CN114590800B - Method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge - Google Patents

Method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge Download PDF

Info

Publication number
CN114590800B
CN114590800B CN202210347490.7A CN202210347490A CN114590800B CN 114590800 B CN114590800 B CN 114590800B CN 202210347490 A CN202210347490 A CN 202210347490A CN 114590800 B CN114590800 B CN 114590800B
Authority
CN
China
Prior art keywords
arc plasma
sliding arc
graphene
coal tar
magnetic drive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN202210347490.7A
Other languages
Chinese (zh)
Other versions
CN114590800A (en
Inventor
瞿广飞
吴缓缓
崔庆渊
李军燕
颜洲鹏
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kunming University of Science and Technology
Original Assignee
Kunming University of Science and Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kunming University of Science and Technology filed Critical Kunming University of Science and Technology
Priority to CN202210347490.7A priority Critical patent/CN114590800B/en
Publication of CN114590800A publication Critical patent/CN114590800A/en
Application granted granted Critical
Publication of CN114590800B publication Critical patent/CN114590800B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00Carbon; Compounds thereof
    • C01B32/15Nano-sized carbon materials
    • C01B32/182Graphene
    • C01B32/184Preparation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The invention discloses a method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge, which comprises the steps of gasifying coal tar, feeding the gasified coal tar into a catalytic pyrolysis furnace filled with argon, adding nano metal or metal oxide as a catalyst into the pyrolysis furnace, mixing and reacting gaseous coal tar with the catalyst to generate a carbonized precursor, feeding the carbonized catalytic precursor and hydrogen into a magnetic drive sliding arc plasma discharge device, generating high-density non-thermal sliding arc plasma by an auxiliary magnetic field, and converting the carbonized precursor under the action of the high-density non-thermal sliding arc plasma to generate graphene; the method has the advantages of low cost, simple equipment and no need of condensation, and can realize the conversion from coal tar to the graphene with high added value product.

Description

Method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge
Technical Field
The invention belongs to the technical field of graphene preparation, and particularly relates to a method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge.
Background
The coal tar is mainly obtained through a coal pyrolysis carbonization process, is a byproduct in the coking process, and has the yield accounting for 3% -5% of the coal in the furnace. The tar has complex chemical structure, poor stability, low heat value and toxicity, and can block pipelines and equipment. The fraction is heavy and has poor quality, and particularly, the quality and content of metal and asphalt are high, so that the comprehensive chemical analysis and utilization of coal tar are difficult tasks. Coal tar contains a large amount of polycyclic aromatic hydrocarbon, and can be used as a carbon source for preparing graphene. The graphene is produced by a plurality of methods, a mechanical stripping method is adopted in a common method, the cost is low, the operation is easy, the yield and the purity are low, and the product structure is inconsistent; the method for cutting the carbon nano tube is characterized in that the prepared graphene has high elasticity and high tensile strength, but is aggregated in a solvent in a refractory manner Jie Yi; the arc discharge method has the advantages of easier production, no need of substrate transfer, high repeatability, but high reaction energy consumption; the chemical vapor deposition method has low cost and high yield, is beneficial to industrial production, is difficult to position a proper substrate, and has easily damaged graphene molecular structure; the reduced graphite oxidation method is simple to operate and high in yield, but the product has certain defects; the graphene prepared by the catalytic pyrolysis method has large area and good uniformity, but the preparation process is still immature and has strict requirements on equipment. In general, although the physical method for preparing the graphene has low synthesis cost and simple technology, the prepared graphene has low purity, inconsistent structure and weak controllability. Chemical methods often limit the industrial production of graphene due to expensive carbon precursors, difficulty in locating suitable substrates, product structural defects, and the like.
The arc plasma discharge does not need a catalyst, the process is simple, no pollution is caused, but a carbon source is easy to crack at high temperature to generate target substances, a large amount of byproducts are generated at the same time, and the arc discharge method has higher energy consumption and more expensive environmental conditions. While sliding arc plasma is a non-thermal plasma with little erosion of the electrode and does not require cooling of the electrode. Ma Sali g university ( Hypergravity synthesis of graphitic carbon nanomaterial in glide arc plasma[J]. Materials Research Bulletin, 2014, 54:61-65.) a nanostructured carbon material was synthesized using a methane/helium sliding arc plasma under hypergravity conditions. The sliding movement of sliding arc discharge along the electrode is more prominent due to the action of gravity, but the research process low-temperature plasma generator adopts a double-blade electrode reactor, so that the problems of poor arc stability, small reaction contact area and the like exist, and industrialization is difficult to realize. The group (Continuous preparation and formation mechanism of few-layer graphene by gliding arc plasma[J]. Chemical Engineering Journal, 2020, 387:124102.) of the object Hong Reyu of the Fuzhou university reports that the sliding arc plasma pyrolysis using methane as a carbon source prepares few layers of graphene powder, but the sliding arc plasma is non-thermal plasma, so that the system flux is low and the reaction efficiency is low due to the small volume and low energy density.
Disclosure of Invention
In order to solve the problems, the invention provides a method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge, which comprises the steps of gasifying coal tar, feeding the gasified coal tar into a catalytic pyrolysis furnace filled with argon or helium, adding nano metal or metal oxide as a catalyst into the pyrolysis furnace, mixing and reacting gaseous coal tar with the catalyst to generate a carbonized precursor, feeding the carbonized catalytic precursor and hydrogen into a magnetic drive sliding arc plasma discharge device, generating high-density non-thermal sliding arc plasma by an auxiliary magnetic field, and converting the carbonized precursor under the action of the high-density non-thermal sliding arc plasma to generate graphene.
According to the invention, the gaseous coal tar is subjected to preliminary pyrolysis under the condition of argon or helium, hydrocarbon in the gaseous coal tar reacts with a catalyst, carbon bonds are combined with the catalyst to generate a carbonized precursor while dehydrogenation, the carbonized precursor is subjected to pyrolysis cracking in a magnetic drive sliding arc plasma discharge device, carbon atoms are combined at high temperature to generate carbon clusters and carbon chains, and the carbonized precursor is continuously elongated to generate large-area graphene; the suspension carbon bond is terminated by hydrogen, the graphene is prevented from forming a closed structure, a graphene product is deposited at the bottom of the magnetic drive sliding arc plasma discharge device, gas and the graphene enter the cyclone separation device under the action of the induced draft fan, the graphene product is collected at the bottom of the cyclone separation device, and the gas is collected in the gas collection tank.
The catalyst is one or more of the nano particles Ni, cu, pt, pd, al, niO, al 2O3.
The temperature in the catalytic pyrolysis furnace is 650-850 ℃.
The argon accounts for 90% -97% of the volume of the mixed gas of the argon and the hydrogen, and the helium accounts for 90% -97% of the volume of the mixed gas of the helium and the hydrogen.
The magnetic drive sliding arc plasma discharge device comprises a shell, a cathode, an anode, a magnetic field generator, a stainless steel screen, a direct current high-frequency high-voltage power supply and a pressure gauge, wherein the cathode is arranged in the shell and is positioned at the center of the shell, the anode is positioned at two sides of the cathode, the magnetic field generator is arranged outside the shell and generates a magnetic field to cover a reaction area, the stainless steel screen is arranged in the shell and is positioned below the cathode, the direct current high-frequency high-voltage power supply is respectively connected with the anode and the cathode, and the pressure gauge is arranged on the shell.
The invention also aims to provide a device for completing the method, which comprises an inert gas tank, more than one gasification tank, more than one catalytic pyrolysis furnace, a magnetic drive sliding arc plasma discharge device, a cyclone separation device, a draught fan and a hydrogen tank, wherein the inert gas tank and the more than one gasification tank are respectively connected with the more than one catalytic pyrolysis furnace, the catalytic pyrolysis furnace is connected with the cyclone separation device through the magnetic drive sliding arc plasma discharge device, the cyclone separation device is connected with the gas collection tank through the draught fan, and the hydrogen tank is connected with the magnetic drive sliding arc plasma discharge device.
The method has the advantages and technical effects that:
the coal tar is used as a carbon source to prepare graphene, so that the value of the coal tar can be greatly increased, the purity of a product can be improved through preliminary pyrolysis of the coal tar, a carbonization precursor is generated, the rotation speed of an arc is accelerated due to the loading effect of a magnetic field through magnetic drive sliding arc plasma, the energy density is increased, and a stable plasma region can be formed; then, various parameters in the system are regulated and controlled to generate high-quality few-layer graphene; according to the method, dangerous waste coal tar is converted into the graphene material with high added value, the carbon source is cheap and easy to obtain, the method is simple, and continuous industrial production can be realized.
Drawings
FIG. 1 is a schematic diagram of an apparatus for carrying out the method of the present invention;
FIG. 2 is a schematic diagram of a magnetic drive sliding arc plasma discharge apparatus;
In the figure: 1: an inert gas tank; 2-1: a gasification tank I; 2-2: a gasification tank II; 3: a gas flow meter; 4-1: a catalytic pyrolysis furnace I; 4-2: a catalytic pyrolysis furnace II; 5: a hydrogen tank; 6: magnetically driven sliding arc plasma generator; 7: a pressure gauge; 8: a DC high-frequency high-voltage power supply; 9: a cyclone separation device; 10: a product collection port; 11: an induced draft fan; 12: a gas collection tank; 13: a housing; 14: a cathode; 15: an anode; 16: a magnetic field generator; 17: stainless steel screen cloth.
Detailed Description
The present invention will be described in detail with reference to the following specific embodiments, but the scope of the present invention is not limited to the above description; the methods in the examples are all conventional methods unless specified otherwise, and the reagents used are all conventional commercial reagents or reagents prepared by conventional methods unless specified otherwise;
The device for carrying out the method in the following embodiment comprises an inert gas tank 1, a gasification tank I2-1, a gasification tank II 2-2, a catalytic pyrolysis furnace I4-1, a catalytic pyrolysis furnace II 4-2, a hydrogen tank 5, a magnetic drive sliding arc plasma generating device 6, a cyclone separation device 9, an induced draft fan 11 and a gas collecting tank 12; the inert gas tank 1, the gasification tank I2-1 and the gasification tank II 2-2 are respectively connected with the catalytic pyrolysis furnace I4-1 and the catalytic pyrolysis furnace II 4-2, the catalytic pyrolysis furnace I4-1 and the catalytic pyrolysis furnace II 4-2 are connected with the cyclone separation device 9 through a magnetic driving sliding arc plasma discharge device, the cyclone separation device 9 is connected with the gas collection tank 12 through a draught fan 11, and the hydrogen tank 5 is connected with the magnetic driving sliding arc plasma discharge device 6; the inert gas tank 1, the gasification tank I2-1 and the gasification tank II 2-2 are provided with gas flow meters 3 on outlet pipelines;
The magnetic drive sliding arc plasma discharging device comprises a shell 13, a cathode 14, an anode 15, a magnetic field generator 16, a direct current high-frequency high-voltage power supply 8 and a pressure gauge 7, wherein an inlet is formed in the shell 13, an outlet is formed in the lower portion of the shell, the cathode 14 is arranged in the shell and is positioned in the center of the shell, the anode 15 is an arc plate-shaped electrode and is positioned on two sides of the cathode, the magnetic field generator 16 is arranged outside the shell and generates a magnetic field to cover a reaction area, a stainless steel screen 17 is arranged in the shell and is positioned below the cathode, the direct current high-frequency high-voltage power supply 8 is respectively connected with the anode and the cathode, and the pressure gauge 7 is arranged on the shell; the magnetic field generator 4 is a permanent magnet;
Example 1
The coal tar which is a byproduct generated in the coking process of the coal accounts for 3 to 5 percent of the coal in the furnace. In recent years, coal tar is becoming a research focus on high-value materials, especially graphene; the arc discharge in various graphene preparation processes does not need substrate transfer, has high repeatability, and has good prospect in continuous industrial production.
As shown in fig. 1 and 2, in the embodiment, gasified coal tar and argon are introduced into a catalytic pyrolysis furnace I4-1 and a catalytic pyrolysis furnace II 4-2 from a gasification tank I2-1, a gasification tank II 2-2 and an inert gas tank 1 through pipelines according to the volume ratio of 10:1 for pyrolysis, wherein the mass of a nano NiO catalyst in the furnace is 54.560 g/(1L of gasified coal tar); at the pyrolysis temperature of 650 ℃, 83% of carbon atoms in coal tar are combined with a catalyst, the flow rate of inert gas is regulated to enable the reaction to stay for 20 minutes, carbonized precursor is generated, the carbonized precursor and hydrogen in a hydrogen tank 5 are led into a magnetic drive sliding arc plasma discharging device 6 together, wherein argon accounts for 90% of the volume of a mixed gas of argon and hydrogen, the magnetic drive sliding arc plasma discharging device 6 is powered by a 40Hz and 220V direct-current high-frequency high-voltage power supply 8, the magnetic field strength is 0.3T, high-density non-thermal sliding arc plasma is driven and generated by the pushing of air flow entering along the reactor and the magnetic field generated by a permanent magnet, unreacted coal tar or other large-particle amorphous carbon generated by the carbonized precursor is filtered out by a stainless steel screen 17, the graphene and the gas enter a cyclone separation device 9 together under the action of a draught fan 11, the product graphene is collected by a product collecting port 10 at the bottom of the cyclone device, and the gas generated in the reaction process is sent into a gas collecting tank 12 through the draught fan 11.
Example 2
In the embodiment, gasified coal tar and argon are sent into a catalytic pyrolysis furnace I4-1 and a catalytic pyrolysis furnace II 4-2 for pyrolysis according to the volume ratio of 15:1, wherein 48.740 g/(1L of gasified coal tar) Ni/NiO nano particles are filled in the pyrolysis furnace, the pyrolysis temperature is set to 850 ℃, the gas flow rate is regulated to ensure the residence time of the reaction to be 10 minutes, a carbonized precursor is generated, and the conversion rate of the catalyst to hydrocarbon of the coal tar is 93.5%; after the graphene is discharged out of the pipeline, the graphene is mixed with hydrogen (wherein argon accounts for 95% of the volume of a mixed gas of the argon and the hydrogen), and then is fed into a magnetic drive sliding arc plasma discharge device with the magnetic intensity of 0.3T, the magnetic drive sliding arc plasma discharge device is powered by a direct-current high-frequency high-voltage power supply with the magnetic intensity of 40Hz and 220V, carbonized precursors are decomposed in a plasma reactor, carbon atoms generate carbon clusters, the clusters are cyclized and aggregated to finally generate graphene through a hydrogen termination dangling bond, unreacted coal tar or other produced large-particle amorphous carbon is filtered by the graphene through a stainless steel screen, the graphene and the gas enter a cyclone separation device 9 together under the action of a draught fan 11, the graphene is collected at a product collecting port 10, and the gas is collected by a gas collecting tank 12.
Example 3
According to the embodiment, gasified coal tar and argon are introduced into a catalytic pyrolysis furnace I4-1 and a catalytic pyrolysis furnace II 4-2 filled with 55.130 g/(1L of gasified coal tar) of nano Al 2O3 powder according to the volume ratio of 12:1 for pyrolysis, the pyrolysis temperature is controlled at 800 ℃, the gas flow rate is regulated to ensure that the residence time of the reaction is 8 minutes, a carbonized precursor is generated, and the conversion rate of the catalyst to hydrocarbon of the coal tar is 90%; the carbonized precursor is mixed with hydrogen (wherein argon accounts for 92% of the volume of the mixed gas of the argon and the hydrogen) after exiting from a pipeline and then is fed into a magnetic drive sliding arc plasma discharge device with the magnetic strength of 0.25T, the magnetic drive sliding arc plasma discharge device is powered by a direct-current high-frequency high-voltage power supply with the magnetic strength of 40Hz and 220V, the carbonized precursor is decomposed in a plasma reactor, carbon atoms generate carbon clusters, the clusters are cyclized and aggregated to finally generate graphene through hydrogen termination dangling bonds, the graphene is filtered out of other large-particle impurities through a stainless steel screen 17, and then is jointly introduced into a cyclone separation device 9 with gas generated in the reaction process under the action of a draught fan 11, the product graphene is collected at a bottom product collecting port 10 of the cyclone separation device, and the gas generated in the reaction process is fed into a gas collecting tank 12.

Claims (5)

1. A method for continuously preparing graphene by magnetically driving sliding arc plasma high-voltage discharge is characterized by comprising the following steps of: gasifying coal tar, feeding the gasified coal tar into a catalytic pyrolysis furnace filled with argon or helium, adding nano metal or metal oxide serving as a catalyst into the pyrolysis furnace, mixing the gaseous coal tar with the catalyst to react to generate a carbonized precursor, feeding the carbonized precursor and hydrogen into a magnetic driving sliding arc plasma discharge device, generating high-density non-thermal sliding arc plasma through an auxiliary magnetic field, and converting the carbonized precursor under the action of the high-density non-thermal sliding arc plasma to generate graphene;
The catalyst is one or more of the nano particles Ni, cu, pt, pd, al, niO, al 2O3.
2. The method for continuously preparing graphene by magnetically driving sliding arc plasma high-voltage discharge according to claim 1, wherein the method comprises the following steps: the pyrolysis temperature is 650-850 ℃.
3. The method for continuously preparing graphene by magnetically driving sliding arc plasma high-voltage discharge according to claim 2, wherein the method comprises the following steps: the magnetic drive sliding arc plasma discharge device comprises a shell (13), a cathode (14), an anode (15), a magnetic field generator (16), a stainless steel screen (17), a direct current high-frequency high-voltage power supply (8) and a pressure gauge (7), wherein the cathode (14) is arranged in the shell and located at the center of the shell, the anode (15) is located at two sides of the cathode, the magnetic field generator (16) is arranged outside the shell and generates a magnetic field to cover a reaction area, the stainless steel screen (17) is arranged in the shell and located below the cathode, the direct current high-frequency high-voltage power supply (8) is connected with the anode and the cathode, and the pressure gauge (7) is arranged on the shell.
4. The method for continuously preparing graphene by magnetically driving sliding arc plasma high-voltage discharge according to claim 3, wherein the method comprises the following steps: argon accounts for 90% -97% of the volume of the mixed gas of argon and hydrogen, and helium accounts for 90% -97% of the volume of the mixed gas of helium and hydrogen.
5. A system for performing the method for continuously preparing graphene by magnetically driving sliding arc plasma high-voltage discharge as claimed in claim 4, wherein: the device comprises an inert gas tank, more than one gasification tank, more than one catalytic pyrolysis furnace, a magnetic drive sliding arc plasma discharge device, a cyclone separation device, a draught fan and a hydrogen tank, wherein the inert gas tank and the more than one gasification tank are respectively connected with the more than one catalytic pyrolysis furnace, the catalytic pyrolysis furnace is connected with the cyclone separation device through the magnetic drive sliding arc plasma discharge device, the cyclone separation device is connected with the gas collection tank through the draught fan, and the hydrogen tank is connected with the magnetic drive sliding arc plasma discharge device.
CN202210347490.7A 2022-04-03 2022-04-03 Method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge Active CN114590800B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210347490.7A CN114590800B (en) 2022-04-03 2022-04-03 Method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210347490.7A CN114590800B (en) 2022-04-03 2022-04-03 Method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge

Publications (2)

Publication Number Publication Date
CN114590800A CN114590800A (en) 2022-06-07
CN114590800B true CN114590800B (en) 2024-05-10

Family

ID=81812151

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202210347490.7A Active CN114590800B (en) 2022-04-03 2022-04-03 Method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge

Country Status (1)

Country Link
CN (1) CN114590800B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115924895A (en) * 2022-12-12 2023-04-07 合肥工业大学 Device for preparing graphene by arc process
CN116281971A (en) * 2023-03-03 2023-06-23 昆明理工大学 Method and device for easily separating and generating graphene

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1903713A (en) * 2006-08-02 2007-01-31 太原理工大学 Method of preparing nano-carbon fiber using coal tar asphalt as raw material

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100473601C (en) * 2003-01-23 2009-04-01 佳能株式会社 Method for producing nano-carbon materials
CA3141894C (en) * 2016-12-21 2023-02-28 Raymor Industries Inc. Plasma processes for producing graphene nanosheets

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1903713A (en) * 2006-08-02 2007-01-31 太原理工大学 Method of preparing nano-carbon fiber using coal tar asphalt as raw material

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
"煤焦油气相催化裂解生成轻质芳烃的研究";闫伦靖;《中国博士学位论文数据库 工程科技I辑》;B016-3 *
Dongning Li et. al.."Synrhesis of graphene flakes using a non-thermal plasma based on magnetically stabilized gliding arc discharge".《Fullerences,Nanotubes and Carbon Nanostructures》.2020,第28卷(第10期),846-856. *

Also Published As

Publication number Publication date
CN114590800A (en) 2022-06-07

Similar Documents

Publication Publication Date Title
CN114590800B (en) Method for continuously preparing graphene by magnetic drive sliding arc plasma high-voltage discharge
Zhao et al. Biomass pyrolysis in an argon/hydrogen plasma reactor
US20040253168A1 (en) System and method for hydrocarbon processing
CN112250061A (en) Continuous preparation system and preparation method of single-walled carbon nanotubes
CN108840325B (en) Biomass energy stepwise-conversion hydrogen production and CO coordination2Emission reduction system and method
CN114604859B (en) Method and device for continuously preparing graphene by one-stage pyrolysis of coal tar
WO2023235486A1 (en) Recycled feedstocks for carbon and hydrogen production
CN100595139C (en) Method for mass production of bamboo joint shaped carbon nano-tube by adopting chemical vapor deposition method
CN112591739A (en) Preparation method of graphene
CN108163841A (en) A kind of method that graphene is prepared using tar
CN107311146A (en) A kind of serialization prepares the device and method of nano-carbon material
CN105623685A (en) Method and equipment for continuous co-production of gas and charcoal through biomass material in-situ catalytic cracking
CN1262627C (en) Oven gas generation of plasma gasified coke oven
CN110922996A (en) Method for modulating coal catalytic pyrolysis gas-phase product by using high-temperature coke oven gas
CN111892040B (en) Method for preparing graphene by arc process
EP4237372A1 (en) Hydrogen production from hydrocarbons by plasma pyrolysis
CN112225200A (en) Method and device for continuously preparing high-purity carbon nano tube
CN107381541B (en) method for manufacturing carbon nano tube by using pyrolysis carbon black as carbon source
CN201454524U (en) Plasma coal cracking reaction device involving flow-shading components
CN216419348U (en) Thermal plasma reaction device for preparing nano powder material
CN1378974A (en) Process and equipment for preparing nano carbon tubes
CN111115614B (en) Carbon nano tube prepared by catalytic cracking of hydrocarbon by rotary method, device and method
CN113233447A (en) Method for continuously synthesizing doped graphene
CN116332159B (en) Method and device for preparing carbon nano tube by catalytically cracking hydrocarbon under assistance of ultrasound
CN114180519B (en) Device and method for preparing hydrogen and nano carbon material by virtue of reaction of decomposing coalbed methane by using plasma

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant