CN114602266A - Temporary direct-discharge treatment system and process for tail gas of tar distillation device - Google Patents

Temporary direct-discharge treatment system and process for tail gas of tar distillation device Download PDF

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Publication number
CN114602266A
CN114602266A CN202210213558.2A CN202210213558A CN114602266A CN 114602266 A CN114602266 A CN 114602266A CN 202210213558 A CN202210213558 A CN 202210213558A CN 114602266 A CN114602266 A CN 114602266A
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tail gas
nitrogen
sealed
gas
temporary
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CN202210213558.2A
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Chinese (zh)
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杨雪松
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Acre Coking and Refractory Engineering Consulting Corp MCC
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Acre Coking and Refractory Engineering Consulting Corp MCC
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Priority to CN202210213558.2A priority Critical patent/CN114602266A/en
Publication of CN114602266A publication Critical patent/CN114602266A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10CWORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C1/00Working-up tar
    • C10C1/04Working-up tar by distillation
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004Gaseous mixtures, e.g. polluted air
    • G01N33/0009General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0036General constructional details of gas analysers, e.g. portable test equipment concerning the detector specially adapted to detect a particular component

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Food Science & Technology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The invention relates to a temporary direct exhaust treatment system and process for tail gas of a tar distillation device, wherein a tail gas outlet of the tar distillation device is connected with a gas suction pipeline or an incineration system through a nitrogen-sealed tail gas main pipe, and a tail gas induced draft fan and a buffer tank are arranged on the nitrogen-sealed tail gas main pipe; the temporary direct exhaust treatment system for the tail gas comprises a temporary direct exhaust pipeline, an air cooler, a gas-liquid separator, a filtering unit and a chimney; a tail gas direct discharge outlet and a first electromagnetic valve are arranged on a nitrogen-sealed tail gas main pipe at the downstream of the buffer tank, one end of the temporary direct discharge pipeline is connected with the tail gas direct discharge outlet, and the other end of the temporary direct discharge pipeline is connected with a chimney; and the temporary direct drainage pipeline is provided with a second electromagnetic valve, an air cooler, a gas-liquid separator and a filtering unit. According to the invention, a temporary straight exhaust pipeline is led out from the nitrogen-sealed tail gas main pipe and is used for discharging the nitrogen-sealed tail gas after temporary treatment when the oxygen content exceeds a set value, and simultaneously, the oxygen content in the nitrogen-sealed tail gas is monitored on line, so that the purposes of safety and environmental protection are realized.

Description

Temporary direct-discharge treatment system and process for tail gas of tar distillation device
Technical Field
The invention relates to the technical field of coking, in particular to a system and a process for temporarily directly discharging tail gas of a tar distillation device.
Background
According to the recommendation of 'environmental protection design code for steel industry' (GB50406-2017), a negative pressure gas system introduction method is adopted for tail gas treatment of a tar distillation device, the method is characterized in that the diffused gas is recycled to a negative pressure gas pipeline by utilizing the suction force in front of an air blower of a gas purification device, the unorganized emission of the diffused gas is basically avoided, no secondary pollution is caused, benzene, ammonia and the like in the diffused gas can be recycled through the gas purification system, the diffused gas is changed into valuable, and the field environment is improved.
The specific implementation mode is as follows: the pressure balance type nitrogen seal sealing system is adopted in various oil depots, the middle tank area and the automobile loading and unloading station, the control system is in a micro-positive pressure state, nitrogen is supplemented when the pressure is lower than a set value, and nitrogen seal tail gas is discharged when the pressure is higher than the set value. The discharged nitrogen-sealed tail gas is collected into a nitrogen-sealed tail gas main pipe, and is pressurized by a tail gas draught fan and then is sent to a gas suction pipeline. If the condition of the suction gas pipeline is not sent, the gas can also be sent to the incineration system. Before the nitrogen-sealed tail gas is sent into a gas suction pipeline or an incineration system, the oxygen content in the nitrogen-sealed tail gas needs to be monitored, and under some extreme conditions, a large amount of air can be supplemented through a breather valve due to the fact that nitrogen is not supplemented timely. If the oxygen content in the nitrogen-sealed tail gas is higher than the set value, the nitrogen-sealed tail gas needs to be stopped from being sent out so as to avoid danger. At this time, the breather valve or the safety valve on various storage tanks and other equipment in the tar distillation device is about to be started for direct discharge, and the normal discharge of the nitrogen-sealed tail gas is resumed after the nitrogen is fully replaced, namely the oxygen content in the nitrogen-sealed tail gas is lower than a set value. The above direct discharging process can pollute the environment, and meanwhile, the oxygen content in the nitrogen-sealed tail gas after nitrogen replacement is not generally measured on line, and normal discharge can be restarted only after evaluation, so that potential safety hazards still exist.
Disclosure of Invention
The invention provides a system and a process for temporarily and directly discharging tail gas of a tar distillation device.
In order to achieve the purpose, the invention adopts the following technical scheme:
a temporary direct exhaust treatment system for tail gas of a tar distillation device is characterized in that a tail gas outlet of the tar distillation device is connected with a gas suction pipeline or an incineration system through a nitrogen-sealed tail gas main pipe, and a tail gas induced draft fan and a buffer tank are arranged on the nitrogen-sealed tail gas main pipe; the system is characterized in that the temporary direct exhaust treatment system of the tail gas comprises a temporary direct exhaust pipeline, an air cooler, a gas-liquid separator, a filtering unit and a chimney; a tail gas direct discharge outlet and a first electromagnetic valve are sequentially arranged on the nitrogen-sealed tail gas main pipe at the downstream of the buffer tank along the tail gas flowing direction, one end of the temporary direct discharge pipeline is connected with the tail gas direct discharge outlet, and the other end of the temporary direct discharge pipeline is connected with a chimney; and the temporary straight exhaust pipeline is sequentially provided with a second electromagnetic valve, an air cooler, a gas-liquid separator and a filtering unit along the tail gas flowing direction.
A pressure recording and adjusting instrument is arranged on a nitrogen seal tail gas main pipe at the upstream of the tail gas induced draft fan, the nitrogen seal tail gas main pipes at the two ends of the tail gas induced draft fan are connected through a parallel pipeline, and a pressure adjusting valve is arranged on the parallel pipeline; and the pressure regulating valve and the pressure recording regulating instrument are controlled in an interlocking manner.
An oxygen content on-line measuring instrument is arranged on the temporary straight exhaust pipeline at the upstream of the second electromagnetic valve, and the oxygen content on-line measuring instrument, the first electromagnetic valve and the second electromagnetic valve are controlled by a fan motor in the air cooler in an interlocking manner.
The filtering unit comprises a ceramic filter and an active carbon filter which are sequentially arranged along the flowing direction of the tail gas.
The ceramic filter is a ceramic filter element oil mist filter.
The ceramic filter sets up 2 in parallel, and one works and is equipped with to all be equipped with steam blowback regenerating unit, blowback steam outlet connection dashpot.
The air cooler is arranged at the highest position of the temporary straight-discharge pipeline.
And a condensate outlet at the bottom of the buffer tank and a condensate outlet at the bottom of the gas-liquid separator are respectively connected with the emptying tank.
A temporary direct-discharge treatment process for tail gas of a tar distillation device comprises the following steps:
1) the nitrogen-sealed tail gas collected by each unit of the tar distillation device is uniformly sent out by a nitrogen-sealed tail gas main pipe, is pressurized by a tail gas induced draft fan and is sent to a gas suction pipeline or an incineration system through a buffer tank; monitoring the oxygen content in the nitrogen-sealed tail gas through an oxygen content on-line measuring instrument, and closing the first electromagnetic valve in an interlocking manner when the oxygen content exceeds a set value;
2) opening a second electromagnetic valve while closing the first electromagnetic valve, enabling the nitrogen-sealed tail gas to enter a temporary straight exhaust pipeline, purifying the nitrogen-sealed waste gas through an air cooler, a gas-liquid separator, a ceramic filter and an activated carbon filter, and discharging the nitrogen-sealed waste gas through a chimney after the nitrogen-sealed waste gas reaches the standard;
3) when the oxygen content on-line measuring instrument monitors that the oxygen content in the nitrogen-sealed tail gas is lower than a set value, the second electromagnetic valve is closed in an interlocking mode, meanwhile, the first electromagnetic valve is opened, and the nitrogen-sealed tail gas is sent to a gas suction pipeline or an incineration system through the nitrogen-sealed tail gas main pipe again.
Compared with the prior art, the invention has the beneficial effects that:
1) a temporary straight exhaust pipeline is led out from the nitrogen-sealed tail gas main pipe and is used for discharging the nitrogen-sealed tail gas when the oxygen content exceeds a set value after temporary treatment, so that the direct exhaust pollution of a breather valve or a safety valve during starting is avoided;
2) the oxygen content of the nitrogen-sealed tail gas is monitored in real time by using an oxygen content on-line measuring instrument, and is controlled by being interlocked with the first electromagnetic valve and the second electromagnetic valve, so that the automatic switching between normal discharge (sending and sucking a gas pipeline or an incineration system) and temporary direct discharge (discharging from a chimney after being purified by an air cooler, a gas-liquid separator, a ceramic filter and an activated carbon filter) is realized.
Drawings
FIG. 1 is a schematic structural diagram of a temporary direct exhaust treatment system of the tail gas of the tar distillation device.
In the figure: 1. tail gas draught fan 2, buffer tank 3, air cooler 4, gas-liquid separator 5, gas-liquid separator 6, active carbon filter 7, chimney 8, pressure regulating valve 9, electromagnetic valve I10, electromagnetic valve II
PRC-01 pressure recording regulating instrument O2AS-01 oxygen content on-line measuring instrument M fan motor
Detailed Description
The following further describes embodiments of the present invention with reference to the accompanying drawings:
as shown in figure 1, the temporary direct exhaust treatment system for the tail gas of the tar distillation device is characterized in that a tail gas outlet of the tar distillation device is connected with a gas suction pipeline or an incineration system through a nitrogen-sealed tail gas main pipe, and a tail gas induced draft fan 1 and a buffer tank 2 are arranged on the nitrogen-sealed tail gas main pipe; the tail gas temporary direct-discharging treatment system comprises a temporary direct-discharging pipeline, an air cooler 3, a gas-liquid separator 4, a filtering unit and a chimney 7; a tail gas direct discharge outlet and a first electromagnetic valve 9 are sequentially arranged on the nitrogen-sealed tail gas main pipe at the downstream of the buffer tank 2 along the tail gas flowing direction, one end of the temporary direct discharge pipeline is connected with the tail gas direct discharge outlet, and the other end of the temporary direct discharge pipeline is connected with a chimney 7; the temporary straight exhaust pipeline is sequentially provided with a second electromagnetic valve 10, an air cooler 3, a gas-liquid separator 5 and a filtering unit 6 along the tail gas flowing direction.
A pressure recording and adjusting instrument PRC-01 is arranged on a nitrogen-sealed tail gas main pipe at the upstream of the tail gas draught fan 1, the nitrogen-sealed tail gas main pipes at the two ends of the tail gas draught fan 1 are connected through a parallel pipeline, and a pressure adjusting valve 8 is arranged on the parallel pipeline; the pressure regulating valve 8 is controlled in an interlocking manner with the pressure recording regulating instrument PRC-01.
An oxygen content on-line measuring instrument O2AS-01 is arranged on the temporary straight discharge pipeline at the upstream of the second electromagnetic valve 10, and the oxygen content on-line measuring instrument O2AS-01, the first electromagnetic valve 9, the second electromagnetic valve 10 and a fan motor M in the air cooler are controlled in an interlocking mode.
The filtering unit comprises a ceramic filter 5 and an active carbon filter 6 which are sequentially arranged along the flowing direction of the tail gas.
The ceramic filter 5 is a ceramic filter element oil mist filter.
The ceramic filter 5 is provided with 2 ceramic filters in parallel, one ceramic filter is provided with one steam back flushing regeneration device, and a back flushing steam outlet is connected with the buffer tank.
The air cooler 3 is arranged at the highest position of the temporary straight-discharge pipeline.
And a condensate outlet at the bottom of the buffer tank 2 and a condensate outlet at the bottom of the gas-liquid separator 4 are respectively connected with the emptying tank.
A temporary direct-discharge treatment process for tail gas of a tar distillation device comprises the following steps:
1) the nitrogen-sealed tail gas collected by each unit of the tar distillation device is uniformly sent out by a nitrogen-sealed tail gas main pipe, is pressurized by a tail gas induced draft fan 1 and then is sent to a gas suction pipeline or an incineration system through a buffer tank 2; monitoring the oxygen content in the nitrogen-sealed tail gas through an oxygen content on-line measuring instrument O2AS-01, and interlocking and closing the first electromagnetic valve 9 when the oxygen content exceeds a set value;
2) opening a second electromagnetic valve 10 while closing the first electromagnetic valve 9, enabling the nitrogen-sealed tail gas to enter a temporary straight exhaust pipeline, purifying the nitrogen-sealed waste gas through an air cooler 3, a gas-liquid separator 4, a ceramic filter 5 and an activated carbon filter 6, and discharging the nitrogen-sealed waste gas through a chimney 7 after the nitrogen-sealed waste gas reaches the standard;
3) when the oxygen content in the nitrogen-sealed tail gas is monitored by the oxygen content on-line measuring instrument O2AS-01 to be lower than a set value, the second electromagnetic valve 10 is closed in an interlocking manner, the first electromagnetic valve 9 is opened at the same time, and the nitrogen-sealed tail gas is sent to a gas suction pipeline or an incineration system through the nitrogen-sealed tail gas main pipe again.
In order to avoid environment pollution caused by direct discharge when breather valves or safety valves on various storage tanks and other equipment are started, a temporary straight discharge pipeline is led out from a nitrogen-sealed tail gas pipeline at the upstream of a first electromagnetic valve 9, and a second electromagnetic valve 10, an air cooler 3, a gas-liquid separator 4, a ceramic filter 5 and an active carbon filter 6 are sequentially arranged along the tail gas flowing direction and used for purifying nitrogen-sealed tail gas in an accident state and finally discharging the qualified nitrogen-sealed tail gas through a chimney 7.
And the second electromagnetic valve 10 is arranged at the upstream of the temporary straight exhaust pipeline and is interlocked with the oxygen content on-line measuring instrument O2AS-01, when the oxygen content in the nitrogen-sealed tail gas exceeds a set value, the first electromagnetic valve 9 is closed in an interlocking manner, and meanwhile, the second electromagnetic valve 10 is opened to introduce the nitrogen-sealed tail gas into the temporary straight exhaust pipeline.
And the air cooler 3 is arranged at the downstream of the second electromagnetic valve 10 and is positioned at the highest position of the temporary straight exhaust pipeline and used for cooling the nitrogen-sealed tail gas. Because the nitrogen-sealed tail gas main pipe is a accompanied pipeline, the temperature is higher, after the nitrogen-sealed tail gas main pipe is cooled by the air cooler 3, a part of condensable oil gas can be separated, and the load of subsequent purification equipment is reduced.
The gas-liquid separator 4 can adopt a horizontal buffer tank structure or a gas-liquid separation tank for separating gas and condensate, and the condensate is periodically sent to an emptying tank.
The ceramic filter 5 can adopt a ceramic filter element oil mist filter, and can effectively filter oil mist. Preferably 2 equipment is selected, one is working, the other is standby, the steam can be used for back flushing regeneration, and back flushing gas can be sent to the buffer tank 2.
The activated carbon filter 6 is used for finally removing fog drops in the tail gas and removing strong carcinogens such as benzopyrene and other condensable and non-condensable harmful gases.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (9)

1. A temporary direct exhaust treatment system for tail gas of a tar distillation device is characterized in that a tail gas outlet of the tar distillation device is connected with a gas suction pipeline or an incineration system through a nitrogen-sealed tail gas main pipe, and a tail gas induced draft fan and a buffer tank are arranged on the nitrogen-sealed tail gas main pipe; the system is characterized by comprising a temporary direct exhaust pipeline, an air cooler, a gas-liquid separator, a filtering unit and a chimney; a tail gas direct discharge outlet and a first electromagnetic valve are sequentially arranged on the nitrogen-sealed tail gas main pipe at the downstream of the buffer tank along the tail gas flowing direction, one end of the temporary direct discharge pipeline is connected with the tail gas direct discharge outlet, and the other end of the temporary direct discharge pipeline is connected with a chimney; and the temporary straight exhaust pipeline is sequentially provided with a second electromagnetic valve, an air cooler, a gas-liquid separator and a filtering unit along the tail gas flowing direction.
2. The temporary direct exhaust treatment system for tail gas of the tar distillation device according to claim 1, wherein a pressure recording and adjusting instrument is arranged on a nitrogen-sealed tail gas main pipe at the upstream of a tail gas induced draft fan, the nitrogen-sealed tail gas main pipes at two ends of the tail gas induced draft fan are connected through parallel pipes, and a pressure adjusting valve is arranged on the parallel pipes; and the pressure regulating valve and the pressure recording regulating instrument are controlled in an interlocking manner.
3. The temporary direct exhaust treatment system for tail gas of the tar distillation device as claimed in claim 1, wherein an online oxygen content measuring instrument is installed on the temporary direct exhaust pipeline at the upstream of the second electromagnetic valve, and the online oxygen content measuring instrument, the first electromagnetic valve and the second electromagnetic valve are interlocked with a fan motor in the air cooler for control.
4. The system of claim 1, wherein the filtering unit comprises a ceramic filter and an activated carbon filter sequentially arranged along the flowing direction of the tail gas.
5. The system of claim 4, wherein the ceramic filter is a ceramic filter element oil mist filter.
6. The temporary direct exhaust treatment system for tail gas of tar distillation device as claimed in claim 4, wherein the ceramic filter is connected in parallel with 2 filter units, one filter unit and one spare filter unit, and each filter unit is provided with a steam back-blowing regeneration device, and the back-blowing steam outlet is connected with the buffer tank.
7. The system of claim 1, wherein the air cooler is disposed at the highest position of the temporary straight pipeline.
8. The temporary direct exhaust treatment system for tail gas of tar distillation device as claimed in claim 1, wherein the condensate outlet at the bottom of the buffer tank and the condensate outlet at the bottom of the gas-liquid separator are connected to the emptying tank respectively.
9. The temporary direct-discharge treatment process of the tail gas of the tar distillation device based on the system of any one of claims 1 to 8, characterized by comprising the following steps:
1) the nitrogen-sealed tail gas collected by each unit of the tar distillation device is uniformly sent out by a nitrogen-sealed tail gas main pipe, is pressurized by a tail gas induced draft fan and is sent to a gas suction pipeline or an incineration system through a buffer tank; monitoring the oxygen content in the nitrogen-sealed tail gas through an oxygen content on-line measuring instrument, and closing the first electromagnetic valve in an interlocking manner when the oxygen content exceeds a set value;
2) opening a second electromagnetic valve while closing the first electromagnetic valve, enabling the nitrogen-sealed tail gas to enter a temporary straight exhaust pipeline, purifying the nitrogen-sealed waste gas through an air cooler, a gas-liquid separator, a ceramic filter and an activated carbon filter, and discharging the nitrogen-sealed waste gas through a chimney after the nitrogen-sealed waste gas reaches the standard;
3) when the oxygen content on-line measuring instrument monitors that the oxygen content in the nitrogen-sealed tail gas is lower than a set value, the electromagnetic valve II is closed in an interlocking manner, meanwhile, the electromagnetic valve I is opened, and the nitrogen-sealed tail gas is sent to a gas suction pipeline or an incineration system through the nitrogen-sealed tail gas main pipe again.
CN202210213558.2A 2022-03-04 2022-03-04 Temporary direct-discharge treatment system and process for tail gas of tar distillation device Pending CN114602266A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201807289U (en) * 2010-12-10 2011-04-27 河南尚宇新能源股份有限公司 Guiding device for recovered trichlorosilane tail gas
CN109609219A (en) * 2019-01-17 2019-04-12 青岛华世洁环保科技有限公司 A kind of coking method for treating tail gas and device
CN111298550A (en) * 2020-02-27 2020-06-19 萍乡市华星环保工程技术有限公司 VOCs tail gas treatment method
CN111957165A (en) * 2020-09-04 2020-11-20 中冶焦耐(大连)工程技术有限公司 Tail gas treatment process and system for kettle type heating modified asphalt reaction kettle
CN217220700U (en) * 2022-03-04 2022-08-19 中冶焦耐(大连)工程技术有限公司 Temporary direct-discharge treatment system for tail gas of tar distillation device

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201807289U (en) * 2010-12-10 2011-04-27 河南尚宇新能源股份有限公司 Guiding device for recovered trichlorosilane tail gas
CN109609219A (en) * 2019-01-17 2019-04-12 青岛华世洁环保科技有限公司 A kind of coking method for treating tail gas and device
CN111298550A (en) * 2020-02-27 2020-06-19 萍乡市华星环保工程技术有限公司 VOCs tail gas treatment method
CN111957165A (en) * 2020-09-04 2020-11-20 中冶焦耐(大连)工程技术有限公司 Tail gas treatment process and system for kettle type heating modified asphalt reaction kettle
CN217220700U (en) * 2022-03-04 2022-08-19 中冶焦耐(大连)工程技术有限公司 Temporary direct-discharge treatment system for tail gas of tar distillation device

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