CN114657031A - Multi-cavity washing gel bead - Google Patents
Multi-cavity washing gel bead Download PDFInfo
- Publication number
- CN114657031A CN114657031A CN202210438610.4A CN202210438610A CN114657031A CN 114657031 A CN114657031 A CN 114657031A CN 202210438610 A CN202210438610 A CN 202210438610A CN 114657031 A CN114657031 A CN 114657031A
- Authority
- CN
- China
- Prior art keywords
- detergent
- liquid detergent
- lignosulfonate
- sodium bicarbonate
- laundry bead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011324 bead Substances 0.000 title claims abstract description 33
- 238000005406 washing Methods 0.000 title abstract description 10
- 239000003599 detergent Substances 0.000 claims abstract description 67
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 36
- 239000007788 liquid Substances 0.000 claims abstract description 35
- 229920001732 Lignosulfonate Polymers 0.000 claims abstract description 34
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 18
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 18
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 14
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 11
- 239000002904 solvent Substances 0.000 claims abstract description 10
- 235000013305 food Nutrition 0.000 claims abstract description 5
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims abstract description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 19
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 10
- 239000000194 fatty acid Substances 0.000 claims description 10
- 229930195729 fatty acid Natural products 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 9
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 7
- -1 fatty acid monoethanolamine salt Chemical class 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 239000003346 palm kernel oil Substances 0.000 claims description 6
- 235000019865 palm kernel oil Nutrition 0.000 claims description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 5
- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 235000021355 Stearic acid Nutrition 0.000 claims description 4
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 239000008117 stearic acid Substances 0.000 claims description 4
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 claims description 3
- JLFNLZLINWHATN-UHFFFAOYSA-N pentaethylene glycol Chemical compound OCCOCCOCCOCCOCCO JLFNLZLINWHATN-UHFFFAOYSA-N 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 claims description 3
- 239000002304 perfume Substances 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 239000004744 fabric Substances 0.000 abstract description 16
- 238000009833 condensation Methods 0.000 abstract description 4
- 230000005494 condensation Effects 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 description 10
- 150000004996 alkyl benzenes Chemical class 0.000 description 9
- 229940092714 benzenesulfonic acid Drugs 0.000 description 8
- 238000003756 stirring Methods 0.000 description 7
- 239000000047 product Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229920003169 water-soluble polymer Polymers 0.000 description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- 238000006386 neutralization reaction Methods 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002633 protecting effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/045—Multi-compartment
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/30—Sulfonation products derived from lignin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C11D2111/12—
Abstract
The invention discloses a multi-cavity laundry gel bead. It has a sachet made of water-soluble film, said sachet having at least 2 independent chambers, wherein one independent chamber contains liquid detergent and the other chamber contains softening detergent; the liquid detergent contained in one of the separate chambers includes food grade sodium bicarbonate, an anionic surfactant, a nonionic surfactant, and a solvent, wherein: the mass percentage of the food-grade sodium bicarbonate in the liquid detergent is 0.01-6%; the anionic surfactant contains modified lignosulfonate, and the mass percent of the modified lignosulfonate in the liquid detergent is 0.1-2.5%. The invention adopts food-grade sodium bicarbonate in the fabric detergent in the multi-cavity washing condensation bead, improves the product safety, and solves the technical problems that the sodium bicarbonate is easy to separate out in the concentrated liquid fabric detergent and the fabric is hard.
Description
Technical Field
The invention relates to the technical field of daily chemical detergents, in particular to a multi-cavity washing gel bead.
Background
The fabric detergent is used in a large amount in daily life of people, and the greenness and safety of the product are continuously improved. For certain people, such as infants, skin-sensitive people and the like, the product safety of the fabric detergent needs to be ensured to be higher in order to reduce irritation and potential harm. To achieve this goal, it is desirable to select a fabric detergent material with improved safety. However, these raw materials usually face technical difficulties such as high cost and compatibility in practical application.
Food-grade sodium bicarbonate is a high-safety raw material and is widely applied to various wheaten food products as a food additive. And when the food-grade sodium bicarbonate is applied to the detergent, on one hand, the safety of the detergent product can be improved, and meanwhile, alkalescence can be provided to help mild decontamination. Sodium bicarbonate is soluble in water and insoluble in organic solvents such as ethanol, but its solubility in water at 20 ℃ is only 9.6 g, so when sodium bicarbonate is applied to laundry beads containing high concentrations of actives, it is difficult to form a stable dissolution dispersion system due to the low water content of the laundry bead product, and the sodium bicarbonate gradually precipitates.
Disclosure of Invention
The invention aims to provide a multi-cavity laundry bead, which effectively solves the defects of the prior art.
In order to achieve the purpose, the invention adopts the following technical scheme:
the adopted technical scheme is as follows:
a multi-chamber laundry bead having a sachet made from a water-soluble film, said sachet having at least 2 separate chambers, one of which contains a liquid detergent and the other contains a softening detergent; the liquid detergent contained in one of the separate chambers includes food grade sodium bicarbonate, an anionic surfactant, a nonionic surfactant, and a solvent, wherein: the mass percentage of the food-grade sodium bicarbonate in the liquid detergent is 0.01-6%; the anionic surfactant contains modified lignosulfonate, and the mass percent of the modified lignosulfonate in the liquid detergent is 0.1-2.5%.
Further, the modified lignosulfonate is carboxymethyl lignosulfonate, and the carboxymethyl lignosulfonate is one or a combination of sodium carboxymethyl lignosulfonate, potassium carboxymethyl lignosulfonate and ammonium carboxymethyl lignosulfonate.
Further, the carboxymethyl lignosulfonate has a molecular weight of 4000-7000, a sulfo content of 1-1.6mmol/g and a carboxyl content of 0.8-2 mmol/g.
Further, the mass percent of the anionic surfactant in the liquid detergent is 35-55%; the mass percentage of the nonionic surfactant in the liquid detergent is 15-30%.
Further, the anionic surfactant also comprises fatty acid monoethanolamine salt and/or alkyl benzene sulfonic acid monoethanolamine salt, wherein the fatty acid in the fatty acid monoethanolamine salt comprises one or more of oleic acid, castor oil and palm kernel oil; the alkyl benzene sulfonic acid carbon chain in the alkyl benzene sulfonic acid monoethanolamine salt is preferably 12-18. The nonionic surfactant comprises fatty alcohol-polyoxyethylene ether, the carbon chain is preferably 12-14, and the EO number is preferably 7-9.
Further, the mass percent of the solvent in the liquid detergent is 5-25%,
further, the solvent comprises one of propylene glycol, glycerin, PEG400, ethylene glycol or a combination thereof.
Further, the softening detergent comprises the following components in percentage by mass: 25-40% of oleic acid monoethanolamine salt, 4-12% of hydrogenated castor oil, 10-20% of palm kernel oil monoethanolamine, 4-8% of dioctadecyl dimethyl ammonium chloride, 0.4-1% of stearic acid, 8-20% of glycerol and 5-15% of polyethylene glycol. Further, the softening detergent may further comprise typical ingredients such as perfume, pigment and the like.
Further, the mass percentage of the liquid detergent and the softening detergent is 3.5-2: 1.
Further, the sachet may also have separate chambers for enclosing solid fragrance-retaining particles, liquid disinfectant and/or solid disinfectant.
The invention selects the modified lignosulfonate as the dispersant, and can help sodium bicarbonate particles to be stably dispersed in the liquid detergent. The lignosulfonate is mainly derived from papermaking byproducts, is green and environment-friendly, and can be widely applied to industries such as dye, cement and the like as a dispersant; when the cleaning agent is applied to a detergent, the molecular structure of the cleaning agent contains a certain number of phenolic hydroxyl groups, so that the cleaning agent has a certain staining effect on textile fibers and influences the cleaning effect. According to the invention, carboxymethylation modified lignosulfonate is further selected as a sodium bicarbonate stabilizer, the larger the number of sulfonic groups in lignosulfonate is, the better the dispersion and prevention of contamination to fabric fibers are, but the larger the number of sulfonic groups can influence the adsorption of lignosulfonate on solid particles and influence the dispersion performance, and the addition of carboxyl can improve the contamination prevention of fibers and simultaneously reduce the adsorption influence of lignosulfonate on solid particles due to the increase of hydrophilic groups. The amount of sulfonic acid group and carboxyl group is in the preferable range, and the better dispersing performance can be achieved.
The present invention provides cleaning efficacy in a plurality of closed chamber laundry beads wherein one chamber encloses the concentrated fabric detergent described above and the other chamber encloses a concentrated softening detergent. The invention provides the optimal compatibility proportion of the detergent and the softening detergent, and can provide better softening effect under the proportion, and simultaneously reduce the 'hardness' of the fabric possibly caused by the deposition of sodium bicarbonate. The product design of the multi-cavity coagulated beads reduces the negative effect brought by certain efficacy and provides a washing and protecting effect with better comprehensive performance.
Compared with the prior art, the invention has the following beneficial effects:
1. the food-grade sodium bicarbonate is adopted in the fabric detergent in the multi-cavity washing condensation bead, so that the safety of the product is improved;
2. the carboxymethyl modified lignosulfonate is used as a dispersing agent, so that the technical problem that sodium bicarbonate is easy to separate out in a concentrated liquid fabric detergent is solved;
3. the use of a multi-cavity laundry bead pattern provides both washing and softening benefits, provides good softening benefits, and reduces the potential 'stiffness' problem of sodium bicarbonate deposition on fabrics.
Detailed Description
The invention relates to a multi-cavity laundry bead, which is provided with a bag made of a water-soluble film, wherein the bag is provided with 2 independent cavities, one independent cavity contains liquid detergent, and the other cavity contains softening detergent.
The liquid detergent contained in one of the separate chambers comprises food grade sodium bicarbonate, an anionic surfactant, a nonionic surfactant, and a solvent, wherein: the mass percentage of the food-grade sodium bicarbonate in the liquid detergent is 0.01-6%; the anionic surfactant contains modified lignosulfonate, and the mass percent of the modified lignosulfonate in the liquid detergent is 0.1-2.5%.
The modified lignosulfonate is carboxymethyl lignosulfonate, which is one or a combination of sodium carboxymethyl lignosulfonate, potassium carboxymethyl lignosulfonate and ammonium carboxymethyl lignosulfonate. Furthermore, the carboxymethyl lignosulfonate has a molecular weight of 4000-7000, a sulfo content of 1-1.6mmol/g and a carboxyl content of 0.8-2 mmol/g.
The mass percent of the anionic surfactant in the liquid detergent is 35-55%; the mass percentage of the nonionic surfactant in the liquid detergent is 15-30%. The anionic surfactant also comprises fatty acid monoethanolamine salt and/or alkyl benzene sulfonic acid monoethanolamine salt, wherein the fatty acid in the fatty acid monoethanolamine salt comprises one or more of oleic acid, castor oil and palm kernel oil; the alkyl benzene sulfonic acid carbon chain in the alkyl benzene sulfonic acid monoethanolamine salt is preferably 12-18. The nonionic surfactant comprises fatty alcohol-polyoxyethylene ether, the carbon chain is preferably 12-14, and the EO number is preferably 7-9.
The solvent is 5-25% by weight of the liquid detergent, and comprises one or combination of propylene glycol, glycerol, PEG400, and ethylene glycol.
The softening detergent comprises the following components in percentage by mass: 25-40% of oleic acid monoethanolamine salt, 4-12% of hydrogenated castor oil, 10-20% of palm kernel oil monoethanolamine, 4-8% of dioctadecyl dimethyl ammonium chloride, 0.4-1% of stearic acid, 8-20% of glycerol and 5-15% of polyethylene glycol.
The mass percentage of the liquid detergent and the softening detergent is 3.5-2: 1.
The preparation method of the multi-cavity laundry gel bead comprises the following steps:
1. the preparation method of the liquid detergent in the multi-cavity washing condensation bead comprises the following steps:
(1) putting the solvent into a reaction kettle, and uniformly stirring;
(2) the alkyl benzene sulfonic acid monoethanolamine salt and the fatty acid monoethanolamine salt are prepared by putting alkyl benzene sulfonic acid, fatty acid and monoethanolamine into a reaction kettle for neutralization reaction: adding monoethanolamine into a reaction kettle, adding fatty acid in a molten state into the reaction kettle, adding alkylbenzene sulfonic acid into the reaction kettle, and stirring uniformly to complete a neutralization reaction;
(3) adding the modified lignosulfonate into a reaction kettle, and uniformly stirring;
(4) putting the non-ionic surfactant in a molten state into a reaction kettle;
(5) adding essence and pigment.
2. The preparation method of the softening detergent in the multi-cavity washing condensation bead comprises the following steps:
(1) putting polyethylene glycol, hydrogenated castor oil and palm kernel oil monoethanolamide into a reaction kettle and stirring uniformly; the oleic acid monoethanolamine salt is prepared by adopting neutralization reaction of oleic acid and monoethanolamine: and adding monoethanolamine into the reaction kettle, adding the oleic acid in a molten state into the reaction kettle, and uniformly stirring to complete a neutralization reaction. A mixture a is obtained.
(2) Adding process water according to the formula amount in a homogenizer, starting stirring, heating to 45 ℃, and adding dioctadecyl dimethyl ammonium chloride and stearic acid until the mixture is dissolved uniformly; cooling to 30 ℃, and adding glycerol to obtain a mixture B.
(3) And adding the mixture B into the mixture A, and uniformly stirring. If necessary, essence and pigment can be added.
3. The preparation method of the multi-cavity washing gel bead comprises the following steps:
(1) respectively putting the liquid detergent and the softening detergent into a slurry tank of an automatic bead packaging machine wrapped by a water-soluble film;
(2) a multi-cavity bead-condensing bead-making mold is adopted, a water-soluble polymer film is heated and then is drawn into the mold, and the water-soluble polymer film is plasticized in the mold through vacuum forming;
(3) quantitatively feeding each group of slurry into different chambers through conveying pipes;
(4) and (3) drawing the water-soluble polymer film into a mould after water is applied to the water-soluble polymer film, and bonding and sealing the water-soluble polymer film under the action of a compression roller to obtain the multi-cavity water-soluble film-coated coagulated beads.
Examples
Table 1 lists examples of concentrated fabric detergents and table 2 lists examples of concentrated softening detergents. Table 1, table 2 examples multi-chamber laundry beads were prepared according to the mass percentages listed in table 3.
Table 1: concentrated fabric detergent examples
Table 2: concentrated fabric softening detergent examples
Table 3: mass ratio of fabric detergent to softening detergent
| Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | |
| Example A | 10g | |||||
| Example B | 20g | |||||
| Example C | 20g | |||||
| Example D | 15g | |||||
| Example E | 8g | |||||
| Example F | 12g | |||||
| Example R1 | 4g | |||||
| Example R2 | 6g | 6g | ||||
| Example R3 | 8g | 3g | ||||
| Example R4 | 5g |
4. EXAMPLES determination of soil Release ability
Taking examples 1-6 as an example, the results of the detergency determination by the detergency determination method in the QB/T1224-:
table 4: detergency test
As can be seen from the results in Table 4, the detergency of examples 1 to 6 of the present invention all meet the national standards.
5, stability tests were conducted on the above examples.
The multi-cavity laundry beads prepared in examples 1 to 6 were placed in a thermostat at 48 ℃ for 1 month, and then taken out to visually check whether layering and precipitation were observed. The results of the experiment are shown in Table 5.
TABLE 5
The multi-cavity laundry beads prepared in examples 1 to 6 were placed in a 5 ℃ thermostat for 1 month, and then taken out to visually check whether layering and precipitation were observed. The results of the experiment are shown in Table 6.
TABLE 6
As can be seen from tables 5 and 6, in none of examples 1 to 6, there was no precipitation or delamination, indicating that there was no unstable precipitation of sodium bicarbonate particles in the liquid detergent.
Claims (10)
1. A multi-compartment laundry bead having a sachet formed from a water-soluble film, said sachet having at least 2 separate compartments, one of said separate compartments containing a liquid detergent and the other containing a softening detergent, wherein said liquid detergent contained in one of said separate compartments comprises food grade sodium bicarbonate, anionic surfactant, nonionic surfactant and solvent, wherein: the mass percentage of the food-grade sodium bicarbonate in the liquid detergent is 0.01-6%; the anionic surfactant contains modified lignosulfonate, and the mass percent of the modified lignosulfonate in the liquid detergent is 0.1-2.5%.
2. A multichamber laundry bead as in claim 1 wherein said modified lignosulfonate is a carboxymethyl lignosulfonate, said carboxymethyl lignosulfonate being one or a combination of sodium, potassium, and ammonium carboxymethyl lignosulfonates.
3. A multi-cell laundry bead according to claim 1 or 2 wherein the carboxymethyl lignosulfonate has a molecular weight of 4000-7000, a sulfo content of 1-1.6mmol/g and a carboxyl content of 0.8-2 mmol/g.
4. A multi-chamber laundry bead according to claim 1 wherein the anionic surfactant is present in the liquid detergent at a level of from 35% to 55% by weight; the mass percent of the nonionic surfactant in the liquid detergent is 15-30%.
5. A multi-chamber laundry bead according to claim 1 wherein the anionic surfactant further comprises fatty acid monoethanolamine salt and/or alkylbenzene sulfonic acid monoethanolamine salt; the nonionic surfactant comprises fatty alcohol-polyoxyethylene ether.
6. A multi-cell laundry bead according to claim 1 wherein the solvent is present in the liquid detergent in an amount of from 5 to 25% by weight.
7. A multi-chamber laundry bead according to claim 6 wherein said solvent comprises one or a combination of propylene glycol, glycerin, PEG400, ethylene glycol.
8. A multi-chamber laundry bead according to claim 1 wherein the softening detergent comprises the following components in mass percent: 25-40% of oleic acid monoethanolamine salt, 4-12% of hydrogenated castor oil, 10-20% of palm kernel oil monoethanolamine, 4-8% of dioctadecyl dimethyl ammonium chloride, 0.4-1% of stearic acid, 8-20% of glycerol and 5-15% of polyethylene glycol.
9. A multi-cell laundry bead according to claim 8 wherein said softening detergent further comprises perfumes and colorants.
10. A multi-chamber laundry bead according to claim 1 wherein the liquid detergent and softening detergent are present in a mass percentage of 3.5-2: 1.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100075878A1 (en) * | 2008-09-19 | 2010-03-25 | The Procter & Gamble Company | Modified Lignin Biopolymer Useful in Cleaning Compositions |
| CN103562370A (en) * | 2011-05-26 | 2014-02-05 | 荷兰联合利华有限公司 | Liquid laundry composition |
| CN206624198U (en) * | 2017-03-29 | 2017-11-10 | 余姚市德派日用品有限公司 | The solidifying pearl of one kind laundry |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100075878A1 (en) * | 2008-09-19 | 2010-03-25 | The Procter & Gamble Company | Modified Lignin Biopolymer Useful in Cleaning Compositions |
| CN103562370A (en) * | 2011-05-26 | 2014-02-05 | 荷兰联合利华有限公司 | Liquid laundry composition |
| CN206624198U (en) * | 2017-03-29 | 2017-11-10 | 余姚市德派日用品有限公司 | The solidifying pearl of one kind laundry |
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