CN114593358A - Method and device for energy storage production by coupling with air separation device - Google Patents

Method and device for energy storage production by coupling with air separation device Download PDF

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Publication number
CN114593358A
CN114593358A CN202210074507.6A CN202210074507A CN114593358A CN 114593358 A CN114593358 A CN 114593358A CN 202210074507 A CN202210074507 A CN 202210074507A CN 114593358 A CN114593358 A CN 114593358A
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China
Prior art keywords
air separation
liquid nitrogen
liquid
liquid oxygen
pipeline
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Pending
Application number
CN202210074507.6A
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Chinese (zh)
Inventor
翟晖
顾燕新
文顺清
叶婧柔
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Hangzhou Oxygen Plant Group Co Ltd
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Hangzhou Oxygen Plant Group Co Ltd
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Priority to CN202210074507.6A priority Critical patent/CN114593358A/en
Publication of CN114593358A publication Critical patent/CN114593358A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C5/00Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C13/00Details of vessels or of the filling or discharging of vessels
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17DPIPE-LINE SYSTEMS; PIPE-LINES
    • F17D1/00Pipe-line systems
    • F17D1/08Pipe-line systems for liquids or viscous products
    • F17D1/082Pipe-line systems for liquids or viscous products for cold fluids, e.g. liquefied gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17DPIPE-LINE SYSTEMS; PIPE-LINES
    • F17D3/00Arrangements for supervising or controlling working operations
    • F17D3/01Arrangements for supervising or controlling working operations for controlling, signalling, or supervising the conveyance of a product
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E70/00Other energy conversion or management systems reducing GHG emissions
    • Y02E70/30Systems combining energy storage with energy generation of non-fossil origin

Abstract

The invention discloses a method and a device for coupling energy storage production with an air separation device, wherein the air separation device is connected with a liquid nitrogen storage tank through a liquid nitrogen pipeline, the air separation device is connected with a liquid oxygen storage tank through a liquid oxygen pipeline, the liquid nitrogen storage tank is connected with a liquid nitrogen pump through a liquid nitrogen pipeline, the liquid nitrogen pump is connected with the upper end of the air separation device through a liquid nitrogen pipeline, the liquid oxygen storage tank is connected with a liquid oxygen pump through a liquid oxygen pipeline, the liquid oxygen pump is connected with the middle end of the air separation device through a liquid oxygen pipeline, the use amount of high-price electric energy can be reduced, the electric energy generated by a power plant at night can be efficiently used, the waste of the electric energy is avoided, the resources are efficiently utilized, the production cost of a factory is also reduced, the liquid oxygen energy storage and release processes are converted by taking liquid nitrogen as a medium, and the running cost of the air separation device is reduced on the premise of not influencing the oxygen supply load of the air separation device, has obvious economic benefit.

Description

Method and device for energy storage production by coupling with air separation device
Technical Field
The invention relates to a production method and a device thereof, in particular to a method for energy storage production coupled with an air separation device and a device thereof, belonging to the field of air separation devices.
Background
With the development of the power structure of China towards green and low-carbon, the proportion of the installed capacity of non-fossil energy power generation such as wind, photoelectricity and the like is continuously improved. Because the supply of new energy such as wind, photoelectricity and the like is limited by natural conditions, active variable load production cannot be realized, and higher requirements are put forward on the consumption capability of a power grid. In order to reduce power grid fluctuation caused by time-space unevenness of generated energy and power consumption and improve the stability of a power grid, time-of-use electricity price policies are vigorously carried out in various places, and electric power price difference in peak-valley periods is continuously expanded.
The air separation device is an energy-consumption intensive production device which mainly consumes electric energy and produces industrial gases such as oxygen, nitrogen and the like on a large scale. The air separation device has certain variable load production capacity, and if the peak-to-peak production can be carried out by utilizing the time-of-use electricity price, the low-load production is carried out when the electricity price is high, and the high-load production is carried out when the electricity price is low, so that the production electricity cost can be greatly reduced. However, the air supply load of the air separation plant is restricted by the production requirements of downstream users, so that the production load of the air separation plant cannot be adjusted at will.
In addition to the characteristic of high transmission speed, electricity is the most important factor to be limited to the non-mass storage property. Electricity is storable, but not storable in large quantities. Because the storage equipment is necessarily very expensive if the storage equipment is stored in a large amount, the most obvious example is that the storage battery is very heavy, the stored electric quantity is limited, and if the storage battery is stored with more than one electric quantity generated by a power plant, huge resources are wasted, so that the production and the transmission of the electricity are required to be carried out simultaneously. However, the electricity generated by the power plant is usually planned in advance, is not changed at any time, is not constant, is changed and is short, and generally, the electricity is more used in the daytime and less used at night, so that the electricity generated at night is more than the electricity used, and a large amount of electricity is lost on a circuit or various power generation and transmission equipment, thereby causing resource waste.
Disclosure of Invention
In order to solve the problems in the prior art, the invention provides the device which is coupled with the air separation device for storing energy, has the technical characteristics of simple structure, energy conservation, high-efficiency utilization of night power resources, avoidance of waste of the night power resources and the like, and is used for solving the problems in the prior art.
The invention also aims to develop a brand new air separation process flow with energy storage and material recovery functions based on the characteristics of power generation of a power plant and the production status that the air separation unit supplies air and maintains stable load, so as to balance the power demand of a power grid, exploit the operation potential of the air separation unit and promote the function diversification of the air separation unit, and provide an air separation production method with energy storage and material recovery functions. The method realizes the energy storage and material recovery functions of the air separation device by arranging a liquid storage and back-flow conveying device on the basis of the gas air separation device. The gas air separation unit is an air separation unit mainly used for producing oxygen products.
In order to achieve the purpose, the invention is realized by the following technical scheme:
the utility model provides a carry out device that energy storage produced with air separation plant coupling, contains air separation plant, air separation plant has the liquid nitrogen storage tank through a liquid nitrogen tube coupling, air separation plant has the liquid oxygen storage tank through a liquid oxygen tube coupling, the liquid nitrogen storage tank has a liquid nitrogen pump through No. two liquid nitrogen tube couplings, No. one the upper end department at air separation plant through No. three liquid nitrogen tube couplings, the liquid oxygen storage tank has No. two liquid oxygen pumps through No. two liquid oxygen tube couplings, No. two liquid oxygen pumps are connected at air separation plant middle-end department through No. three liquid oxygen tube couplings.
Preferably, the third liquid oxygen pipeline and the first liquid oxygen pipeline are both connected to a main cooler in an upper tower of the air separation plant.
Preferably, the first liquid nitrogen pipeline and the third liquid nitrogen pipeline are both connected to an upper tower of the air separation plant, and the lower end of the air separation plant is a lower tower.
The invention relates to a production method for energy storage by coupling with an air separation device, which comprises the following steps:
during valley electricity, the production load of the air separation unit is improved, liquid nitrogen stored in a liquid nitrogen storage tank is poured into an upper tower of the air separation unit through a second liquid nitrogen pipeline and a third liquid nitrogen pipeline under the action of a first liquid nitrogen pump, the cold energy of the poured liquid nitrogen is utilized, main cold of the air separation unit can produce surplus liquid oxygen, the liquid oxygen is sent into a liquid oxygen storage tank through a first liquid oxygen pipeline to be stored, and the oxygen supply amount of the air separation unit is kept unchanged;
during off-peak electricity, the production load of the air separation unit is reduced, liquid oxygen produced during off-peak electricity and stored in a liquid oxygen storage tank is reversely poured to main cooling of the air separation unit through a second liquid oxygen pipeline and a third liquid oxygen pipeline under the action of a second liquid oxygen pump to supplement a gap of air separation oxygen supply amount, and the air separation unit can produce surplus liquid nitrogen by utilizing the cold energy of the reversely poured liquid oxygen and sends the liquid nitrogen into the liquid nitrogen storage tank through a first liquid nitrogen pipeline to be stored.
Has the advantages that: according to the liquid storage and reverse flow conveying device, low-price electric energy used due to load improvement during valley power is stored in a liquid oxygen mode, and the electric energy stored by the liquid oxygen is released during off-valley power, so that the use amount of the high-price electric energy is reduced, the electric energy generated by a power plant at night is efficiently used, the waste of the electric energy is avoided, the resources are efficiently utilized, and the production cost of a factory is also reduced; the liquid oxygen energy storage and release process is characterized in that liquid nitrogen is used as a medium for conversion, a small amount of liquid nitrogen products are lost in the conversion process, the operation cost of the air separation device is reduced on the premise of not influencing the air separation oxygen supply load, and the liquid oxygen energy storage and release process has remarkable economic benefit.
Drawings
FIG. 1 is a schematic flow diagram of the production of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the terms "upper", "lower", "inside", "outside", and the like indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, and are only for convenience in describing the present invention and simplifying the description, but do not indicate or imply that the device referred to must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention.
In the description of the present invention, it is to be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "disposed," "connected," and the like are to be construed broadly, such as "connected," which may be fixedly connected, detachably connected, or integrally connected; may be mechanically coupled or may be indirectly coupled through an intermediary. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Fig. 1 shows a specific embodiment of an apparatus coupled to an air separation plant for energy storage production, which includes an air separation plant, the air separation plant is connected to a liquid nitrogen storage tank 4 through a liquid nitrogen pipeline 16, the air separation plant is connected to a liquid oxygen storage tank 5 through a liquid oxygen pipeline 13, the liquid nitrogen storage tank 4 is connected to a liquid nitrogen pump 6 through a liquid nitrogen pipeline 11, the liquid nitrogen pump 6 is connected to the upper end of the air separation plant through a liquid nitrogen pipeline 12, the liquid oxygen storage tank 5 is connected to a liquid oxygen pump 7 through a liquid oxygen pipeline 14, and the liquid oxygen pump 7 is connected to the middle end of the air separation plant through a liquid oxygen pipeline 15. The gas air separation device can be an external compression flow path or an internal compression flow path, and the flow form and the scale are not limited.
In a preferred embodiment mode, the third liquid oxygen pipeline 15 and the first liquid oxygen pipeline 13 are connected to a main cooler 2 in an upper tower of the air separation plant, and the main cooler 2 refers to a condensing evaporator. The first liquid nitrogen pipeline 16 and the third liquid nitrogen pipeline 12 are both connected to an upper tower 1 of the air separation device, and the lower end of the air separation device is a lower tower 3. The embodiment of fig. 1 is a preferred embodiment of the invention, but the invention is not limited to the specific embodiment described above. As mentioned above, the position where the liquid nitrogen flows backward into the air separation plant in fig. 1 may be the top of the upper tower 1 or the top of the lower tower 3, the position where the liquid nitrogen product in the air separation plant is taken out may be the top of the upper tower 1 or the top of the lower tower 3, if the air separation plant is provided with a liquid oxygen evaporator, the position where the liquid oxygen flows backward into the air separation plant in fig. 1 may also be the liquid oxygen evaporator, and the position where the liquid oxygen product in the air separation plant is taken out may also be the liquid oxygen evaporator.
The invention relates to a production method for energy storage by coupling with an air separation device, which is characterized by comprising the following steps:
during valley electricity, the production load of the air separation plant is increased, liquid nitrogen stored in a liquid nitrogen storage tank 4 is filled back into an upper tower 1 of the air separation plant through a second liquid nitrogen pipeline 11 and a third liquid nitrogen pipeline 12 under the action of a first liquid nitrogen pump 6, the cold energy of the liquid nitrogen filled back is utilized, main cold 2 of the air separation plant can produce surplus liquid oxygen, and then the liquid oxygen is sent into a liquid oxygen storage tank 5 through a first liquid oxygen pipeline 13 for storage, and the oxygen supply amount of the air separation plant is kept unchanged at the moment;
during off-peak electricity, the production load of the air separation unit is reduced, liquid oxygen produced during off-peak electricity and stored in a liquid oxygen storage tank 5 is reversely poured to a main cooling tank 2 of the air separation unit through a second liquid oxygen pipeline 14 and a third liquid oxygen pipeline 15 under the action of a second liquid oxygen pump 7 to supplement the gap of air separation oxygen supply amount, surplus liquid nitrogen can be produced by the air separation unit by utilizing the cold energy of the reversely poured liquid oxygen, and the liquid nitrogen is sent into a liquid nitrogen storage tank 4 through a first liquid nitrogen pipeline 16 to be stored.
The invention releases the electric energy stored by the liquid oxygen during off-peak electricity, thereby reducing the usage amount of high-price electric energy, efficiently using the electric energy generated by the power plant at night, avoiding the waste of the electric energy, efficiently utilizing resources and reducing the production cost of the factory.
Finally, it should be noted that the present invention is not limited to the above embodiments, and many variations are possible. All modifications which can be derived or suggested by the person skilled in the art from the present disclosure are to be considered within the scope of the present invention.

Claims (4)

1. The utility model provides a device that carries out energy storage with air separation plant coupling which characterized in that: contain air separation plant, air separation plant is connected with liquid nitrogen storage tank (4) through liquid nitrogen pipeline (16), air separation plant is connected with liquid oxygen storage tank (5) through a liquid oxygen pipeline (13), liquid nitrogen storage tank (4) are connected with liquid nitrogen pump (6) through No. two liquid nitrogen pipelines (11), upper end department at air separation plant is connected through No. three liquid nitrogen pipelines (12) in liquid nitrogen pump (6), liquid oxygen storage tank (5) are connected with No. two liquid oxygen pumps (7) through No. two liquid oxygen pipelines (14), No. two liquid oxygen pumps (7) are connected at air separation plant middle-end department through No. three liquid oxygen pipelines (15).
2. An apparatus for storing energy coupled with an air separation plant according to claim 1, wherein: and the third liquid oxygen pipeline (15) and the first liquid oxygen pipeline (13) are connected to a main cooler (2) in an upper tower of the air separation device.
3. An apparatus for storing energy coupled with an air separation plant according to claim 1 or 2, characterized in that: the first liquid nitrogen pipeline (16) and the third liquid nitrogen pipeline (12) are both connected to an upper tower (1) of the air separation device, and the lower end of the air separation device is a lower tower (3).
4. A production method for energy storage by coupling with an air separation device is characterized by comprising the following steps:
during valley electricity, the production load of the air separation plant is improved, liquid nitrogen stored in a liquid nitrogen storage tank (4) is poured into an upper tower 1 of the air separation plant through a second liquid nitrogen pipeline (11) and a third liquid nitrogen pipeline (12) under the action of a first liquid nitrogen pump (6), the cold energy of the liquid nitrogen is utilized to flow backwards, main cold (2) of the air separation plant can produce surplus liquid oxygen, and then the liquid oxygen is sent into a liquid oxygen storage tank (5) through a first liquid oxygen pipeline (13) to be stored, and the oxygen supply amount of the air separation plant is kept unchanged at the moment;
during off-peak electricity, the production load of the air separation unit is reduced, liquid oxygen produced during off-peak electricity and stored in a liquid oxygen storage tank (5) is reversely filled into a main cooling tank (2) of the air separation unit through a second liquid oxygen pipeline (14) and a third liquid oxygen pipeline (15) under the action of a second liquid oxygen pump (7), a gap of air separation oxygen supply amount is supplemented, surplus liquid nitrogen can be produced by the air separation unit by utilizing the cold energy of the reversely filled liquid oxygen, and the liquid nitrogen is sent into a liquid nitrogen storage tank (4) through a first liquid nitrogen pipeline (16) to be stored.
CN202210074507.6A 2022-01-21 2022-01-21 Method and device for energy storage production by coupling with air separation device Pending CN114593358A (en)

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4529425A (en) * 1982-08-24 1985-07-16 Air Products And Chemicals, Inc. Plant for producing gaseous oxygen
US5084081A (en) * 1989-04-27 1992-01-28 Linde Aktiengesellschaft Low temperature air fractionation accommodating variable oxygen demand
ES2079800T3 (en) * 1991-11-15 1996-01-16 Air Prod & Chem CO-PRODUCTION OF A PURE AND ULTRA-PURE VOLATILE COMPONENT FROM A CURRENT OF VARIOUS CONSTITUENTS.
CN2612913Y (en) * 2003-04-29 2004-04-21 攀枝花新钢钒股份有限公司氧气厂 Operating mode variation oxygen production installation
CN201694836U (en) * 2010-06-17 2011-01-05 杜金明 Oxygen generator
CN106225423A (en) * 2016-08-19 2016-12-14 浙江智海化工设备工程有限公司 A kind of device and method reducing air separation unit energy consumption
CN106285944A (en) * 2016-09-13 2017-01-04 中国华能集团公司 A kind of IGCC peak-load regulation device and method utilizing space division system energy storage
CN106288657A (en) * 2016-10-21 2017-01-04 成都深冷液化设备股份有限公司 Liquid oxygen, liquid nitrogen exchange process units and production technology
CN206695507U (en) * 2016-12-19 2017-12-01 陆诗敏 Health care gas integrated form is produced and feedway
CN110319652A (en) * 2019-06-25 2019-10-11 杭州杭氧化医工程有限公司 A kind of air separation oxygenerator for energy storing-releasing

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4529425A (en) * 1982-08-24 1985-07-16 Air Products And Chemicals, Inc. Plant for producing gaseous oxygen
US5084081A (en) * 1989-04-27 1992-01-28 Linde Aktiengesellschaft Low temperature air fractionation accommodating variable oxygen demand
ES2079800T3 (en) * 1991-11-15 1996-01-16 Air Prod & Chem CO-PRODUCTION OF A PURE AND ULTRA-PURE VOLATILE COMPONENT FROM A CURRENT OF VARIOUS CONSTITUENTS.
CN2612913Y (en) * 2003-04-29 2004-04-21 攀枝花新钢钒股份有限公司氧气厂 Operating mode variation oxygen production installation
CN201694836U (en) * 2010-06-17 2011-01-05 杜金明 Oxygen generator
CN106225423A (en) * 2016-08-19 2016-12-14 浙江智海化工设备工程有限公司 A kind of device and method reducing air separation unit energy consumption
CN106285944A (en) * 2016-09-13 2017-01-04 中国华能集团公司 A kind of IGCC peak-load regulation device and method utilizing space division system energy storage
CN106288657A (en) * 2016-10-21 2017-01-04 成都深冷液化设备股份有限公司 Liquid oxygen, liquid nitrogen exchange process units and production technology
CN206695507U (en) * 2016-12-19 2017-12-01 陆诗敏 Health care gas integrated form is produced and feedway
CN110319652A (en) * 2019-06-25 2019-10-11 杭州杭氧化医工程有限公司 A kind of air separation oxygenerator for energy storing-releasing

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