CN114574028A - Anti-counterfeiting pigment composition and preparation method thereof - Google Patents
Anti-counterfeiting pigment composition and preparation method thereof Download PDFInfo
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- CN114574028A CN114574028A CN202210163181.4A CN202210163181A CN114574028A CN 114574028 A CN114574028 A CN 114574028A CN 202210163181 A CN202210163181 A CN 202210163181A CN 114574028 A CN114574028 A CN 114574028A
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- 239000000049 pigment Substances 0.000 title claims abstract description 195
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 238000002834 transmittance Methods 0.000 claims abstract description 24
- 239000000463 material Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 16
- 238000002310 reflectometry Methods 0.000 claims description 16
- -1 polyethylene Polymers 0.000 claims description 15
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 6
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- PLDDOISOJJCEMH-UHFFFAOYSA-N neodymium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Nd+3].[Nd+3] PLDDOISOJJCEMH-UHFFFAOYSA-N 0.000 claims description 6
- 239000004038 photonic crystal Substances 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 6
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 claims description 6
- VFLXBUJKRRJAKY-UHFFFAOYSA-N 13768-86-0 Chemical compound O=[Se](=O)=O VFLXBUJKRRJAKY-UHFFFAOYSA-N 0.000 claims description 3
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 claims description 3
- JMMZCWZIJXAGKW-UHFFFAOYSA-N 2-methylpent-2-ene Chemical compound CCC=C(C)C JMMZCWZIJXAGKW-UHFFFAOYSA-N 0.000 claims description 3
- 229920000178 Acrylic resin Polymers 0.000 claims description 3
- 239000004925 Acrylic resin Substances 0.000 claims description 3
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- DQEFEBPAPFSJLV-UHFFFAOYSA-N Cellulose propionate Chemical compound CCC(=O)OCC1OC(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C1OC1C(OC(=O)CC)C(OC(=O)CC)C(OC(=O)CC)C(COC(=O)CC)O1 DQEFEBPAPFSJLV-UHFFFAOYSA-N 0.000 claims description 3
- 239000001856 Ethyl cellulose Substances 0.000 claims description 3
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 3
- 239000000020 Nitrocellulose Substances 0.000 claims description 3
- 239000004962 Polyamide-imide Substances 0.000 claims description 3
- 239000004695 Polyether sulfone Substances 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000004793 Polystyrene Substances 0.000 claims description 3
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- 239000002174 Styrene-butadiene Substances 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 3
- 239000005083 Zinc sulfide Substances 0.000 claims description 3
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims description 3
- 229920006243 acrylic copolymer Polymers 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- OYLGJCQECKOTOL-UHFFFAOYSA-L barium fluoride Chemical compound [F-].[F-].[Ba+2] OYLGJCQECKOTOL-UHFFFAOYSA-L 0.000 claims description 3
- 229910001632 barium fluoride Inorganic materials 0.000 claims description 3
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 3
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims description 3
- 229910001634 calcium fluoride Inorganic materials 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims description 3
- 229920006218 cellulose propionate Polymers 0.000 claims description 3
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 3
- QCCDYNYSHILRDG-UHFFFAOYSA-K cerium(3+);trifluoride Chemical compound [F-].[F-].[F-].[Ce+3] QCCDYNYSHILRDG-UHFFFAOYSA-K 0.000 claims description 3
- 229920001249 ethyl cellulose Polymers 0.000 claims description 3
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 3
- 229910001940 europium oxide Inorganic materials 0.000 claims description 3
- AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052735 hafnium Inorganic materials 0.000 claims description 3
- 229910000449 hafnium oxide Inorganic materials 0.000 claims description 3
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 claims description 3
- WHJFNYXPKGDKBB-UHFFFAOYSA-N hafnium;methane Chemical compound C.[Hf] WHJFNYXPKGDKBB-UHFFFAOYSA-N 0.000 claims description 3
- 229910003437 indium oxide Inorganic materials 0.000 claims description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 claims description 3
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 claims description 3
- 229920000554 ionomer Polymers 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 claims description 3
- 229910001635 magnesium fluoride Inorganic materials 0.000 claims description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
- 239000010445 mica Substances 0.000 claims description 3
- 229910052618 mica group Inorganic materials 0.000 claims description 3
- ZKATWMILCYLAPD-UHFFFAOYSA-N niobium pentoxide Inorganic materials O=[Nb](=O)O[Nb](=O)=O ZKATWMILCYLAPD-UHFFFAOYSA-N 0.000 claims description 3
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 claims description 3
- 229920001220 nitrocellulos Polymers 0.000 claims description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 3
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 3
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 claims description 3
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 3
- 229920002492 poly(sulfone) Polymers 0.000 claims description 3
- 229920002312 polyamide-imide Polymers 0.000 claims description 3
- 229920001083 polybutene Polymers 0.000 claims description 3
- 239000004417 polycarbonate Substances 0.000 claims description 3
- 229920000515 polycarbonate Polymers 0.000 claims description 3
- 229920006393 polyether sulfone Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 3
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229910003447 praseodymium oxide Inorganic materials 0.000 claims description 3
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims description 3
- 229910001954 samarium oxide Inorganic materials 0.000 claims description 3
- 229940075630 samarium oxide Drugs 0.000 claims description 3
- OJIKOZJGHCVMDC-UHFFFAOYSA-K samarium(iii) fluoride Chemical compound F[Sm](F)F OJIKOZJGHCVMDC-UHFFFAOYSA-K 0.000 claims description 3
- FKTOIHSPIPYAPE-UHFFFAOYSA-N samarium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[Sm+3].[Sm+3] FKTOIHSPIPYAPE-UHFFFAOYSA-N 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- 229920000638 styrene acrylonitrile Polymers 0.000 claims description 3
- 239000011115 styrene butadiene Substances 0.000 claims description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 3
- PBCFLUZVCVVTBY-UHFFFAOYSA-N tantalum pentoxide Inorganic materials O=[Ta](=O)O[Ta](=O)=O PBCFLUZVCVVTBY-UHFFFAOYSA-N 0.000 claims description 3
- 229920001169 thermoplastic Polymers 0.000 claims description 3
- 239000004416 thermosoftening plastic Substances 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- BYMUNNMMXKDFEZ-UHFFFAOYSA-K trifluorolanthanum Chemical compound F[La](F)F BYMUNNMMXKDFEZ-UHFFFAOYSA-K 0.000 claims description 3
- XRADHEAKQRNYQQ-UHFFFAOYSA-K trifluoroneodymium Chemical compound F[Nd](F)F XRADHEAKQRNYQQ-UHFFFAOYSA-K 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 3
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 9
- 238000011161 development Methods 0.000 abstract description 6
- 238000012360 testing method Methods 0.000 description 7
- 238000007639 printing Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000005566 electron beam evaporation Methods 0.000 description 2
- 238000007733 ion plating Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000696 magnetic material Substances 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/50—Sympathetic, colour changing or similar inks
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The application discloses an anti-counterfeiting pigment composition and a preparation method thereof. The anti-counterfeiting pigment composition comprises: the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment have the following mass ratio of 10-80 percent: 20% -90%, wherein the transmittance of the infrared reflection pigment to visible light wave band is more than 90%, and the reflectance of the infrared reflection pigment to infrared wave band with interval of 780nm-1200nm is more than 85%. The anti-counterfeiting pigment composition provided by the application is a combination of a pigment with anti-counterfeiting characteristics and an infrared reflection pigment, has multiple anti-counterfeiting effects, and is good in color development and high in color uniformity.
Description
Technical Field
The application relates to the technical field of optical anti-counterfeiting, in particular to an anti-counterfeiting pigment composition and a preparation method thereof.
Background
In recent years, with the development of anti-counterfeiting technology, a plurality of color-changing and special synthetic materials gradually expose the corners. The color-changing material is widely applied to the traditional visual anti-counterfeiting technology, and more invisible anti-counterfeiting technologies are added to the color-changing material, such as infrared anti-counterfeiting and magnetic anti-counterfeiting.
However, infrared highly reflective materials are often monochrome pigments, and can only be used to authenticate security elements on specific identification devices. The magnetic and infrared double anti-counterfeiting can be printed only by two different kinds of printing ink at present and cannot be directly combined for use.
Disclosure of Invention
The application provides an anti-counterfeiting pigment composition and a preparation method thereof, the anti-counterfeiting pigment composition is easy to prepare, low in cost and capable of achieving multiple anti-counterfeiting effects, and the anti-counterfeiting pigment composition is good in color development and high in color uniformity.
In order to solve the technical problem, the application adopts a technical scheme that: there is provided a security pigment composition comprising: the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment have the following mass ratio: 10-80%, and the mass ratio of the infrared reflection pigment is as follows: 20% -90%, wherein the transmittance of the infrared reflection pigment to visible light wave band is more than 90%, and the reflectance of the infrared reflection pigment to infrared wave band with interval of 780nm-1200nm is more than 85%.
Furthermore, the anti-counterfeiting pigment composition has a preset reflectivity for an infrared band and a preset transmittance for a visible light band, the pigment with anti-counterfeiting characteristics has a preset anti-counterfeiting index, the preset anti-counterfeiting index combines the preset reflectivity and the preset transmittance to obtain an identification index, and the identification index is used for anti-counterfeiting identification.
Further, the pigment with the anti-counterfeiting characteristic comprises optically variable pigment and/or magnetic pigment, and the preset anti-counterfeiting index comprises magnetic index and/or optically variable index.
Furthermore, the pigment with the anti-counterfeiting characteristic is a photonic crystal, a flaky pearly-luster material or a flaky film material.
Further, the infrared reflective pigment is a material having a refractive index of not more than 1.65 and/or a sheet-like material in which materials having a refractive index of more than 1.65 are stacked.
Further, the material having a refractive index of not more than 1.65 includes: silica, alumina, magnesium fluoride, aluminum fluoride, cerium fluoride, lanthanum fluoride, neodymium fluoride, samarium fluoride, barium fluoride, calcium fluoride, lithium fluoride polystyrene, polyethylene, polymethyl methacrylate, polyamideimide, polyperfluoroethylpropylene, tetrafluoroethylene, chlorotrifluoroethylene, cellulose propionate, cellulose acetate butyrate, methylpentene polymer, homopolyformaldehyde, acrylic resin, cellulose nitrate, ethyl cellulose, polypropylene, polysulfone, polyethersulfone, mica, a heteroisomorphous polymer, polybutene, an ionomer, an acrylic copolymer, a thermoplastic, styrene butadiene, polyvinyl chloride, urea formaldehyde, styrene acrylonitrile, or a polycarbonate; materials with refractive indices greater than 1.65 include: lanthanum titanate, trititanium pentoxide, niobium pentoxide, zinc sulfide, zinc oxide, zirconium oxide, titanium dioxide, carbon, indium oxide, indium tin oxide, tantalum pentoxide, cerium oxide, yttrium oxide, europium oxide, iron oxide, triiron tetroxide, hafnium nitride, hafnium carbide, hafnium oxide, lanthanum oxide, magnesium oxide, neodymium oxide, praseodymium oxide, samarium oxide, antimony trioxide, silicon carbide, silicon nitride, silicon monoxide, selenium trioxide, tin oxide, or tungsten trioxide.
To solve the above technical problem, another technical solution adopted by the present application is: provided is a method for preparing a forgery-preventing pigment composition, the method comprising: obtaining a pigment with anti-counterfeiting characteristics and an infrared reflection pigment, wherein the transmittance of the infrared reflection pigment to a visible light wave band is more than 90%, and the reflectance of the infrared reflection pigment to an infrared wave band with the interval of 780nm-1200nm is more than 85%; mixing the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment according to a preset proportion to obtain the anti-counterfeiting pigment composition, wherein the mass ratio of the pigment with the anti-counterfeiting characteristic is as follows: 10-80%, and the mass ratio of the infrared reflection pigment is as follows: 20 to 90 percent.
Furthermore, the anti-counterfeiting pigment composition has a preset reflectivity for an infrared band and a preset transmittance for a visible light band, the pigment with anti-counterfeiting characteristics has a preset anti-counterfeiting index, the preset anti-counterfeiting index combines the preset reflectivity and the preset transmittance to obtain an identification index, and the identification index is used for anti-counterfeiting identification.
Further, the pigment with the anti-counterfeiting characteristic comprises optically variable pigment and/or magnetic pigment, and the preset anti-counterfeiting index comprises magnetic index and/or optically variable index.
Furthermore, the pigment with the anti-counterfeiting characteristic is a photonic crystal, a flaky pearlescent material or a flaky film material.
The beneficial effect of this application is: in contrast to the state of the art, the security pigment composition of the present application comprises: the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment have the following mass ratio of 10-80 percent: 20% -90%, wherein the transmittance of the infrared reflection pigment to visible light wave band is more than 90%, and the reflectance of the infrared reflection pigment to infrared wave band with interval of 780nm-1200nm is more than 85%. The anti-counterfeiting pigment composition is easy to prepare and low in cost; and the pigment with the anti-counterfeiting characteristic is combined with the infrared invisible anti-counterfeiting pigment, so that the composition has multiple anti-counterfeiting effects, and in addition, the composition has good color development and high color uniformity.
Drawings
In order to more clearly illustrate the embodiments of the present application or the technical solutions in the prior art, the drawings needed to be used in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present application, and it is obvious for those skilled in the art to obtain other drawings without creative efforts.
FIG. 1 is a schematic flow diagram of one embodiment of a method for preparing a security pigment composition provided herein.
Detailed Description
The present application will be described in further detail with reference to the following drawings and examples. It is to be noted that the following examples are only illustrative of the present application, and do not limit the scope of the present application. Likewise, the following examples are only some examples and not all examples of the present application, and all other examples obtained by a person of ordinary skill in the art without any inventive step are within the scope of the present application.
The terms "inner" and "outer" and similar terms used in the description and claims of the present application and the above-described drawings are used for indicating orientations and positional relationships based on the orientations and positional relationships shown in the drawings or the orientations and positional relationships customarily placed in use of products of the present application, and are used merely for convenience in describing the present application and for simplicity in description, and do not indicate or imply that the devices or elements referred to must have a particular orientation, be constructed and operated in a particular orientation, and therefore, should not be construed as limiting the present application.
Furthermore, the terms "first," "second," and the like (if any) in the description and claims of this application and the above-described drawings are used for distinguishing between similar elements and not necessarily for describing a particular sequential or chronological order. It is to be understood that the data so used may be interchanged under appropriate circumstances such that the embodiments of the application described herein may be implemented, for example, in sequences other than those illustrated or described herein. Furthermore, the terms "comprising" and "having," as well as any variations thereof, are intended to cover non-exclusive inclusions.
The application provides an anti-counterfeiting pigment composition, aiming at solving the problem of multiple anti-counterfeiting composite application in the anti-counterfeiting field. The present application provides a security pigment composition comprising: the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment are characterized in that the pigment with the anti-counterfeiting characteristic comprises the following components in percentage by mass: 10-80 percent of infrared reflection pigment, and the mass ratio of the infrared reflection pigment is as follows: 20-90%, preferably, the mass ratio of the pigment with the anti-counterfeiting characteristic is 30-50%, and the mass ratio of the infrared reflection pigment is as follows: 50 to 70 percent. That is, the anti-counterfeiting pigment composition is obtained by mixing a pigment with anti-counterfeiting characteristics and an infrared reflection pigment according to a certain proportion.
The mass ratio of the pigment with the security feature herein refers to the ratio of the mass of the pigment with the security feature to the total mass of the security pigment composition, and the mass ratio of the infrared-reflective pigment refers to the ratio of the mass of the infrared-reflective pigment to the total mass of the security pigment composition. For example, in the present application, the mass ratio of the pigment with the anti-counterfeiting feature may be 10%, the mass ratio of the infrared reflective pigment may be 90%, or the mass ratio of the pigment with the anti-counterfeiting feature may be 30%, and the mass ratio of the infrared reflective pigment may be 70%, or the mass ratio of the pigment with the anti-counterfeiting feature may be 40%, and the mass ratio of the infrared reflective pigment may be 60%, or the mass ratio of the pigment with the anti-counterfeiting feature may be 80%, and the mass ratio of the infrared reflective pigment may be 20%, and the like, and the configuration may be specifically performed according to the actual situation.
Further, in the application, the infrared reflection pigment is a transparent pigment, the transmittance of the infrared reflection pigment to a visible light wave band is more than 90%, and the reflectance of the infrared reflection pigment to an infrared wave band with an interval of 780nm-1200nm is more than 85%.
The anti-counterfeiting pigment composition is low in cost and easy to prepare, combines the pigment with anti-counterfeiting characteristics with the infrared invisible anti-counterfeiting pigment to improve the anti-counterfeiting effect, and is good in color development and high in color uniformity.
Further, pigments having security features herein include, but are not limited to, optically variable pigments and/or magnetic pigments. That is, security features herein include, but are not limited to, optically variable, magnetic, and the like.
The pigment with the anti-counterfeiting feature can be an optical pigment with an optical structure, for example, the pigment with the anti-counterfeiting feature can be a photonic crystal, a flaky pearlescent material or a flaky film material. For example, when the pigment having the security feature is a magnetic pigment, the magnetic material may be a magnetic photonic crystal, a magnetic flaky pearlescent material, or a flaky thin film material.
Further, the pigment having the anti-counterfeiting feature can be prepared by a chemical vapor deposition method, a sputtering method, a solution coating method, an electron beam evaporation method, an ion plating method, a dipping method, a chemical synthesis method, a sintering method or a spraying method. The above preparation method is within the scope of one skilled in the art and will not be described in detail herein.
The infrared-reflective pigment may be a material having a refractive index of not more than 1.65 and/or a sheet-like material in which materials having a refractive index of more than 1.65 are stacked. Wherein the material having a refractive index of not more than 1.65 comprises: silica, alumina, magnesium fluoride, aluminum fluoride, cerium fluoride, lanthanum fluoride, neodymium fluoride, samarium fluoride, barium fluoride, calcium fluoride, lithium fluoride polystyrene, polyethylene, polymethyl methacrylate, polyamideimide, polyperfluoroethylpropylene, tetrafluoroethylene, chlorotrifluoroethylene, cellulose propionate, cellulose acetate butyrate, methylpentene polymer, homopolyformaldehyde, acrylic resin, cellulose nitrate, ethyl cellulose, polypropylene, polysulfone, polyethersulfone, mica, a heteroisomorphous polymer, polybutene, an ionomer, an acrylic copolymer, a thermoplastic, styrene butadiene, polyvinyl chloride, urea formaldehyde, styrene acrylonitrile, or a polycarbonate. Materials with refractive indices greater than 1.65 include: lanthanum titanate, trititanium pentoxide, niobium pentoxide, zinc sulfide, zinc oxide, zirconium oxide, titanium dioxide, carbon, indium oxide, indium tin oxide, tantalum pentoxide, cerium oxide, yttrium oxide, europium oxide, iron oxide, triiron tetroxide, hafnium nitride, hafnium carbide, hafnium oxide, lanthanum oxide, magnesium oxide, neodymium oxide, praseodymium oxide, samarium oxide, antimony trioxide, silicon carbide, silicon nitride, silicon monoxide, selenium trioxide, tin oxide, or tungsten trioxide.
The infrared reflective pigment can also be prepared by chemical vapor deposition, sputtering, solution coating, electron beam evaporation, ion plating, dipping, chemical synthesis, sintering, or spraying. The above preparation method is within the scope of one skilled in the art and will not be described in detail herein.
The anti-counterfeiting pigment composition has a preset reflectivity for an infrared band and a preset transmittance for a visible light band, and the reflectivity and the transmittance can be measured by a specific instrument. After the two pigments are combined, the transmittance and the reflection ratio of the formed composition are inconsistent according to different mixing ratios of the two pigments, so that the anti-counterfeiting tracing can be carried out by taking the ratio value as a characteristic.
Furthermore, the pigment with the anti-counterfeiting characteristic has a preset anti-counterfeiting index, the preset anti-counterfeiting index is combined with the reflectivity and the transmittance of the anti-counterfeiting pigment composition to obtain an identification index, and the identification index is used for anti-counterfeiting identification. Thus, the anti-counterfeiting effect of the composition can be improved.
The pigment with anti-counterfeiting characteristics has anti-counterfeiting indexes which can be magnetic indexes and/or optically variable indexes. For example, when the pigment having the anti-counterfeiting characteristic is a magnetic pigment, the anti-counterfeiting index is a magnetic index. Magnetic indicators include, but are not limited to, magnetic saturation magnetization. In other embodiments, the magnetic pigment may also be magnetically fixed with a 3D effect.
The anti-counterfeiting pigment composition has a preset reflectivity to an infrared band, for example, the preset reflectivity is 90%, the anti-counterfeiting pigment composition has a preset transmittance to a visible light band, for example, the preset transmittance is 95%, the pigment with anti-counterfeiting characteristics has a preset anti-counterfeiting index, for example, the anti-counterfeiting index is a magnetic index, the magnetic index combines the preset reflectivity and the preset transmittance to obtain an identification index, and the identification index is used for anti-counterfeiting identification so as to improve the anti-counterfeiting effect of the anti-counterfeiting pigment composition.
For example, after the anti-counterfeiting pigment composition is printed, the anti-counterfeiting pigment composition has the anti-counterfeiting characteristic of the anti-counterfeiting characteristic pigment on one hand, and on the other hand, infrared signals of the anti-counterfeiting pigment composition can be collected through an infrared signal collecting device, the whole printing area is subjected to micro-area division, infrared signals of different micro-areas have randomness due to printing randomness, the number or the intensity of the infrared signals of the micro-areas are coded, signal data of the whole printing characteristic recognition area is integrated, a unique recognition code (the code can be a two-dimensional code or a bar code) can be formed, anti-counterfeiting traceability can be carried out through establishing a coding data base, the characteristic anti-counterfeiting recognition of one object and one code can be realized, and thus, the anti-counterfeiting effect can be improved.
In summary, the anti-counterfeiting pigment composition combines the pigment with anti-counterfeiting characteristics and the infrared reflection pigment, can realize multiple anti-counterfeiting effects, and is easy to prepare, low in cost, good in color development and high in color uniformity.
Referring to fig. 1, fig. 1 is a schematic flow chart of an embodiment of a method for preparing a security pigment composition provided by the present application, where the method includes:
s11: the method comprises the steps of obtaining a pigment with anti-counterfeiting characteristics and an infrared reflection pigment, wherein the transmittance of the infrared reflection pigment to a visible light wave band is more than 90%, and the reflectance of the infrared reflection pigment to an infrared wave band with the interval of 780nm-1200nm is more than 85%.
Firstly, the pigment with anti-counterfeiting characteristics and the infrared reflection pigment are obtained. For the description of the pigment with the anti-counterfeiting feature and the infrared reflection pigment, reference is made to the description of the above embodiments, and the description is omitted here. Wherein, the transmittance of the infrared reflection pigment to visible light wave band is more than 90%, and the reflectance of the infrared reflection pigment to infrared wave band with the interval of 780nm-1200nm is more than 85%.
S12: mixing the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment according to a preset proportion to obtain the anti-counterfeiting pigment composition, wherein the mass ratio of the pigment with the anti-counterfeiting characteristic is as follows: 10-80 percent of infrared reflection pigment, and the mass ratio of the infrared reflection pigment is as follows: 20 to 90 percent.
After the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment are obtained, the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment can be mixed according to a preset proportion, then the mixture is crushed and uniformly mixed to obtain the anti-counterfeiting pigment composition, and the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment can be respectively crushed and then mixed according to a preset proportion. Wherein, the mass ratio of the pigment with the anti-counterfeiting characteristic is 10-80 percent, and the mass ratio of the infrared reflection pigment is 20-90 percent.
In the application, a database can be prepared in advance, and anti-counterfeiting indexes and infrared test data corresponding to compositions obtained by mixing infrared reflection pigments with anti-counterfeiting characteristics in different proportions are stored in the database. The anti-counterfeiting indexes and the infrared test data corresponding to the compositions with different proportions can be a standard value determined by multiple measurements, or a standard range, so as to be used as a reference in the subsequent composition adjustment. In specific application, namely, when the infrared reflection pigment and the pigment with the anti-counterfeiting characteristic are actually matched, the infrared reflection pigment and the pigment with the anti-counterfeiting characteristic can be firstly matched according to a preset proportion to obtain the anti-counterfeiting pigment composition, and then the anti-counterfeiting pigment composition is measured. For example, the actual anti-counterfeiting index and infrared test data of the composition are measured. Then comparing the measured actual result with the test data of the composition in the database under the same proportion, and if the measured result is consistent with the data in the corresponding database or the difference between the measured result and the data in the database is small, such as the error does not exceed five percent, the formulated anti-counterfeiting pigment composition is qualified; if the measured result is not consistent with the corresponding test data in the database, or the difference between the two is large, for example, the error exceeds five percent, the formulated composition is considered to be unqualified, and the formulated composition needs to be adjusted. After the adjustment, the anti-counterfeiting index and the infrared data of the blended composition are measured continuously, and the obtained measurement result is compared with the test data until the measurement result is consistent with the test data. By the method, the proportion of the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment can be intelligently blended to obtain the anti-counterfeiting pigment composition meeting the conditions, and the reliability of preparing the anti-counterfeiting pigment composition is improved.
In summary, the preparation method of the anti-counterfeiting pigment composition provided by the application is simple and easy to prepare, and the anti-counterfeiting pigment composition obtained by the preparation method has low cost.
The above description is only for the purpose of illustrating embodiments of the present application and is not intended to limit the scope of the present application, and all modifications of equivalent structures and equivalent processes, which are made by the contents of the specification and the drawings of the present application or are directly or indirectly applied to other related technical fields, are also included in the scope of the present application.
Claims (10)
1. A security pigment composition, characterized in that the security pigment composition comprises: the pigment with the anti-counterfeiting characteristic comprises a pigment with the anti-counterfeiting characteristic and an infrared reflection pigment, wherein the mass ratio of the pigment with the anti-counterfeiting characteristic is as follows: 10-80%, wherein the mass ratio of the infrared reflection pigment is as follows: 20 to 90 percent of the total weight of the mixture,
the transmittance of the infrared reflection pigment to a visible light wave band is larger than 90%, and the reflectivity of the infrared reflection pigment to an infrared wave band with the interval of 780-1200 nm is larger than 85%.
2. The anti-counterfeiting pigment composition according to claim 1, wherein the anti-counterfeiting pigment composition has a preset reflectivity for infrared band and a preset transmittance for visible band, the pigment with anti-counterfeiting characteristics has a preset anti-counterfeiting index, and the preset anti-counterfeiting index combines the preset reflectivity and the preset transmittance to obtain an identification index, and the identification index is used for anti-counterfeiting identification.
3. A security pigment composition as claimed in claim 2 wherein the security-feature pigment comprises optically variable pigments and/or magnetic pigments and the predetermined security criteria comprises magnetic criteria and/or optically variable criteria.
4. The security pigment composition of claim 1 wherein the security pigment is a photonic crystal, platelet-like pearlescent material, or platelet-like film material.
5. A security pigment composition as claimed in claim 1, wherein the infrared-reflective pigment is a sheet-like material of a material having a refractive index of not more than 1.65 and/or a stack of materials having a refractive index of more than 1.65.
6. A security pigment composition as claimed in claim 5, wherein the material having a refractive index of not more than 1.65 comprises: silica, alumina, magnesium fluoride, aluminum fluoride, cerium fluoride, lanthanum fluoride, neodymium fluoride, samarium fluoride, barium fluoride, calcium fluoride, lithium fluoride polystyrene, polyethylene, polymethyl methacrylate, polyamideimide, polyperfluoroethylpropylene, tetrafluoroethylene, chlorotrifluoroethylene, cellulose propionate, cellulose acetate butyrate, methylpentene polymer, homopolyformaldehyde, acrylic resin, cellulose nitrate, ethyl cellulose, polypropylene, polysulfone, polyethersulfone, mica, a heteroisomorphous polymer, polybutene, an ionomer, an acrylic copolymer, a thermoplastic, styrene butadiene, polyvinyl chloride, urea formaldehyde, styrene acrylonitrile, or a polycarbonate; the material with the refractive index larger than 1.65 comprises: lanthanum titanate, trititanium pentoxide, niobium pentoxide, zinc sulfide, zinc oxide, zirconium oxide, titanium dioxide, carbon, indium oxide, indium tin oxide, tantalum pentoxide, cerium oxide, yttrium oxide, europium oxide, iron oxide, triiron tetroxide, hafnium nitride, hafnium carbide, hafnium oxide, lanthanum oxide, magnesium oxide, neodymium oxide, praseodymium oxide, samarium oxide, antimony trioxide, silicon carbide, silicon nitride, silicon monoxide, selenium trioxide, tin oxide, or tungsten trioxide.
7. A method for preparing a security pigment composition, the method comprising:
obtaining a pigment with anti-counterfeiting characteristics and an infrared reflection pigment, wherein the transmittance of the infrared reflection pigment to a visible light wave band is more than 90%, and the reflectivity of the infrared reflection pigment to an infrared wave band with an interval of 780-1200 nm is more than 85%;
mixing the pigment with the anti-counterfeiting characteristic and the infrared reflection pigment according to a preset proportion to obtain the anti-counterfeiting pigment composition, wherein the mass ratio of the pigment with the anti-counterfeiting characteristic is as follows: 10% -80%, wherein the infrared reflection pigment comprises the following components in percentage by mass: 20 to 90 percent.
8. The preparation method of claim 7, wherein the anti-counterfeiting pigment composition has a predetermined reflectivity in the infrared band and a predetermined transmittance in the visible band, the pigment with anti-counterfeiting characteristics has a predetermined anti-counterfeiting index, and the predetermined anti-counterfeiting index combines the predetermined reflectivity and the predetermined transmittance to obtain an identification index, and the identification index is used for anti-counterfeiting identification.
9. The method according to claim 8, wherein the pigment with security feature comprises optically variable pigment and/or magnetic pigment, and the predetermined security index comprises magnetic index and/or optically variable index.
10. The method of claim 7, wherein the security pigment is a photonic crystal, a flake pearlescent material, or a flake film material.
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Application publication date: 20220603 |