CN1145728C - Canvasses reinforced with metal members - Google Patents

Canvasses reinforced with metal members Download PDF

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Publication number
CN1145728C
CN1145728C CNB008041423A CN00804142A CN1145728C CN 1145728 C CN1145728 C CN 1145728C CN B008041423 A CNB008041423 A CN B008041423A CN 00804142 A CN00804142 A CN 00804142A CN 1145728 C CN1145728 C CN 1145728C
Authority
CN
China
Prior art keywords
band
metalwork
thermoplastic
canvas
prime coat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB008041423A
Other languages
Chinese (zh)
Other versions
CN1341177A (en
Inventor
��L����˹��ɭ
L·阿德里安森
G·梵德瓦勒
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bekaert NV SA
Original Assignee
Bekaert NV SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bekaert NV SA filed Critical Bekaert NV SA
Publication of CN1341177A publication Critical patent/CN1341177A/en
Application granted granted Critical
Publication of CN1145728C publication Critical patent/CN1145728C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/04—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles
    • D04H3/045—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles for net manufacturing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0094—Fibrous material being coated on one surface with at least one layer of an inorganic material and at least one layer of a macromolecular material
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04H—BUILDINGS OR LIKE STRUCTURES FOR PARTICULAR PURPOSES; SWIMMING OR SPLASH BATHS OR POOLS; MASTS; FENCING; TENTS OR CANOPIES, IN GENERAL
    • E04H15/00—Tents or canopies, in general
    • E04H15/32—Parts, components, construction details, accessories, interior equipment, specially adapted for tents, e.g. guy-line equipment, skirts, thresholds
    • E04H15/54—Covers of tents or canopies
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/042—Polyolefin (co)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/045—Vinyl (co)polymers
    • D06N2203/048—Polyvinylchloride (co)polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/061—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/06—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N2203/065—Polyamides

Abstract

The invention relates to a fabric (10) for reinforcement of canvasses. The fabric comprises a warp (12) and a weft (14). At least one of the warp or the weft is formed by a strip comprising at least one elongated metal member (18) and a thermoplastic material (22) as matrix. A primer layer (20) is applied on the metal member before the application of the thermoplastic material to obtain a good adhesion between the thermoplastic material and the metal member.

Description

The canvas that metalwork strengthens
Invention field
The present invention relates to a kind of fabric and band that is used to strengthen the canvas that contains plastic coating.The present invention also relates to be used to strengthen the application of the fabric and the band of the canvas that contains plastic coating.
Background of invention
Illustrate, plastic-faced canvas is used to cover the tote of automobile or container, and they also are used as tent material.
These canvas must satisfy several requirements.
They must be solid to being enough to avoid because tearing of causing of the carrying of tote, Yi Bian simultaneously they want enough pliable and tough in case can be easily and sliding into apace open.Further requiring is that they must have excellent protection to wanton destruction and robbery behavior.Therefore just need be to lancinating or scissors is cut strong opposing.Since the weight limits of canvas the amount of tote of automobile or container traffic, so this weight must be low as much as possible.
A kind of fabric that is used to strengthen canvas has been described in WO98/55682.This enhancing body is made up of the band that contains thermoplastic matrix and several parallel metal spares.
Make pliability that canvas produces and the character that goodish opposing is lancinated or cutter is cut like this.The repellence to scissors that obtains by this embodiment also is nowhere near.
Description of the invention
The purpose of this invention is to provide a kind of fabric that is used to strengthen canvas, this canvas improves to the repellence of lancinating and cutting and scissors are cut.Second purpose of the present invention provides a kind of fabric with good corrosion resistance.Another object of the present invention provides a kind of lightweight fabric.
According to an aspect of the present invention, provide a kind of enhancing to have the fabric of the canvas of plastic coating.This fabric contains warp and parallel.At least a in warp or the parallel forms by containing the band that at least a stretching metalwork and thermoplastic matrix form.Thermoplastic can be adhered on the plastic coating of canvas.Be coated with a prime coat before thermoplastic is coated to said coating metal spare thereon, this is in order to realize good bonding between thermoplastic and the metalwork.This is with the thick 0.5-3mm in cross section, the wide 3-25mm in cross section, preferred thick 0.5-2mm, wide 3-15mm.
Forming the band of warp and the band formation full-size of formation parallel is the net of 5-30cm.The size of these mesh can adapt to the kind of wanting freight.In most cases, preferred maximum dimension is approximately 7-15cm.
The band that forms parallel can be soldered to and form being with of warp, perhaps can be fixed with each other by adhesive.
According to a second aspect of the invention, provide a kind of band that is used to strengthen the canvas that contains plastic coating.This band contains at least one stretching metalwork and thermoplastic matrix.Thermoplastic can be adhered on the plastic coating of canvas.Primer coating layer on metalwork.Needing this prime coat is for thermoplastic is adhered on the metalwork well.Before applying thermoplastic, such prime coat is coated on the metalwork surface.
When primer coating layer not, metal wire can be extracted out from band easily.
And, not being coated with such prime coat, thermoplastic for example polyvinyl chloride can flow away when receiving tape welding on the canvas.At this moment, welding back metalwork will be no longer by base matter around.This will cause fabric to be easy to be corroded.
Preferably, even this material for example heat-treated these tape weldings are received on the canvas, prime coat still keeps its cohesiveness.
Therefore, prime coat preferably can be stood the heat treatment of a few minutes, for example 150 ℃ following 5 minutes and do not lose its character.
The coating of metal upper base enamelled coating has further reduced thermoplastic material layer's thickness.Because the thermoplastic use amount has direct influence to the weight that strengthens canvas, so this point is extremely important.As mentioned above, the weight of canvas is as far as possible for a short time is desired.
Preferably in all directions, metalwork must make band have enough intensity but also must make band keep enough pliabilities.The pliability of band is used for the influence of type of the metalwork of reinforcing band consumingly.
The preferably flat silk of metalwork.Flat silk is pliable and tough on the vertical direction of the flat avris of silk.
Because pliability depends on the thickness of silk, therefore silk is more preferably less than 0.35mm, for example less than 0.30mm preferably less than 0.40mm.
Because the repellence that TENSILE STRENGTH is cut scissors when high increases, so preferred tensile strength 1500N/mm at least 2, more preferably about 1700N/mm 2
In order to obtain required TENSILE STRENGTH, carbon content preferably approximately 0.40%.
Preferably silk is carried out rounding and handle so that the cross section does not have wedge angle, if any, can canvas be damaged.
The I-type silk that operable another metalwork is a fillet.I-type silk is the silk of the similar I-type in cross section.The thickness on these both sides is greater than center thickness.
This flat silk pliability identical with I-type silk center thickness with thickness is identical.Compare with flat silk, I-type silk has improved the repellence that scissors is cut.Though the weight of comparing I-type silk with flat silk has reduced, when the thickness of flat silk thickness and I-type silk left end and right-hand member is identical, I-type silk to the repellence of scissors but with put down thread identical.
In another embodiment, metalwork contains at least two kinds of metalworks.These metalworks are preferably arranged with the plane parallel of band.Metalwork can be the silk of round wire, edgewise wire, rectangle silk or another type.Contact with at least a other metalwork at this each metalwork, so that they form a kind of flat silk together.
The multicomponent of stretching metalwork makes and has good pliability.Owing to form the arrangement of the metalwork of flat silk, therefore kept for lancinating or the repellence of scissors.
In order to improve the corrosion resistance of fabric, metalwork or metalwork group can apply with metal coating, for example zinc or contain 2-10%Al and the 0.1-0.4% rare earth metal kirsite of La and/or Ce for example.
Thermoplastic for example polyvinyl chloride can be coated on the metalwork.This coating can be undertaken by any conventional method.Preferred painting method be extrude, fluid bed applies or plastisol (plastisol) applies.
When the cleaning surfaces of line, the bonding force between prime coat and the line surface improves.Therefore, the grease of removing the line surface before the primer coating layer is expected.
The coating of prime coat can be undertaken by any conventional method.
Operable first group of prime coat is thermosets.Adhesive can be dissolved in the organic solvent, perhaps uses the dispersant of limiting the quantity of that adhesive is dispersed in the water to form emulsion or suspension.
Suitable bonding can be based on acrylate, alkyd/melmac, epoxy or phenolic aldehyde (fenol)/epoxy resin.There is other adhesive of good bond properties also can use for metal and PVC.
Can add for example anticorrosive pigment of additive, wetting agent and/or stabilizing agent.
By metal impregnation is applied to primer layer composition on the metal in solution, emulsion or the suspension of prime coat material; Primer layer composition also can be passed through spray coating.
The thickness of wet prime coat is by calibrating wire and prime coat by the calibration hole of mould.
As a kind of alternative method, the thickness of prime coat can be swept or the calibration of controllable air purge by felt.
The thickness of prime coat can be by further dilution primer layer composition change.
This silk can solidify by heat drying.
Because canvas weight is as far as possible for a short time to be favourable, so prime coat thickness is essential little.The dry bottom thickness of paint layer is more preferably less than 5 μ m preferably less than 10 μ m, for example less than 1 μ m.
The resin of radiation-hardenable is the also suitable priming paint of doing of ultraviolet light polymerization, electronic beam curing or far infrared cured resin for example.
Second group of prime coat that can be coated with is thermoplastic resin, for example ethylene copolymer such as EVA (ethene-vinyl acetate copolymer), polyamide or polyester.In order to obtain enough thin layer, preferably use 200 ℃ of viscosity less than 20Pa.s, be more preferably less than the thermoplastic resin of 15Pa.s.This thermoplastic resin can be coated with by plurality of devices.Well-adapted is to melt pot.Extrusion coatedly also can carry out under certain conditions.A kind of extrusion coating method is disclosed among the patent application BE1006346.
According to the viscosity and the method for primer coating layer, the thickness of prime coat can be less than 25 μ m, for example less than 5 μ m.
The 3rd group is silane compound.A functional group in these coupling agents is responsible for metal or metal oxide bonding, another functional group and polymer reaction.
Can obtain the more detailed description of these silane compounds among the PCT application PCT/BE98/0015.Although these silane compounds can be diluted in other solvent or the water, normally be diluted in the alcohol.Use this compounds can obtain thickness and be 20nm or littler prime coat.
Bonding force in the middle of thermoplastic and the metalwork can pass through following testing evaluation.
Can use sharp of cutter that the PVC layer is vertically moved about 5cm.Use the root face of cutter that the PVC layer is mentioned gently.Try synthetic resin layer is taken off from metalwork with nail at last.
It is difficult more that the PVC layer is taken off, bonding strong more in the middle of PVC and the metalwork.
The primer coating layer thread all carried out above-mentioned test before silk that the PVC layer is directly extruded thereon and PVC layer were extruded.
The PVC layer of directly extruding on metalwork is easy to take off, and when primer coating layer on metalwork the PVC layer take off difficult more.
On metalwork after the primer coating layer, coating thermoplastic material thereon.
Thermoplastic must to canvas produce bonding.Although have good other bonding thermoplastic to use with PVC, because canvas normally applies PVC, so the preferred PVC compound of this thermoplastic.
Canvas also can be to be made by polypropylene, polyethylene or polyester.Be exactly to select with this polymer good bonding thermoplastic is arranged this moment.
Brief description of drawings
The present invention will be explained in more detail with reference to following accompanying drawing.
Fig. 1 represents the fabric according to first aspect present invention.
Fig. 2, Fig. 3 and Fig. 4 represent three bands according to second aspect present invention.
The description of the preferred embodiment for the present invention
Fig. 1 represents the embodiment according to the first aspect present invention fabric.
Fabric 10 contains band that forms warp 12 and the band that forms parallel 14.Be with 12 be with 14 to be welded to one another and to be in the same place.The wide W of mesh is 7.5cm, and the high H of mesh is 15cm.
Fig. 2 represents to be with 16 according to second aspect present invention.
This band comprises the rolling flat steel wire 18 that 4.00 * 0.30mm type is hard, TENSILE STRENGTH R mBe 1700N/mm 2The carbon content of this steel equals 0.70%.
Primer coating 20 on this silk.Alkyd/melmac is dissolved in solvent for example in benzene, dimethylbenzene or the alcohol.Wherein add anticorrosive pigment.Said composition approximately contains 30% adhesive and about 70% solvent.This priming paint is used acetone diluted once more.Behind the dry solidification, this prime coat thickness is 0.8-2.5 μ m.
This band is made matrix material 22 with PVC.This PVC material is by extruding coating.
This bandwidth is 6.00mm, back 0.80mm.
Fig. 3 represent to contain the I-type silk 18 of fillet ' another be with 16.This TENSILE STRENGTH is 1750N/mm 2, carbon content equals 0.80%.This wide 4.00mm.Center thickness 0.30mm, both sides thickness are 0.45mm.This has thick flat pliability for 0.30mm, and the repellence that scissors is cut is suitable with the flat silk of thick 0.45mm.
Primer coating 20 on this silk.Paint base composition composed as follows: about 30% phenolic aldehyde (fenol)/epoxy resin, the alcohol of 8-10%, 2.5% is dissolved in the diethanol amine in the water.The thickness of this prime coat is 1-4 μ m behind the dry solidification.
This band contains PVC and makes matrix material 22.This PVC is coated with by fluidized bed coating.This is flat with 16 at least one surface.
This bandwidth 6.00mm, thick 0.90mm.
Fig. 4 represents to contain four round steel wires 18 that diameter is 0.40mm " with another embodiment of 16.
These are parallel to the planar alignment with 16.Be adjacent to each other at this every rhizoid.
This TENSILE STRENGTH is 2550N/mm 2, carbon content is 0.80%.
Primer coating on this silk.This band contains PVC and makes matrix material 22.This is flat with at least one surface.This bandwidth 5.00mm, thick 0.80mm.

Claims (20)

1. band (16) that is used to strengthen the canvas that contains plastic coating, described band contains the metalwork (18) of at least one stretching and the matrix of thermoplastic (22), described thermoplastic extrusion molding is on the metalwork of described stretching, described thermoplastic can be adhered on the plastic coating of canvas, it is characterized in that being extruded moulding before coating metal spare at said thermoplastic, described stretching metalwork has been used prime coat (20) coating, to realize bonding between said thermoplastic and the said stretching metalwork.
2. the band of claim 1, wherein said prime coat contains thermosets.
3. the band of claim 2, wherein said thermosets is selected from acrylate-based resin, epoxy or pure acidic group resin.
4. the band of claim 1, wherein said prime coat contains a kind of hot melt.
5. the band of claim 4, wherein said hot melt is selected from ethylene copolymer, polyamide or polyester.
6. the band of claim 1, wherein said prime coat contains a kind of bifunctional silane compound.
7. each band among the claim 1-6, wherein said thermoplastic is a polyvinyl chloride.
8. each band among the claim 1-6, wherein said thermoplastic is a kind of polyvinyl chloride compound.
9. each band among the claim 1-6, wherein said metalwork is that TENSILE STRENGTH is greater than 1500N/mm 2Flat silk.
10. each band among the claim 1-6, wherein said metalwork is that TENSILE STRENGTH is greater than 1700N/mm 2Flat silk.
11. each band among the claim 1-6, wherein said metalwork are the flat silk of thickness less than 0.35mm.
12. each band among the claim 1-6, the line of the I-type that wherein said metalwork is a fillet.
13. each band among the claim 1-6, wherein said metalwork are the steel wires of carbon content at least 0.40%.
14. each band among the claim 1-6, wherein said metalwork contains at least two hardwares.
15. the band of claim 14, wherein the plane parallel of metalwork and band is arranged, and other hardware of each hardware and at least one contacts.
16. each band among the claim 1-6, wherein said metalwork is coated with zinc layer or zinc alloy layer.
17. a fabric (10) that is used to strengthen the canvas that contains plastic coating, described fabric comprises warp (12) and parallel (14), and at least a in warp or the parallel is to be formed by each band among the claim 1-16.
18. all passing through described band, the fabric of claim 17, its middle longitude and parallel form.
19. according to each the application of band in strengthening canvas among the claim 1-16.
20. the application of fabric in strengthening canvas according to claim 17 or 18.
CNB008041423A 1999-03-16 2000-03-06 Canvasses reinforced with metal members Expired - Fee Related CN1145728C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP99200806.0 1999-03-16
EP99200806A EP1041192A1 (en) 1999-03-16 1999-03-16 Canvasses reinforced with metal members

Publications (2)

Publication Number Publication Date
CN1341177A CN1341177A (en) 2002-03-20
CN1145728C true CN1145728C (en) 2004-04-14

Family

ID=8239992

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB008041423A Expired - Fee Related CN1145728C (en) 1999-03-16 2000-03-06 Canvasses reinforced with metal members

Country Status (9)

Country Link
EP (2) EP1041192A1 (en)
JP (1) JP2002539342A (en)
CN (1) CN1145728C (en)
AT (1) ATE227368T1 (en)
AU (1) AU3286600A (en)
BR (1) BR0009020B1 (en)
DE (1) DE60000730T2 (en)
ES (1) ES2186635T3 (en)
WO (1) WO2000055419A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2003077692A1 (en) * 2002-03-15 2003-09-25 Eric Hazan Cut-resistant and cut-warning fabric
CN100419196C (en) * 2003-09-19 2008-09-17 贝卡尔特股份有限公司 An architectural fabric
CN100458009C (en) * 2007-04-03 2009-02-04 东华大学 Multifunctional canvas for awning and manufacturing method thereof
ES2731376T3 (en) * 2014-06-30 2019-11-15 Hexcel Holding Gmbh Non-woven fabrics
JP6900594B2 (en) * 2016-07-12 2021-07-07 福井県 Metal / resin fiber tape material woven fabric and its manufacturing method, and metal / resin fiber tape material woven fabric laminate material
CN108950879A (en) * 2018-08-21 2018-12-07 珠海水丝新材料有限公司 A kind of production method of superabsorbent water longitude and latitude non-woven fabrics

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2663965B2 (en) * 1990-02-06 1993-07-02 Tissus Tech De Trevoux SHEET OR SIMILAR MATERIAL HAVING IMPROVED TEAR RESISTANCE.
GB2317363A (en) * 1996-09-20 1998-03-25 C M I Forming a cut resistant material
CN1101871C (en) * 1997-06-06 2003-02-19 贝克特股份有限公司 Canvass reinforcement

Also Published As

Publication number Publication date
BR0009020B1 (en) 2010-11-03
EP1161591B1 (en) 2002-11-06
WO2000055419A1 (en) 2000-09-21
DE60000730D1 (en) 2002-12-12
CN1341177A (en) 2002-03-20
ATE227368T1 (en) 2002-11-15
BR0009020A (en) 2001-12-26
EP1161591A1 (en) 2001-12-12
AU3286600A (en) 2000-10-04
JP2002539342A (en) 2002-11-19
DE60000730T2 (en) 2003-07-31
EP1041192A1 (en) 2000-10-04
ES2186635T3 (en) 2003-05-16

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