CN114657301A - Device transformation method for treating molten iron backflow - Google Patents

Device transformation method for treating molten iron backflow Download PDF

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Publication number
CN114657301A
CN114657301A CN202210310736.3A CN202210310736A CN114657301A CN 114657301 A CN114657301 A CN 114657301A CN 202210310736 A CN202210310736 A CN 202210310736A CN 114657301 A CN114657301 A CN 114657301A
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China
Prior art keywords
parts
molten iron
skimmer
slag
steel
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Pending
Application number
CN202210310736.3A
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Chinese (zh)
Inventor
张旭
左俊杰
曾凡辉
武卫东
刘大维
王德慧
张立军
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Shandong Laigang Yongfeng Steel and Iron Co Ltd
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Shandong Laigang Yongfeng Steel and Iron Co Ltd
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Priority to CN202210310736.3A priority Critical patent/CN114657301A/en
Publication of CN114657301A publication Critical patent/CN114657301A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/14Discharging devices, e.g. for slag
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B7/00Blast furnaces
    • C21B7/04Blast furnaces with special refractories
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38Non-oxide ceramic constituents or additives
    • C04B2235/3852Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
    • C04B2235/3865Aluminium nitrides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/40Metallic constituents or additives not added as binding phase
    • C04B2235/405Iron group metals
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/60Process control or energy utilisation in the manufacture of iron or steel
    • C21B2100/66Heat exchange
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21BMANUFACTURE OF IRON OR STEEL
    • C21B2100/00Handling of exhaust gases produced during the manufacture of iron or steel
    • C21B2100/80Interaction of exhaust gases produced during the manufacture of iron or steel with other processes

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Metallurgy (AREA)
  • Structural Engineering (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Blast Furnaces (AREA)
  • Furnace Charging Or Discharging (AREA)

Abstract

The invention relates to the technical field of slag iron treatment in blast furnace production of metallurgical enterprises, and discloses a device transformation method for treating molten iron backflow, which comprises the following steps: s1: cleaning the residual materials in the main channel and the skimmer by using a tool; s2: the width of tunnels on two sides of a main channel of the skimmer is enlarged by 30-32cm respectively, and the depth is increased by 18-20 cm; s3: according to the specific size, a steel large well and small well passageway mold is newly manufactured; s4: and (5) installing a steel mould, and dropping the position of the skimmer by 10-12 cm. The invention ensures that molten iron can safely and smoothly pass through the slag skimmer, eliminates the phenomenon of molten iron recharging, avoids blasting hidden danger caused by molten iron flowing into a slag runner, reduces the impact and erosion force of the small well wall of the skimmer, and avoids the molten iron leakage accident caused by local burning-through of the iron storage device.

Description

Method for modifying device for treating molten iron backflow
Technical Field
The invention relates to the technical field of slag iron treatment in blast furnace production of metallurgical enterprises, in particular to a device transformation method for treating molten iron backflow.
Background
The working state of the skimmer plays an important role during tapping of the blast furnace, the skimmer consists of a front groove (a large well), a sand dam, a large gate, a groove head, a passage hole, a small well, a sand hole and a main iron groove, and the basic working principle is to separate iron slag by utilizing the specific gravity difference of the iron slag and the slag. The slag and the molten iron flowing out of the iron notch flow to the skimmer through the main channel, and the molten iron is heavy and sinks below the skimmer, while the molten slag is light and floats above the skimmer to generate slag and iron layering. Under the action of a ditch head at an outlet of the skimmer, a small pit and a small well which are connected by the through hole are filled with molten iron, and the through hole can only pass the molten iron; the large gate plays a role of a retaining wall, the molten slag is retained in front of the large gate, when the molten slag reaches a certain thickness on the molten iron surface, the sand hill is properly cut down, and the molten slag flows into the slag discharge groove.
The central task of the slag skimmer is to ensure that slag and iron are separated, the slag is not excessive and has no slag, and the slag and iron cannot overflow, so that normal and safe production is ensured; when the slag skimmer works, whether all parts are damaged or not must be checked, the parts are timely found, repaired and baked in time, residual iron is cleaned, and tools are prepared. When the skimmer is treated, the crust is opened, and a sand hole, a sand dam and a sand hill are well blocked. When the tapping begins to have slag, properly scattering a layer of heat preservation material on the surface of the slag iron of the skimmer; pushing down the sand hill on the slag discharging groove according to the regulation so as to enable slag to flow out, observing the change of the skimmer in the tapping process, pushing away a residue sand dam after the iron port is confirmed to be sealed, discharging the residue in the main groove, and spreading a heat insulating material on the surface of the molten iron after the slag flows out.
If the newly manufactured skimmer is not baked, blasting accidents are easily caused, and the newly repaired skimmer is not firmly repaired to cause floating ships, so that the wall is burnt and leaked, accidents are caused, and people and equipment are easily burned. The slag skimmer has a large hole, and when slag is contained in iron, the molten iron tank is easy to crust. The sand dam is not firm or the sand dam is pushed too early or too low, so that iron in the discharged slag is over-discharged, slag runner explosion is easy to cause personnel injury.
Because the design and the installation structure of the skimmer are unreasonable, the liquid level of the main runner is high, the hidden danger that molten iron is poured back to burn out an iron notch exists, the drop height of the skimmer is small, and the slag runner is easily doped with the molten iron when the slag flows into the slag runner, so that the hidden danger of blasting of the slag runner is caused.
Disclosure of Invention
The invention aims to solve the problems that in the prior art, an iron notch is burnt out by molten iron recharging, the drop height of a skimmer is small, and molten iron is easily doped when slag flows into a slag runner, so that the blasting hidden danger of the slag runner is caused, and the method for modifying the device for treating the molten iron backflow is provided.
In order to achieve the purpose, the invention adopts the following technical scheme:
a method for modifying a device for treating molten iron backflow comprises the following steps:
s1: cleaning the residual materials in the main channel and the skimmer by using a tool;
s2: the width of tunnels on two sides of a main channel of the skimmer is enlarged by 30-32cm respectively, and the depth is increased by 18-20 cm;
s3: according to the specific size, a steel large well and small well passageway mold is newly manufactured;
s4: installing a steel mould, and fixing the skimmer by dropping 10-12cm and the small well by dropping 15-17 cm;
s5: fully stirring the refractory materials, and pouring each part;
s6: after pouring, introducing smoke generated in the other normal-working ladle refining furnaces into the main channel, baking the surface of the steel mould, and dismantling the steel mould after 2-3 hours;
s7: igniting the prepared wood, and heating in a big well and a small well;
s8: baking is continued for 6 h.
Preferably, in the step S2, after the width of the pits on both sides of the main trench is widened, the surfaces of the pits are trimmed to maintain the surfaces horizontal.
Preferably, in the step S3, air outlets are reserved in advance on the steel mold to serve as channels for discharging water and air in the refractory material, so as to prevent the refractory material from bursting during baking and heating.
Preferably, in the step S4, when the steel mold is fixed, the hanger applies an upward pulling force to the steel mold to suspend the steel mold, so as to reduce the pressure applied to the main trench by the steel mold, and prevent the steel mold from being deformed due to the stress applied to the main trench, thereby preventing the position of the steel mold from moving.
Preferably, in the step S5, the refractory material includes the following components in parts by weight: 10-13 parts of mica powder, 5-8 parts of aluminum nitride, 4-6 parts of coke powder, 15-20 parts of kaolin clay, 8-11 parts of nickel-based alloy powder, 7-9 parts of limestone, 10-12 parts of silicon dioxide, 11-14 parts of benzyl silicone resin, 6-7 parts of alumina trihydrate, 5-7 parts of a coagulant and 4-7 parts of a binding agent.
Preferably, in the step S7, the wood is pine wood, the pine wood is broken into small pieces, and the small pieces are dried; when wood is combusted in the big well and the small well, oxygen is supplied to the flame center.
Compared with the prior art, the invention provides a device transformation method for treating molten iron backflow, which has the following beneficial effects:
1. according to the device transformation method for treating molten iron backflow, the channel height of the skimmer is adjusted, the front and rear fall of the main ditch is increased, the liquid level height of molten iron stored in the main ditch is reduced, the molten iron can safely and smoothly pass through the skimmer, the molten iron recharging phenomenon is eliminated, the blasting hidden danger caused by the fact that the molten iron flows into the slag ditch is avoided, the impact and erosion force of the small well wall body of the skimmer is reduced, and the molten iron leakage accident caused by local burning-through of the skimmer is avoided.
2. According to the device transformation method for treating molten iron backflow, smoke generated in the other normal working ladle refining furnaces is introduced into the main channel, the surface of the steel mould is baked, so that a refractory material in the steel mould is heated, the solidification speed of the refractory material in the steel mould is improved, and waste smoke is recycled.
3. According to the device transformation method for treating molten iron backflow, the air outlet holes are reserved in advance on the steel mould and used as the pore channels for discharging water and air in the refractory material, so that the refractory material is prevented from cracking when being baked and heated.
4. According to the method for modifying the device for treating the molten iron backflow, the refractory material formed by stirring the mica powder, the aluminum nitride, the coke powder, the kaolin clay, the nickel-based alloy powder, the limestone, the silicon dioxide, the phenylmethylsilicone resin, the alumina trihydrate, the coagulant and the binder is greatly improved in high-temperature refractory performance, the linear change rate of the product is small, and the filling effect, the adhesive strength and the wear resistance are good.
The device has the advantages that the parts which are not involved are the same as or can be realized by adopting the prior art, the invention ensures that molten iron can safely and smoothly pass through, eliminates the phenomenon of molten iron recharging, avoids blasting hidden danger caused by the fact that the molten iron flows into a slag runner, reduces the impact and erosion force of a small well wall body of the skimmer, and avoids the molten iron leakage accident caused by local burning-through of the iron storage device.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments.
A method for modifying a device for treating molten iron backflow comprises the following steps:
s1: cleaning the residual materials in the main ditch and the skimmer by using a tool;
s2: expanding the width of the tunnel at two sides of the main trench of the skimmer, respectively increasing by 30cm and by 20cm, and finishing the surface of the tunnel to keep the surface horizontal;
s3: according to the specific size, a large steel well and a small steel well passageway mold is newly manufactured, and air outlet holes are reserved in the steel mold in advance and are used as pore passages for discharging water and air in the refractory material, so that the refractory material is prevented from cracking when being baked and heated;
s4: installing a steel mould, enabling the skimmer to fall for 10cm, enabling the small well to fall for 15cm, fixing, and applying upward pulling force to the steel mould through a hanging bracket when the skimmer is fixed, so that the steel mould is suspended, the pressure applied to the main ditch gallery by the steel mould is reduced, and the phenomenon that the position of the steel mould is moved due to deformation caused by stress of the main ditch gallery is avoided;
s5: fully stirring a refractory material, wherein the refractory material comprises the following components in parts by weight: 10 parts of mica powder, 8 parts of aluminum nitride, 6 parts of coke powder, 15 parts of kaolin clay, 8 parts of nickel-based alloy powder, 9 parts of limestone, 10 parts of silicon dioxide, 14 parts of benzyl silicone resin, 6 parts of alumina trihydrate, 5 parts of a coagulant and 4 parts of a binding agent, so that the high-temperature fire resistance of the refractory material is greatly improved, the linear change rate of the product is small, the refractory material has good filling effect, adhesive strength and wear resistance, and the refractory material formed by stirring is poured on each part;
s6: after pouring, introducing smoke generated in the other normal-working ladle refining furnaces into the main channel, baking the surface of the steel mould to heat the refractory material in the steel mould, improving the solidification speed of the refractory material in the steel mould, recycling waste smoke, and dismantling the steel mould after 3 hours;
s7: breaking pine wood into small pieces, drying, stacking, igniting, supplying oxygen to flame center, and heating in large and small wells;
s8: baking is continued for 6 h.
According to the invention, the integral fall of the skimmer is 30cm, so that the liquid level of the main ditch falls by 10cm, the height of the bottom layer of the skimmer is reduced during pouring by adjusting the channel height of the skimmer, the front and rear fall of the main ditch is increased, the liquid level height of iron stored in the main ditch is reduced, the molten iron can safely and smoothly pass through the skimmer, the phenomenon of molten iron recharging is eliminated, the potential safety hazard of burning out an iron notch is avoided, the transition interval of slag passing through the skimmer is increased, the hidden danger of blasting when the molten iron flows into the slag ditch is avoided, the impact and erosion force of a small well wall body of the skimmer is reduced, and the molten iron leakage accident caused by local burning-through of the iron stored is avoided.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (6)

1. A method for modifying a device for treating molten iron backflow is characterized by comprising the following steps:
s1: cleaning the residual materials in the main channel and the skimmer by using a tool;
s2: the width of tunnels on two sides of a main channel of the skimmer is enlarged by 30-32cm respectively, and the depth is increased by 18-20 cm;
s3: according to the specific size, a steel large well and small well passageway mold is newly manufactured;
s4: installing a steel mould, and fixing the skimmer by dropping 10-12cm and the small well by dropping 15-17 cm;
s5: fully stirring the refractory materials, and pouring each part;
s6: after pouring, introducing smoke generated in the other normal-working ladle refining furnaces into the main channel, baking the surface of the steel mould, and dismantling the steel mould after 2-3 hours;
s7: igniting the prepared wood, and heating in a big well and a small well;
s8: baking is continued for 6 h.
2. The method of modifying an apparatus for processing molten iron backflow according to claim 1, wherein in the step S2, after the width of the excavation on both sides of the main trench is widened, the surface of the excavation is modified to maintain the surface level.
3. The method of claim 1, wherein in the step S3, air outlets are reserved in advance on the steel mold to serve as openings for discharging water and air from the interior of the refractory material, so as to prevent the refractory material from bursting during baking and heating.
4. The method of claim 1, wherein in the step S4, when the steel mold is fixed, the steel mold is suspended by applying an upward pulling force to the steel mold through the hanger, so as to reduce a pressure applied to the main channel by the steel mold, and prevent the position of the steel mold from moving due to deformation of the main channel caused by the force.
5. The method of modifying an apparatus for processing molten iron backflow according to claim 1, wherein in the step S5, the refractory material includes the following components in parts by weight: 10-13 parts of mica powder, 5-8 parts of aluminum nitride, 4-6 parts of coke powder, 15-20 parts of kaolin clay, 8-11 parts of nickel-based alloy powder, 7-9 parts of limestone, 10-12 parts of silicon dioxide, 11-14 parts of benzyl silicone resin, 6-7 parts of alumina trihydrate, 5-7 parts of a coagulant and 4-7 parts of a binding agent.
6. The method of modifying an apparatus for processing molten iron backflow as claimed in claim 1, wherein in the step S7, wood is pine wood, the pine wood is broken into small pieces, and the small pieces are dried; when wood is combusted in the big well and the small well, oxygen is supplied to the flame center.
CN202210310736.3A 2022-03-28 2022-03-28 Device transformation method for treating molten iron backflow Pending CN114657301A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115433794A (en) * 2022-09-28 2022-12-06 山东莱钢永锋钢铁有限公司 Treatment method for reducing molten iron corrosion

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CN204529891U (en) * 2015-02-25 2015-08-05 鞍钢股份有限公司 Mould repaired by the large lock of main trough of blast furnace
CN210596132U (en) * 2019-08-26 2020-05-22 山东钢铁股份有限公司 Quick mould for pouring of slag skimmer of main iron runner of blast furnace
CN111235335A (en) * 2020-03-20 2020-06-05 广东韶钢松山股份有限公司 Method for repairing skimmer on line
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CN204529891U (en) * 2015-02-25 2015-08-05 鞍钢股份有限公司 Mould repaired by the large lock of main trough of blast furnace
CN210596132U (en) * 2019-08-26 2020-05-22 山东钢铁股份有限公司 Quick mould for pouring of slag skimmer of main iron runner of blast furnace
CN111235335A (en) * 2020-03-20 2020-06-05 广东韶钢松山股份有限公司 Method for repairing skimmer on line
CN212982977U (en) * 2020-07-15 2021-04-16 新兴铸管股份有限公司 Quick maintenance device of skimmer
CN214244490U (en) * 2020-12-22 2021-09-21 北京联合荣大工程材料股份有限公司 Blast furnace iron storage type iron runner

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115433794A (en) * 2022-09-28 2022-12-06 山东莱钢永锋钢铁有限公司 Treatment method for reducing molten iron corrosion

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