CN114573328A - High-alumina brick produced by using waste high-alumina brick and production process thereof - Google Patents

High-alumina brick produced by using waste high-alumina brick and production process thereof Download PDF

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Publication number
CN114573328A
CN114573328A CN202011386013.9A CN202011386013A CN114573328A CN 114573328 A CN114573328 A CN 114573328A CN 202011386013 A CN202011386013 A CN 202011386013A CN 114573328 A CN114573328 A CN 114573328A
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granularity
parts
alumina
waste
alumina brick
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CN202011386013.9A
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Inventor
张向前
鲁志燕
唐兵
于宝童
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Prco Kisc Yunnan Refractories Co ltd
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Prco Kisc Yunnan Refractories Co ltd
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Publication of CN114573328A publication Critical patent/CN114573328A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/10Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on aluminium oxide
    • C04B35/101Refractories from grain sized mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/77Density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention discloses a high-alumina brick produced by using waste high-alumina bricks and a production process thereof, which is characterized in that: the high-alumina brick comprises the following components in parts by weight: 3-6 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1-2 parts of waste high-alumina bricks with the granularity of 0-0.088mm, 0-3 parts of No. 60 bauxite with the granularity of 0.089-4mm, 0-1 part of No. 60 bauxite with the granularity of 0-0.088mm, and 1-2 parts of soft clay powder with the granularity of 0-0.088 mm; the high-alumina brick has high compression strength, good wear resistance and good thermal shock performance, and has good use effect on a lime kiln and a heating furnace.

Description

High-alumina brick produced by using waste high-alumina brick and production process thereof
Technical Field
The invention relates to the field of refractory materials, in particular to a high-alumina brick produced by utilizing waste high-alumina bricks and a production process thereof.
Background
The high-alumina brick is mainly produced by using high-alumina bauxite clinker and partial combined clay. The bauxite raw material belongs to non-renewable resources, and along with the gradual mining of the raw material, the raw material resources are gradually reduced, and the raw material price is gradually increased; by recycling the waste high-alumina bricks, the recycling rate of waste resources is improved, resources and energy are saved, the emission of industrial wastes is reduced, the national industrial development environmental protection policy requirements are met, the product formula cost is reduced, and the product competitiveness is improved.
Disclosure of Invention
The invention aims to provide a high-alumina brick produced by using waste high-alumina bricks and a production process thereof aiming at the defects of the prior art.
In order to achieve the above object, the present invention is achieved by the following technical solutions.
The utility model provides an utilize high-alumina brick of useless high-alumina brick production which characterized in that: the high-alumina brick comprises the following components in parts by weight: 3-6 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1-2 parts of waste high-alumina bricks with the granularity of 0-0.088mm, 0-3 parts of 60# bauxite with the granularity of 0.089-4mm, 0-1 part of 60# bauxite with the granularity of 0-0.088mm and 1-2 parts of soft clay powder with the granularity of 0-0.088 mm.
Further, the high-alumina brick comprises the following components in parts by weight: 3 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1 part of waste high-alumina bricks with the granularity of 0-0.088mm, 3 parts of No. 60 bauxite with the granularity of 0.089-4mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
Further, the high-alumina brick comprises the following components in parts by weight: 6 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1 part of waste high-alumina bricks with the granularity of 0-0.088mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
Further, the high-alumina brick comprises the following components in parts by weight: 4 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 2 parts of waste high-alumina bricks with the granularity of 0-0.088mm, 2 parts of No. 60 bauxite with the granularity of 0.089-4mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 1 part of soft clay powder with the granularity of 0-0.088 mm.
Further, the high-alumina brick comprises the following components in parts by weight: 6 parts of waste high-alumina brick with the granularity of 0.089-4mm, 2 parts of waste high-alumina brick with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
Furthermore, the waste high-alumina brick with the granularity of 0.089-4mm and 0-0.088mm has the content of aluminum oxide of 60-75 percent and the content of ferric oxide in the waste high-alumina brick is less than 2.5 percent.
The process for producing high-alumina bricks from waste high-alumina bricks according to any one of claims 1 to 5, which comprises the following steps:
(1) treating waste high-alumina bricks: the waste high-alumina bricks are crushed, and iron removal treatment is carried out in the crushing process, so that surface karst caves or over-standard black spots caused by high iron content in the firing process are reduced;
(2) mixing and stirring: weighing the raw materials according to the proportion, putting the raw materials into a wet mill, premixing for 2-3 min, adding 4-6 parts by weight of syrup water solution, and mixing and stirring for 10-15 min to obtain an initial product;
(3) pressing: putting the primary product into a press machine to be pressed into a mold, and then firing the mold in a kiln to obtain a semi-finished product;
(4) firing: drying the obtained semi-finished product at the temperature of 80-150 ℃ for 18-30 hours, and then firing at the high temperature of 1300-1350 ℃ for 6-8 hours to obtain the finished product.
The invention has the beneficial effects that: the high-alumina brick product produced by the proportion and the process has the compression strength of more than 50MPa, the apparent porosity of less than or equal to 26 percent and the refractoriness under load of 0.2MPa of more than or equal to 1450 ℃. The high-alumina brick has high compression strength, good wear resistance and good thermal shock performance, and has good use effect on a lime kiln and a heating furnace.
Detailed Description
The present invention is further illustrated by the following examples, but is not limited to the details of the description.
The invention aims to provide a high-alumina brick produced by using waste high-alumina bricks and a production process thereof aiming at the defects of the prior art.
In order to achieve the above object, the present invention is achieved by the following technical solutions.
The utility model provides an utilize high-alumina brick of useless high-alumina brick production which characterized in that: the high-alumina brick comprises the following components in parts by weight: 3-6 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1-2 parts of waste high-alumina bricks with the granularity of 0-0.088mm, 0-3 parts of 60# bauxite with the granularity of 0.089-4mm, 0-1 part of 60# bauxite with the granularity of 0-0.088mm and 1-2 parts of soft clay powder with the granularity of 0-0.088 mm.
The waste high-alumina brick with the granularity of 0.089-4mm and 0-0.088mm has the content of aluminum oxide of 60-75 percent and the content of ferric oxide in the waste high-alumina brick of less than 2.5 percent.
Specific example 1: the high-alumina brick comprises the following components in parts by weight: 3 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1 part of waste high-alumina bricks with the granularity of 0-0.088mm, 3 parts of No. 60 bauxite with the granularity of 0.089-4mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
Specific example 2: the high-alumina brick comprises the following components in parts by weight: 6 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1 part of waste high-alumina bricks with the granularity of 0-0.088mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
Specific example 3: the high-alumina brick comprises the following components in parts by weight: 4 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 2 parts of waste high-alumina bricks with the granularity of 0-0.088mm, 2 parts of No. 60 bauxite with the granularity of 0.089-4mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 1 part of soft clay powder with the granularity of 0-0.088 mm.
Specific example 4: the high-alumina brick comprises the following components in parts by weight: 6 parts of waste high-alumina brick with the granularity of 0.089-4mm, 2 parts of waste high-alumina brick with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
The process for producing high-alumina bricks from waste high-alumina bricks according to any one of claims 1 to 5, which comprises the following steps:
(1) treating waste high-alumina bricks: the waste high-alumina bricks are crushed, and iron removal treatment is carried out in the crushing process, so that surface karst caves or over-standard black spots caused by high iron content in the firing process are reduced;
(2) mixing and stirring: weighing the raw materials according to the proportion, putting the raw materials into a wet mill, premixing for 2-3 min, adding 4-6 parts by weight of syrup water solution, and mixing and stirring for 10-15 min to obtain an initial product;
(3) pressing: putting the primary product into a press machine to be pressed into a mold, and then firing the mold in a kiln to obtain a semi-finished product;
(4) firing: drying the obtained semi-finished product at the temperature of 80-150 ℃ for 18-30 hours, and then firing at the high temperature of 1300-1350 ℃ for 6-8 hours to obtain the finished product.
The invention has the beneficial effects that: by passingThe high-alumina brick product produced by the proportioning and the process has the compression strength of more than 50MPa, the content of aluminum oxide of more than or equal to 55 percent and the volume density of more than or equal to 2.25g/cm3The apparent porosity is less than or equal to 26 percent, and the refractoriness under load of 0.2MPa is more than or equal to 1450 ℃. The high-alumina brick has high compression strength, good wear resistance and good thermal shock performance, and has good use effect on a lime kiln and a heating furnace. It should be understood that the above-described embodiments of the present invention are merely examples for clearly illustrating the present invention, and are not intended to limit the embodiments of the present invention. Other variations and modifications will be apparent to persons skilled in the art in light of the above description. Not all embodiments are exhaustive. All obvious changes and modifications which are obvious to the technical scheme of the invention are covered by the protection scope of the invention.

Claims (7)

1. The utility model provides an utilize high-alumina brick of useless high-alumina brick production which characterized in that: the high-alumina brick comprises the following components in parts by weight: 3-6 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1-2 parts of waste high-alumina bricks with the granularity of 0-0.088mm, 0-3 parts of 60# bauxite with the granularity of 0.089-4mm, 0-1 part of 60# bauxite with the granularity of 0-0.088mm, and 1-2 parts of soft clay powder with the granularity of 0-0.088 mm.
2. The high-alumina brick produced by using the waste high-alumina brick as claimed in claim 1, which is characterized in that: the high-alumina brick comprises the following components in parts by weight: 3 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1 part of waste high-alumina bricks with the granularity of 0-0.088mm, 3 parts of No. 60 bauxite with the granularity of 0.089-4mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
3. The high-alumina brick produced by utilizing waste high-alumina bricks according to claim 1, which is characterized in that: the high-alumina brick comprises the following components in parts by weight: 6 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 1 part of waste high-alumina bricks with the granularity of 0-0.088mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
4. The high-alumina brick produced by utilizing waste high-alumina bricks according to claim 1, which is characterized in that: the high-alumina brick comprises the following components in parts by weight: 4 parts of waste high-alumina bricks with the granularity of 0.089-4mm, 2 parts of waste high-alumina bricks with the granularity of 0-0.088mm, 2 parts of No. 60 bauxite with the granularity of 0.089-4mm, 1 part of No. 60 bauxite with the granularity of 0-0.088mm and 1 part of soft clay powder with the granularity of 0-0.088 mm.
5. The high-alumina brick produced by using the waste high-alumina brick as claimed in claim 1, which is characterized in that: the high-alumina brick comprises the following components in parts by weight: 6 parts of waste high-alumina brick with the granularity of 0.089-4mm, 2 parts of waste high-alumina brick with the granularity of 0-0.088mm and 2 parts of soft clay powder with the granularity of 0-0.088 mm.
6. The alumina brick produced by using the waste alumina brick according to any one of claims 1 to 5, wherein the waste alumina brick with the grain size of 0.089 to 4mm and 0 to 0.088mm has an alumina content of 60 to 75 percent and an iron oxide content of less than 2.5 percent.
7. The process for producing high-alumina bricks from waste high-alumina bricks according to any one of claims 1 to 5, which comprises the following steps:
(1) treating waste high-alumina bricks: the waste high-alumina bricks are crushed, and iron removal treatment is carried out in the crushing process, so that surface karst caves or over-standard black spots caused by high iron content in the firing process are reduced;
(2) mixing and stirring: weighing the raw materials according to the proportion, putting the raw materials into a wet mill, premixing for 2-3 min, adding 4-6 parts by weight of syrup water solution, and mixing and stirring for 10-15 min to obtain an initial product;
(3) pressing: putting the primary product into a press machine to be pressed into a mold, and then firing the mold in a kiln to obtain a semi-finished product;
(4) and (3) firing: drying the obtained semi-finished product at the temperature of 80-150 ℃ for 18-30 hours, and then firing at the high temperature of 1300-1350 ℃ for 6-8 hours to obtain the finished product.
CN202011386013.9A 2020-12-01 2020-12-01 High-alumina brick produced by using waste high-alumina brick and production process thereof Pending CN114573328A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3953563A (en) * 1970-04-01 1976-04-27 Advanced Mineral Research Method for producing high alumina refractory material
CN101139208A (en) * 2006-09-05 2008-03-12 宝山钢铁股份有限公司 Low-cost fire-resistant pouring material and method for making same
CN102161212A (en) * 2011-01-18 2011-08-24 北京利尔高温材料股份有限公司 Method for manufacturing low-cost slag blocking dam
CN105130472A (en) * 2015-09-10 2015-12-09 中钢集团耐火材料有限公司 Low-cost high-aluminum fireproof brick
CN110577397A (en) * 2019-08-28 2019-12-17 云南濮耐昆钢高温材料有限公司 high-performance clay brick produced by waste clay brick and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3953563A (en) * 1970-04-01 1976-04-27 Advanced Mineral Research Method for producing high alumina refractory material
CN101139208A (en) * 2006-09-05 2008-03-12 宝山钢铁股份有限公司 Low-cost fire-resistant pouring material and method for making same
CN102161212A (en) * 2011-01-18 2011-08-24 北京利尔高温材料股份有限公司 Method for manufacturing low-cost slag blocking dam
CN105130472A (en) * 2015-09-10 2015-12-09 中钢集团耐火材料有限公司 Low-cost high-aluminum fireproof brick
CN110577397A (en) * 2019-08-28 2019-12-17 云南濮耐昆钢高温材料有限公司 high-performance clay brick produced by waste clay brick and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
上海黑色冶金设计院: "《小型高铁联合企业》", 30 November 1959, 上海科学技术出版社, pages: 67 - 68 *
钟香崇译: "《高级耐火材料》", 30 November 1956, 冶金工业出版社, pages: 131 - 132 *

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