚0.3份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份。Preferably, it includes the following raw materials by weight: 50 parts of unbleached kraft softwood pulp, 20 parts of water, 0.1 part of polyethylene glycol, 1 part of polyacrylamide, copolymerization of 2-ethylhexyl acrylate and styrene 1 part of carbon fiber, 1 part of oxidized starch, 1 part of tetrasodium pyrophosphate, 0.1 part of formaldehyde, 0.3 part of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, mesh carbon fiber reinforcement 1 part of ribs, 1 part of fireproof coating and 1 part of UV wear-resistant coating.
本发明还提出了一种加厚绝缘纸板的生产方法,包括以下步骤:The present invention also proposes a method for producing thickened insulating cardboard, comprising the following steps:
S1:按以下重量份依次称取原材料:未漂硫酸盐针叶木浆50-70份,水20-30份,聚乙二醇0.1-0.6份,聚丙烯酰胺1-5份,丙烯酸-2-乙基己脂与苯乙烯的共聚物1-6份,氧化淀粉1-10份,焦磷酸四钠1-3份,甲醛0.1-0.5份,对硝基酚0.3-0.6份,防水薄膜1-5份,玻璃纤维网格布1-5份,防火泥1-5份,网格状碳纤维加强筋板1-5份,防火涂层1-5份和UV耐磨涂层1-5份;S1: Weigh the raw materials in order by the following parts by weight: 50-70 parts of unbleached kraft softwood pulp, 20-30 parts of water, 0.1-0.6 parts of polyethylene glycol, 1-5 parts of polyacrylamide, acrylic acid-2- 1-6 parts of copolymer of ethylhexyl ester and styrene, 1-10 parts of oxidized starch, 1-3 parts of tetrasodium pyrophosphate, 0.1-0.5 parts of formaldehyde, 0.3-0.6 parts of p-nitrophenol, waterproof film 1- 5 parts, 1-5 parts of glass fiber mesh cloth, 1-5 parts of fireproof mud, 1-5 parts of grid carbon fiber reinforced plate, 1-5 parts of fireproof coating and 1-5 parts of UV wear-resistant coating;
S2:将S1所述的水送入滤箱内进行初次过滤,将水中的大颗粒杂质进行过滤,随后将初滤后的水输送进软化水设备中进行软化,软化后的水再送入反渗透和净水机中,使水分子和离子态的矿物质元素通过反渗透膜,而溶解在水中的绝大部分无机盐,有机物以及细菌,病毒等无法透过反渗透膜,从而使渗透过的纯净水和无法渗透过的浓缩水严格的分开,得到净化水,净化后的水可降低含盐量,有效去除水中的多种杂质,降低水中导电离子,从而降低了导电率,也提升了出水电阻率;S2: The water described in S1 is sent into the filter box for primary filtration, and the large-particle impurities in the water are filtered, and then the water after the primary filtration is sent to the softening water equipment for softening, and the softened water is sent to reverse osmosis. And in the water purifier, water molecules and ionic mineral elements pass through the reverse osmosis membrane, and most of the inorganic salts, organic substances, bacteria, viruses, etc. dissolved in the water cannot pass through the reverse osmosis membrane, so that the permeated Purified water and impermeable concentrated water are strictly separated to obtain purified water. The purified water can reduce the salt content, effectively remove various impurities in the water, and reduce the conductive ions in the water, thereby reducing the conductivity and improving the effluent. resistivity;
S3:将S1所述的未漂硫酸盐针叶木浆送入碎浆机中进行打碎,得到碎浆料,再将碎浆料送入打浆机中进行打浆,同时将聚乙二醇,聚丙烯酰胺,丙烯酸-2-乙基己脂与苯乙烯的共聚物,氧化淀粉,焦磷酸四钠,甲醛和对硝基酚同时放入打浆机内进行搅拌,再将S2所述的净化水加入打浆机内一同搅拌,随后将打浆后的浆料送入抄纸机中进行加工成半成品,在抄纸机加工过程中使用气浮机对细小纤维进行回收,并送入碎浆机中继续加工,得到湿纸,可增加浆料中的细小纤维含量,可对绝缘纸板的强度起到提升,还可提高湿纸页的强度;S3: The unbleached kraft softwood pulp described in S1 is sent to a pulper for crushing to obtain crushed pulp, and then the crushed pulp is sent to a pulper for beating. Acrylamide, the copolymer of acrylic acid-2-ethylhexyl and styrene, oxidized starch, tetrasodium pyrophosphate, formaldehyde and p-nitrophenol are put into the beater at the same time for stirring, and then the purified water described in S2 is added Stir together in the beater, and then send the beaten pulp to the paper machine for processing into semi-finished products. During the processing of the paper machine, the air flotation machine is used to recover the fine fibers, and then sent to the pulper for further processing. , to obtain wet paper, which can increase the content of fine fibers in the pulp, which can improve the strength of insulating cardboard and improve the strength of wet paper sheets;
S4:将S3所述的湿纸送入输送机内进行输送,输送机将湿纸送入热压机中进行热压,即可得到绝缘纸板;S4: The wet paper described in S3 is sent into the conveyor for conveying, and the conveyor sends the wet paper into the hot press for hot pressing to obtain insulating cardboard;
S5:将S4所述的绝缘纸板送入加工台,并将绝缘纸板的两侧分别粘贴连接防水薄膜,在两个防水薄膜上再粘贴连接玻璃纤维网格布,在两个玻璃纤维网格布上再涂抹防火泥,在两个防火泥表面再安装网格状碳纤维加强筋板,最后再将两个网格状碳纤维加强筋板的表面喷涂防火涂层和UV耐磨涂层,得到加厚绝缘纸板。S5: The insulating cardboard described in S4 is sent to the processing table, and the two sides of the insulating cardboard are respectively pasted and connected to the waterproof film, and the glass fiber mesh cloth is pasted and connected on the two waterproof films. Apply fireproof mud on top, install grid-like carbon fiber reinforced rib plates on the surface of the two fire-proof mud, and finally spray the surface of the two grid-like carbon fiber reinforced rib plates with fireproof coating and UV wear-resistant coating to obtain a thickening. Insulating cardboard.
优选的,所述S3中,碎浆机的碎浆时间为30-40分钟,碎浆机内的粉碎转速为8000-12000r/min。Preferably, in S3, the pulping time of the pulper is 30-40 minutes, and the crushing speed in the pulper is 8000-12000 r/min.
优选的,所述S3中,打浆机的打浆时间为40-60分钟,碎浆机内的粉碎转速为4000-6000r/min。Preferably, in the S3, the beating time of the pulper is 40-60 minutes, and the grinding speed in the pulper is 4000-6000 r/min.
优选的,所述S4中,热压机的工作温度为130℃-180℃,压力为0.2-0.9MPa。Preferably, in the S4, the working temperature of the hot press is 130°C-180°C, and the pressure is 0.2-0.9 MPa.
优选的,所述S5中,防水薄膜的厚度为0.3-0.6mm,玻璃纤维网格布的厚度为1.5-2.5mm。Preferably, in the S5, the thickness of the waterproof film is 0.3-0.6 mm, and the thickness of the glass fiber mesh is 1.5-2.5 mm.
与现有技术相比,本发明的有益效果在于:Compared with the prior art, the beneficial effects of the present invention are:
本发明的加厚绝缘纸板的层间结合力较强,且抗张强度较高,导电率较低,使用时的防水防火性能较好,长时间使用也可避免发生开裂,使用寿命更长。The thickened insulating paperboard of the present invention has strong interlayer bonding force, high tensile strength, low electrical conductivity, good waterproof and fireproof performance during use, and can avoid cracking during long-term use, and has a longer service life.
具体实施方式Detailed ways
下面将对本发明实施例中的技术方案进行清楚,完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。The technical solutions in the embodiments of the present invention will be clearly and completely described below. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments.
实施例一Example 1
一种加厚绝缘纸板,包括以下重量份的原料:未漂硫酸盐针叶木浆50份,水20份,聚乙二醇0.1份,聚丙烯酰胺1份,丙烯酸-2-乙基己脂与苯乙烯的共聚物1份,氧化淀粉1份,焦磷酸四钠1份,甲醛0.1份,对硝基酚0.3份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份。A thickened insulating paperboard, comprising the following raw materials by weight: 50 parts of unbleached sulfate softwood pulp, 20 parts of water, 0.1 part of polyethylene glycol, 1 part of polyacrylamide, 2-ethylhexyl acrylate and 1 part of styrene copolymer, 1 part of oxidized starch, 1 part of tetrasodium pyrophosphate, 0.1 part of formaldehyde, 0.3 part of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, net 1 part of lattice carbon fiber reinforced plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating.
本实施例还提出了一种加厚绝缘纸板的生产方法,包括以下步骤:The present embodiment also proposes a method for producing thickened insulating cardboard, comprising the following steps:
S1:按以下重量份依次称取原材料:未漂硫酸盐针叶木浆50份,水20份,聚乙二醇0.1份,聚丙烯酰胺1份,丙烯酸-2-乙基己脂与苯乙烯的共聚物1份,氧化淀粉1份,焦磷酸四钠1份,甲醛0.1份,对硝基酚0.3份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份;S1: Weigh the raw materials in order by the following parts by weight: 50 parts of unbleached kraft softwood pulp, 20 parts of water, 0.1 part of polyethylene glycol, 1 part of polyacrylamide, a mixture of 2-ethylhexyl acrylate and styrene 1 part of copolymer, 1 part of oxidized starch, 1 part of tetrasodium pyrophosphate, 0.1 part of formaldehyde, 0.3 part of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, mesh carbon fiber 1 part of rib plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating;
S2:将S1所述的水送入滤箱内进行初次过滤,将水中的大颗粒杂质进行过滤,随后将初滤后的水输送进软化水设备中进行软化,软化后的水再送入反渗透和净水机中,使水分子和离子态的矿物质元素通过反渗透膜,而溶解在水中的绝大部分无机盐,有机物以及细菌,病毒等无法透过反渗透膜,从而使渗透过的纯净水和无法渗透过的浓缩水严格的分开,得到净化水,净化后的水可降低含盐量,有效去除水中的多种杂质,降低水中导电离子,从而降低了导电率,也提升了出水电阻率;S2: The water described in S1 is sent into the filter box for primary filtration, and the large-particle impurities in the water are filtered, and then the water after the primary filtration is sent to the softening water equipment for softening, and the softened water is sent to reverse osmosis. And in the water purifier, water molecules and ionic mineral elements pass through the reverse osmosis membrane, and most of the inorganic salts, organic substances, bacteria, viruses, etc. dissolved in the water cannot pass through the reverse osmosis membrane, so that the permeated Purified water and impermeable concentrated water are strictly separated to obtain purified water. The purified water can reduce the salt content, effectively remove various impurities in the water, and reduce the conductive ions in the water, thereby reducing the conductivity and improving the effluent. resistivity;
S3:将S1所述的未漂硫酸盐针叶木浆送入碎浆机中进行打碎,得到碎浆料,再将碎浆料送入打浆机中进行打浆,同时将聚乙二醇,聚丙烯酰胺,丙烯酸-2-乙基己脂与苯乙烯的共聚物,氧化淀粉,焦磷酸四钠,甲醛和对硝基酚同时放入打浆机内进行搅拌,再将S2所述的净化水加入打浆机内一同搅拌,随后将打浆后的浆料送入抄纸机中进行加工成半成品,在抄纸机加工过程中使用气浮机对细小纤维进行回收,并送入碎浆机中继续加工,得到湿纸,可增加浆料中的细小纤维含量,可对绝缘纸板的强度起到提升,还可提高湿纸页的强度;S3: The unbleached kraft softwood pulp described in S1 is sent to a pulper for crushing to obtain crushed pulp, and then the crushed pulp is sent to a pulper for beating. Acrylamide, the copolymer of acrylic acid-2-ethylhexyl and styrene, oxidized starch, tetrasodium pyrophosphate, formaldehyde and p-nitrophenol are put into the beater at the same time for stirring, and then the purified water described in S2 is added Stir together in the beater, and then send the beaten pulp to the paper machine for processing into semi-finished products. During the processing of the paper machine, the air flotation machine is used to recover the fine fibers, and then sent to the pulper for further processing. , to obtain wet paper, which can increase the content of fine fibers in the pulp, which can improve the strength of insulating cardboard and improve the strength of wet paper sheets;
S4:将S3所述的湿纸送入输送机内进行输送,输送机将湿纸送入热压机中进行热压,即可得到绝缘纸板;S4: The wet paper described in S3 is sent into the conveyor for conveying, and the conveyor sends the wet paper into the hot press for hot pressing to obtain insulating cardboard;
S5:将S4所述的绝缘纸板送入加工台,并将绝缘纸板的两侧分别粘贴连接防水薄膜,在两个防水薄膜上再粘贴连接玻璃纤维网格布,在两个玻璃纤维网格布上再涂抹防火泥,在两个防火泥表面再安装网格状碳纤维加强筋板,最后再将两个网格状碳纤维加强筋板的表面喷涂防火涂层和UV耐磨涂层,得到加厚绝缘纸板。S5: The insulating cardboard described in S4 is sent to the processing table, and the two sides of the insulating cardboard are respectively pasted and connected to the waterproof film, and the glass fiber mesh cloth is pasted and connected on the two waterproof films. Apply fireproof mud on top, install grid-like carbon fiber reinforced rib plates on the surface of the two fire-proof mud, and finally spray the surface of the two grid-like carbon fiber reinforced rib plates with fireproof coating and UV wear-resistant coating to obtain a thickening. Insulating cardboard.
本实施例中,所述S3中,碎浆机的碎浆时间为30-40分钟,碎浆机内的粉碎转速为8000-12000r/min。In this embodiment, in S3, the pulping time of the pulper is 30-40 minutes, and the crushing speed in the pulper is 8000-12000 r/min.
本实施例中,所述S3中,打浆机的打浆时间为40-60分钟,碎浆机内的粉碎转速为4000-6000r/min。In this embodiment, in S3, the beating time of the pulper is 40-60 minutes, and the grinding speed in the pulper is 4000-6000 r/min.
本实施例中,所述S4中,热压机的工作温度为130℃-180℃,压力为0.2-0.9MPa。In this embodiment, in S4, the working temperature of the hot press is 130°C-180°C, and the pressure is 0.2-0.9MPa.
本实施例中,所述S5中,防水薄膜的厚度为0.3-0.6mm,玻璃纤维网格布的厚度为1.5-2.5mm。In this embodiment, in S5, the thickness of the waterproof film is 0.3-0.6 mm, and the thickness of the glass fiber mesh cloth is 1.5-2.5 mm.
表一生产用水净化前后数据Table 1 Data before and after purification of production water
实施例二Embodiment 2
一种加厚绝缘纸板,包括以下重量份的原料:未漂硫酸盐针叶木浆55份,水25份,聚乙二醇0.2份,聚丙烯酰胺2份,丙烯酸-2-乙基己脂与苯乙烯的共聚物2份,氧化淀粉2份,焦磷酸四钠2份,甲醛0.2份,对硝基酚0.5份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份。A thickened insulating paperboard, comprising the following raw materials by weight: 55 parts of unbleached sulfate softwood pulp, 25 parts of water, 0.2 parts of polyethylene glycol, 2 parts of polyacrylamide, acrylic acid-2-ethylhexyl resin and 2 parts of styrene copolymer, 2 parts of oxidized starch, 2 parts of tetrasodium pyrophosphate, 0.2 parts of formaldehyde, 0.5 parts of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, net 1 part of lattice carbon fiber reinforced plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating.
本实施例还提出了一种加厚绝缘纸板的生产方法,包括以下步骤:The present embodiment also proposes a method for producing thickened insulating cardboard, comprising the following steps:
S1:按以下重量份依次称取原材料:未漂硫酸盐针叶木浆55份,水25份,聚乙二醇0.2份,聚丙烯酰胺2份,丙烯酸-2-乙基己脂与苯乙烯的共聚物2份,氧化淀粉2份,焦磷酸四钠2份,甲醛0.2份,对硝基酚0.5份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份;S1: Weigh the raw materials in order by the following parts by weight: 55 parts of unbleached kraft softwood pulp, 25 parts of water, 0.2 parts of polyethylene glycol, 2 parts of polyacrylamide, a mixture of 2-ethylhexyl acrylate and styrene 2 parts of copolymer, 2 parts of oxidized starch, 2 parts of tetrasodium pyrophosphate, 0.2 parts of formaldehyde, 0.5 parts of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, mesh carbon fiber 1 part of rib plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating;
S2:将S1所述的水送入滤箱内进行初次过滤,将水中的大颗粒杂质进行过滤,随后将初滤后的水输送进软化水设备中进行软化,软化后的水再送入反渗透和净水机中,使水分子和离子态的矿物质元素通过反渗透膜,而溶解在水中的绝大部分无机盐,有机物以及细菌,病毒等无法透过反渗透膜,从而使渗透过的纯净水和无法渗透过的浓缩水严格的分开,得到净化水,净化后的水可降低含盐量,有效去除水中的多种杂质,降低水中导电离子,从而降低了导电率,也提升了出水电阻率;S2: The water described in S1 is sent into the filter box for primary filtration, and the large-particle impurities in the water are filtered, and then the water after the primary filtration is sent to the softening water equipment for softening, and the softened water is sent to reverse osmosis. And in the water purifier, water molecules and ionic mineral elements pass through the reverse osmosis membrane, and most of the inorganic salts, organic substances, bacteria, viruses, etc. dissolved in the water cannot pass through the reverse osmosis membrane, so that the permeated Purified water and impermeable concentrated water are strictly separated to obtain purified water. The purified water can reduce the salt content, effectively remove various impurities in the water, and reduce the conductive ions in the water, thereby reducing the conductivity and improving the effluent. resistivity;
S3:将S1所述的未漂硫酸盐针叶木浆送入碎浆机中进行打碎,得到碎浆料,再将碎浆料送入打浆机中进行打浆,同时将聚乙二醇,聚丙烯酰胺,丙烯酸-2-乙基己脂与苯乙烯的共聚物,氧化淀粉,焦磷酸四钠,甲醛和对硝基酚同时放入打浆机内进行搅拌,再将S2所述的净化水加入打浆机内一同搅拌,随后将打浆后的浆料送入抄纸机中进行加工成半成品,在抄纸机加工过程中使用气浮机对细小纤维进行回收,并送入碎浆机中继续加工,得到湿纸,可增加浆料中的细小纤维含量,可对绝缘纸板的强度起到提升,还可提高湿纸页的强度;S3: The unbleached kraft softwood pulp described in S1 is sent to a pulper for crushing to obtain crushed pulp, and then the crushed pulp is sent to a pulper for beating. Acrylamide, the copolymer of acrylic acid-2-ethylhexyl and styrene, oxidized starch, tetrasodium pyrophosphate, formaldehyde and p-nitrophenol are put into the beater at the same time for stirring, and then the purified water described in S2 is added Stir together in the beater, and then send the beaten pulp to the paper machine for processing into semi-finished products. During the processing of the paper machine, the air flotation machine is used to recover the fine fibers, and then sent to the pulper for further processing. , to obtain wet paper, which can increase the content of fine fibers in the pulp, which can improve the strength of insulating cardboard and improve the strength of wet paper sheets;
S4:将S3所述的湿纸送入输送机内进行输送,输送机将湿纸送入热压机中进行热压,即可得到绝缘纸板;S4: The wet paper described in S3 is sent into the conveyor for conveying, and the conveyor sends the wet paper into the hot press for hot pressing to obtain insulating cardboard;
S5:将S4所述的绝缘纸板送入加工台,并将绝缘纸板的两侧分别粘贴连接防水薄膜,在两个防水薄膜上再粘贴连接玻璃纤维网格布,在两个玻璃纤维网格布上再涂抹防火泥,在两个防火泥表面再安装网格状碳纤维加强筋板,最后再将两个网格状碳纤维加强筋板的表面喷涂防火涂层和UV耐磨涂层,得到加厚绝缘纸板。S5: The insulating cardboard described in S4 is sent to the processing table, and the two sides of the insulating cardboard are respectively pasted and connected to the waterproof film, and the glass fiber mesh cloth is pasted and connected on the two waterproof films. Apply fireproof mud on top, install grid-like carbon fiber reinforced rib plates on the surface of the two fire-proof mud, and finally spray the surface of the two grid-like carbon fiber reinforced rib plates with fireproof coating and UV wear-resistant coating to obtain a thickening. Insulating cardboard.
本实施例中,所述S3中,碎浆机的碎浆时间为30-40分钟,碎浆机内的粉碎转速为8000-12000r/min。In this embodiment, in S3, the pulping time of the pulper is 30-40 minutes, and the crushing speed in the pulper is 8000-12000 r/min.
本实施例中,所述S3中,打浆机的打浆时间为40-60分钟,碎浆机内的粉碎转速为4000-6000r/min。In this embodiment, in S3, the beating time of the pulper is 40-60 minutes, and the grinding speed in the pulper is 4000-6000 r/min.
本实施例中,所述S4中,热压机的工作温度为130℃-180℃,压力为0.2-0.9MPa。In this embodiment, in S4, the working temperature of the hot press is 130°C-180°C, and the pressure is 0.2-0.9MPa.
本实施例中,所述S5中,防水薄膜的厚度为0.3-0.6mm,玻璃纤维网格布的厚度为1.5-2.5mm。In this embodiment, in S5, the thickness of the waterproof film is 0.3-0.6 mm, and the thickness of the glass fiber mesh cloth is 1.5-2.5 mm.
实施例三Embodiment 3
一种加厚绝缘纸板,包括以下重量份的原料:未漂硫酸盐针叶木浆60份,水25份,聚乙二醇0.2份,聚丙烯酰胺3份,丙烯酸-2-乙基己脂与苯乙烯的共聚物3份,氧化淀粉3份,焦磷酸四钠3份,甲醛0.2份,对硝基酚0.2份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份。A thickened insulating paperboard, comprising the following raw materials by weight: 60 parts of unbleached sulfate softwood pulp, 25 parts of water, 0.2 parts of polyethylene glycol, 3 parts of polyacrylamide, acrylic acid-2-ethylhexyl resin and 3 parts of styrene copolymer, 3 parts of oxidized starch, 3 parts of tetrasodium pyrophosphate, 0.2 parts of formaldehyde, 0.2 parts of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, net 1 part of lattice carbon fiber reinforced plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating.
本实施例还提出了一种加厚绝缘纸板的生产方法,包括以下步骤:The present embodiment also proposes a method for producing thickened insulating cardboard, comprising the following steps:
S1:按以下重量份依次称取原材料:未漂硫酸盐针叶木浆60份,水25份,聚乙二醇0.2份,聚丙烯酰胺3份,丙烯酸-2-乙基己脂与苯乙烯的共聚物3份,氧化淀粉3份,焦磷酸四钠3份,甲醛0.2份,对硝基酚0.2份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份;S1: Weigh the raw materials in sequence according to the following parts by weight: 60 parts of unbleached kraft softwood pulp, 25 parts of water, 0.2 part of polyethylene glycol, 3 parts of polyacrylamide, a mixture of 2-ethylhexyl acrylate and styrene 3 parts of copolymer, 3 parts of oxidized starch, 3 parts of tetrasodium pyrophosphate, 0.2 parts of formaldehyde, 0.2 parts of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, mesh carbon fiber 1 part of rib plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating;
S2:将S1所述的水送入滤箱内进行初次过滤,将水中的大颗粒杂质进行过滤,随后将初滤后的水输送进软化水设备中进行软化,软化后的水再送入反渗透和净水机中,使水分子和离子态的矿物质元素通过反渗透膜,而溶解在水中的绝大部分无机盐,有机物以及细菌,病毒等无法透过反渗透膜,从而使渗透过的纯净水和无法渗透过的浓缩水严格的分开,得到净化水,净化后的水可降低含盐量,有效去除水中的多种杂质,降低水中导电离子,从而降低了导电率,也提升了出水电阻率;S2: The water described in S1 is sent into the filter box for primary filtration, and the large-particle impurities in the water are filtered, and then the water after the primary filtration is sent to the softening water equipment for softening, and the softened water is sent to reverse osmosis. And in the water purifier, water molecules and ionic mineral elements pass through the reverse osmosis membrane, and most of the inorganic salts, organic substances, bacteria, viruses, etc. dissolved in the water cannot pass through the reverse osmosis membrane, so that the permeated Purified water and impermeable concentrated water are strictly separated to obtain purified water. The purified water can reduce the salt content, effectively remove various impurities in the water, and reduce the conductive ions in the water, thereby reducing the conductivity and improving the effluent. resistivity;
S3:将S1所述的未漂硫酸盐针叶木浆送入碎浆机中进行打碎,得到碎浆料,再将碎浆料送入打浆机中进行打浆,同时将聚乙二醇,聚丙烯酰胺,丙烯酸-2-乙基己脂与苯乙烯的共聚物,氧化淀粉,焦磷酸四钠,甲醛和对硝基酚同时放入打浆机内进行搅拌,再将S2所述的净化水加入打浆机内一同搅拌,随后将打浆后的浆料送入抄纸机中进行加工成半成品,在抄纸机加工过程中使用气浮机对细小纤维进行回收,并送入碎浆机中继续加工,得到湿纸,可增加浆料中的细小纤维含量,可对绝缘纸板的强度起到提升,还可提高湿纸页的强度;S3: The unbleached kraft softwood pulp described in S1 is sent to a pulper for crushing to obtain crushed pulp, and then the crushed pulp is sent to a pulper for beating. Acrylamide, the copolymer of acrylic acid-2-ethylhexyl and styrene, oxidized starch, tetrasodium pyrophosphate, formaldehyde and p-nitrophenol are put into the beater at the same time for stirring, and then the purified water described in S2 is added Stir together in the beater, and then send the beaten pulp to the paper machine for processing into semi-finished products. During the processing of the paper machine, the air flotation machine is used to recover the fine fibers, and then sent to the pulper for further processing. , to obtain wet paper, which can increase the content of fine fibers in the pulp, which can improve the strength of insulating cardboard and improve the strength of wet paper sheets;
S4:将S3所述的湿纸送入输送机内进行输送,输送机将湿纸送入热压机中进行热压,即可得到绝缘纸板;S4: The wet paper described in S3 is sent into the conveyor for conveying, and the conveyor sends the wet paper into the hot press for hot pressing to obtain insulating cardboard;
S5:将S4所述的绝缘纸板送入加工台,并将绝缘纸板的两侧分别粘贴连接防水薄膜,在两个防水薄膜上再粘贴连接玻璃纤维网格布,在两个玻璃纤维网格布上再涂抹防火泥,在两个防火泥表面再安装网格状碳纤维加强筋板,最后再将两个网格状碳纤维加强筋板的表面喷涂防火涂层和UV耐磨涂层,得到加厚绝缘纸板。S5: The insulating cardboard described in S4 is sent to the processing table, and the two sides of the insulating cardboard are respectively pasted and connected to the waterproof film, and the glass fiber mesh cloth is pasted and connected on the two waterproof films. Apply fireproof mud on top, install grid-like carbon fiber reinforced rib plates on the surface of the two fire-proof mud, and finally spray the surface of the two grid-like carbon fiber reinforced rib plates with fireproof coating and UV wear-resistant coating to obtain a thickening. Insulating cardboard.
本实施例中,所述S3中,碎浆机的碎浆时间为30-40分钟,碎浆机内的粉碎转速为8000-12000r/min。In this embodiment, in S3, the pulping time of the pulper is 30-40 minutes, and the crushing speed in the pulper is 8000-12000 r/min.
本实施例中,所述S3中,打浆机的打浆时间为40-60分钟,碎浆机内的粉碎转速为4000-6000r/min。In this embodiment, in S3, the beating time of the pulper is 40-60 minutes, and the grinding speed in the pulper is 4000-6000 r/min.
本实施例中,所述S4中,热压机的工作温度为130℃-180℃,压力为0.2-0.9MPa。In this embodiment, in S4, the working temperature of the hot press is 130°C-180°C, and the pressure is 0.2-0.9MPa.
本实施例中,所述S5中,防水薄膜的厚度为0.3-0.6mm,玻璃纤维网格布的厚度为1.5-2.5mm。In this embodiment, in S5, the thickness of the waterproof film is 0.3-0.6 mm, and the thickness of the glass fiber mesh cloth is 1.5-2.5 mm.
实施例四Embodiment 4
一种加厚绝缘纸板,包括以下重量份的原料:未漂硫酸盐针叶木浆60份,水25份,聚乙二醇0.3份,聚丙烯酰胺4份,丙烯酸-2-乙基己脂与苯乙烯的共聚物3份,氧化淀粉4份,焦磷酸四钠3份,甲醛0.4份,对硝基酚0.4份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份。A thickened insulating paperboard, comprising the following raw materials by weight: 60 parts of unbleached sulfate softwood pulp, 25 parts of water, 0.3 parts of polyethylene glycol, 4 parts of polyacrylamide, acrylic acid-2-ethylhexyl resin and 3 parts of styrene copolymer, 4 parts of oxidized starch, 3 parts of tetrasodium pyrophosphate, 0.4 parts of formaldehyde, 0.4 parts of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, net 1 part of lattice carbon fiber reinforced plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating.
本实施例还提出了一种加厚绝缘纸板的生产方法,包括以下步骤:The present embodiment also proposes a method for producing thickened insulating cardboard, comprising the following steps:
S1:按以下重量份依次称取原材料:未漂硫酸盐针叶木浆60份,水25份,聚乙二醇0.3份,聚丙烯酰胺4份,丙烯酸-2-乙基己脂与苯乙烯的共聚物3份,氧化淀粉4份,焦磷酸四钠3份,甲醛0.4份,对硝基酚0.4份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份;S1: Weigh the raw materials in order by the following parts by weight: 60 parts of unbleached kraft softwood pulp, 25 parts of water, 0.3 parts of polyethylene glycol, 4 parts of polyacrylamide, a mixture of 2-ethylhexyl acrylate and styrene 3 parts of copolymer, 4 parts of oxidized starch, 3 parts of tetrasodium pyrophosphate, 0.4 parts of formaldehyde, 0.4 parts of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, mesh carbon fiber 1 part of rib plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating;
S2:将S1所述的水送入滤箱内进行初次过滤,将水中的大颗粒杂质进行过滤,随后将初滤后的水输送进软化水设备中进行软化,软化后的水再送入反渗透和净水机中,使水分子和离子态的矿物质元素通过反渗透膜,而溶解在水中的绝大部分无机盐,有机物以及细菌,病毒等无法透过反渗透膜,从而使渗透过的纯净水和无法渗透过的浓缩水严格的分开,得到净化水,净化后的水可降低含盐量,有效去除水中的多种杂质,降低水中导电离子,从而降低了导电率,也提升了出水电阻率;S2: The water described in S1 is sent into the filter box for primary filtration, and the large-particle impurities in the water are filtered, and then the water after the primary filtration is sent to the softening water equipment for softening, and the softened water is sent to reverse osmosis. And in the water purifier, water molecules and ionic mineral elements pass through the reverse osmosis membrane, and most of the inorganic salts, organic substances, bacteria, viruses, etc. dissolved in the water cannot pass through the reverse osmosis membrane, so that the permeated Purified water and impermeable concentrated water are strictly separated to obtain purified water. The purified water can reduce the salt content, effectively remove various impurities in the water, and reduce the conductive ions in the water, thereby reducing the conductivity and improving the effluent. resistivity;
S3:将S1所述的未漂硫酸盐针叶木浆送入碎浆机中进行打碎,得到碎浆料,再将碎浆料送入打浆机中进行打浆,同时将聚乙二醇,聚丙烯酰胺,丙烯酸-2-乙基己脂与苯乙烯的共聚物,氧化淀粉,焦磷酸四钠,甲醛和对硝基酚同时放入打浆机内进行搅拌,再将S2所述的净化水加入打浆机内一同搅拌,随后将打浆后的浆料送入抄纸机中进行加工成半成品,在抄纸机加工过程中使用气浮机对细小纤维进行回收,并送入碎浆机中继续加工,得到湿纸,可增加浆料中的细小纤维含量,可对绝缘纸板的强度起到提升,还可提高湿纸页的强度;S3: The unbleached kraft softwood pulp described in S1 is sent to a pulper for crushing to obtain crushed pulp, and then the crushed pulp is sent to a pulper for beating. Acrylamide, the copolymer of acrylic acid-2-ethylhexyl and styrene, oxidized starch, tetrasodium pyrophosphate, formaldehyde and p-nitrophenol are put into the beater at the same time for stirring, and then the purified water described in S2 is added Stir together in the beater, and then send the beaten pulp to the paper machine for processing into semi-finished products. During the processing of the paper machine, the air flotation machine is used to recover the fine fibers, and then sent to the pulper for further processing. , to obtain wet paper, which can increase the content of fine fibers in the pulp, which can improve the strength of insulating cardboard and improve the strength of wet paper sheets;
S4:将S3所述的湿纸送入输送机内进行输送,输送机将湿纸送入热压机中进行热压,即可得到绝缘纸板;S4: The wet paper described in S3 is sent into the conveyor for conveying, and the conveyor sends the wet paper into the hot press for hot pressing to obtain insulating cardboard;
S5:将S4所述的绝缘纸板送入加工台,并将绝缘纸板的两侧分别粘贴连接防水薄膜,在两个防水薄膜上再粘贴连接玻璃纤维网格布,在两个玻璃纤维网格布上再涂抹防火泥,在两个防火泥表面再安装网格状碳纤维加强筋板,最后再将两个网格状碳纤维加强筋板的表面喷涂防火涂层和UV耐磨涂层,得到加厚绝缘纸板。S5: The insulating cardboard described in S4 is sent to the processing table, and the two sides of the insulating cardboard are respectively pasted and connected to the waterproof film, and the glass fiber mesh cloth is pasted and connected on the two waterproof films. Apply fireproof mud on top, install grid-like carbon fiber reinforced rib plates on the surface of the two fire-proof mud, and finally spray the surface of the two grid-like carbon fiber reinforced rib plates with fireproof coating and UV wear-resistant coating to obtain a thickening. Insulating cardboard.
本实施例中,所述S3中,碎浆机的碎浆时间为30-40分钟,碎浆机内的粉碎转速为8000-12000r/min。In this embodiment, in S3, the pulping time of the pulper is 30-40 minutes, and the crushing speed in the pulper is 8000-12000 r/min.
本实施例中,所述S3中,打浆机的打浆时间为40-60分钟,碎浆机内的粉碎转速为4000-6000r/min。In this embodiment, in S3, the beating time of the pulper is 40-60 minutes, and the grinding speed in the pulper is 4000-6000 r/min.
本实施例中,所述S4中,热压机的工作温度为130℃-180℃,压力为0.2-0.9MPa。In this embodiment, in S4, the working temperature of the hot press is 130°C-180°C, and the pressure is 0.2-0.9MPa.
本实施例中,所述S5中,防水薄膜的厚度为0.3-0.6mm,玻璃纤维网格布的厚度为1.5-2.5mm。In this embodiment, in S5, the thickness of the waterproof film is 0.3-0.6 mm, and the thickness of the glass fiber mesh cloth is 1.5-2.5 mm.
实施例五Embodiment 5
一种加厚绝缘纸板,包括以下重量份的原料:未漂硫酸盐针叶木浆60份,水30份,聚乙二醇0.3份,聚丙烯酰胺5份,丙烯酸-2-乙基己脂与苯乙烯的共聚物5份,氧化淀粉10份,焦磷酸四钠1份,甲醛0.1份,对硝基酚0.3份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份。A thickened insulating paperboard, comprising the following raw materials by weight: 60 parts of unbleached sulfate softwood pulp, 30 parts of water, 0.3 parts of polyethylene glycol, 5 parts of polyacrylamide, acrylic acid-2-ethylhexyl resin and 5 parts of styrene copolymer, 10 parts of oxidized starch, 1 part of tetrasodium pyrophosphate, 0.1 part of formaldehyde, 0.3 part of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, net 1 part of lattice carbon fiber reinforced plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating.
本实施例还提出了一种加厚绝缘纸板的生产方法,包括以下步骤:The present embodiment also proposes a method for producing thickened insulating cardboard, comprising the following steps:
S1:按以下重量份依次称取原材料:未漂硫酸盐针叶木浆60份,水30份,聚乙二醇0.3份,聚丙烯酰胺5份,丙烯酸-2-乙基己脂与苯乙烯的共聚物5份,氧化淀粉10份,焦磷酸四钠1份,甲醛0.1份,对硝基酚0.3份,防水薄膜1份,玻璃纤维网格布1份,防火泥1份,网格状碳纤维加强筋板1份,防火涂层1份和UV耐磨涂层1份;S1: Weigh the raw materials in order by the following parts by weight: 60 parts of unbleached kraft softwood pulp, 30 parts of water, 0.3 parts of polyethylene glycol, 5 parts of polyacrylamide, a mixture of 2-ethylhexyl acrylate and styrene 5 parts of copolymer, 10 parts of oxidized starch, 1 part of tetrasodium pyrophosphate, 0.1 part of formaldehyde, 0.3 part of p-nitrophenol, 1 part of waterproof film, 1 part of glass fiber mesh, 1 part of fireproof mud, mesh carbon fiber 1 part of rib plate, 1 part of fireproof coating and 1 part of UV wear-resistant coating;
S2:将S1所述的水送入滤箱内进行初次过滤,将水中的大颗粒杂质进行过滤,随后将初滤后的水输送进软化水设备中进行软化,软化后的水再送入反渗透和净水机中,使水分子和离子态的矿物质元素通过反渗透膜,而溶解在水中的绝大部分无机盐,有机物以及细菌,病毒等无法透过反渗透膜,从而使渗透过的纯净水和无法渗透过的浓缩水严格的分开,得到净化水,净化后的水可降低含盐量,有效去除水中的多种杂质,降低水中导电离子,从而降低了导电率,也提升了出水电阻率;S2: The water described in S1 is sent into the filter box for primary filtration, and the large-particle impurities in the water are filtered, and then the water after the primary filtration is sent to the softening water equipment for softening, and the softened water is sent to reverse osmosis. And in the water purifier, water molecules and ionic mineral elements pass through the reverse osmosis membrane, and most of the inorganic salts, organic substances, bacteria, viruses, etc. dissolved in the water cannot pass through the reverse osmosis membrane, so that the permeated Purified water and impermeable concentrated water are strictly separated to obtain purified water. The purified water can reduce the salt content, effectively remove various impurities in the water, and reduce the conductive ions in the water, thereby reducing the conductivity and improving the effluent. resistivity;
S3:将S1所述的未漂硫酸盐针叶木浆送入碎浆机中进行打碎,得到碎浆料,再将碎浆料送入打浆机中进行打浆,同时将聚乙二醇,聚丙烯酰胺,丙烯酸-2-乙基己脂与苯乙烯的共聚物,氧化淀粉,焦磷酸四钠,甲醛和对硝基酚同时放入打浆机内进行搅拌,再将S2所述的净化水加入打浆机内一同搅拌,随后将打浆后的浆料送入抄纸机中进行加工成半成品,在抄纸机加工过程中使用气浮机对细小纤维进行回收,并送入碎浆机中继续加工,得到湿纸,可增加浆料中的细小纤维含量,可对绝缘纸板的强度起到提升,还可提高湿纸页的强度;S3: The unbleached kraft softwood pulp described in S1 is sent to a pulper for crushing to obtain crushed pulp, and then the crushed pulp is sent to a pulper for beating. Acrylamide, the copolymer of acrylic acid-2-ethylhexyl and styrene, oxidized starch, tetrasodium pyrophosphate, formaldehyde and p-nitrophenol are put into the beater at the same time for stirring, and then the purified water described in S2 is added Stir together in the beater, and then send the beaten pulp to the paper machine for processing into semi-finished products. During the processing of the paper machine, the air flotation machine is used to recover the fine fibers, and then sent to the pulper for further processing. , to obtain wet paper, which can increase the content of fine fibers in the pulp, which can improve the strength of insulating cardboard and improve the strength of wet paper sheets;
S4:将S3所述的湿纸送入输送机内进行输送,输送机将湿纸送入热压机中进行热压,即可得到绝缘纸板;S4: The wet paper described in S3 is sent into the conveyor for conveying, and the conveyor sends the wet paper into the hot press for hot pressing to obtain insulating cardboard;
S5:将S4所述的绝缘纸板送入加工台,并将绝缘纸板的两侧分别粘贴连接防水薄膜,在两个防水薄膜上再粘贴连接玻璃纤维网格布,在两个玻璃纤维网格布上再涂抹防火泥,在两个防火泥表面再安装网格状碳纤维加强筋板,最后再将两个网格状碳纤维加强筋板的表面喷涂防火涂层和UV耐磨涂层,得到加厚绝缘纸板。S5: The insulating cardboard described in S4 is sent to the processing table, and the two sides of the insulating cardboard are respectively pasted and connected to the waterproof film, and the glass fiber mesh cloth is pasted and connected on the two waterproof films. Apply fireproof mud on top, install grid-like carbon fiber reinforced rib plates on the surface of the two fire-proof mud, and finally spray the surface of the two grid-like carbon fiber reinforced rib plates with fireproof coating and UV wear-resistant coating to obtain a thickening. Insulating cardboard.
本实施例中,所述S3中,碎浆机的碎浆时间为30-40分钟,碎浆机内的粉碎转速为8000-12000r/min。In this embodiment, in S3, the pulping time of the pulper is 30-40 minutes, and the crushing speed in the pulper is 8000-12000 r/min.
本实施例中,所述S3中,打浆机的打浆时间为40-60分钟,碎浆机内的粉碎转速为4000-6000r/min。In this embodiment, in S3, the beating time of the pulper is 40-60 minutes, and the grinding speed in the pulper is 4000-6000 r/min.
本实施例中,所述S4中,热压机的工作温度为130℃-180℃,压力为0.2-0.9MPa。In this embodiment, in S4, the working temperature of the hot press is 130°C-180°C, and the pressure is 0.2-0.9MPa.
本实施例中,所述S5中,防水薄膜的厚度为0.3-0.6mm,玻璃纤维网格布的厚度为1.5-2.5mm。In this embodiment, in S5, the thickness of the waterproof film is 0.3-0.6 mm, and the thickness of the glass fiber mesh cloth is 1.5-2.5 mm.
通过检测设备对现有产品和本实施例产品中的抗张强度,电导率和电气强度进行测试,对测试的结果进行记录;The tensile strength, electrical conductivity and electrical strength of the existing products and the products of this embodiment are tested by testing equipment, and the test results are recorded;
结果表明:本发明制备的加厚绝缘纸板抗张强度、电导率和电气强度均较好。The results show that the tensile strength, electrical conductivity and electrical strength of the thickened insulating paperboard prepared by the invention are all good.
本发明相对现有技术获得的技术进步是:本发明的加厚绝缘纸板的层间结合力较腔,且抗张强度较高,导电率较低,使用时的防水防火性能较好,长时间使用也可避免发生开裂,使用寿命更长。Compared with the prior art, the technical progress obtained by the present invention is: the thickened insulating paperboard of the present invention has stronger interlayer bonding force, higher tensile strength, lower electrical conductivity, better waterproof and fireproof performance during use, and can be used for a long time. The use can also avoid cracking and have a longer service life.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1357817A (en) * | 1970-09-25 | 1974-06-26 | Toray Industries | Process for making paper forming pulp |
CN105198116A (en) * | 2015-08-31 | 2015-12-30 | 南京林业大学 | Method for reducing wastewater generation during clean papermaking |
CN106638079A (en) * | 2016-12-08 | 2017-05-10 | 中山市为客包装制品有限公司 | Method for producing antistatic paper pulp |
CN109577070A (en) * | 2018-12-06 | 2019-04-05 | 康峰(苏州)纸品有限公司 | A kind of wear-resisting paper tube of environmental-protection flame-retardant and its preparation process |
CN208932056U (en) * | 2018-09-07 | 2019-06-04 | 成都君诚轨道交通设备有限公司 | A kind of novel paper honeycomb |
-
2020
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1357817A (en) * | 1970-09-25 | 1974-06-26 | Toray Industries | Process for making paper forming pulp |
CN105198116A (en) * | 2015-08-31 | 2015-12-30 | 南京林业大学 | Method for reducing wastewater generation during clean papermaking |
CN106638079A (en) * | 2016-12-08 | 2017-05-10 | 中山市为客包装制品有限公司 | Method for producing antistatic paper pulp |
CN208932056U (en) * | 2018-09-07 | 2019-06-04 | 成都君诚轨道交通设备有限公司 | A kind of novel paper honeycomb |
CN109577070A (en) * | 2018-12-06 | 2019-04-05 | 康峰(苏州)纸品有限公司 | A kind of wear-resisting paper tube of environmental-protection flame-retardant and its preparation process |
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