CN114574021A - UV-curable art pigment and preparation method thereof - Google Patents
UV-curable art pigment and preparation method thereof Download PDFInfo
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- CN114574021A CN114574021A CN202210325743.0A CN202210325743A CN114574021A CN 114574021 A CN114574021 A CN 114574021A CN 202210325743 A CN202210325743 A CN 202210325743A CN 114574021 A CN114574021 A CN 114574021A
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- 239000000049 pigment Substances 0.000 title claims abstract description 51
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 239000000178 monomer Substances 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 17
- 239000000853 adhesive Substances 0.000 claims abstract description 16
- 230000001070 adhesive effect Effects 0.000 claims abstract description 16
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 12
- 238000009736 wetting Methods 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 6
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical group C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 5
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- 239000004814 polyurethane Substances 0.000 claims abstract description 4
- 229920002635 polyurethane Polymers 0.000 claims abstract description 4
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000011347 resin Substances 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 claims abstract description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 29
- 238000010008 shearing Methods 0.000 claims description 25
- 239000002002 slurry Substances 0.000 claims description 25
- 239000006185 dispersion Substances 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 239000003973 paint Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000006229 carbon black Substances 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 2
- 239000000203 mixture Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 230000007547 defect Effects 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- 238000001514 detection method Methods 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- JETSKDPKURDVNI-UHFFFAOYSA-N [C].[Ca] Chemical compound [C].[Ca] JETSKDPKURDVNI-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses an ultraviolet-curable art pigment and a preparation method thereof, wherein the pigment is prepared from the following raw materials in parts by mass: 30-40 parts of UV prepolymer, 32-42 parts of monomer, 6-8 parts of photoinitiator, 10-40 parts of pigment, 8-10 parts of filler, 0.5-1 part of dispersing aid, 0.2-0.5 part of wetting aid, 0.5-1 part of defoaming aid and 0.2 part of leveling aid, wherein the UV prepolymer is one of epoxy acrylate, polyester acrylate resin, polyurethane acrylic resin and pure acrylate resin, and the monomer is tripropylene glycol diacrylate or 1, 6-hexanediol diacrylate resin. The method can improve the comprehensive performance of the pigment, shorten the curing time, enhance the three-dimensional effect of the picture, and overcome the defects that the solid content of the water-based art pigment is too low and the water-based art pigment is difficult to have three-dimensional effect, and the curing speed is quite slow and the curing time is long due to the water solubility of the adhesive system.
Description
Technical Field
The invention belongs to the field of art pigments, and particularly relates to an ultraviolet-curable art pigment and a preparation method thereof.
Background
Ultraviolet curing generally refers to a process of curing by a rapid polymerization reaction after irradiation of ultraviolet light. In the past, most of art pigments are mainly water-based, namely watercolor pigments. In the art of art paints in the past, aqueous art paints have been developed for many years, but have their own disadvantages: solid content is too low to have stereoscopic impression; ② the curing speed is rather slow and the curing time is long due to the water solubility of the adhesive system.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide the art pigment which can accelerate curing, is fully cured and has strong stereoscopic impression and can be cured by ultraviolet light and the preparation method thereof.
In order to achieve the purpose, the invention adopts the technical scheme that:
an ultraviolet-curable art pigment is prepared from the following raw materials in parts by mass:
30-40 parts of UV prepolymer; 32-42 parts of a monomer;
6-8 parts of a photoinitiator; 10-40 parts of pigment;
8-10 parts of a filler; 0.5-1 part of dispersing auxiliary agent;
0.2-0.5 part of wetting assistant; 0.5-1 part of defoaming auxiliary agent;
0.2 part of leveling auxiliary agent;
the UV prepolymer is one of epoxy acrylate, polyester acrylate resin, polyurethane acrylic resin and pure acrylate resin;
the monomer is tripropylene glycol diacrylate or 1, 6-hexanediol diacrylate resin.
The pigment is a compound of one or more than two of titanium dioxide, 6# carbon black, CI pigment red 8 and 19# purple.
The filler is light superfine calcium carbon black or superfine barium sulfate.
The preparation method of the art pigment capable of being cured by ultraviolet light comprises the following steps:
1) adding the UV prepolymer into a dispersion machine, and shearing and dispersing for 10-15 minutes at 400-600 rpm;
2) adding the monomer into a dispersion machine, and shearing and dispersing for 30-35 minutes at 400-600 rpm to prepare an adhesive;
3) adding a photoinitiator solution into the adhesive, and heating to completely dissolve the photoinitiator solution at the heating temperature of 60-80 ℃;
4) adding the pigment into an adhesive system, and shearing and dispersing for 60-70 minutes at 600-3600 r/min to obtain slurry;
5) adding a filler into the slurry, and shearing and dispersing for 30-40 minutes;
6) adding a dispersing aid and a wetting aid into the slurry, and shearing and dispersing for 15-20 minutes;
7) pouring the dispersed slurry into a grinding machine which is a three-roller grinding machine, wherein the times of dispersing white, red and yellow colors are three, and the times of grinding black, purple and other deep colors are five, the materials are ground until the fineness is less than 5 micrometers, the grinding speed is 100KG/30 minutes, a scraper fineness meter is used for fineness detection, and the detection mode can refer to 'operating specification of the scraper fineness meter';
8) and pouring the ground slurry into a dispersion machine, adding a defoaming auxiliary agent and a leveling auxiliary agent, and uniformly dispersing to obtain the ultraviolet-curable art pigment.
The invention utilizes the characteristic that the acrylic resin structure with the molecular chain end containing active double bonds can be used for carrying out bridging reaction to achieve curing effect, and the UV prepolymer, the monomer, the photoinitiator, the pigment, the filler, the dispersing auxiliary agent, the wetting auxiliary agent, the defoaming auxiliary agent and the leveling auxiliary agent are matched and used according to different proportions, so that an ultraviolet curing art pigment product with practical value can be flexibly designed, the comprehensive performance of the pigment can be improved, the curing time can be shortened, and the three-dimensional effect of the picture can be enhanced. Overcomes the defects that the water-based art pigment has low solid content and is difficult to have stereoscopic impression, and the curing speed is quite slow and the curing time is long because the adhesive system is water-soluble in the prior art pigment.
The product prepared by the invention can achieve the performance and effect of rapid curing and 3D (three-dimensional) stereoscopic property, has the advantages of low energy consumption and low pollution, has the advantages of excellent high gloss, stable chemical property and high curing speed, and provides conditions for the development of painting and block print to a direction of higher and new technology.
Detailed Description
Example 1
An ultraviolet-curable art pigment is prepared from the following raw materials in parts by mass:
30 parts of UV prepolymer;
32 parts of a monomer;
6 parts of a photoinitiator;
10 parts of pigment;
8 parts of a filler;
0.5 part of a dispersing auxiliary agent;
0.2 part of wetting assistant;
0.5 part of defoaming auxiliary agent;
0.2 part of leveling auxiliary agent;
wherein, the UV prepolymer is epoxy acrylate, the monomer is tripropylene glycol diacrylate, the pigment is titanium dioxide, and the filler is light ultrafine calcium carbonate black.
The preparation method of the art pigment capable of being cured by ultraviolet light comprises the following steps:
1) adding the UV prepolymer into a dispersion machine, and shearing and dispersing for 15 minutes at 400 rpm;
2) adding the monomers into a dispersion machine, and shearing and dispersing for 35 minutes at a speed of 400 revolutions per minute to prepare an adhesive;
3) adding a photoinitiator solution into the adhesive, and heating to completely dissolve the photoinitiator solution at the heating temperature of 60 ℃;
4) adding the pigment into a binder system, and shearing and dispersing for 70 minutes at 600 revolutions per minute to obtain slurry;
5) adding a filler into the slurry, and shearing and dispersing for 30 minutes;
6) adding a dispersing aid and a wetting aid into the slurry, and shearing and dispersing for 15 minutes;
7) pouring the dispersed slurry into a grinder, grinding until the fineness of the material is less than 5 micrometers, wherein the grinding speed is 100KG/30 minutes, a scraper blade fineness meter is used for fineness detection, and the detection mode can refer to 'operation procedures of the scraper blade fineness meter';
8) and pouring the ground slurry into a dispersion machine, adding a defoaming auxiliary agent and a leveling auxiliary agent, and uniformly dispersing to obtain the ultraviolet-curable art pigment.
Example 2
An art paint capable of being cured by ultraviolet light is prepared from the following raw materials in parts by mass:
35 parts of UV prepolymer;
37 parts of a monomer;
7 parts of a photoinitiator;
25 parts of pigment;
9 parts of a filler;
0.75 part of dispersing auxiliary agent;
0.35 part of wetting assistant;
0.75 part of defoaming auxiliary agent;
0.2 part of leveling auxiliary agent;
wherein, the UV prepolymer is polyester acrylate resin, the monomer is 1, 6-hexanediol diacrylate resin, the pigment is No. 6 carbon black, and the filler is superfine barium sulfate.
The preparation method of the art pigment capable of being cured by the ultraviolet light comprises the following steps:
1) adding the UV prepolymer into a dispersion machine, and shearing and dispersing for 12 minutes at 500 revolutions per minute;
2) adding the monomers into a dispersion machine, and shearing and dispersing for 30 minutes at 500 revolutions per minute to prepare an adhesive;
3) adding a photoinitiator solution into the adhesive, and heating to completely dissolve the photoinitiator solution at 80 ℃;
4) adding the pigment into an adhesive system, and shearing and dispersing for 60 minutes at 2000 rpm to obtain slurry;
5) adding a filler into the slurry, and shearing and dispersing for 30 minutes;
6) adding a dispersing aid and a wetting aid into the slurry, and shearing and dispersing for 15 minutes;
7) pouring the dispersed slurry into a grinding machine which is a three-roller grinding machine, grinding until the fineness of the material is less than 5 micrometers, wherein the grinding speed is 100KG/30 minutes, a scraper blade fineness meter is used for fineness detection, and the detection mode can refer to 'operation specification of the scraper blade fineness meter';
8) and pouring the ground slurry into a dispersion machine, adding a defoaming auxiliary agent and a leveling auxiliary agent, and uniformly dispersing to obtain the ultraviolet-curable art pigment.
Example 3
An art paint capable of being cured by ultraviolet light is prepared from the following raw materials in parts by mass:
40 parts of UV prepolymer;
42 parts of a monomer;
8 parts of a photoinitiator;
40 parts of pigment;
10 parts of a filler;
1 part of a dispersing auxiliary agent;
0.5 part of wetting assistant;
1 part of defoaming auxiliary agent;
0.2 part of leveling auxiliary agent;
wherein, the UV prepolymer is polyurethane acrylic resin, the monomer is tripropylene glycol diacrylate, the pigment is CI pigment red 8, and the filler is light ultrafine calcium carbonate black.
The preparation method of the art pigment capable of being cured by ultraviolet light comprises the following steps:
1) adding the UV prepolymer into a dispersion machine, and shearing and dispersing for 10 minutes at 600 revolutions per minute;
2) adding the monomers into a dispersion machine, and shearing and dispersing for 30 minutes at 600 revolutions per minute to prepare an adhesive;
3) adding a photoinitiator solution into the adhesive, and heating to completely dissolve, wherein the heating temperature is 60-80 ℃;
4) adding the pigment into a binder system, and shearing and dispersing at 3600 rpm for 60 minutes to obtain slurry;
5) adding a filler into the slurry, and shearing and dispersing for 35 minutes;
6) adding a dispersing aid and a wetting aid into the slurry, and shearing and dispersing for 15 minutes;
7) pouring the dispersed slurry into a grinding machine which is a three-roller grinding machine, grinding until the fineness of the material is less than 5 micrometers, wherein the grinding speed is 100KG/30 minutes, a scraper blade fineness meter is used for fineness detection, and the detection mode can refer to 'operation specification of the scraper blade fineness meter';
8) and pouring the ground slurry into a dispersion machine, adding a defoaming auxiliary agent and a leveling auxiliary agent, and uniformly dispersing to obtain the ultraviolet-curable art pigment.
Claims (6)
1. The art pigment capable of being cured by ultraviolet light is characterized by being prepared from the following raw materials in parts by mass:
30-40 parts of UV prepolymer; 32-42 parts of a monomer;
6-8 parts of a photoinitiator; 10-40 parts of a pigment;
8-10 parts of a filler; 0.5-1 part of dispersing auxiliary agent;
0.2-0.5 part of wetting assistant; 0.5-1 part of defoaming auxiliary agent;
0.2 part of leveling auxiliary agent;
the UV prepolymer is one of epoxy acrylate, polyester acrylate resin, polyurethane acrylic resin and pure acrylate resin;
the monomer is tripropylene glycol diacrylate or 1, 6-hexanediol diacrylate resin.
2. The UV-curable art pigment according to claim 1, wherein the pigment is a mixture of one or more of titanium dioxide, 6# carbon black, CI pigment Red 8 and 19# Violet.
3. An ultraviolet-curable art pigment according to claim 1, wherein the filler is light ultra-fine calcium carbonate or ultra-fine barium sulfate.
4. A process for producing an ultraviolet-curable art pigment as set forth in claim 1, which comprises the steps of:
1) adding the UV prepolymer into a dispersion machine, and shearing and dispersing for 10-15 minutes at 400-600 rpm;
2) adding the monomer into a dispersion machine, and shearing and dispersing for 30-35 minutes at 400-600 rpm to prepare an adhesive;
3) adding a photoinitiator solution into the adhesive, and heating until the photoinitiator solution is completely dissolved;
4) adding the pigment into an adhesive system, and shearing and dispersing for 60-70 minutes at 600-3600 rpm to obtain slurry;
5) adding a filler into the slurry, and shearing and dispersing for 30-40 minutes;
6) adding a dispersing aid and a wetting aid into the slurry, and shearing and dispersing for 15-20 minutes;
7) pouring the dispersed slurry into a grinder, and grinding until the fineness of the material is less than 5 microns;
8) and pouring the ground slurry into a dispersion machine, adding a defoaming auxiliary agent and a leveling auxiliary agent, and uniformly dispersing to obtain the ultraviolet-curable art pigment.
5. A process for preparing an ultraviolet-curable art pigment according to claim 4, wherein the heating temperature in the step 3) is 60 to 80 ℃.
6. A process for preparing an ultraviolet-curable art paint according to claim 4, wherein in the step 7), the grinding speed is 100KG/30 min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210325743.0A CN114574021A (en) | 2022-03-30 | 2022-03-30 | UV-curable art pigment and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210325743.0A CN114574021A (en) | 2022-03-30 | 2022-03-30 | UV-curable art pigment and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN114574021A true CN114574021A (en) | 2022-06-03 |
Family
ID=81781655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210325743.0A Pending CN114574021A (en) | 2022-03-30 | 2022-03-30 | UV-curable art pigment and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN114574021A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805534A (en) * | 2009-12-25 | 2010-08-18 | 深圳云之彩美术工艺用品有限公司 | Color-change pigment |
| CN103881557A (en) * | 2014-02-26 | 2014-06-25 | 金甲化工企业(中山)有限公司 | Colored UV dope |
| CN105030566A (en) * | 2015-06-23 | 2015-11-11 | 上海零玖科技有限公司 | Ultraviolet curing fingernail pigment and preparation method thereof |
-
2022
- 2022-03-30 CN CN202210325743.0A patent/CN114574021A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805534A (en) * | 2009-12-25 | 2010-08-18 | 深圳云之彩美术工艺用品有限公司 | Color-change pigment |
| CN103881557A (en) * | 2014-02-26 | 2014-06-25 | 金甲化工企业(中山)有限公司 | Colored UV dope |
| CN105030566A (en) * | 2015-06-23 | 2015-11-11 | 上海零玖科技有限公司 | Ultraviolet curing fingernail pigment and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 刘琳等: "紫外光固化环氧丙烯酸酯涂料的研制", 《涂料工业》 * |
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