CN114656869B - Wind power tower finish paint containing indium chloride coated carbon nanofibers and preparation method and use method thereof - Google Patents

Wind power tower finish paint containing indium chloride coated carbon nanofibers and preparation method and use method thereof Download PDF

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CN114656869B
CN114656869B CN202210417511.8A CN202210417511A CN114656869B CN 114656869 B CN114656869 B CN 114656869B CN 202210417511 A CN202210417511 A CN 202210417511A CN 114656869 B CN114656869 B CN 114656869B
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indium chloride
wind power
chloride coated
coated carbon
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CN114656869A (en
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李太江
李巍
李聚涛
娄正计
周昊
李生文
杨强斌
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Xian Thermal Power Research Institute Co Ltd
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Xian Thermal Power Research Institute Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/70Wind energy
    • Y02E10/72Wind turbines with rotation axis in wind direction

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a wind power tower finish paint containing indium chloride coated carbon nanofibers, and a preparation method and a use method thereof, and belongs to the technical field of erosion resistance of offshore wind power preservatives. On the basis of the traditional finish paint coating, the high-toughness carbon nanofibers are added based on a fiber toughening mechanism, so that the toughness of the finish paint is improved, the erosion resistance of the paint layer is also obviously improved, and the protective paint layer is more suitable for the erosion resistance protection of an ocean wind turbine generator compared with the traditional protective paint layer. Furthermore, the nano carbon fiber is coated with non-conductive indium chloride on the surface by a physical vapor deposition method, so that the reduction of the corrosion resistance of the paint layer due to the addition of the conductive carbon fiber is avoided. The preparation method is simple and convenient, the raw materials are easy to obtain, and the prepared surface paint film has the characteristics of high toughness, high adhesive force, erosion resistance and corrosion resistance, and can remarkably prolong the safe service life of the paint film in sea wave impact environments such as a wind power tower splashing area.

Description

Wind power tower finish paint containing indium chloride coated carbon nanofibers and preparation method and application method thereof
Technical Field
The invention belongs to the technical field of offshore wind power electric erosion protection, and particularly relates to a wind power tower finish paint containing indium chloride coated carbon nanofibers, and a preparation method and a use method thereof.
Background
Sea wind has the advantages of abundance, stability, high power generation efficiency and the like, but because the salt content of the sea atmosphere is high and the humidity is high, the sea wind power generation system has high requirements on the erosion resistance of the sea wind power generation set. The service environments of the offshore wind turbine generator are mainly divided into five types: atmospheric zone, splash zone, tidal range zone, full immersion zone, sea mud zone. The splash zone is generally an area 0-2 meters above sea level, which is an area where sea waves can splash and are not submerged by sea water when the sea water rises. The splash zone is affected by the corrosive environment of the ocean atmospheric region, and is also affected by wetting and impact of splash sea waves, and dry and wet are frequently alternated, so that the area which is most easily subjected to coating stripping failure due to erosion is formed.
At present, the offshore wind turbine generator mainly depends on high polymer coatings such as resin and the like, and anti-erosion protection is realized in a mode of partially assisting in sacrificing an anode, so that the purpose of prolonging the service life of the offshore wind turbine generator is achieved. Although the traditional resin-based polymer coating has good flexibility and corrosion resistance, the erosion resistance of the traditional resin-based polymer coating is low due to the characteristics of the traditional resin-based polymer coating. Particularly, the polymer coating mainly made of resin is easy to crack and peel under the influence of severe environments such as sea wave impact in a splashing area and the like, so that the protection effect and service life of the coating are greatly reduced, and the anti-erosion protection cost of the wind turbine generator is increased.
Disclosure of Invention
In order to solve the problems, the invention discloses a wind power tower finish containing indium chloride coated carbon nanofibers, and a preparation method and a use method thereof.
The invention is realized by the following technical scheme:
the invention discloses a wind power tower finish paint containing indium chloride coated carbon nanofibers, which comprises the following raw materials in parts by mass:
50-60 parts of resin, 3-5 parts of dispersant, 5-7 parts of fumed silica, 2-3 parts of flatting agent, 2-3 parts of drier, 2-4 parts of light stabilizer, 5-15 parts of indium chloride coated carbon nanofiber, 0.5-2 parts of humectant and 0.1-1 part of o-benzoylsulfimide.
Preferably, the resin is polyurethane resin, the dispersing agent is acrylate, the flatting agent is fluorine modified acrylate, the drier is organic tin drier T-12, the light stabilizer is a compound of aniline oxalic acid light absorber and hindered amine light stabilizer, and the moistening agent is dibutyl phthalate or sodium dodecyl diphenyl ether disulfonate.
Further preferably, in the light stabilizer, the mass ratio of the aniline oxalic acid light absorber to the hindered amine light stabilizer is 1.
Preferably, the indium chloride-coated filamentous nanocarbon has a diameter of 100 to 700nm and a length of 10 to 30 μm.
Preferably, the indium chloride-coated filamentous nanocarbon is prepared by coating the carbon nanofibers with indium chloride by a physical vapor deposition method.
The invention discloses a preparation method of wind power tower finish paint containing indium chloride coated carbon nanofibers, which comprises the following steps:
fully and uniformly stirring 50-60 parts of resin, 5-15 parts of indium chloride coated carbon nanofibers, 0.5-2 parts of a humectant, 3-5 parts of a dispersant and 5-7 parts of fumed silica;
step 2: on the basis of the mixed system obtained in the step 1, adding 2-3 parts of flatting agent, 2-3 parts of drier, 0.1-1 part of o-benzoylsulfimide and 2-4 parts of light stabilizer while stirring, fully stirring until the mixture is completely and uniformly dispersed, and standing and defoaming to obtain wind power tower finish paint containing indium chloride coated carbon nanofibers;
the dosage parts are all parts by mass.
Preferably, in step 1, the stirring speed is 550-600rpm and the time is 20-35min.
Preferably, in step 2, the stirring speed is 550-600rpm, and after all the components are added, the stirring is continued for 10-25 minutes.
The invention discloses a using method of wind power tower finish paint containing indium chloride coated carbon nanofibers, which is prepared by the preparation method, wherein when the wind power tower finish paint containing the indium chloride coated carbon nanofibers is used, 30-40 parts of polyether polyol serving as a curing agent is added, a diluent is added after the polyether polyol is uniformly mixed to adjust the viscosity to the required viscosity, and the mixture is uniformly coated on the surface of a workpiece through spraying, roll coating or brush coating.
Preferably, the dry film thickness of the finish coat after coating is 100 to 150 μm.
Compared with the prior art, the invention has the following beneficial technical effects:
the wind power tower finish paint containing the indium chloride coated carbon nanofibers, disclosed by the invention, is added with the high-toughness carbon nanofibers on the basis of a traditional finish paint coating based on a fiber toughening mechanism, so that the toughness of the finish paint can be improved, the erosion resistance of a paint layer can be obviously improved, and the wind power tower finish paint is more suitable for the erosion resistance protection of an ocean wind power unit compared with a traditional protective paint layer. Furthermore, the surface of the carbon fiber is coated with a layer of non-conductive indium chloride by a physical vapor deposition method, so that the corrosion resistance of the paint layer is prevented from being reduced due to the addition of the conductive carbon fiber. Meanwhile, the invention improves the binding force between the carbon nanofibers and the matrix by adding the moistening agent, and ensures the realization of excellent performance of the toughening agent. Finally, the stress removing agent o-benzoylsulfimide is added into the finish paint, so that the problem that the stress of a paint film is increased possibly due to the addition of the carbon nanofibers is solved. Therefore, under the combined action of the non-conductive indium chloride coated carbon nanofiber toughening agent, the moistening agent, the stress removing agent and the like, the prepared finish paint has the characteristics of excellent toughness, high adhesive force, erosion resistance and abrasion resistance, and can play an excellent erosion-resistant protection effect in severe marine environments such as a splashing area.
The preparation method and the use method of the wind power tower finish paint containing the indium chloride coated carbon nanofibers are simple and convenient to operate and convenient to use on site.
Detailed Description
The present invention will now be described in further detail with reference to specific examples, which are intended to be illustrative, but not limiting, of the invention. Unless otherwise specified, the parts referred to in the examples are in parts by mass.
Example 1
The paint film of the embodiment comprises the following components: 50 parts of polyurethane; 5 parts of indium chloride coated carbon nanofiber; 3 parts of acrylic ester; 5 parts of fumed silica; 2 parts of fluorine modified acrylate; 2 parts of T-12 organic tin drier; 2 parts of aniline oxalic acid light absorbent and hindered amine light stabilizer compound (compounded according to the mass ratio of 1; 0.5 part of dibutyl phthalate; 0.1 part of o-benzoylsulfonyl imide; 30 parts of polyether polyol.
Step 1: adding 50 parts of polyurethane into a clean container, stirring at a stirring speed of 600rpm while adding 5 parts of indium chloride coated carbon nanofibers, 0.5 part of dibutyl phthalate, 3 parts of acrylate and 5 parts of fumed silica, and continuously stirring at the stirring speed of 600rpm for 20 minutes after all reagents are added;
step 2: 2 parts of fluorine modified acrylate, 2 parts of organic tin drier T-12, 0.1 part of o-benzoylsulfimide, 2 parts of aniline oxalic acid light absorber and hindered amine light stabilizer compound are added into the slurry obtained in the step 1 at a stirring speed of 550rpm while stirring. After all the reagents are added, continuously stirring for 20min at the stirring speed of 550rpm, and standing until bubbles completely disappear;
and step 3: and (3) adding 30 parts of polyether polyol into the slurry prepared in the step (2), uniformly mixing, and then adjusting the slurry to a proper viscosity.
And 4, step 4: and (4) spraying the slurry obtained in the step (3) on a low-carbon steel plate.
And 5: and (3) standing and airing the test piece obtained in the step (4) at room temperature, wherein the results of various technical indexes are shown in table 1.
Example 2
The paint film of the embodiment comprises the following components: 53 parts of polyurethane; 10 parts of indium chloride coated carbon nanofiber; 4 parts of acrylic ester; 6 parts of fumed silica; 2.5 parts of fluorine modified acrylate; 3 parts of T-12 organic tin drier; 3 parts of an aniline oxalic acid light absorbent and hindered amine light stabilizer compound (compounded according to a mass ratio of 1; 1 part of dibutyl phthalate; 0.6 part of o-benzoylsulfonyl imide; 35 parts of polyether polyol.
Step 1: adding 53 parts of polyurethane into a clean container, stirring at a stirring speed of 600rpm while adding 10 parts of indium chloride coated carbon nanofibers, 1 part of dibutyl phthalate, 4 parts of acrylate and 6 parts of fumed silica, and continuing stirring at a stirring speed of 600rpm for 20 minutes after all reagents are added;
step 2: 2.5 parts of fluorine modified acrylate, 3 parts of organic tin drier T-12, 0.6 part of o-benzoylsulfonimide, 3 parts of aniline oxalic acid light absorber and hindered amine light stabilizer compound are added into the slurry obtained in the step 1 at a stirring speed of 550rpm while stirring. Stirring for 20min after all reagents are added, and standing until bubbles completely disappear;
and step 3: and (3) adding 35 parts of polyether polyol into the slurry prepared in the step (2), uniformly mixing, and then adjusting the slurry to a proper viscosity.
And 4, step 4: and (4) spraying the slurry obtained in the step (3) on a low-carbon steel plate.
And 5: and (4) standing and airing the test piece obtained in the step (4) at room temperature, wherein the results of various technical indexes are shown in a table 2.
Example 3
The paint film of the embodiment comprises the following components: 55 parts of polyurethane; 12 parts of indium chloride coated carbon nanofiber; 4 parts of acrylic ester; 6 parts of fumed silica; 2.5 parts of fluorine modified acrylate; 3 parts of T-12 organic tin drier; 3 parts of an aniline oxalic acid absorbent and hindered amine light stabilizer compound (compounded according to the mass ratio of 1; 1 part of dibutyl phthalate; 0.6 part of o-benzoylsulfonyl imide; 35 parts of polyether polyol.
Step 1: adding 55 parts of polyurethane into a clean container, adding 12 parts of indium chloride coated carbon nanofibers, 1 part of dibutyl phthalate, 4 parts of acrylate and 6 parts of fumed silica while stirring at a stirring speed of 600rpm, and continuously stirring at the stirring speed of 600rpm for 20 minutes after all reagents are added;
step 2: 2.5 parts of fluorine modified acrylate, 3 parts of organic tin drier T-12, 0.6 part of o-benzoylsulfonimide, 3 parts of aniline oxalic acid light absorber and hindered amine light stabilizer compound are added into the slurry obtained in the step 1 at a stirring speed of 550rpm while stirring. Stirring at a stirring speed of 550rpm for 20min after all the reagents are added, and standing until bubbles completely disappear;
and step 3: and (3) adding 35 parts of polyether polyol into the slurry prepared in the step (2), uniformly mixing, and then adjusting the slurry to a proper viscosity.
And 4, step 4: and (4) spraying the slurry obtained in the step (3) on a low-carbon steel plate.
And 5: and (3) standing and airing the test piece obtained in the step (4) at room temperature, wherein the results of various technical indexes are shown in a table 3.
Example 4
The paint film of the embodiment comprises the following components: 55 parts of polyurethane; 12 parts of indium chloride coated carbon nanofiber; 4 parts of acrylic ester; 6 parts of fumed silica; 2.5 parts of fluorine modified acrylate; 3 parts of T-12 organic tin drier; 3 parts of an aniline oxalic acid light absorbent and hindered amine light stabilizer compound (compounded according to a mass ratio of 1; 1 part of dibutyl phthalate; 0.6 part of o-benzoylsulfonyl imide; 35 parts of polyether polyol.
Step 1: adding 55 parts of polyurethane into a clean container, stirring at a stirring speed of 550rpm while adding 12 parts of indium chloride coated carbon nanofibers, 1 part of dibutyl phthalate, 4 parts of acrylate and 6 parts of fumed silica, and continuing stirring for 30 minutes after all reagents are added;
step 2: 2.5 parts of fluorine modified acrylate, 3 parts of organic tin drier T-12, 0.6 part of o-benzoylsulfonimide, 3 parts of aniline oxalic acid light absorber and hindered amine light stabilizer compound are added into the slurry obtained in the step 1 at a stirring speed of 550rpm while stirring. Adding all reagents, stirring for 25min, and standing until bubbles completely disappear;
and step 3: and (3) adding 35 parts of polyether polyol into the slurry prepared in the step (2), uniformly mixing, and then adjusting the slurry to a proper viscosity.
And 4, step 4: and (4) spraying the slurry obtained in the step (3) on a low-carbon steel plate.
And 5: and (4) standing and airing the test piece obtained in the step (4) at room temperature, wherein the results of various technical indexes are shown in a table 4.
Example 5
The paint film of the embodiment comprises the following components: 60 parts of polyurethane; 10 parts of indium chloride coated carbon nanofiber; 4 parts of acrylic ester; 6 parts of fumed silica; 2.5 parts of fluorine modified acrylate; 3 parts of T-12 organic tin drier; 3 parts of an aniline oxalic acid light absorbent and hindered amine light stabilizer compound (compounded according to a mass ratio of 1; 1 part of dibutyl phthalate; 0.6 part of o-benzoylsulfonyl imide; 35 parts of polyether polyol.
Step 1: adding 60 parts of polyurethane into a clean container, stirring at a stirring speed of 600rpm while adding 10 parts of indium chloride coated carbon nanofiber, 1 part of dibutyl phthalate, 4 parts of acrylate and 6 parts of fumed silica, and continuously stirring at the stirring speed of 600rpm for 20 minutes after all reagents are added;
step 2: 2.5 parts of fluorine modified acrylate, 3 parts of organic tin drier T-12, 0.6 part of o-benzoylsulfimide and 3 parts of aniline oxalic acid light absorber and hindered amine light stabilizer compound are added into the slurry obtained in the step 1 at a stirring speed of 550rpm while stirring. Stirring at a stirring speed of 550rpm for 20min after all the reagents are added, and standing until bubbles completely disappear;
and 3, step 3: and (3) adding 35 parts of polyether polyol into the slurry prepared in the step (2), uniformly mixing, and then adjusting the slurry to a proper viscosity.
And 4, step 4: and (4) spraying the slurry obtained in the step (3) on a low-carbon steel plate.
And 5: and (3) standing and airing the test piece obtained in the step (4) at room temperature, wherein the results of various technical indexes are shown in a table 5.
TABLE 1
Serial number Item Technical index Results Standard of reference
1 Appearance of the product Normal appearance Normal appearance GB/T 1766-2008
2 Impact resistance 50cm 80cm GB/T1732-2020
3 Adhesion force ≥5MPa 9.7MPa GB/T 31817-2015
4 Flexibility 2mm 2mm GB/T6742-2007
TABLE 2
Serial number Item Technical index Results Standard of merit
1 Appearance of the product Normal appearance Normal appearance GB/T 1766-2008
2 Impact resistance 50cm 90cm GB/T1732-2020
3 Adhesion force ≥5MPa 9.4MPa GB/T 31817-2015
4 Flexibility 2mm 2mm GB/T6742-2007
TABLE 3
Serial number Item Technical index Results Standard of reference
1 Appearance of the product Normal appearance Normal appearance GB/T 1766-2008
2 Impact resistance 50cm 100cm GB/T1732-2020
3 Adhesion force ≥5MPa 9.9MPa GB/T 31817-2015
4 Flexibility 2mm 2mm GB/T6742-2007
TABLE 4
Serial number Item Technical index As a result, the Standard of merit
1 Appearance of the product The appearance is positiveOften times Normal appearance GB/T 1766-2008
2 Impact resistance 50cm 95cm GB/T1732-2020
3 Adhesion force ≥5MPa 9.5MPa GB/T 31817-2015
4 Flexibility 2mm 2mm GB/T6742-2007
TABLE 5
Serial number Item Technical index Results Standard of merit
1 Appearance of the product Normal appearance Normal appearance GB/T 1766-2008
2 Impact resistance 50cm 90cm GB/T1732-2020
3 Adhesion force ≥5MPa 9.0MPa GB/T 31817-2015
4 Flexibility of the film 2mm 2mm GB/T6742-2007
The results show that the anti-corrosion and impact-resistant finish paint prepared according to the component proportion has the performances of high toughness, high impact resistance, high bonding strength and the like, and can meet the requirements of severe environments such as a splashing area and the like on the long service life and the long maintenance period of a paint film surface layer.
It should be noted that the above description is only a part of the embodiments of the present invention, and equivalent changes made to the system described in the present invention are included in the protection scope of the present invention. Persons skilled in the art to which this invention pertains may substitute similar alternatives for the specific embodiments described, all without departing from the scope of the invention as defined by the claims.

Claims (8)

1. The wind power tower finish paint containing indium chloride coated carbon nanofibers is characterized by comprising the following raw materials in parts by mass:
50-60 parts of resin, 3-5 parts of dispersant, 5-7 parts of fumed silica, 2-3 parts of flatting agent, 2-3 parts of drier, 2-4 parts of light stabilizer, 5-15 parts of indium chloride coated carbon nanofiber, 0.5-2 parts of humectant and 0.1-1 part of o-benzoylsulfimide;
the preparation method comprises the following steps:
step 1: fully and uniformly stirring 50-60 parts of resin, 5-15 parts of indium chloride coated carbon nanofibers, 0.5-2 parts of a moistening agent, 3-5 parts of a dispersing agent and 5-7 parts of fumed silica;
step 2: on the basis of the mixed system obtained in the step 1, adding 2-3 parts of a flatting agent, 2-3 parts of a drier, 0.1-1 part of o-benzoylsulfimide and 2-4 parts of a light stabilizer while stirring, fully stirring until the materials are completely and uniformly dispersed, and standing and defoaming to obtain a wind power tower finish containing indium chloride coated carbon nanofibers;
the resin is polyurethane resin, the dispersing agent is acrylate, the flatting agent is fluorine modified acrylate, the drier is organic tin drier T-12, the light stabilizer is a compound of aniline oxalic acid light absorbent and hindered amine light stabilizer, and the humectant is dibutyl phthalate or sodium dodecyl diphenyl ether disulfonate; the diameter of the indium chloride coated carbon nanofiber is 100-700 nm, and the length of the indium chloride coated carbon nanofiber is 10-30 mu m.
2. The wind power tower finish paint containing the indium chloride coated carbon nanofibers according to claim 1, wherein the mass ratio of the aniline oxalic acid light absorber to the hindered amine light stabilizer in the light stabilizer is 1.
3. The wind power tower finish paint containing the indium chloride coated nano carbon fiber as claimed in claim 1, wherein the indium chloride coated nano carbon fiber is prepared by coating indium chloride on the nano carbon fiber by a physical vapor deposition method.
4. The preparation method of the wind power tower finish paint containing the indium chloride coated carbon nanofibers as claimed in any one of claims 1 to 3, is characterized by comprising the following steps:
step 1: fully and uniformly stirring 50-60 parts of resin, 5-15 parts of indium chloride coated carbon nanofibers, 0.5-2 parts of a humectant, 3-5 parts of a dispersant and 5-7 parts of fumed silica;
step 2: on the basis of the mixed system obtained in the step 1, adding 2-3 parts of a flatting agent, 2-3 parts of a drier, 0.1-1 part of o-benzoylsulfimide and 2-4 parts of a light stabilizer while stirring, fully stirring until the materials are completely and uniformly dispersed, and standing and defoaming to obtain a wind power tower finish containing indium chloride coated carbon nanofibers;
the dosage parts are all parts by mass.
5. The method for preparing the wind power tower finish paint containing the indium chloride coated nano carbon fibers as claimed in claim 4, wherein in the step 1, the stirring speed is 550-600rpm, and the stirring time is 20-35min.
6. The method for preparing the wind power tower finish paint containing the indium chloride coated carbon nanofibers according to claim 4, wherein in step 2, the stirring speed is 550-600rpm, and after all components are added, the stirring is continued for 10-25 minutes.
7. The use method of the wind power tower finish paint containing the indium chloride coated carbon nanofibers prepared by the preparation method according to any one of claims 4 to 6 is characterized in that when the prepared wind power tower finish paint containing the indium chloride coated carbon nanofibers is used, 30-40 parts of polyether polyol serving as a curing agent is added, a diluent is added after the polyether polyol is uniformly mixed to adjust the viscosity to a required value, and the mixture is uniformly coated on the surface of a workpiece through spraying, roll coating or brush coating.
8. The use method of the wind power tower finish paint containing the indium chloride coated carbon nanofibers according to claim 7, wherein the dry film thickness of the finish paint coating after coating is 100-150 μm.
CN202210417511.8A 2022-04-20 2022-04-20 Wind power tower finish paint containing indium chloride coated carbon nanofibers and preparation method and use method thereof Active CN114656869B (en)

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CN109679474A (en) * 2018-12-19 2019-04-26 长春安旨科技有限公司 A kind of low viscosity wind electricity blade polyurethane material
CN111391446A (en) * 2020-04-13 2020-07-10 江苏道蓬科技有限公司 High-toughness corrosion-resistant marine anticorrosive composite coating and preparation method thereof
CN111850534B (en) * 2020-06-16 2022-03-01 中国石油天然气集团有限公司 Martensite stainless steel oil pipe low-stress pre-passivation film and preparation method thereof
CN112662299A (en) * 2020-12-22 2021-04-16 苏州禾川化学技术服务有限公司 Ship anticorrosive paint capable of preventing microbial adsorption
CN112712944B (en) * 2020-12-24 2022-04-08 武汉肯达科讯科技有限公司 High-thermal-conductivity insulating gasket and preparation method thereof

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